ALBERT

Notes: An exact expression is derived for the optimal spacing between interfering wells in a rectangular well field in an ideal confined aquifer. A simple, practical method for determining the optimal spacing is presented. The optimal spacing is shown to be substantially different from the spacing determined by use of the Theis formulation. The economic savings resulting from use of the revised approach are evaluated and found to be considerable, especially when the number of wells is large and the transmissivity of the aquifer low.

Notes: Abstract. A hydrologic test system has been designed to measure the intrinsic permeabilities of individual fractures in crystalline rock. This report contains the design schematics and specifications necessary to build and/or modify this test system for other similar field applications. This system is used to conduct constant pressure/declining flow rate and pressure pulse hydraulic tests. The system is composed of four distinct units: (1) The Packer System, (2) Injection System, (3) Collection System, and (4) Electronic Data Acquisition System. The apparatus is built in modules so it can be easily transported and reassembled. It is also designed to operate over a wide range of pressures (0–300 psig) and flow rates (0.2–1.0 gal/min). This system has proved extremely effective and versatile in its use at the Climax Facility, Nevada Test Site.

Notes: Field and laboratory analyses of pH, alkalinity, and specific conductance from water samples collected from the Columbia aquifer on the Delmarva Peninsula in eastern Maryland were compared to determine if laboratory analyses could be used for making regional water-quality interpretations.On the basis of 170 field pH and specific conductance measurements, 165 laboratory pH and specific conductance measurements, and 86 field and 135 laboratory alkalinity measurements, a significant difference at the 0.1-percent level was found between laboratory and field analyses of pH and specific conductance. No significant difference was found between laboratory and field analyses of alkalinity. In most samples, laboratory pH was greater than field pH, laboratory specific conductance was less than field specific conductance, and laboratory alkalinity was equally likely to be less than, the same as, or greater than field alkalinity.Kruskal-Wallis tests of field and laboratory data grouped by north-south and east-west coordinates and by land use indicate that the difference between field and laboratory values is usually not enough to affect the outcome of the statistical tests. Thus, laboratory measurements of these constituents may be adequate for making certain regional water-quality interpretations, although they may result in errors if used for geochemical interpretations.

Notes: Preliminary vadose zone nitrate extraction experiments have revealed the extractant (2N KCl) volume affects the determination of nitrate and its nitrogen isotope ratio.In five cores, extractable NO3-N concentrations increased an average of 1.7 times after the soil-to-extractant ratio was increased from 1:1 to 1:10. An increased extractant volume resulted in a large positive shift of stable nitrogen values (δ15N), which averaged +6.2%.An underestimation of available NO3-N for leaching and transport through the vadose zone and a biased source interpretation from the δ15N values probably would occur if a procedure which leads to incomplete extraction of nitrate is used.

Notes: Currently, one of the most popular methods of containing contaminated ground water is through use of subsurface impermeable barriers. These barriers can take one of three forms: slurry walls, grout curtains, or steel sheet piles. Successful operation of these barrier systems is dependent upon three basic criteria. First, the barrier must be truly impermeable and remain so over time even upon exposure to the contaminated ground water. Second, there must exist an underlying impermeable formation, at a reasonable depth, to which the barrier can be connected. Third, an adequate connection between the barrier and the underlying formation must be assured.This paper presents the results of the analysis of the movement of contaminated ground water under or through an imperfect barrier. The first phase of the analysis consists of the development of an analytical solution for the flow of ground water under a barrier and a simple numerical integration technique for developing concentration breakthrough curves. This simple solution algorithm was applied to the cases of variable recharge rates and lengths, variable depths of penetration of the barrier, and anisotropic soils. The second phase of the analysis involves applying a numerical solute transport model to analyze the performance of a barrier with and without the effects of hydrodynamic dispersion, and in the presence of a layered soil, and finally the performance of a fully penetrating but partially permeable barrier.

Notes: Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other.The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents.A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system.The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers.Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator.Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.

Notes: A total of four vertical electrical soundings were conducted in a layered andesitic rock aquifer known in places to yield ground water with total dissolved solids (TDS) in excess of 2,000 milligrams per liter (mg/L). The objective of the soundings was to locate zones of moderate to high permeability but with acceptable chemical quality.The resistivity of a geologic unit is a function that includes the quantity of total dissolved solids in the interstitial water and the distribution of the water within the unit. Thus, the resistivity of most granular soils and rocks is controlled more by porosity, water content and water quality than by the conductivity of the matrix materials.The electrical data delimited a drill site where it was believed that ground water of acceptable chemical quality could be expected. Completion and test pumping of two exploration wells confirmed the electrical sounding results.The first test well drilled prior to the survey yielded only small amounts of ground water with total dissolved solids in excess of 2,000 mg/L. The second exploration well drilled at the site as a result of the electrical study yielded in excess of 100 gallons per minute of ground water with total dissolved solids of 830 mg/L.

Notes: An advanced two-way radio link (transceiver units) and data logging system have provided a powerful means of real-time series data collection and analysis. The application of this telemetry system to surface tiltmeter surveys provides significant cost savings for testing and analysis of deep, large-scale horizontal anisotropic permeability and heterogeneity determinations.The determination of horizontal anisotropic properties requires one pumping well and eight to 10 tiltmeter monitoring stations. The validity of the depth of the test may reach 4,000 feet below land surface. With the addition of one partially penetrating observation well, the entire three-dimensional anisotropic permeability can be determined. With the addition of a fully penetrating well, the storage coefficient can be determined as well as leakage property (including vertical permeability of the confining layers). An example test case was analyzed for horizontal anisotropic permeability with remarkable success despite relatively unfavorable detection conditions.A thorough understanding of the geology overlying the aquifer system must be made in order to assess the applicability of the surface tiltmeter survey to large-scale horizontal anisotropic permeability determinations.

Notes: This paper describes a new system for ground water monitoring, “the BAT System,” which includes the following functions: (a) sampling of ground water in most types of soils, (b) measurement of pore water pressure, and (c) in situ measurement of hydraulic conductivity. The system can also be used for tracer tests. The system utilizes a permanently installed filter tip attached to a steel or PVC pipe. Installation is normally performed by pushing the tip down to the desired depth. The filter tip can also be buried beneath a landfill. The primary feature of the new system is that the filter tip contains a self-sealing quick coupling unit, which makes it possible to temporarily connect the filter tip to adapters for various functions, e.g. water sampling and for measurement of pore pressure and hydraulic conductivity. The new technique makes sampling of both pressurized water and gas possible. Samples are obtained directly in hermetically sealed, pre-sterilized sample cylinders. Sampling of ground water and measurement of pore pressure can be repeated over a long period of time with undiminished accuracy. This technique is also well-adapted for taking water samples from different strata in a soil profile, in both the saturated and unsaturated zones. Actual installations range from 0.5 to 60m depth.

Notes: State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.

Notes: Transmissivity can be estimated by several well documented methods employing data from rising water level slug tests in wells. A very simple and relatively inexpensive system can be constructed to lower the water level in a well. Compressed air is injected through a sealed device called a well head manifold, which screws onto the casing top and contains an air pressure gauge, an air entry valve, a quick release valve and a multi-channel water level indicator or a pressure transducer. Either of the latter is lowered into the well prior to pressurization.Compressed air is injected into the casing at a low rate through the manifold, depressing the water level a desired amount. After stabilization, the quick release valve is opened and the air pressure inside the casing is reduced to atmospheric pressure instantaneously; the water level then starts to rise. Successive elevations of the rising water level are determined with the indicator or transducer and their elapsed times from valve opening are recorded. Plots of water level recovery vs. time can then be used to estimate transmissivity by the published methods of Cooper, Bredehoeft and Papadopulos (1967), Ferris and Knowles (1954) and Hvorslev(1951).All of the items used for construction, with the exception of the quick release valve, can be bought off the shelf. The valve can be easily constructed in a machine shop. The total cost of the device, exclusive of the transducer, should be less than $500.

