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  • Other Sources  (190)
  • Elsevier  (180)
  • Inst. f. Geophys., Ruhr-Univ. Bochum
  • Universität Göttingen,Abteilung Bodenphysik
  • 2010-2014  (176)
  • 1980-1984  (14)
  • 2010  (176)
  • 1981  (14)
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  • 2010-2014  (176)
  • 1980-1984  (14)
Year
  • 1
    Publication Date: 2021-03-29
    Description: According to a model by Cerling (1991, 1999), the carbon isotope composition of calcretes should depend on the soil type and the CO2-concentration in the atmosphere. We have tested Cerling’s model by investigating 14 Palaeozoic sections with soil profiles. A large number of carbonate types of different genetic origin exist in the localities examined. Comparing the Palaeozoic samples with recent and subrecent calcretes, it can be demonstrated that anhedral, cryptocrystalline (〈10 μm) and subhedral microcrystalline (10 - 40 μm) carbonates are clearly of pedogenic origin. Crystals of larger size with a poikilotopic texture are of groundwater or burial diagenetic origin. Macro- and micromorphological features, typical of recent calcretes, occur in several soil profiles, but thin section microscopy reveals a strong diagenetic overprint of most pedogenic carbonates. Time equivalent sections with comparable soil types (protosols, calcisols and vertisols) show large variations in carbon isotope composition. On the other hand, different carbonate generations at one site do not differ much. Therefore Palaeozoic calcretes appear to be unsuitable for a deduction of the Palaeozoic CO2-concentration.
    Description: German Research Foundation (DFG)
    Description: research
    Keywords: 551.9 ; 552.5 ; VKB 350 ; VJJ 110 ; VCA 300 ; VKB 332 ; VKA 300 ; VKB 371 ; VEA 000 ; VKB 372 ; Lithogenese {Sedimentologie} ; Geochemie der Stabilen Isotopen ; Paläozoische Geologie ; Sedimentationsbedingungen ; Petrogenese ; Klastische Sedimentgesteine ; Europa insgesamt {Geologie} ; Karbonatische Sedimentgesteine ; Kohlenstoffkreislauf ; C-isotope ; Jungpaläozoikum ; Paläopedologie ; Kalkkruste ; CO2 ; calcrete ; carbon cycle ; upper Paleozoic ; paleosol ; C-13/C-12 ; Europa ; paläoklima ; Europe ; 38.41 ; 38.61 ; 38.32
    Language: English
    Type: article
    Format: application/pdf
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  • 2
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    Universität Göttingen,Abteilung Bodenphysik
    In:  Universität Göttingen
    Publication Date: 2024-04-26
    Description: research
    Keywords: Wasserhaushalt ; Bodenphysik ; Physikochemische Bodeneigenschaft ; Hydrodynamik Hochebene ; Pseudogley ; Waldboden
    Language: German
    Type: doc-type:book
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  • 3
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    Universität Göttingen,Abteilung Bodenphysik
    In:  Universität Göttingen
    Publication Date: 2024-04-26
    Description: research
    Keywords: Pflanzensoziologie ; Waldgesellschaft ; Ostalpen ; Exkursion Italien ; Waldpflanzen ; Forst Ostalpen ; Vegetation ; Italienische Alpen ; Oberitalien
    Language: German
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  • 4
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    Universität Göttingen,Abteilung Bodenphysik
    In:  Universität Göttingen
    Publication Date: 2024-04-25
    Description: research
    Keywords: Plantagenwirtschaft ; Teakbaumplantage ; Nährstoffhaushalt ; Forstlicher Standort ; Caparo ; Venezuela
    Language: German
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  • 5
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    Universität Göttingen,Abteilung Bodenphysik
    In:  Universität Göttingen
    Publication Date: 2024-05-03
    Description: research
    Keywords: NITROGEN FERTILIZERS ; NEUTRAL SOlLS ; ACID LOESS SOlLS ; BEHAVIOUR OF NITROGEN FERTILIZERS
    Language: English
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  • 6
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    Universität Göttingen,Abteilung Bodenphysik
    In:  Universität Göttingen
    Publication Date: 2024-05-20
    Description: thesis
    Keywords: Dissertation
    Language: German
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  • 7
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    Elsevier
    In:  Bull., Polar Proj. OP-O3A4, Computer-aided Seismic Analysis and Discrimination, London, Elsevier, vol. 16, no. 4, pp. 97-109, (ISBN 0080419208)
    Publication Date: 1981
    Keywords: Group veloc. ; Velocity analysis
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  • 8
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    Inst. f. Geophys., Ruhr-Univ. Bochum
    In:  Wissenschaftl. Veröffentl. (Reihe B), Hrsg. H.-P. Harjes, Atlanta, Inst. f. Geophys., Ruhr-Univ. Bochum, vol. 10, no. PL-TR-91-2127, pp. 1219-1222
    Publication Date: 1981
    Keywords: BUG ; ERDSTOSS (see also rockburst and Gebirgsschlag) ; Mining geophysics ; GEBIRGSSCHLAG (see also rockburst and Erdstoss) ; Earthquake catalog ; Rock bursts (see also ERDSTOSS and GEBIRGSSCHLAG) ; Local earthquakes
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  • 9
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    Inst. f. Geophys., Ruhr-Univ. Bochum
    In:  Dissertation, Berichte, Bochum, Inst. f. Geophys., Ruhr-Univ. Bochum, vol. 10, no. 9, pp. 1109-1111
    Publication Date: 1981
    Keywords: Geomagnetics ; Plate tectonics ; Borehole geophys.
