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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems  (8)
  • 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology  (6)
  • 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects  (3)
  • Elsevier  (17)
  • Annual Reviews
  • 2005-2009  (17)
  • 1990-1994
  • 1980-1984
  • 2005  (17)
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  • 2005-2009  (17)
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  • 1
    Publication Date: 2020-12-15
    Description: The eruptive events of the July–August 2001 and October 2002–January 2003 at Mt. Etna provide new insights for reconstructing the complex geometry of the feeding system and their relationship to regional tectonics. The 2001 eruption took place mainly on the upper southern sector of the volcano. The eruption was preceded by a large earthquake swarm for a few days before its onset and accompanied by ground deformation and fracturing. The development of surface cracking along with the seismic pattern has allowed us to recognize three distinct eruptive systems (the SW–NE, NNW–SSE and N–S systems) which have been simultaneously active. Such eruptive systems are only the upper portions of a complex feeding system that was fed at the same time by two distinct magmas. The SW–NE and NNW–SSE systems, connected with the SE crater conduit, were fed by magma coming from depth, whereas the N–S system served instead as an ascending pathway for an amphibole-bearing magma residing in a shallow reservoir. The eruptive activity started again on October 2002 on the NE Rift Zone, where about 20 eruptive vents were aligned between 2500 and 1900 m a.s.l., and on the southern flank, from the central crater to the Montagnola. The onset of eruptive activity was accompanied by a seismic swarm. As in the 2001 eruptive event, two independent feeding systems formed, characterized by distinct magmas. The SW–NE system controlled the feeding of the Northeast Rift and was accommodated by left-lateral displacement along the WNW–ESE trending Pernicana Fault. The N–S system fed the eruptions on the southern flank. Moreover, the associated crustal deformation triggered seismic reactivation of tectonic structures in the eastern flank of the volcano and offshore. These two last eruptions indicate that at Mt. Etna the ascent of magma, as well as the accommodation of deformation, is strongly dominated by local extensional structures that are connected to a regional tectonic regime.
    Description: Published
    Description: 211-233
    Description: partially_open
    Keywords: extensional tectonics ; volcanic activity ; seismicity ; Sicily ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 2
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 3
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 4
    Publication Date: 2017-04-04
    Description: The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece,and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments. Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature. N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and 13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism.
    Description: European community
    Description: Published
    Description: 2321–2334
    Description: partially_open
    Keywords: fumarolic gases ; hydrothermal systems ; chemical and isotopic equilibrium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 5
    Publication Date: 2017-04-04
    Description: The properties of volcanic tremor wavefield at Mt. Etna Volcano, Italy, are investigated using data from two dense, smallaperture arrays of short-period seismometers deployed on the North and South flank of the volcano. Spectral analysis shows that most of the seismic energy is associated to several, narrow spectral peaks spanning the 1–5 Hz frequency band. Analysis of simultaneous recordings evidences that most of these peaks are common to different sites, thus suggesting a source effect as the origin of this energy. Frequency-slowness analyses evidence a complex wavefield, where body- and surface-waves alternatively dominate depending on the frequency band and component of motion taken into account. Surface waves are found to dominate at frequencies below 1 Hz and above 3 Hz. Conversely, the 0.8–2.3 Hz vertical- and radial-component wavefields at both arrays exhibit a nondispersive nature, with apparent velocities spanning the 1–2 s/km range. Particle motion analysis suggests these arrivals are associated to both P- and SV-waves inciding at shallow angles. At the northern array, back-azimuths of these waves encompass the whole summit crater area. At the southern array, back-azimuths are instead clustered around a direction pointing about 500 m east of the SE crater. At frequency around 4 Hz, the dominant direction of wave propagation at the southern site shifts about 30jW, pointing to the Bocca-Nuova/Voragine craters, and concordance of location is found with the source imaged by the northern array. The 0.8–2.3 Hz transverse-component of motion depicts velocities of about 0.5 km/s, a value which is about three times lower than those associated to the vertical and radial components. Results from polarization analyses at the two array sites depict the dominance of horizontal, linear particle motion oriented transversally with respect to the source direction. Polarization ellipsoids at the stations of the sparse network all depict a quasi-horizontal setting. With two exceptions, the direction of particle motion is always oriented tangentially to the summit volcanic edifice. The origin of the large transverse motion observed at the two array sites is thus attributed to SH waves generated by free-surface interaction of waves impinging the concave topography. The correlation method is used to derive the dispersion properties of short-period (0.5–5 Hz) Rayleigh waves, from which the shallow shear-wave velocity structures are derived for beneath the two semicircular arrays. Using a probabilistic approach, we invert slowness data measured at the two dense arrays for retrieving source location and extent. The joint inversion of slowness data from the two arrays point to different sources. This observation is interpreted in terms of ray bending associated to lateral heterogeneity and/or strong topographic effects on wave propagation. Once the propagation effects are taken into account, the most probable source locations are associated to a shallow region encompassing the summit craters and the eruptive fissures active at the time of the experiment (September 1999).
