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  • Articles  (183)
  • Wiley-Blackwell  (183)
  • 1985-1989  (92)
  • 1980-1984  (91)
  • 1925-1929
  • 1987  (92)
  • 1983  (91)
  • Architecture, Civil Engineering, Surveying  (183)
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  • Articles  (183)
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  • 1985-1989  (92)
  • 1980-1984  (91)
  • 1925-1929
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 38-40 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 2
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 132-149 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: To assess the utility of a laboratory test for smoke and fume emission from overheated materials, six materials were heated to 500°C in larger amounts in three locations in an air-conditioned aircraft fuselage on the ground. Smoke, acidic or alkaline gases and carbon monoxide were monitored. It was shown that the laboratory test results could be a basis for predicting the smoke- and fume-emission behaviour of materials subjected to overheating, e. g. in aircraft in flight.
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  • 3
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 128-131 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Smoke toxicity test methods which determine only lethal toxicological potency under ‘worst case’ conditions do not satisfactorily address the critical issue of relative hazard, including time-to-escape and tenability limits resulting from the fire performance of materials under comparable conditions. Since threats to escape from a fire are largely time-dependent, toxic insults produced by burning materials should also be considered as rate processes. Assessment of time thresholds exhibited by burning materials under test conditions to effect performance impairment (incapacitation) of an animal model would appear to be more relevant than lethal toxicological potencies in estimating probability of successful escape from fires. A model is advanced in which intoxication rate thresholds for materials are obtained using a rodent exposure test method. Concentration-time curves, obtained from experimentally derived concentration-time-response surfaces, are the basis for estimating rate thresholds which are distinctively different for each material and which vary as a function of test conditions. it is this performance impairment response surface which is potentially a key to the modeling of toxic hazards of smoke in perspective with other hazards presented by fire.
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  • 4
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 157-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The term ‘bed’ has a variety of meanings in different countries. In central Europe, ‘bed’ is used for a bedstead with a mattress, a duvet and a pillow, Following clear definitions of the components of a ‘bed’ the author considers methods for testing the burning characteristics of beds and reports on experiences with model beds in fire tests.
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  • 5
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 150-156 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A device constructed and used to determine the flammability limits of pyrolysate-air mixtures as a function of percentage weight loss on pyrolysis has been employed to investigate the pyrolysate gases generated from poly (ethylene terephthalate) both in the presence and absence of chemical flame retardants. The chemicals tripropyl phosphate (TPP), dibromopropanol (DBP) and tris (2, 3 dibromopropyl) phosphate (TRIS) all influenced both the lower and upper flammability limits, with the largest effects being obtained when both phosphorus and bromine were present, followed by bromine only and then phosphorus only. The results indicate TPP has negligible condensed phase activity with only small gas phase action. DBP has no condensed phase activity but is a very active gas phase inhibitor. In contrast, TRIS has a detrimental effect upon the condensed phase reactions in that it is responsible for the formation of a more flammable pyrolysate gas mixture. Fortunately, its gas phase inhibition reaction is capable of reducing the overall flammability.
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  • 6
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 180-184 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Flammability tests are difficult because of the complexity of burning processes and of safety considerations. Experimental fires only give a partial view of the combustion process. Owing to the dynamic processes occurring in the flame, tests are very sensitive to external influences. Use, therefore, of flammability test methods should be made only with a clear understanding of what is being tested. Only officially standardized and recognized test methods should be sued.
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  • 7
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 173-179 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Polymeric Dielectrics are usually chemically complex, and it is attractive to establish techniques capable of providing a general assessment of material composition and thermal behaviour. Simultaneous thermal analysis (STA) is capable of providing such an assessment and complementing flammability studies. The use of STA in both of these roles is demonstrated for a number of polymer materials used in high-voltage cables. The materials investigated include various polyethylenes, ethylene-copolymers and filled polyvinylchloride formulations. Fingerprint identification of materials and the influence of chemical structure and additives on thermal behaviour is discussed. In particular the influence of antimony trioxide-chlorinated hydrocarbon flame retardants is examined. The application of STA information in guiding flammability studies is shown by example, and some potential routes for further development are also discussed.
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  • 8
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 185-192 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Detailed quantitative studies are reported on the kinetics of acetonitrile pyrolysis using an isothermal quartz tubular flow reactor at 720-1033 K and 1 atm. Pressure using flow rates, in nitrogen, of 2-200 ml min-1. The pyrolysis of several other nitriles (acrylonitrile, propionitrile, methacrylonitrile and benzonitrile) has also been investigated qualitatively by pyrolysis-gas chromatography.
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  • 9
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    Fire and Materials 7 (1983), S. 193-201 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire retardants improve reaction to fire characteristics such as ignitability and flame propagation. This paper presents the toxicological results of tests performed on eleven pairs of untreated and treated materials, including woods, synthetic materials and textiles (both natural and synthetic). It is shown that the effects of fire retardants on toxicity results can be variable. In addition, the problem of the use of toxicity results is discussed more generally.
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  • 10
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    Fire and Materials 7 (1983), S. 210-215 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A Preliminary study of the thermal degradation of wool fabric was carried out under a wide range of oxidative degradation conditions including flaming combustion. Product collection methods and analysis conditions were designed to minimize secondary reactions. The degradation products obtained included a variety of organic nitriles and heterocyclic compounds as well as the usual aromatic and oxygenated products. Variations in moisture content and fire retardant level in the wool had little effect on the organic volatiles produced form the fabrics.
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  • 11
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    Fire and Materials 7 (1983), S. 202-209 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There is widespread concern at present about the fire risk form the use of modern materials in upholstery and other domestic articles. One of the main characteristics of fires in dwellings which start with the ignition of textiles or furniture is that they have a high casualty rate compared with other kinds of domestic fires. Most of the casualties form such fires occur in fires which start in upholstery or bedding, often accidentally ignited by smokers' materials. Asphyxiations by smoke is the commonest cause of death in ‘textile’ and ‘upholstery’ fires. This paper presents relevant statistical information on fires in dwellings attended by local authority fire brigades which result from the ignition of upholstery, bedding, other textiles or furniture and the casualties which these fires cause.