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  • 10
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    Inst. f. Geophys., Ruhr-Univ. Bochum
    In:  Diplomarbeit, Rome, Inst. f. Geophys., Ruhr-Univ. Bochum, vol. 10, no. 13, pp. 1431-1434, (ISBN 0 08 042822 3)
    Publication Date: 1981
    Keywords: Velocity ; Physical properties of rocks ; Laboratory measurements ; Instruments ; Wohrl
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  • 11
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    Inst. f. Geophys., Ruhr-Univ. Bochum
    In:  Diplomarbeit, Tokyo, Inst. f. Geophys., Ruhr-Univ. Bochum, vol. C 560, 183 pp., no. 29, pp. 1321-1323, (ISBN 3-933346-037)
    Publication Date: 1981
    Keywords: SEModelling ; Channel waves ; Mining geophysics ; Rayleigh waves ; Kuhbach
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  • 12
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    Inst. f. Geophys., Ruhr-Univ. Bochum
    In:  Dissertation, Berichte, Houston, Inst. f. Geophys., Ruhr-Univ. Bochum, no. 10, pp. 103-155
    Publication Date: 1981
    Keywords: Stress ; cracks and fractures (.NE. fracturing) ; Fracture ; Laboratory measurements
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  • 13
    Publication Date: 2017-07-18
    Description: The granule floatation is a serious issue of the anammox (anaerobic ammonium oxidation) process when high loading rates are applied that results in instability or even system collapse. The present study reports the granule floatation in an anammox reactor when high loading rates were applied. The comparison of enlarged photos taken for the settling and floating granules showed that the two kinds of granules both contained macroscopic gas pockets accounting for 11 +/- 14% of total volume. The settling granules had gas tunnels that could release the gas bubbles, while the floating granules did not. The presence of gas bubbles enclosed in the gas pockets led to the small density of 979.2 +/- 15.8 mg L(-1) and flotation of anammox granules. Consequently, the flotation caused washout of anammox granules and the deterioration of anammox process (volumetric removal rate decreased from 4.00 to 2.46 kg N m(-3) d(-1)). The collection of floating granules, breaking them into small pieces and then returning to the anammox reactor proved an effective control strategy. The volumetric removal rate was finally up to 16.5 kg N m(-3) d(-1) after the control strategy was put into use.
    Type: Article , PeerReviewed
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  • 14
    Publication Date: 2018-03-06
    Description: A geochemical proxy for surface ocean nutrient concentrations recorded in coral skeleton could provide new insight into the connections between sub-seasonal to centennial scale nutrient dynamics, ocean physics, and primary production in the past. Previous work showed that coralline P/Ca, a novel seawater phosphate proxy, varies synchronously with annual upwelling-driven cycles in surface water phosphate concentration. However, paired contemporaneous seawater phosphate time-series data, needed for rigorous calibration of the new proxy, were lacking. Here we present further development of the P/Ca proxy in Porites lutea and Montastrea sp. corals, showing that skeletal P/Ca in colonies from geographically distinct oceanic nutrient regimes is a linear function of seawater phosphate (PO4 SW) concentration. Further, high-resolution P/Ca records in multiple colonies of Pavona gigantea and Porites lobata corals grown at the same upwelling location in the Gulf of Panamá were strongly correlated to a contemporaneous time-series record of surface water PO4 SW at this site (r2 = 0.7–0.9). This study supports application of the following multi-colony calibration equations to down-core records from comparable upwelling sites, resulting in ±0.2 and ±0.1 μmol/kg uncertainties in PO4 SW reconstructions from P. lobata and P. gigantea, respectively. Inter-colony agreement in P/Ca response to PO4 SW was good (±5–12% about mean calibration slope), suggesting that species-specific calibration slopes can be applied to new coral P/Ca records to reconstruct past changes in surface ocean phosphate. However, offsets in the y-intercepts of calibration regressions among co-located individuals and taxa suggest that biologically-regulated “vital effects” and/or skeletal extension rate may also affect skeletal P incorporation. Quantification of the effect of skeletal extension rate on P/Ca could lead to corrected calibration equations and improved inter-colony P/Ca agreement. Nevertheless, the efficacy of the P/Ca proxy is thus supported by both broad scale correlation to mean surface water phosphate and regional calibration against documented local seawater phosphate variations.
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  • 15
    Publication Date: 2018-06-26
    Description: We present the latest 3D velocity field of the Fennoscandian glacial isostatic adjustment (GIA) process from BIFROST. It is derived from more than 4800 days (13 years) of data at more than 80 permanent GPS sites. We use the GAMIT/GLOBK and the GIPSY/OASIS II software packages for GPS analysis and compare the results. The solution has an internal accuracy at the level of 0.2 mm/year (1 sigma) for horizontal velocities at the best sites. We also present a revised GIA prediction model. At the best sites, the optimal model agrees with the observations to within 0.4 mm/year. However, the model systematically overpredicts the magnitude of horizontal rates in the north. We discuss limitations in computed and presented GNSS station velocities, where especially possible instability over time causing non-linear pattern in vertical time series are considered. In extension, preliminary results from an investigation applying revised analysis strategies on a sparse subset of the database are presented, indicating possible improvements for the future.
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  • 16
    Publication Date: 2018-03-08
    Description: The flow of groundwater beneath barrier islands has been cited as a possible pathway for salt water and chemical exchange between a protected embayment and the open sea. Evidence is presented that identifies an exchange of groundwater through a highly permeable paleoinlet along the barrier beach of Cavallino, which separates the northern Venice Lagoon from the Adriatic Sea. We utilized both point measurements of submarine groundwater discharge (SGD) and a geophysical investigation of the subsurface resistivity to analyze the movement of saline groundwater. Discharge of groundwater and associated nutrients, was higher at the site of a former inlet than at a similar site along the barrier and modulated by the difference in tidal water level between the lagoon and Adriatic Sea. If the measured conditions are typical, storm surge barriers could potentially result in a saline groundwater flow of up to 1.5×106 m3 d−1 into the lagoon.
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  • 17
    Publication Date: 2017-11-24
    Description: Like other low-elevation passive margins, the French Atlantic margin is characterized by a gradual topographic transition from the coast to low-altitude interior plains or plateaus. Here we propose a morphostratigraphic analysis to constrain long-term landscape evolution and denudation rates, through the characterization of palaeotopographies and related palaeoweatherings in an area restricted to the southeast Armorican Massif. Two regional-scale palaeosurfaces are recognized: (i) the Infraliassic palaeosurface, the truncated weathering profiles of which are sealed by Liassic marine deposits; (ii) the Eocene palaeosurface, underlain by thick kaolinite- and iron-rich palaeosaprolites and by siliceous duricrusts (silcretes). Quantitative constraints on large-scale tectonic uplift and long-term denudation are obtained from these morphostratigraphic markers. Mean uplift and denudation rates calculated on post-Eocene times range between 0.5 and 2 m.Ma-1. These low values imply high landscape stability of the inland margin over most of the Cenozoic.
