ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas  (27)
  • Elsevier  (27)
  • Annual Reviews
  • 2005-2009  (27)
  • 1990-1994
  • 1980-1984
  • 2008  (12)
  • 2007  (15)
  • 1982
Collection
Years
  • 2005-2009  (27)
  • 1990-1994
  • 1980-1984
Year
  • 1
    Publication Date: 2020-10-29
    Description: We present new viscosity measurements for melts spanning a wide range of anhydrous compositions including: rhyolite, trachyte, moldavite, andesite, latite, pantellerite, basalt and basanite. Micropenetration and concentric cylinder viscometry measurements cover a viscosity range of 10−1 to 1012 Pas and a temperature range from 700 to 1650 °C. These new measurements, combined with other published data, provide a high-quality database comprising ∼800 experimental data on 44 well-characterized melt compositions. This database is used to recalibrate the model proposed by Giordano and Dingwell [Giordano, D., Dingwell, D. B., 2003a. Non-Arrhenian multicomponent melt viscosity: a model. Earth Planet. Sci. Lett. 208, 337–349] for predicting the viscosity of natural silicate melts. The present contribution clearly shows that: (1) the viscosity (η)–temperature relationship of natural silicate liquids is very well represented by the VFT equation [log η=A+B/ (T−C)] over the full range of viscosity considered here, (2) the use of a constant high-T limiting value of melt viscosity (e.g., A) is fully consistent with the experimental data, (3) there are 3 different compositional suites (peralkaline, metaluminous and peraluminous) that exhibit different patterns in viscosity, (4) the viscosity of metaluminous liquids is well described by a simple mathematical expression involving the compositional parameter (SM) but the compositional dependence of viscosity for peralkaline and peraluminous melts is not fully controlled by SM. For these extreme compositions we refitted the model using a temperature-dependent parameter based on the excess of alkalies relative to alumina (e.g., AE/SM). The recalibrated model reproduces the entire database to within 5% relative error (e.g., RMSE of 0.45 logunits).
    Description: Published
    Description: 42–56
    Description: reserved
    Keywords: Viscosity ; Model ; Silicate melts ; Metaluminous ; Peraluminous ; Peralkaline ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 717294 bytes
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2020-10-29
    Description: Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 11 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest 13 cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of 90 vol.%. The 14 phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable 15 quench temperatures, investigated by coupling experiments with Pt-wire and Pt- capsule sample containers inset 2,again did not produce crystallization of trachyte, whereas latitic samples are characterized by 10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature b1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass- forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (b0.125 °C/min), in comparison to latitic melts (RcN0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.
    Description: Published
    Description: 91-101
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: crystallization ; lava flows ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2020-11-26
    Description: During the July^August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (67‡ dip) in the Torre del Filosofo area, and perpendicular to the steep slope (V25‡ dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14‡ for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.
    Description: Published
    Description: 281-294
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dykes ; extensional fractures ; grabens ; slope failures ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2020-10-29
    Description: Viscosity of hydrous trachytes from the Agnano Monte Spina eruption (Phlegrean Fields, Italy) has been determined at 1.0 GPa and temperatures between 1200 and 1400 °C using the falling sphere method in a piston cylinder apparatus. The H2O content in the melts ranged from 0.18 to 5.81 wt.%. These high-temperature hydrous viscosities, along with previous ones determined at low-temperature (anhydrous and hydrous) and at high-temperature (anhydrous), at 1 atm on the same melt composition, represent the only complete viscosity data set available for K-trachyticmelts, frommagmatic to volcanic conditions.Viscosity decreases with increasing temperature andwater content in the melt.At constant temperature, viscosity appears to significantly decreasewhen the first wt.% ofH2Ois added.At H2O content higher than 3 wt.% the effect of temperature on viscosity is slight. Moreover, the deviation from Arrhenian behaviour towards greater “fragility” occurs with increasing water content. We combined low- and high-temperature viscosities (also from literature) and parameterized themby the use of a modified Vogel–Fulcher–Tamman equation, which accommodates the non-Arrhenian temperature dependence ofmelt viscosity.Moreover, in order to explore the extent to which the improved knowledge of Agnano Monte Spina trachyte viscosity may affect simulation of volcanic eruption at Phlegrean Fields, we included our viscosity models in numerical simulations of magma flow and fragmentation along volcanic conduits. These simulations show that the new parameterizations (and hence the new equations) give stronger predictions in the temperature interval relevant for magmatic and eruptive processes.
    Description: Published
    Description: 124-137
    Description: JCR Journal
    Description: reserved
    Keywords: Viscosity ; Trachyte ; Falling sphere method ; Vogel–Fulcher–Tamman equation ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2021-01-27
    Description: The eruptive dynamics of volcanic systems are largely controlled by the viscosity of deforming magma. Here we report the results of a series of high-temperature, high-pressure experiments at conditions relevant for volcanic conduits (250 MPa confining pressure and temperature between 500 °C and 900 °C) that were undertaken to investigate the rheology of magma with crystal fractions varying between 0.5 and 0.8 (50 to 80 wt.%) at different strain-rate conditions. The experiments demonstrate that the presence of crystals increases the relative viscosity (ratio between the viscosity of the mixture and the viscosity of the melt phase) of magmas and additionally induces a decrease of the relative viscosity with increasing strain-rate (shear thinning, non-Newtonian behavior). The experimental results, combined with existing data at low crystal fractions (0–0.3), were used to develop a semi-empirical parameterization that describes the variations of relative viscosity for crystal fractions between 0 and 0.8 and accounts for the complex non-Newtonian rheology of crystal-bearing magmas. The new parameterization, included into numerical models simulating the magma ascent dynamics, reveals that strain-rate-dependent rheology significantly modifies the dynamic behavior inside volcanic conduits, particularly affecting the magma fragmentation conditions.