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  • 12
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    Fire and Materials 7 (1983), S. 216-218 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 13
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    Fire and Materials 11 (1987) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
    ISSN: 0308-0501
    Keywords: Cone Calorimeter ; ignitability ; plastics ; radiant ignition ; upholstered furniture ; wood materials ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Cone Calorimeter is a new-generation instrument developed primarily for making rate of heat release measurements. This instrument, containing a uniform and well-characterized irradiance source, was also seen to be useful for making measurements of radiant ignition on materials. Data have now been collected for a wide range of illustrating the performance of similar materials in other apparatuses. Finally, for a selected material, Douglas fir particle board, a detailed comparison with an ignition model has been made.
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  • 15
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    Fire and Materials 11 (1987), S. 45-47 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This short note describes studies of the pyrolysis of methacrylonitrile over a wide range of temperatures under flowing nitrogen at atmospheric pressure. Hydrogen cyanide was not found to be a primary product, but several organic nitriles are formed which decompose at higher temperature (〉 1100 K) to produce hydrogen cyanide almost quantitatively.
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  • 16
    ISSN: 0308-0501
    Keywords: carbon monoxide ; combustion products ; fire retardants ; hydrogen cyanide ; literature reviews ; polyurethane foams ; rigid foams ; thermal decomposition ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The literature on rigid polyurethane foam has been reviewed with an emphasis on the gaseous products generated under various thermal decomposition conditions and the toxicity of those products. This review is limited to publications in English through 1984. Carbon monoxide (CO) and hydrogen cyanide (HCN) were the predominant toxicants found among more than a hundred other gaseous products. The generation of CO and HCN was found to increase with increasing combustion products from various rigid polyurethane foams. Lethality, incapacitation, physiological and biochemical parameters were employ as biological end points. In general, the combustion products generated from rigid polyurethane foam in the flaming mode appear from to be more toxic than those produced in the non-flaming mode. The LC50 values for 30-min exposures ranged from 10 to 17 mg l-1 in the flaming mode and were greater then 34 mg l-1 in the non-flaming mode. With the exception of one case, in which a reactive type phosphorus containing fire retardant was used, the addition of fire retardants to rigid polyurethane foams does not appear to generate unusual toxic combustion products.
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  • 17
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    Fire and Materials 11 (1987), S. 49-51 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes a survey which was undertaken to ascertain those features of house design and construction which were important to the survival of house in the ‘Ash Wednesday Bushfires’ of 16 February 1983. The Otway Ranges are of Victoria was chosen and 1153 house, with varying degrees of damage, were included in the survey. Results of a preliminary analysis of data collected are given, together with observations made concerning the so-called ‘exploding house’ phenomenon, the role of wind and the part that people played in house survival. Evidence for the ways that houses were ignited (i.e. by radiation, flame contact and wind-blown embers) was also gathered. The importance of these ignition modes is discussed and examples given. Preliminary observations on the rebuilding process are also given.
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  • 18
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    Fire and Materials 11 (1987), S. 53-53 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Fire and Materials 11 (1987) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
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    Fire and Materials 11 (1987), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 21
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    Fire and Materials 11 (1987), S. 95-104 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The equivalent fire exposure (EFE) is visualized as a quantifier of the destructive potential of real-world compartment fires in terms of the time to failure of building elements in standard test fires. Five methods of calculating the EFE are reviewed and compared in the light of some experimental data.
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  • 22
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    Fire and Materials 11 (1987), S. 89-93 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Structural residues of the original polymer remain in the char portion of degraded polymer depending on the temperature and duration of the thermal degradation and the temperature. Elementary analysis and infrared spectroscopy have been used for the identification of char residues.
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  • 23
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    Fire and Materials 11 (1987), S. 71-88 
    ISSN: 0308-0501
    Keywords: Combustion products ; literature reviews ; nylon ; pyrolysis, thermal decomposition ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The literature on polyamides was reviewed to determine the nature and extent of information available on these materials which are commonly used in consumer and industrial applications. This review was limited to aliphatic polyamides normally called nylon and excludes aromatic polyamides such as Nomex and bicomponent polymers consisting of nylon and other polymers. The review was further limited to those publications in English through June 1984. Typical pyrolysis products from a broad range of nylons do not appear to differ greatly. Many of the decomposition products detected in vacuum pyrolysis experiments appear as products of thermal degradation in inert and air atmospheres. In air, a general reduction in the quantities of heavier hydrocarbons is noted along with an increase in the production of CO, CO2, H2O, NH3, HCN and NOx. The toxicity of the thermal degradation products from various types of nylon has been evaluated by nine different protocols. Reported LC50 values range from 10.8 m l-1 to 61.9 mg l-1. Dyes apparently do not affect the materials' combustion products toxicity but an increase in the amount of backcoating on a nylon fabric increases toxicity. Time to death measurements show that volatile products from nylons are less toxic than those from rayons or cotton, while the blending of wool with nylon greatly increases the toxicity of the thermal decomposition products. In general, however, the overall toxicity of the thermal degradation products from nylon do not appear to be greatly different than those from many other polymeric materials. Large-scale test results are ambiguous, and it is difficult to interpret the results in terms of a single component in a multicomponent system.
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  • 24
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    Fire and Materials 11 (1987) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 25
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    Fire and Materials 11 (1987), S. 55-70 
    ISSN: 0308-0501
    Keywords: Combustion products ; literature reviews ; polyethylenes ; thermal decomposition ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The literature on polyethylenes has been reviewed with an emphasis on the identification of gaseous products generated under various thermal decomposition conditions and the toxicity of those products. This review is limited to publications in English through 1984. The analytical chemical studies of the thermal decomposition products generated under vacuum, inert and oxidative experimental conditions are described. In oxidative atmosphere, which most closely simulate real fire conditions, carbon monoxide (CO) was found to be the predominant toxicant. Acrolein was another toxicant often noted in these reviewed studies. More acrolein was generated under non-flaming than under flaming conditions. Results from seven different test procedures were considered in assessing the acute inhalation toxicity of combustion products from various polyethylene formulations. The combustion products generated from the polyethylenes studied in the non-flaming mode appeared to be slightly more toxic than those produced in the flaming mode. In the non-flaming mode the LC50 values ranged from 5 to 75 mg l-1. In the flaming mode the LC50 values ranged from 31 to 51 mg l-1. The toxicity of the degradation products of polyethylenes appears to be similar to that found for other common materials designed for the same end uses.