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  • 18
    Publication Date: 2018-05-04
    Description: The objective of this study was to investigate the geochemical and hydrogeological effects of earthquakes on fluids in aquifers, particularly in a seismically active area such as Eskisehir (Turkey) where the Thrace–Eskisehir Fault Zone stretches over the region. The study area is also close to the North Anatolian Fault Zone generating devastating earthquakes such as the ones experienced in 1999, reactivating the Thrace–Eskisehir Fault. In the studied area, Rn and CO2 gas concentrations, redox potential, electrical conductivity, pH, water level, water temperature, and the climatic parameters were continuously measured in five stations for about a year. Based on the gathered data from the stations, some ambiguous anomalies in geochemical parameters and Rn concentration of groundwater were observed as precursors several days prior to an earthquake. According to the mid-term observations of this study, well-water level changes were found to be a good indicator for seismic estimations in the area, as it comprises naturally filtered anomalies reflecting only the changes due to earthquakes. Also, the results obtained from this study suggest that both the changes in well-water level and gas–water chemistry need to be interpretated together for more accurate estimations. Valid for the studied area, it can be said that shallow earthquakes with epicentral distances of 〈30 km from the observation stations have more influence on hydrochemical parameters of groundwater and well-water level changes. Although some hydrochemical anomalies were observed in the area, it requires further observations in order to be able to identify them as precursors.
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  • 19
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    Elsevier
    In:  Journal of Environmental Radioactivity, 101 (7). pp. 519-520.
    Publication Date: 2018-03-08
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  • 20
    Publication Date: 2018-03-15
    Description: A novel flow injection ion chromatograph (FI-IC) system has been developed to fully automate pretreatment procedures for multi-elemental analysis of trace metals in seawater by inductively coupled plasma mass spectrometer (ICPMS). By combining 10-port, 2 position and 3-way valves in the FI-IC manifold, the system effectively increase sample throughput by simultaneously processing three seawater samples online for: sample loading, injection, buffering, preconcentration, matrix removal, metal elution, and sample collection. Forty-two seawater samples can be continuously processed without any manual handing. Each sample pretreatment takes about 10 min by consuming 25 mL of seawater and producing 5 mL of processed concentrated samples for multi-elemental offline analysis by ICPMS. The offline analysis improve analytical precision and significantly increase total numbers of isotopes determined by ICPMS, which include the metals Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Ti, V, and Zn. The blank value and detection limits of trace metals using the system with ICPMS analysis all range from 0.1 to 10 parts per trillion (ppt), except Al, Fe, and Zn. The accuracy of the pretreatment system was validated by measuring open-ocean and coastal reference seawater, NASS-5 and CASS-4. Using the system with ICPMS analysis, we have obtained reliable trace metal concentrations in the water columns of the South China Sea. Possessing the features of full automation, high throughput, low blank, and low reagent volume used, the system automates and simplifies rigorous and complicated pretreatment procedures for multi-elemental analysis of trace metals in seawater and effectively enhances analytical capacity for trace metal analysis in environmental and seawater samples.
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  • 21
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    Elsevier
    In:  Geochimica et Cosmochimica Acta, 74 (23). pp. 6801-6813.
    Publication Date: 2017-03-09
    Description: Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ65Cu, δ66Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g−1 Cu and 2084 μg g−1 Zn in the organic horizons. The δ65Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ66ZnIRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ66Zn values occur, probably caused by biogeochemical fractionation in the soil–plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ66Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ66Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.
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  • 22
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    Elsevier
    In:  Precambrian Research, 183 (1). pp. 44-49.
    Publication Date: 2020-06-10
    Description: The sensitive high-resolution ion microprobe (SHRIMP) developed at the Australian National University (ANU) was the first of the high-resolution ion microprobes. The impact of this instrument on geochronological research over the last twenty years has been immense. This is particularly so for lunar geochronology where it has opened up avenues of research that were not possible using conventional TIMS techniques. The great advantage of SHRIMP is that it provides a means for determining precise U–Pb isotopic ratios on selected micron-size areas on polished grains of zircon and other U-bearing minerals. One of the first projects undertaken on the newly invented SHRIMP I was an investigation of U–Pb ages of lunar zircon. Using SHRIMP, multiple analyses could be made on areas of individual zircons to test the stability of U–Pb systems in shocked grains. Also, by analysing grains “in situ”, textural relationships between the analysed zircon and the components of the sample breccia could be used in the interpretation of the SHRIMP data. As a result of this research it was realised that most lunar zircons have ages up to 500Ma older than the Imbrium and Serenitatis impacts at ca. 3.9 Ga, demonstrating that the zircons have not been affected by the these impact events although heating and shock effects have profoundly disturbed other dating systems. This has opened the way for research into the early lunar magmatic and bombardment record. For example, recent SHRIMP results have revealed profound differences in the ages of zircons from breccias from the Apollo 14 and Apollo 17 sample sites, raising new questions about the evolution of lunar magmatism. Also, multiple SHRIMP analyses on complex lunar zircons have shown that these grains can record U–Pb disturbance by later impact events. SHRIMP U–Pb age determinations on phosphates in lunar meteorites has identified lunar events not recognised in samples from the Apollo program. SHRIMP-based research on lunar materials is ongoing and, in combination with other chemical and structural evidence, continues to stimulate new ideas on the early evolution of the Moon.
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  • 23
    Publication Date: 2018-03-08
    Description: Geochemical cycles occurring at the interface between terrestrial and marine groundwaters, in the so-called subterranean estuary (STE), are not well understood for most elements. This is particularly true of the transition metals, many of which have particular ecological relevance as micronutrients or toxicants. To gain a first approximation of trace metal geochemistry in the mixing zone, we examined the distribution of nine dissolved metals (Fe, Mn, Mo, V, Co, Ni, Cu, Pb, and Al) through a shallow STE in Great South Bay, New York, USA. We also performed a simple kinetic and chemical separation of labile and organic-complexed metal species in the STE. Dissolved Mn showed marked subsurface enrichment (up to 755 µM at 15 cm depth) that was suggestive of diagenetic remobilization. Dissolved Fe, however, was higher by more than three orders-of-magnitude in fresh groundwater (90 µM) as compared to marine groundwater (0.02 µM), and pH-mediated removal was evident as slightly acidic fresh groundwater (pH 6.8) mixed with marine groundwater (pH ∼ 8.0). Dissolved Mo, Co, and Ni were primarily cycled with Mn, and highly elevated concentrations relative to bay surface waters (up to 300, 75, and 44 nM, respectively) were observed in the STE. High levels of dissolved Pb (up to 4250 pM) observed in the fresh groundwater were nearly quantitatively removed within the salinity mixing zone, in conjunction with marked reduction of dissolved Al. Dissolved Cu exhibited non-conservative removal throughout the STE, and was correlated with the redox potential of the porewaters. Substantial percentages (〉 15%) of organic-metal species were only observed for Cu and Ni, suggesting that these complexes were not generally very important for metal cycling in the STE. Kinetically labile species were observed for all metals examined except Cu and Pb, and represented an approximately constant proportion (between 10% and 70%) of the total dissolved pool for each metal, indicating equilibrium between labile and non-labile species throughout the mixing zone. The non-conservative behavior observed for all metals examined in this study suggests that reactions occurring in the STE are vastly important to the source/sink function of permeable sediments, and studies seeking to quantify SGD-derived trace metal fluxes must take into account biogeochemical processes occurring in the subterranean estuary.
