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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 433 (2005), S. 728-731 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Silicon has a crucial role in many biogeochemical processes—for example, as a nutrient for marine and terrestrial biota, in buffering soil acidification and in the regulation of atmospheric carbon dioxide. Traditionally, silica fluxes to soil solutions and stream waters are thought to be ...
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Regional and global environmental modeling depend on soil data for input layers or parameterization. However, randomly located observations, such as provided by agricultural databases, are not always representative of trends identified in field studies conducted under carefully controlled conditions. Many researchers lament the paucity of soil profile data in Amazônia, and suggest that given more data, regional studies would more closely approximate field research results. We assess the ability of a well-populated regional database collected in the southwestern Brazilian Amazon to reproduce expected biogeochemical trends associated with forest clearing and pasture establishment, and explore the ramifications of relying on independently collected soil data for regional modeling. The Soteron database includes analyses of approximately 3000 soil cores collected for zoning purposes in the state of Rondônia. Pasture ages were determined from a time series of Landsat TM images classified using spectral mixture analysis.Although regional averages showed some of the temporal trends expected based on field study results (e.g. increase in pH following forest clearing), the trends were not statistically significant. Stratification by precipitation and other variables showed pasture age to be important but difficult to separate from other potential controls on soil conditions, mainly because of the reduced number of observations in each stratum. Using multiple regression, which permitted the inclusion of all potential explanatory factors and interactions, pasture age was shown to be a statistically significant predictor of soil conditions. However, the expected temporal sequence of changes documented by field chronosequence studies could not be reproduced. Properties dominated by large-scale environmental gradients – pH, sum of base cations, aluminum saturation, and exchangeable calcium – were moderately well modeled, while those more strongly linked to dynamic spatially heterogeneous processes such as biological cycling and land management, particularly organic carbon and nitrogen, could not be modeled.Management-induced soil changes occur at too fine a scale to be captured by most maps, and the relative changes are small compared with spatial heterogeneity caused by controls on soil development over large regions. Therefore, regardless of whether chronosequence-derived models of biogeochemical response to land-cover change are correct, the results of these models will not lead to spatially explicit maps that can be validated by regional reconnaissance, nor will they facilitate realistic predictions of the regional biogeochemical consequences of land-cover change. The change from local to regional scale entails a change in the relative importance of processes controlling soil property behavior.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1435-0629
    Keywords: Key words: chronosequence; soil development; climate history; erosion; subsidence; Hawaii; ecosystem development; slow processes.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We evaluated changes in temperature and precipitation associated with climate change, subsidence, and erosion on a chronosequence of sites across Hawaii. The sites range in age from 0.3 to 4100 ky, and the current temperature and precipitation are similar at all sites. Interpretations of fossil pollen records suggest that cooler, dryer conditions prevailed in windward Hawaii during the last glacial period. If the previous glacial periods were similar, the 20-, 150-, and 1400-ky-old sites would have spent 60% or more of their development under relatively cool and dry conditions, whereas the 0.3- and 2.1-ky-old sites have experienced only the warmer, wetter climate of the present interglacial. Subsidence and erosion have also affected the temperature and precipitation of these sites over time; in the past, some of them have been in the dry air above the trade wind inversion or in the lee of larger mountains. Combining these components of change, we estimate that the average temperature over the history of Pleistocene-aged sites (20, 150, and 1400 ky) was up to 2.2°C cooler and that the average precipitation was only about 50% of current values. Under current conditions, it would take only 230 ky for as much water to leach through the 1400-ky-old site as we calculate has leached over 1400 ky. Incorporating more reasonable assumptions about environmental history has the potential to allow more powerful interpretations of chronosequence data and thereby improve the predictive potential of models of soil and ecosystem development.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Soil Science Society of America journal 63 (1999), S. 169-177 
    ISSN: 1435-0661
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: + selectivity and (ii) structural charge as affected by pedogenic mineral transformations in an age sequence of Hawaiian soils. The Cs+→ Li+ exchange experiments were conducted on soils collected from six sites [basaltic parent material deposited 0.3, 20, 150, 400, 1400 and 4100 thousands of years (ky) ago.] Identical exchange experiments were performed with kaolinite, montmorillonite, and illite for comparison. Selectivity for Cs+ on soils and clays increased with adsorbed mole fraction of Cs+ . Cesium-accessible structural charge of the surface soils increased initially with soil age from 20 mmolc kg-1 at the 0.3 ky site to 113 mmolc kg-1 at the 400-ky site. Increased weathering beyond 400 ky reduced structural charge to 21 mmolc kg-1 for the oldest site. The magnitude of Cs retention in the soils is correlated with the presence of 2∝1 layer-type silicates detected by x-ray diffraction (XRD) after removal of poorly crystalline constituents. The results indicate a modest accumulation of secondary 2∝1 layer-type silicates (with larger accumulations of poorly crystalline clays), followed by their subsequent declines, during the course of soil weathering.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillan Magazines Ltd.
