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  • Gas chromatography  (32)
  • reservoir  (23)
  • Springer  (55)
  • Annual Reviews
  • 2020-2024
  • 2005-2009
  • 1990-1994
  • 1980-1984  (55)
  • 1975-1979
  • 1982  (55)
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  • 2020-2024
  • 2005-2009
  • 1990-1994
  • 1980-1984  (55)
  • 1975-1979
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  • 1
    ISSN: 1612-1112
    Keywords: Teflon capillary columns ; Chemically modified teflon ; Gas chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The preparation of teflon capillary columns employing direct coating of the stationary phase to the chemically modified teflon surface and the role of the chemically modified teflon in the separation mechanism are described. Two types of contributions from the modified teflon have been observed: nonspecific adsorption of the carbon surface and specific interactions of polar groups in the carbon skeleton. The use of polar liquid phases can eliminate adsorption due to the presence of polar groups in the modified teflon.
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  • 2
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    Chromatographia 16 (1982), S. 60-62 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Amines ; Derivatization ; Chloroformate esters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The gas chromatographic analysis of amines after conversion to electron capture sensitive carbamates in two-phase systems has been studied. Hydrophilic compounds, for instance methylamine, are reacted with 2,2,2-trichloro-tert. butyl chloroformate. Quantitation below 10−7 M can be made by thermionic or electron capture detection. A hydrophobic amine, namely N,N-dimethyl-n-octylamine, was derivatized with 2,4,6-tribromophenyl chloroformate with addition of iodide ion to the aqueous phase. The favorable effect of iodide ion as well as the choice of pH and chloroformate ester is discussed.
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  • 3
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    Chromatographia 16 (1982), S. 98-102 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Rectangular channel ; Efficiency ; Capacity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Gas chromatographic experiments have been performed in a truly rectangular channel with a 60∶1 cross-sectional aspect ratio, constructed according to the field-flow fractionation technology. It is shown that the peak broadening is controlled by the thickness of the channel while the maximum load is determined by the largest cross-sectional dimension. However, even with its elongated configuration, the side walls contribute significantly to the band broadening of solutes with a high diffusivity. Good agreement is found between the experimental plate height data and the recent theoretical calculations of Golay [13] taking into account the side-wall effect.
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  • 4
    ISSN: 1573-5117
    Keywords: zooplancton ; phénologie ; mise en eau ; reservoir
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper presents the results of an investigation which lasted three years, on the effects of impounding a river on its zooplankton community. Forty zooplankton samples were collected from the Desaulniers River and from a string bog (53°35′N, 77°35′W) in 1976 before impoundment. Sampling was also conducted in 1977 (331 samples) and 1978 (153 samples) during and after impoundment. The population dynamics of zooplankton show different patterns in 1977 and 1978. The main impacts of impoundment on the river and the bog communities are the increase of the population density, particulary of Rotifera and Copepoda, the increase of the number of species of Rotifera and the increase of the diversity indices based on numbers and biomass. These changes are observed at each sampling station. The total biomass increases in lotic stations but decreases in the string bog because the density and the biomass of Cladocera increases in the river but drops in the bog. Results are compared to those obtained in natural lakes and bog of the same area and to those published in other studies.
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  • 5
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    Hydrobiologia 88 (1982), S. 55-55 
    ISSN: 1573-5117
    Keywords: reservoir ; education
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
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  • 6
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    Hydrobiologia 88 (1982), S. 117-133 
    ISSN: 1573-5117
    Keywords: phytoplankton ; reservoir ; succession ; abundance ; control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The development of a seasonal succession of phytoplankton species in Rutland Water is described. The factors controlling their succession and abundance are discussed in relation to changes in physical and chemical variables. At present, input of water from the catchment and by pumping from the Rivers Welland and Nene, has the greatest influence on phytoplankton abundance.
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  • 7
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    Hydrobiologia 88 (1982), S. 159-169 
    ISSN: 1573-5117
    Keywords: Chironomidae ; bathymetric ; distribution ; Rutland Water ; reservoir ; SPSS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The bathymetric distribution of the eight most abundant taxa of chironomid larvae is described from benthic grab samples collected in Rutland Water from May 1977 to April 1979. Cricotopus, Psectrocladius and Endochironomus larvae were generally restricted to water less than 9 m deep. Procladius, Chironomus, Microtendipes, Polypedilum and Tanytarsini larvae were all recorded at depths down to 25 m. However, the highest population densities of the latter five taxa were recorded in shallow water. The results are discussed in relation to the diet of trout and certain management practices at the reservoir. Also described is the application of SPSS (Statistical Package for the Social Sciences) to the analysis of these data.
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  • 8
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    Hydrobiologia 88 (1982), S. 211-224 
    ISSN: 1573-5117
    Keywords: nature reserve ; reservoir ; planning ; design ; management ; wildfowl
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract This paper illustrates how practical conservation management has helped to create a nature reserve of international importance for wildfowl. The development of existing and introduced habitats has produced a wide diversity of fauna and flora without causing an unnatural ecological balance and close liaison with other reservoir users has establoshed zoning areas free from disturbance resulting in both man and birds benefiting from such agreements.