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  • 24
    Publication Date: 2018-03-08
    Description: Ra isotopes are a powerful tool for quantifying the flux of submarine groundwater discharge (SGD) into the sea. Previous studies of 223Ra and 224Ra mass balances in coastal embayments have shown that the Ra balance is dominated by supply via SGD, exchange with the open ocean and radioactive decay. The current study shows that a single time series over a tidal cycle at the principal inlet to Great South Bay (NY, US) is sufficient to determine the net flux of Ra across the inlet, and also can be used to estimate the decay of short-lived Ra in the bay. Estimates of the net Ra flux obtained from a single tidal time-series by using three different approaches agree with those determined from a more time-consuming survey of Ra within the bay, and may represent a first step of estimating SGD in bays and coastal lagoons.
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  • 25
    Publication Date: 2017-12-04
    Description: Core PRAD 1-2, located on the western flank of the Mid-Adriatic Deep, contains a continuous sediment record extending back to upper MIS-11. The upper part of the record which spans the mid Holocene to MIS 5–4 (the last ca 105,000 years) has been investigated for tephra content. A total of 25 discrete tephra layers were discovered, only one of which was visible in the core sequence. The other 24 are not visible to the naked eye, nor were the majority detected by routine down-core scanning methods. A total of 625 geochemical measurements obtained from individual glass shards using WDS-EPMA enabled 21 of the 25 tephras to be assigned to known volcanic events emanating from the Campanian Province (Campi Flegrei, Somma-Vesuvius and Ischia Island). The results provide an independent basis for establishing an age–depth profile for the upper part of the PRAD 1-2 record. This study demonstrates that the number of non-visible tephra layers can significantly exceed the number of visible layers in some deep marine sequences. Routine testing for the presence of non-visible tephra layers can therefore prove rewarding, leading to the detection of additional isochrons for dating and correlating marine sequences, and for their synchronisation with terrestrial records.
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  • 26
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    Elsevier
    In:  Geochimica et Cosmochimica Acta, 74 (13). pp. 3735-3750.
    Publication Date: 2018-02-22
    Description: Calcium isotopes in tissues are thought to be influenced by an individual’s diet, reflecting parameters such as trophic level and dairy consumption, but this has not been carefully assessed. We report the calcium isotope ratios (δ44/42Ca) of modern and archaeological animal and human bone (n = 216). Modern sheep raised at the same location show 0.14 ± 0.08‰ higher δ44/42Ca in females than in males, which we attribute to lactation by the ewes. In the archaeological bone samples the calcium isotope ratios of the herbivorous fauna vary by location. At a single site, the archaeological fauna do not show a trophic level effect. Humans have lower δ44/42Ca than the mean site fauna by 0.22 ± 0.22‰, and the humans have a greater δ44/42Ca range than the animals. No effect of sex or age on the calcium isotope ratios was found, and intra-individual skeletal δ44/42Ca variability is negligible. We rule out dairy consumption as the main cause of the lower human δ44/42Ca, based on results from sites pre-dating animal domestication and dairy availability, and suggest instead that individual physiology and calcium intake may be important in determining bone calcium isotope ratios.
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  • 27
    Publication Date: 2017-08-07
    Description: Porangahau Ridge, located offshore the Wairarapa on the Hikurangi Margin, is an active ocean-continent collision region in northeastern New Zealand coastal waters. Bottom simulating reflections (BSRs) in seismic data indicate the potential for significant gas hydrate deposits across this part of the margin. Beneath Porangahau Ridge a prominent high-amplitude reflection band has been observed to extend from a deep BSR towards the seafloor. Review of the seismic data suggest that this high-amplitude band is caused by local shoaling of the base of gas hydrate stability due to advective heat flow and it may constitute the location of elevated gas hydrate concentrations. During R/V Tangaroa cruise TAN0607 in 2006 heat flow probing for measurements of vertical fluid migration, sediment coring for methane concentrations, and additional seismic profiles were obtained across the ridge. In a subsequent 2007 expedition, on R/V Sonne cruise SO191, a controlled source electromagnetic (CSEM) experiment was conducted along the same seismic, geochemical, and heat flow transect to reveal the electrical resistivity distribution. CSEM data highlight a remarkable coincidence of anomalously high resistivity along the western, landward flank of the ridge which point to locally higher gas hydrate concentration above the high amplitude reflection band. Measured sediment temperature profiles, also along the western flank, consistently show non-linear and concave geothermal gradients typical of advective heat flow. Geochemical data reveal elevated methane concentrations in surface sediments concomitant with a rapid decline in sulfate concentrations indicating elevated methane flux and oxidation of methane in conjunction with sulfate reduction at the landward ridge base. Together, these data sets suggest that the western rim of Porangahau Ridge is a tectonically driven zone of rising fluids that transport methane and cause an upward inflection of the base of gas hydrate stability and the formation of locally enriched gas hydrate above the reflective zone.