    Description: Published
    Description: 402-419
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: partially_open
    Keywords: magma rheology ; experimental deformation ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2020-10-29
    Description: In-situ falling-sphere viscometry using shadow radiography in a multianvil apparatus was conducted on a series of samples along the NaAlSi3O8–H2O join up to 2.8 wt.% H2O at the Spring-8 synchrotron radiation facility (Hyogo, Japan). This allowed us to determine viscosities normally too low to be measured at ambient pressure for hydrous silicate melts at high temperatures due to rapid devolatilization. Pressure was fixed at 2.5 GPa for all experiments allowing us to gauge the effect of chemical composition on viscosity. In particular, the series of samples allowed us to vary the melt's degree of polymerization while maintaining a constant Al to Si ratio. Our results show that, for all samples, viscosity decreases as a function of pressure between 1 atm and 2.5 GPa at 1550 °C, indicating that the pressure anomaly can still be observed as depolymerization of the melt increases from nominally 0 (dry albite liquid) to NBO/T=0.8 (assuming water speciation entirely as hydroxyl groups at experimental conditions). We also find that the magnitude of the decrease in viscosity over this pressure interval does not appear to be dependent on the amount of water in the melt (i.e., NBO/T). An explanation for this behavior might be that the molar volume, at least over this limited compositional range, is nearly constant and the effects of compression of these melts, though different in degree of polymerization, are similar.
    Description: Published
    Description: 2-9
    Description: JCR Journal
    Description: reserved
    Keywords: Viscosity ; Silicate melts ; High pressure ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2017-04-04
    Description: New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Srisotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation– Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999– 1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energyconstrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.
    Description: Published
    Description: 303– 329
    Description: reserved
    Keywords: Mt. Somma–Vesuvius volcano ; Sr isotopes ; Geochemistry ; Crustal contamination ; Mantle source ; Phenocryst entrapment ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 879803 bytes
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2017-04-04
    Description: The Etna 122 BC basaltic eruption had two Plinian phases, each preceded and followed by weak phreatic and phreatomagmatic activity. This study infers changing eruption dynamics from density, grain size, and microtextural data from the erupted pyroclasts. The Plinian clasts show no evidence for quenching by external water; instead, all clasts are microvesicular and have high bubble number densities relative to the products of weaker basaltic explosive eruptions, suggesting that the 122 BC magma underwent coupled degassing linked to rapid ascent and decompression. This coupled degassing was probably enhanced by crystallization of abundant microlites, which increased the magma's effective viscosity during conduit ascent. Detailed measurements of vesicles and microlites show wide variations in number densities, size distributions, and shapes among clasts collected over narrow stratigraphic intervals. For such a diversity of clasts to be expelled together, portions of melt with contrasting ascent and degassing histories must have arrived at the fragmentation surface at essentially the same time. We suggest that a parabolic velocity profile across the conduit ensured that magma near the conduit walls ascended more slowly than magma along the axis, leading to a longer residence time and more advanced degrees of outgassing and crystallization in the marginal magma. In our model, accumulation of this outgassed, viscous magma along conduit walls reduced the effective radius of the shallow conduit and led to blockages that ended the Plinian phases.
    Description: Published
    Description: 333-354
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: basaltic Plinian ; Etna ; vesicles ; microlites ; conduit dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2017-04-04
    Description: The October 17 to November 5, 1999, eruption of Mount Etna’s Bocca Nuova crater emplaced a V15U106 m3 flow field. The eruption was characterized by 11 paroxysmal events during which intense Strombolian and lava fountain activity fed vigorous channelized PaPa flows at eruption rates of up to 120 m3 s31. Each paroxysm lasted between 75 and 450 min, and was separated by periods of less intense Strombolian activity and less vigorous (610 m3 s31) effusion. Ground-based, satellite- and model-derived volumetric data show that the eruption was characterized by two periods during which eruption rates and cumulative volume showed exponential decay. This is consistent with a scenario whereby the system was depressurized during the first eruptive period (October 17^23), repressurized during an October 24 pause, and then depressurized again during the second period (October 25^28). The imbalance between the erupted and supplied volumes mean that the two periods involved the collection of 1.5^5.7U106 m3 and 1.2^ 3.6U106 m3, respectively, or an increase in the time-averaged supply to 11.6^13.6 m3 s31 and 12.5^14.9 m3 s31. Two models are consistent with the observed episodic fountaining, derived volumetric trends and calculated volume imbalance: a magma collection model and a pulsed supply model. In the former case, depressurization of a shallow reservoir cause the observed volumetric trends and foam collapse at the reservoir roof powers fountaining. In the pulsing case, variations in magma flux account for pressurization^depressurization and supply the excess volume. Increases in rise rate and volatile flux, coupled with rapid exsolution during ascent, trigger fountaining. Limiting equations that define critical foam layer volumes and magma rise rates necessary for Hawaiian-style fountaining favor the latter model.