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  • 26
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    Fire and Materials 11 (1987), S. 105-108 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A method has been developed enabling comparison of polymeric Materials on the basis of the heat evolved during combustion. The calculated heat index yields information on the heat capacity of the material compared with cellulose as a standard material.
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  • 27
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    Fire and Materials 11 (1987), S. 109-130 
    ISSN: 0308-0501
    Keywords: combustion products ; fire data ; literature reviews ; polystyrene ; pyrolysis products ; test methods ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The current English literature through 1984 on the products of pyrolysis and combustion from polystyrenes and the toxicity of those products is reviewed. Among 57 compounds detected by chemical analyses of the thermal decomposition products produced under various atmospheric conditions (vacuum, inert and oxidative), the main volatile component is the styrene monomer, Evidence is provided that the mass fraction of styrene increases with furnace temperatures at least through 500°C. At 800°C and above, the concentration of styrene decreases. In oxidative atmospheres, carbon monoxide (CO), carbon dioxide (CO2) and oxidative hydrocarbons are formed. The concentrations of CO and CO2 are a function of temperature and combustion conditions, i.e. greater amounts are produced in the flaming than in the non-flaming mode. Eleven different test procedures were used to evaluate the toxicity of the pyrolysis and combustion atmospheres of polystyrenes. The more toxic environments produced under flaming conditions appear to be mainly attributed to CO and CO2 but rather to some other toxicant, probably the styrene monomer. When compared with other common materials used in buildings and residences, polystyrenes, in general, are among the least toxic.
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  • 28
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    Fire and Materials 11 (1987), S. 159-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Combustible and toxic properties greatly influence the application of materials in shipbuilding. These materials, especially plastics, create a serious toxic hazard during fire. Under fire conditions they decompose thermally, giving off considerable amounts of smoke and volatile toxic substances which cause a serious hazard to people overcome by fire inside a compartment.1-3Lethal poisoning by the thermal degradation products of plastics has attracted the attention of many investigators to toxic hazards during a fire.1,4 Underwater systems create, in particular, a serious fire hazard. Fire in a decompression chamber spreads in a different way to land fires and usually causes the death of the crew and complete destruction of equipment in the chamber. Theoretically, complete fire protection in a chamber could be achieved by the total elemination of combustible materials and their replacement by incombustible ones. However, from a practical point of view this is impossible. The general principles of materials selection used in underwater systems are defined by Det Norske Veritas.5 Unfortunately, these do not describe the methods of testing materials nor the criteria of materials selection. There is also a lack of information in the literature on toxic hazards under elevated pressures. This problem has been studied in detail with oxygen-enriched atmospheres in aerospace programmes,6 but because those studies are classified there is only fragmentary information in the literature.
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  • 29
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    Fire and Materials 11 (1987), S. 131-142 
    ISSN: 0308-0501
    Keywords: carbon monoxide ; combustion products ; hydrochloric acid ; large-scale fire tests ; polyvinyl chloride ; pyrolysis products ; small-scale fire tests ; toxicity ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Poly(vinyl chlorides) (PVC) constitute a major class of synthetic plastics, Many surveys of the voluminous literature have been performed. This report reviews the literature published in English from 1969 through 1984 and endeavors to be more interpretive than comprehensive. PVC compounds, in general, are among the more fire resistant common organic polymers, natural or synthetic. The major products of thermal decomposition include hydrogen chloride, benzene and unsaturated hydrocarbons. In the presence of oxygen, carbon monoxide, carbon dioxide and water are included among the common combustion products. The main toxic products from PVC fires are hydrogen chloride (a sensory and pulmonary irritant) and carbon monoxide (an asphyxiant). The LC50 value calculated for a series of natural and synthetic materials thermally decomposed according to the NBS toxicity test method ranged from 0.045 to 57 mg l-1 in the flaming mode and from 0.045 to 〉 40 mg l-1 in the non-flaming mode. The LC50 results for a PVC resin decomposed under the same conditions were 17 mg l-1 in the flaming mode and 20 mg l-1 in the non-flaming mode. These results indicate that PVC decomposition products are not extremely toxic when compared with those from other common building materials. When the combustion toxicity (based on their HCI content) of PVC materials in compared with pure HCI experiments, it appears that much of the post-exposure toxicity can be explained by the HCI that is generated.
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    Fire and Materials 11 (1987) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 31
    ISSN: 0308-0501
    Keywords: ABS ; plastics ; chemistry ; combustion products ; literature reviews ; nylon ; polyester ; polyethylene ; polystyrene ; polyvinyl chloride ; pyrolysis products ; polyurethane foams ; rigid foams ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of literature reviews was undertaken by the National Bureau of Standards to examine the toxicity and chemistry of the effluents produced when seven plastics were decomposed under various thermal and atmospheric condition. These plastics are: acrylonitrile-butadiene-styrenes, nylons, polyesters, polyethylenes, polystyrenes, poly(vinyl chlorides) and rigid polyurethane foams. The English-language literature on each of these was reviewed and published as a separate report of the National Bureau of Standards. Over 400 different thermal decomposition products, many common to more than one plastic, were identified. The toxicity of most of these individual products is products, many common to more than one plastic, were identified. The toxicity of most of these individual products is unknown and an assessment of the toxicity of the multitude of possible combinations is not feasible at this time. Therefore a variety of bioassay toxicity protocols have been used to assess the toxicity of the gaseous atmospheres generated by the thermal decomposition of these plastics. In general, these seven plastics did not produce unusually or extremely toxic pyrolysis or combustion products when compared with those of other synthetic or natural materials. In a few cases involving additives, toxic products of concern were produced.
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  • 32
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    Fire and Materials 11 (1987), S. 163-172 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Piloted ignition of six common thermoplastics has been studied by exposing horizontal samples (65 times; 65 times; 6 mm thick) to irradiance levels in the range 10-40 kw m-2. Fine thermocouples were attached to the exposed face and allowed the surface temperature to be monitored continuously. Times to sustained ignition from a small pilot flame and the corresponding surface temperature were recorded. Within experimental error, ignition temperatures showed no systematic dependence on surface area when this was reduced to ca 20 mm square. Times to ignition were dependent not only on radiant intensity but also on the spectral characteristics of the source.
