ALBERT

Description: REITNER, Joachim & KOHRING, Rolf: Prof. Dr. Gundolf ERNST zum 65. Geburtstag. Eine kritische Würdigung des Jubilars ... 5 ; VOIGT, Ehrhard & GORDON, Dennis P.: Ascancestor and Confusocella - two new genera of cheilostomate Bryozoa from the Upper Cretaceous with transitional frontal-shield morphologies ... 15 ; KENNEDY, William J. & KAPLAN, Ulrich: Pseudojacobites farmeryi (CRICK, 1905), ein seltener Ammonit des westfälischen und englischen Ober-Turon ... 25 ; SEIBERTZ, Ekbert & SPAETH, Christian: Die Kreide-Belemniten von Mexiko II. Belemniten des Turon Nord-Mexikos ... 45 ; WIESE, Frank & WILMSEN, Markus: Erstnachweis aus Europa von Litophragmatoceras incomptum (Ammonoidea, Kreide) aus dem Mittel-Cenoman von Liencres (Kantabrien, Nordspanien) ... 53 ; WIESE, Frank: Das mittelturone Romaniceras kallesi-Event im Raum Santander (Nordspanien): Lithologie, Stratigraphie, laterale Veränderung der Ammonitenassoziationen und Paläobiogeographie ... 61 ; KRÜGER, Fritz J.: Leere Oberkretazische Echiniden-Coronen als Habitat benthonischer Organismen ... 79 ; MEHL, Dorte & NIEBUHR, Birgit: Diversität und Wachstumsformen bei Coeloptychium (Hexactinellida, Lychniskosa) der Meiner Mulde (Untercampan, NW-Deutschland) und die Palökologie der Coeloptychidae ... 91 ; REHFELD, Ursula & OTTO, Armin: Distribution and preservation of siliceous sponges of the rhythmically bedded spongiolitic rocks in the Lower Campanian of northern Spain (Cantabria, Santander area): Response to autecology and sea level development ... 109 ; FECHNER, Glenn G.: Phytoplankton und Sporomorphen aus dem Cenoman-Basiskonglomerat von Bochum (Nordrheinwestfalen, Deutschland) ... 129 ; KEUPP, Helmut: Die kalkigen Dinoflagellaten-Zysten aus dem Ober-Alb der Bohrung Kirchrode 1/91 (zentrales Niedersächsisches Becken, NW-Deutschland) ... 155 ; VOIGT, Silke: Verbreitung humider und arider Klimate der nördlichen Hemisphäre während der Oberkreide ... 201 ; HORNA, Frank: Komplexer Nachweis einer Tufflage im Turon von Hoppenstedt ... 207 ; WRAY, David S. & WOOD, Christopher J.: Geochemical identification and correlation of tuff layers in Lower Saxony, Germany ... 215 ; MUTTERLOSE, Jörg & WIEDENROTH, Kurt: Die Bio- und Lithofazies der Unterkreide (Hauterive bis Apt) in NW-Deutschland ... 227 ; TRÖGER, Karl-Armin & VOIGT, Thomas: Event-und Sequenzstratigraphie in der Sächsischen Kreide... 255 ; SEIBERTZ, Ekbert: Towards the single-species boundary definition - a concept proposal with application to the Turonian-Coniacian stage boundary (Upper Cretaceous) ... 269 ; WOOD, Christopher J. & MORTIMORE, Rory N.: An anomalous Black Band succession (Cenomanian - Turonian boundary interval) at Melton Ross, Lincolnshire, eastern England and its international significance ... 277 ; KUTZ, Andreas: Kalk-Mergel-Rhythmite der Oberkreide (Campan und Maastricht) am Massiv von Oroz Betelu (N-Spanien, Provinz Navarra). Ein Exkursionsführer ... 289 ; WOLF, Ernst-Otto.: Sedimentologie, Paläogeographie und Faziesentwicklung der Allochthonite des Campan von Beckum/Zentrales Münsterland ... 305 ; KRIWET, Jürgen & GLOY, Uwe: Zwei mesopelagische Raubfische (Actinopterygii: Euteleostei) aus dem Unterturon der Kronsberg-Mulde bei Hannover / Misburg (NW-Deutschland) ... 335 ; RAUHUT, Oliver W.M.: Zur systematischen Stellung der afrikanischen Theropoden Carcharodontosaurus STROMER 1931 und Bahariasaurus STROMER 1934 ... 357 ; WERNER, Christa: Neue Funde von mesozoischen Wirbeltieren in Äthiopien... 377 ;

Description: commemorativepublication

Description: DFG, SUB Göttingen

Description: SCHUDACK, Michael E.: Neue mikropaläontologische Beiträge (Ostracoda, Charophyta) zum Morrison-Ökosystem (Oberjura des Western Interior, USA) ... 389 ; BARTHOLDY, Jan, BELLAS, Spyridon M., MERTMANN, Dorothee, MACHANIEC, Elsbieta & MANUTSOGLU, Emmanuil: Fazies- Entwicklung und Biostratigraphie einer Sequenz eozäner Sedimente im Steinbruch Pod Capkami, Tatra-Gebirge, Polen ... 409 ; SCHULZ, Eberhard: Palynologische Untersuchungen des marinen Mittelrhäts im Creuzburger Graben bei Eisenach (W-Thüringen) ... 427 ; KRUTZSCH, Wilfried: Verbreitung der Trockenzonen im Kainophytikum - Eine Skizze ... 439 ; KOHRING, Rolf & SCHLÜTER, Thomas: Erhaltungsmechanismen känozoischer Insekten in fossilen Harzen und Sedimenten ... 457 ; ZILS, Wolfgang, WERNER, Christa, MORITZ, Andrea & SAANANE, Charles: Orientierende Tendaguru-Expedition 1994 ... 483 ; KIENEL, Ulrike, REHFELD, Ursula & BELLAS, Spyridon M.: The Miocene Blue Clay Formation of the Maltese Islands: Sequence-stratigraphic and palaeoceanographic implications based on calcareous nannofossil stratigraphy ... 533 ; SOUJON, Andr6, MANUTSOGLU, Emmanuil, REITNER, Joachim & JACOBSHAGEN, Volker: Lithistide Demospongiae aus der metamorphen Plattenkalk-Serie der Trypali Ori (Kreta/Griechenland) … 559 ; BARON-SZABO, Rosemarie C.: Taxonomy and Palaeoecology of Late Miocene corals of NW-Crete (Gramvoüssa, Roka- and Koukounaras- Fms.) ... 569 ; MANUTSOGLU, Emmanuil, MERTMANN, Dorothee, SoujON, Andre, DORNSIEPEN, Ulrich Friedrich & JACOBSHAGEN, Volker: Zur Nomenklatur der Metamorphite auf der Insel Kreta, Griechenland ... 579 ; FRYDAS, D., KONTOPOULOS, N., STAMATOPOULOS, L., GUERNET, C. & VOLTAGGIO, M.: Middle-Late Pleistocene sediments in the northwestern Peloponnesus, Greece. A combined study of biostratigraphical, radiochronological and sedimentological results ... 589 ; BECKER, R. Thomas: Taxonomy and Evolution of Late Famennian Tornocerataceae (Ammonoidea) ... 607 ; GRÖSCHKE, Manfred & KAPILIMA, Saldi: Ammoniten aus dem Septarienmergel (Kimmeridgium) des Mandawa-Mahokondo-Gebietes bei Nchia, Südtansania ... 645 ; KEUPP, Helmut & RIEDEL, Frank: Nautilus pompilius in captivity: a case study of abnormal shell growth ... 663 ; KRIWET, Jürgen: Beitrag zur Kenntnis der Fisch-Fauna des Ober-Jura (unteres Kimmeridge) der Kohlengrube Guimarota bei Leiria, Mittel-Portugal: 1 . Asteracanthus biformatus n. sp. (Chondrichthyes: Hybodontoidea) ... 683 ; MARTIN, Thomas: Incisor enamel microstructure and phylogenetic interrelationships of Pedetidae and Ctenodactyloidea (Rodentia) ... 693 ; ERESKOVSKY, Alexander V.: Materials to the Faunistic Study of the White and Barents seas sponges. 5. Quantitative Distribution ... 709 ; ERESKOVSKY, Alexander V.: Materials to the Faunistic Study of the White and Barents seas sponges. 6. The origin of the White and Barents seas sponge faunas ... 715 ; WÖRHEIDE, Gert: Bi- und multivariate Analyse borealer und mediterraner Populationen der Echinocardium cordatum - Gruppe (Echinoidea; Spatangoida) ... 731 ; HILBRECHT, Heinz: Computergestützte Methoden in der Morphometrie ... 765 ; CLAUSING, Andreas: Some critical notes on qualitative versus quantitative analysis in terrestrial palaeoecology ... 781 ; GLOY, Uwe: Bibliographie 1994, Institut für Paläontologie, Freie Universität Berlin ... 787 ;

