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  • Articles  (22)
  • Geochemistry
  • diatoms
  • hydrogen bonding
  • Springer  (22)
  • 2020-2023
  • 1995-1999  (22)
  • 1996  (22)
  • Geosciences  (22)
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  • Articles  (22)
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  • Springer  (22)
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  • 2020-2023
  • 1995-1999  (22)
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  • 1
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    Journal of chemical crystallography 26 (1996), S. 747-752 
    ISSN: 1572-8854
    Keywords: Phosphine oxide ; quaternary ammonium ; water-soluble phosphine ; crystal structure ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the centrosymmetric triclinic space group $$P\bar 1$$ withZ=4. The crystallographic asymmetric unit contains two independent cations; interatomic distances within these include P=O=1.47(1) and 1.47(1) Å, P−C6H5=1.78(2)–1.81(1)Å and P−CH2CH2NMe3 +=1.80(1) and 1.81(1) Å. The phosphine oxide moiety is involved in intermolecular hydrogen bonding ()...H−C, with O...H≥2.42Å) and the iodide is involved in I...H−C contacts with I...H≥3.10Å.
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  • 2
    ISSN: 1572-8854
    Keywords: Ruthenium(II) ; bipyridyl ; phenyldi(o-tolyl)phosphine ; solvate ; hydrogen bonding ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The complexcis-[Ru(bpy)2{PPh(o-tolyl)2}Cl+][ClO4 −] crystallized from a solution in dichloromethane as the dichloromethane-water solvate. The structure was refined toR=4.5% for those 2433 reflections with |F o|〉6σ(|F o|). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru−Cl=2.434(3)Å, Ru-PPh(o-tol)2=2.382(2)Å, and Ru−N=2.037(7)–2.088(7)Å. The structure is stabilized by a hydrogen-bonded CH2Cl2...ClO4 −...H2O channel which incorporates adventitious water of crystallization.
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  • 3
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    Journal of chemical crystallography 26 (1996), S. 483-487 
    ISSN: 1572-8854
    Keywords: Steroid conformation ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystal structure of an orthorhombic polymorph of the title compound, crystallized by sublimation, has been determined. Dehydroepiandrosterone, C19H28O2, space groupP212121 witha=6.6408(4)b=11.4423(11)c=22.085(2)Å,V=1678.2(4)Å3,Z=4. The structure was refined toR=0.051 for 2645 observed reflections. The conformation of the molecule is similar to that found in other polymorphs and solvates, with a chair A ring, an 8β, 9α half-chair B ring, a chair C ring, and a 14α envelope D ring. Molecules are linked in chains by OH...O hydrogen bonds involving the carbonyl oxygen atom. The O...O distance is 2.855(3) Å, and the angle about H is 171(2)o.
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  • 4
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    Journal of chemical crystallography 26 (1996), S. 361-364 
    ISSN: 1572-8854
    Keywords: Crystal structure ; carboxylic acid ; phosphine oxide ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Diphenylphosphinylacetic acid crystallizes in the monoclinic space groupP2l/n with unit cell dimensionsa=5.6875(7),b=17.049(4),c=13.471(2) Å, β=93.36(1)° and Z=4. The molecular packing consists of hydrogen bonded chains arising from intermolecular interactions between a carboxylic acid hydroxyl group and an oxygen of an adjacent phosphine oxide moiety.
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  • 5
    ISSN: 1572-8854
    Keywords: Thiosemicarbazone ; 2-benzoylpyridine ; N4-substituted ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract 2-Benzoylpyridine N4-methyl-N4-phenylthiosemicarbazone, HBz4MePh, monoclinic,P2(1)/n a=9.141(2),b=18.507(4),c=11.401(2) Å, β=110.58(3)o,V=1805.6(9) Å3,Z=4, μ=1.655 mm−1. HBz4MePh crystallizes in a hydrogen bonded Z isomeric conformation with respect to the C7−N2 bond. The intramolecular hydrogen bond is between N3−H...N1, and the S atom isZ to the azomethine nitrogne, N2.