Notes: Ground water flow in karst terranes generally occurs in the solution channels of carbonate aquifers. A hydrogeologist may utilize borehole geophysical methods to identify these solution channels in aquifers. Two specific methods that are applicable in karst terrains are:1. Natural gamma ray logging2. Borehole caliper logging.Gamma ray logging can detect the presence of inter-bedded strata in the main limestone unit, such as shale, which emit high levels of gamma radiation. Gamma ray logging can also detect clay deposits in solution channels that may act to restrict the flow of ground water. The areal extent of these rock strata or clay-filled solution channels can be determined when gamma ray logs are conducted at several borehole locations across the site of investigation.Borehole caliper logging can be employed to determine the presences of solution channels within the aquifer when penetrated by a borehole. In addition, since shale layers and clay filling are less resistant than the surrounding limestone, the caliper log may detect both the presence and the thickness of shale or clay layers in the aquifer.Gamma ray logs can be used in conjunction with caliper logs to provide data on the stratigraphic location and thickness of solution channels and clay and shale layers within a limestone aquifer. This information is valuable to the hydrogeologist performing investigations at sites located in limestone terranes because ground water flow preferentially occurs along solution channels.

Notes: Column leaching experiments show that fly ash Interlayered with sulfide-rich tailings can reduce the vertical permeability of tailings by at least three orders of magnitude. Chemical reactions between the fluid, alkaline fly ash from Western coal and pyritic tailings result in a one to three order of magnitude reduction in the dissolved metals content of the effluent solution. Metal precipitation, which produces the dissolved metals reduction, is a significant element in the permeability reduction. The combined factors reduce the metals flux from the tailings by four to six orders of magnitude. We believe that tailings ponds with fly ash layers as amendments can greatiy reduce ground water contamination from pyritic tailings. In addition, concentrated application of fly ash layers near the end of mining should act to restrict infiltration and access of oxygen, thereby enhancing reclamation. Similar results maybe obtainable using other amendments with lower base capacity (lime, crushed limestone, trona).

Notes: This article describes a computer automated, hydrologic analysis system designed to allow the collection of high quality, long-term pumping test data. The instrument solves two of the major problems encountered in the field during aquifer tests: insufficient data, particularly during the early part of a test when drawdown is rapid; and high labor costs associated with long-term monitoring.To illustrate the system's application, results are presented from the test of a highly transmissive aquifer. The aquifer's drawdown response was rapid; thus the time-drawdown curve was essentially flat after the first two minutes of the test, and correspondingly rapid data acquisition was essential for a unique solution of the aquifer's three-dimensional hydraulic conductivities.

Notes: Traditional monitoring methods using chemical analysis of ground water samples to detect pollutant migration are being superseded or used in conjunction with innovative approaches. A need to detect pollutants before they reach the water table has drawn interest to vadose (unsaturated) zone monitoring and brought together hydrogeologists, soil scientists and agricultural engineers who have been working on this subject for years.Recent studies have identified over 50 different types of vadose zone monitoring devices and methods that have optimum utility in varying hydrogeologic settings. In general, measurements made in the vadose zone are trying to define storage, transmission of liquid waste in terms of flux and velocity, and pollutant mobility.Criteria for the selection of alternative vadose zone monitoring methods are important for the development of site-specific systems. These criteria include: type of site; applicability to new, active, and abandoned sites; power requirements; depth limitations; multiple use capability; type of data collection system; reliability and life expectancy; degree of operational complexity; direct versus indirect methods; applicability to alternate media; effect on flow regime; and effect of hazardous waste on sampling or measurements. Application of the selection criteria is discussed in Everett et al. (1982a).

Notes: In recent years we have seen major advances in the variety and quality of ground water sampling instrumentation, in almost every case involving increases in sensitivity of one or more orders of magnitude. Software number-crunching ability brings us the capability of running sophisticated mathematical and statistical programs, while modern analytical chemistry routinely makes determinations of metals, organics and radioactive elements accurate in the parts per billion range.The construction of sample points rarely supports these levels of precision. The well is the basic sampling machine for the ground water industry and its ability to produce a truly representative sample underpins all data and conclusions. Regardless of the type of instrumentation employed, a sample point that cannot be shown to be truly representative and that fails to provide a series of reliable samples over the long term–let us say 25 years minimum–is a negative investment.In the authors’professional sampling work, it has been observed that, wherever it is possible to improve the quality of the ground water sample point, a reduction in the measured level of pollutant elements in the sample is found and the confidence level improves. Volatile organic values are the sole exception to this observed reduction in concentration, the reason being that sample point and method improvements capture the fully representative water sample, thus reducing volatile losses.It is not possible to address all hydrogeologic environments and sampling methods in this review. Instead, features were selected that had been found to be important in commercial, high-precision, water quality sampling in Western U.S. environments. In this area, water movement is slow and little or no exchange of water occurs between wells and the surrounding aquifer without artificial stimulation. Water quality stabilization requires multiple casing volume evacuations in wells ranging to 1,000 feet deep. High-volume pumping or mechanized bailing is an economic requirement. Dedicated installations cannot supply the volume of water required for comprehensive analytical programs.It is the nature of these sources, as well as practical recommendations for corrective action, that will be addressed in this article.Any attempted improvement in utilization of data by mathematical processing or statistical treatment will be inadequate because:〈list xml:id="l1" style="custom"〉• Samplings are infrequent and often accumulate at rates of only two or four sample suites per year. Seasonal variations may obscure evidence of passage of a low-intensity pollution front and some years may elapse before the true situation becomes apparent from statistical analyses. By such time, the problem pollutant may have escaped from the treatment area.• Powerful biases occur due to the failure of the sample point to eliminate false contributions to the sample from sources other than the natural environment or a pollution source, most frequently originating in casing materials and annular seal leakage.

Notes: A cancer risk assessment methodology based upon the Armitage–Doll multistage model of cancer is applied to animal bioassay data. The method utilizes the exact time-dependent dose pattern used in a bioassay rather than some single measure of dose such as average dose rate or cumulative dose. The methodology can be used to predict risks from arbitrary exposure patterns including, for example, intermittent exposure and short-term exposure occurring at an arbitrary age. The methodology is illustrated by applying it to a National Cancer Institute bioassay of ethylene dibromide in which dose rates were modified several times during the course of the experiment.

Notes: Several recent nuclear power plant probabilistic risk assessments (PRAs) have utilized broadened Reactor Safety Study (RSS) component failure rate population variability curves to compensate for such things as expert “overvaluation bias” in the estimates upon which the curves are based.A simple two-components of variation empirical Bayes model is proposed for use in estimating the between-expert variability curve in the presence of such biases. Under certain conditions this curve is a population variability curve. Comparisons are made with the existing method.The popular procedure appears to be generally much more conservative than the empirical Bayes method in removing such biases. In one case the broadened curve based on the popular method is more than two orders of magnitude broader than the empirical Bayes curve. In another case it is found that the maximum justifiable degree of broadening of the RSS curve is to increase α from 5% to 12%, which is significantly less than the 20% value recommended in the popular approach.

Notes: A study of driver behavior before and after a mandatory seat belt use law in Newfoundland found that the benefits of such legislation are not reduced by riskier driving, as has been suggested by some theorists. On average, belt use in Newfoundland increased from 16% of drivers before the law to 77% after the law. At the same time, the quality of driving changed very little when compared to control groups of Nova Scotia drivers, who were not subject to the law and whose belt use rates did not change. In only one situation did Newfoundland drivers differ from the control group in Nova Scotia: after the belt law, drivers in Newfoundland became relatively more cautious (slower) in their speeds on four-lane expressways. These data confirm the results of earlier less controlled studies that also found no changes in driving behavior following nonvoluntary changes in occupant protection. Since the “risk-compensation” hypothesis predicts such changes, it seems to have no merit in explaining changes in fatalities and injuries after occupant protection legislation.

Notes: The benefits and costs of automobile safety policies are compared using a methodology which explicitly quantifies the uncertainties. The policies addressed include both voluntary and compulsory manual belt usage, nondetachable passive (automatic) seat belts, and air bags. Estimates of the effectiveness and usage rates of these alternatives were obtained in the form of subjective probability distributions from eight experts. Their opinions were combined using equal weighting. The direct economic costs of the technologies were also estimated probabilistically. The number of lives saved and the net benefits of the policies were calculated probabilistically for a range of values of lifesaving. Probabilistic computations and sensitivity analysis were performed by the Demos modelling system using Monte Carlo simulation. The results are highly uncertain and quite sensitive to the value of lifesaving. Nevertheless, they imply that repeal of the passive-restraint standard is defensible according to the net-benefit criterion only if a relatively low value is assigned to lifesaving. The degree of uncertainty emphasizes the potential value of demonstration programs to obtain better information.