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    Fire and Materials 11 (1987), S. 173-178 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A simple model for predicting as concentrations, temperature and heat release rate in a room fire was developed. The CO, CO2 yield rates and O2 yield rates and O2 depletion rate were calculated using this model for wood fuel. The calculated values were compared with the experimental ones and a fairly good accuracy was obtained. As this model can apply to any kind of fuel by replacing the assumption for the fuel pyrolysis, it may be useful for evaluating toxic hazards in a room fire.
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    Fire and Materials 11 (1987), S. 179-190 
    ISSN: 0308-0501
    Keywords: compartment fires ; fire growth ; flashover ; full-scale tests ; interior finish ; physical models ; room fires ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Quarter-scale tests of ten full-scale room fire tests were conducted by using an existing scaling technique developed at the National Bureau of Standards. Test results confirmed earlier studies which showed that, under constant fire exposure conditions, quarter-scale room testing ranked interior finish materials in the same order as did full-scale tests based on their times to achieve room flashover. In general, quarter-scale tests were less severe and took longer to reach peak room fire buildup because of a lower convective and radiative heat transfer in the quarter-scale room. These tests also generated more CO per unit mass of material and experienced lower combustion efficiencies than did their corresponding full-scale tests.
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    Fire and Materials 11 (1987), S. 201-203 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 11 (1987), S. 191-194 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Laboratory tests demonstrated that the intumescence resulting from application of some proprietary flame-retardant paint and coating systems to timber planks could reduce char formation in the planks by as much as 70% during the first 30 min of exposure to ASTM E-19 fire conditions. Applications of these coating systems to the exposed surfaces of planks used in construction of heavy timber building assemblies should increase the fire resistance of these components by at least 30 min. This would represent a significant increase in the fire resistance of heavy timber roof systems and could extend the use of this type of construction system to many of the non-residential buildings for which building code authorities presently require fire resistance ratings greater than 1 h.
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    Fire and Materials 11 (1987), S. 195-199 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Having characterized the current classification of building materials in Scandinavia the use of the International Standards Organization ignitability test for classifying coverings, linings and materials is discussed. Further evidence for the assumption of a linear function for 1/tig (where tig is the time for sustained surface ignition) versus irradiance was gained for a number of materials, mainly wood-based. This has been utilized in forecasting the ignitability behaviour in the new test by correlation of classes. Through definition of two borderline segments a simple table giving proposed criteria for tig is obtained.
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    Fire and Materials 11 (1987), S. 205-205 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 11 (1987), S. 206-206 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 40
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    Fire and Materials 7 (1983) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 7 (1983), S. 1-24 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: This review concerns the mathematical modeling of fire phenomena. The fire is treated as a head and mass source driving a fluid flow process. Combustion is not included. It deals in detail with the field modeling approach incorporating the effects of turbulence, strong buoyancy and variable density on the transport of momentum, heat and mass. For the sake of simplicity, other effects such as those due to the interactions of the above mechanisms with the wall, radiation, etc., which may be crucial to the dynamics of the fire phenomenon, are not dealt with in this review. These effects will be the subject of future work.
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    Fire and Materials 7 (1983), S. 25-31 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Studies have been made of the influence on smoke generation from polystyrene of the incorporation of a number of apparently inert solids, the smoke-producing tendency being expressed in terms of the maximum specific optical density of smoke per unit weight of polymer consumed. Of the compounds investigated, by far the most efficient smoke suppressant is pyrogenic silica, the effect of which is, over a wide range, directly proportional to the total surface area of the material introduced. Examination of partially burned polystyrene-pyrogenic silica composites reveals the presence at the surface of a hard rigid skin, which is not observer with polystyrene alone of with polymer samples containing other additives. The formation of a protective skin is also indicated by the kinetics of forced burning of these composites where the weight loss is a linear function of log time and by measurements of the rate of change of thickness of polymer samples during combustion. Thermogravimetric experiments in which polystyrene and pyrogenic silica are heated in contact with one another show that the silica encourages the formation of a carbon residue from the polymer. A mechanism of skin production is proposed which involves the build-up of layers of tangential spherical silica particles cemented together by cross-linked polystyrene.
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    Fire and Materials 7 (1983), S. 32-37 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Raman scattering is a possible technique for analysing gas mixtures. In the work here described Raman scattering was used for detection of gases extracted from different model fires, where wood, polymethylmetachrylate (PMMA) and polystyrene were used as test materials. Raman spectra of gas samples from differently ventilated model fires are presented as well as the variation of O2, CO2 and CO concentrations as a function of time with an effective time constant of less than 5 s. The sensitivity of the experimental set-up was estimated to be about 1000 ppm, but suggestions are given how to reach a detection limit of about 1 ppm. The feasibility of the technique and various ways of improving it are briefly discussed.
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    Fire and Materials 7 (1983) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 7 (1983), S. 49-61 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fourteen mathematical models of post-flashover compartment fires are classified on the basis of fourteen principal modeling aspects. Expressions are presented for the potential of fire to spread by destruction and convection. The assessment of the fire resistance requirements for the compartment boundaries is discussed and measures to counter the potential of fires to spread by convection are outlined.
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    Fire and Materials 7 (1983), S. 41-48 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A study has been made of the effect of molybdenum trioxide on the thermal degradation of a series of chlorinated and brominated polyester thermosets. Like antimony oxide, it showed flame retardant activity in all the halogenated polyesters. It was shown to affect the char yield, and the temperature and weight loss of each degradation step. X-Ray diffraction studies of the degraded dibromoneopentyl glycol polyesters showed that in air a near-quantitative yield of molybdenum trioxide was present above 550 °C. Some dioxide was present before the final char oxidation step occurred. In a nitrogen atmoshphere the trioxide was reduced to the dioxide at first, but this finally reacted to give the carbide at around 900 °C. Infrared spectroscopy showed that inclusion of the molybdenum trioxide resulted in structural changes in the high-temperature polyester residues which were more prominent when bromine was present. Elemental analysis of the residues indicated that the presence of the trioxide in the brominated polyesters accelerated the release of bromine at high temperatures and confirmed its char-promoting tendencies.