Description: commemorativepublication

Description: DFG, SUB Göttingen

Description: Am Westrand des Basko-Kantabrischen Beckens (Soba-Region, Prov. Cantabria, Nordspanien) sind die Plattform/Becken-Übergangszonen des Apt und Alb in nahezu ungestörtem Verband erhalten. Entlang dieser Randzonen befinden sich großdimensionierte Mud Mound-Strukturen mit einer Basisbreite bis 150 m und einer Höhe bis zu 70 m. Diese Arbeit zielt auf die Erarbeitung der Prozesse, die die Bildung der Mounds begleiten, beeinflussen oder steuern. Das Intervall Oberapt (Clansay) bis Mittelaib besteht aus sechs sedimentär-diagenetischen Zyklen (asymmetrische Trans-, Regressionszyklen), die in Kombination mit Markerhorizonten eine stratigraphische Kontrolle über den Plattform/Becken-Transekt ermöglichen. Meeresspiegelschwankungen (Paläokarst) sind im Apt/Alb-Grenzintervall und hohen Unteralb (Ammonitenzone: Douvilleiceras mammilatum) nachweisbar. Die Vorkommen der Mud Mounds sind an transgressive Faziesdiskontinuitäten gebunden. Ihre Position entspricht dem zu Strömungen exponierten Hang und dem oberen Plattformrand. Die Biofazies reicht von einer aphotischen Gemeinschaft aus “Lithistida“, Hexactinellida, krustosen Foraminiferen, Polychaeten, Thecideen und Acanthochaeteten zu der photischen Biofazies mit Scleractinia, Lithophyllum und Bacinella/Lithocodium. Die Strukturbildung erfolgt durch eine autochthone Mikritproduktion (Automikrit). Akkretionäre Automikrite bilden Stromatolithe, Thrombolithe und massive Gefügetypen. Container-Automikrit befindet sich in geschützten und geschlossen Räumen. Kieselschwamm Container-Automikrite sind aphanitisch, peloidal und peloidal-bakterioform. Unabhängig von Kieselschwämmen treten Container-Automikrite in Kleinhöhlen, Taschen und im Interpartikelvolumen auf. Sie bestehen aus in-situ Peloiden und in-situ Ooiden mit massivem und/oder stromatolithischem Gefüge. Die verschiedenen Automikrittypen besetzen zwischen 50 und 80 Vol.-% der Mud Mounds. Anbohrungen durch lithophage Bivalven und Aka sowie die ausschließliche Produktion angularer Mound-Lithoklasten belegen eine Lithifizierung in statu nascendi. Die Primärmineralogie der Automikrite ist Hoch-Mg-Calcit; die Residualgehalte an MgCOa liegen zwischen 1 ,2 und 3,6 Mol-%. Die Zusammensetzung der stabilen Isotope S13C und S18O (vs PDB) ist analog zu anorganisch gebildeten, marinen Zementen (513C von 2,9 bis 3,8 und S18O von -1,5 bis -4). Die vergleichende Aminosäuren-Analyse ergibt ein relatives Maximum bei Glu und Asp, Pyruvaten und Glycin, resp. Tyrosin. Das Spektrum ist analog zu den Literaturdaten von modernen Automikriten aus Riffhöhlen von Lizard Island (GBR) und unterscheidet sich grundlegend von den strukturgebundenen Skelett-Automikriten von Bacinella/Lithocodium. Die Biomarker-Analyse akkretionärer Automikrite ergab ein spezifisches n-Alkan Muster, ebenfalls vergleichbar mit Spektren rezenter Thrombolithe (Lizard Island) und Beispielen der oberjurassischen Spongiolith-Fazies. Die Grundvoraussetzung der Mud Mound-Genese ist daher die Bereitstellung saurer Makromoleküle (Organomikrit) und eine anhaltend ungestörte Wechselwirkung mit dem umgebenden Medium. Die chemische Randbedingung ist eine erhöhte Karbonatalkalinität. Nach mikrofaziellen Kriterien ist Organomikrit ein faziesbrechendes Element der unterkretazischen Plattformränder. Beispiele reichen von karbonatischen Barrensanden mit Organomikrit-Rindenkörnern, über deltaische Sandsteine (Organomikrit um Quarz) bis zu Kondensationshorizonten auf Paläokarst sowie Drowning-Sequenzen auf Korallenpflastern (Sclercatinia zu Kalkalgen zu Thrombolith). Die Bildung der Mud Mounds (Organomikrit-Riffe) der Soba-Region ist korreliert mit einer regional extrem herabgesetzten Karbonatproduktion. Diese durch terrigenen Input und mögliche Eutrophierungen verursachten Produktionskrisen setzten die relativ uneffektive Organomikritproduktion in Vorteil gegenüber den stenoöken Gemeinschaften der euphotischen Zone. Die erhöhte Karbonatalkalinität kann von der Zufuhr der Verwitterungslösungen (regional) und dem Abau organischer Substanzen abgeleitet werden (lokal, Sulfatreduktion). Möglicherweise bestand ein Zusammenhang mit der Auslaugung von Keuperdiapiren.

Description: At the western margin of the Vasco-Cantabrian Basin (Soba-Region, Prov. Cantabria, N-Spain) the primary facies architecture of the Aptian-Albian platform/basin transition is well preserved. Along these zones large-scaled mud mounds reach 70 meters in height with a basal diameter of up to 150 meters. Aim of this work is to point out processes that are limited to coexistance and such that influence or even control mud mound formation. The Upper Aptian (Clansayesian) to Middle Albian interval consists of six sedimentary-diagenetic cycles that represent asymmetric transgressive/regressive facies sequences. In combination with marker horizons these cycles provide a stratigraphic control across the platform/basin transition. Sea-level changes recorded as paleokarst are documented in the Aptian/Albian boundary interval and within the upper parts of the Lower Albian (ammonite zone: Douvilleiceras mammilatum). Mud Mounds follow transgressive discontinuities of facies. These structures are both located at slopes facing wave-induced current systems and at the upper platform margin. The involved biofacies include an aphotic community with lithistid demosponges, hexactinellids, encrusting foraminifera, polychaetes, thecidean brachiopods and acanthochaetetids as well as a photic community with scleractinian corals, calcareous algae such as Lithophyllum and the problematic structure of Bacinella/ Lithocodium. Mud mounds are constructed by autochthonous production of micrite (automicrite). Accretionary automicrites form stromatolites and thrombolites as well as massive fabrics. Container-automicrite is restricted to protected and closed spaces. Container-automicrites of siliceous sponges reveal aphanic, peloidal and peloidal-bacterioform microfabrics. However, container-automicrite may also occur within minicaves, pockets and the interstitial space of rudstones lacking any sponge evidence. These automicrites consist of in-situ peloids and in-situ ooids forming massive and/or stromatolitic microfabrics. All automicrites, variously developed, hold 50 to 80 % of the total mud mound volume. Borings by lithopagous bivalves and sponges (Aka) and additionally the exclusive occurrence of angular mound lithoclasts provide evidence for lithification in statu nascendi. The primary mineralogy of the automicrites is high Mg-calcite with residual MgCOa-contents between 1.2 and 3.6 mole-%. The composition of stable isotopes (S13C and S18O vs. PDB) goes along with inorganically precipitated marine cements (813C: 2.9 to 3.8, S18O: -1,5 to -4). The comparative analysis of amino acid quantity reveals relative maxima of glutamin and asparagin, pyruvates and glycin as well as tyrosin. The relative amounts of amino acids are very similar to those obtained from modern automicrites of Lizard Island reef caves (GBR) and are clearly seperated from skeletal automicrites of Bacinella/ Lithocodium. In addition, biomarker analysis of accretionary automicrites resulted in a specific n-alkane pattern comparable to literature data of modern marine thrombolites (Lizard Island) and Upper Jurassic spongiolites. According to these results, the basic neccessity for mud mound genesis is the occurrence of acidic macromolecules producing a specific automicrite (organomicrite) and their persistent interaction with thesurrounding medium. Chemically, an increased carbonate alkalinity is required. Thin section analysis provides evidence that organomicrite is a widespread element of Lower Cretaceous platform margins overlapping different facies zones. These include carbonate shoal sediments with organomicrite-coated grains and deltaic sandstones with organomicrite-coated quartz grains. Further examples are intervals of stratigraphic condensation overlaying paleokarst or drowning sequences following a succession from scleractinian corals towards calcareous algae and thrombolites. On the regional scale mud mounds (organomicrite reefs) of the Soba-Region correlate with times of drastically reduced carbonate production. This, potentially caused by terrigenous input and episodes of eutrophism, leads to a dominance of the relatively ineffective production of organomicrite over the highly productive stenotopic (euphotic) communities. An increase of carbonate alkalinity can be deduced from regional scale continental weathering and from sulfate reduction on local scale. Possibly, a correlation between brines of subsoluted diapirs (Keuper) and the formation of automicrites might have existed.

Description: thesis

Description: DFG, SUB Göttingen

Description: In der vorliegenden Arbeit wird die Krustenstruktur im östlichen Andenvorland untersucht. Das Gebiet umfaßt den Nordwesten Argentiniens, zwischen dem 22° und 25° südlichen Breitengrad und dem 66° und 62° westlichen Längengrad. Aus morphologischer Sicht befindet sich das Untersuchungsgebiet im Übergang zwischen dem Subandin (Sierras Subandinas) und der südlichen Ostkordillere zum Chaco Vorland (Llanura Chaqueña). Im Untersuchungsgebiet zeichnet sich ein Wechsel in den tektonischen Strukturen ab, welcher als Interaktion zwischen der tertiären Andenorogenese und kretazischen Riftbildungen gedeutet wird. Dieser als Inversionstektonik bekannte tektonischer Stil hat nicht nur oberflächennahe Strukturen hervorgerufen, sondern auch tiefgreifende Massenveränderungen verursacht. Teile dieser Modifikationen sind in der Signatur des Schwerefeldes erhalten geblieben, und somit ist die Interpretation gravimetrischer Meßergebnisse zusammen mit den geologischen Randbedingungen eine Grundvorraussetzung zur Untersuchung dieser tektonischen Interaktion. Zum Verständnis dieser Strukturen war es notwendig, sowohl den Teil des Beckens zu untersuchen, welcher nicht von der andinen Orogenese betroffen ist, als auch jenen der direkt in die letztere miteinbezogen wurde. Aus gravimetrischer Sicht ist die Bougueranomalie des Gebietes stark vom Effekt der Andenwurzel geprägt. Jedoch deuten einige Abweichungen auf die Existenz lokalerer Störkörper hin, die Ziel der Modellierung waren. Ein solcher Störkörper wurde am südöstlichen Rand des kretazischen Rifts identifiziert. Die Modellierung wurde einerseits zweidimensional durchgeführt um einen Überblick über das Gebiet zu bekommen. Eine regionale 3D Modellierung führte dann zu einer präziseren Interpretation des Gebietes. Insbesondere wurde dabei der Effekt überschobener Riftschollen am Ostrand des Beckens untersucht. Diese Überschiebungen drücken sich im gravimetrischen Restfeld als deutliche positive Anomalie aus. Allerdings kann diese Anomalie nicht direkt mit einem Astenosphärenanstieg, welcher durch Riftbildung entstanden sein könnte, in Einklang gebracht werden - wie von einigen Autoren vermutet wurde. Eine weitere modellierte Struktur bildete die Vortiefe, welche durch die Auflast der andinen Überschiebung enstanden ist. Die dadurch hervorgerufenen negativen Anomalien bilden einen deutlichen Kontrast zu der beschriebenen positiven Anomalie im Vorland, der sich auch im Restfeld als starker Gradient äußert. Die 2D Modellierung erbrachte folgende Ergebnisse: im anorogenen Breich des Untersuchungsgebietes wurde die Existenz einer deutliche Asymmetrie des Beckens bestätigt, mit einer nach Südosten geneigten Riftabscherungsfläche. Die Orogenese hinterließ deutliche Spuren in der Reaktivierung der Abscherungen wobei entlang der südostvergenten Störungen tieferes Krustenmaterial emporgeschoben wurde. Mit einer größeren Dichte wird dieser Vorgang als Ursache der positiven Anomalie intepretiert. Westvergente Störungen scheinen nur oberflächennahe Bereiche miteinbezogen haben. Im regionalen 3D Modell wurde ein Ansteigen der Unterkruste unterhalb des Beckens angenommen. Die asymmetrische Anordnung dieses Anstiegs deutet eher auf einen kompressive tektonischen Effekt hin als auf eine residuale Krustenverdünnung. Zusammenfassend kann gesagt werden, daß sich in diesem Breich im Schwerefeld die Effekte des Andengradienten mit denen der überschobenen Basement-Tektonik und der Vorlandtief kombinieren und als solche fur einen starken lokalen Gradienten am Rande des Effekts der Andenwurzel verantwortlich sind.