Notes: This paper examines taxonomies for classifying risks and conflicts about risky technologies. First, we describe six levels of conflict that represent various “ shades of gray” between purely factual and purely value laden conflicts in technology disputes. Subsequently, we survey several recent taxonomies of risks and hazards that were at least partly intended to clarify the nature of the public conflicts about technologies and their risks. After pointing out that non-risk features frequently shape technology debates, we develop a taxonomy of the disputes themselves, based on a collection of 162 cases. Our taxonomy of technological controversies is related to the recent risk taxonomies and to the different levels of conflict. It turns out that the different technological disputes create quite different levels of conflict ranging from mainly factual (consumer products, drugs) to extremely value laden (nuclear power, genetic engineering). Depending on the type of controversy and level of conflict we suggest alternative conflict management strategies.

Notes: Scientists disagree in their risk analyses because they use intuitive judgments to generalize results from the laboratory to circumstances not yet studied. If this assertion is correct, techniques intended to reduce intuitive judgments and increase analytical cognition should reduce scientific dispute. The results of a test case involving allegedly high risk and sharp dispute among scientists are described.

Notes: Probabilistic risk assessment (PRA) is a relatively new tool in the nuclear industry. The Reactor Safety Study started the present trend of conducting PRAs for nuclear power plants when it was published in 1975. Now, nine years later, those in the industry currently using PRA techniques are frequently asked the same question: Why should the nuclear utility industry, with so many accepted analytical tools already available, invest the time and manpower to develop a new technique with so many uncertainties?

Notes: The historical basis and more recent activities and products of probabilistic risk analysis (PRA) in the Atomic Energy Commission and Nuclear Regulatory Commission (NRC) are reviewed. Current NRC program activities and objectives are described. The author's opinions on the best uses of PRA are presented.

Notes: There are many uncertainties in a probabilistic risk analysis (PRA). We identify the different types of uncertainties and describe their implications. We then summarize the uncertainty analyses which have performed in current PRAs and characterize results which have been obtained. We draw conclusions regarding interpretations of uncertainties, areas having largest uncertainties, and needs which exist in uncertainty analysis. We finally characterize the robustness of various utilizations of PRA results.

Notes: Data on the effects of human exposure to carcinogens are limited, so that estimation of the risks of carcinogens must be obtained indirectly. Current risk estimates are generally based on lifetime animal bioassays which are expensive and which take more than two years to complete. We here show how data on acute toxicity can be used to make a preliminary estimate of carcinogenic risk and give an idea of the uncertainty in that risk estimate. The estimates obtained are biased upwards, and so are useful for setting interim standards and determining whether further study is worthwhile. A general scheme which incorporates the use of such estimates is outlined, and it is shown by example how adoption of the procedures suggested could have prevented regulatory hiatus in the past.

Notes: During the period from 1977 to 1984, Pickard, Lowe and Garrick, Inc., had the lead in preparing several full scope probabilistic risk assessments for electric utilities. Five of those studies are discussed from the point of view of advancements and lessons learned. The objective and trend of these studies is toward utilization of the risk models by the plant owners as risk management tools. Advancements that have been made are in presentation and documentation of the PRAs, generation of more understandable plant level information, and improvements in methodology to facilitate technology transfer. Specific areas of advancement are in the treatment of such issues as dependent failures, human interaction, and the uncertainty in the source term. Lessons learned cover a wide spectrum and include the importance of plant specific models for meaningful risk management, the role of external events in risk, the sensitivity of contributors to choice of risk index, and the very important finding that the public risk is extremely small. The future direction of PRA is to establish less dependence on experts for in-plant application. Computerizing the PRAs such that they can be accessed on line and interactively is the key.

Notes: A synopsis is given of research projects on probabilistic systems analysis conducted by the Risk Assessment Program of the Electric Power Research Institute. A brief outline of the value of systems analysis both within PRA and as a stand-alone discipline is used to show how the objectives of the research program are related to industry needs. Research projects and their deliverables are discussed in relation to three objectives: (1) to improve the credibility of the methods and results, (2) to provide computer tools and technology transfer, and (3) to develop use of the methods to improve safety and availability in operation. Recent achievements and future plans are briefly described and an up to date list of relevant EPRI publications is provided.

Notes: Expert judgments expressed as subjective probability distributions provide an appropriate means of incorporating technical uncertainty in some quantitative policy studies. Judgments and distributions obtained from several experts allow one to explore the extent to which the conclusions reached in such a study depend on which expert one talks to. For the case of sulfur air pollution from coal-fired power plants, estimates of sulfur mass balance as a function of plume flight time are shown to vary little across the range of opinions of leading atmospheric scientists while estimates of possible health impacts are shown to vary widely across the range of opinions of leading scientists in air pollution health effects.

Notes: A uranium miner who smokes develops lung cancer: what is the probability that radiation, rather than tobacco, caused it? This paper briefly explains the principles and limits of probability models for which this question makes sense, and then shows how principles of risk accounting can be applied to obtain a solution to the general problem of attributing risk in the presence of joint, possibly interacting, causes. A procedure for calculating each factor's “share” in a jointly caused risk is proposed, and shown to be a generalization of the “probability of causation” concept. Problems of implementation and interpretation for the proposed attribution procedure are discussed, and illustrative error bounds are derived for a simple decision rule, in which probability of causation or attributable risk share calculations are made using aggregate data as a proxy for unknown individual data.

Notes: A large number of PRA studies have been completed for specific plants at specific sites. From these studies, taken individually or collectively, many significant insights have evolved into items important to risk and safety. The content of this paper is primarily based on the material contained in the EPRI funded review of five PRA studies: Big Rock Point, Zion, Limerick, Grand Gulf, and Arkansas Nuclear One. The first three were the utility sponsored studies publicly available at the time of project initiation while the other two were deemed representative of the NRC's RSSMAP and IREP programs respectively. The results of PRA studies are usually expressed in terms of core melt frequencies, radionuclide release frequencies, and frequencies of occurrence of different reactor accident consequences (e.g., early and latent fatalities) depending on the level of PRA. These subjects are prominently addressed in this paper. One of the results of a PRA study is identification of a relatively small number of accident sequences that represent the dominant contributors to core melt. An analysis of the salient features of the dominant accident sequences from eleven PRA's yielded a characterization of accident sequence categories discussed at some length. Impact of external events is discussed very briefly. Next to an explicit quantification of public risk or core melt frequency, the identification of specific safety concerns and the evaluation of possible solutions to implement risk management are probably the best recognized and most widely used applications of PRA. Several illustrative examples are briefly discussed. Human interactions are extremely important contributors to safety and reliability of the plants. A review of PRA studies concluded that it was necessary to account for five types of human interactions; some of which may mitigate while others may exacerbate an accident sequence.

Notes: The dissected till plains physiographic province contains extensive areas of pre-Illinoian drift in Kansas, Nebraska, Iowa, and Missouri. The drift is typically a clay-rich, oxidized, and highly weathered till. In many areas of Missouri, this shallow drift represents the only readily available aquifer suitable for domestic and small agricultural users. There are, however, only few published data on the region's hydrogeology. Water budget analyses indicate that approximately 30% of mean annual rainfall is discharged by stream flow and 70% by evapotranspiration. The shallow drift flow systems are best considered unconfined, steady-state systems. Each watershed corresponds roughly to a local ground-water system. There is, typically, little hydraulic connection between the shallow drift systems and underlying strata. The drift hydraulic conductivity varies from approximately 1011 m/sec (laboratory tests) to 10−6 to 10−7 m/sec (field tests) when permeable sand lenses or joints are intersected. Ground-water discharge is concentrated in the immediate vicinity of stream channels, and recharge is concentrated on nearly horizontal hillslope summits. The ground water is generally potable (averaging 455 mg/1 total dissolved solids), but may be high in iron or polluted locally by organic wastes.