    Description: Published
    Description: 79-95
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; lava fountaining ; eruption rates ; lava channel ; foam layers ; rise rates ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2017-04-04
    Description: Determining consistent sets of vent conditions for next expected eruptions at Vesuvius is crucial for the simulation of the sub-aerial processes originating the volcanic hazard and the eruption impact. Herewerefer to the expected eruptive scales and conditions defined in the frame of the EC Exploris project, and simulate the dynamics of magma ascent along the volcanic conduit for sub-steady phases of next eruptions characterized by intensities of the Violent Strombolian (VS), Sub-Plinian 2 (SP2), and Sub-Plinian 1 (SP1) scale. Sets of conditions for the simulations are determined on the basis of the bulk of knowledge on the past history of Vesuvius [Cioni, R., Bertagnini, A., Santacroce, R., Andronico, D., Explosive activity and eruption scenarios at Somma–Vesuvius (Italy): towards a new classification scheme. Journal of Volcanology and Geothermal Research, this issue.]. Volatile contents (H2O and CO2) are parameterized in order to account for the uncertainty in their expected amounts for a next eruption. In all cases the flow in the conduit is found to be choked, with velocities at the conduit exit or vent corresponding to the sonic velocity in the two-phase non-equilibrium magmatic mixture. Conduit diameters and vent mixture densities are found to display minimum overlapping between the different eruptive scales, while exit gas and particle velocities, as well as vent pressures, largely overlap. Vent diameters vary from as low as about 5 m for VS eruptions, to 35–55 m for the most violent SP1 eruption scale. Vent pressures can be as low as less than 1 MPa for the lowest volatile content employed of 2 wt.% H2O and no CO2, to 7–8 MPa for highest volatile contents of 5 wt.% H2O and 2 wt.% CO2 and large eruptive scales. Gas and particle velocities at the vent range from 100–250 m/s, with a tendency to decrease, and to increase the mechanical decoupling between the phases, with increasing eruptive scale. Except for velocities, all relevant vent quantities are more sensitive to the volatile content of the discharged magma for the highest eruptive scales considered.
    Description: Published
    Description: 359-365
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Vesuvius ; Numerical simulations ; Vent conditions ; Volcanic hazard ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Publication Date: 2017-04-04
    Description: The diffusion of the halogens fluorine, chlorine, and bromine was measured in a hawaiitic melt from Mt. Etna at 500 MPa and 1.0 GPa, 1250 to 1450 ºC at anhydrous conditions; the diffusion of F and Cl in the melt was also studied with about 3 wt% of dissolved water. Experiments were performed using the diffusion-couple technique in a piston cylinder. Most experiments were performed with only one halogen diffusing between the halogen-enriched and halogen-poor halves of the diffusion couple, but a few experiments with a mixture of halogens (F, Cl, Br) were also performed in order to investigate the possibility of interactions between the halogens during diffusion. Fluorine and chlorine diffusivity show a very similar behavior, slightly diverging at low temperature. Bromine diffusion is a factor of about 2 to 5 lower than the other halogens in this study. Diffusion coefficients for fluorine range between 2.3x10−11 and 1.4x10−10 m2s−1, for chlorine between 1.1x10−11 and 1.3x10−10 and for bromine between 9.4x10−12 and 6.8x10−11 m2s−1. No pressure effect was detected at the conditions investigated. In experiments involving mixed halogens, the diffusivities appear to decrease slightly (by a factor of ~ 3), and are more uniform among the three elements. However, activation energies for diffusion do not appear to differ between experiments with individual halogens or when they are all mixed together. The effect of water increases the diffusion coefficients of F and Cl by no more than a factor of 3 compared to the anhydrous melt (DF = 4.0x10−11 to 1.6x10−10 m2s−1; DCl = 3.0x10−11 to 1.9x10−10 m2s−1). Comparing our results to the diffusion coefficients of other volatiles in nominally dry basaltic melts, halogen diffusivities are about one order of magnitude lower than H2O, similar to CO2, and a factor of ~5 higher than S. The contrasting volatile diffusivities may affect the variable extent of volatile degassing upon melt depressurization and vesiculation, and can help our understanding of the compositions of rapidly grown magmatic bubbles.
    Description: NSERC Discovery grant INGV-DPC 2004-2006 Projects (V3_6 – Etna)
    Description: Published
    Description: 3570-3580
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Diffusion ; Halogens ; Basalt ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Publication Date: 2017-04-04
    Description: During an eruption at the Bocca Nuova, one of the summit craters of Mt. Etna, in October-November 1999 a part of the crater floor near its WNW rim was uplifted to form a dome-shaped feature that consisted of older lava and pyroclastics filling the crater. This endogenous dome grew rapidly over the crater rim, thus being perched precariously over the steep outer slope of the Bocca Nuova, and near-continuous collapse of its steep flanks generated swiftly moving pyroclastic avalanches over a period of several hours. These avalanches advanced at speeds of 10-20 m s-1 and extended up to 0.7 km from their source on top of lavas emplaced immediately before. Their deposits were subsequently covered by lava flows that issued from vents below the front of the dome and from the Bocca Nuova itself. Growth of the dome was caused by the vertical intrusion of magma in the marginal W part of the crater, which deformed and uplifted previously emplaced, still hot and plastically deformable eruptive products filling the crater. The resulting avalanches had all characteristics of pyroclastic flows spawned by collapse of unstable flanks of lava domes, but in this case the magma involved was of mafic (hawaiitic) composition and would have, under normal circumstances, produced fluid lava flows. The formation of the dome and the generation of the pyroclastic avalanches owe their occurrence to the rheological properties of the eruptive products filling the crater, which were transformed into the dome, and to the morphological configuration of the Bocca Nuova and its surroundings. The density contrast between successive erupted products may also have played a role. Although events of this type are to be considered exceptional at Etna, their recurrence might represent a serious hazard to visitors to the summit area.