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  • 6
    ISSN: 1572-8854
    Keywords: Betaine ; 4-dimethylaminopyridinioacetate ; hydrogen bonding ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The crystalline dihydrate and hydrochloride trihydrate of a new betaine, namely, L·2H2O (1) and [L2H]Cl·3H2O(2) (L=p-Me2NC5H4N+CH2CO2), have been synthesized and characterized by X-ray crystallography. Molecule L in compound1 [space groupPbcn, witha=15.732(3),b=7.894(2),c=18.304(4) Å, andZ=8] possesses approximateC s symmetry. The formation of hydrogen bonds by water molecules bridging neighboring carboxy oxygen atoms leads to an infinite two-dimensional network composed of a packing of two different kinds of 12-membered rings. In compound2 [space group PT witha=7.341(2),b=9.543(2),c=17.010(4) Å, α=82.43(2)°, δ=80.34(2)°, λ=74.05(2)°, andZ=2], the carboxylate groups of a pair of betaine molecules are bridged by a proton to form a dimeric cation L2H+ with a very strong asymmetric hydrogen bond of length 2.464(7) Å. The crystal structure features a hydrogen-bonded corrugated ribbon comprising an alternate arrangement of edge-sharing centrosymmetric (H2O)4(Cl−)2 and (H2O)4 rings running parallel to thea axis.
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  • 7
    ISSN: 1572-8854
    Keywords: Bidentate ligand ; crystal structure ; pyrazolyl group ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound lies on a site of C2 symmetry, with the two planar pyrazolyl moieties oriented at 86.1° to one another. The hydrogen atoms were located and refined.
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  • 8
    ISSN: 1572-8854
    Keywords: Pyrazolyl group ; crystal structure ; bidentate ligand ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound consists of two planar pyrazolyl fragments oriented at 73.0° to each other and linked to a common carbon atom. All hydrogen atoms were located unambiguously and their positions were refined.
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  • 9
    ISSN: 1437-3262
    Keywords: L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome, Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote-plagioclase-blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiitesapproaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
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  • 10
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    Journal of paleolimnology 15 (1996), S. 19-45 
    ISSN: 1573-0417
    Keywords: diatoms ; grain-size analysis ; lake-level changes ; Lake Michigan ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleolimnological investigations of a marginal lake in the Lake Michigan basin revealed signals of long-term lake-level changes primarily controlled by climatic forces. Multiple analyses identified concurrent signals in sediment chemistry, grain size, and the microfossil record. Coarse-grained sediments, benthic diatoms, and nutrient response species increased as lake levels rose or fell. Finer sediments and higher percentages of taxa associated with stable thermocline conditions occurred during high-lake periods. Sedimentary evidence revealed corresponding strong high-lake signals c. 2500–2200, 1800–1500, 1170–730, and 500–280 BP. Low-lake periods occurred c. 1500–1170 and 700–500 B.P. An additional signal of lake-level decline was apparent beginning c. 280 BP but was interrupted by anthropogenic effects. Evidence of extreme low-lake levels (c. 1400–1300 BP), and signals for a medieval warming period (1030–910 BP) and the Maunder minimum (370–325 BP) indicate occurrence of short-lived dry climatic conditions.
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  • 11
    ISSN: 1573-0417
    Keywords: diatoms ; high arctic ; Ellesmere Island ; laminated sediments ; rheophilous ; river input ; marine isolation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms preserved in the sediments of Lake C2 (82°50′ N, 76°00′ W), a high arctic meromictic lake, track changes in the lake's salinity which have occurred as the basin was isolated from the sea. An assemblage dominated by marine taxa, such as Chaetoceros species, Nitzschia cylindrus and Diploneis spp., was replaced by a Cyclotella kuetzingiana var. planetophora dominated freshwater flora. A brief brackish period separates the two assemblages. Relatively little floristic change occurred within either the marine or freshwater periods, indicating rather stable environmental conditions, except that rheophilous diatoms fluctuated in relative abundance during the lacustrine phase, perhaps tracking past changes in discharge from inflowing streams. These may reflect periods of warmer, wetter environmental conditions.