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  • 9
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    Hydrobiologia 89 (1982), S. 177-188 
    ISSN: 1573-5117
    Keywords: Chironomidae ; littoral ; reservoir ; salinity ; chlorides ; particulate organic matter ; temperature ; wind
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Texoma in southcentral Oklahoma was formed by the impoundment of the Washita and Red Rivers. The Red River is more highly saline than the Washita and creates a complex salinity gradient across the reservoir. Populations of chironomids were monitored with multiple-plate samplers in areas of high (34–113 mg l−1 Cl−), intermediate (35–60 mg l−1 Cl−) and low (4–27 mg l−1 Cl−) salinity during the spring and summer of 1978. Food availability, temperature, salinity and wind direction influenced the distribution of the 14 genera and at least 22 species of chironomids which colonized the multiple-plate samplers. Filter-feeders attained their highest densities in the river-arm stations where levels of particulate organic matter (POM) were high. Algal grazers attained their highest densities in the clear intermediate area where the plates of the samplers were covered with algal mats. Most of the genera believed to be feeding primarily on POM decreased in density as the temperature and density of Glyptotendipes sp. rose. Certain species were restricted to either the Red River arm or the Washita River arm and this is probably a reflection of different salinity tolerances.
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  • 10
    ISSN: 1573-5117
    Keywords: benthos ; depth distribution ; Diptera ; dragonfly ; Ephemeroptera ; Odonata ; reservoir ; South Carolina ; thermal effluent ; Trichoptera
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The distribution and abundance of macroinvertebrates along a water depth gradient were studied in thermal and ambient temperature areas of a reservoir in the southeastern United States. Benthic samples were taken at 10 depths (0.16–5 m) during January–April, 1978. Factors affecting the depth distribution of Ceratopogonidae, Chaoboridae, Chironomidae, Ephemeroptera, Odonata, and Trichoptera are discussed. The relationship between abundance of organisms and water depth was more complex than an inverse relationship generally reported in the literature.
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  • 11
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    Hydrobiologia 88 (1982), S. 43-46 
    ISSN: 1573-5117
    Keywords: Rutland Water ; landscape ; amenity planning ; tree planting ; reservoir ; draw-down
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The landscape problems encountered at Rutland Water were: 1) the reconciliation of the reservoir and its works with the rural surroundings; 2) siting and treatment of all ancillary works; 3) mitigation of exposure of shore by draw-down; 4) the provision of opportunities for recreation without damage to the environment; and 5) conservation of nature. The means adopted were: 1) forward planning; 2) consultation and co-operation with all interests concerned; 3) extensive planting of native species and of ground shaping; and 4) arrangements for appropriate maintenance.
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  • 12
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    Hydrobiologia 88 (1982), S. 93-101 
    ISSN: 1573-5117
    Keywords: reservoir ; raw water ; management ; chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The options available for the management of Rutland Water are identified and their use discussed. The changes in the chemistry of the stored water with regard to sulphate, silica (molybdate-reactive), dissolved reactive phosphate and total oxidised nitrogen are shown.
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  • 13
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    Hydrobiologia 91-92 (1982), S. 623-639 
    ISSN: 1573-5117
    Keywords: reservoir ; sedimentation ; River Nile ; High Aswan Dam
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The River Nile receives most of its sediment load from the Atbara and Blue Nile rivers, which carry eroded sediments north from the Ethiopian mountains during the seasonal flood period between August and October. Prior to the construction and operation of the High Aswan Dam, in 1964, 9–10 × 106 metric tons of suspended sediment were deposited annually in the flood plain of the Nile, while about 93% of the total average annual suspended load of 124 × 106 metric tons was carried out into the Mediterranean Sea. Since the full operation of the High Aswan Dam in 1968, the flood discharge of the Nile, below the dam, has been greatly modified and more than 98% of the total suspended load has been retained within the reservoir. Based on long-term records; estimated relationships between discharge and suspended load, and field measurements, the life span of the dead storage capacity has been estimated at a minimum of about 360 years. Although this preliminary calculation is less than the estimated design capacity of 450 years, it is expected that progressively more suspended solids will be released in the outflow of the reservoir and that together with the use of flood diversion schemes the High Aswan Dam is likely to approach its design life span.
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  • 14
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    Hydrobiologia 91-92 (1982), S. 623-639 
    ISSN: 1573-5117
    Keywords: reservoir ; sedimentation ; River Nile ; High Aswan Dam
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The River Nile receives most of its sediment load from the Atbara and Blue Nile rivers, which carry eroded sediments north from the Ethiopian mountains during the seasonal flood period between August and October. Prior to the construction and operation of the High Aswan Dam, in 1964, 9–10 × 106 metric tons of suspended sediment were deposited annually in the flood plain of the Nile, while about 93% of the total average annual suspended load of 124 × 106 metric tons was carried out into the Mediterranean Sea. Since the full operation of the High Aswan Dam in 1968, the flood discharge of the Nile, below the dam, has been greatly modified and more than 98% of the total suspended load has been retained within the reservoir. Based on long-term records; estimated relationships between discharge and suspended load, and field measurements, the life span of the dead storage capacity has been estimated at a minimum of about 360 years. Although this preliminary calculation is less than the estimated design capacity of 450 years, it is expected that progressively more suspended solids will be released in the outflow of the reservoir and that together with the use of flood diversion schemes the High Aswan Dam is likely to approach its design life span.