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    Fire and Materials 7 (1983), S. 62-66 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The conversion of fuel-N species to NOx in diffusion flames has been studied by adding acetonitrile to the fuel flow for a methane-Oxygen-argon diffusion flame burning in excess oxygen. It is shown that the conversion is significantly lower than that obtained in a ‘corresponding’ pre-mixed flame, although the observed concentrations of NOx are still much higher than the appropriate thermodynamic equilibrium concentrations. The effect of initial concentration of acetonitrile, flame temperature and amount of excess oxygen on the conversion can all be explained in terms of the basic structure of a diffusion flame. This enables molecular nitrogen to be formed in the reducing atmosphere which exists on the fuel side of the flame through reaction of cyanide radicals with nitric oxide. The latter diffuses back from the oxygen side of the flame where it is formed, but the overall result is that a proportion of the fuel-N is converted to molecular nitrogen before it can be converted to nitric oxide.
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    Fire and Materials 7 (1983), S. 73-78 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Two models of creep, one proposed by Harmathy1, the other empirical, have been fitted to published measurements of creep in seven steels. The data have been selected so as to cover the range needed for predicting the survival of protected steel or reinforced concrete buildings exposed to fire.
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    Fire and Materials 7 (1983), S. 67-72 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A study of fire deaths in the Glasgow area has been extended to the rest of the United Kingdom in order to assess the applicability of the conclusions reached in the Glasgow study to the whole country. With assistance from pathologists in a number of other areas, 71 cases were included in the study, covering both pathology and toxicology of the deaths where possible. In both the Glasgow and UK studies, most of the fire deaths occurred in dwelling-house fires. These and other demographic characteristics were in agreement with national fire statistics. The principal features of pathology in this study were burns (79 per cent of cases), respiratory system injury (72 per cent of cases) and soot deposition in the respiratory tract (96 per cent of cases), and these reflected a similar incidence in Glasgow study. Carbon monoxide was considered to be the cause of death in 51 per cent of the deaths in this study and to be implicated in the death of 37 per cent of the other cases (54 per cent and 31 per cent respectively in Glasgow). Cyanide was estimated to be a significant factor in 33 per cent of the deaths in the UK study (24 per cent in Glasgow). Alcoholic intoxication was found to be a significant additional factor in Glasgow but was much less prominent in the other areas of the UK. It concluded that, with the exception of alcohol, the results of the Glasgow study are valid for the UK as a whole.
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    Fire and Materials 7 (1983), S. 96-97 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 7 (1983), S. 98-99 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 7 (1983), S. 89-95 
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    Notes: This paper reviews the current literature on the behaviour of thermoset polymers under fire conditions. These polymers are important and widely used materials. They are generally infusible and insoluble, and consist, on the molecular scale, of extensive cross-linked networks rather than discrete macromolecules. Materials in this class include phenol-formaldehydes, epoxides, cross-linked polyester, amino resins and polyurethanes. As the use of plastics generally has grown, so there have been changes in the conditions prevailing in modern fires, and such changes are described, together with the potential fire hazards arising from the varying uses of the individual thermosets. Subsequently, literature on the pyrolytic and combustion characteristics of these materials is reviewed in order to assess their probable behaviour in real fires. Finally, existing approaches towards improving their fire behaviour are described.
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    Fire and Materials 7 (1983), S. 79-88 
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    Notes: There are two major fire processes, an understanding of which is essential for effective fire safety design: (1) the conditions under which a combustible material may become involved in flaming combustion, and (2) the rate at which such a material, once involved, will provide an output of heat, smoke, toxic gases, etc., which can endanger people and property. The first process may be regarded as covering both ignition and spread of fire on materials; its complement is the way in which fire may become extinguished. It is necessary for such processes to bring in a characteristic of the basic combustion reaction which, directly or indirectly, expresses the reactivity of the combustion process. Thus pilot ignition is usually associated with an approximate surface fuel temperature. More basically, it is associated with a critical flow rate of volatiles and a critical heat loss from the flame, the latter being influenced by ambient oxygen and temperatures conditions as well as heat lost and gained by the fuel itself. The most important factor governing the production of dangerous product is the rate at which volatiles first (fuel controlled fires) and later air (air controlled fires) are fed into the flames. The reactivity is of less importance, although it may be one of the factors which control combustion efficiency. In general, the more efficient is the combustion the more heat is produced, but the less smoke and toxic gases are produced. Some of the main advances in the above areas are reviewed in this paper.
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    Fire and Materials 7 (1983), S. 99-99 
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    Fire and Materials 7 (1983), S. 101-110 
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    Notes: The smoke propensity of plastics as measured in the NBS Smoke Chamber method has been rationalized in terms of the influence of specimen thickness and resolved in a relation between mass optical density (MOD) and mass loss, which gives two parameters for characterizing behaviour, a maximum MOD for thin specimens and an asymptotic MOD for thicker ones. Data have been obtained for unplasticized piolyvinylchloride formulations and compared to that obtained by the Arapahoe Smoke Chamber and the Australian Standard method (AS 1530 Part 3). Although correlation coefficients between the methods were generally poor, the same formulations were ranked as the best performers in each method and the improvement over a standard formulation was potentially important in terms of wider acceptance under Australian building regulations.
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    Fire and Materials 7 (1983), S. i 
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    Fire and Materials 7 (1983), S. 163-168 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A test chamber for performing complete investigation of the dangerous effects of thermal degradation products of polymeric materials has been designed. The tow-chamber system with separated combustion chamber and smoke chamber has a steep temperature gradient between both chambers and enables continuous analysis of combustion products of the tested polymeric material for carbon monoxide and carbon dioxide to be performed, to monitor the oxygen content in the chamber during testing and to perform tests of biological toxicity on mice as test animals. The function of the test chamber was verified on combustion of polyethylene, polypropylene, polystyrene and polyamide samples.