Notes: Hydraulic properties of saturated and unsaturated stony soils were studied on a 3.35 m long column, 1.24 m in diameter, filled with alternating sand and boulder layers. The boulders averaged 6.2 × 15 × 20 cm in size and were laid down on their flat side. Tensiometers and a neutron probe access tube were placed in the column for measuring pressure heads and water contents, respectively. Saturated conditions were obtained by ponding the column. The resulting hydraulic conductivity K was 5.1 m/day. This value could also be calculated from the measured K for the sand alone on separate samples, using a simple equation that takes into account the void ratio of the sand alone and that of the boulder-sand mixture. Unsaturated K was determined by applying water at less than ponded infiltration rates. Resulting relations between the unsaturated K and water content or negative pressure head could also be estimated from the relation between unsaturated K and pressure head for the sand alone and the calculated saturated K of the boulder-sand mixture. The method of Millington and Quirk for calculating the relation between unsaturated K and water content also gave reasonable results. The dispersivity of the boulder-sand column was 18 times that of the sand alone. Pore velocity was accurately estimated as the Darcy velocity divided by the volumetric water content. Hydraulic properties of stony vadose zones are difficult to determine. This work shows that they can be estimated from K relations measured in the laboratory on samples of the soil between the rocks. Knowledge of hydraulic properties of vadose zones is important in predicting movement of water and pollutants to the underlying ground water.

Notes: Three case studies from New Mexico illustrate methods by which aquifers can be classified for purposes of the Federal Underground Injection Control program. The principal technique involves preparation of hydrogeologic maps or cross sections which display information on the permeability of rock units and the dissolved solids content of formation fluids. Because deep water wells are lacking in most areas, the analysis normally requires considerable interpretation of geological and geophysical logs collected by energy and mineral companies, plus use of a general model or concept about regional hydrogeology. Injection of waste fluids into aquifers containing water with less than 10,000 mg/1 dissolved solids is not allowed unless an exemption is justified by economic, engineering and other factors. Based on the case studies, regulatory exemptions will be possible for aquifers which are hydrocarbon or mineral-producing, or which are important for brine disposal purposes.

Notes: A parameter-estimation technique based on existing hydrological, geophysical, and geological data was developed to approximate transmissivity values for use in a ground-water flow model of the Animas Valley, southwest New Mexico. Complete Bouguer gravity anomaly maps together with seismic-refraction profiles, geologic maps, geologic, geophysical, and drillers' logs, water levels, and pumping-test data provide insight into the transmissivity of bolson deposits throughout the basin.The transmissivity distribution was primarily based on reported pumping and specific-capacity tests in conjunction with complete Bouguer gravity anomaly maps and well log data. Reported transmissivity values were characterized by gravity values and well log data. In grid blocks lacking pumping and specific-capacity tests, transmissivity values were assigned based on the relationship of gravity values and well log data within the grid block to gravity values and well log data within other grid blocks for which transmissivity values are available.A two-dimensional, finite-difference, ground-water flow computer code was used to evaluate the effectiveness of the parameter-estimation technique. Although the trial-and-error method of calibration was employed, the actual computer time necessary for model calibration was minimal. The conceptually straightforward approach for parameter estimation utilizing existing hydrological, geophysical, and geological data provides realistic parameter estimates.

Notes: Most of the current simulation models for unconfined aquifers are based on the assumption that the free surface variation is small so that it can be combined with permeability to reduce the nonlinear Boussinesq equation to a linear partial differential equation (PDE). One of the most obvious reasons for using the linearization assumption is for the ease of numerical solution. This work presents a simpler alternative which permits an easy direct solution of the Boussinesq equation. A forward in time, central in space (FTCS) explicit finite difference method is used in the simulation model. The model was first validated by comparing its results with known analytical solution. It was then applied to an actual situation in which the short-term responses (from pumping) of an unconfined aquifer were simulated. The study shows that the stability of the model can be easily controlled, and because of the simple algorithm used, the code can be expeditiously developed and economically run on smaller machines. Due to the uncertainties in the calibration results, it is recommended here that more data be collected to improve the calibration before the model is used as a real-time simulation tool.

Notes: The investigation of the regional flow characteristics of aquifers is important with respect to aquifer management. To determine regional flows, use can be made of hydraulic and hydrochemical data. In a study of a Chalk Aquifer System in the south of Lincolnshire, England, a combined hydrochemical approach using major, minor and isotope chemistry is described. The chemical data have been used because hydraulic information is difficult to interpret both locally and regionally as a consequence of multi-layered hydraulic zones, nonhomogeneous fissure zones, and variable erosional features. By characterizing ground-water types on the basis of major ion chemistry, and subsequently interrelating with minor ion distributions (notably iodide supported by strontium), a reasonable assessment of operative flow paths and mechanisms has been made. Substantiation of the conclusions reached using major and minor ion chemistry is provided by the environmental isotope data of carbon and tritium.

Notes: Unlined municipal waste stabilization lagoons are potential sources of ground-water contamination. Fourteen monitoring wells were installed around the McVille, North Dakota lagoon, a site at which the impoundment is excavated into permeable sediments of an unconfined glacio-fluvial aquifer with a shallow water table. One cell at the site, Cell I, retains waste water continuously, while another, Cell II, is used for periodic overflow discharges from Cell I. Seepage through the bottom of Cell I passes through a strongly reducing organic sludge layer. Sulfate in the waste water is reduced to sulfide and possibly precipitated as sulfide minerals in or below this sludge layer. In the unsaturated or shallow saturated zone beneath the pond, the infiltrating waste water reduces ferric iron in iron oxide minerals to more soluble ferrous iron. Proximal down-gradient well analyses indicate high iron concentrations and very low sulfate levels. Downgradient wells near the lagoon have very high ammonium concentrations. The source of the ammonium is either rapid infiltration from Cell II or denitrification of the nitrate present in ground water upgradient from the lagoon. About 300 feet downgradient from Cell I, ammonium concentrations decline to near zero. The most likely mechanism for this decrease is cation

Notes: Abstract. Using known or estimated values of trans-missivity and storativity, the distribution of drawdowns at any time within a discretized flow field can be generated by applying simple trigonometry and numerical approximations of the exponential integral to the Theis equation. Single- and multiple-well systems, as well as image boundaries, are readily simulated with this method. A program employing this technique is presented in BASIC for use with microcomputers. The availability, low cost, and computational power of many small computers makes them ideal for this type of application. Their user-oriented features allow many possible combinations of wells, boundaries, and hydraulic properties to be analyzed in a short time.

Notes: A gravity survey was conducted in a 94-square-mile area of northeastern Hanson County, South Dakota. The 340 measured gravity values, together with test-hole data, were used to approximately delineate a buried valley eroded into the Sioux Quartzite of Precambrian age. This valley contains, in places, an aquifer composed of quartzose sand of pre-Cretaceous age derived from the Sioux Quartzite. The bottom of the valley is approximately 450–600 ft below land surface. Simple Bouguer values were determined from measured gravity data, referenced to a local base station, and interpolated to a 0.5- by 0.5-mile grid. The interpolated simple Bouguer values of residual gravity were determined using a five-ring, inverse-weighted filtering method. The second derivative of the interpolated gravity values, as well as their downward continuation, did not delineate the buried valley as well. Subsequent drilling of nine test holes showed that the gravity method can be used for approximately delineating subsurface features

Notes: Glacial buried-valley aquifers serve as primary sources of potable ground water in northeastern Kansas. A long known problem, however, is that a large percentage of well waters in this region exceed the U.S. Environmental Protection Agency (EPA) limits for nitrate (NO−3). A detailed study of the hydrogeology and water quality of the buried valleys has confirmed the nitrate problem and led to a recognition that some well waters with low (〈inlineGraphic alt="leqslant R: less-than-or-eq, slant" extraInfo="nonStandardEntity" href="urn:x-wiley:0017467X:GWAT755:les" location="les.gif"/〉 5 mg/l) NO−3 concentrations have anomalous (〈inlineGraphic alt="geqslant R: gt-or-equal, slanted" extraInfo="nonStandardEntity" href="urn:x-wiley:0017467X:GWAT755:ges" location="ges.gif"/〉 0.5 mg/l) ammonium ion (NH+4) levels, with an NH+4 range from 〈0.1 to 4.8 mg/l. The extractable NH+4 concentrations in related glacial sediments range up to approximately 75 mg/kg, and the amounts generally increase from an average of 2 mg/kg in the topsoil downward to bedrock. Migration of brines from subjacent Permian or Pennsylvanian bedrock into the unconsolidated sediments locally may cause desorption of NH+4 and an increase in its levels in the associated ground waters. Numerous test holes drilled in the study area showed a black scum on the fluid and cuttings, which may be from buried humic materials. Recently measured total organic carbon (TOC) contents of the ground waters confirm a significant level in some areas, with a range from 0.1 to 2.4 mg/l as C. Chlorination of water with dissolved organics may lead to production of halogenated compounds. Two public-water-supply well waters contained total trihalomethane (TTHM) levels close to the maximum contaminant level (MCL) of 100 /μg/l in chlorinated samples quenched after one week. The presence of NH+4 inhibits the formation of THMs, but it also can give rise to odor and taste problems in the finished water. The inhibition of THM formation by NH+4 is achieved by reactions which compete with the organics for combination with chlorine. These reactions make maintaining appropriate chlorine residuals difficult and also may lead to production of undesirable side products. Present efforts to evaluate the regional water-quality problems are focused in Nemaha County, Kansas.