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  • 15
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    Hydrobiologia 96 (1982), S. 177-184 
    ISSN: 1573-5117
    Keywords: sediment ; reservoir ; stream ; macroinvertebrates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Effects of sediment release from Guernsey Reservoir on macroinvertebrates of the North Platte River, Wyoming, were investigated during summer 1981. Suspended solids concentrations during sediment release increased from 〈20 mg l−1 to 〉300 mg l−1. Because fine particulates remained in suspension, mean particle size of substrates was unaltered. Densities of chironomids decreased 90% + during sediment release but recovered to initial levels in 3 weeks after the release ended. Densities of mayflies and oligochaetes increased. Changes in benthic populations were highly correlated with increases in suspended solids.
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  • 16
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    Hydrobiologia 88 (1982), S. 52-52 
    ISSN: 1573-5117
    Keywords: reservoir ; planning policies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The poster summarised Leicestershire County and Rutland District Councils Planning policies operative in the area surrounding Rutland Water. The policies are contained in the Structure Plan for Rutland, approved in December 1979, Rutland District Council's Settlement Policy and the Empingham District Plan preliminary discussion document. The policies of more specific application to the area surrounding Rutland Water are those of the Empingham District Plan which relate to land use, recreation and traffic management in the Parishes of Burley, Edith Weston, Egleton, Empingham, Exton, Gunthorpe, Hambleton, Horn, Lyndon, Manton, Normanton and Whitwell. The theme reflected in all policies covering this area is one of conservation. It is expressed in one of the Structure Plan's basic policies as follows: ‘Rutland's Planning Role should be one of positive conservation particularly of natural resources with an emphasis on minimising the loss of, and where practicable improving the natural assets of farmland, woodland, minerals and water.’
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  • 17
    ISSN: 1573-5117
    Keywords: reservoir ; Langmuir circulation ; algae ; sedimentation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The quantitative extent to which the large-scale organised water motion in the surface waters of lakes and reservoirs, known as Langmuir circulation, affects the distribution and settling of algae and other suspended particles is not known and has thus been ignored in conventionally used water quality models. Since the distribution and settling of these particles is important in determining water quality, this study set out to investigate these effects using a mathematical model based on the two-dimensional advection-diffusion mass transport equation describing the temporal and spatial distribution of suspended particles in a typical Langmuir cell. The Langmuir circulation flow field and turbulent diffusion coefficients are empirically modelled by relating them to environmental parameters (Buranathanitt et al., in press). The results show that Langmuir circulation does affect particle distribution and settling. For particles with small sinking speeds, such as the lighter algae, the circulation causes intense mixing, resulting in essentially uniform distribution of particles over the cell (as assumed in the ‘well-mixed compartment model’). For particles with high sinking velocities, however, aggregation can occur, giving rise to significant reduction in sinking loss. For diatoms, effective sinking speeds are as much as 6% less than when cells are not operating while for coarse silt particles in a cell of large width to depth ratio a reduction of more than 60% is possible. Two preliminary laboratory experiments have also been performed in order to obtain further information on both the physical characteristics of Langmuir cells and their effects on suspended particles. The results of a wind-wave tank experiment suggest that the Langmuir circulation scale of motion is related to the height of the surface waves, thus providing an empirical means of determining the size of Langmuir cells from environmental variables. A particle settling tank experiment confirmed, in a qualitative way, the results obtained in the analytical study, with both the uniformly mixed and aggregation phenomena being reproduced (Buranathanitti et al., submitted). Full details of the work described in this abstract will be published elsewhere (Buranathanitt et al., in press; Buranathanitt et al., submitted).)
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  • 18
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    Hydrobiologia 88 (1982), S. 179-189 
    ISSN: 1573-5117
    Keywords: reservoir ; trout ; angling ; impoundment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Rutland Water was stocked with trout in 1975 after removing the existing fish populations. Growth and survival of rainbow and brown trout are compared with the reservoir's filling regime, and re-colonisation by other fish species is described. The use of angler success as an indicator of fish stock density and its management is discussed.
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  • 19
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    Hydrobiologia 88 (1982), S. 147-156 
    ISSN: 1573-5117
    Keywords: reservoir ; benthos ; invertebrates ; colonisation ; abundance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The colonisation of Rutland Water by benthic invertebrates has been monitored from 1976 when the reservoir was first filled. A modified Ekman grab was used to sample populations quantitatively while false substrates and dredge samples were used to obtain supplementary data. Hand net and hand-sorting were used to study the littoral zone. The dominant taxa in the reservoir are Asellus aquaticus, A. meridianus, Gammarus pulex, Crangonyx pseudogracilis, Helobdella stagnalis, Erpobdella octoculata, Polycelis tenuis, larval Chironomidae and Oligochaeta. Other species which appeared abundantly, such as Limnaea pereger and Planorbis albus, have now disappeared and it is suggested that the generally low levels of gastropods might account for the poor performance of species such as Dugesia lugubris and Glossiphonia complanata. Other aspects of abundance are discussed, as are the effects of maturation of the system.