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  • 28
    Publication Date: 2016-09-19
    Description: The relationship of sea-level changes and short-term climatic changes with turbidite deposition is poorly documented, although the mechanisms of gravity-driven sediment transport in submarine canyons during sea-level changes have been reported from many regions. This study focuses on the activity of the Dakar Canyon off southern Senegal in response to major glacial/interglacial sea-level shifts and variability in the NW-African continental climate. The sedimentary record from the canyon allows us to determine the timing of turbidite events and, on the basis of XRF-scanning element data, we have identified the climate signal at a sub-millennial time scale from the surrounding hemipelagic sediments. Over the late Quaternary the highest frequency in turbidite activity in the Dakar Canyon is confined to major climatic terminations when remobilisation of sediments from the shelf was triggered by the eustatic sea-level rise. However, episodic turbidite events coincide with the timing of Heinrich events in the North Atlantic. During these times continental climate has changed rapidly, with evidence for higher dust supply over NW Africa which has fed turbidity currents. Increased aridity and enhanced wind strength in the southern Saharan–Sahelian zone may have provided a source for this dust.
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  • 29
    Publication Date: 2020-03-24
    Description: Vertical distributions of iron and iron binding ligands were determined in 2 size classes (dissolved 〈 0.2 μm, soluble 〈 200 kDa, e.g., ~ 0.03 μm) in the Southern Ocean. Colloidal iron and complexing capacity (〉 200 kDa–〈 0.2 μm) were inferred as the difference between the dissolved and soluble fractions. Dissolved iron and ligands exist primarily in the soluble size range in the surface waters, although iron-complexing colloids still represent a significant portion of the dissolved pool and this fraction increases markedly with depth. This work presents evidence for the colloidal nature of a significant portion (37–51% on average) of the ‘dissolved’ organic Fe pool in these oceanic waters. From the data it was not possible to discern whether iron colloids exist as discrete organic complexes and/or inorganic amorphous colloids. Iron-complexing colloids are the most saturated with iron at the thermodynamic equilibrium, whereas soluble organic ligands occur in larger excess compared to soluble iron. It suggests that the exchangeable fraction for iron uptake through dissociation of Fe complexes likely occurs in the soluble fraction, and that soluble ligands have the potential to buffer iron inputs to surface waters whereas iron colloids may aggregate and settle. Expectations based on Fe diffusion rates, distributions and the stability of the soluble iron complexes and iron colloids also suggest that the weaker soluble Fe complexes may be more bio-available, while the strongest colloids may be a major route for iron removal from oceanic waters. Investigations of the size classes of the dissolved organic iron thus can significantly increase our understanding of the oceanic iron cycle.
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  • 30
    Publication Date: 2017-09-27
    Description: Accurate constraints on past ocean temperatures and compositions are critical for documenting climate change and resolving its causes. Most proxies for temperature are not thermodynamically based, appear to be subject to biological processes, require regional calibrations, and/or are influenced by fluid composition. As a result, their interpretation becomes uncertain when they are applied in settings not necessarily resembling those in which they were empirically calibrated. Independent proxies for past temperature could provide an important means of testing and/or expanding on existing reconstructions. Here we report measurements of abundances of stable isotopologues of calcitic and aragonitic benthic and planktic foraminifera and coccoliths, relate those abundances to independently estimated growth temperatures, and discuss the possible scope of equilibrium and kinetic isotope effects. The proportions of 13C–18O bonds in these samples exhibits a temperature dependence that is generally similar to that previously been reported for inorganic calcite and other biologically precipitated carbonatecontaining minerals (apatite from fish, reptile, and mammal teeth; calcitic brachiopods and molluscs; aragonitic coral and mollusks). Most species that exhibit non-equilibrium 18O/16O (d18O) and 13C/12C (δ13C) ratios are characterized by 13C–18O bond abundances that are similar to inorganic calcite and are generally indistinguishable from apparent equilibrium, with possible exceptions among benthic foraminiferal samples from the Arctic Ocean where temperatures are near-freezing. Observed isotope ratios in biogenic carbonates can be explained if carbonate minerals generally preserve a state of ordering that reflects the extent of isotopic equilibration of the dissolved inorganic carbon species.
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  • 31
    Publication Date: 2013-05-15
    Description: Climate-dependent chemical weathering trends have a strong impact on the dissolved Pb isotopic composition of continental runoff during glacial terminations, so that this tracer can be used to reconstruct the impact of the North American deglaciation on aspects of freshwater runoff and ocean chemistry. Here we present authigenic Fe–Mn oxyhydroxide-derived Pb isotope records from lower Laurentian Fan sediments that trace the local deglacial continental runoff signal through the Gulf of St. Lawrence. We use these records to investigate changes in the Pb isotopic composition of the North American runoff, and their relationship to deglacial processes. The new Pb isotope records are very similar to those from the subtropical deep NW Atlantic locations, though the new data are at higher resolution and exhibit much greater amplitudes of change due to their Laurentide Ice Sheet-proximal setting. Unradiogenic compositions (206Pb/204Pb as low as 18.8 at 18.5 ka) during the latest glacial change towards highly radiogenic compositions during the early Holocene (206Pb/204Pb = 20.1 at 11.2 ka). Late Holocene 206Pb/204Pb values return to intermediate values around 206Pb/204Pb = 19.6. These new data support previous inferences that the Pb isotopic composition of the deep Atlantic is controlled during deglaciation by changes in the pattern and intensity of continental chemical weathering. In more detail, the most significant change in the entire Pb isotope record starts at 12.5 ka and lasts until about 11 ka. This observation, of strong Pb isotopic changes across a climatically cold period in the North Atlantic region, suggests that at this location Pb isotopic compositions recorded in deep marine authigenic Fe–Mn oxyhydroxides not only trace deglacial changes in chemical weathering intensity but also highly depend on major freshwater runoff routes in interior North America. Our data suggest a gradual opening of the eastward freshwater runoff route in the course of the Younger Dryas.