Notes: Biofilm processes are potentially important for transformations of organic micropollutants in ground water. Some theoretical hypotheses and empirical observations suggest that a concentration threshold exists for some compounds below which the concentration cannot be reduced by bacterial action. However, in the presence of one compound at a relatively high concentration, termed the primary substrate, another compound present at trace concentrations, termed the secondary substrate, can be biotransformed as well. These concepts were evaluated through laboratory column studies with several halogenated organic compounds of importance in ground water. A biofilm model can successfully describe utilization of trace substrates, and application to modeling the subsurface is discussed. A simplified batch model with first-order kinetics may be adequate for describing subsurface microbial processes when low active organism and pollutant concentrations exist over a large scale.

Notes: Mathematical modeling founded on a strong field data base can be a valuable tool for the analysis of ground-water contamination problems. The purposes of this paper are threefold: (1) we demonstrate the dilemma of a knowledgeable ground-water quality regulator whose regulatory decision-making process is confronted with the output of a mathematical model that is based on very limited field test data; (2) we demonstrate a method available to a knowledgeable regulator for assessing approximately a range of possible performances of a contaminated ground-water recovery well field using a range of input data derived from a very limited data base; and (3) we present a strong case for presenting mathematical model outputs as ranges of values rather than as unique solutions. A range is determined by an examination of the level of sophistication of the field data base. Our experience with 12 field sites wherein ground-water contamination has occurred has led us to conclude that field data are seldom, if ever, adequate to defend a unique solution from a mathematical model. Regulatory decisions generally can be reduced to minimization of risks based on the smallest range of model outputs that can be defended on the basis of the field data base. The more limited the field data base, the greater must be the range of defensible model outputs, and consequently, the greater the risk inherent in subsequent regulatory decisions. The knowledgeable regulator can assess the risks in the regulatory decision-making process only if he is able to assess the extent to which the field data base for the mathematical model output reflects state-of-the-art data collection and analysis technologies and methodologies. If an applicant for a permit or license submits a less than adequate data base and concomitantly a broad range of defensible model outputs, he inherently requests that the knowledgeable regulator accept a risk greater than that required if adequate aquifer testing techniques had been employed.

Notes: Ground-water monitoring to delineate a contaminant plume in fluvial hydrostratigraphic units often is uncertain. Fluvial deposits consist typically of interbedded layers of sands, silts and clays, with buried stream channel deposits of sands or gravels. The channel deposits are often interpreted erroneously to be discontinuous between test holes and in cross section due to their sinuosity. Erroneous conclusions pertaining to the areal continuity of these geometrically complex deposits are inevitable unless the investigator thoroughly understands the depositional environment(s).The hydraulic conductivity of buried stream channel deposits may be several orders of magnitude higher than the matrix materials in which they are enclosed. The higher hydraulic conductivity of buried stream channel deposits has potentially significant ramifications with respect to ground-water monitoring to delineate the geometry of a contaminant plume migrating through these deposits.Ground-water monitoring at uranium mill waste disposal sites located in fluvial environments began on a significant scale in about 1977. A uranium mill tailing disposal site located in such an environment in central Wyoming is among the first sites monitored. Thirty-seven monitor wells were constructed at the site to delineate a seepage plume originating from one of the tailing ponds. This case history illustrates the need for a detailed under—standing of the hydrostratigraphy at a waste disposal site in order to interpret the meaning of ground-water quality data effectively. Water quality data from monitor wells located on a hit or miss basis often are misleading. The hydrostratigraphic horizon from which a water quality sample is collected must be well defined before the sample analyses can be interpreted quantitatively.

Notes: Deep-well injection into fractured sandstone is an option for the disposal of contaminated mine dewatering discharge from an open pit uranium mine. As part of the assessment of potential contaminant migration from deep-well injection, the effect of matrix diffusion was evaluated. An analytical mathematical model was developed for the simulation of the radial movement of a contaminant front away from an injection point under steady flow conditions in a planar fracture with uniform properties. The model includes the effects of advection in the fracture, diffusion of contaminants from the fracture into the rock matrix, and equilibrium adsorption on the fracture surface as well as in the rock matrix. Effective diffusion coefficients obtained from laboratory experiments on 11 intact core samples varied from 3.4 × 10−8 to 3.2 × 10−7 cm2/s. Model simulations were made with diffusion coefficient values in this range and with single-fracture injection rates estimated from fracture frequencies in boreholes, and from bulk hydraulic conductivity values obtained from field tests. Because of matrix diffusion, the rate of outward movement of the front of the nonreactive contaminants from the injection well is much slower than the rate of water flow in the fractures. Simulations of the movement of contaminants that undergo adsorption indicate that even a small distribution coefficient for the rock matrix causes the contaminants to remain very close to the injection well during the one-year period. The results of the simplified model demonstrate that matrix diffusion is an important process that cannot be neglected in the assessment of a waste disposal scheme located in fractured porous rock. However, in order to make a definitive assessment of the capability of matrix diffusion and associated matrix adsorption to significantly limit the extent of contaminant migration around injection wells, it would be necessary to conduct field tests such as a preliminary or experimental injection.

Notes: An abandoned creosote facility in Conroe, Texas, has become a field site for the National Center for Ground Water Research (NCGWR) at Rice University. Ground-water contamination in the shallow aquifer beneath the site was characterized by sampling soils and water quality at 14 monitoring wells and 35 boreholes.Results from six sampling trips over two years for inorganic and organic chemical concentrations in the ground water show wells around the site were contaminated to levels above 800 μg/l for naphthalene, 400 μg/1 for methyl naphthalene, and 150 μg/1 for dibenzofuran. Conservative constituents, traced by chloride concentrations up to 75 mg/l, have migrated 300 ft (90 m) downgradient of the site. Organic contaminants have been adsorbed and microbially degraded in their migration from the waste source as evidenced by their attenuated concentrations. Detailed field pump tests have been performed to evaluate hydraulic conductivity at several of the shallow wells. The U.S. Geological Survey (USGS) Solute Transport Model (Konikow and Bredehoeft, 1978) has been used to predict chloride plume patterns and evaluate parameters which govern transport processes at the Conroe waste site.

Notes: Studies of the relationships between ground-water systems and surface-water systems (lakes) generally require knowledge of the hydrogeologic properties of lakebed materials. Direct measurement of these properties may be prohibitively expensive or difficult in an offshore environment. A correlation between longitudinal conductance, a geoelectric parameter, and lakebed leakance (vertical hydraulic conductivity divided by thickness) may provide a rapid and inexpensive method for estimating lakebed hydrogeological properties using data collected by offshore seismic and electrical surveys. A test of the method at three study sites in Lake Michigan shows a positive linear relationship between the logarithm of longitudinal conductance and the logarithm of lakebed leakance at the three sites.

Notes: Using the type-curve methods of Boulton (1963) and Neuman (1972), and comparisons, at various times, of the cumulative volume of water pumped to the volume of the water-table drawdown cone (volume-balance method), values of specific yield were obtained from pumping test data from numerous piezometers in an unconfined sand aquifer. The long-term value of specific yield for the aquifer was determined from measurements of the laboratory drainage curve of the aquifer material.The volume-balance method gave specific yield values of 0.02, 0.05, 0.12, 0.20, 0.23, and 0.25 at times of 0.25, 0.66, 10, 26, 45, and 65 hours, respectively, indicating a gradual increase in specific yield and an asymptotic approach to the long-term value of 0.30 determined from the laboratory method. The type-curve methods provided values of 0.07 and 0.08, which correspond to the volume-balance values at early times, but which are less than one-third of the value obtained from the laboratory method and from the volume-balance method applied at the end of the pumping test (2.7 days). The type-curve procedures therefore provide unrealistically low values of specific yield for application to problems concerning the long-term yield characteristics of the aquifer.The observed trend towards increasing values of specific yield with increasing duration of pumping, and the vertical hydraulic head profiles that were measured during the pumping test indicate that both delayed drainage from above the water table and downward hydraulic gradients in the saturated zone can be important hydraulic effects contributing to the delayed-drawdown segment that is characteristic of time-drawdown graphs for unconfined aquifers.

