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  • Polymer and Materials Science  (3,648)
  • Life and Medical Sciences  (1,435)
  • Organic Chemistry  (802)
  • GEOPHYSICS  (755)
  • EARTH RESOURCES AND REMOTE SENSING
  • 2015-2019
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  • 2015-2019
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  • 1
    Publication Date: 2011-08-24
    Description: Comparisons are presented of satellite, rocket, and balloon ozone profiles near Natal, Brazil (5.9 deg S, 35.2 deg W). The low variability of stratospheric ozone at Natal during March and April of 1985 has allowed intercomparisons of reasonably large data sets, rather than a small number of paired satellite/in situ comparisons. There are sharp differences between the profile from the SBUV instrument on Nimbus 7 and the in situ measurements. These results support the conclusions of the NASA Ozone Trends Panel that there is an instrumental cause for the very large changes in upper stratospheric ozone seen by SBUV. Along with other comparisons, these results are being used in a reassessment of the SBUV instrument and its data reduction procedures. The agreement between the ozone profiles from the SAGE II instrument on the ERBS satellite and the rocket values is excellent over the full range of comparisons. Both SAGE II and ROCOZ-A must convert from altitude to pressure for intercomparisons with SME and with SBUV-type instruments. The conversion between pressure and altitude is as important as the ozone measurements, especially in the upper stratosphere where the scale height for ozone is approximately half that for pressure.
    Keywords: GEOPHYSICS
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  • 2
    Publication Date: 2011-08-19
    Description: The Multispectral Atmospheric Mapping Sensor (MAMS) is an airborne scanner which collects imagery in eight visible and three IR bands, with ground resolution of 100 m at a nominal aircraft altitude of 20 km. The visible channels provide continuous spectral coverage from 0.42 to 1.05 microns, and the IR channels measure upwelling and reflected radiation at combinations of 3.7, 6.5, 11.1, and 12.5 microns. These include channels nearly identical to the Landsat TM channels 1-4, and similar to those on the VISSR Atmospheric Sounder (VAS) and AVHRR instruments. The high spatial resolution permits investigation of surface thermal and atmospheric water vapor structure at scales not available from current stabilities. Significant modifications have been made since engineering flights in 1985 to improve the radiometric performance. The increased data quality and recent multidisciplinary applications of this data are presented.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 3
    Publication Date: 2011-08-19
    Description: In summer 1988 an intensive field experiment was conducted in the vicinity of the Pisgah lava flow in the Mojave Desert. Physical properties such as microtopography, composition, soil moisture, and dielectric constant were measured at five sites representing surfaces with rms heights varying from less than one centimeter to tens of centimeters. In addition, polarimetric radar images at P-band, L-band, and C-band were acquired at three different incidence angles with the NASA/JPL airborne imaging radar polarimeter. Using trihedral corner reflectors deployed in the area prior to imaging, the L- and C-band images were calibrated to provide sigma0 values for each resolution element in the scene. The results of inferring geophysical parameters such as rms surface height and correlation length of the measured surfaces by fitting the observed signatures with those predicted by the small-perturbation model are presented: for smoother surfaces, the rms height values inferred are in good agreement with in situ measurements.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 4
    Publication Date: 2011-08-19
    Description: Radar modeling of mangal forest stands in the Sundarbans area of southern Bangladesh is discussed. The modeling uses radar system parameters with forest data on tree height, spacing, biomass, species combinations, and water content (including slightly conductive water) in leaves and trunks of the mangal. For Sundri and Gewa tropical mangal forests, six model components are proposed; the models are required to explain the contributions of various combinations of forest species in the attenuation and scattering of mangal-vegetated nonflooded or flooded surfaces. Statistical data of simulated images have been compared with those of SIR-B images both to refine the modeling procedures and to characterize the model output appropriately. The possibility of delineation of flooded or nonflooded boundaries is discussed.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 5
    Publication Date: 2011-08-19
    Description: Surface-air temperature differences are commonly used in a bulk resistance equation for estimating sensible heat flux (H), which is inserted in the one-dimensional energy balance equation to solve for the latent heat flux (LE) as a residual. Serious discrepancies between estimated and measured LE have been observed for partial-canopy-cover conditions, which are mainly attributed to inappropriate estimates of H. To improve the estimates of H over sparse canopies, one- and two-layer resistance models that account for some of the factors causing poor agreement are developed. The utility of the two models is tested with remotely sensed and micrometeorological data for a furrowed cotton field with 20 percent cover and a dry soil surface. It is found that the one-layer model performs better than the two-layer model when a theoretical bluff-body correction for heat transfer is used instead of an empirical adjustment; otherwise, the two-layer model is better.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 6
    Publication Date: 2011-08-19
    Description: Experimental treatments in a Douglas-fir forest in NE New Mexico were carried out to determine whether differences in forest canopy chemistry could be detected using data from the Airborne Imaging Spectrometer (AIS-2). Experimental treatments consisted of nitrogen fertilizer additions, sawdust additions, and control plots. After AIS-2 data were collected, the digital number of a given pixel was extracted from each channel, yielding 128 values that were used to form a spectrum. Four spectra were extracted from each treatment plot. Multiple stepwise linear regressions between first and second difference transformations of AIS-2 spectra and the canopy characteristics of biomass, nitrogen concentration, and nitrogen content were performed. The results showed a coefficient of multiple determination of 0.71 between first-difference AIS-2 spectra and measured nitrogen concentration in foliage, indicating that it may be possible to predict nitrogen concentration in Douglas fir using AIS-2 spectra.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 7
    Publication Date: 2011-08-19
    Description: The information content in polarimetric SAR images is examined, and the polarimetric image variables containing the information that is important to the classification of terrain features in the images are determined. It is concluded that accurate classification can be done when just over half of the image variables are retained. A reduction in image data dimensionality gives storage savings, and can lead to the improvement of classifier performance. In addition, it is shown that a simplified radar system with only phase-calibrated CO-POL or SINGLE TX channels can give classification performance which approaches that of a fully polarimetric radar.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 8
    Publication Date: 2011-08-19
    Description: The spatial and phenological distribution of vegetation was examined in a remote sensing geobotanical study of the East Africa Rift region. Six normalized difference vegetation index (NDVI) AVHRR (advanced very high resolution radiometer) scenes (February, June, and September of both 1984 and 1987) were used as a measure of vegetation presence. NOAA ETOPO-5 elevation and geographic coordinate data were coregistered with the multitemporal NDVI images. Univariate and multivariate statistics indicate that the NDVI values are significantly associated with elevation, latitude, and longitude. This supports the concept of quantifiable, regional gradients that affect large-scale geobotanical studies. A quadratic regression line was fitted to the NDVI, elevation, latitude, and longitudinal data. In this way a regional trend, as affected by elevation, was determined. The deviation of the actual data from this regional trend was displayed as an image, and shows the local climatic and geological influences.