Description: In the present study, the structure of the crust beneath the eastern Andean foreland is analyzed. The area comprises part of northwest Argentina, between 22° and 25° S and 66° and 62° W. In terms of morphotectonics, the area studied covers the transition between the Sierras Subandinas (Subandean Ranges) and the southern part of the Cordillera Oriental (Eastern Cordillera) to the Chaco plains (Llanura Chaqueña). In the area, a pervasive change controls the tectonic features, which is interpreted as a consequence of the interaction between the Andean orogeny and preexistent Cretaceous rifting. This inversion tectonics did not only result in a particular suite of near to surface structures but also modified deeply the mass distribution within the crust. This changes in mass distributions and hence density contrasts is evidenced by the gravity field. As such, a careful analysis of gravity data together with the geological boundary conditions are the basis for an analysis of this tectonic interaction. Understanding these structures implied to analyse not only the part of the rift involved in the Andean compressive orogenesis but also that part where original extensional features are still preserved. From a gravimetrical point of view, the Bouguer-anomaly of the area shows a strong overprint related with the Andean root. Some smaller changes in the field however indicate the existence of local sources, which where the target of the modelling. Such a change had been indentified at the southeastern edge of the Cretaceous rift. Modelling was performed towfold. As such, a 2D model was made in order to get an insight into the regional aspects of the area. A more detailed 3D model led to a more precise interpretation of the area. In particular, the effect of the inverted rift tectonics at the eastern edge of the basin was studied. These upthrusts correlate with a readily identifiable positive anomaly within the residual field. The anomaly neverthless cannot be directly related with an astenospheric uprise, preserved since the rifting stage, as suggested by some authors. In addition, the foredeep related with the tectonic load of the Andean overthurst, was modelled. The negative anomalies generated during this process, show a strong contrast in comparison with the positive anomaly described above, depicted also by a prominent gradient in the residual field. 2D modelling led to the following results. In the region, where Creataceous rifting structures were not overprinted by the Andean orogeny an obvious asymmetry of the basin was defined, being the master detachment dipping to the northeast. The orogeny left evidences of reactivation, where the structures of the southeastern edge were the pathways of the uplift if deeper crustal material with a higher density. This process may be responsible for a part of the positive anomaly mentioned. Structures located at the western and northwestern edge of the basin seem to have only involved nearer-to surface structures. The 3D model assumed a slight uprise of the lower crust beneath the basin. The asymmetry in goemetty seem to stand more for a tectonic effect than for a remanent thinned crust. As a summary, the gravity field in this area shows the combined effects of the regional Andean gradient with the more local effects of the basement tectonics (inverted rifting) and the overthrusted foredeep. Hence, at least these three factors seem to be responsible for the strong local gradient in a lateral position of the Andean root.

Description: thesis

Description: DFG, SUB Göttingen

Description: In dieser Arbeit wurden Laborexperimente im Ultraschallfrequenzbereich und begleitende theoretische Untersuchungen durchgeführt, um zu klären, welche Absorptionsmechanismen in fluidhaltigen Sandsteinen bei geringem einaxialen (26 MPa) und bei erhöhtem hydrostatischen Druck (bis 200 Mpa) wirksam sind. Die Kenntnis der Absorptionsmechanismen ist notwendig, um die Zusammenhänge von lithologischen und seismischen Gesteinsparametern zu verstehen und für die Interpretation von seismischen Feldmessungen zu nutzen. Bekannt war bislang, daß unter geringem einaxialen Druck frequenzabhängige lokale Flüssigkeitsströmungen den wesentlichen Absorptionsmechanismus in fluidhaltigem Gestein darstellen. Im Rahmen der vorliegenden Arbeit wurde gezeigt, daß die Kompressionswellengeschwindigkeit in fluidhaltigem Gestein bei höheren Sättigungsgraden zusätzlich von einem partiellen Gesteinsversteifungseffekt beeinflußt wird. Damit gelang eine vollständige Erklärung des sättigungsabhängigen elastischen und anelastischen Gesteinsverhaltens bei geringem einaxialen Druck. Um die Bedeutung der Gesteinsmikrostruktur (z.B. Rißdichte, Kornkontakte) für die seismischen Gesteinsparameter (Geschwindigkeit, Absorption) direkt nachzuweisen, wurde diese bei einem Gestein künstlich, thermisch verändert. Die Änderung der Mikrostruktur führt bei gleichzeitiger vernachlässigbarer Änderung der makroskopischen Gesteinsparameter (Porosität, Permeabilität) zu einer Vergrößerung der Fluideffekte. Mechanismen und Modelle, in welche ausschließlich makroskopische Gesteinsparameter ein- gehen, erfassen nicht die beobachteten Änderungen im Gesteinsverhalten. Nur mit dem auf die Gesteinsmikrostruktur bezogenen Mechanismus lokaler Flüssigkeitsströmungen konnten die Änderungen der Fluidwirkungen erklärt werden. Diese Ergebnisse an verändertem Gestein bieten somit einen direkten Beweis für den grundlegenden Einfluß der Mikrostruktur auf die seismischen Gesteinsparameter. Bislang war nicht geklärt, ob der Mechanismus lokaler Flüssigkeitsströmungen, welcher von der Existenz feiner Spalten im Gestein abhängt, auch unter erhöhtem hydrostatischen Druck das Gesteinsverhalten bestimmt. Zur Untersuchung der Absorptionsmechanismen in Gestein unter erhöhtem Druck wurden Experimente an Sandstein mit verschiedenen Saturanden und Sättigungsgraden durchgeführt. Die experimentellen Ergebnisse zeigen, dass auch unter erhöhtem Druck fluidbedingte Absorptionsmechanismen wirksam sind und auch hier polare Fluide im gesamten Druckbereich eine Modulerniedrigung verursachen. Der Vergleich der experimentellen Ergebnisse mit Modellvorhersagen ergab, daß lokale Flüssigkeitsströmungen den Einfluß unterschiedlicher Fluide auf Geschwindigkeit und Absorption erklären und auch unter hohem hydrostatischen Druck von wesentlicher Bedeutung für die elastischen und anelastischen Gesteinseigenschaften sind. Folglich existieren trotz einer partiellen Rißschließung auch unter hohem hydrostatischen Druck noch Risse und Spalten im Gestein. Die thermische Veränderung der Mikrostruktur eines Gesteins bewirkt eine Geschwindigkeitserniedrigung im trockenen Gestein, welche auch bei hohem hydrostatischen Druck erhalten bleibt, sowie eine Vergrößerung der Fluideffekte. Die Erklärung des geänderten Verhaltens des fluidhaltigen Gesteins gelang mit dem Mechanismus lokaler Flüssigkeitsströmungen. Die Ergebnisse an verändertem Gestein zeigen direkt, daß die Mikrostruktur auch bei hohem hydrostatischen Druck grundlegend für die seismischen Gesteinsparameter ist. Da auch unter erhöhtem hydrostatischem Druck, also unter ’in-situ’-Bedingungen, der frequenzabhängige Mechanismus lokaler Flüssigkeitsströmungen die seismischen Gesteinsparameterwesentlich beeinflußt, muß diese Frequenzabhängigkeit bei der Übertragung von Laborergebnissen auf die Feld- und Bohrlochseismik beachtet werden.