    Description: Published
    Description: 115-128
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Bocca Nuova ; endogenous lava dome ; pyroclastic avalanches ; magma ascent ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    Publication Date: 2017-04-04
    Description: In this paper we will discuss a simplified thermodynamic description for the saturation of FeS, either liquid or solid, in magmatic melts. The Conjugated-Toop–Samis–Flood–Grjotheim model [Moretti R. and Ottonello G., 2005. Solubility and speciation of sulfur in silicate melts, the Conjugated-Toop–Samis–Flood–Grjotheim (CTSFG) model. Geochimica et Cosmochimica Acta, 69, 801–823] has furnished the theoretical reference frame, since it already accounts for the solubility of gaseous sulfur and the speciation and oxidation state of sulfur in silicate melts. We provide a new model to predict the saturation of magmatic silicate melts with an FeS phase that is internally consistent with these previous parameterizations. The derived model provides an effective sulfogeobarometer, which is superior with respect to previous models. For magmas rising from depth to surface, our appraisal of molar volumes of sulfur-bearing species in silicate melts allows us to model oxidation–reduction processes at different pressures, and sulfur concentrations for saturationwith either liquid or solid phases. In this respect, the nature of the oxygen fugacity buffer is critical. On the basis of model results on some typical compositions of volcanological interest, the sulfur contents at sulfide saturation (SCSS) have been calculated and the results duplicate the experimental observations that the SCSS is positively correlatedwith pressure forwatersaturated acidic melts and negatively correlated with pressure for water-poor basaltic melts. This new model provides fO2–fS2 pairs of FeS saturation of natural silicatemelts. In caseswhere the redox constraint is lacking, the model can be used to investigate whether the dissolved sulfur content approaches SCSS or not, and if so, to estimate at which fO2 value the silicate melt is saturated with a sulfide phase
    Description: Published
    Description: 286–298
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Sulfur ; Silicate melt ; Iron sulfide ; Chemical thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Publication Date: 2017-04-04
    Description: A Digital Terrain Model derived from high resolution Lidar data allows the determination of the morphometric and physical parameters of a lava flow erupted from the Somma–Vesuvius volcano in 1944. The downstream variation of morphometric parameters including slope, aspect, relative relief, thickness, width, and cross sectional area is analyzed, and the changes in viscosity, velocity and flow rate are estimated. The aims of the analyses are to recognize different flow surfaces, to reconstruct the flow kinematics, and to obtain information on the mechanism of emplacement. The results indicate that the 1944 lava flow can be divided in three sectors: a near vent sector (NVS) characterized by a toe-like surface, an intermediate sector (IS) with an ‘a’ātype brittle surface, and a distal sector (DS) with a sheet-like ductile surface. Lateral leveés and channels do not occur in NVS, whereas they are well developed in IS. In DS, leveés increase with an increasing distance from the vent. Fold-like surfaces occur in NVS and DS, reflecting local shortening processes due to a decrease in the slope of the substratum and overflows from the main channel. IS and DS emplaced between March 18 and 21, 1944, whereas NVS emplaced on March 19 and partly covered IS. The morphometric and physical parameters indicate that IS moved in a ‘tube’-like regime, whereas DS emplaced in a 'mobile crust' regime. The IS to DS transition is marked by an increase in velocity and the flow rate, and by a decrease in thickness, width, cross sectional area, and viscosity. This transition is due to an abrupt increase in the slope of the substratum. The estimated velocity values are in good agreement with the measurements during the 1944 eruption. The analysis used here may be extended to other lava flows. Some gravity flows (debris/mud flows, floods, and avalanches) have rheological properties and shapes similar to those of lavas, and the same process-form relationships may apply to these flows. The approach used here may be therefore useful for evaluating hazards from various gravity currents.
    Description: Published
    Description: 223–235
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: 5.4. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: Lava flow ; Gravity flow ; Lidar ; Digital Terrain Model (DTM) ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Publication Date: 2017-04-04
    Description: Intrusive degassing and recycling of degassed and dense magma at depth have been proposed for a long time at Stromboli. The brief explosive event that occurred at the summit craters on 9 January 2005 threw out bombs and lapilli that could be good candidates to illustrate recycling of shallow degassed magma at depth. We present an extensive data set on both the textures and the mineral, bulk rock and glassy matrix chemistry of the “9 Jan” products. The latter have the common shoshonitic–basaltic bulk composition of lavas and scoriae issued from typical strombolian activity. In contrast they differ by the heterogeneous chemistry of their matrix glasses and their crystal textures that testify to crystal dissolution event(s) just prior magma crystallization upon ascent and eruption. Comparison between mineral paragenesis of the natural products and experimental phase equilibria suggest water-induced magma re-equilibration. We propose that mineral dissolution is related to water enrichment of the recycled degassed magma, via differential gas bubble transfer and to some extents its physical mixing with volatile-rich magma blobs. However, all these features illustrate transient processes. Even though evidence of mineral dissolution is ubiquitous at Stromboli, its effect on the bulk magma chemistry is minor because of the subtle interplay between mineral dissolution and crystallization in magmas having comparable bulk chemistry.