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  • 9
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    Publication Date: 2011-08-19
    Description: The statistical characteristics of image speckle are reviewed. Existing segmentation techniques that have been used for speckle filtering, edge detection, and texture extraction are sumamrized. The relative effectiveness of each technique is briefly discussed.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 10
    Publication Date: 2011-08-19
    Description: Theory and experiments have shown that passive microwave radiometers can be used to measure soil moisture. However, the presence of a vegetative cover alters the measurement that might be obtained under bare conditions. Deterministically accounting for the effect of vegetation and developing algorithms for extracting soil moisture from observations of a vegetable-soil complex present significant obstacles to the practical use of this approach. The presence of a vegetation canopy reduces the sensitivity of passive microwave instruments to soil moisture variations. The reduction in sensitivity, as compared to a bare-soil relationship, increases as microwave frequency increases, implying that the longest wavelength sensors should provide the most information. Sensitivity also decreases as the amount of vegetative wet biomass increases for a given type of vegetation.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 11
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  • 12
    Publication Date: 2011-08-19
    Description: Spectral bidirectional reflectances were measured over three natural soil sites using a specially designed radiometer called the Parabola. Two of the sites were bare soils, and the third had a sparse cover of desert scrub. The reflectances were strongly non-Lambertian for all three surfaces, but with markedly different patterns. The measured data were fitted with a quasi-physical reflectance model in which the surface backscattering and forwardscattering are separately formulated. A soil reflectance characterization was obtained by assessing the contributions of the forward, backward, and Lambertian components. This three-parameter characterization produced a satisfactory fit to the measured reflectances and appears promising as a basis for soils categorization.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 13
    Publication Date: 2011-08-19
    Description: A radiative-transfer model for the bidirectional reflectance-distribution function (BRDF) shows that snow is moderately anisotropic in the NIR wavelengths. Although the directional-hemispherical albedo of snow decreases as the grains become larger, the forward scattering also increases, with the result that the illumination and viewing geometry must be considered when interpreting physical properties of the surface layer of the snow pack from remote sensing data. Measurements of the BRDF and the transmittance for a variety of snow conditions were made throughout the winter and spring seasons with an SE-590 spectroradiometer, for wavelengths from 0.38 to 1.11 microns. Coincident with these, the surface grain properties were analyzed by stereological methods. A sphere with the same surface-to-volume ratio as the ice grains is used as the equivalent sphere.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 14
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    Publication Date: 2011-08-19
    Description: Remotely sensed data are being used to estimate foliar chemical content. This paper reviews how stepwise multiple regression and deconvolution have been used to extract chemical information from foliar spectra, and concludes that both methods are useful, but neither is ideal. It is recommended that the focus of research be modeling in the long term and experimentation in the short term. Long-term research should increase our understanding of the interaction between radiation and foliar chemistry so that the focus of research can move from leaf model to canopy model to field experiment. Short-term research should aim to design experiments in which remotely sensed data are used to generate unambiguous and accurate estimates of foliar chemical content.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 271-278
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  • 15
    Publication Date: 2011-08-19
    Description: Surface energy balance components were evaluated by combining satellite-based spectral data with on-site measurements of solar irradiance, air temperature, wind speed, and vapor pressure. Maps of latent heat flux density and net radiant flux density were produced using Landsat TM data for three dates. The TM-based estimates differed from Bowen-ratio and aircraft-based estimates by less than 12 percent over mature fields of cotton, wheat, and alfalfa.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 77-87
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  • 16
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    Publication Date: 2011-08-19
    Description: A recent reanalysis of the International Latitude Serivce (ILS) polar motion data-day has been processed using Kalman filtering techniques to generate the polar motion excitation function over the time-span from 1960 to 1965. The resulting excitation function has been examined for the effects of 1960 Chile in an attempt to determine experimentally how large earthquake affect polar motion. The resulting upper bound of about 75 x 10 to the 22nd N-m for a 10-deg dip (about 36 x 10 to the 22nd N-m for 20-deg dip) is consistent with results obtained from previous seismic studies, including a recent normal mode excitation result. Following future great earthquakes, monitoring of polar motion by space-based techniques such as VLBI should continue at high temporal resolution for several weeks in order to directly measure the rheological parameters of the upper mantle.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 16; 1193-119
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  • 17
    Publication Date: 2011-08-19
    Description: Multipolarization P-, L-, and C-band airborne SAR data sets were acquired over a coastal zone and a forested wetland of southern Louisiana. The data sets were used with field-collected surface-parameter data in order to determine the value of SAR systems in assessing and mapping coastal-zone surface features. The coastal-zone surface features in this study are sediments, sediment distribution, and the formation of new isles and banks. Results of the data analysis indicate that the P-band radar with 68-cm wavelength is capable of detecting the submerged sediment if the area is very shallow (i.e., a water depth of less than one meter). The penetration capability of P-band radar is also demonstrated in the forested wetland area. The composition and condition of the ground surface can be detected, as well as the standing water beneath dense tree leaves.
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  • 18
  • 19
    Publication Date: 2011-08-19
    Description: Multiband radiometric data from an airborne imaging thermal scanner are being studied for use in finding buried gravel deposits. The techniques are based on measuring relative differences in the thermal properties between gravel-laden targets and the surrounding gravelless background. These properties are determined from modeling the spectral radiant emittance recorded over both types of surfaces in conjunction with ground measurements of the most significant heat flows above and below the surface. Thermodynamic properties of sampled materials from control sites are determined, and diurnal and annual subsurface heat waves are recorded. Thermal models that account for heat exchange at the surface, as well as varying levels of soil moisture, humidity, and vegetation, are needed for adaptation and modification to simulate the physical and radiative environments of this region.
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  • 20
    Publication Date: 2011-08-19
    Description: The advanced solid-state array spectroradiometer (ASAS) is an airborne, off-nadir pointing imaging spectroradiometer used to acquire bidirectional radiance data for terrestrial targets. As its platform aircraft flies over a target the sensor can image the target through a sequence of at least seven fore-to-aft view directions ranging up to 45 deg on either side of nadir. ASAS acquires data for 29 spectral bands in the visible and near-infrared portions of the spectrum with a resolution of 15 nm. ASAS data were recently acquired for a prairie ecosystem and a northern forest ecosystem. The data demonstrate the combined effects of reflectance anisotropy and increased atmospheric path length on off-nadir observations. One result of these effects is a variation in vegetation indices as a function of view direction. Normalized-difference-vegetation-indices for prairie grass, coniferous, and deciduous canopies varied up to 14 percent, 23 percent, and 6 percent, respectively, relative to nadir as a function of view zenith angle along the solar principal plane.
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  • 21
    Publication Date: 2011-08-19
    Description: During the First International Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE), 80 gigabytes of image data were generated from a variety of satellite and airborne sensors in a multidisciplinary attempt to study energy and mass exchange between the land surface and the atmosphere. To make these data readily available to researchers with a range of image data handling experience and capabilities, unique image-processing software was designed to perform a variety of nonstandard image-processing manipulations and to derive a set of standard-format image products. The nonconventional features of the software include: (1) adding new layers of geographic coordinates, and solar and viewing conditions to existing data; (2) providing image polygon extraction and calibration of data to at-sensor radiances; and, (3) generating standard-format derived image products that can be easily incorporated into radiometric or climatology models. The derived image products consist of easily handled ASCII descriptor files, byte image data files, and additional per-pixel integer data files (e.g., geographic coordinates, and sun and viewing conditions). Details of the solutions to the image-processing problems, the conventions adopted for handling a variety of satellite and aircraft image data, and the applicability of the output products to quantitative modeling are presented. They should be of general interest to future experiment and data-handling design considerations.
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  • 22
    Publication Date: 2011-08-19
    Description: In order to evaluate the importance of surface thermal flux and emissivity variations on surface and boundary layer processes, a technique that uses thermal data from an airborne multispectral scanner to determine the surface skin temperature and thermal emissivity over a regional area has been developed. These values are used to estimate the total flux density emanating from the surface and at the top of the atmosphere. Data from the multispectral atmospheric mapping sensor (MAMS) collected during the First ISLSCP Field Experiment (FIFE) are used to develop the technique, and to show the time and space variability of the flux values. The ground truth data available during FIFE provide a unique resource to evaluate this technique.
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  • 23
    Publication Date: 2011-08-19
    Description: A common problem in acquiring ground-truth data for use in microwave interaction modeling is the capture of surface roughness data that are both sampled at distances comparable to a fraction of the wavelength and extensive enough to represent the surface statistics in at least one resolution cell of the microwave remote sensor used. A technique has been developed for acquiring the necessary photogrammetric data using twin 70-mm film cameras mounted on a helicopter boom. The apparatus is described, and the accuracy with which ground surface roughness can be characterized using this device is estimated. Both standard and cross-correlation methods were used for data reduction. Stereogrammetry is compared with a completely automated image-matching technique. Dense disparity images were generated from the helicopter stereo pairs. Using interior orientation parameters supplied by the camera manufacturers, and assuming that exterior orientation parameters remain constant between control target and test field photography, an extremely dense DEM (digital elevation model) for a test field has been derived. Results are compared, and accuracy estimates are presented.
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  • 24
    Publication Date: 2011-08-19
    Description: The Clark Mountains in eastern California form a rugged, highly dissected area nearly 5000 ft above sea level, with Clark Mountain rising to 8000 ft. The rocks of the Clark Mountains and the Mescal Range just to the south are Paleozoic carbonate and clastic rocks, and Mesozoic clastic and volcanic rocks standing in pronounced relief above the fractured Precambrian gneisses to the east. The Permian Kaibab Limestone and the Triassic Moenkopi and Chinle Formations are exposed in the Mescal Range, which is the only place in California where these rocks, which are typical of the Colorado Plateau, are found. To the west, the mountains are bordered by the broad alluvial plains of Shadow Valley. Cima Dome, which is an erosional remnant carved on a batholithic intrusion of quartz monzonite, is found at the south end of the valley. To the east of the Clark and Mescal Mountains is found the Ivanpah Valley, in the center of which is located the Ivanpah Play. Studies of the Clark Mountains with the airborne visible/infrared imaging spectrometer are briefly described.
    Keywords: GEOPHYSICS
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  • 25
    Publication Date: 2011-08-19
    Description: Algorithms to correct for atmospheric-scattering effects in high-spatial resolution land-surface images require the ability to perform rapid and accurate computations of the top-of-atmosphere diffuse radiance field for arbitrarily general surface reflectance distributions (which may be both heterogeneous and non-Lambertian) and atmospheric models. Using three-dimensional radiative transfer (3DRT) theory algorithms are being developed. The methodology used to perform the 3DRT calculations is described. It is shown how these calculations are used to perform atmospheric corrections, and the sensitivity of the retrieved surface reflectances to atmospheric structural parameters is illustrated.