Description: Laboratory experiments in the ultrasonic frequency range and accompanying theoretical investigations were performed with the aim to clarify which absorption mechanisms are effective in fluid-containing sandstones at low uniaxial pressure (26 MPa) and at elevated hydrostatic pressure (up to 200 MPa). The knowledge of the effective absorption mechanisms is necessary to understand the relation of lithological and seismic rock parameters and to use it for the interpretation of seismic field measurements. Preceding investigations at the TU-Berlin had revealed that at low uniaxial pressure frequency dependent local-fluid-flow is the dominating absorption mechanism in fluid-containing rock and that polar fluids lead to a modulus reduction. Within the scope of the present study the investigations of the seismic rock parameters (velocity, attenuation) at low uniaxial pressure were continued. It was shown that the compressional wave velocity in fluid-containing rock is additionally influenced by a partial rock stiffening effect at higher saturations. With this result a complete explanation of the saturation dependent elastic and anelastic rock behaviour at low uniaxial pressure was achieved. To prove the significance of the rock microstructure (e.g. crack density, crack aspect ratios, grain contact properties) for the seismic rock parameters directly, the microstructure of a sandstone was artificially changed by thermal cracking. With negligible changes of the macroscopic rock parameters (porosity, permeability) the alteration of the microstructure leads to an increase of the fluid effects on the elastic and anelastic rock properties. Mechanisms and models which are solely based on macroscopic rock parameters do not cover the observed changes in the rock behaviour. Only by applying the mechanism of local-fuid-flow related to microstructure the changes in the fluid effects can be explained. Thus these results obtained on thermally changed rock are a direct prove of the fundamental influence of the microstructure on the seismic rock parameters. Until now it has not yet been clarified whether the mechanism of local-fluid-flow which depends on the existence of narrow cracks in rock also determines the rock behaviour under elevated hydrostatic pressure. To investigate the absorption mechanisms in rock under elevated pressure ultrasonic measurements were performed on sandstone with different saturands and degrees of saturation. The experimental results reveal that under elevated pressure fluid dependent attenuation mechanisms are effective too and polar fluids cause a modulus reduction in the entire pressure range. The comparison of the experimental results with model predictions reveals that local-fluid-flow explains the influence of different fluids on the velocity and attenuation and that this mechanism is of essential significance for the elastic and anelastic rock properties even under high hydrostatic pressure. Consequently despite a partial crack closure sufficient fine cracks exist even under high hydrostatic pressure. The thermal alteration of the microstructure of a rock leads to a velocity decrease in the dry rock which is preserved at high hydrostatic pressure, as well as to an increase of the fluid effects. The explanation of the changed behaviour of the fluid-containing rock was achieved by means of the mechanism of local-fluid-flow. The results obtained on altered rock directly demonstrate that the microstructure is of fundamental significance for the seismic rock parameters at high hydrostatic pressure too. Depending on the rock microstructure the mechanism of local-fluid-flow may cause attenuation and dispersion in all frequency ranges. Since it has been shown in this study that also under elevated hydrostatic pressure, i.e. under ’in-situ’conditions, this frequency dependent mechanism essentially influences the seismic rock parameters, the frequency dependence must be taken into account by extrapolating laboratory results to field and borehole seismic.

Description: thesis

Description: DFG, SUB Göttingen

Description: A non-Fickian physico-chemical model for electrolyte transport in high-ionic strength systems is developed and tested with laboratory experiments with copper sulfate as an example electrolyte. The new model is based on irreversible thermodynamics and uses measured mutual diffusion coefficients, varying with concentration. Compared to a traditional Fickian model, the new model predicts less diffusion and asymmetric diffusion profiles. Laboratory experiments show diffusion rates even smaller than those predicted by our non-Fickian model, suggesting that there are additional, unaccounted for processes retarding diffusion. Ionic diffusion rates may be a limiting factor in transporting salts whose effect on fluid density will in turn significantly affect the flow regime. These findings have important implications for understanding and predicting solute transport in geologic settings where dense, saline solutions occur.

Description: The tissue of 31 demosponge and 7 hexachnelhd species was analyzed for its composition of organic and lnorganic matter With one excephon (Hahclona cf gausaana) inorganic matter i e n~ostly the siliceous skeleton, accounted for most of the dry weight, varying between about 60 and 95%dry wt There were no general trends in the ratio of organic to inorganic matter within sponge orders or genera, and within one species, the ratio could vary between stations For one of the hexactinellids Bathydorus spmosus, several size classes were analyzed and there was no systematic change in the organic inorganic matter ratio w t h specimen size For some species the results from the Weddell Sea sponges are in good agreement with earlier data from McMurdo Sound The low organic matter content in Weddell Sea sponges mphes that sponge biomasses are much lower than hitherto assumed on the basis of then high abundances and large sizes In consequence Antarctic sponges despite their ubiquitousness, may only channel a m n o r fractlon of the general bentho-pelagic flow of matter and energy and their maln role in the ecosystem is likely structural rather than dynamic

Description: During 5 consecutive summer seasons (1990 to 1994) both Aureliaaurita medusa and mesozooplankton abundances were investigated at 2 stations in the Kiel Bight (western Baltic Sea). Stocks of medusae varied considerably between the years, with median abundance of 1 and 0.3 ind. 100 m-3 in 1990 and 1991, 3 and 4 ind. 100 m-3 in 1992 and 1994, but 9 ind. 100 m-3 in 1993. Significant differences in the mesozooplankton stock and community composition were observed in 1993 when compared with the year of rather low Aurelia abundance (1991). Total zooplankton and copepod numbers both exhibited an inverse relationship with the abundance of medusae and were thus considerably lower in 1993 than in 1991. However, not all copepod species were affected by A. aurita. Pseudo- and Paracalanus spp. and Oithonasimilis showed dramatically reduced stocks in the bloom year when compared with the medusa-poor situation, but no significant changes were found for Centropageshamatus and Acartia spp. Also other zooplankton groups with the exception of bivalve larvae were reduced by the medusae. The differential response of zooplankton to varying abundance of medusae led to a shift in the trophic structure of the zooplankton community. Fine-filter feeders and raptorial feeders were much more important in years when medusae occurred in low densities, whereas coarse-filter feeders dominated in the opposite situation.

Description: From the Gulf of Aden along a transect to the central-northern Red Sea the abundance and taxonomic composition of metazoan plankton was studied during the southwest monsoon period (summer 1987). Samples were taken with 0.055 mm mesh nets down to a maximum depth of 1050 m. In the epipelagic zone, a distinct decrease in total plankton abundance was observed from south to north, which was much more pronounced in biomass (by a factor of up to 10) as compared to numbers (by a factor of 2). This could partly be explained by differences in the taxonomic and/or size composition of the planktonic fauna. Among non-calanoid copepods, 40 out of 75 species or taxa investigated decreased in abundance from south to north. Sixteen of these species were completely absent in the central-northern area. Nineteen species or taxa, however, showed the opposite feature of a higher abundance in the central-northern Red Sea. The stations were grouped according to similarities in the taxonomic composition of non-calanoid copepods in the epipelagic zone. The following 3 geographical regions could be separated: (1) Gulf of Aden and Strait of Bab al Mandab; (2) southern Red Sea; and (3) central-northern Red Sea. In the meso- and bathypelagic zones, regional differences were not evident. The results are discussed in relation to hydrographic conditions during summer 1987.

Description: A spring investigation of the phytoplankton in the western Alboran Sea (Mediterranean) was undertaken using chlorophyll and carotenoid biomarkers to characterize the community in the water column and in drifting sediment traps set at 100 and 200 m. During 2 drifter experiments, calm and sunny conditions induced a progressive thermal stratification that reduced pigment sedimentation into deeper water and confined the phytoplankton to the surface layer, resulting in an increase in chlorophyll biomass. 19'-Hexanoyloxyfucoxanthin (prymnesiophytes) and chlorophyll b (chlorophytes, prasinophytes, prochlorophytes) were the major accessory pigments, while fucoxanthin, alloxanthin and peridinin indicated the presence of diatoms, cryptophytes and dinoflagellates, respectively. The proportional contribution of each algal group to the chlorophyll a (chl a) biomass, as derived from multiple regression analysis, revealed that prymnesiophytes, cryptophytes and the green algal group collectively accounted for at least 75% in the upper 100 m, emphasizing the importance of the nanophytoplankton. Phaeopigments, dominated by phaeophorbide a2, were the main pigments observed in sediment traps, although chl a, fucoxanthin and 19'-hexanoyloxyfucoxanthin were detected in smaller concentrations as well as traces of chlorophyll b (chl b). In deep water, fucoxanthin and 19'-hexanoyloxyfucoxanthin were the only accessory pigments present while total phaeopigment/chl a molar ratios 〉1 reflected the active transformation of fine phytogenic material at depth. High particulate organic carbon (POC)/chl a ratios (〉100 in surface water; 〉1000 in deep water) suggested that phytoplankton was a relatively small component of the total carbon biomass down the water column. Using simple budget calculations, we determined that 58 to 65% of the chl a produced in the upper 100 m accumulated in the water column over both experiments. During Expt 1, 29% of the chl a sedimented out, mostly as phaeopigment, at 100 m (24%), and 6% was degraded to colourless residues in the water column. In contrast, only 12% of the chl a sedimented in Expt 2, while 20% was degraded to colourless residues.

Description: The distributions and transports of deepwater masses at the western boundary in the tropical Atlantic off Brazil have been studied on three surveys along 35 degrees W and 5 degrees S and one at 10 degrees S. Transports are obtained from direct measurements of the velocity fields (Pegasus profiling system and lowered acoustic Doppler current profiler) and from geostrophic computations. Using chlorofluoromethane (CFM) and hydrographic distributions, four water masses could be identified forming the North Atlantic Deep Water (NADW) system. Two of these have a high CFM content, the ''shallow upper NADW'' (SUNADW) and the ''overflow lower NADW'' (OLNADW). These exhibit the highest velocity signals at 35 degrees W, where distinct flow cores seem to exist; most of the southeastward flow of the SUNADW (centered around 1600 m) occurs 320 km offshore between 3 degrees 09'S and 1 degrees 50'S (9.7 +/- 3.3 Sv); farther north in that section, a highly variable reversing flow is found in a second velocity maximum. The transport of OLNADW (centered around 3800 m) of 4.6 +/- 2.6 Sv is guided by the Parnaiba Ridge at 1 degrees 45'S, 35 degrees W. The water masses located between the two CFM maxima, the Labrador Sea Water (LSW) and the LNADW old water mass (LNADW-old), did not show any persistent flow features, however, a rather constant transport of 11.1 +/- 2.6 Sv was observed for these two layers. The total southeastward flow of the NADW at 35 degrees W showed a transport of 26.8 +/- 7.0 Sv, if one neglects the reversing SUNADW north of 1 degrees 50'S. At 5 degrees S the flow of all deepwater masses shows vertically aligned cores; the main southward transport occurred near the coast (19.5 +/- 5.3 Sv). The boundary current is limited offshore by a flow reversal, present in all three surveys, but located at different longitudes. At 10 degrees S a southward transport of 4.7 Sv was observed in November 1992. However, the section extended only to 32 degrees 30'W, so that probably a significant part of the flow has been missed. An important result is the large transport variability between single cruises as well as variability of the spatial distribution of the flow at 35 degrees W, which could lead to large uncertainties in the interpretation of single cruise observations. Despite these uncertainties we suggest a circulation pattern of the various deepwater masses near the equator by combining our mean transport estimates with other observations.