    Description: Published
    Description: 325-336
    Description: JCR Journal
    Description: reserved
    Keywords: mineral dissolution ; magma chemistry ; volatiles ; trace elements ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
    Format: 1180996 bytes
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Publication Date: 2017-04-04
    Description: We investigated chemical and isotopic compositions of clinopyroxene crystals from well age-constrained juvenile scoria clasts, lava flows, and hypoabyssal magmatic ejecta representative of the whole eruptive history of the Alban Hills Volcanic District. The Alban Hills is a Quaternary ultra-potassic district that was emplaced into thick limestone units along the Tyrrhenian margin of Italy. Alban Hills volcanic products, even the most differentiated, are characterised by low SiO2 content. We suggest that the low silica activity in evolving magmas can be ultimately due to a decarbonation process occurring at the magma/limestone interface. According to the liquid line of descent we propose, the differentiation process is driven by crystallisation of clinopyroxene+leuciteFapatiteFmagnetite coupled with assimilation of a small amount of calcite and/or with interaction with crustal CO2. By combining age, chemical data, strontium and oxygen isotopic compositions, and REE content of clinopyroxene, we give insights into the evolution of primitive ultrapotassic magmas of the Alban Hills Volcanic District over an elapsed period of about 600 kyr. Geochemical features of clinopyroxene crystals, consistent with data coming from other Italian ultrapotassic magmas, indicate that Alban Hills primary magmas were generated from a metasomatized lithospheric mantle source. In addition, our study shows that the 87Sr / 86Sr and LREE/HREE of Alban Hills magmas continuously diminished during the 600–35 ka time interval of the Alban Hills eruptive history, possibly reflecting the progressive depletion of the metasomatized mantle source of magmas.
    Description: Published
    Description: 330–346
    Description: JCR Journal
    Description: reserved
    Keywords: Clinopyroxene ; 87Sr / 86Sr ; REE ; Ultrapotassic rocks ; Alban Hills ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    Publication Date: 2017-04-04
    Description: The Alban Hills ultrapotassic volcanic district is one of the main districts emplaced during Quaternary time along the Tyrrhenian margin of Italy. Alban Hills lava flows and scoria clasts are made up essentially of clinopyroxenes and leucites and their chemical composition is mostly K-foiditic. Differentiated products (MgO〈3 wt%) are characterized by low SiO2 concentration (〈50 wt%) and geochemical features indicate that this unique differentiation trend is driven by crystal fractionation plus carbonate crust interaction. Notably, the Alban Hills Volcanic District was emplaced into thick limestone units. With the aim of constraining the magmatic differentiation, we performed experiments on the Alban Hills parental composition (plagioclase-free phono-tephrite) under anhydrous, hydrous, and hydrous-carbonated conditions. Experiments were carried out at 1 atm, 0.5 GPa and 1 GPa, temperatures ranging from 1050 to 1300 °C, and H2O and CaCO3 in the starting material up to 2 and 7 wt%, respectively. The experiments performed at 0.5 GPa resulted to be the most representative of the Alban Hills plumbing system. Clinopyroxene and leucite are the main phases occurring under all the investigated conditions and the liquidus phases. Nevertheless, our experimental results demonstrate that the occurrence of CaCO3 in the starting material strongly affects phase relations. Experiments performed under hydrous conditions crystallize magnetite and phlogopite at relatively high temperature. This early crystallization drives the glass composition towards a silica enrichment, resulting in a differentiation trend moving from phono-tephritic (Alban Hills parental composition) to phonolitic compositions. This is in contrast with micro-textural evidences showing late crystallization of magnetite and phlogopite in the natural products and with the composition of the juvenile products. On the contrary, in the CaCO3-bearing experiments (i.e., simulating magma-carbonate interaction) the magnetite and phlogopite stability fields are strongly reduced. As a consequence, the melt differentiation is mainly controlled by the cotectic crystallization of clinopyroxene and leucite, resulting in a differentiation trend moving towards K-foiditic compositions. These experimental results are in agreement with micro-textural features and chemical compositions of Alban Hills natural products and with the magmatic differentiation model inferred by geochemical data. Magma-carbonate interaction is not a rare process and its occurrence has been demonstrated for different plumbing systems. However, the uniqueness of the Alban Hills liquid line of descent suggests that the efficacy of the carbonate contamination process is controlled by different factors, the dynamics of the plumbing system being one of the most important.
    Description: INGV-DPC Project V3_1 Colli Albani Project FIRB MIUR “Development of innovative technologies for the environmental protection from natural events”.