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  • 26
    Publication Date: 2011-08-19
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  • 27
    Publication Date: 2011-08-19
    Description: A model for the brightness temperature of a canopy which is based on the physical characteristics of the vegetation is being developed. This model uses the Peake model to relate the scattering coefficient of the vegetation to its radiometric brightness temperature and a discrete scattering model to computer the scattering coefficient. A distorted Born approximation is used to provide a tractable solution to the scattering problem. To verify the theory a comparison has been made with experiments. Radiometric measurements of brightness temperature were made at L- and C-bands over a crop of mature soybeans, along with ground truth measurements. All model input parameters were measured; there were no free parameters to adjust to obtain agreement with the measurements. Results showed that agreement between theory and measurements was reasonable for horizontal polarization at both L- and C-bands with dry underlying soil.
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  • 28
    Publication Date: 2011-08-19
    Description: During the spring of 1988, the NASA/JPL multifrequency, multipolarization SAR (synthetic aperture radar) flew in series of calibration experiments over the Goldstone dry lake bed. An array of calibration devices was deployed, including dihedral and trihedral corner reflectors, polarimetric active radar calibrators, passive receivers, and CW (continuous wave) tone generators. The aim of the campaign was to calibrate both amplitude and phase of the resulting SAR images, over long and short time scales. The results of the analysis of the calibration data collected in the spring of 1988 are presented. Trihedral corner reflector signatures and certain image background measures are used to externally calibrate relative amplitude and phase between polarizations at a given frequency, and to calibrate across frequencies. Assessments are made of the calibration accuracy as a function of image frame position for each frequency, and the stability of the radar calibration over long and short time-scales.
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  • 29
    Publication Date: 2011-08-19
    Description: An unsupervised clustering algorithm is used to segment multifrequency polarimetric radar data from the NASA/JPL airborne SAR (synthetic aperture radar). Twenty-two parameters are evaluated for their discriminatory capability for each pixel of an image. A clustering analysis is then performed using different subsets of these parameters. This analysis relies on data taken as part of an intensive field experiment during the summer of 1988 in the vicinity of the Pisgah lava flow in the Mojave Desert in southern California. As part of the experiment, extensive ground truth was acquired, including dielectric constant and topography measurements. Segmentation results show good agreement with these measurements.
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  • 30
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    Publication Date: 2011-08-19
    Description: Microwave limb-sounding can be used to improve understanding of earth's upper atmosphere. This paper summarizes general features of the technique. An experiment being developed for the Upper Atmosphere Research Satellite is described. Plans for the future Earth Observing System are discussed.
    Keywords: GEOPHYSICS
    Type: Atmospheric Research (ISSN 0169-8095); 23; 391-410
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  • 31
    Publication Date: 2011-08-19
    Description: This paper presents an extension of the conventional uncertainty analysis which characterizes the sources of uncertainty in the coefficients of the geomagnetic field models. The new formalism accounts for the systematic errors introduced by the omission of such sources as the presence of crustal fields, the external fields, and the field from the truncated terms. The usefulness of this formalism depends on two critical conditions. The first of these is the knowledge of the statistical properties of the fields whose parameters are not solved in the analysis, i.e., the crustal field and the external field. The second critical point in the practical use of the method is the approximation used for the weight matrix.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 12281-12
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  • 32
    Publication Date: 2011-08-19
    Description: Analysis of small-scale structure in the in situ measurements made from the ER-2 during the Airborne Antarctic Ozone Experiment shows the existence of a region at the boundary of the chemiclly perturbed region where the mixing ratios and small-scale structure of trace gases are influenced by transport across the boundary. This transition region is characterized by horizontal interchange and vertical layering of air parcels from within and outside of the chemically perturbed region and negative small-scale correlations between ClO and ozone. The horizontal transport in this region creates large surface areas between dissimilar air masses, providing the potential for substantial mixing. Correlations between ClO and O3 show that the transition region extends to 2-4 deg of latitude to either side of the boundary of the chemically perturbed region. A + or - 4-deg-wide transition region would contain nearly as much air as the chemically perturbed region proper. Analysis of water vapor and nitrous oxide data suggests that diabatic descent is associated with dehydration. This could be caused by strong radiative cooling of those polar stratospheric clouds in which enough water condenses for the particles to fall and dehydrate the air.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11669-11
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  • 33
    Publication Date: 2011-08-19
    Description: Fluid dynamic aspects of the Antarctic ozone hole phenomena are studied. Data collected by the ER-2 aircraft as part of the Airborne Antarctic Ozone Experiment (AAOE) are used to calculate the potential vorticity distribution on potential temperature surfaces. Most of the ER-2 flights show a monotonic decrease in potential vorticity and nitrous oxide toward the pole on isentropic surfaces.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11625-11
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  • 34
    Publication Date: 2011-08-19
    Description: Localized rapid reductions in total ozone (miniholes), which were observed during the Airborne Antarctic Ozone Experiment, are studied with particular attention given to meteorological aspects. It is suggested that miniholes are forced by tropospheric weather features and that they are largely reversible distortions to the airflow around the vortex. The relationship between the miniholes and upper tropospheric and lower stratospheric synoptic-scale disturbances is studied. Trajectory calculations are presented which demonstrate the exchange of air from low latitudes with air from within the vortex, with the vortex air subsequently moving to lower latitudes.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11641-11
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  • 35
    Publication Date: 2011-08-19
    Description: Whole-air samples collected aboard the NASA ER-2 and DC-8 aircraft as part of the Airborne Antarctic Ozone Experiment were analyzed in a field laboratory set up at Punta Arenas, Chile. Mixing ratios obtained from gas chromatographic analyses of these samples are presented for CH4, CO, N2O, CFCl3, CF2Cl2, C2F3Cl3, CH3CCl3, and CCl4. A comparison of CFCl3/N2O mixing ratios from the flights of September 16-29, 1987 provides evidence of sustained subsidence.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11599-11
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  • 36
    Publication Date: 2011-08-19
    Description: Simultaneous measurements of the atmospheric burdens of CH4, N2O, CO2, CF2Cl2, and CO above McMurdo Station, Antarctica, have been derived from solar absorption spectra obtained by the Jet Propulsion Laboratory high-resolution Fourier transform spectrometer. In all cases the burdens are smaller than midlatitude values. Furthermore, retrievals of N2O and CH4 indicate that the tropospheric mixing ratios were normal and that the depletion of the burdens can best be accounted for by a downward shift of the volume mixing ratio profiles by some 6-8 km. This rules out the possibility of large-scale upwelling of ozone-poor tropospheric air into the stratosphere being the cause of the Antarctic springtime ozone depletion.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11613-11
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  • 37
    Publication Date: 2011-08-19
    Description: In situ N2O measurements were made using an airborne tunable laser absorption spectrometer (ATLAS) on 12 flights into the Antarctic vortex, as well as on five transit flights outside the vortex region in August and September 1987, as part of the Airborne Antartic Ozone Experiment. Vertical profiles of N2O were obtained within the vortex on most of these flights and were obtained outside the vortex on several occasions. Flights into the vortex region show N2O decreasing southward between 53 and 72 S latitude on constant potential temperature surfaces in the lower stratosphere. The data lead to two important conclusions about the vortex region: (1) the lower stratosphere in August/September 1987 was occupied by 'old' air, which had subsided several kilometers during polar winter; (2) the N2O profile in the vortex was in an approximately steady state in August/September 1987, which indicates that the spring upwelling, suggested by several theories, did not occur.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11589-11
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  • 38
    Publication Date: 2011-08-19