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  • 20
    ISSN: 1573-5117
    Keywords: trout ; Salmo trutta ; Salmo gairdneri ; diet ; Rutland Water ; reservoir
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The diet of brown trout (Salmo trutta L.) and rainbow trout (S. gairdneri Richardson) in Rutland Water were compared during the first two fishing seasons (April–October 1977 and 1978). Fortnightly samples of approximately forty stomachs were obtained from boat and bank, rod-and-line caught trout giving a total of 1046 stomachs over the two seasons. During 1977 seasonal changes in the diet were divided into two phases; the first being a period of abundant drowned terrestrial food until June. This was followed by a period of more stable water level from July onwards when chironomid larvae and pupae were consistently the most important food items and the diversity of food also increased. In 1978 the proportion of chironomid pupae and larvae declined and they were replaced in the diet by Gammarus and Asellus.
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  • 21
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    Hydrobiologia 88 (1982), S. 7-17 
    ISSN: 1573-5117
    Keywords: Rutland Water ; reservoir ; water supply ; demand ; design ; recreation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Rutland Water was planned in the 1960s to meet the water needs of the expanding East Midland region of England. Chosen from 64 possible sites, it was approved in 1970 and construction started in 1971. The dam was closed and the reservoir started to fill from its natural catchment in 1975; pumping started from the rivers Welland and Nene in 1976 and the reservoir was full by March 1979. Details of the stages in its development are given together with an indication of the ways in which the recreational uses of the reservoir have been integrated with its water supply function.
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  • 22
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    Hydrobiologia 88 (1982), S. 191-198 
    ISSN: 1573-5117
    Keywords: trout ; littoral fauna ; impoundment ; flooding ; reservoir ; Rutland Water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Fingerling Salmo trutta L. and S. gairdneri R. were stocked in Rutland Water in early 1975. Initial rapid growth was associated with feeding on littoral and planktonic Crustacea during this year. Rapid water level changes occurred over the winter months, interspersed with longer periods of stability during the summer. These changes caused changes in trout diet. Terrestrial food (e.g. earthworms), released from flooded land was important during winter months; aquatic items which increased in abundance during periods of stable water levels (e.g. Gammarus pulex, Limnaea pereger, Chironomidae larvae and pupae) were important during spring, summer and autumn. It is suggested that the rapid growth rates recorded in the first two years of the reservoir are the result of the ready availability of different food sources.
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  • 23
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    Hydrobiologia 91-92 (1982), S. 623-639 
    ISSN: 1573-5117
    Keywords: reservoir ; sedimentation ; River Nile ; High Aswan Dam
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The River Nile receives most of its sediment load from the Atbara and Blue Nile rivers, which carry eroded sediments north from the Ethiopian mountains during the seasonal flood period between August and October. Prior to the construction and operation of the High Aswan Dam, in 1964, 9–10 × 106 metric tons of suspended sediment were deposited annually in the flood plain of the Nile, while about 93% of the total average annual suspended load of 124 × 106 metric tons was carried out into the Mediterranean Sea. Since the full operation of the High Aswan Dam in 1968, the flood discharge of the Nile, below the dam, has been greatly modified and more than 98% of the total suspended load has been retained within the reservoir. Based on long-term records; estimated relationships between discharge and suspended load, and field measurements, the life span of the dead storage capacity has been estimated at a minimum of about 360 years. Although this preliminary calculation is less than the estimated design capacity of 450 years, it is expected that progressively more suspended solids will be released in the outflow of the reservoir and that together with the use of flood diversion schemes the High Aswan Dam is likely to approach its design life span.
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  • 24
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    Hydrobiologia 88 (1982), S. 51-51 
    ISSN: 1573-5117
    Keywords: tree-planting ; reservoir ; drawdown
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The aesthetic problems posed by reservoir margins have been recognised for many years. They stem from a complex pattern of action and interaction of several environmental variables — water manipulation patterns, wave action, substrate characteristics, grazing and other factors. These factors usually result in reservoir margins being not only visually unattractive and physically unstable, but also of low ecological diversity. The Natural Environment Research Council and Water Research Centre have, since 1968, together funded a research programme to investigate the use of plant species to combat these problems. In isolated instances in the UK, woody species in particular have succeeded in colonising margins naturally, to very good visual effect (e.g. at Lake Vyrnwy). ‘Biotechnical’ treatments — using artificially planted shrubs and trees — have been successfully used in large Central European reservoirs to combat soil erosion by waves. Following trials of various woody species on the margins of established reservoirs, 10 species/cultivars were ‘pre-planted’ above and below the future top water level (TWL) of Rutland Water in 1973, 5 years before reservoir filling was completed. Pre-planting theoretically allows better survival by trees of subsequent partial inundation. The precise siting of pre-planted trees in the vertical dimension should normally be done using modelled predictions of reservoir summer median water level (a variable important to tree survival). The complex factors affecting the operation of Rutland Water made precise prediction impossible; the experimental plot eventually extended from 500 mm above TWL, to 2 000 mm below TWL, in 500 mm steps. 252 trees were involved in the plot and their growth has been monitored for the past 7 years. The species being predominantly hydrophytic, drought was a problem in the years prior to reservoir filling. Mulching with grass-cuttings proved to be helpful in this respect. Subsequently, prolonged periods of high water level have been deleterious to tree survival in the lower areas of the plot. Once abstraction/recharging patterns become more cyclic, it is anticipated that tree growth will stabilise.