    Description: Published
    Description: 223-245
    Description: partially_open
    Keywords: Mount Etna ; Volcanic tremor ; Volcanic seismicity ; Seismic monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 6
    Publication Date: 2017-04-04
    Description: On October 9, 1999 an earthquake of ML =3.6 occurred about 3 km beneath the central cone of Mt. Vesuvius, near Naples, Italy. The event had the highest magnitude recorded for at least 25 years, and possibly since the last eruption of this volcano (1944), and was not accompanied by other geophysical or geochemical changes. The present paper essentially deals with the seismological data collected at Mt. Vesuvius for 29 years before the October 9 earthquake till the end of 2001, and describes the time pattern distribution of seismic slip release and the b-parameter of the Gutenberg^Richter distribution. The self-similarity of the source process is investigated through the scaling law of the seismic spectrum. Results indicate a two-fold pattern of stress release, with high values (up to 100 bar) for earthquakes occurring close to the top of the carbonate basement that underlies the volcano at 2^3 km of depth, and low values (down to 0.1 bar) for the shallow events occurring within the volcanic edifice. The scaling law of the seismic spectrum is non-self-similar, indicating that the source dimensions do not scale with the seismic moment. For this reason the low-magnitude events substantially contribute to the overall cumulative seismic slip release. The bparameter of the Gutenberg^Richter distribution shows a variation around 1980, and a substantial constancy in the other time periods. The presence of extended aquifers, with their tops at about 1 km beneath the crater, favors the hypothesis of the triggering of the shallowest events by water-level changes. This hypothesis is in agreement with the low values of the stress drop measured for the shallowest seismic events. The existence of a carbonate basement with its top at about 2.5 km beneath the crater and the higher stress drops for the deeper events make reasonable the hypothesis that the pre-fractured carbonate basement may be the site of tectonic stress release.
    Description: Published
    Description: 23-39
    Description: partially_open
    Keywords: Vesuvius ; Seismicity ; Seismic source ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 7
    Publication Date: 2017-04-04
    Description: On July 18, 2001, two main eruptive vents opened on the southern flank of Mount Etna volcano (Italy) at ~2100 m and ~2550 m a.s.l., respectively. The former vent fed mild strombolian activity and lava flows, while the latter represented the main explosive vent, producing strong phreato-magmatic explosions. Explosions at this latter vent, however, shifted to a strombolian style in the following days, before switching back to phreato-magmatic activity towards the end of the eruption, which ended on August 9, 2001. On August 3, a small seismoacoustic array was deployed close to the eruptive vents. The array was composed of three stations, which recorded seismic and infrasonic waves coming from both of the eruptive vents. A further seismoacoustic station, equipped with a thermal-infrared sensor, was also installed several kilometers north of the first array. Seismic signals relating to the strombolian activity at the 2100-m vent were characterized by a strong decompression at the source. Analysis of the time delays between seismic, infrasonic and infrared event onsets also revealed that ejection velocities during explosions from both vents were subsonic. Time delays between the onset of explosive events apparent in the infrared and infrasound data indicated that the explosion source at the 2550-m vent was located 220–250 m below the crater rim. In comparison, the depth of the seismic source was estimated to be between 230 and 335 m below the rim. This converts to 120–150 and 130–235 m below the preexisting ground surface. In addition, time delays between seismic and infrasonic signals recorded for the lower (2100 m) vent also revealed a seismic source that was no more than a few tens of meters deeper than the fragmentation surface.