    Description: The quasi-biennial oscillation (QBO) in total ozone and temperature has been extracted from 9 years of Total Ozone Mapping Spectrometer (TOMS) observations and National Meteorological Center (NMC) analyses. Years in which QBO-related variations in the total ozone and temperature are positive are found to correspond to years with smaller September Antarctic total ozone hole decline rates and vice versa. The QBO appears to be responsible for September decline rate deviations up to 0.4 Dobson units (DU) per day. Also, the QBO at mid-latitudes appears to be better correlated with the 30-mbar tropical QBO winds than with those at 50 mbar. Possible mechanisms that would explain these phenomena are discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11559-11
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  • 39
    Publication Date: 2011-08-19
    Description: Results from the Lagrangian photochemical model integrated along computed air parcel trajectories intersected by the ER-2 aircraft are presented and compared with AAOE observations. According to the model, the BrO observations made from the ER-2 within the dehydrated denitrified region are consistent with there being approximately 5 parts per trillion by volume of BrO(y) at 428 K in spring. Within the high ClO region, ozone destruction rates are expected to exceed 2 percent/d with approximately 80 percent due to the ClO dimer mechanism.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11529-11
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  • 40
    Publication Date: 2011-08-19
    Description: A program designed to study the Antarctic ozone hole using ER-2 high-altitude and DC-8 aircraft was conducted out of Punta Arenas, Chile during August 17-September 22, 1987. Graphs are presented of ozone and chlorine monoxide when crossing the boundary of the chemically perturbed region on August 23 and on September 21. Interpretations of ClO, H2O, and N2O measurements are presented, indicating ongoing diabetic cooling and advective poleward transport across the boundary.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11437-11
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  • 41
    Publication Date: 2011-08-19
    Description: Mixing ratios changed dramatically for ozone in the austral polar stratosphere during August and September 1987. Data were obtained with an ultraviolet photometer mounted in the equipment bay of an ER-2 aircraft. Measurements were made between the latitudes of 53 and 72 deg S at pressure altitudes (U.S. Standard Atmosphere, 1976) up to 21 km in a series of flights from Punta Arenas, Chile, over the Palmer Peninsula. Additional data were obtained between 37 N and 53 deg S on the ferry flights leaving from and returning to Moffett Field, California. The sampling-collecting system and the analytical techniques are described. In September the mixing ratios for ozone at pressure altitudes above 15 km in the southernmost part of the flights over the Palmer Peninsula were significantly lower than values for midlatitudes. The various latitudes of the ER-2 aircraft's encounters with the boundary of the region of depleted ozone lie between 59 and 71 deg S. Near the 425 K potential temperature surface and well within the vortex, the measured mixing ratio of ozone declined from about 2 parts per million by volume (ppmv) to about 0.6 ppmv during the period of the ER-2 flights. The distributions of ozone as a function of altitude indicate the presence of layering of ozone.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11449-11
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  • 42
    Publication Date: 2011-08-19
    Description: A Fourier transform spectrometer was flown aboard a DC-8 on 10 flights over Antarctica during August and September, 1987, as part of the Airborne Antarctic Ozone Experiment (AAOE). Observing the sun at infrared wavelengths, it was possible to determine the integrated column amount above the flight altitude for ozone and a number of other chemical species that are believed to be important in the perturbed chemistry of the 'ozone hole'. The paper describes the method, the observations, the data analysis procedure, and the ozone results. During the observation period, ozone developed a steep gradient near the edge of the polar vortex; deep within the vortex, the average ozone column decreased by about 1.6 percent per day during September.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11413-11
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  • 43
    Publication Date: 2011-08-19
    Description: Filter samples obtained as part of the AAOE to determine the total nitrate, sulfate, acidic chloride, and acidic fluoride content along the flight path of the NASA ER-2 are studied. These compounds were obtained in the aerosol and vapor phase. The ratio of particulate sulfate observed outside the chemically perturbed region (CPR) of the vortex to that inside the CPR was 2.6. The ratio of total acidic chloride to total acidic flouride within the CPR is near 1, indicating the removal of chloride from the air mass or the partitioning of chloride into an unmeasured species.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11285-11
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  • 44
    Publication Date: 2011-08-19
    Description: The 1987 Airborne Antarctic Ozone Experiment, in which the NO3, Cl, and SO4 contents of stratospheric aerosols were estimated, is discussed. The aerosol size and chemical composition measurements were carried out on samples collected during August 17 to September 4, 1987. The data indicate that condensed nitrate is found below a threshold temperature of 193.6 + or - 3.0 K, which is generally found at latitudes exceeding 64 deg S. A negative correlation exists between condensed nitrate and ozone correlation.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11271-11
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  • 45
    Publication Date: 2011-08-19
    Description: Measurements of the vertical profile of particles with condensation nuclei counters and eight channel aerosol detectors at McMurdo Station, Antarctica, in 1987 verified observations made in 1986 concerning the absence of upwelling in the polar vortex and the presence of a condensation nuclei layer in conjunction with the ozone hole region. New observations of a bimodal aerosol size distribution, consisting of a large-particle mode mixed in with the small-particle sulfate mode, at temperatures below -79 C are consistent with the presence of nitric acid-water particles at low concentrations. Higher concentrations of large particles were observed in association with nacreous clouds. An unusual particle layer which contained enhanced concentrations of both the small-particle (sulfate) mode and the large-particle (nitric acid) mode was detected at temperatures below -85 C, suggesting simultaneous nucleation and growth phenomena. The vortex condensation nuclei layer was observed to form at the same time as the ozone hole, indicating that formation of the layer is triggered by photochemical processes and may be important in controlling ozone depletion above 22 km.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11253-11
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  • 46
    Publication Date: 2011-08-19
    Description: The Microwave Temperature Profiler (MTP) measures profiles of air temperature versus altitude. The altitude coverage is about 5 km at a flight altitude of 20 km (66,000 feet), and the profiles are obtained every 14 s. The MTP instrument is installed on NASA's ER-2 aircraft, which flew 13 missions over Antarctica during the Airborne Antarctic Ozone Experiment. Altitude temperature profiles were used to derive potential temperature cross sections. These cross sections have been useful in detecting atmospheric waves. Many wave encounters have been identified as 'mountain waves'. The mountain waves are found to extend from the lowest altitudes measured to the highest (about 24 km). The southern part of the Palmer Peninsula was found to be associated with mountain waves more than half the time. Altitude temperature profiles were also used to measure the lapse rate along the flight track. Lapse rate versus latitude plots do not show significant changes at the ozone hole boundary.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11223-11
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  • 47
    Publication Date: 2011-08-19
    Description: Pedogenic calcite-crystal coatings on clasts were examined in four soils along an altitudinal gradient on Kyle Canyon alluvium in southern Nevada. Clast coatings were studied rather than matrix carbonate to avoid the effects of soil matrix on crystallization. Six crystal sizes and shapes were recognized and distinguished. Equant micrite was the dominant crystal form with similar abundance at all elevations. The distributions of five categories of spar and microspar appear to be influenced by altitudinally induced changes in effective moisture. In the drier, lower elevation soils, crystals were equant or parallel prismatic with irregular, interlocking boundaries while in the more moist, higher elevation soils they were randomly oriented, euhedral, prismatic, and fibrous. There was little support for the supposition that Mg(+2) substitution or increased (Mg + Ca)/HCO3 ratios in the precipitating solution produced crystal elongation.
    Keywords: GEOPHYSICS
    Type: Soil Science Society of America, Journal (ISSN 0038-0776); 53; 211-219
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  • 48
    Publication Date: 2011-08-19
    Description: Chemical, physical, and microscopic data for three soils in the northern Monitor Valley are analyzed. The soils ranked in order of increasing age are: Mule, Rotinom, and Nayped. The procedures and techniques used to obtain and study that data are described. It is observed that: (1) redistribution of carbonate is detectable in all soils; (2) clay illuviation is insignificant in the Mule soil, weak but identifiable in the Rotinom soil, and significant in the Nayped soil; and (3) the maximum sodium adsorption ratio (SAR) and electrical conductivity (EC) for the Mule soil is between 64-89 cm, for the Rotinom soil the values are below 100 cm, and for Nayped the maximum SAR values range from 51-117 cm and maximum EC values are between 117-152 cm. The relationship between volcanic glass weathering and the amount of silica cementation in the soils is studied. It is noted that silicification of Monitor Valley holocene soils is due to there being enough moisture to release silica from volcanic glass, but not enough to leach the weathering products from the profile.