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  • 25
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    Hydrobiologia 88 (1982), S. 53-54 
    ISSN: 1573-5117
    Keywords: reservoir ; visitors ; traffic ; amenity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
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  • 26
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    Hydrobiologia 88 (1982), S. 103-116 
    ISSN: 1573-5117
    Keywords: reservoir ; treatment ; pulsator ; quality ; haloforms
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The paper describes the treatment facilities and processes at the Wing Works where Rutland water is treated to potable standards. It summarises the experience gained in the operation of the works since it opened in 1977 and includes a brief account of an investigation into the production of haloforms.
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  • 27
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    Chromatographia 15 (1982), S. 704-706 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Isopropyliden-sorboses ; TMS-derivatives ; GC-MS combined technique ; Mass spectra
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A method has been developed using gas chromatography — electron impact mass spectrometry for the determination of the di-0-isopropylidene-sorbofuranose and mono-0-isopropylidene-sorbofuranose. The compounds are separated as their trimethylsilyl derivatives on a capillary column coated with the stationary phase SE-52. The mass spectra show that the silylation reaction is quantitiative and that the isopropylidene groups does not change.
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  • 28
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    Chromatographia 15 (1982), S. 183-185 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Analysis of ethylbenzene hydroperoxide ; Time normalization method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A gas chromatographic method, based on the time normalization technique, is described for the analysis of ethylbenzene hydroperoxide in mixtures containing ethylbenzene, acetophenone, 1-phenylethanol, benzaldehyde and phenol. Different liquid phases were tested and the best results were obtained with tricresyl phosphate and neopentyl glycol sebacate. The influence of the support, the liquid loading and the gas velocity are discussed.
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  • 29
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    Chromatographia 15 (1982), S. 625-630 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Open-tubular (capillary) columns ; Comparison of liquid phases ; Influence of temperature ; Retention index data
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The influence of temperature and liquid phase film thickness of open-tubular (capillary) columns on the retention index values of hydrocarbons on methylsilicone liquid phases is discussed. Data obtained on methylsilicones and squalane are compared. Retention index values of 43 hydrocarbons between 40 and 70 °C on OV-101 liquid phase are listed.
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  • 30
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    Chromatographia 15 (1982), S. 351-354 
    ISSN: 1612-1112
    Keywords: Supported catalysts ; Reserved-flow GC ; Drying step ; Gas chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Application of reversed-flow gas chromatography to study the drying step in the preparation of supported catalysts is proposed. It is demonstrated that this technique can be applied to investigate the kinetic law followed, as well as to obtain kinetic parameters of drying (rate constants, activation energies and frequency factors). Amaterial illustrating this application is γ-Al2O3 impregnated with usual organic solvents (n-C5H12,n-C6H14,n-C7H16, CH3COCH3 and CH3CH2OH). It was found that in all cases above a simple first-order law based onone kind of active site is followed. Moreover, it was observed that the activation energyE a of the drying process increases almost linearly with the relative molecular mass of the solvent, whereas for the same solventE a increases with the amount used. The operation of a kinetic compensation effect suggests “similar” activated complexes of the various solvents used.
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  • 31
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Fused silica capillaries ; New polar phases: OV-1701 and RSL-310 ; Immobilization
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    Topics: Chemistry and Pharmacology
    Notes: Summary The possibilities of OV-1701 and RSL-310, two new stationary phases, have been evaluated for capillary gas chromatography in fused silica columns. OV-1701 is a cyanopropylphenyldimethyl polysiloxane of moderate polarity possessing excellent chromatographic characteristics. The phase exhibits high coating and chromatographic efficiencies, high temperature stability and is suitable for cross-linking. RSL-310 is a polar liquid stationary phase yet to be permanently bonded in a capillary column. The selectivity of both phases extends the applicability of fused silica columns.
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  • 32
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    Chromatographia 15 (1982), S. 241-244 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Monosaccharides ; Polyols ; GC of TMS derivatives
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    Topics: Chemistry and Pharmacology
    Notes: Summary This paper describes the gas chromatographic separation of the mixture of isopropylidene monosaccharides, and their trimethylsilyl derivatives. Based on the total analysis time and resolution the best stationary phase was SF-96 using Chromosorb G as the solid support and temperature programming.
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  • 33
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    Chromatographia 15 (1982), S. 312-314 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Injection-port modification ; Oxygen and nitrogen traces
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    Topics: Chemistry and Pharmacology
    Notes: Summary The paper presents a new device modifying normal injection port of a gas chromatograph for eliminating air contamination thus enabling determination of traces of oxygen or nitrogen. Further modification is also proposed which enables the analysis to be carried out with a limited quantity of sample gas. Potential application of this device in the analysis of reactive gases like florine has been indicated.