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  • 32
    Publication Date: 2017-08-08
    Description: Many biological seep studies focused on the distribution, structure, nutrition and food web architecture of seep communities as well as on their interaction with the seep geochemistry. However, overall respiration at cold seeps received only little attention. We conducted in-situ oxygen flux measurements in combination with ex-situ oxygen micro-profiles, respiration measurements, as well as rate determinations of microbial methane and sulfate turnover to assess respiration pathways as well as carbon turnover at a seep habitat that was recently discovered alongside the Hikurangi Margin offshore northern New Zealand. This habitat is dominated by dense beds of tube-building, heterotrophic ampharetid polychaetes. Average total oxygen uptake (TOU) from this habitat was very high (83.7 mmol m− 2 day− 1). TOU at a non-seep reference site ranged between 2.7 and 5.8 mmol m− 2 day− 1. About 37% (30.8 mmol m− 2 day− 1) of the average TOU was consumed by ampharetids. Considering mean diffusive oxygen uptake (8.5 mmol m− 2 day− 1) the remaining fraction of ~ 53% of the TOU (44.4 mmol m− 2 day− 1) might be explained by respiration of epibenthic organisms as well as aerobic methane and sulfide oxidation at the sediment–water interface. The strongly negative carbon isotopic signatures (− 52.9 ± 5‰ VPDB) of the ampharetid tissues indicate a methane derived diet. However, carbon production via anaerobic oxidation of methane (AOM) was too low (0.1 mmol C m− 2 day− 1) to cover the mean carbon demand of the ampharetid communities (21 mmol C m− 2 day− 1). Likely, organic carbon generated via aerobic methane oxidation represents their major carbon source. This is in contrast to other seep habitats, where energy bound in methane is partly transferred to sulfide via AOM and finally consumed by sulfide-oxidizing chemoautotrophs providing carbon that subsequently enters the benthic food web.
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  • 33
    Publication Date: 2019-09-23
    Description: Estimating the magnitude of Agulhas leakage, the volume flux of water from the Indian to the Atlantic Ocean, is difficult because of the presence of other circulation systems in the Agulhas region. Indian Ocean water in the Atlantic Ocean is vigorously mixed and diluted in the Cape Basin. Eulerian integration methods, where the velocity field perpendicular to a section is integrated to yield a flux, have to be calibrated so that only the flux by Agulhas leakage is sampled. Two Eulerian methods for estimating the magnitude of Agulhas leakage are tested within a high-resolution two-way nested model with the goal to devise a mooring-based measurement strategy. At the GoodHope line, a section halfway through the Cape Basin, the integrated velocity perpendicular to that line is compared to the magnitude of Agulhas leakage as determined from the transport carried by numerical Lagrangian floats. In the first method, integration is limited to the flux of water warmer and more saline than specific threshold values. These threshold values are determined by maximizing the correlation with the float-determined time series. By using the threshold values, approximately half of the leakage can directly be measured. The total amount of Agulhas leakage can be estimated using a linear regression, within a 90% confidence band of 12 Sv. In the second method, a subregion of the GoodHope line is sought so that integration over that subregion yields an Eulerian flux as close to the float-determined leakage as possible. It appears that when integration is limited within the model to the upper 300 m of the water column within 900 km of the African coast the time series have the smallest root-mean-square difference. This method yields a root-mean-square error of only 5.2 Sv but the 90% confidence band of the estimate is 20 Sv. It is concluded that the optimum thermohaline threshold method leads to more accurate estimates even though the directly measured transport is a factor of two lower than the actual magnitude of Agulhas leakage in this model.
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  • 34
    Publication Date: 2020-10-21
    Description: Here we present the first radiometric age data and a comprehensive geochemical data set (including major and trace element and Sr–Nd–Pb–Hf isotope ratios) for samples from the Hikurangi Plateau basement and seamounts on and adjacent to the plateau obtained during the R/V Sonne 168 cruise, in addition to age and geochemical data from DSDP Site 317 on the Manihiki Plateau. The 40Ar/39Ar age and geochemical data show that the Hikurangi basement lavas (118–96 Ma) have surprisingly similar major and trace element and isotopic characteristics to the Ontong Java Plateau lavas (ca. 120 and 90 Ma), primarily the Kwaimbaita-type composition, whereas the Manihiki DSDP Site 317 lavas (117 Ma) have similar compositions to the Singgalo lavas on the Ontong Java Plateau. Alkalic, incompatible-element-enriched seamount lavas (99–87 Ma and 67 Ma) on the Hikurangi Plateau and adjacent to it (Kiore Seamount), however, were derived from a distinct high time-integrated U/Pb (HIMU)-type mantle source. The seamount lavas are similar in composition to similar-aged alkalic volcanism on New Zealand, indicating a second wide-spread event from a distinct source beginning ca. 20 Ma after the plateau-forming event. Tholeiitic lavas from two Osbourn seamounts on the abyssal plain adjacent to the northeast Hikurangi Plateau margin have extremely depleted incompatible element compositions, but incompatible element characteristics similar to the Hikurangi and Ontong Java Plateau lavas and enriched isotopic compositions intermediate between normal mid-ocean-ridge basalt (N-MORB) and the plateau basement. These younger (not, vert, similar52 Ma) seamounts may have formed through remelting of mafic cumulate rocks associated with the plateau formation. The similarity in age and geochemistry of the Hikurangi, Ontong Java and Manihiki Plateaus suggest derivation from a common mantle source. We propose that the Greater Ontong Java Event, during which not, vert, similar1% of the Earth’s surface was covered with volcanism, resulted from a thermo-chemical superplume/dome that stalled at the transition zone, similar to but larger than the structure imaged presently beneath the South Pacific superswell. The later alkalic volcanism on the Hikurangi Plateau and the Zealandia micro-continent may have been part of a second large-scale volcanic event that may have also triggered the final breakup stage of Gondwana, which resulted in the separation of Zealandia fragments from West Antarctica.
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  • 35
    Publication Date: 2019-01-24
    Description: Three novel natural products, sorbifuranones A–C (4–6), were isolated from a Penicillium chrysogenum fungus isolated from the marine sponge Ircinia fasciculata. Sorbifuranones B (5) and C (6) and 2′,3′-dihydrosorbicillin, a putative precursor to sorbifuranone B, were also found in the culture of another Penicillium strain, which was isolated from the sponge Tethya aurantium. Their constitutions were elucidated mainly by 2D NMR. NOE correlations in combination with quantum chemical calculations and comparison of experimental and calculated electronic circular dichroism (CD) spectra permitted assignment of the absolute configuration of sorbifuranone C. The structures hint at a two-step cleavage-cyclization sequence of sorbifuranone A (4) leading to the spiro compound sorbifuranone C, while sorbifuranone B is likely to be the respective cleavage product of a putative 2′,3′-dihydrosorbifuranone A, which cannot cyclize further.
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  • 36
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    Elsevier
    In:  Comparative Biochemistry and Physiology Part B: Biochemistry and molecular biology, 155 (4). pp. 413-418.