    Keywords: GEOPHYSICS
    Type: Soil Science Society of America, Journal (ISSN 0038-0776); 53; 158-164
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  • 49
    Publication Date: 2011-08-19
    Description: An experiment to study the hypothesis that winter cold fronts are more important that violent summer storms in moving sediment in midlatitude coastal river deltas. The experiment is based on Calibrated Airborne Multispectral Scanner (CAMS) data. A new approach for the georeferencing of aircraft imagery has been developed for use in this experiment. The software for the approach uses the aircraft inertial navigation data and is able to automatically map a three-channel 1600 line file through a 90 deg rotation in less than 14 minutes. Results from tests of the technique show rms errors of less than 2/3 of a pixel.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Photogrammetric Engineering and Remote Sensing (ISSN 0099-1112); 4; 1161-116
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  • 50
    Publication Date: 2011-08-19
    Description: One-dimensional aerosol microphysical and photochemical models are used to study the chemistry of stratospheric volcanic clouds. The results indicate that the aerosol microphysical processes of condensation and coagulation produce larger particles as the SO2 injection rate is increased. Larger particles have a smaller optical depth per unit mass and settle out of the stratosphere at a faster rate than smaller ones, restricting the total number of particles in the stratosphere. The microphysical processes moderate the impact of volcanic clouds on the earth's radiation budget and climate, suggesting that volcanic effects may be self limiting. It is noted that the injection of HCl into the stratosphere, which could lead to large ozone changes, is limited by a cold trap effect in which HCl and water vapor condense on ash particles in the rising volcanic plume and fall out as ice.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11165-11
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  • 51
    Publication Date: 2011-08-19
    Description: Nine experiments obtained stratospheric ozone measurements during the fall 1985 Middle Atmosphere Program (MAP) Global Budget of Stratospheric Trace Constituents (GLOBUS) NO(x) campaign. Measurements are grouped into four sets from four air masses and compared. Agreement between individual experiments and weighted mean profiles is generally within 10 percent and within absolute accuracies. Dobson Umkehr values in layer 5 differ by more than absolute accuracies from weighted mean profiles. Brewer sonde values for one data set are outside absolute accuracies near the ozone peak. Solar UV occultation measurements are 30-35 percent less than the weighted mean profile and outside absolute accuracies. Measurements from the Exospheric Satellite backscattered ultraviolet experiment, not previously compared with other techniques, agree within 10-15 percent of weighted mean profiles. Results of the campaign are generally consistent with those of four previous intercomparison campaigns.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11074-11
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  • 52
    Publication Date: 2011-08-19
    Description: The secular increase of the total vertical column abundance of carbon monoxide has been derived from sets of infrared solar spectra recorded from an altitude of 3.58 km at the Jungfraujoch Station, Switzerland, in 1950-1951 and in 1985-1987. The results are based on equivalent width measurements of the R3 line of the 1-0 vibration-rotation band of (C-12)(0-16) at 2159.30/cm. The set of 1985-1987 observations indicates a strong seasonal cycle in the total column abundance of CO, with a + or - 25 percent modulation between minimum values in late summer and the maximum values in late winter. Variability on shorter time scales is also present in both the old and recent data sets. The mean cumulative rate of increase of the total column abundance of CO above the Jungfraujoch is found to be (0.85 + or - 0.20) percent/yr between 1950-1951 and 1985-1987. The present findings are compared with trends reported in earlier studies.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 11021-11
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  • 53
    Publication Date: 2011-08-19
    Description: The dilatational strains associated with vertical faults embedded in a horizontal plate are examined in the framework of fault kinematics and simple displacement boundary conditions. Using boundary element methods, a sequence of examples of dilatational strain fields associated with commonly occurring strike-slip fault zone features (bends, offsets, finite rupture lengths, and nonuniform slip distributions) is derived. The combinations of these strain fields are then used to examine the Parkfield region of the San Andreas fault system in central California.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 10204-10
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  • 54
    Publication Date: 2011-08-19
    Description: A technique for resolving the ambiguities in the GPS carrier phase data (which are biased by an integer number of cycles) is described which can be applied to geodetic baselines up to 2000 km in length and can be used with dual-frequency P code receivers. The results of such application demonstrated that a factor of 3 improvement in baseline accuracy could be obtained, giving centimeter-level agreement with coordinates inferred by very-long-baseline interferometry in the western United States. It was found that a method using pseudorange data is more reliable than one using ionospheric constraints for baselines longer than 200 km. It is recommended that future GPS networks have a wide spectrum of baseline lengths (ranging from baselines shorter than 100 km to those longer than 1000 km) and that GPS receivers be used which can acquire dual-frequency P code data.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 10187-10
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  • 55
    Publication Date: 2011-08-19
    Description: Recent studies of solar UV spectra and various indices of solar activity indicate a strong period at about 5 months. In the 10.7 cm solar radio flux (F10.7), a conventional index for the solar EUV and UV variabilities, the spectral power of the 5 month period is comparable to the well known 27 day solar period. However, in the solar UV flux at 205 nm, directly measured from the Nimbus-7 SBUV spectrometer, the (spectral) power of the 5 month period is about half that of the 27 day period. This paper examines the possible impact of the 5 month solar period on ozone and temperature at various pressure levels in the stratosphere and discusses the implications of differences in solar forcing at the 27 day and 5 month periods. It is shown that ozone, both in the lower and the upper stratosphere, has a measurable response to solar UV forcing at 27 days. Such a solar response is not observed at 5 month period because of a relatively weaker 5 month solar UV component in the solar signal and a strong interference from dynamical signals associated with planetary wave activity.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 16; 711-714
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  • 56
    Publication Date: 2011-08-19
    Description: The operational Stratospheric Aerosol and Gas Experiment II multichannel data inversion algorithm is described. Aerosol and ozone retrievals obtained with the algorithm are discussed. The algorithm is compared to an independently developed algorithm (Lenoble, 1989), showing that the inverted aerosol and ozone profiles from the two algorithms are similar within their respective uncertainties.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 8339-835
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  • 57
    Publication Date: 2011-08-19
    Description: The validity of particulate extinction coefficients derived from limb path solar radiance measurements obtained during the Stratospheric Aerosol and Gas Experiment (SAGE) II is tested. The SAGE II measurements are compared with correlative aerosol measurements taken during January 1985, August 1985, and July 1986 with impactors, laser spectrometers, and filter samplers on a U-2 aircraft, an upward pointing lidar on a P-3 aircraft, and balloon-borne optical particle counters. The data for July 29, 1986 are discussed in detail. The aerosol measurements taken on this day at an altitude of 20.5 km produce particulate extinction values which validate the SAGE II values for similar wavelengths.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 8367-838
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  • 58
    Publication Date: 2011-08-19
    Description: The process of validating data from the Stratospheric Aerosol and Gas Experiment (SAGE) II and the initial use of the validated data are reviewed. The instruments developed for the SAGE II, the influence of the eruption of El Chichon on the global stratospheric aerosol, and various data validation experiments are discussed. Consideration is given to methods for deriving aerosol physical and optical properties from SAGE II extinction data and for inferring particle size distribution moments from SAGE II spectral extinction values.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 8335-833
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  • 59
    Publication Date: 2011-08-19
    Description: The spherical harmonic equation for the gravitational potential inside the earth is presented. The equation satisfies Poisson's equation and converges uniformly. It obviates the need for downward continuation of the exterior potential with its attendant convergence difficulties but of course requires some knowledge of the earth's density distribution. The equation is used to derive the general expression for the geophysical measurement of the gravitational constant G made inside the earth, such as in boreholes and mine shafts. Numerical evidence is also presented to show that the long- to intermediate-wavelength gravity anomalies can masquerade as the 'fifth force' if not properly corrected for.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 7563-756
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  • 60
    Publication Date: 2011-08-19
    Description: Rapid loss of ozone over Antarctica in spring requires that the abundance of gaseous nitric acid be very low. Precipitation of particulate nitric acid has been assumed to occur in association with large ice crystals, requiring significant removal of H2O and temperatures well below the frost point. However, stratospheric clouds exhibit a bimodal size distribution in the Antarctic atmosphere, with most of the nitrate concentrated in particles with radii of 1 micron or greater. It is argued here that the bimodal size distribution sets the stage for efficient denitrification, with nitrate particles either falling on their own or serving as nuclei for the condensation of ice. Denitrification can therefore occur without significant dehydration, and it is unnecessary for temperatures to drop significantly below the frost point.
    Keywords: GEOPHYSICS
    Type: Nature (ISSN 0028-0836); 339; 525-527
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  • 61
    Publication Date: 2011-08-19
    Description: For three weeks, from January 18 to February 5, 1988, scientists and engineers from 13 countries and 30 international agencies and institutions cooperated in the most extensive GPS (Global Positioning System) field campaign, and the largest geodynamics experiment, in the world to date. This collaborative eperiment concentrated GPS receivers in Central and South America. The predicted rates of motions are on the order of 5-10 cm/yr. Global coverage of GPS observations spanned 220 deg of longitude and 125 deg of latitude using a total of 43 GPS receivers. The experiment was the first civilian effort at implementing an extended international GPS satellite tracking network. Covariance analyses incorporating the extended tracking network predicted significant improvement in precise orbit determination, allowing accurate long-baseline geodesy in the science areas.