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  • 12
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    Journal of paleolimnology 16 (1996), S. 323-354 
    ISSN: 1573-0417
    Keywords: diatoms ; chrysophytes ; pollen ; charcoal ; hemlock decline ; Holocene ; Massachusetts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We examined the stratigraphic record of North Pond, a small, oligotrophic lake in western Massachusetts, U.S.A. to describe late and post-glacial watershed-lake interactions. In particular we investigated the effects of two similar vegetation changes in the watershed on lake biogeochemistry. There was a transient (about 100 years) decline in hemlock ca. 7500 yr B.P. that has not been recorded in other pollen stratigraphies in the northeast. The second event was the classical hemlock decline that occurred ca. 4800 yr B.P. and lasted about 2000 years. This decline occurred throughout the range of hemlock and is thought to have been caused by a pathogen. As the climate began to warm ca. 10 000 yr B.P., a spruce dominated boreal woodland was established in the watershed. Sediment chemistry data showed that as soils became more acidic, the lake also acidified as evidenced by diatom-inferred (DI) pH. Hemlock was established in the watershed by about 8000 yr B.P. This was accompanied by a slight decrease in DI pH. The transient hemlock decline ca. 7500 yr B.P. was associated with an increase in sedimentary charcoal particles, that suggested fire was responsible for its demise. The diatom stratigraphy indicated a brief, slight, increase in productivity and alkalinity and a brief decrease in lakewater dissolved organic carbon concentrations. Aquatic microfossil data indicated a decrease in the area of the littoral zone ca. 7500 yr B.P. Following the transient decline the lake became more acidic. There were only brief, subtle changes associated with the classical hemlock decline, including a slight decline in DI pH. Although the two disturbances involved a similar vegetation shift, the timing and mechanisms of the disturbances had a greater impact on lake biogeochemistry.
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  • 13
    ISSN: 1573-0417
    Keywords: diatoms ; lotic diatoms ; varves ; paleolimnology ; turbidities ; high arctic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Both habitat preferences and community associations for some of the most prominent pennate taxa in our profile were established using samples from the modern lake and its watershed. Habitat preferences were used to establish a simple indicator for the relative contribution of lotic communities in this lake (Lotic Index) and indicator taxa for both littoral (Achnanthes spp. and Cymbella spp.) and lotic (Hannaea arcus and Meridion circulare) communities. When profiled, the Lotic Index showed a clear positive relationship to sedimentation rate as recorded in the varves, while profiles of littoral indicator taxa show the opposite trends. It seems likely that the patterns we observed in the Lotic Index are related to changes in runoff. Apparently, there was a period of declining runoff beginning ca. two centuries ago and ending in the late 1800's. This was followed by increasing runoff lasting until the middle of the 20th century. A brief minimum occurred in ca. 1970 followed by a recovery by ca. 1980. A strong positive relationship was also found between the dates of major turbidites, exceptionally thick varves and the concentration of valves in the sediment. It is possible that many of the thicker varves in the profiles contain littoral material transported to the site of deposition by turbid interflows and underflows. For this reason, the concentration of valves in the sediment in our cores appears to be a proxy for sediment deposition from turbidity currents.
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  • 14
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    Journal of paleolimnology 15 (1996), S. 129-132 
    ISSN: 1573-0417
    Keywords: meromixis ; diatoms ; laminations ; varves
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Meromixis has several powerful effects on lakes, yet there is no single definitive sediment indicator of meromixis. In this study three sediment indicators of meromixis were compared in Brownie Lake, Minneapolis, Minnesota, a small eutrophic lake that became meromictic around 1925. The results show that in Brownie the onset of laminations and changes in the iron to manganese ratio most likely occurred before the development of permanently anoxic bottom water and that changes in the diatom assemblage occurred later, most likely only when meromixis was well developed.