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  • 34
    ISSN: 1612-1112
    Keywords: Phthalides ; Gas chromatography ; Chromosorb W ; Isomerization ; Ligustilide
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    Topics: Chemistry and Pharmacology
    Notes: Summary During GLC of naturally occurring mixtures of phthalides on packed columns an artefact was sometimes detected that originated from Z-ligustilide. Active sites of Chromosorb W were responsible for the formation of the artefact, that was assumed to be E-ligustilide as GC-MS revealed that its mass spectrum was identical with that of Z-ligustilide. No isomerization was observed when freshly coated Chromosorb W was used or the support was deactivated by benzoyl chloride or melamine. The identity of the artefact was confirmed by UV irradiation experiments.
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  • 35
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    Chromatographia 15 (1982), S. 30-32 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Arsenic ; Inorganic materials
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    Topics: Chemistry and Pharmacology
    Notes: Summary A method is described for the quantitative chlorination and extraction of arsenic as arsenic trichloride from a number of alloys. The conditions for the quantitative gas chromatographic measurement of the volatile chloride have been studied. The proposed method for inorganic materials is very fast giving results within 10 min; sensitive, 1.5·10−13 g As can be detected, simple and accurate. At the ng level of As the error is about 20% with a standard deviation less than 20%, and at the 10pg level the error is about 36% with a standard deviation of 44%.
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  • 36
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    Chromatographia 15 (1982), S. 765-768 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Preparative scale chromatography ; Capacity ; Dual-stage separation
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    Topics: Chemistry and Pharmacology
    Notes: Summary The capacity of different versions of single- and dual-stage separation of mixtures on a preparative scale is considered. It has been shown that dual-stage separation with intermediate condensation considerably enhances the capacity of the installation as compared with a single-stage process.
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  • 37
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    Chromatographia 15 (1982), S. 117-124 
    ISSN: 1612-1112
    Keywords: Various packed GC column ; Gas chromatography ; Porous layer beads ; GC/MS analysis
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    Topics: Chemistry and Pharmacology
    Notes: Summary Theoretical comparisons of various packed GC column types are presented with respect to analysis time, efficiency, sample dilution, and sample capacity for a given maximum inlet pressure. In particular, totally porous particles, porous layer beads, and glass beads are compared with one another. It is shown that 30 μm porous layer beads offer a useful compromise between analysis time and plate count with relatively good sample capacity. Moreover, when using 1 mm i.d. columns (microbore), outlet flow rates that are reasonable for direct coupling to magnetic sector mass spectrometers are achieved making these columns suitable for GC/MS. Using 30 μm Zipax porous layer beads, columns yielding 8,000 to 10,000 plates/meter have been produced with inlet pressures of 13 to 26 atm. A simple modification of the injection port converts the maximum inlet pressure of a commercial gas chromatograph to 26 atm. With such pressures, columns in excess of 20,000 plates can be achieved. Chromatograms are presented illustrating the promise of these microbore columns for GC and GC/MS analysis.
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  • 38
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    Chromatographia 15 (1982), S. 245-248 
    ISSN: 1612-1112
    Keywords: Chromatoscopy ; Gas chromatography ; Graphitized carbon black ; Molecular structure and retention ; Aromatic hydrocarbons
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    Topics: Chemistry and Pharmacology
    Notes: Summary A molecular-statistical calculation of the retention volumes at zero sample size on graphitized thermal carbon black is carried out for quasi-rigid molecules of fluorene, indene, 1-methylindene, 2-methylindene and three dimethylindenes. A reasonable agreement is observed between the calculated and the available experimental gas chromatographic data. The potential barrier to internal rotation and the torsional angle in styrene molecules are estimated by comparing theoretically calculated and measured retention volumes.
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  • 39
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Silicone liquid phases ; Oxidation
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    Topics: Chemistry and Pharmacology
    Notes: Summary The on-column oxidation of apolar and polar silicones used as gas chromatographic stationary phases is investigated. Even at 225° the effects of oxidation are found to be slight. Of the materials investigated the methylphenylsilicones are the most stable.
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  • 40
    ISSN: 1612-1112
    Keywords: Glass capillary ; Gas chromatography ; Methyl chloroacetates ; Methyl chloropropanoates ; Methyl chlorobutanoates
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    Topics: Chemistry and Pharmacology
    Notes: Summary The gas chromatography of all chlorinated methyl acetates, methyl propanoates and methyl mono- and dichlorobutanoates has been studied on Carbowax 20M and SE-30 glass capillary columns under various running conditions. The order of elution on a non-polar column was largely determined by the boiling point of esters, whereas on a polar column it was much influenced by the structure of compounds. Complete separation of the combined mixture of all 27 compounds could not be achieved, however, methyl 3,3-dichlorobutanoate was the only ester overlapped on both columns in spite of the various column temperatures used. The best separation of the mixture was on Carbowax 20M with a temperature program from 50°C at 8°C/min, isothermal running conditions leading either to poor separation of volatile components or long analysis time and broad peaks of higher chlorinated esters. The relative retention times for compounds at the various column temperatures are given and the retention order on a polar and on a non-polar column discussed.
