ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Sumnary The glass transition temperatures of 2,4-diphenylpentane, 2,4,6triphenylheptane and 2,4,6,8-tetraphenylnonane are shown to follow the relation Tg = 325 − 2.64 × 104/Mn where Mn is the molecular weight. 2,4-diphenylpentane-2,4,6-triphenylheptane mixtures exhibit only one glass transition temperature which follow the relation Tg = (1 − ω2) Tg1 + ω2 Tg2 where ω2 is the weight % of 2,4-diphenylpentane. The configurational structure of these polystyrene model molecules is shown to slightly influence the Tg's values.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00256801
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