    Keywords: GEOPHYSICS
    Type: IEEE Transactions on Instrumentation and Measurement (ISSN 0018-9456); 38; 648-651
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  • 62
    Publication Date: 2011-08-19
    Description: Space photography has been successfully used to extend the space remote sensing data base for environmental monitoring by a decade. In this study of Lake Chad, space photographs were digitized and registered to a topographic base map before water classifications were performed. From 1966 to 1985 over a 21,000-square-kilometer decrease in lake surface area was observed.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Geocarto International (ISSN 1010-6049); 4; 75-79
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  • 63
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    Publication Date: 2011-08-19
    Description: Space Shuttle astronauts have used handheld cameras to take about 30,000 photographs of the earth as seen from orbit. These pictures provide valuable, true-color depictions of many geologically significant areas. While the photographs have areal coverages and resolutions similar to the more familiar Landsat MSS and TM images, they differ from the latter in having a wide variety of solar illumination angles and look angles. Astronaut photographs can be used as very small scale aerial photographs for geologic mapping and planning logistical support for field work. Astronaut photography offers unique opportunities, because of the intelligence and training of the on-orbit observer, for documenting dynamic geologic activity such as volcanic eruptions, dust storms, etc. Astronauts have photographed more than 3 dozen volcanic eruption plumes, some of which were not reported otherwise. The stereographic capability of astronaut photography also permits three-dimensional interpretation of geologic landforms which is commonly useful in analysis of structural geology. Astronauts have also photographed about 20 known impact craters as part of project to discover presently unknown examples in Africa, South America, and Australia.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Geocarto International (ISSN 1010-6049); 4; 49-54
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  • 64
    Publication Date: 2011-08-19
    Description: The possiblity is investigated that a substantial change has occurred in middle-atmospheric water vapor as a result of the increase in atmospheric methane over the past century and a half. It is shown from modeling of mesospheric ice-particle formation that noctilucent cloud brightness should be a sensitive indicator of the water content at the high-latitude summertime mesopause. From an examination of the historical record of noctilucent cloud occurrence, it is found that such clouds are absent from the record before 1885, a finding which is consistent with the hypothesis proposed in this paper.
    Keywords: GEOPHYSICS
    Type: Nature (ISSN 0028-0836); 338; 490-492
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  • 65
    Publication Date: 2011-08-19
    Description: The possible depletion of ozone due to heterogeneous reactions occurring in Arctic polar stratospheric clouds (PSCs) is fundamentally different from the Antarctic situation. PSCs in the Arctic are relatively short-lived and occur over limited regions of the Arctic stratosphere. The Arctic situation is examined using a model which calculates photochemical processes as a function of longitude in air circulating with fixed velocity around the pole at fixed pressure level and latitude. The model allows sunlight to vary diurnally and PSCs to occur in specified subregions of the domain. Measurements of chemical species including HCl, ClO, NO2 and HNO3 downwind from a PSC should show obvious changes compared to measurements in air unaffected by clouds. These species concentrations are found to be sensitive to sticking coefficients, cloud characteristics including particle number density and surface area, and to the PSC exposure time.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 16; 131-134
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  • 66
    Publication Date: 2011-08-19
    Description: The distributions in the stratosphere of a variety of chemical species were calculated for a 6-day period during the February 1979 stratospheric major warming, using winds derived from a spectral forecast model which included O(x), NO(x), HO(x), and ClO(x) chemistries as well as longitudinally varying reaction rate coefficients and photolysis rates for these molecules. The results obtained indicate a particular importance of chemistry and transport for the Cl-containing species ClO, ClONO2, HCl, and HOCl. Dynamical effects dominate the variability of HCl, while diurnal effects dominate that of ClONO2 and ClO. The effects of strong planetary wave activity may be seen in terms of large longitudinal variability of the total HCl and ClONO columns in the stratosphere; in the middle and high northern latitudes, it is sufficiently large to exceed the diurnal variability of the column.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 1057-108
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  • 67
    Publication Date: 2011-08-19
    Description: Representative chemical, structural, and morphological analyses of the large (greater than 1 micron diameter) solid particles from three impaction collection surfaces have been performed. These collections sampled the stratosphere at approximately 17-19 km in altitude during 1976, 1981, and 1984. For these sampling periods, the stratospheric solid-particle number densities have been determined to be 0.089, 0.16, and 1.7 particles/cu m of air, respectively, for particles of greater than 1 micron diameter. This rise in solid-particle number density for the stratosphere over the collection period is likely due to the influx of solid rocket exhaust and rocket and satellite debris into the atmosphere in increasingly larger amounts with time. Some of this material is shed from spacecraft during ascent through the atmosphere, but the majority is probably provided during the descent of material from earth's growing belt of debris in low-earth orbit.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 1047-105
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  • 68
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    Publication Date: 2011-08-19
    Description: The Upper Atmosphere Research Satellite (UARS) has been proposed for intensive studies of the 15-100 km-altitude region of the earth's atmosphere, begining in 1991. This 14,000-lb satellite will carry a suite of 10 instruments able to study the energy input and loss, photochemistry, and circulation of the upper atmosphere, as well as the extensive web of interactions among these three processes. UARS's remote sensors will give attention to the atmospheric molecular species of the nitrogen, hydrogen, and chlorine families.
    Keywords: GEOPHYSICS
    Type: Aerospace America (ISSN 0740-722X); 27; 24-26
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  • 69
    Publication Date: 2011-08-19
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Geocarto International (ISSN 1010-6049); 4; 63-66
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  • 70
    Publication Date: 2011-08-19
    Description: The environmental, geologic, meteorologic, and oceanographic phenomena documented by earth photography during the Space Shuttle STS-29 mission are reviewed. A map of the nadir point positions of earth-viewing photographs from the mission is given and color photographs of various regions are presented. The mission photographs include atmospheric dust and smoke over parts of Africa and Asia, Sahelian water sites, center pivot irrigation fields in the Middle East, urban smog over Mexico City, isolated burning in the Bolivian Amazon, and various ocean features and cloud formations.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Geocarto International (ISSN 1010-6049); 4; 67-80
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  • 71
    Publication Date: 2011-08-19
    Description: Antarctic polar stratospheric cloud (PSC) sightings by the orbiting SAM II sensor during September and October show a pronounced quasi-biennial oscillation (QBO) signal, and October sightings have increased markedly over the past 10 years in years of westerly QBO phase. The QBO in PSC frequency is likely to affect the rate of Antarctic heterogeneous chemical processes and, hence, ozone depletion. Studies of the observed long-term temperature trend suggest that the decadal PSC trend probably results from the ozone decline, through its effect on stratospheric heating rates. A more detailed analysis of data from 1986 to 1987 shows that there were more PSCs in 1987, and that they persisted much later into the spring season as compared to 1986. Qualitatively similar behavior was found for the OClO column abundances and 18-km ozone depletion observed at McMurdo Station during these 2 years. These observations suggest that both the intensity and duration of heterogeneous chemical processes are likely greater during colder OBQ-westerly phase years.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 16; 1157-116
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  • 72
    Publication Date: 2011-08-19
    Description: Problems encountered during efforts to reformulate the IRI description of the electron density profile are examined. Consideration is given to Booker's (1979) proposal that the unique, analytic profile functions should cover the entire ionospheric height range. The IRI topside model is reviewed and the electron density profile of the middle and lower ionosphere are discussed. Rawer's (1983) procedure for combining the topside, middle, and lower ionospheric profiles into one analytic profile is reviewed.
    Keywords: GEOPHYSICS
    Type: Journal of Atmospheric and Terrestrial Physics (ISSN 0021-9169); 51; 781-790
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  • 73
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    Publication Date: 2011-08-19
    Description: An observed 0.23 m/year thickening of the Greenland ice sheet indicates a 25 percent to 45 percent excess ice accumulation over the amount required to balance the outward ice flow. The implied global sea-level depletion is 0.2 to 0.4 mm/year, depending on whether the thickening is only recent (5 to 10 years) or longer term (less than 100 years). If there is a similar imbalance in the northern 60 percent of the ice-sheet area, the depletion is 0.35 to 0.7 mm/year. Increasing ice thickness suggests that the precipitation is higher than the long-term average; higher precipitation may be a characteristic of warmer climates in polar regions.
    Keywords: GEOPHYSICS
    Type: Science (ISSN 0036-8075); 246; 1589-159
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  • 74
    Publication Date: 2011-08-19
    Description: Particle Measuring Systems laser particle spectrometer (ASAS-X and FSSP) probes were used to measure aerosol particle concentrations and size distributions during 11 ER-2 flights between Punta Arenas (53 deg S) and Antarctica (up to 72 deg S) from August 17 to September 22, 1987. The time resolution was 10 s, corresponding to a spatial resolution of 2 km. The data were divided into two size classes (0.05-0.25 and 0.53-5.5 micron radius) to separate the small particle from the coarse particle populations. Results show that the small-particle concentrations are typical for a background aerosol during volcanic quiescence. This concentration is generally constant along a flight track; in only one instance a depletion of small particles during a polar stratospheric cloud (PSC) encounter was measured, suggesting a nucleation of type I PSC particles on background aerosols. Temporary increases of the coarse particle concentrations indicated the presence of tenuous polar stratospheric clouds that were encountered most frequently at the southernmost portion of a flight track and when the aircraft descended to lower altitudes. During 'particle events', particle modes were found at 0.6-micron radius, corresponding to type I PSCs, and occasionally, at 2.0-micron radius corresponding to type II PSCs.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 16459-16
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  • 75
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    Publication Date: 2011-08-19
    Description: The Total Ozone Mapping Spectrometer (TOMS), on-board NASA's Nimbus-7 weather satellite, has been observing ozone over the earth once daily for the last 10 yr. A time-lapse atlas of 3440 color-coded images drawn from the TOMS archive from 1978 to 1988 has been visualized on a standard VHS videotape that is now available from NASA. The rapid and complex ozone variations presented demonstrate the difficulty of separating man-induced climate changes from natural variability. This article presents a few images from the atlas and describes interesting features in the animation, such as the correlation between ozone and 'the weather', and the recent deepening of the annual ozone hole over the South Pole. Originally intended as a browsing tool for the TOMS digital database, the videotape is a vivid presentation of the earth's atmospheric dynamics and chemistry that is recommended for scientists, educators, policy makers, and citizens concerned about the global environment.