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  • 41
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    Chromatographia 15 (1982), S. 517-520 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Carbon-silica adsorbents ; n-Octadecanol film ; Phase transitions
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    Topics: Chemistry and Pharmacology
    Notes: Summary The properties of the n-octadecanol film on carbon-silica adsorbent (Carbosil) were investigated. It was found that n-octadecanol forms an oriented film on the Carbosil's surface. If the surface of the basic silica gel is not completely covered with carbon, then the phase transition takes place in this film at a temperature higher than the melting temperature of n-octadecanol. One may distinguish two forms of this film, characterised by the different structures and the temperatures of the phase transitions. The first exists on the surface of silica gel unblocked by carbon. This part of the film is a monolayer, in which the alcohol molecules are vertically oriented. The solid compact-liquid expanded type phase transition at the well-defined temperature occurs in this film. In the second part of the film formed on the carbon surface, there is a multilayer of n-octadecanol. Its molecules are probably parallely oriented in relationship to the adsorbent surface. This film desintegrates progressively when the temperature increase. Maximum temperature of this phase transition is lower than the temperature of its analogue on pure silica gel surface.
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  • 42
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    Chromatographia 15 (1982), S. 546-558 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary columns ; Quantitative analysis ; Sample inlet systems ; High-speed analysis
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    Topics: Chemistry and Pharmacology
    Notes: Summary The attainment of precise quatitative analytical data using open-tubular (capillary) columns in standard, commercially available gas chromatographic instrumentation is demonstrated. Key elements in the design and proper utilization of the instrumentation are discussed. The function of the various sample introduction systems is elaborated and their quantitative performance demonstrated. The extra-column contribution to band-spreading is determined and the resultant data is used assessing the suitability of commercial instrumentation for highspeed capillary gas chromatography. The quantitative analysis of a sample containing some eleven components in less than thirty seconds is shown.
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  • 43
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Crystal hydrates as stationary phases ; Mobile Phases containing water ; Selective retentions
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    Topics: Chemistry and Pharmacology
    Notes: Summary The use of crystallohydrates, crystallohydrate solutions and melts as stationary phases in gas chromatography has been proposed. Crystallohydrates have been shown to display high selectivity in the separation of polar organic compounds when use is made of water vapours as the mobile phase. Some aspects of gas-liquid chromatography in water vapours and with the stationary phase comprising crystallohydrates have been studied, and the preliminary results obtained point to the desirability of further progress in this field.
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  • 44
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    Chromatographia 16 (1982), S. 201-203 
    ISSN: 1612-1112
    Keywords: Phenols ; Whisky ; Gas chromatography ; Aroma compounds
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    Topics: Chemistry and Pharmacology
    Notes: Summary Twelve volatile phenols were identified in whisky by combined gas chromatography-mass spectrometry. Of these phenols 2,4-dimethylphenol was found for the first time in the aroma of whisky. The content of phenol, o-, m-, and p-cresol, guaiacol, p-ethylphenol, p-ethylguaiacol and eugenol in whiskies originating from different countries was determined by gas chromatography as their 2,4-dinitrophenyl ethers using electron capture detection. The results show that Scotch whiskies differ from others in the content of o-, m-, and p-cresol. The odour threshold values of phenols studied were determined in a 10% (v/v) ethanol-water mixture and in some cases also in the whiskies. Cresols have been found to make contribution to the aroma of Scotch whisky.
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  • 45
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    Chromatographia 16 (1982), S. 26-31 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Ionization detectors ; Gaia
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    Topics: Chemistry and Pharmacology
    Notes: Summary This paper is an account of the development of the gaia hypothesis as seen through the eyes of a gas chromatographer. Gaia is a radical notion about the Earth which postulates the climate and chemical composition to be regulated at an optimum by and for life. Gas chromatography played an important role in the gathering of evidence for the hypothesis but most significantly the art of inventing detectors lead to the developement of a planetary life detector through which gaia was revealed.
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  • 46
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    Chromatographia 16 (1982), S. 282-285 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Naphtha analysis ; Gasoline analysis ; Hydrocarbon type analysis
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    Topics: Chemistry and Pharmacology
    Notes: Summary Two different gas chromatographic methods are used for the determination of hydrocarbon type distribution in naphtha and gasoline samples with final boiling points up to 275 °C. The methods are based either on a single capillary column or on a valve-switched packed column system. Both methods give extensive information on paraffins, olefins, naphthenes and aromatics in total as well as by carbon-number. In each case the analysis is fully automated with a computer controlling the entire analysis from injection to results presentation. The advantages and limitations of both methods are discussed.
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  • 47
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    Chromatographia 16 (1982), S. 322-324 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Graphitized carbon black supports ; Determination of hydroxyacids
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    Topics: Chemistry and Pharmacology
    Notes: Summary Acid-washed graphitized carbon black (Carbopakc B) modified with trimesic adic and PEG 20M has proved to be effective for quantitative analysis of underivatized low molecular weight hydroxyacids. Calibration data revealed good linear relationships between relative peak area and concentration for lactic and 3-hydroxybutyric acids down to 0.05 mmol/l. The packing material was suitable for the analysis of aqueous solutions of hydroxyacids as it is tolerant to injections of water over a prolonged period of use. The GC system developed has been applied to the analysis of some hydroxyacids of biomedical interest in blood plasma and lactic acid contained in wine and beer.