Notes: Flow simulations supplemented resource evaluation studies of the Lower Greensand aquifer. The annual recharge has hitherto been considered to be the resource available for development although a large confined storage exists. Pumping is principally in urban areas but recent monitoring suggests that the aquifer may have suffered excessive drawdowns. Therefore, simulation studies were carried out to refine the annual recharge estimate, to define the past effects of pumping and to obtain an indication of future trends. Catchment water balance indicates average annual recharge of 28 × 106 m3. One-dimensional (ID) ground-water flow simulation suggests that regional abstractions affect outcrop-water levels. The study showed that the aquifer reached a new equilibrium with the current pumping regime. An improved insight to the aquifer has permitted the formulation of strategies for future resource development.

Notes: The U.S. Geological Survey is studying the potential for storage of heated water in a sandstone aquifer in St. Paul, Minnesota. The efficiency of the aquifer to store thermal energy is related, in part, to the hydrogeologic characteristics of the aquifer. The movement of heat away from the injection well is directly related to the anisotropy. Aquifer tests were conducted to determine the anisotropy near the heated-water injection well. The maximum and minimum values of transmissivity along the principal directions of the hydraulic conductivity tensors of the Ironton and Galesville Sandstones in St. Paul, Minnesota are approximately 1,090 and 480 feet squared per day. The storage coefficient is 4.5 × 10−5. These values represent the average of four determinations of nonsteady flow to a well in an idealized infinite anisotropic aquifer. Analysis of the values of transmissivity and storage coefficient for hypothetical changes in location of two of the monitoring wells where depth-deviation surveys were not available indicates that computed transmissivities vary less than 5 percent and storage coefficients vary less than ±6 percent.

Notes: The acceptability of the hypothesis of Darcian flow through a semiconfined carbonate aquifer was tested prior to running a multiple-day aquifer test in Pinellas County, Florida. The approach used to test the hypothesis was to run a number of hour-long aquifer tests at different discharges with drawdown measured at the same time during each test in two observation wells, one at 35 feet and the other at 733 feet from the pumped well. If the hypothesis were acceptable, a plot of drawdown versus discharge should describe a straight line.A linear relation was described in 15-minute and 1-hour data plots of drawdown versus discharge for both observation wells. Thus, the hypothesis of Darcian flow through the semiconfined carbonate aquifer was deemed acceptable. Drawdown data from the distant observation well collected during the following multiple-day aquifer test were then analyzed for aquifer-property values of transmissivity, storage coefficient, and leakance coefficient using standard methods. Discharge for the multiple-day test was within the discharge range of the hour-long tests.

Notes: A 43-acre watershed in Muskingum County, Ohio, was studied to determine the hydrologic consequences of strip mining for coal. A quantitative description of the effects on the ground-water flow components of the hydrologic system has been obtained using digital models.The premining watershed was characterized by nearly flat-lying sedimentary rocks of the Pennsylvanian System. Underclay beneath the two major coal beds formed bases for perched zones, creating three separate aquifers. Recharge to the ground-water system occurred mainly by percolation of precipitation. Most of the discharge from the top and middle aquifers occurred by downward leakage to the underlying aquifers. A smaller amount of discharge occurred as springflow or streamflow near the intersections of the underclays and land surface.Mining has destroyed the top aquifer, and has replaced the bedrock by spoil material. Water levels in the spoils are at a much lower altitude than existed in the premining top aquifer because of a combination of (1) a larger hydraulic conductivity, (2) areal variations of the hydraulic characteristics of the confining bed, and (3) a slower rate of recharge from precipitation caused by removal of vegetation and soil compaction. Covering of previously exposed portions of the middle aquifer and a lower hydraulic head in the spoils has allowed less recharge to the middle aquifer. Additional flow is induced across the western boundary of the watershed and has reduced the outflow across the eastern boundary. Discharge from the middle aquifer as downward leakage and streamflow is less than before mining.

Notes: The seepage meter and the mini-piezometer were utilized in an attempt to evaluate ground-water reservoir interactions over a 12-month period at Echo Bay in Lake Mead. In conjunction with these techniques three standard piezometers, refraction seismic data, and water chemistry data were utilized to interpret seepage device results. During a four-month period, from December 1979 to March 1980, an 8 ft (2.5 m) rise in reservoir stage, the reservoir contributed water to Echo Wash bank storage at rates of up to 0.29 gpd/ft2 (12 lpd/m2). Ground-water discharge occurred for the remainder of the project, during a stage decline from April 1980 to May 1980, a rise in June 1980, and leveling off and slight decline for the remainder of the year, July 1980 to December 1980. The maximum seepage meter ground-water discharge rate of 3.0 gpd/ft2 (122 lpd/m2) was recorded in December 1980. Seepage meter water chemistry data for June were similar to Lake Mead water chemistry and were interpreted to be previously recharged Lake Mead water. September water chemistry data showed two possible components of ground-water discharge, a high SpC calcium sulfate Echo Wash ground water and a lower SpC Lake Mead recharged bank storage water. December ground-water chemistry data showed discharge to be a high SpC calcium sulfate water similar to Echo Wash ground-water quality which was apparently unaffected by Lake Mead inflow. Mini-piezometer data were collected at each seepage meter site. However, these data usually did not provide correlative results with seepage meter data probably because of suspended sediment in the piezometer water column and plugging of the perforated tip. Seepage meters were successfully utilized to characterize reservoir ground-water interaction in Echo Bay.

Notes: Abstract. This paper describes how a numerical method of pumping test analysis, which has proved to be useful in many practical situations, can be run on microcomputers. Full details of a program in BASIC and a test problem are provided. The need to perform all the calculations to a sufficient accuracy is stressed, and the choice of suitable mesh spacings and time steps is discussed.

Notes: Effective management of a ground-water system requires description and prediction of the transport and fate of contaminants in that system. This can be facilitated by using mathematical models which accurately represent the physical phenomena operative in the system. One of the most significant phenomena impacting the transport of many organic pollutants is partitioning between the solid (soil) and aqueous (ground-water) phases.The tendency of a contaminant to partition may be roughly approximated from measurements of such constitutive properties as the octanol: water partition coefficient of the contaminant and organic carbon content of the soil. Such rough approximations provide a basis for cursory appraisal, but are inadequate for quantitative system descriptions, particularly where nonlinear equilibrium sorption, kinetically dependent partitioning, or irreversible and/or hysteretic phase distribution phenomena are operative. Accurate simulation of solute transport frequently requires the incorporation of kinetic parameters and/or a nonlinear isotherm relationship to define transport phenomena in the fundamental equations governing mass transport. Laboratory measurements may be utilized to assess sorptive factors of importance, kinetic properties of an organic solute and a soil system, and equilibrium partitioning relationships. Such measurements can be utilized to provide more accurate modeling of contaminant transport.

Notes: Abstract. Two useful programs have been developed for the Hewlett Packard HP41CV programmable calculator. The THEIS program is designed to simulate a well pumping from a confined or unconfined aquifer. Drawdown, residual drawdown, t/t1 and t/r2 are calculated. The BOUN program is designed to solve for drawdown in a well pumping from an aquifer bounded by two parallel impermeable barriers. The programs can be used in aquifer pumping test design, pumping test analysis, and aquifer response predictions.