    Description: Published
    Description: 219-230
    Description: partially_open
    Keywords: Mt. Etna ; explosive eruptions ; arrays ; seismic ; infrasonic and thermal data ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 8
    Publication Date: 2017-04-04
    Description: We present here new measurements of sulfur dioxide and hydrogen sulfide emissions from Vulcano, Etna, and Stromboli (Italy), made by direct sampling at vents and by filter pack and ultraviolet spectroscopy in downwind plumes. Measurements at the F0 and FA fumaroles on Vulcano yielded SO2/H2S molar ratios of 0.38 and 1.4, respectively, from which we estimate an H2S flux of 6 to 9 for the summit crater. For Mt. Etna and Stromboli, we found SO2/H2S molar ratios of 20 and 15, respectively, which combined with SO2 flux measurements, suggest H2S emission rates of 50 to 113 and 4 to 8, respectively. We observe that source and plume SO2/H2S ratios at Vulcano are similar, suggesting that hydrogen sulfide is essentially inert on timescales of seconds to minutes. This finding has important implications for estimates of volcanic total sulfur budget at volcanoes since most existing measurements do not account for H2S emission.
    Description: Published
    Description: 1861–1871
    Description: partially_open
    Keywords: H2S atmospheric budget ; volcanic degassing ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 9
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 10
    Publication Date: 2017-04-04
    Description: This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 mg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at Vulcano Island and the Phlegrean Fields. In both areas the dissolution of As-bearing sulphides is likely to be the main source of As. Mature Cl-rich groundwaters, representative of the discharge from the deep thermal reservoirs, are typically enriched in As with respect to SO4-rich ‘‘steam heated groundwaters’’. In the HCO3 groundwaters recovered at Vesuvius and Etna, aqueous As cycling is limited by the absence of high-temperature interactions and by high-Fe content of the host rocks, resulting in oxidative As adsorption. Thermodynamic modelling suggests that reducing H2S-rich groundwaters are in equilibrium with realgar, whereas in oxidising environments over-saturation with respect to Fe oxyhydroxides is indicated. Under these oxidising conditions, As solubility decreases controlled by As co-precipitation with, or adsorption on, Fe oxy-hydroxides. Consistent with thermodynamic considerations, As mobility in the studied areas is enhanced in intermediate redox environments, where both sulphides and Fe hydroxides are unstable.
    Description: Published
    Description: 1283–1296
    Description: partially_open
    Keywords: Hydrogeochemistry ; Arsenic ; volcanic groundwaters ; speciation ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 11
    Publication Date: 2017-04-04
    Description: This study presents a detailed analysis and interpretation of the seismicity that occurred on July 2-7 and August 22, 2000, during a ground uplift episode which started on March 2000 at Solfatara crater, Campi Flegrei. Earthquakes are located using a probabilistic grid-search procedure acting on a 3-D heterogeneous earth structure. The mainshock of the July swarm depicts a spectrum characterized by a few narrow peaks spanning the 1^5-Hz frequency band. For this event, we hypothesize a direct involvement of magmatic fluids in the source process. Conversely, the spectra of the August events are typical of shear failure. For these latter events, we evaluate the source properties from P-and Swave displacement spectra. Results for the most energetic shocks (Md around 2) yield a source radius in the order of 100 m and stress drop around 10 bars, in agreement with most of the earthquakes that occurred during the 1982-1984 bradyseismic crises. For the August swarm we identify two clusters of similar earthquakes. Application of highresolution relative location techniques to these events allows for the recognition of two parallel alignments trending NE^SW. The relationship among source dimension and relative location evidences overlapping of sources. This may be interpreted in terms of either a heterogeneous stress field or a lubrication process acting over the fault surface. For a selected subset of the August events, we also analyze the splitting of the shear waves: results are indicative of wave propagation through a densely fractured medium characterized by a distribution of cracks oriented NE-SW. The pattern of faulting suggested by relative locations and shear-wave splitting is not consistent with the surface trace of NW^SE striking faults. However, a detailed mesostructural analysis carried out over the Solfatara area indicated the occurrence of two main crack systems striking NW-SE and NE-SW. This latter system shows a strike consistent with that derived from seismic evidence. Results from a stress analysis of the crack systems indicate that a fluid overpressure within the NW-SE-striking faults is able to form NE-SW cracks. We found that the pressure of fluids Pf required to activate the NW-SE faults is less than cHmin, while the Pf value required to open the NE-SW cracks is higher than cHmax. Our main conclusions are: (a) the Solfatara area is affected by two orthogonal fracture systems, and the fluid pathway during the 2000 crisis mainly occurred along the NNE-SSW/NE-SW-striking crack system; (b) the July seismicity is associated to the upward migration of a pressure front triggered by an excess of fluid pressure from a small-size magmatic intrusion; conversely, the August events are associated to the brittle readjustment of the inflated system occurring along some lubricated structures.