    Description: Published
    Description: On line First
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Alban Hills ; ultrapotassic rocks ; experimental petrology ; magma-carbonate interaction ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Publication Date: 2017-04-04
    Description: During 2001–2005, Mount Etna was characterized by intense eruptive activity involving the emission of petrologically different products from several vents, which involved at least two types of magma with different degrees of evolution. We investigated the ratios and abundances for noble-gas isotopes in fluid inclusions trapped in olivines and pyroxenes in the erupted products. We confirm that olivine has the most efficient crystalline structure for preserving the pristine composition of entrapped gases, while pyroxene can suffer diffusive He loss. Both the minerals also experience noble gas air contamination after eruption. Helium isotopes of the products genetically linked to the two different magmas fall in the isotopic range typical of the Etnean volcanism. This result is compatible with the metasomatic process that the Etnean mantle is undergoing by fluids from the Ionian slab during the last ten kyr, as previously inferred by isotope and trace element geochemistry. Significant differences were also observed among olivines of the same parental magma that erupted throughout 2001–2005, with 3He/4He ratios moving from about 7.0 Ra in 2001 volcanites, to 6.6 Ra in 2004–2005 products. Changes in He abundances and isotope ratios were attributed to variations in protracted degassing of the same magma bodies from the 2001 to the 2004–2005 events, with the latter lacking any contribution of undegassed magma. The decrease in 3He/4He is similar to that found from measurements carried out every fifteen days during the same period in gases discharged at the periphery of the volcano. To our knowledge this is the first time that such a comparison has been performed so in detail, and provides strong evidence of the real-time feeding of peripheral emissions by magmatic degassing.
    Description: Published
    Description: 683-690
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: fluid inclusions ; noble gases ; helium isotopes ; magma degassing ; olivine ; pyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Publication Date: 2017-04-04
    Description: The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.
    Description: In press
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; basaltic explosive activity ; ash-rich jet and plume ; tachylite ; sideromelane ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Publication Date: 2017-04-04
    Description: Our knowledge of the degassing pattern of sulphur, chlorine and fluorine during ascent and eruption of basaltic magmas is still fragmental and mainly limited to water-poor basalts. Here we model and discuss the pressure-related degassing behaviour of S, Cl and F during ascent, differentiation and extrusion of H2O–CO2-rich alkali basalt on Mount Etna (Sicily) as a function of eruptive styles. Our modelling is based on published and new melt inclusion data for dissolved volatiles (CO2, H2O, S, Cl, F) in quenched explosive products from both central conduit (1989–2001) and lateral dyke (2001 and 2002) eruptions. Pressures are obtained from the dissolved H2O and CO2 concentrations, and vapour–melt partition coefficients of S, Cl and F are derived from best fitting of melt inclusion data for each step of magma evolution. This allows us to compute the compositional evolution of the gas phase during either open or closed system degassing and to compare it with the measured composition of emitted gases. We find that sulphur, chlorine and fluorine begin to exsolve at respective pressures of ∼140 MPa, ∼100 MPa and ≤10 MPa during Etna basalt ascent and are respectively degassed at 〉95%, 22–55%, and ∼15% upon eruption. Pure open system degassing fails to explain gas compositions measured during either lateral dyke or central conduit eruptions. Instead, closed-system ascent and eruption of the volatile-rich basaltic melt well accounts for the time-averaged gas composition measured during 2002-type lateral dyke eruptions (S/Cl molar ratio of 5±1, 35% bulk Cl loss). Extensive magma fragmentation during the most energetic fountaining phases enhances Cl release (55%) and produces a lower S/Cl ratio of 3.7, as actually measured. Comparatively slower magma rise in the central conduits of Etna favours both sulphide saturation of the melt and greater chlorine release (55%), resulting in a distinct S/Cl evolution path and final ratio in eruptive gas. In both eruption types, any previous bubble–melt separation at depth leads to increased S/Cl and S/F ratios in emitted gas. High S/Cl ratios measured during some discrete eruptive events can thus be explained by transitions from closed (deep) to open (shallow) system degassing, with differential gas transfer extending down to ∼2 km depth below the vents. This depth coincides with the base of the volcanic pile where structural discontinuities and the high magma vesicularity (60%) may favour separate gas flow. Finally, the excess S–Cl–F gas discharge through Etna summit craters during non-eruptive periods requires a mixed supply from shallow magma degassing in the volcanic conduits and deeper-derived SO2-rich bubbles from the sub-volcano plumbing system. Our modelling provides a useful reference framework for interpreting the monitored variations of S, Cl and F in Mount Etna gas emissions as a function of volcanic activity. More broadly, the observations made for S, Cl and F degassing on Etna may apply to other basaltic volcanoes with water-rich magmas, such as in arcs.