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  • 15
    ISSN: 1573-0417
    Keywords: lake developmental history ; diatoms ; sediment chemistry ; glacial refugia ; Baffin Island ; Arctic Canada
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment diatom and chemical analyses of cores from three poorly buffered extra-glacial lakes on the northeastern margin of the Canadian Shield (Cumberland Peninsula, Baffin Island) record interactions between aquatic and terrestrial spheres that were influenced by late Quaternary climatic conditions. Although differences exist between each of the lakes, notably with regards to the intensity of pre-Holocene catchment erosion and the timing of the onset of organic sedimentation, an underlying pattern of lake ontogeny, common to all three lakes, is identified. Although intensified watershed erosion characterized the Late Wisconsinan and Neoglacial cold periods, the lakes nonetheless remained viable ecosystems at these times. Sudden catchment stabilization during the late-glacial to earliest Holocene is associated with incipient organic sedimentation. Lake-water pH increased at this time, likely in response both longer base cation residence times as lake flushing rates decreased, and enhanced alkalinity production from sediment biogeochemical reactions. Subsequently, as the catchments remained stable during the productive early Holocene (c.9–7 ka BP), then gradually received a renewed increase of minerogenic sedimentation, the breakdown of sources of lake alkalinity resulted in natural acidification. Burial of cation-rich mineral sediments and the loss of permanent sedimentary sinks for the products of microbial reduction likely impeded within-lake alkalinity production, and catchment-derived base cations appeared ineffective in curtailing pH declines. The general nature of the Holocene development of these lakes is similar to that observed elsewhere on crystalline terrains, following deglaciation. Our data therefore suggest that catchment glaciation is not a necessary precursor for models of lake development characterized by initial base cation enrichment and subsequent gradual acidification.
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  • 16
    ISSN: 1573-0417
    Keywords: Hamilton Harbour ; paleolimnology ; diatoms ; sediment isotopes ; palynology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Limnological changes in Hamilton Harbour, Lake Ontario, over the Holocene were investigated by using proxy evidence from diatoms and other siliceous microfossils in a radiometrically dated sediment core (HH26comp), together with environmental data derived from sediment pollen and oxygen and carbon isotope analyses. The evidence demonstrates that the site of Hamilton Harbour has changed over the past 8300 y from a shallow, separate waterbody, to a deep embayment of Lake Ontario. The earliest evidence, from 8300 BP to 7000 BP, is of a mesotrophic pond of moderate alkalinity, warmer than present, and probably with an extensive marginal wetland. An initial transitory connection with the rising water level of Lake Ontario was established at c. 7000 BP, possibly via a deep outlet channel. This connection is 2000 y earlier then previously estimated. Permanent confluence with Lake Ontario was established at c. 6200 BP, causing a decline in inferred trophic level and water temperatures. Microfossils reach a minimum at 4400 BP coincident with the Nipissing Flood. Decreased mixing of Lake Ontario water from about 4000 BP following the Nipissing Flood highstand is evidenced in isotopic and diatom data. Three isolated shifts in the diatom spectrum at c. 4900 BP, 4500 BP, and 3500 BP may be associated with extreme turbidity or storm deposit events. Between 3200 BP and 280 BP, Hamilton Harbour was evidently a moderately alkaline embayment of Lake Ontario, oligotrophic to mesotrophic, and relatively cooler than present. The final 280 y sedimentary record reveals the magnitude of anthropogenically induced changes to the harbour, including eutrophication and organic pollution.
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  • 17
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    Journal of paleolimnology 15 (1996), S. 65-77 
    ISSN: 1573-0417
    Keywords: diatoms ; lake sediments ; pH ; alkalinity ; colour ; weighted averaging (WA) ; weighted averaging partial least squares (WA-PLS) ; calibration ; Northern Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The diatom composition in surface sediments from 119 northern Swedish lakes was studied to examine the relationship with lake-water pH, alkalinity, and colour. Diatom-based predictive models, using weighted-averaging (WA) regression and calibration, partial least squares (PLS) regression and calibration, and weighted-averaging partial least squares (WA-PLS) regression and calibration, were developed for inferences of water chemistry conditions. The non-linear response between the diatom assemblages and pH and alkalinity was best modelled by weighted-averaging methods. The lowest prediction error for pH was obtained using weighted averaging, with or without tolerance downweighting. For alkalinity there was still some information in the residual structure after extracting the first weighted-averaging component, which resulted in a slight improvement of predictions when using a two component WA-PLS model. The best colour predictions were obtained using a two component PLS model. Principal component analysis (PCA) of the prediction errors, with some characteristics of the training set included as passive variables, was performed to compare the results for the different alkalinity predictive models. The results indicate that calibration techniques utilizing more than one component (PLS and WA-PLS) can improve the predictions for lakes with diatom taxa that have broad tolerances. Furthermore, we show that WA-PLS performs best compared with the other techniques for those lakes that have a high relative abundance of the most dominant taxa and a corresponding low sample heterogeneity.