    Description: Published
    Description: 229-246
    Description: partially_open
    Keywords: Seismicity ; Hydrothermal fuids ; Fuid pressure ; Faults ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 12
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 13
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 14
    Publication Date: 2017-04-04
    Description: Data from two dense arrays of short-period seismometers are used to retrieve source locations of the explosion quakes at Stromboli volcano. Slowness vectors stimated at both arrays with the zero-lag cross-correlation technique constitute the experimental data set. A probabilistic approach based on a grid search spanning the volcano interior is used to calculate the probability of the source location. Results depict a shallow source, located beneath the crater area, at depths not greater than 500 m below the surface. Results are slightly different from, but comparable to, those obtained in a companion experiment carried out in the same time period using a broad-band seismometer network, which show a source shifted some hundreds of meters northwest of the crater area. The method is revealed to be effective and useful for future studies having the purpose of real-time tracking of the explosion quakes and tremor.
    Description: Published
    Description: 123-142
    Description: partially_open
    Keywords: Stromboli ; Array ; Explosion quake ; Source location ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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    Type: article
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  • 15
    Publication Date: 2017-04-04
    Description: Here, a new technique for the determination of dissolved He isotope ratios in ground-waters is presented. This method is based on the extraction and subsequent equilibrium of dissolved gases in an added ‘‘host’’ gas phase. Ultra pure N2 is placed in glass flasks (250 cc), containing water samples, that were hermetically sealed after their collection. After shaking in an ultrasonic bath for 10 min, an aliquot of the separated gas phase was removed from the flask for MS analysis. 3He/4He ratios are measured by using a modified double collector mass spectrometer (VG 5400-TFT). Helium and Ne concentrations are calculated by comparing the partial pressures of masses 4 and 20 of the samples with those of the air-standard measured by a quadrupole mass spectrometer (QMS;VG Quartz). Using He and Ne equilibrium partitioning coefficients, it is possible to calculate the amount of gas originally dissolved in the water. The technique was tested on both air-saturated waters (ASW) and thermal waters from Stromboli (Aeolian Islands, South Italy), the results of which confirmed good reproducibility (ffi5%) and accuracy (ffi3%) of the data. The method was then applied to three thermal water samples collected from the same volcanic area and the results compared with those of a fumarolic and a soil gas. The isotope ratios for dissolved He gave values of 4.06–4.23 Ra, which are significantly higher than those previously reported in the literature (3.0, 3.5 and 2.9 Ra) and that measured at the fumarole (3.09 Ra), suggesting a newer and higher isotopic signature for the volcanic system. The proposed method appears to be a useful tool in the determination of 3He/4He ratios in ground-water systems, especially when free gases are not available or are dangerous to collect.
    Description: Published
    Description: 665–673
    Description: partially_open
    Keywords: dissolved helium isotopes ; gas water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 16
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 17
    Publication Date: 2022-05-24
    Description: Many studies have assessed the strong influence of volcanic activity on the surrounding environment. This is particularly true for strong gas emitters such as Mt. Etna and Stromboli volcanoes. Among volcanic gases, fluorine compounds are potentially very harmful. Fluorine cycling through rainwater in the above volcanic areas was studied analysing more than 400 monthly bulk samples. Data indicate that only approximately 1% of fluorine emission through the plume is deposited on the two volcanic areas by meteoric precipitations. Although measured bulk rainwater fluorine fluxes are comparable to and sometimes higher than in heavily polluted areas, their influence on the surrounding vegetation is limited. Only annual crops, in fact, show some damage that could be an effect of fluorine deposition, indicating that long-living endemic plant species or varieties have developed some kind of resistance.
    Description: Published
    Description: 175–185
    Description: partially_open
    Keywords: Fluorine ; Rainwater chemistry ; Volcanic activity ; Mt. Etna ; Stromboli Island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
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