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    Fire and Materials 7 (1983), S. 169-172 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A chamber has been designed which allows total assessment of products formed during the thermal stressing of polymer material samples. The chamber is of oval shape and creates an infinite track for the movement of products formed in the course of the thermal degradation process. It allows the complete analysis of the products to be carried out to monitor the contents of the most important of them, to determine the oxygen content, to measure the optical density of smoke and to measure the temperature inside the chamber in the course of the experiment. The chamber was used for testing the combustion products of polyethylene, polypropylene, polystyrene and polyamide.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 117-127 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A coupled finite element-rigid block model for the transient analysis of caverns in jointed media is presented. This coupling permits the modelling of lined openings in a jointed rock mass as well as the propagation of stress waves to the cavern. Both the finite element and the rigid block algorithms employ explicit time integration; an efficient, stable scheme is developed for coupling the two algorithms. Two numerical examples are given: one is a simple validation, the second is a representation of a lined cavern in a sparsely jointed medium.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983) 
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    Keywords: Engineering ; Engineering General
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  • 62
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 385-393 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. ii 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 457-468 
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    Notes: This paper sets forth the theoretical background and basic numerical expressions for the incorporation of elastic-plastic constitutive equations for ductile rock into a finite element computer code. The derivation of an expression for the total strain rate is performed both for a total stress formulation and for a formulation that employs the concept of effective stress for inelastic behaviour. Specific expressions for the incremental strain rate are presented for the case of a porous material having a quadratic initial yield surface and observing the associated flow rule with a special hardening law for subsequent plastic deformation. A final section of the paper summarizes the expressions required to insert the quadratic yield surface model into a finite element code.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 1-15 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
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    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A numerical procedure is described for the analysis of vertical deformation of smooth, rigid foundations of arbitrary shape on homogeneous and layered soil media. The contact area at the interface of the foundation and soil medium is approximated by square subdivisions. The response of the system is then obtained from the superposition of the influence of the individual subdivisions. The flexibility influence coefficients are based on equivalent smooth, rigid circular areas with the same contact area as the square subdivisions. For foundations on a homogeneous, isotropic elastic half-space, the flexibility coefficients are given analytically by the integrated forms of the Boussinesq's solution. For a layered soil medium, the flexibility coefficients are determined from an axisymmetric finite element analysis which is essentially two dimensional. Thus, there is no necessity for a full three-dimensional finite element analysis. Comparison with solutions obtained using the integral transform technique for smooth, rigid rectangular foundations on a homogeneous, isotropic elastic half-space shows good agreement. Parametric solutions are presented for the response of rectangular foundations on some ‘typical’ soil profiles. The use of a simplified method to estimate the settlement of rectangular foundations on a layered soil medium by superposing solutions for homogeneous, elastic strata is discussed.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 61-77 
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    Keywords: Engineering ; Engineering General
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    Notes: The complete solution is presented for the transient effects of pumping fluid from a point sink embedded in a saturated, porous elastic half-space. It is assumed that the medium is homogeneous and isotropic with respect to its elastic properties and homogeneous but anisotropic with respect to the flow of pore fluid. The soil skeleton is modelled as a linear elastic material obeying Hooke's law, while the pore fluid is assumed to be incompressible with its flow governed by Darcy's law. The solution has been evaluated for a particular value of Poisson's ratio of the solid skeleton, i.e. 0.25, and the results have been presented graphically in the form of isochrones of excess pore pressure and surface profile for the half-space. The solutions presented may have application in practical problems such as dewatering operations in compressible soil and rock masses.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 115-129 
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    Keywords: Engineering ; Engineering General
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    Notes: To facilitate the practical numerical analysis of tunnel structures by means of the finite element method in the case of viscoplastic properties of the rock mass and viscoelastic properties of the shotcrete, this method is coupled to boundary elements. In this way, the unchanged properties of the boundary element region provide enormous savings in computing time. In order to improve the numerical stability of such calculations, a variable time-step analysis was employed for each time step with an iterative correction method. Characteristic values are obtained from measured values by back-analysis.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 143-153 
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    Keywords: Engineering ; Engineering General
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    Notes: The heat extraction through a geothermal reservoir on an oblique fault plane in the earth's crust is considered. The fault could be modelled mechanically as a frictional contact interface of two elastic bodies. The heat is recovered by circulating fluid through the reservoir, and then the surface of the reservoir is cooled by the fluid. The analysis is based on the two-dimensional theory of quasi-static thermoelasticity. It is concluded from numerical calculations that a geothermal reservoir can be created on an oblique fault plane, and the opened region, i.e. the fluid-filled region, increases gradually with time during the heat extraction. Also discussed are the effects of the fluid pressure and the coefficient of friction on the behaviour of the reservoir.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 283-305 
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    Keywords: Engineering ; Engineering General
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    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A finite element, variable mesh analysis of unconfined steady-state seepage problems is presented based on a nonlinear programming algorithm. It is shown that the minimization of an objective function which merely represents a measure of the total flux leaving or entering the mesh at the free surface nodes (except those that belong also to pervious boundaries) does not permit a unique definition of the free surface geometry. This problem, which is apparently related to the numerical instabilities often met when using variable mesh approaches, can be eliminated by adding to the objective function a term representing a sort of overall ‘regularity’ condition for the shape of the free surface. The modified solution procedure turns out to be stable and able to provide meaningful results for practical problems even when rather coarse meshes are adopted.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. i 
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 381-390 