Description: During March 1994 a survey of the western boundary of the tropical Atlantic, between 10 degrees N and 10 degrees S, was carried out by conductivity-temperature-depth and current profiling using shipboard and lowered acoustic Doppler current profilers. In the near-surface layer, above sigma. = 24.5, the inflow into the boundary regime came dominantly from low latitudes; out of the 14 Sv that crossed the equator in the upper part of the North Brazil Current (NBC), only 2 Sv originated from south of 5 degrees S, while 12 Sv came in from the east at 1 degrees-5 degrees S with the South Equatorial Current (SEC). After crossing the equator near 44 degrees W, only a minor fraction of the near-surface NBC retroflected eastward, while a net through flow of about 12 Sv above sigma. = 24.5 continued northwestward along the boundary, By contrast, in the isopycnal range sigma. = 24.5-26.8 encompassing the Equatorial Undercurrent (EUC), the source waters of the equatorial circulation were dominantly of higher-latitude South Atlantic origin. While only 3 Sv of eastern equatorial water entered the region through the SEC at 3 degrees-5 degrees S, there was an inflow of 10 Sv of South Atlantic water in the North Brazil Undercurrent (NBUC) along the South American coast that originated south of 10 degrees S, The transport of 14 Sv arriving at the equator along the boundary in the undercurrent layer was almost entirely retroflected into the EUC with only marginal northern water additions along its path to 35 degrees W. The off-equatorial undercurrents in the upper thermocline, the South and North Equatorial Undercurrents carried only small transports across 35 degrees W, of 5 Sv and 3 Sv, respectively, dominantly supplied out of SEC recirculation rather than out of the boundary current. Still deeper, three zonal undercurrents were observed: the westward-flowing Equatorial Intermediate Current (EIC) in the depth range 200-900 m below the EUC, and two off-equatorial eastward undercurrents, the Northern and Southern Intermediate Countercurrents (NICC, SICC) at 400-1000 m and 1 degrees-3 degrees latitude. In the lower part of the NBUC there was an Antarctic Intermediate Water (AAIW) inflow along the coast of 6 Sv, and there was a clear connection at the AAIW level to the SICC by low salinities and high oxygens and a weaker suggestion also that some supply of the NICC might be through AAIW out of the deep NBUC.

Description: We reconstructed late Quaternary deep (3000–4100 m) and intermediate depth (1000–2500 m) paleoceanographic history of the Eurasian Basin, Arctic Ocean from ostracode assemblages in cores from the Lomonosov Ridge, Gakkel Ridge, Yermak Plateau, Morris Jesup Rise, and Amundsen and Makarov Basins obtained during the 1991 Polarstern cruise. Modern assemblages on ridges and plateaus between 1000 and 1500 m are characterized by abundant, relatively species-rich benthic ostracode assemblages, in part, reflecting the influence of high organic productivity and inflowing Atlantic water. In contrast, deep Arctic Eurasian basin assemblages have low abundance and low diversity and are dominated by Krithe and Cytheropteron reflecting faunal exchange with the Greenland Sea via the Fram Strait. Major faunal changes occurred in the Arctic during the last glacial/interglacial transition and the Holocene. Low-abundance, low-diversity assemblages from the Lomonosov and Gakkel Ridges in the Eurasian Basin from the last glacial period have modern analogs in cold, low-salinity, low-nutrient Greenland Sea deep water; glacial assemblages from the deep Nansen and Amundsen Basins have modern analogs in the deep Canada Basin. During Termination 1 at intermediate depths, diversity and abundance increased coincident with increased biogenic sediment, reflecting increased organic productivity, reduced sea-ice, and enhanced inflowing North Atlantic water. During deglaciation deep Nansen Basin assemblages were similar to those living today in the deep Greenland Sea, perhaps reflecting deepwater exchange via the Fram Strait. In the central Arctic, early Holocene faunas indicate weaker North Atlantic water inflow at middepths immediately following Termination 1, about 8500–7000 year B.P., followed by a period of strong Canada Basin water overflow across the Lomonosov Ridge into the Morris Jesup Rise area and central Arctic Ocean. Modern perennial sea-ice cover evolved over the last 4000–5000 years. Late Quaternary faunal changes reflect benthic habitat changes most likely caused by changes in the import of cold, deepwater of Greenland Sea origin and warmer and middepth Atlantic water to the Eurasian Basin through the Fram Strait, and export of Arctic Ocean deepwater.

Description: Sediment cores of 20 cm diameter contaning the natural benthic fauna were subjected to low oxygen conditions in a laboratory microcosm system. After several days of oxic conditions ('oxic stage') the oxygen content of the water was reduced to 25% saturation for 15 d ('hypoxic stage'), followed by a 'reoxygenation stage'. Effective solute transport rates were calculated using measurements with the conservative tracer ion bromide. Profiles of oxygen and ΣCO2 were measured and molecular diffusive as well as effective fluxes, account mg for effective solute exchange, were calculated. The overall response of the benthic community was to compensate for low oxygen content of the overlying water by increased pumping activity. On average, effective diffusion coefficients (Den} were 3 times higher in hypoxia than under oxic conditions. D eff reached 1.5 x 10^-4 cm2 s^-1, a value 30 times that of molecular diffusion. During hypoxia we observed low molecular diffusive O2 flux, higher effective O2 flux, as well as an increase in ΣCO2 within the sediment. We interpret this as a shift of transport away from diffusion within the bulk sediment interstices (oxic conditions) to the advective transport pathways along burrows during hypoxia. This facilitates fast transport of oxygen and bromide along burrows and contrasts with the slower transport of CO2 from the interstices governed by molecular diffusion. In this transient situation calulations based on gradients result in an unrealistic molar ratio of fluxes(CO2/O2)as high as 11.

Description: Eight time slices of surface-water paleoceanography were reconstructed from stable isotope and paleotemperature data to evaluate late Quaternary changes in density, current directions, and sea-ice cover in the Nordic Seas and NE Atlantic. We used isotopic records from 110 deep-sea cores, 20 of which are accelerator mass spectrometry (AMS)-14C dated and 30 of which have high (〉8 cm /kyr) sedimentation rates, enabling a resolution of about 120 years. Paleotemperature estimates are based on species counts of planktonic foraminifera in 18 cores. The δ18O and δ13C distributions depict three main modes of surface circulation: (1) The Holocene-style interglacial mode which largely persisted over the last 12.8 14C ka, and probably during large parts of stage 3. (2) The peak glacial mode showing a cyclonic gyre in the, at least, seasonally ice-free Nordic Seas and a meltwater lens west of Ireland. Based on geostrophic forcing, it possibly turned clockwise, blocked the S-N flow across the eastern Iceland-Shetland ridge, and enhanced the Irminger current around west Iceland. It remains unclear whether surface-water density was sufficient for deepwater formation west of Norway. (3) A meltwater regime culminating during early glacial Termination I, when a great meltwater lens off northern Norway probably induced a clockwise circulation reaching south up to Faeroe, the northward inflow of Irminger Current water dominated the Icelandic Sea, and deepwater convection was stopped. In contrast to circulation modes two and three, the Holocene-style circulation mode appears most stable, even unaffected by major meltwater pools originating from the Scandinavian ice sheet, such as during δ18O event 3.1 and the Bölling. Meltwater phases markedly influenced the European continental climate by suppressing the “heat pump” of the Atlantic salinity conveyor belt. During the peak glacial, melting icebergs blocked the eastward advection of warm surface water toward Great Britain, thus accelerating buildup of the great European ice sheets; in the early deglacial, meltwater probably induced a southward flow of cold water along Norway, which led to the Oldest Dryas cold spell.

Description: The 14 Ma caldera-forming composite ignimbrite P1 on Gran Canaria (Canary Islands) represents the first voluminous eruption of highly differentiated magmas on top of the basaltic Miocene shield volcano. Compositional zonation of the ignimbrite is the result of vertically changing proportions of four component magmas, which were intensely mixed during eruption: (1) Crystal-poor to highly phyric rhyolite (∼10 km3), (2) sodic trachyandesite through mafic to evolved trachyte (∼6 km3), (3) Na-poor trachyandesite (〈1 km3), and (4) basalt zoned from 5.2 to 4.3 wt % MgO (∼26 km3). P1 basalt is composed of two compositionally zoned magma batches, B2 basalt and B3 basalt. B3 basalt is derived from a mantle source depleted in incompatible trace elements compared to the shield basalt source. Basaltic magmas were stored in a reservoir probably underplating the crust, in which zoned B2 basaltic magma formed by mixing of “enriched” (shield) and “depleted” (B3) mafic melts and subsequent crystal fractionation. Evolved magmas formed in a shallow crustal chamber, whereas intermediate magmas formed at both levels. Abundant pyroxenitic to gabbroid cumulates in P1 support crystal fractionation as the major differentiation process. On the basis of major and trace element modeling, we infer two contemporaneous fractional crystallization series: series I from “enriched” shield basalt through Na-poor trachyandesite to rhyolite, and series II from “depleted” P1 basalt through sodic trachyandesite to trachyte. Series II rocks were significantly modified by selective contamination involving feldspar (Na, K, Ba, Eu, Sr), zircon (Zr) and apatite (P, Y, rare earth elements) components; apatite contamination also affected series I Na-poor trachyandesite. Substantial sodium introduction into sodic trachyandesite is the main reason for the different major element evolution of the two series, whereas their different parentage is mainly reflected in the high field strength trace elements. Selective element contamination involved not only rapidly but also slowly diffusing elements as well as different saturation conditions. Contamination processes thus variably involved differential diffusion, partial dissolution of minerals, partial melt migration, and trace mineral incorporation. Magma mixing between trachyte and rhyolite during their simultaneous crystallization in the P1 magma chamber is documented by mutual mineral inclusions but had little effect on the compositional evolution of both magmas. Fe-Ti oxide thermometry yields magmatic temperatures of around 850°C for crystal-poor through crystal-rich rhyolite, ∼815°C for trachyte and ∼850°–900°C for the trachyandesitic magmas. High 1160°C for the basalt magma suggest its intrusion into the P1 magma chamber only shortly before eruption. The lower temperature for trachyte compared to rhyolite and the strong crustal contamination of trachyte and sodic trachyandesite support their residence along the walls of the vertically and laterally zoned P1 magma chamber. The complex magmatic evolution of P1 reflects the transient state of Gran Canaria's mantle source composition and magma plumbing system during the change from basaltic to silicic volcanism. Our results for P1 characterize processes operating during this important transition, which also occurs on other volcanic ocean islands.