    Publication Date: 2020-08-04
    Description: Thermal tolerance was determined in two closely related amphipod species from contrasting environments (sub-littoral and supra-littoral zones of the sea) using HSP expression and the activity of antioxidant enzymes. The levels of HSP70 and small HSPs present in untreated control animals were higher in the supra-littoral Orchestia gammarellus than in the sub-littoral Gammarus oceanicus. Under the acute thermal stress, HSP levels increased less strongly in O. gammarellus than in G. oceanicus. Activities of antioxidant enzymes peroxidase, catalase and glutathione S-transferase, were more pronounced in the supra-littoral O. gammarellus then in the sub-littoral G. oceanicus. We conclude that the environmental temperature regime modifies key cellular defense mechanisms in amphipods. Higher levels of constitutive HSP synthesis and higher levels of antioxidant enzymes in the supra-littoral species likely reflects adaptation to this highly thermally variable environment.
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  • 37
    Publication Date: 2020-07-09
    Description: We present recently-acquired high-resolution seismic data and older lower-resolution seismic data from Rock Garden, a shallow marine gas hydrate province on New Zealand's Hikurangi Margin. The seismic data reveal plumbing systems that supply gas to three general sites where seeps have been observed on the Rock Garden seafloor: the ‘LM3’ sites (including LM3 and LM3-A), the ‘Weka’ sites (including Weka-A, Weka-B, and Weka-C), and the ‘Faure’ sites (including Faure-A, Faure-B, and Rock Garden Knoll). At the LM3 sites, seismic data reveal gas migration from beneath the bottom simulating reflection (BSR), through the gas hydrate stability zone (GHSZ), to two separate seafloor seeps (LM3 and LM3-A). Gas migration through the deeper parts of GHSZ below the LM3 seeps appears to be influenced by faulting in the hanging wall of a major thrust fault. Closer to the seafloor, the dominant migration pathways appear to occupy vertical chimneys. At the Weka sites, on the central part of the ridge, seismic data reveal a very shallow BSR. A distinct convergence of the BSR with the seafloor is observed at the exit point of one of the Weka seep locations (Weka-A). Gas supply to this seep is predicted to be focused along the underside of a permeability contrast at the BGHS caused by overlying gas hydrates. The Faure sites are associated with a prominent arcuate slump feature. At Faure-A, high-amplitude reflections, extending from a shallow BSR towards the seafloor, are interpreted as preferred gas migration pathways that exploit relatively-high-permeability sedimentary layers. At Faure-B, we interpret gas migration to be channelled to the seep along the underside of the BGHS — the same scenario interpreted for the Weka-A site. At Rock Garden Knoll, gas occupies shallow sediments within the GHSZ, and is interpreted to migrate up-dip along relatively high-permeability layers to the area of seafloor seepage. We predict that faulting, in response to uplift and flexural extension of the ridge, may be an important mechanism in creating fluid flow conduits that link the reservoir of free gas beneath the BGHS with the shallow accumulations of gas imaged beneath Rock Garden Knoll. From a more regional perspective, much of the gas beneath Rock Garden is focused along a northwest-dipping fabric, probably associated with subduction-related deformation of the margin.
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  • 38
    Publication Date: 2017-08-07
    Description: The southern Hikurangi Subduction Margin is characterized by significant accretion with predicted high rates of fluid expulsion. Bottom simulating reflections (BSRs) are widespread on this margin, predominantly occurring beneath thrust ridges. We present seismic data across the Porangahau Ridge on the outer accretionary wedge. The data show high-amplitude reflections above the regional BSR level. Based on polarity and reflection strength, we interpret these reflections as being caused by free gas. We propose that the presence of gas above the regional level of BSRs indicates local upwarping of the base of gas hydrate stability caused by advective heatflow from upward migrating fluids, although we cannot entirely rule out alternative processes. Simplified modelling of the increase of the thermal gradient associated with fluid flow suggests that funnelling of upward migrating fluids beneath low-permeability slope basins into the Porangahau Ridge would not lead to the pronounced thermal anomaly inferred from upwarping of the base of gas hydrate stability. Focussing of fluid flow is predicted to take place deep in the accretionary wedge and/or the underthrust sediments. Above the high-amplitude reflections, sediment reflectivity is low. A lack of lateral continuity of reflections suggests that reflectivity is lost because of a destruction of sediment layering from deformation rather than gas-hydrate-related amplitude blanking. Structural permeability from fracturing of sediments during deformation may facilitate fluid expulsion on the ridge. A gap in the BSR in the southern part of the study area may be caused by a loss of gas during fluid expulsion. We speculate that gaps in otherwise continuous BSRs that are observed beneath some thrusts on the Hikurangi Margin may be characteristic of other locations experiencing focussed fluid expulsion.