    Nature 389 (1997), S. 170-173 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] A large source of uncertainty in present understanding of the global carbon cycle is the distribution and dynamics of the soil organic carbon reservoir. Most of the organic carbon in soils is degraded to inorganic forms slowly, on timescales from centuries to millennia. Soil minerals are known ...
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  • 6
    ISSN: 1432-1939
    Keywords: Key words Atmospheric inputs ; Ecosystem development ; Hawaii ; Metrosideros polymorpha ; Rock weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We used isotopes of Sr to quantify weathering versus atmospheric sources of foliar Sr in 34 Hawaiian forests on young volcanic soils. The forests varied widely in climate, and in lava flow age and texture. Weathering supplied most of the Sr in most of the sites, but atmospheric deposition contributed 30–50% of foliar Sr in the wettest rainforests. A stepwise multiple regression using annual precipitation, distance from the ocean, and texture of the underlying lava explained 76% of the variation in Sr isotope ratios across the sites. Substrate age did not contribute significantly to variation in Sr isotope ratios in the range of ages evaluated here (11–3000 years), although atmospheric sources eventually dominate pools of biologically available Sr in Hawaiian rainforests in older substrates (≥150,000 years).
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 24 (1994), S. 115-127 
    ISSN: 1573-515X
    Keywords: carbon sequestration ; landscape geochemistry ; mineral weathering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Carbon is sequestered in soils by accumulation of recalcitrant organic matter and by bicarbonate weathering of silicate minerals. Carbon fixation by ecosystems helps drive weathering processes in soils and that in turn diverts carbon from annual photosynthesis-soil respiration cycling into the long-term geological carbon cycle. To quantify rates of carbon transfer during soil development in moist temperate grassland and desert scrubland ecosystems, we measured organic and inorganic residues derived from the interaction of soil biota and silicate mineral weathering for twenty-two soil profiles in arkosic sediments of differing ages. In moist temperate grasslands, net annual removal of carbon from the atmosphere by organic carbon accumulation and silicate weathering ranges from about 8.5 g m−2 yr−1 for young soils to 0.7 g M−2 yr−1 for old soils. In desert scrublands, net annual carbon removal is about 0.2 g m−2 yr−1 for young soils and 0.01 g m−2 yr−1 for old soils. In soils of both ecosystems, organic carbon accumulation exceeds CO2 removal by weathering, however, as soils age, rates of CO2 consumption by weathering accounts for greater amounts of carbon sequestration, increasing from 2% to 8% in the grassland soils and from 2% to 40% in the scrubland soils. In soils of desert scrublands, carbonate accumulation far outstrips organic carbon accumulation, but about 90% of this mass is derived from aerosolic sources that do not contribute to long-term sequestration of atmospheric carbon dioxide.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 42 (1998), S. 21-53 
    ISSN: 1573-515X
    Keywords: carbon dioxide ; deforestation ; organic carbon ; mineral weathering ; plants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract This paper is centered on the specific effects of plants on the soil weathering environment; we attempt to address how to quantify this component of the ecosystem and assess feedbacks between plants and weathering processes that influence the degree and rates of mineral weathering. The basic processes whereby plants directly influence the soil chemical environment is through the generation of weathering agents, biocycling of cations, and the production of biogenic minerals. Plants may indirectly influence soil processes through the alteration of regional hydrology and local soil hydrologic regime which determines the residence time of water available for weathering. We provide a brief review of the current state of knowledge regarding the effects of plants on mineral weathering and critical knowledge gaps are highlighted. We summarize approaches that may be used to help quantify the effects of plants on soil weathering such as state factor analyses, mass balance approaches, laboratory batch experiments and isotopic techniques. We assess the changes in the soil chemical environment along a tropical bioclimatic gradient and identify the possible effects of plant production on the soil mineralogical composition. We demonstrate that plants are important in the transfer of atmospheric carbon dioxide into the mineral weathering cycle and speculate how this may be related to ecosystem properties such as NPP. In the soils of Hawaiian rainforests subjected to deforestation, pasture grasses appear to change the proportion of non crystalline to crystalline minerals by altering the soil hydrologic regime or partitioning silica into more stable biogenic forms. A better understanding of the relationship between soil weathering processes and ecosystem productivity will assist in the construction predictive models capable of evaluating the sensitivity of biogeochemical cycles to perturbations.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 2015-01-05
    Description: Many researchers believe that prehistoric Rapa Nui society collapsed because of centuries of unchecked population growth within a fragile environment. Recently, the notion of societal collapse has been questioned with the suggestion that extreme societal and demographic change occurred only after European contact in AD 1722. Establishing the veracity of demographic dynamics has been hindered by the lack of empirical evidence and the inability to establish a precise chronological framework. We use chronometric dates from hydrated obsidian artifacts recovered from habitation sites in regional study areas to evaluate regional land-use within Rapa Nui. The analysis suggests region-specific dynamics including precontact land use decline in some near-coastal and upland areas and postcontact increases and subsequent declines in other coastal locations. These temporal land-use patterns correlate with rainfall variation and soil quality, with poorer environmental locations declining earlier. This analysis confirms that the intensity of land use decreased substantially in some areas of the island before European contact.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 10
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