Description: This experimental study investigated the vertical migratory response of benthic forammifera in sediments that were initially oxygenated, to variations in dissolved-oxygen concentrations ranging from well-oxygenated to dysaerobic conditions. Two box cores, with a carpet of polychaete tubes extending above the sediment-seawater interface, were recovered from 71 m water depth in Oslofjord, southern Norway. The seawater oxygen concentration of one box core was decreased every 4 wk, to a minimum value of 〈0.2 ml 0; 1'. Aerated seawater circulation was maintained in the other (control) box core. In a time course, 2 subcores were taken from each mesocosm every 4 wk and sectioned in 0 5 cm mtervals to depths of 2.0 cm, and 1.0 cm intervals from 2.0 to 4.0 cm. The portion of the polychaete tubes extending into the overlymg water was collected and treated as an additional sample. Live foramimferal distributions were examined in the 〉 63 pm fraction of each interval shallower than 2 cm using both an ATP assay and a rose Bengal staining method, while only rose Bengal was used to assess distributions from 2 to 4 cm. Results indicate that larger numbers of live and stained forammifera are found on the polychaete tubes and in the superficial 0.5 cm of sediment after exposure to dysaerobic conditions compared to original and control abundances. After re-oxygenation for 4 mo, the foraminifera re-migrated into the sediments, exhibiting distributions similar to those of the control mesocosm. These observations suggest that some species actively migrate to a microenvironment with a particular oxygen concentration, rather than maintaining a stable position with respect to the sediment-water interface.

Description: Currents and temperatures were measured using Pegasus current profilers across Northwest Providence and Santaren Channels and across the Florida Current off Cay Sal Bank during four cruises from November 1990 to September 1991. On average, Northwest Providence (1.2 Sv) and Santaren (1.8 Sv) contribute about 3 Sv to the total Florida Current transport farther north (e.g., 27°N). Partitioning of transport into temperature layers shows that about one-half of this transport is of “18°C” water (17°C–19.5°C); this can account for all of the “excess” 18°C water observed in previous experiments. This excess is thought to be injected into the 18°C layer in its region of formation in the northwestern North Atlantic Ocean. Due to its large thickness, potential vorticities in this layer in its area of formation are very low. In our data, lowest potential vorticities in this layer are found on the northern end of Northwest Providence Channel and are comparable to those observed on the eastern side of the Florida Current at 27°N. On average a low-potential-vorticity 18°C layer was not found in the Florida Current off Cay Sal Bank.

Description: Currents and temperatures were measured using Pegasus current profilers across Northwest Providence and Santaren Channels and across the Florida Current off Cay Sal Bank during four cruises from November 1990 to September 1991. On average, Northwest Providence (1.2 Sv) and Santaren (1.8 Sv) contribute about 3 Sv to the total Florida Current transport farther north (e.g., 27°N). Partitioning of transport into temperature layers shows that about one-half of this transport is of “18°C” water (17°C–19.5°C); this can account for all of the “excess” 18°C water observed in previous experiments. This excess is thought to be injected into the 18°C layer in its region of formation in the northwestern North Atlantic Ocean. Due to its large thickness, potential vorticities in this layer in its area of formation are very low. In our data, lowest potential vorticities in this layer are found on the northern end of Northwest Providence Channel and are comparable to those observed on the eastern side of the Florida Current at 27°N. On average a low-potential-vorticity 18°C layer was not found in the Florida Current off Cay Sal Bank.

Description: Measurements of dissolved methane in the surface waters of the western Sea of Okhotsk are evaluated in terms of methane exchange rates and are used to assess the magnitude of seasonal variations of methane fluxes from the ocean to the atmosphere in this area. Methane concentrations northeast of Sakhalin were observed to range from 385 nmol L−1 under the ice cover in winter to 6 nmol L−1 in the icefree midsummer season. The magnitude of supersaturations indicates that this part of the Okhotsk Sea is a significant source for atmospheric methane. From the seasonal variation of the supersaturations in the surface waters it is evident that the air-sea exchange is interrupted during the winter and methane from sedimentary sources accumulates under the ice cover. According to our measurements an initial early summer methane pulse into the atmosphere of the order of 560 mol km−2 d−1 can be expected when the supersaturated surface waters are exposed by the retreating ice. The methane flux in July is approximately 150 mol km−2 d−1 which is of the order of the average annual flux in the survey area. The magnitude of the seasonal CH4 flux variation northeast of Sakhalin corresponds to an amount of 7.3 × 105 g km−2 whereby 74% or 5.4 × 105 g km−2 are supplied to the atmosphere between April and July. For the whole Sea of Okhotsk the annual methane flux is roughly 0.13 × 1012 g (terragrams), based on the assumption that 15% of the entire area emit methane. Variations of long-term data of atmospheric methane which are recorded at the same latitude adjacent to areas with seasonal ice cover show a regional methane pulse between April and July. The large-scale level of atmospheric methane in the northern hemisphere undergoes an amplitudinal variation of about 25 parts per billion by volume (ppbv) which translates into approximately 36 Tg. Thus the estimated 0.6 Tg of ice-induced methane dynamics in northern latitudes can hardly explain this seasonal signal. However, the effects of seasonal ice cover on pulsed release of methane appear strong enough to contribute, in concert with other seasonal sources, to characteristic short-term wobbles in the atmospheric methane budget which are observed between 50°N and 60°N.

Description: In the North Atlantic we define H-0 as a Heinrich-like event which occurred during the Younger Dryas chron. On the SE Baffin shelf prior to 11 ka, surface water productivity was reasonably high, as measured by the numbers of diatom and planktic foraminifera per gram, but an abrupt increase in detrital carbonate (DC-0 event) (from approximately 15% up to 50% carbonate by weight) occurred at 11 ± 14C ka and continued to circa 10 ka. These deposits, 2–6 m thick, are dominated by detrital calcite and silt- and clay-sized sediments. During this event (DC-0/H-0), ice extended onto the inner shelf but did not reach the shelf break and probably originated from a center over Labrador-Ungava. As a consequence, the pattern of ice-rafted debris and sediment provenance shown by H-O in the North Atlantic is different from that during H-1 (14.5 ka) or H-2 (20 ka) when the ice sheet extended along the axis of Hudson Strait and may have reached the shelf break; for example, there is no concrete evidence for DC-O is cores on the floor of the Labrador Sea due east of Hudson Strait (HU75-55,-56), but H-O has been noted in cores off Newfoundland and west of Ireland. A coeval carbonate event to DC-0, but this one dominated by dolomite, occurs in HU82-SU5 on the west side of Davis Strait with a source either from northern Baffin Bay or Cumberland Sound. Although other sources for North Atlantic detrital carbonate cannot be totally excluded, our evidence suggests that H-0 represents the expression of glaciological instability of the Laurentide Ice Sheet within the general region of Hudson Strait and probably to the north (Cumberland Sound and northernmost Baffin Bay). There is one younger DC event, dated circa 8.4 ka, present in sediments along the Labrador margin and in Hudson Strait, which represents the final collapse of the ice sheet within Hudson Strait and Hudson Bay.

Description: Eight time slices of surface-water paleoceanography were reconstructed from stable isotope and paleotemperature data to evaluate late Quaternary changes in density, current directions, and sea-ice cover in the Nordic Seas and NE Atlantic. We used isotopic records from 110 deep-sea cores, 20 of which are accelerator mass spectrometry (AMS)-14C dated and 30 of which have high (〉8 cm /kyr) sedimentation rates, enabling a resolution of about 120 years. Paleotemperature estimates are based on species counts of planktonic foraminifera in 18 cores. The δ18O and δ13C distributions depict three main modes of surface circulation: (1) The Holocene-style interglacial mode which largely persisted over the last 12.8 14C ka, and probably during large parts of stage 3. (2) The peak glacial mode showing a cyclonic gyre in the, at least, seasonally ice-free Nordic Seas and a meltwater lens west of Ireland. Based on geostrophic forcing, it possibly turned clockwise, blocked the S-N flow across the eastern Iceland-Shetland ridge, and enhanced the Irminger current around west Iceland. It remains unclear whether surface-water density was sufficient for deepwater formation west of Norway. (3) A meltwater regime culminating during early glacial Termination I, when a great meltwater lens off northern Norway probably induced a clockwise circulation reaching south up to Faeroe, the northward inflow of Irminger Current water dominated the Icelandic Sea, and deepwater convection was stopped. In contrast to circulation modes two and three, the Holocene-style circulation mode appears most stable, even unaffected by major meltwater pools originating from the Scandinavian ice sheet, such as during δ18O event 3.1 and the Bölling. Meltwater phases markedly influenced the European continental climate by suppressing the “heat pump” of the Atlantic salinity conveyor belt. During the peak glacial, melting icebergs blocked the eastward advection of warm surface water toward Great Britain, thus accelerating buildup of the great European ice sheets; in the early deglacial, meltwater probably induced a southward flow of cold water along Norway, which led to the Oldest Dryas cold spell.