    Keywords: GEOPHYSICS
    Type: American Meteorological Society, Bulletin (ISSN 0003-0007); 70; 1564-156
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  • 76
    Publication Date: 2011-08-19
    Description: The stratospheric Aerosol and Gas Experiments (SAGE) I and II measure Mie, Rayleigh, and gaseous extinction profiles using the solar occultation technique. These global measurements yield ozone profiles with a vertical resolution of 1 km which have been routinely obtained for the periods from February 1979 to November 1981 (SAGE I) and October 1984 to the present (SAGE II). The long-term periodic behavior of the measured ozone is presented as well as case studies of the observed short-term spatial and temporal variability. A linear regression shows annual, semiannual, and quasi-biennial oscillation features at various altitudes and latitudes which, in general, agree with past work. Also, ozone, aerosol, and water vapor data are described for the Antarctic springtime, showing large variation relative to the vortex. Cross-sections in latitude and altitude and polar plots at various altitudes clearly delineate the ozone hole vertically and areally.
    Keywords: GEOPHYSICS
    Type: Planetary and Space Science (ISSN 0032-0633); 37; 1567-158
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  • 77
    Publication Date: 2011-08-19
    Description: The general behavior of total ozone by season and latitude was known before 1930 through the pioneering observations by Dobson. The ozone record at Oxford and other European stations was dominated by an annual cycle and by irregular short term fluctuations. The amplitude and phase of the annual cycle were determined at representative latitudes in both hemispheres. However, the short term variations appeared to be meteorological origin, although the specific cause could not be identified. Data from the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus 7 spacecraft, with global coverage at an average spatial resolution of 66 km, can now be used to completely map the total ozone field. These maps demonstrate that troughs and ridges in the upper troposphere are responsible for the large, short term ozone variations found at middle latitudes, while in the tropics, the steady, low ozone levels show broad scale structure associated with the Hadley circulation.
    Keywords: GEOPHYSICS
    Type: Planetary and Space Science (ISSN 0032-0633); 37; 1555-156
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  • 78
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    Publication Date: 2011-08-19
    Description: Remote sensing instruments for monitoring global changes are examined. The use of the earth observing system, a set of instrument platforms in polar, sun-synchoronous orbit that provide coverage of the entire globe, is discussed. The radar and imaging spectrometers utilized to obtain surface measurements are described. Atmospheric data is collected by the atmospheric IR sounder, the tropospheric emission spectrometer, and the stratospheric wind IR limb sounder. Consideration is given to the operation of the microwave limb sounder, the active cavity radiometer, and the TDRSS.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Signal (ISSN 0049-0474)
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  • 79
    Publication Date: 2011-08-19
    Description: Measurements of ice-sheet elevation change by satellite altimetry show that the Greenland surface elevation south of 72 deg north latitude is increasing. The vertical velocity of the surface is 0.20 + or - 0.06 meters/year from measured changes in surface elevations at 5906 intersections between Geosat paths in 1985 and Seasat in 1978, and 0.28 + or - 0.02 meters/year from 256,694 intersections of Geosat paths during a 548-day period of 1985 to 1986.
    Keywords: GEOPHYSICS
    Type: Science (ISSN 0036-8075); 246; 1587-158
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  • 80
    Publication Date: 2011-08-19
    Description: Multispectral imaging systems provide much of the basic data used by the land and ocean civilian remote-sensing community. There are numerous multispectral imaging systems which have been and are being developed. A common way to compare the radiometric performance of these systems is to examine their noise-equivalent change in reflectance, NE Delta-rho. The NE Delta-rho of a system is the reflectance difference that is equal to the noise in the recorded signal. A comparison is made of the noise equivalent change in reflectance of seven different multispectral imaging systems (AVHRR, AVIRIS, ETM, HIRIS, MODIS-N, SPOT-1, HRV, and TM) for a set of three atmospheric conditions (continental aerosol with 23-km visibility, continental aerosol with 5-km visibility, and a Rayleigh atmosphere), five values of ground reflectance (0.01, 0.10, 0.25, 0.50, and 1.00), a nadir viewing angle, and a solar zenith angle of 45 deg.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 81
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    Publication Date: 2011-08-19
    Description: Analysis of SAR data of the Greenland ice sheet in summer and winter suggest the use of SAR to monitor the temporal hydrology of ice sheets. Comparisons of each SAR data set with summer Landsat TM imagery show an areal-positive correlation with summer SAR data and a negative correlation with winter SAR data. It is proposed that the summer SAR data are most sensitive to the variable concentrations of free water in the surface snow and that the winter SAR data indicate variations in snow grain size.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 82
    Publication Date: 2011-08-19
    Description: The NASA Ames Ecosystem Science and Technology Branch and the U.S. Army Medical Research Institute of Infectious Diseases are conducting research to detect Rift Valley fever (RVF) vector habitats in eastern Africa using active and passive remote-sensing. The normalized difference vegetation index (NDVI) calculated from Landsat TM and SPOT data is used to characterize the vegetation common to the Aedes mosquito. Relationships have been found between the highest NDVI and the 'dambo' habitat areas near Riuru, Kenya on both wet and dry data. High NDVI values, when combined with the vegetation classifications, are clearly related to the areas of vector habitats. SAR data have been proposed for use during the rainy season when optical systems are of minimal use and the short frequency and duration of the optimum RVF mosquito habitat conditions necessitate rapid evaluation of the vegetation/moisture conditions; only then can disease potential be stemmed and eradication efforts initiated.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 83
    Publication Date: 2011-08-19
    Description: The possibility of using detailed spatial soil moisture maps as input to a runoff model was investigated. The water balance of a small drainage basin was simulated using a simple storage model. Aircraft microwave measurements of soil moisture were used to construct two-dimensional maps of the spatial distribution of the soil moisture. Data from overflights on different dates provided the temporal changes resulting from soil drainage and evapotranspiration. The study site and data collection are described, and the soil measurement data are given. The model selection is discussed, and the simulation results are summarized. It is concluded that a time series of soil moisture is a valuable new type of data for verifying model performance and for updating and correcting simulated streamflow.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 84
    Publication Date: 2011-08-19
    Description: Multiwavelength, multipolarization radar image data can be processed to allow the clear depiction of most information in color composite displays. The first principal component, depicted as variations in image intensity, captures the dominant variation in the data and reduces noise without degradation of spatial detail. Other principal components, depicted primarily as variations in image chromaticity, are derived from spatially filtered data so that image colors can be attributed to significant wavelength and polarization contrasts, and not to speckle. Processing paths can be designed to emphasize wavelength contrasts, polarization contrasts, or overall discrimination of surface features.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 85
    Publication Date: 2011-08-19
    Description: An analysis is made of time-dependent covariance of the greenness vegetation index with mapped terrain variables over the Konza Prarie (Kansas) during the 1987 growing season. The analysis was part of an ongoing project to establish appopriate ground-sampling and data-integration strategies for satellite-based monitoring of land surface climate conditions. Greenness images for six dates between May and October were derived from atmospherically corrected thematic mapper (TM) data and coregistered with maps of woody vegetation, fire, and soils. Local variance in greenness peaked in mid-June, falling rapidly until mid-August, and declining gradually thereafter. Greenness images exhibited positive autocorrelation up to distances of 180-210 m, but the dominant scale of pattern occurred at a block size of 60 m by 60 m throughout the growing season. 40-44 percent of total scene variance in July and August was accounted for by the effects of woody vegetation (8.9 percent of the area), prairie burning, and soil type. The effect of these terrain variables was fairly consistent between June and late August and was manifested as additional high-frequency spatial variation in imagery from that period.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 86
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    Publication Date: 2011-08-19
    Description: The Alaska SAR (synthetic-aperture radar) Facility (ASF) will be capable of receiving, processing, archiving, and producing a variety of SAR image products from three satellite-borne SARs: E-ERS-1 (ESA), J-ERS-1 (NASDA) and Radarsat (Canada). Crucial to the success of the ASF is the Alaska SAR processor (ASP), which will be capable of processing over 200 100-km x 100-km (Seasat-like) frames per day from the raw SAR data, at a ground resolution of about 30 m x 30 m. The processed imagery is of high geometric and radiometric accuracy, and is geolocated to within 500 m. Special-purpose hardware has been designed to execute a SAR processing algorithm to achieve this performance. This hardware is currently undergoing acceptance testing for delivery to the University of Alaska. Particular attention has been devoted to making the operations semi-automated and to providing a friendly operator interface via a computer workstation. The operations and control of the Alaska SAR processor are described.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 87
    Publication Date: 2011-08-19
    Description: The problem of estimating areal averages from point measurement has been extensively studied by mining engineers and hydrologists. Its application to satellite measurements has recently been introduced. The semivariaogram has been used in many geostatistical applications to estimate spatial structures of observed properties, such as mineral distributions. An examination is made of snow variations in Colorado from daily snow data collected in 11 SNOTEL stations. The associated semivariogram is estimated. The objective is to estimate the spatial structure of the snow field so that the point data can be used for comparison with, and validation for, satellite measurements.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 88