    Description: Published
    Description: 772-786
    Description: reserved
    Keywords: Mt Etna ; volatiles ; magma degassing ; eruptive mechanisms ; modelling ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 663124 bytes
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Publication Date: 2017-04-04
    Description: The exceptionally persistent activity of Stromboli volcano has lasted for at least 1400 years. The normal strombolian activity is periodically interrupted by more energetic explosions (1–2 per year) and by sporadic effusive episodes (every 10–20 years). Normal activity and effusive episodes are characterized by crystal-rich high-K to shoshonitic basalts issuing from a volatile-poor shallow system. Crystal-poor pumice are emitted only during more violent explosions, and are thought to derive from deep pulses of volatile-rich magma. Shallow level degassing induces massive crystallization of deep pulses of feeding magma that, continuously mixing with the resident one, produces the crystal-rich shoshonite of the persistent activity. We examined the crystallization history of the crystal-rich, shallow reservoir using plagioclase Crystal Size Distribution (CSD) analysis of scoriae and lavas emitted in the past twenty years. CSDs show a linear dependence from crystal size in the size interval 0.06–1.2 mm; number density of larger crystals is biased by right hand truncation effects. CSDs slopes and intercepts are quite constant during the whole considered time span revealing a system that is close to the equilibrium also from a kinetic point of view. The linear crystal size distribution are reached by the system through episodes of growth and resorption, respectively occurring in the degassed and undegassed magma during the continuous mixing in the feeding system. Plagioclase net growth rate (2*10−11 cm/s) results from a balance of growth (10−10 cm/s) and resorption episodes which induce spectacular zoning and resorption textures in crystals larger than 200 μm. CSDs of mafic phases cannot be accurately acquired on each single sample due to poor counting statistics; the evaluation of pyroxene and olivine CSD on the whole data set, however, confirms the conclusions acquired from plagioclase CSDs.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: crystal size distribution ; plagioclase growth ; magma residence time ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Publication Date: 2017-04-04
    Description: Three lava flows (hereafter, flows A, B, and C) from Salina Island (Italy) consist of basaltic andesitic enclaves dispersed in a dacitic matrix. Enclaves represent 8–12 vol.% of the erupted magma. The number of enclaves and the surface covered by the enclaves at each outcrop do not vary significantly with the distance from the vent in the flows A and B. These feature reflect the dynamics of magma mingling within the reservoir and not the kinematics of the lava flow. In the flow C, these parameters vary irregularly. The statistical entropy S(t) of the enclaves, which is a measure of their spatial distribution (dispersion), is estimated in outcrops located at different distance from the vent. The Kolmogorov–Sinai entropy rate k, which describes the variations of S(t) with time, is also determined. In the lava flow A, S(t) increases linearly with time t for 0btb0.4; k is 0.04. For tN0.5, S(t) attains its maximum value and maintains constant with increasing t. In the lava flow B, S(t) linearly increases with t, and k is 0.01. In the lava flow C, there is not correlation between S(t) and t. The comparison between the results from the analysis of the Porri enclaves and those from numerical experiments on the variation of S(t) in chaotic advective mixing systems and from previous experimental models on magma mixing, allow us to draw some conclusions on dynamics of the basaltic andesite– dacite mingling in the magma chamber. Fully chaotic magma mingling systems show three evolution stages. An initial stage, which is unknown because of the disruption of the initial configuration of the interacting magmas, a second stage characterized by a linear increase of the statistical entropy with time, and a third stage, in which the uniformity of the system is reached, and the entropy does not vary with increasing time. A system in which the uniformity is never attained, is characterized by irregular variations of S(t) with time. In the flows A and B, the relations between S(t) and t are consistent with those of a fully chaotic dynamics possibly associated to convection. The basaltic andesite was uniformly distributed in the dacitic host due to the occurrence of convective movements driven by the injection of the basaltic andesite within the dacitic chamber. The mingling system recorded by the lava flow A evolved with a higher rate with respect to that of the flow B. This suggests that chaotic advection (stirring and folding) is more efficient in the magmatic system A than in B. On the contrary, the mingling system C is characterized by a non-uniform distribution of the basaltic andesite within dacite. This reflects the occurrence of a dynamics in which stirring and folding processes do not operate efficiently and are unable to uniformly distribute the dispersed phase within the continuous one. The decrease of k from A to B, and the lack of a measurable k in C, along with the observation that A and B were emitted before C, indicate that the efficiency of advective movements within the Porri magma chamber declined with decreasing time. Mingled magmas characterized by a homogeneous spatial distribution of enclaves or an initially inhomogeneous distribution evolving towards a homogeneous one are indicative of efficient advection processes that may favor magma mixing. Mingled magmas characterized by an inhomogeneous distribution of enclaves suggest low dynamical interaction between the two end-members. Magma mixing is not allowed.