Description: Measurements of dissolved methane in the surface waters of the western Sea of Okhotsk are evaluated in terms of methane exchange rates and are used to assess the magnitude of seasonal variations of methane fluxes from the ocean to the atmosphere in this area. Methane concentrations northeast of Sakhalin were observed to range from 385 nmol L−1 under the ice cover in winter to 6 nmol L−1 in the icefree midsummer season. The magnitude of supersaturations indicates that this part of the Okhotsk Sea is a significant source for atmospheric methane. From the seasonal variation of the supersaturations in the surface waters it is evident that the air-sea exchange is interrupted during the winter and methane from sedimentary sources accumulates under the ice cover. According to our measurements an initial early summer methane pulse into the atmosphere of the order of 560 mol km−2 d−1 can be expected when the supersaturated surface waters are exposed by the retreating ice. The methane flux in July is approximately 150 mol km−2 d−1 which is of the order of the average annual flux in the survey area. The magnitude of the seasonal CH4 flux variation northeast of Sakhalin corresponds to an amount of 7.3 × 105 g km−2 whereby 74% or 5.4 × 105 g km−2 are supplied to the atmosphere between April and July. For the whole Sea of Okhotsk the annual methane flux is roughly 0.13 × 1012 g (terragrams), based on the assumption that 15% of the entire area emit methane. Variations of long-term data of atmospheric methane which are recorded at the same latitude adjacent to areas with seasonal ice cover show a regional methane pulse between April and July. The large-scale level of atmospheric methane in the northern hemisphere undergoes an amplitudinal variation of about 25 parts per billion by volume (ppbv) which translates into approximately 36 Tg. Thus the estimated 0.6 Tg of ice-induced methane dynamics in northern latitudes can hardly explain this seasonal signal. However, the effects of seasonal ice cover on pulsed release of methane appear strong enough to contribute, in concert with other seasonal sources, to characteristic short-term wobbles in the atmospheric methane budget which are observed between 50°N and 60°N.

Description: This study documents the biological signatures impressed upon the sedimentary record underlying both the 5°N upwelling system of the Somali Current and the equatorial area of the Somali Basin out of the upwelling influence. The evolution of these two distinct hydrographic systems is compared for the last 160 kyr. Correspondence and cluster analyses are performed on combined radiolarian and planktonic foraminiferal quantitative data in order to study the changes of the planktonic assemblages through time and space. The Upwelling Radiolarian Index (URI) is used as a productivity proxy. The water temperature and hydrographic structure of the upper water masses appear to be the major factors controlling the distribution patterns of the fauna. The relative abundances of three groups of foraminifera, cold water form (dextral N. pachyderma), mixed layer dwellers (G. trilobus, G. ruber, G. sacculifer, G. conglobatus, and G. glutinata), and thermocline dwellers (G. menardii, G. tumida, N. dutertrei, G. crassaformis, and P. obliquiloculata), follow distinct evolutionary patterns at the two sites during the last 160 kyr. At the equatorial site (core MD 85668), downcore fluctuations in the relative abundances of the three groups are closely related to the glacial/interglacial cyclicity and provide some insights into the interpretation of hydrographic changes. The dominance of the mixed layer foraminifera at the transition intervals between isotope stages 6/5 and 2/1, combined with weak URI values, is thought to reflect the reorganization of the oceanographic circulation. These short-term events (with a duration of 〈 5000 year) could be related to the rapid inflow of oxygen-depleted water through the Indonesian straits as a result of sea level rise during deglaciation. Underneath the 5°N gyre (core MD 85674), the response to global climatic changes is overprinted by the regional effect of the Somalian upwelling, which has been persistent over the last 160 kyr.

Description: During the multidisciplinary ‘NEW92’ cruise of the United States Coast Guard Cutter (USCGC) Polar Sea to the recurrent Northeast Water (NEW) Polynya (77–81°N, 6–17°W; July–August 1992), total dissolved inorganic carbon and total alkalinity in the water column were measured with high precision to determine the quantitative impact of biological processes on the regional air-sea flux of carbon. Biological processes depleted the total inorganic carbon of summer surface waters by up to 2 mol C m−2 or about 3%. On a regional basis this depletion correlated with depth-integrated values of chlorophyll a, particulate organic carbon, and the inorganic nitrogen deficit. Replacement of this carbon through exchange with the atmosphere was stalled owing to the low wind speeds during the month of the cruise, although model calculations indicate that the depletion could be replenished by a few weeks of strong winds before ice forms in the autumn. These measurements and observations allowed formulation of a new hypothesis whereby seasonally ice-covered regions like the NEW Polynya promote a unique biologically and physically mediated “rectification” of the typical (ice free, low latitude) seasonal cycle of air-sea CO2 flux. The resulting carbon sink is consistent with other productivity estimates and represents an export of biologically cycled carbon either to local sediments or offshore. If this scenario is representative of seasonally ice-covered Arctic shelves, then the rectification process could provide a small, negative feedback to excess atmospheric CO2.

Description: The TAG active hydrothermal mound, located 2.4 km east of the neovolcanic zone at 26°N, Mid-Atlantic Ridge, is −200 m in diameter, exhibits 50 m of relief, and is covered entirely by hydrothermal precipitates. Eight different types of vent solids were recovered from the mound by the submersibles Alvin and Mir in 1986, 1990, and 1991. Detailed petrographic and geochemical studies of samples and their distribution are used to deduce patterns of fluid flow and seawater/hydrothermal fluid interaction. Geochemical modeling calculations using fluid composition data corroborate these interpretations. Current activity includes highly focused flow of 363°C fluid from a chimney cluster on the top of the mound and deposition of a high ƒS2-ƒO2 mineral assemblage that reflects low concentrations of H2S in black smoker fluid. Slow percolation of black smoker fluid pooled beneath the black smoker cluster and entrainment of seawater result in formation of massive sulfide crusts and massive anhydrite. These three sample types are enriched in Co and Se. Blocks of sulfide and white smoker chimneys, enriched in Zn, Au, Ag, Sb, Cd, and Pb, are forming on the surface of the mound from black smoker fluid that has been modified by mixing with entrained seawater, precipitation of sulfides and anhydrite, and dissolution of sphalerite within the mound. This is the first time that on-going remobilization, zone refinement, and significant modification of high-temperature fluid in the near surface has been documented in a seafloor hydrothermal system. Deposits of ocherous material and massive sulfide with outer oxidized layers that formed during previous hydrothermal episodes are exposed on the steep outer walls of the mound. Studies of the full range of samples demonstrate that highly focused fluid flow, consequent seawater entrainment, and mixing within the mound can result in formation of a large seafloor hydrothermal deposit exhibiting sample types similar to those observed in Cyprus-type ore bodies.

Description: Seismic tomography and the isotope geochemistry of Cenozoic volcanic rocks suggest the existence of a large, sheet-like region of upwelling in the upper mantle which extends from the eastern Atlantic Ocean to central Europe and the western Mediterranean. A belt of extension and rifting in the latter two areas appears to lie above the intersection of the centre of the upwelling region with the base of the lithosphere. Lead, strontium and neodymium isotope data for all three regions converge on a restricted composition, inferred to be that of the upwelling mantle.

Description: The seasonal evolution of anomalous interhemispheric sea surface temperature (SST) gradients in the tropical Atlantic from January to April is studied by composites of the 10 warmest (warm) and 10 coldest (cold) Januaries during 1948–1993 in the equatorial Pacific using Comprehensive Ocean‐Atmosphere Data Set ship observations. In the warm as compared with the cold years, an anomalous weakening of the northward SST gradient develops, mainly due to anomalous warming in the tropical North Atlantic. This stems from the combination of three forcings all related to the weakened North Atlantic trade winds during Pacific warm events. Most important are the reduced latent heat flux in much of the tropical North Atlantic and anomalous downwelling equatorward of 20°N, with a further contribution from increased net radiation resulting from the reduced cloudiness due to the diminished convergence in the downstream portion of the North Atlantic trades. In response to the development of warm anomalies in the tropical North Atlantic during January–March, the cross‐equatorial northward winds accelerate to April, and this leads south of the equator not only to Ekman downwelling, enhanced divergence, reduced cloudiness, and increased net radiation, but also to enhanced wind speed and evaporation. The result is a modest anomalous warming in the western tropical South Atlantic. Increased air temperature over the entire basin, presumably due to atmospheric advection from the Pacific, has little effect on the Atlantic SST pattern. The anomalous interhemispheric SST gradient, controlled primarily by the warm anomaly in the North Atlantic, has a pivotal role to play in steering the late boreal winter atmospheric circulation in the tropical Atlantic sector and thus regional climate anomalies.

Description: Recently reported radioisotopic dates and magnetic anomaly spacings have made it evident that modification is required for the age calibrations for the geomagnetic polarity timescale of Cande and Kent (1992) at the Cretaceous/Paleogene boundary and in the Pliocene. An adjusted geomagnetic reversal chronology for the Late Cretaceous and Cenozoic is presented that is consistent with astrochronology in the Pleistocene and Pliocene and with a new timescale for the Mesozoic.