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    Notes: Hydraulic and mechanical properties of rock masses are largely dependent upon the distribution and variation of fracture areas. Consequently, it is essential to develop good models for analysing the spatial geometric characteristics of fracture fields. The latter, however, may be ascertained only by measuring open cuts or boreholes. The most important factor from the analysis of areas is to be able to determine spatial networks. Without an exhaustive and expensive inventory, the classical methods involving measurements of dip and strike do not provide either a correct estimation of fracture orientations in space, or a good estimation of their distribution.At present, automatic analysis of linear traces on large plane areas is used by several authors1,2 and the field strike and dip measurements are applied only for verification purposes. This method of computing spatial networks is especially suitable because of the nature of data so obtained, since it permits various simulations on computed networks. It is based upon classical methods of vector geometry that involve a measurements data matrix and provide a means of solving a double system of equations. Results are the directional spatial fracture densities. The object of this paper is to define the geometric parameters of this problem and the computation method, to present an example and, finally, to conclude with critical comments supported by certain proposals for a variety of applications.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 503-520 
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    Keywords: Engineering ; Engineering General
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    Notes: The constitutive model of sands is proposed to describe the characteristics of plastic behaviour for cyclic loadings. A non-associated flow rule is used and both yield function and plastic potential are generalized forms of the Modified Cam clay model. The hardening parameter is represented by the plastic work related to different portions of volumetric and deviatoric changes. The boundary surface is employed to describe the plastic strain within the yield surface. The directional independency of yield condition in triaxial compression and extension tests is extended to that in general stress states. Several drained and undrained cyclic tests are predicted and the comparison is made with experimental results. The proposed model is capable of representing the monotonic and cyclic behaviours of sands with reasonable accuracy. The simulation is performed for both included and excluded membrane penetration effects and it is suggested that the membrane penetration causes the significant influences on the results of undrained cyclic tests.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 521-542 
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    Notes: A review of the literature indicates that the elastic behaviour of granular materials is isotropic and that Poissony's ratio is constant, whereas Young's Modulus, the bulk modulus and the shear modulus vary with the mean normal stress and the deviatoric stress. A nonlinear, isotropic model for the elastic behaviour is developed on the basis of theoretical considerations involving the principle of conservation of energy. Energy is therefore neither generated not dissipated in closed-loop stress paths or in closed-loop strain paths. The framework for the model consists of Hooke's law, in which Poission's ratio is constant and Young's modulus is expressed as a power function invlving the first invariat of the stress tensor and the second invariant of the deviatoric stress tensor. The characteristics of the model are described, and the accuracy is evaluated by comparison with experimental results from triaxial tests and three-dimensional cubical triaxial tests with a variety of stress paths. Parameter determination from unloading-reloading cycles in conventional triaxial compression tests is demonstrated, typical parameter values are given for granular materials and extension of the model to soils with effective cohesion is described.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 551-551 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987) 
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 603-620 
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    Notes: The general yield function in the hierarchical approach for constitutive modelling of materials is used with Perzyna's theory to characterize viscoplastic behaviour of geologic materials: a sand and rock salt. Particular attention is given to determination of the constants from laboratory quasistatic or short term, and creep tests. The proposed model is verified with respect to observed laboratory response of the sand and salt. It is implemented in a non-linear finite element procedure and applied to analyse time-dependent behaviour of a cavity in the rock salt.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 621-638 
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    Keywords: Engineering ; Engineering General
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    Notes: A numerical method of analysis based on elasticity theory is presented for the analysis of axially and laterally loaded pile groups embedded in nonhomogeneous soils. The problem is decomposed into two systems, namely the group piles acted upon by external applied loads and pile-soil interaction forces, and a layered soil continuum acted upon by a system of pile-soil interaction forces at the imaginary positions of the piles. The group piles are discretized into discrete elements while the nonhomogeneous soil behaviour is determined from an economically viable finite element procedure. The load-deformation relationship of the pile group system is then determined by considering the equilibrium of the pile-soil interaction forces, and the compatibility of the pile and soil displacements. The influence of soil nonlinearity can be studied by limiting the soil forces at the pile-soil interface, and redistributing the ‘excess forces’ by an ‘initial stress’ process popular in elasto-plastic finite element analysis. The solutions from this approach are compared with some available published solutions for single piles and pile groups in homogeneous and nonhomogeneous soils. A limited number of field tests on pile groups are studied, and show that, in general, the computed response compares favourably with the field measurements.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 665-666 
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 1-7 
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    Notes: The Finite Element Method is frequently used to analyse problems involving an ‘infinite domain’. A typical problem is an underground excavation in prestressed infinite medium in either tunnelling or mining operations or a foundation in an infinite half space.This paper examines the implications of mesh truncation on the accuracy of the accuracy of the solution.At the same time, a more economical and accurate method of analysing these problems using special ‘infinite domain’ Finite Elements is presented.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 57-74 
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    Keywords: Engineering ; Engineering General
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    Notes: The problem of an impervious dam on a poro-elastic foundation is solved analytically. Using the known solution for the fluid pressure in the pores, the elastostatic stress field in the solid skeleton is analysed by reduction to two simpler problems whose solutions can be obtained by complex variable techniques. For welded contact, the rotation of the dam base is then found along with the stresses and strains in the ground. Modification for finite friction along the base is outlined in the appendix.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 269-272 
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    Notes: This paper corrects an impression, created by a recent contribution to the International Journal for Numerical and Analytical Methods in Geomechanics, that the mathematical equivalence of the direct and indirect boundary element methods for the diffusion equation implies that their respective computational needs with regard to the body integral terms are equal. It is shown that in a stepwise implementation of the numerical procedure for solving a finite body problem, indirect methods requirean integration over an infinite region and not merely over the body as is the case for the direct version.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 286-286 
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 33-50 
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    Notes: The upper bound method of limit analysis of perfect plasticity is applied to stability problems of slopes with a general nonlinear failure criterion. Based on the upper bound method, a numerical procedure is suggested, which converts the complex system of differential equations to an initial value problem. Using this numerical procedure, an effective numerical method, called the inverse method, suitable for the solution of slope stability problems in soil mechanics with a general nonlinear failure criterion, is presented. A general nonlinear failure criterion for soils is also suggested, from which the effects of nonlinear failure parameters on the stability of slopes are discussed.