Notes: The hydrogeology of the chemical waste disposal site in the closed basin at Alkali Lake, Oregon has been examined. Interest in the site is due to the burial (November 1976) of 25,000 drums of herbicide manufacturing residues in unlined trenches on the playa of the basin. Included in the wastes were large amounts of chlorophenols and polymeric chlorophenoxyphenols. The flow of the alkaline (pH ∼10) ground water in the site area is driven by: (1) springs which create a mound east of the site; and (2) the sump effect of “West Alkali Lake,” a topographic low to the west of the site. Porosity, bulk mass densities, and grain-size distributions were determined. At one piezometer, the depth to ground water ranged between 0.9 m and 2.2 m. With the bottoms of the trenches in which the chemicals were buried between 0.60 and 0.75 m below the level of the ground surface, the bottom portions of the trenches may, at least occasionally, be in direct contact with the ground water.

Notes: The city of St. Petersburg is testing subsurface injection of treated sewage into the Floridan aquifer as a means of eliminating discharge of sewage to surface waters and as a means of storing treated sewage for future nonpotable reuse. The injection zone at the test site at the start of injection contained saline water with chloride concentrations ranging from 14,000 to 20,000 milligrams per liter (mg/1).Treated sewage with a mean chloride concentration of 170 mg/1 was injected through a single well for 12 months at a mean rate of 4.7 × 105 cubic feet per day. The volume of water injected during the year was 1.7 × 108 cubic feet. Dissolved oxygen was contained in the sewage prior to injection. Water removed from the injection zone during injection was essentially free of oxygen. Probable growth of denitrifying bacteria and, thus, microbial denitri-fication, was suggested by bacterial counts in water from two observation wells that were close to the injection well.The volume fraction of treated sewage in water from wells located 35 feet and 733 feet from the injection well and open to the upper part of the injection zone stabilized at about 0.9 and 0.75, respectively. Chloride concentrations stabilized at about 1,900 mg/1 in water from the well that was 35 feet from the injection well and stabilized at about 4,000 mg/1 in water from the well that was 733 feet from the injection well. These and other data suggest that very little near injection-quality treated sewage would be recoverable from storage in the injection zone.

Notes: Quaternary alluvium, ranging in thickness from a few to 100 meters underlain by Precambrian rocks of metamor-phic and igneous origin, constitutes an important source of ground water in Wadi Al-Yammaniyah, Saudi Arabia. The purpose of this report is to assess the hydraulic properties, quality of water, and estimated change in storage in waterbearing rocks in the area.The results of eight pumping tests carried out in hand-dug, large-diameter wells, indicate that the hydraulic conductivity of the alluvial aquifer ranges from 5.6 × 10−5 to 1.85 × 10−3 cm/second (3.36 × 10−5 to 1.11 × 10−3 m/minute) and that its storativity varies from 8.23 × 10−2 to 1.17 × 10−1.The aquifer is replenished by sporadic but intensive rainfall of short duration. The present withdrawal is only about 10 percent of the annual recharge which is estimated at 52 × 106 m3. It is shown that there is a substantial potential for the future development of potable ground water which would be required for the development of the area.

Notes: Chemical studies have been carried out on a number of water wells from the Dibdiba Formation northeast of Kuwait. Water salinity of this formation ranges between 3,300 mg/l to 7,000 mg/l, increasing with depth. The water entrapped in Dibdiba Formation is mainly sodium chloride type which can be differentiated into three different groups according to the ranges of concentration of the main cations and anions. These groups are: (3331113) sodium chloride water type in which Cl 〉 Na, group (3333113) sodium chloride water type in which Na 〉 Cl. In both groups the sequence of dominant cations is Na 〉 Ca 〉 Mg. Group (3333111) sodium chloride water type has Na 〉 Cl and the sequence of dominant cations is Na 〉 Mg 〉 Ca. Chemical ratios of Ca/Mg, Na/Cl, and C1/HCO3 were worked out for Dibdiba ground water. The ratio of Ca/Mg Dibdiba Formation ranges from 0.4 to 8.58, the ratio of Na/Cl ranges between 0.98 to 1.33, and the ratio of C1/HCO3 is 232.A plot of chemical analysis on a trilinear diagram shows that Dibdiba Formation ground-water chemical properties are dominated by alkalies (Na 〉 Ca) and strong acid (Cl 〉 SO4). Water chemistry may reflect the history of the flow path, indicating regional flow as shown by increasing Na+, Cl-, SO–4 and where Ca+, Mg+ achieve equilibrium.

Notes: Nitrate concentrations in ground water on Long Island, New York, have increased markedly in the last 30 years. A significant amount of this increase has been attributed to lawn and garden fertilizers in addition to cesspool and septic-tank discharges. The increase in nitrate concentration is of particular concern in the central and eastern part of the island, where ground water is the sole source of drinking water.Ground-water samples were collected from 14 wells screened near the water table in the sewered Twelve Pines housing development constructed in Medford, Suffolk County, in 1970. Samples were collected during 1972–79 and analyzed for total ammonium, organic nitrogen, and nitrate.Statistical analyses indicate that concentrations of nitrate-nitrogen in water from 10 of the wells increased significantly during 1972–79; those in water from the other four wells did not.Nitrogen loads were estimated to be 2,300 kg/yr from fertilizers, less than 80 kg/yr from irrigation water, 200 kg/yr from animals, and less than 670 kg/yr from precipitation. Leakage from sewers was considered negligible.Nitrate-nitrogen isotope ratios also suggest that the greatest source of nitrogen is from cultivation sources (either mineralized soil nitrogen or fertilizers) rather than human or animal wastes.

Notes: Bedrock depths can be calculated readily from ground magnetic profiles using either Werner deconvolution or Fourier spectral analysis. For crystalline basement rocks of New England and eastern Canada, a vertical dike is a useful magnetic source model. Formulae for these methods are presented along with some practical guidelines for implementing them.Six field examples from metamorphic and igneous areas in New Hampshire show that bedrock depths from spectral analysis agree well with estimates from seismic refraction, from wells and from outcrops. The Werner estimates are much more variable but commonly bracket the others. At several of these sites, measurements by other geophysical methods would be impractical, more expensive, or restricted to certain times of the year.

Notes: A newly developed technique which allows the down-hole sampling and subsequent analysis of ground water for trace organic contaminants was tested during an investigation of contaminant migration at an inactive landfill site in Burlington, Ontario, Canada. The sampling device, which is lowered down piezometers with a tube, consists of a small cylindrical cartridge of sorbent material attached to a syringe. Vacuum or pressure applied at the surface controls the movement of the plunger in the syringe. The volume of the syringe determines the volume of sample water that passes through the cartridge. The cartridge is removed from the syringe at the surface. One cartridge is used for each sampling; the syringe is reusable. The residual water in the cartridge is removed in the laboratory, and the cartridge is desorbed to a fused silica capillary column for analysis by gas chromatography (GC). The analyses discussed here were performed on a GC/mass spectrometer/data system (GC/MS/DS). Of the many organic compounds that were identified in the samples, three compounds were clearly landfill-related: 1,1,1-trichloroethane, chlorobenzene, and para-dichlorobenzene. The three compounds were found at levels substantially above blank levels in 9, 5, and 5 piezometers, respectively. The average concentrations were 14., 5.3, and 0.88μg/1 (ppb), respectively. The pooled coefficients of variation for the analyses for the three compounds were 27., 6.9, and 6.4%, respectively. The volatility of 1,1,1-trichloroethane was probably the cause of the greater variability in its analytical data. The main advantages of the technique over most conventional sampling methods include: (1) down-hole sampling in a manner which minimizes the potential for volatilization losses; (2) avoidance of passage of the sample through long sections of tubing that may contaminate the sample or cause adsorptive losses; (3) convenience of sample handling, storage, and shipping; and (4) high sensitivity.

Notes: A technique is presented for the estimation of ground–water recharge in a region where the formations overlying an aquifer cannot transmit all of the available water to the aquifer. The method is based on a routing model which is derived from the physical nature of formations overlying the aquifer. The model takes into account precipitation, evapotranspiration, soil moisture balance and the passage of water through strata such as boulder clay. The validity of the model is tested by calculated and field stream flow hydrographs.

Notes: In order to understand the flow pattern around a pumping well partially penetrating a vertically extensive aquifer, a specially designed pumping test was carried out in Pakistan. In this paper salient features of the test have been described. The spatial distributions of drawdown have been shown graphically. Some of the preliminary conclusions made from the drawdown pattern include:〈list xml:id="l1" style="custom"〉•The distance beyond which the flow is likely to be horizontal increases with decrease in the degree of aquifer penetration.•In equidistant observation wells open at different depths, (1) the drawdowns tend to merge at larger times, provided the observation point is located within the screened section of the aquifer; (2) the less the depth of penetration is, the earlier the drawdowns start merging; and (3) the initial rate of drawdown near the aquifer top is slow but catches up with time to exceed those at deeper points.