Description: Within the Australian-Antarctic Discordance (AAD), a boundary exists between isotopically defined “Pacific-type” and “Indian-type” mid-ocean ridge basalt (MORB) erupted along the Southeast Indian Ridge (SEIR). This boundary has migrated westward beneath the easternmost AAD spreading segment at a minimum rate of 25 mm/yr since 4 Ma; however, its long-term history remains a matter of speculation. To determine if Pacific-type upper mantle has migrated westward beneath the eastern Indian Ocean basin as Australia and Antarctica drifted apart during the last 70 m.y., we present new Sr-Nd-Pb isotope data, combined with trace element and 40Ar-39Ar radiometric age determinations, for samples from Legs 28 and 29 of the Deep Sea Drilling Project (DSDP). Basaltic basement at these DSDP sites provides a record of their upper mantle source composition and shows regional variations consistent with upper mantle flow in this region. East of the South Tasman Rise, all DSDP basalts have 87Sr/86Sr (0.7025–0.7029) and 206Pb/204Pb (18.80–19.48) ratios typical of Pacific-type MORB indicating that Pacific-type upper mantle existed east of the Australian-Antarctic continental margin and beneath the Tasman Sea during the early stages of seafloor spreading in this region. Basalts from DSDP sites west of the AAD have high 87Sr/86Sr (0.7030–0.7035), low 206Pb/204Pb (17.99–18.10) and trace element characteristics typical of present day Indian-type SEIR MORB. Between these two regions, DSDP basalts recovered along the western margin of the South Tasman Rise have isotopic characteristics that are, in one case consistent with an Indian-type MORB source (Site 280A) and, in the second case, transitional between Pacific-type and Indian-type mantle sources. The occurrence of seafloor basalts with transitional or Indian-type isotopic characteristics well to the east of the present Indian-Pacific MORB isotopic boundary within the AAD strongly implies that Pacific-type upper mantle has migrated westward into the region since the South Tasman Rise separated from Antarctica circa 40 Ma.

Description: A survey of parasites in 600 short-finned squid Illex coindetii (Vérany, 1839) taken from 2 locations (north and south Galicia) off the northwesterb Iberian Peninsula revealed the presence of numerous somatoxenous helminths. Three genera of Tetraphyllidean plerocercoids were represented (prevalences: Phyllobothrium sp., 45,7%; Dinobothrium sp., 0.8%; and Pelichnibothrium speciosum, 0.001%); 1 Trypanorhynchidean metacestode was also present (Nybelinia yamagutii, 0.4%). In addition, larval nematodes of Anisakis simplex (L3) were recorded (10.6%). Abundance of infection was examined in relation to squid sex, standard length, maturity and locality. This analysis indicated that parasite infection was lower in the southern squids than in the northern squid group. Over the entire survey area, parasite infection showed a positive correlation with host life.cycle, often with the greatest number of parasites among the largest and highest maturity individuals (〉18 to 20cm; maturity stage V).

Description: An analysis of a large drifting buoy data set is presented. The objective is to obtain a self‐contained description of the properties of the near‐surface circulation (drogue depth 100 m) in the central North Atlantic Ocean, independent of hydrographic data. A necessary preanalysis step was the removal of all data from undrogued buoys from the data set. The physical parameters of the circulation were deduced by averaging the remaining data in 2°×3° boxes. The minimum amount of data which is necessary to get statistically stable results was determined by an empirical quality criterion. All important mean currents in the investigation area are reproduced by the near‐surface mean velocity field. A separation of the mean velocity field into a nondivergent and an irrational part shows that the flow field is almost nondivergent. The distribution of eddy kinetic energy is concentrated along the mean currents and provides the largest part of the total kinetic energy, but there are regional variations. Energy from inertial movements dominates the high‐frequency part of the kinetic energy. Its distribution is very patchy. The analysis of the Reynolds stress terms shows an energy transfer from the eddy field to the mean circulation in the vicinity of the North Atlantic Current.

Description: THE hydrothermal circulation of sea water through permeable ocean crust results in rock–water interactions that lead to the formation of massive sulphide deposits. These are the modern analogues of many ancient ophiolite-hosted deposits1–4, such as those exposed in Cyprus. Here we report results obtained from drilling a series of holes into an actively forming sulphide deposit on the Mid-Atlantic Ridge. A complex assemblage of sulphide–anhydrite–silica breccias provides striking evidence that such hydrothermal mounds do not grow simply by the accumulation of sulphides on the sea floor. Indeed, the deposit grows largely as an in situ breccia pile, as successive episodes of hydrothermal activity each form new hydrothermal precipitates and cement earlier deposits. During inactive periods, the collapse of sulphide chimneys, dissolution of anhydrite, and disruption by faulting cause brecciation of the deposit. The abundance of anhydrite beneath the present region of focused hydrothermal venting reflects the high temperatures ( 〉 150 °C) currently maintained within the mound, and implies substantial entrainment of cold sea water into the interior of the deposit. These observations demonstrate the important role of anhydrite in the growth of massive sulphide deposits, despite its absence in those preserved on land.

Description: The role of sea ice in preconditioning the mixed layers of the central Greenland Sea for deep convection is investigated, with particular emphasis on the formation of the “Nordbukta.” The opening of the ice free bay in late January 1989 indicated that the upper layer was well preconditioned for deep convection which reached down to 1500 m depth in March 1989. We propose that the ice free bay occurred due to diminishing new ice formation without extensive ice melt. A key process is wind‐driven ice drift to the southwest, as observed by upward looking acoustic Doppler current profilers, which will alter the upper ocean freshwater budget when an ice volume gradient along the ice‐drift direction exists. We investigated the importance and effects of such an ice‐drift‐induced freshwater loss on upper ocean properties using an ice‐ocean mixed‐layer model. Observed temperature and salt profiles from December 1988 served as initial conditions, and the model was integrated over the winter season. Given the one‐dimensional physics and climatological surface fluxes, the model was not able to produce a reasonable ice and mixed‐layer evolution. However, allowing ice drift to reduce the local ice thickness improved the ice‐ocean model performance dramatically. An average ice export of 5–8 mm d−1 was needed to be consistent with the observed evolution of mixed‐layer properties and ice cover. Using the same fluxes and ice export, but initial conditions from the “Is Odden” region, yielded ice cover throughout the winter over a shallow mixed layer, both of which are consistent with the observations from the Odden region.

Description: Nutrient and oxygen distributions were measured during a hydrographic survey of the Northeast Water Polynya off the northeast coast of Greenland (77–81°N, 6–17°W) during July–August 1992 and were interpreted in the context of satellite imagery of the region. Satellite imagery revealed a convoluted plume of cold water flowing along isobaths from underneath fast ice in the southwestern portion of the polynya toward the northeast. This plume carried relatively high nutrient and low oxygen inventories. Nitrate to phosphate ratios were low in the polar water, consistent with an ultimate source of this water mass in the Pacific sector of the Arctic Ocean. It is hypothesized that the low N:P Arctic outflow might be the cause of nitrate limitation along the east coast of America as far as Cape Hatteras. Gradients of both nutrients and oxygen inventories in the euphotic zone were observed along and across the axis of mean flow within the polynya and are shown to be due to net production of organic matter. On the basis of these spatial gradients of nitrate and oxygen, an assumed along-axis current velocity of 10 cm s−1, and the observed relationships of biologically removed inorganic carbon with nitrate and oxygen, the net organic matter production was estimated to be 40–60 mmol(C) m−2 d−1. This represents the organic carbon available for export from the polynya euphotic zone. Nutrient-deficient and oxygen-rich waters were observed merging with the southward flowing East Greenland Current, suggestive of possible export, however, the ultimate fate of organic carbon produced within the polynya requires further study.

Description: Three lakes of concentrated brine were discovered in the seabed of the Mediterranean Ridge, southwest of Crete in late 1993 and early 1994. These lakes have a distinctive appearance on side-scan sonar images with no backscattering from the lake surface and enhanced backscattering at their edges (Figure 1). Measurements with conductivity-temperature-depth (CTD) and heat flow probe show in one case a near-isothermal temperature for the lake water and in another thermal layering. The chemistry of the brines varies in each lake and shows that the brines are derived from selective solution of different parts of the Messinian evaporites that lie beneath the seafloor. Flow of seawater through the sediments containing the Messinian evaporites appears to be required to form the lakes.

Description: A survey is given of the dimensions and composition of the present continental crust. The abundances of immobile elements in sedimentary rocks are used to establish upper crustal composition. The present upper crustal composition is attributed largely to intracrustal differentiation resulting in the production of granites senso lato. Underplating of the crust by ponded basaltic magmas is probably a major source of heat for intracrustal differentiation. The contrast between the present upper crustal composition and that of the Archean upper crust is emphasized. The nature of the lower crust is examined in the light of evidence from granulites and xenoliths of lower crustal origin. It appears that the protoliths of most granulite facies exposures are more representative of upper or middle crust and that the lower crust has a much more basic composition than the exposed upper crust. There is growing consensus that the crust grows episodically, and it is concluded that at least 60% of the crust was emplaced by the late Archean (ca. 2.7 eons, or 2.7 Ga). There appears to be a relationship between episodes of continental growth and differentiation and supercontinental cycles, probably dating back at least to the late Archean. However, such cycles do not explain the contrast in crustal compositions between Archean and post‐Archean. Mechanisms for deriving the crust from the mantle are considered, including the role of present‐day plate tectonics and subduction zones. It is concluded that a somewhat different tectonic regime operated in the Archean and was responsible for the growth of much of the continental crust. Archean tonalites and trond‐hjemites may have resulted from slab melting and/or from melting of the Archean mantle wedge but at low pressures and high temperatures analogous to modern boninites. In contrast, most andesites and subduction‐related rocks, now the main contributors to crustal growth, are derived ultimately from the mantle wedge above subduction zones. The cause of the contrast between the processes responsible for Archean and post‐Archean crustal growth is attributed to faster subduction of younger, hotter oceanic crust in the Archean (ultimately due to higher heat flow) compared with subduction of older, cooler oceanic crust in more recent times. A brief survey of the causes of continental breakup reveals that neither plume nor lithospheric stretching is a totally satisfactory explanation. Speculations are presented about crustal development before 4000 m.y. ago. The terrestrial continental crust appears to be unique compared with crusts on other planets and satellites in the solar system, ultimately a consequence of the abundant free water on the Earth.