    Publication Date: 2011-08-19
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 89
    Publication Date: 2011-08-19
    Description: Spaceborne observations have become increasingly accepted for studies of the hydrological cycle and as a source of information that can be used for management and assessment of water resources over large areas. As data records are extended over long periods of time, using sensors that improve their reliability and quality, the utility of spaceborne observations will become increasingly evident. The Earth Observing System (EOS) concept being studied by NASA holds potential for providing improved means and procedures for hydrological studies, particularly on a global basis, using spaceborne sensors and a comprehensive information system. Continuing emphasis needs to be placed on research exploring the interpretation of remotely sensed observations through the assimilation and use of these data in models of hydrological processes.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 90
    Publication Date: 2011-08-19
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 91
    Publication Date: 2011-08-19
    Description: A study undertaken to determine SIR-C (Shuttle Imaging Radar-C) science requirements for polarimetric calibration is described. A model describing the effect of miscalibration is presented, followed by a description of specific experiments and the resulting requirements levied on the system. The effects of miscalibration on some commonly used measures which can be extracted from SAR (synthetic aperture radar) data are also discussed. It is concluded that polarimetric calibration requirements are strongly application-dependent, and that a compromise must be made to maximize the domain of application of the data without prohibitive cost. Data summarizing SIR-C polarimetric calibration goals are also presented.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
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  • 92
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    Publication Date: 2011-08-19
    Description: Regression and ratio estimators are used to integrate AVHRR-Global Area Coverage (GAC) and Landsat MSS digital data to estimate forest area in the continental United States. Forestlands are enumerated for the 48 contiguous states using five different AVHRR-GAC data sets. Results indicated that the GAC and MSS forest estimates were not highly correlated. Although the ratio of means and linear regression corrections were, on the average, closer to national U.S. Forest Service forest area estimates, these correction procedures did not consistently improve GAC estimates of forest area. GAC forest area estimates tended to be high in densely forested regions such as the northeast and low in sparsely forested areas.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 201-216
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  • 93
    Publication Date: 2011-08-19
    Description: Consideration is given to the possibility of using Landsat TM data to detect differences and changes in the leaf area index (LAI) of closed canopy pine plantations in central Massachusetts. Field measurements of the LAI were obtained using locally-derived allometric relationships between leaf area and trunk diameter. The relationship between the Landsat TM Band 3/Band 4 ratio and regional differences in LAI is examined. A thinning treatment was conducted to demonstrate the ability of TM to detect a known reduction in LAI. It is concluded that, for the detection of moderate changes and differences in the LAI of closed canopy pine plantations at local scales, the TM sensor is better than field measurements involving allometric equations.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 129-140
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  • 94
    Publication Date: 2011-08-19
    Description: Results are presented from field experiments relating spectral reflectance to intercepted photosynthetically active radiation (PAR) and net CO2 exchange in a natural canopy composed of the marsh cordgrass (Spartina alterniflora). Reflectance measurements made by a hand-held radiometer with Landsat TM spectral wavebands are used to compute remote sensing indices such as the normalized difference vegetation index. Consideration is given to the impact of standing dead canopy material on the relationship between intercepted PAR and spectral vegetation indices and the impact of changes in photosynthetic efficiency on the relationship between vegetation indices and CO2 exchange rates. The results suggest that quantitative remote assessment of photosynthesis and net gas exchange in natural vegetation is feasible, especially if the analysis incorporates information on biological responses to environmental variables.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 115-128
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  • 95
    Publication Date: 2011-08-19
    Description: A method to detect plant water stress by remote sensing is proposed using indices of near-IR and mid-IR wavelengths. The ability of the Leaf Water Content Index (LWCI) to determine leaf relative water content (RWC) is tested on species with different leaf morphologies. The way in which the Misture Stress Index (MSI) varies with RWC is studied. On test with several species, it is found that LWCI is equal to RWC, although the reflectances at 1.6 microns for two different RWC must be known to accurately predict unknown RWC. A linear correlation is found between MSI and RWC with each species having a different regression equation. Also, MSI is correlated with log sub 10 Equivalent Water Thickness (EWT) with data for all species falling on the same regression line. It is found that the minimum significant change of RWC that could be detected by appying the linear regression equation of MSI to EWT is 52 percent. Because the natural RWC variation from water stress is about 20 percent for most species, it is concluded that the near-IR and mid-IR reflectances cannot be used to remotely sense water stress.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: Remote Sensing of Environment (ISSN 0034-4257); 30; 43-54
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  • 96
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    Publication Date: 2011-08-19
    Description: Derivation of statistically significant size distributions from impactor samples of rarefield stratospheric aerosols imposes difficult sampling constraints on collector design. It is shown that it is necessary to design impactors of different size for each range of aerosol size collected so as to obtain acceptable levels of uncertainty with a reasonable amount of data reduction.
    Keywords: GEOPHYSICS
    Type: Aerosol Science and Technology (ISSN 0278-6826); 11; 65-79
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  • 97
    Publication Date: 2011-08-19
    Description: A new Michelson-type interferometer system operating in the infrared at very high resolution has been used to record numerous balloon-borne solar absorption spectra of the stratosphere, ground-based solar absorption spectra, and laboratory spectra of molecules of atmospheric interest. In the present work results obtained for several important stratospheric trace gases, HNO3, CIONO2, HO2NO2, NO2, and COF2, in the 8- to 12-micron spectral region are reported. Many new features of these gases have been identified in the stratospheric spectra. Comparison of the new spectra with line-by-line simulations shows that previous spectral line parameters are often inadequate and that new analysis of high-resolution laboratory and atmospheric spectra and improved theoretical calculations will be required for many bands. Preliminary versions of several sets of improved line parameters under development are discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 14945-14
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  • 98
    Publication Date: 2011-08-19
    Description: Hydrogen isotope analyses were used to determine water content and deuterium content for 18 samples of the Mount St Helens dome dacite in an attempt to identify the triggering mechanisms for periodic dome-building eruptions of lava. These isotope data, the first ever collected from an active lava dome, suggest a steady-state process of magma evolution combining crystallization-induced volatile production in the chamber with three different degassing mechanisms: closed-system volatile loss in the magma chamber, open-system volatile release during ascent, and kinetically controlled degassing upon eruption at the surface. The data suggest the future dome-building eruptions may require a new influx of volatile-rich magma into the chamber.
    Keywords: GEOPHYSICS
    Type: Nature (ISSN 0028-0836); 341; 521-523
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  • 99
    Publication Date: 2011-08-19
    Description: This paper describes the Earth Radiation Budget Experiment (ERBE) data products being made available to the community. The Science Team used ten validation criteria to judge the acceptability of the data for archival. These criteria are listed, and uncertainty estimates based on them for four typical data products are presented. A brief description of the radiation budget for April 1985 from the combined data of ERBE and NOAA-9 concludes this paper.
    Keywords: GEOPHYSICS
    Type: American Meteorological Society, Bulletin (ISSN 0003-0007); 70; 1254-126
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  • 100
    Publication Date: 2011-08-19
    Description: From December 1986 until April 1987 ground-based microwave observations of the diurnal variation of mesospheric ozone were made over Bern, Switzerland. These data were of sufficient quality to define the characteristics diurnal behavior of the ozone mixing ratio during winter and equinoctial conditions. The observed diurnal variation of ozone peaks at about 74 km, where its amplitude is about a factor of 6. At 65 km the observed diurnal variation is a factor of 3, whereas at 55 km it is only a factor of 1.4. One-dimensional model calculations accurately reproduce the relative diurnal variation of ozone at equinox, suggesting that the model value of the ozone photolysis rate coefficient is accurate to better that 10 percent. For winter conditions, however, the model underpredicts the observed relative diurnal variation by a factor of 2; a major part of this discrepancy is due to an observed postmidnight increase in ozone. Various suggested changes in model parameters to better produce the ozone abundance vertical profile result in only small differences in the relative diurnal variation, indicating that these observations do not provide a sensitive test of the mesospheric chemistry controlling the abundance of odd oxygen.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 94; 12819-12
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