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 363-380 
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    Notes: A method is presented for obtaining the consolidation behaviour of a layered soil subjected to strip, circular, or rectangular surface loadings, or subjected to fluid withdrawal due to pumping. The solution method involves applying a Fourier or Hankel transform to the field quantities along with a Laplace transformation. The effect of the Fourier or Hankel transform is to reduce a two- or three-dimensional problem or one involving axial symmetry, to one involving only a single spatial dimension. In cases where the soil is horizontally layered, this has great advantages over conventional methods, such as finite element or finite difference methods, since very little computer storage and data preparation time is required. Solution of the time dependent problem is achieved by applying a Laplace transformation to the field variables, obtaining solutions in Laplace transform space, and then numerically inverting the transformed solutions to obtain the real time behaviour. This eliminates the need for ‘marching type’ schemes where a solution is found from one at a previous time. By direct inversion of the Laplace transform, a solution may be obtained directly at any given time.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 39-55 
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    Keywords: Engineering ; Engineering General
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    Notes: The theory of consolidation is extended to partly saturated clay soils, and formulated for finite element analyses. This formulation couples the effects of both stress and flow. It takes account of variations of this permeability of the soil and compressibility of the pore fluid with changes in void ratio, and the non-linear stress-strain behaviour of soil. The Cam Clay model is revised to model the stress-strain behaviour of compacted soils. The compressibility of pore fluid is derived using Boyle's Law and Henry's Law, taking into account the effect of surface tension. An empirical equation is developed for permeability of pore fluid. An example of settlement of a footing on partly saturated soil is described and discussed.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983) 
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 245-268 
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    Notes: Using the correspondence principle of viscoelasticity the Displacement Discontinuity Method has been extended to model the rate-dependent behaviour of a jointed rock mass. The intact rock is assumed to behave as a linear viscoelastic material while, in general, a non-linear rate-dependent behaviour of the rock joints can be accounted for. A number of numerical examples are presented which illustrate the accuracy and potential of the method for analysing complex engineering problems.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 273-281 
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    Notes: In many cases the analysis of the consolidation of axi-symmetric bodies subjected to non axi-symmetric loading may be carried out without recourse to a full three-dimensional treatment. Advantage may be taken of the axi-symmetric nature of the body and field quantities such as displacement and pore pressure can be given a Fourier representation. The problem is then reduced from one in three spatial dimensions (r, θ, z) and the time domain to one in two spatial dimensions (r, z) and the time domain.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. i 
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    Keywords: Engineering ; Engineering General
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 337-356 
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    Notes: A theory describing plastic deformation of granular (purely frictional) materials is presented. The theory is developed from postulates for energy dissipation and for the mode of plastic deformation. The postulates are based on some restrictions for the properties of granular materials and on a frictional analogy. A distinction is made between the description of plastic behaviour of a locally homogeneous and a locally non-homogeneous material. An interpretation of the deformation process is presented which implies that the theory accounts for the changes in the density of some local non-homogeneities underlying a plastic hardening effect. Based on this interpretation, an analogy between elastic-plastic behaviour of granular materials and frictional, sliding of two solid bodies is assumed. In the general case, the presented constitutive equations describe two hardening (softening) effects and are capable of describing both initial and advanced plastic deformations. A special, simplest form of the constitutive equations is examined in detail and a yield condition and a stress-strain relationship are derived. An example of elastic-plastic stress-strain-strength behaviour is presented for the cuboidal loading conditions.
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 395-395 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. ii 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
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  • 93
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 435-455 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The consolidation problem in a plane strain porous elastic medium is treated by adopting a consistent formulation of the finite element model. To this purpose, the fluid-phase behaviour is modelled in static terms through a piecewise linear description of the pore pressure field and the behaviour of the two-phase medium is consistently modelled through rigorously equilibrated piec̰ewise linear stress distribution.Incompressibility of the pore fluid and of the skeleton grains is assumed, as is linear elastic behaviour of the solid phase.After a compact description of the model, the governing equations for the continuum problem are recalled and the solution system for the discretized problem is obtained following Galerkin's method of weighted residuals. Some examples are finally illustrated, in order to assess the reliability of the approach and to introduce possible comparisons with other methods.
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  • 94
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    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 371-384 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A simple friction-contact interface element is introduced which simulates frictional slippage, separation, and re-bonding of two bodies initially mating at a common interface and subsequently deforming with an arbitrary static loading schedule. Constraint equations between initially mating node pairs and the general principle of virtual work are used to formulate the interface element for a finite element solution procedure. Some advantages of the interface element include; easy implementation intostandard finite element programs, direct determination of interface forces without round-off problems, and the generality afforded by the virtual work formulation to include other non-conservative models in the system.The application of the interface element to an idealized buried culvert problem illustrates that the model behaves properly. A second application, for a long-span culvert installation with incremental soil loading, demonstrates the importance of modelling slippage at the culvert-soil interface in order to conform with experimental observations.
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  • 95
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 221-240 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: In this paper, liquefaction potential of loose sand deposit subjected to an earthquake loading is evaluated. The analysis is performed by using a finite element technique incorporating the equations of dynamics of saturated porous elastoplastic media. The soil response is modelled by an anisotropic hardening rule, similar to that as proposed by Poorooshasb and Pietruszczak.1 The concept is based on the theory of bounding surface plasticity incorporating a non-associated flow rule and the idea of reflected plastic potential. The present paper provides a modified formulation to that discussed in Reference 1. Modifications are aimed at simplifying the concept for numerical implementations.
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  • 96
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 79-102 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A rational approach for dealing with uncertainties in geotechnical performance predictions is presented. First, sources of uncertainty are identified and treated stochastically. Then, the relative importance of each source is analysed and its influence in the decision-making process is evaluated. Strong inferences concerning the spatial structure of soils are drawn from field or laboratory measurements, while maintaining consistency with engineering knowledge and experimenal findings. Optimal estimates of soil properties are derived by a stochastic method which is mathematically meaningful and portrays adequately the real behaviour of the data. The method is powerful when the data exhibit homogeneous or non-homogeneous characteristics, and works well with any kind of data support. Its applicability is illustrated in a case study involving field vane data. Furthermore, contributions and benefits of the results obtained to the geotechnical decisions and design are discussed.
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  • 97
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 193-202 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Triaxial fracture tests with overburden pressures ranging from 0.69 to 136 MPa were performed to determine the material parameters involved in a cap model for limestone. Three material parameters A, B and C, were evaluated through Powell's optimization method and the remaining parameters through simulation-curve fitting procedure. The resulting cap model was tested against separate triaxial fracture and hydrostatic compression tests. Modification of the original hardening function, as proposed by DiMaggio and Sandler, provided an improved fit for the experimental data.
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  • 98
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 215-217 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Additional Material: 2 Tab.
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  • 99
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 257-268 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: An approximate, analytical solution is found for the gravity-induced stresses in the neighbourhood of an axisymmetric topographic feature on an elastic half-space. The solution is in the form of a perturbation expansion in powers of the characteristic slope, ∊. The leading order problem, at O(1), is for a distributed normal load on a plane half-space. The O(∊) correction is due to a distributed shear traction. The vertical variation of the near-surface stress perturbation and the rotation of the principal stress directions are O(∊) effects, and thus include contribution s of like order from both the normal and shear loads. The method requires general solutions for axisymmetric, normal and shear tractions of arbitrary radial distribution, and these are found in terms of Hankel transforms.
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  • 100
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    International Journal for Numerical and Analytical Methods in Geomechanics 11 (1987), S. 323-323 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
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