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  • 48
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Modified thermal energy analyzer ; Selective detection of nitrogen compounds
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    Topics: Chemistry and Pharmacology
    Notes: Summary A modification to the TEATM Analyzer is described, which allows it to be used as a highly selective GC detector for nitrogen compounds as well as for N-nitrosamines and nitro compounds. The modified Analyzer is as sensitive as the AFID, but has a much higher selectivity towards nitrogen compounds than the AFID. Its response appears to be molar, with an output that is dependent only on the number of nitrogen atoms present. The performance of the modified Analyzer for the analysis of ammonia, amines,N-nitrosamines, nitriles and organonitro compounds is reported and discussed, as is its application to the detection of these compounds in bacon and beer samples.
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  • 49
    ISSN: 1612-1112
    Keywords: Graphizized carbon black traps ; Organic air pollutants ; Work areas ; Gas chromatography
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    Topics: Chemistry and Pharmacology
    Notes: Summary The use of traps containing graphitized carbon black for the collection and pre-analysis of atmospheric pollutants in industrial areas is presented. The working conditions, in terms of trapping capability and effectiveness of release by thermal desorption are discussed. Some practical applications are also given.
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  • 50
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Van der Waals' volume ; Polarity of stationary phase ; Retention index
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    Topics: Chemistry and Pharmacology
    Notes: Summary Equations for Retention Index (I) versus Van der Waals, volume (Vw) on squalane are studied for alcohols, carbonyls, esters and ethers. Each equation includes linear and branching substances with different positions of the functional group in the carbon chain. The study is extended to stationary phases with polarities from 4.29 to 91.54 on the Tarjan et al. scale. Variations of the slope and origin ordinate values with the polarity of the stationary phase are discussed.
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  • 51
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    Chromatographia 15 (1982), S. 125-132 
    ISSN: 1612-1112
    Keywords: Capillary columns ; Fast analysis ; Gas chromatography ; Instrumental effects ; Optimization
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    Topics: Chemistry and Pharmacology
    Notes: Summary The efficiency of fast GC columns depends largely on the quality of the chromatograph. A theoretical and experimental study shows the relative importance of the various phenomena involved and permits the optimization of a GC System. Extremely good performances, exceeding 2,500 plates per second have been routinely obtained.
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  • 52
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    Chromatographia 15 (1982), S. 180-182 
    ISSN: 1612-1112
    Keywords: Acidic fermentation products ; Characterisation ; Gas chromatography ; Methyl esters
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    Topics: Chemistry and Pharmacology
    Notes: Summary A rapid and simple method for the identification of acidic fermentation products is described. Methyl esters of volatile and non-volatile acids are separated on a single chromatographic column. Retention time data for a number of acids are tabulated.
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  • 53
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    Chromatographia 15 (1982), S. 521-524 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Retention index ; Connectivity index ; Van der Waals' volume ; Alkanes
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    Topics: Chemistry and Pharmacology
    Notes: Summary The relationships between retention index and Van der Waals' volume and between retention index and connectivity index have been studied for 58 different alkanes (C1−C9) on squalane. The correlation coefficient for the former is higher than for the latter. From these equations a linear relationship between Van der Waals' volume and connectivity index is obtained which indicates that the two parameters are equivalent. A simple method for calculating the Van der Waals' volume of alkanes is proposed.
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  • 54
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary columns ; Fused silica capillaries ; Capillary drawing ; Glass capillaries
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    Topics: Chemistry and Pharmacology
    Notes: Summary A compact description is given of a simple and reliable method of drawing flexible fused silica capillary for gas chromatography. Some emphasis is given to the fact that the practices of drawing optical fibres should not be followed too slavishly so this leads to unnecessarily complicated and expensive equipment. Satisfactory capillary column silica tubing can be made with straightfoward extension of the method developed earlier for drawing thick walled capillary. A simple glass/silica hydrogen oxygen diffusion flame bumer is described for fusing the preform tubing at the draw point which is enclosed by a water cooled glass enclosure to trap evaporated silica and maintain the operation under dust free conditions. The uniformity of the capillary diameter is better than 5% which is adequate for most gas chromatographic purposes. The second part of the paper yet to be published will cover the methods developed for coating the capillary both internally and externally.
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    Chromatographia 16 (1982), S. 107-111 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Thermionic ionization ; Catalytic flame ionization
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    Topics: Chemistry and Pharmacology
    Notes: Summary A newly designed thermionic detector was operated in two modes of thermionic ionization detection (TID), and a third mode of catalytic flame ionization detection (CFID). Operating modes were varied by changing the composition of the electrically-heated thermionic/catalytic source, and the composition of gases supplied to the detector. A TID-2 source activated by a low concentration of Cs/ceramic was operated in a dilute H2/air environment and provided specific responses to nitrogen and phosphorus compounds. A TID-1 source activated by a high concentration of Cs/ceramic was operated in a N2 environment and provided very high specificities and picogram detectivities to compounds containing electronegative functional groups such as the NO2 group. A CFID source formed from Ni/ceramic was operated in a H2/air flame environment and provided universal responses to all organics with enhanced responses to some heteroatom compounds.
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