Notes: The ground-water flow and ground-water quality of extensive gravel deposits in the Lower Colne Valley, near London, England are described. The great demand for aggregates in southeast England over the past 30 years has resulted in extensive exploitation of these gravels, the worked-out pits being either left water-filled for recreational purposes, or filled with a variety of waste materials. Both after-uses are shown to alter the ground-water situation either by locally lowering or raising ground-water levels, such effects having been described in both French and German literature, or by causing ground-water and surface-water pollution problems. If the scale of pit development or landfilling is large as in the Lower Colne Valley, then remedial measures have to be undertaken to minimize the pollution risk and to obviate problems caused by raised or lowered ground-water levels.

Notes: Confined flow of ground water through a tunnel, which might be encountered in tunneling under the bottom of a sea or river, is numerically analyzed by a reductive finite element method formulated in our research. That is, the rate and potential distribution of the confined flow of ground water through an opening are obtained in connection with the permeability of rock masses, the thickness of covered ground, the location of impermeable bedrock, and other variables.In addition, flow through an opening in the ground with highly permeable masses and discharge of ground water through a tunnel in grouted masses are illustrated, and some useful results for the practical application of tunneling work are obtained.

Notes: The ground-water flow system in the Lower Susquehanna River Basin in Pennsylvania and Maryland can be considered as one complex unconfined aquifer in which secondary porosity and permeability are the dominant influences on the occurrence and flow of ground water. The degree of development of secondary porosity and permeability in the various lithologies of the lower basin determines the aquifer characteristics of each lithology. Based on qualitative evidence, the use of a porous-media model was assumed to be appropriate on a regional scale and a finite-difference ground-water flow model was constructed for the lower basin.The conceptual model of ground-water flow in the lower basin incorporates the major features of the flow system. Through the use of two layers, 21 hydrogeologic units, and five topographic settings, the conceptual model was systematically reduced to arrive at a simplified conceptual model. Further reduction produced a numerical model representation of the conceptual model, in which the essential features of the lower-basin flow system were quantified for input into the numerical model.The model was calibrated under both steady-state and transient conditions, and was used to evaluate the water-supply potential of the 21 hydrogeologic units. The carbonate units have the greatest potential for ground-water development and the Triassic sedimentary and crystalline units have the least potential. A total ground-water yield potential of about 900 million gallons per day could be obtained from the lower basin with a consequent 50-percent reduction of base flow in streams.

Notes: An algorithm for the Theis solution of pumping test data has been developed taking into account the basic principles of graphical approach of curve-matching. The method is simple and does not need initial approximation of transmissivity and storativity as required by approaches suggested by Saleem (1970) and McElwee (1980). As a measure of error of fitting, integral square error is computed between the observed drawdown and drawdown calculated from the theoretical equation with the values of coefficients estimated by the procedure. Also root mean square deviation in drawdown is calculated. The algorithm is capable of identifying data with errors in observation or recording. The reliability of the algorithm and its limitations are discussed on the basis of test runs with synthetic data having varying magnitudes of error and varying distributions of error points in the data set. The estimates of parameters by the proposed algorithm for a typical field test data compare very well with the estimates by the sensitivity approach developed by McElwee (1980).

Notes: During the two-week period from March 12 through March 26, 1982, a preliminary conceptual design analysis on various remedial measures for the Lipari Landfill, New Jersey, was performed. This site is currently ranked at the top of the EPA's Superfund Cleanup List. This report demonstrates the practical benefits and limitations of applying models (both analytical and numerical) to a hazardous waste site in a restricted period of time. The numerical model was used to simulate current flow conditions at the site and provide initial conditions for a series of sensitivity simulations. These sensitivity simulations were designed to test (1) a slurry wall, (2) drain location, (3) drain depth, and (4) a clay cap. Analytical solutions were designed to analyze (1) water in place, (2) flow through an underlying layer, the lower Cohansey, (3) draining the lower Cohansey, (4) flushing the contaminated area using wells, and (5) convective arrival time of contaminants to drains. This analysis quantified discharge to drains, flow rates to a swamp downstream of the landfill, time required to drain the landfill, and contaminant travel times that would result from the implementation of each of the remedial measures that were suggested. The conclusions from this study were used by engineers and planners who incorporated, economics and engineering decisions for the various remedial measures considered.

Notes: A zone of contaminated ground water has been identified in an unconfined sand aquifer adjacent to a pit into which spent pulp liquor was intermittently discharged from 1970 to 1979. A network of multilevel sampling, bundle-type piezometers was installed. Up to seven depthspecific sampling points were incorporated into each piezometer providing a cost-effective means for three-dimensional mapping of hydraulic head and water quality in the unconfined sand aquifer. Ground-water samples retrieved from this network showed an area of contamination 900 m long, 400 m wide, and more than 25 m deep. This plume is dispersed about the ground-water flow lines passing beneath the waste disposal pit, and it terminates at a vigorous ground-water discharge area located 800 m from the pit.The contaminated ground water is characterized by elevated concentrations of sodium (3,000 mg/1), chloride (590 mg/1), alkalinity (2,700 mg/1), total organic carbon (2,000 mg/1), chemical oxygen demand (10,800 mg/1), biological oxygen demand (2,000 mg/1), tannin and lignin (780 mg/1), and lower sulphate (1 mg/1) compared to background ground waters in the area. The apparent rate of sodium migration is more than 50 m/yr and is close to the average linear ground-water velocity. Removal of some organic matter by biological transformation has produced the increased alkalinity in the contaminated ground water and somewhat reduced pH. Tannin and lignin are relatively inert compared to other organic compounds found in the waste liquor. Extremely low sulphate levels occurring in the highly contaminated ground waters indicate the existence of conditions favorable for microbially-mediated sulphate reduction.

Notes: Fluoride contents range from 〈0.05 to 5.9 milligrams per liter (mg/1) based upon 255 water samples collected from wells in nine counties of northeastern Ohio. Only 16 samples had fluoride contents exceeding 1 mg/1, and all are from the southern trio of counties. Furthermore, all samples high in fluoride are from wells close to or penetrating the contact between the Allegheny and Pottsville Formations.Data from a line of 34 wells for which logs were obtained indicate that high fluoride water occurs in either the lower part of the Allegheny Formation, or more probably, in the upper part of the Pottsville Formation.Ground waters high in fluoride are related to the bedrock geology. Fluoride data, particularly in the area of potentially high values, are important to health professionals in the prescription of fluoride supplements for children. Such prescriptions should be made only after the water has been tested.

Notes: A computer simulation study was conducted to quantify the potential thermal impact of residential water-source heat pump usage on ground-water aquifers.In a first phase of the study, weather data for nine locations throughout the country were used to estimate the energy requirements for heating and air conditioning a typical residence. These energy requirements were then translated into the volumetric water demands for a selected heat pump at each location. A representative model aquifer was then defined and its characteristics used, along with the heat pump water requirements and design ΔT's (difference between inlet and outlet water temperature) to identify the important parameters that contribute to heat transfer and to model the movement of the thermal front resulting from injection of heat pump discharge water at the nine locations.The major factor that determines the heat pump thermal impact was found to be the net amount of heat injected into, or removed from an aquifer. Other significant factors included well design, heat pump design ΔT, and physical properties of the aquifer such as thickness, porosity and dispersivity.The study showed that, in climates where winter heating demand is very nearly equal to summer cooling demands, the injection of heat pump discharge water did not cause any significant modification of the ambient model aquifer temperature. However, in hot or cold climates where air conditioning or heating demand dominates, measurable thermal changes occurred in the model aquifer. In most cases, the maximum temperature

Notes: In order to investigate the aquifer parameters of a fissured layered sandstone aquifer, it was found necessary to construct and test an abstraction borehole using laboratory, double packer, geophysical and pumping test techniques. Good correlation was found between the techniques when the aquifer was represented by a fissured layered aquifer with low permeability bands separating layers of higher permeability. The use of multiple piezometers proved to be the only way of obtaining sensible results for field pumping tests and has given storage coefficients for both the confined and unconfined sections of the aquifer.