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  • 18
    ISSN: 1573-0417
    Keywords: palaeolimnology ; acidification ; diatoms ; chrysophytes ; pigments ; chironomids ; temperature ; Alps ; Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A palaeoecological study of an oligotrophic alpine lake, Paione Superiore (Italy), provided a record of historical changes in water quality. Historical trends in lake acidification were reconstructed by means of calibration and regression equations from diatoms, chrysophycean scales and pigment ratios. The historical pH was inferred by using two different diatom calibration data sets, one specific to the alpine region. These pH trends, together with the record of sedimentary carbonaceous particles and chironomid remains, indicate a recent acidification of this low alkalinity lake. Concentration of total organic matter, organic carbon, nitrogen, biogenic silica (BSiO2), chlorophyll derivatives (CD), fucoxanthin, diatom cell concentration and number of chironomid head capsules increased during the last 2–3 decades. When expressed as accumulation rates, most of these parameters tended to decrease from the past century to c. 1950, then all except P increased to the present day. A marked increase in sedimentary nitrogen may be related to atmospheric pollution and to the general increases in output of N in Europe. High C/N ratios indicate a prevailing allochthonous source of organic matter. Finally, the increase in measured air temperature from the mid-1800's appeared to be related to lake water pH before industrialization: cold periods generally led to lower pH and vice-versa. The more recent phenomenon of anthropogenic acidification has apparently decoupled this climatic-water chemistry relationship.
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  • 19
    ISSN: 1432-0495
    Keywords: Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minor amounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0,33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe 〉 Mn 〉 Cr 〉 Zn 〉 Ni 〉 Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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  • 20
    ISSN: 1432-0495
    Keywords: Key words Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minoramounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0.33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe〉Mn〉Cr〉Zn〉Ni〉Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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  • 21
    ISSN: 0016-7835
    Keywords: Key words L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome ; Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote–plagioclase–blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiites approaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
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  • 22
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    Geologische Rundschau 85 (1996), S. 162-171 
    ISSN: 0016-7835
    Keywords: Key words KTB pilot hole ; Metabasites ; Geochemistry ; Sr ; Nd isotopes ; Fluid ; Lamprophyre
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Geochemical analyses were interpreted on the dominant lithological units and on a deep crustal fluid from the Continental Deep Drilling Project (KTB) Pilot Hole, situated at the western margin of the Variscan Bohemian Massif. The biotite gneiss (from 384 m depth) shows a rare earth element pattern very similar to the European shale composite with Nd model ages of 940 Ma (CHUR) and 1.4 Ga (DM). The lamprophyre dike in the upper profile (1549 m), a nepheline and olivine normative basalt, is geochemically and isotopically similar to rocks from the Tertiary Central European Volcanic Province. The lower metabasite sequence (3575–4000 m), with an intrusion age of approximately 500 Ma, is made up primarily of highly metamorphosed subalkalic olivine basalts. The geochemical characteristics of the metabasites are a (La/Yb)N of 5–10, an La concentration of 20–50 times chondrite as well as (87Sr/86Sr)i of 0.7035–0.7038 and εNd(T) of 4–6. These values suggest a depleted mantle source for the igneous precursors, evolving by assimilation-fractional crystallization processes with up to 25% of upper crust into the ultramafic, basaltic, and intermediate rock types of the metabasite sequence. The strong geochemical and chronological similarities between the KTB metabasites and rocks from the Münchberg Massif suggest that these units belong to the same lithological complex. The high salinity as well as the radiogenic 87Sr/86Sr ratio of 0.709413 in the KTB fluid from 4000 m depth might be the result of migrating fluids reacting with the regional Permo-Mesozoic evaporite deposits, followed by extensive Sr isotopic exchange with the upper crust.
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