    Description: Published
    Description: 128–140
    Description: JCR Journal
    Description: reserved
    Keywords: volcanology ; petrology ; magma mingling ; enclaves ; lava flows ; entropy ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Publication Date: 2017-04-04
    Description: On 28 December 2002, the persistent Strombolian activity at Stromboli was interrupted by the sudden onset of lava emission onto the Sciara del Fuoco slope, a horseshoe-shaped depression on the NW flank of the volcano. The effusive episode went on until 22 July 2003 and produced a cumulative volume of lavas of 11×106 m3 ranking the event as the largest occurred in the past 30 years. The eruptive vents were mainly located in the NE sector of the Sciara del Fuoco depression, at an elevation of 550–600 m a.s.l. On 30 December, the eastern portion of the Sciara del Fuoco collapsed producing a tsunamigenic landslide. On 5 April 2003, a paroxysmal eruption occurred at the summit craters during which crystal-poor pumiceous products were emitted. The paroxysm did not interrupt the lava emission. The Strombolian activity at the summit craters gradually resumed starting from March 2003 and fully recovered by the end of July. Periodic sampling of the lava at the active vents was carried out during the entire effusive event. All the analysed samples are shoshonitic basalts (SiO2 48.5–50.4 wt.%; K2O 2.1–2.4 wt.%) in the range of composition observed in the products erupted during the past 20 years. They bear about 50 vol.% zoned crystals of plagioclase An90–60, diopside–augite and olivine Fo70–73 in a compositionally homogeneous shoshonitic groundmass. Bulk rock major and trace element contents measured with different methodologies at different laboratories show only minor variations. Sr and Nd isotope ratios are close to those of the crystal-rich scoriae erupted in the previous years. Despite of small compositional variations related to the emptying of the zoned topmost portion of the conduit, the data show that the switch from Strombolian explosive to effusive activity is not associated with changes of the textures and composition of the erupted products. Slight but somehow systematic variation of trace elements and isotope ratios between products erupted before and after the 5 April eruption are likely accounted by limited mixing between the fresh, volatile-rich, crystal-poor, magma erupted as pumice during the paroxysm, and the volatile-poor, crystal-rich magma feeding the lava flow. The uniform composition of the erupted lava indicates the presence of a large volume of well-mixed, crystal-rich, homogeneous magma residing in the shallow plumbing system of the volcano. Two possible trigger mechanism of the effusive event are here proposed: (i) a discrete input of fresh magma into the lower part of the shallow magmatic system occurred some months before the eruption and was followed by crystallisation, degassing and mixing with the crystal-rich shallow magma which re-homogenised the system. These processes eventually led to the rise of the magma at a higher level and failure of the conduit walls. (ii) The onset of the effusion may represent the consequence of a gradual rise of the magma level in the conduits occurred in the past two decades. The process of progressive refilling, initiated after the 1985 effusive eruption, ultimately culminated on 28 December 2002 with the failure of the conduit wall and the opening of vents 100–150 m below the summit craters
    Description: Published
    Description: 263-284
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; Aeolian Islands ; 2002–2003 eruption ; Mineralogy ; Geochemistry ; Sr isotope ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Publication Date: 2017-04-04
    Description: The exceptionally persistent activity of Stromboli volcano has lasted for at least 1400 years. The normal strombolian activity is periodically interrupted by more energetic explosions (1–2 per year) and by sporadic effusive episodes (every 10–20 years). Normal activity and effusive episodes are characterized by crystal-rich high-K to shoshonitic basalts issuing from a volatile-poor shallow system. Crystal-poor pumice are emitted only during more violent explosions, and are thought to derive from deep pulses of volatile-rich magma. Shallow level degassing induces massive crystallization of deep pulses of feeding magma that, continuously mixing with the resident one, produces the crystal-rich shoshonite of the persistent activity. We examined the crystallization history of the crystal-rich, shallow reservoir using plagioclase Crystal Size Distribution (CSD) analysis of scoriae and lavas emitted in the past twenty years. CSDs show a linear dependence from crystal size in the size interval 0.06–1.2 mm; number density of larger crystals is biased by right hand truncation effects. CSDs slopes and intercepts are quite constant during the whole considered time span revealing a system that is close to the equilibrium also from a kinetic point of view. The linear crystal size distribution are reached by the system through episodes of growth and resorption, respectively occurring in the degassed and undegassed magma during the continuous mixing in the feeding system. Plagioclase net growth rate (2 × 10− 11 cm/s) results from a balance of growth (10− 10 cm/s) and resorption episodes which induce spectacular zoning and resorption textures in crystals larger than 200 μm. CSDs of mafic phases cannot be accurately acquired on each single sample due to poor counting statistics; the evaluation of pyroxene and olivine CSD on the whole data set, however, confirms the conclusions acquired from plagioclase CSDs.
    Description: Published
    Description: 86-98
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: crystal size distribution ; plagioclase growth ; magma residence time ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Publication Date: 2017-04-04
    Description: The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcanotectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.
    Description: Published
    Description: 289-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; tectonics ; fisssure eruptions ; columnar basalt ; fault escarpment ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
    Publication Date: 2017-04-04
    Description: The recent eruption of Stromboli in February–April 2007 offered a unique chance to test our current understanding of processes driving the transition from ordinary (persistent Strombolian) to effusive activity, and the ability of instrumental geophysical and geochemical networks to interpret and predict these events. Here, we report on the results of two years of in-situ sensing of the CO2/SO2 ratio in Stromboli's volcanic gas plume, in the attempt to put constraints on the trigger mechanisms and dynamics of the eruption. We show that large variations of the plume CO2/SO2 ratio (range, 0.9–26) preceded the onset of the eruption (since December 2007), interrupting a period of relatively-steady and low ratios (time-averaged ratio, 4.3) lasting from at least May to November 2006. By contrasting our observations with numerical simulations of volcanic degassing at Stromboli, derived by use of an equilibrium saturation model, we suggest that the pre-eruptive increase of the ratio reflected an enhanced supply of deeply-derived CO2-rich gas bubbles to the shallowplumbing system. This larger-than-normal ascent of gas bubbles was likely sourced by a 1–3 km deep gas– melt separation region (probably a magma storage zone), and caused faster convective overturning of magmas in the shallow conduit; an increase in the explosive rate and in seismic tremor, and finally the collapse of the la Sciara del Fuoco sector triggering the effusive phase. The high CO2/SO2 ratios (up to 21) observed during the effusive phase, and particularly in the days and hours before a paroxysmal explosion on March 15, 2007, indicate the persistence of the same gas source; and suggest that de-pressurization of the same 1–3 km deep magma storage zone could have been the trigger mechanism for the paroxysm itself
    Description: In press
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; plume chemistry ; magma degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...