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A chromatoscopic study of fluorene, indenes and styrene (1982)

Dimitrov, L. D. ; Kiselev, A. V. ; Petrova, R. S.

Springer

Chromatographia 15 (1982), S. 245-248

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ISSN: 1612-1112

Keywords: Chromatoscopy ; Gas chromatography ; Graphitized carbon black ; Molecular structure and retention ; Aromatic hydrocarbons

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary A molecular-statistical calculation of the retention volumes at zero sample size on graphitized thermal carbon black is carried out for quasi-rigid molecules of fluorene, indene, 1-methylindene, 2-methylindene and three dimethylindenes. A reasonable agreement is observed between the calculated and the available experimental gas chromatographic data. The potential barrier to internal rotation and the torsional angle in styrene molecules are estimated by comparing theoretically calculated and measured retention volumes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02265656

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