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  • 39
    Publication Date: 2017-08-08
    Description: The imbricated frontal wedge of the central Hikurangi subduction margin is characteristic of wide (ca. 150 km), poorly drained and over pressured, low taper (not, vert, similar 4°) thrust systems associated with a relatively smooth subducting plate, a thick trench sedimentary sequence (not, vert, similar 3–4 km), weak basal décollement, and moderate convergence rate (not, vert, similar 40 mm/yr). New seismic reflection and multibeam bathymetric data are used to interpret the regional tectonic structures, and to establish the geological framework for gas hydrates and fluid seeps. We discuss the stratigraphy of the subducting and accreting sequences, characterize stratigraphically the location of the interplate décollement, and describe the deformation of the upper plate thrust wedge together with its cover sequence of Miocene to Recent shelf and slope basin sediments. We identify approximately the contact between an inner foundation of deforming Late Cretaceous and Paleogene rocks, in which widespread out-of-sequence thrusting occurs, and a 65–70 km-wide outer wedge of late Cenozoic accreted turbidites. Although part of a seamount ridge is presently subducting beneath the deformation front at the widest part of the margin, the morphology of the accretionary wedge indicates that frontal accretion there has been largely uninhibited for at least 1–2 Myr. This differs from the offshore Hawkes Bay sector of the margin to the north where a substantial seamount with up to 3 km of relief has been subducted beneath the lower margin, resulting in uplift and complex deformation of the lower slope, and a narrow (10–20 km) active frontal wedge. Five areas with multiple fluid seep sites, referred to informally as Wairarapa, Uruti Ridge, Omakere Ridge, Rock Garden, and Builders Pencil, typically lie in 700–1200 m water depth on the crests of thrust-faulted, anticlinal ridges along the mid-slope. Uruti Ridge sites also lie in close proximity to the eastern end of a major strike-slip fault. Rock Garden sites lie directly above a subducting seamount. Structural permeability is inferred to be important at all levels of the thrust system. There is a clear relationship between the seeps and major seaward-vergent thrust faults, near the outer edge of the deforming Cretaceous and Paleogene inner foundation rocks. This indicates that thrust faults are primary fluid conduits and that poor permeability of the Cretaceous and Paleogene inner foundation focuses fluid flow to its outer edge. The sources of fluids expelling at active seep sites along the middle slope may include the inner parts of the thrust wedge and subducting sediments below the décollement. Within anticlinal ridges beneath the active seep sites there is a conspicuous break in the bottom simulating reflector (BSR), and commonly a seismically-resolvable shallow fault network through which fluids and gas percolate to the seafloor. No active fluid venting has yet been recognized over the frontal accretionary wedge, but the presence of a widespread BSR, an extensive protothrust zone (〉 200 km by 20 km) in the Hikurangi Trough, and two unconfirmed sites of possible previous fluid expulsion, suggest that the frontal wedge could be actively dewatering. There are presently no constraints on the relative fluid flux between the frontal wedge and the active mid-slope fluid seeps. Article Outline
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  • 40
    Publication Date: 2016-11-01
    Description: Understanding the upward motion of CO2 droplets or CH4 bubbles in oceanic waters is prerequisite to predict the vertical distribution of the two most important greenhouse gases in the water column after these have been released from the seabed. One of the key parameters governing the fate of droplets or bubbles dissolving into the surrounding seawater as they rise, is the terminal velocity, uT. The latter is strongly influenced by the ability of both compounds to form skins of gas hydrate, if pressure and temperature satisfy thermodynamic framework conditions. Experimental efforts aiming to elucidate the rise properties of CO2 droplets and CH4 bubbles and specifically the influence of hydrate skins open the possibility to obtain a parameterization of uT applicable to both hydrate-coated and pure fluid particles of CH4 and CO2. With the present study, we report on experimentally determined terminal velocities of single CH4 bubbles released to pressurized and temperature-regulated seawater. Hydrate skins were identified by high bubble sphericities and changed motion characteristics. Based on these experiments as well as published data on the rise of hydrate-coated and pure liquid CO2 droplets and physical principles previously successfully used for clean bubbles near atmospheric pressures, a new parameterization of uT is proposed. Model predictions show a good agreement with the data base established from the laboratory-based measurements.
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  • 41
    Publication Date: 2017-02-21
    Description: This paper presents magnetic fabric analysis to examine the internal structure of the accretionary prism toe in the Nankai Trough, off the east coast of Japan. Two sites (C0006 and C0007) drilled during Integrated Ocean Drilling Program (IODP) Expedition 316 penetrated the sediment section, including intra wedge thrusts and the frontal thrust. Anisotropy of magnetic susceptibility (AMS) measurements provides insight into recorded strain during sedimentary and tectonic processes. Results from the upper part of the wedge show sedimentary acquired compaction fabric in general. In the lower part, AMS fabrics occasionally rotate almost ninety degrees and suggest horizontal compression. In contrast, magnetic fabrics did not show any correspondence to the thrusts or minor normal faults, which implies that those faults develop with concentrated shear deformation without disturbing surrounding sediments. Two adjacent drilling sites and dense sampling demonstrated clearly the change in strain field which is reported by previous studies. Based on these results, we propose a model of structural evolution at the toe of the prism. Underthrusting sediments induce horizontal stress in the lower part of the wedge, which reduces the effective stress and forms a high pore pressure anomaly and zones of fracturing. The frontal thrust is bent geometrically and terminates its activity in response to an increase of friction that triggers initiation of the next-generation frontal thrust. The upper part of the wedge tilts accordingly, resulting in an unstable slope.
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  • 42
    Publication Date: 2017-08-09
    Description: The Kamchatka Peninsula in far eastern Russia represents the most volcanically active arc in the world in terms of magma production and the number of explosive eruptions. We investigate large-scale silicic volcanism in the past several million years and present new geochronologic results from major ignimbrite sheets exposed in Kamchatka. These ignimbrites are found in the vicinity of morphologically-preserved rims of partially eroded source calderas with diameters from ∼ 2 to ∼ 30 km and with estimated volumes of eruptions ranging from 10 to several hundred cubic kilometers of magma. We also identify and date two of the largest ignimbrites: Golygin Ignimbrite in southern Kamchatka (0.45 Ma), and Karymshina River Ignimbrites (1.78 Ma) in south-central Kamchatka. We present whole-rock geochemical analyses that can be used to correlate ignimbrites laterally. These large-volume ignimbrites sample a significant proportion of remelted Kamchatkan crust as constrained by the oxygen isotopes. Oxygen isotope analyses of minerals and matrix span a 3‰ range with a significant proportion of moderately low-δ18O values. This suggests that the source for these ignimbrites involved a hydrothermally-altered shallow crust, while participation of the Cretaceous siliceous basement is also evidenced by moderately elevated δ18O and Sr isotopes and xenocryst contamination in two volcanoes. The majority of dates obtained for caldera-forming eruptions coincide with glacial stages in accordance with the sediment record in the NW Pacific, suggesting an increase in explosive volcanic activity since the onset of the last glaciation 2.6 Ma. Rapid changes in ice volume during glacial times and the resulting fluctuation of glacial loading/unloading could have caused volatile saturation in shallow magma chambers and, in combination with availability of low-δ18O glacial meltwaters, increased the proportion of explosive vs effusive eruptions. The presented results provide new constraints on Pliocene–Pleistocene volcanic activity in Kamchatka, and thus constrain an important component of the Pacific Ring of Fire.
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  • 43
    Publication Date: 2019-09-23
    Description: Iodine and its radioisotope 129I have been successfully used to trace the origin of pore waters in submarine fluid escape structures because of their close association with organic material in deeply buried sediments. We report here halogen concentrations and 129I/I ratios for fluids of five mud volcanoes sampled along an E–W transect across the Gulf of Cadiz in the NE Atlantic Ocean. Concentrations of iodide and bromide increase consistently seaward accompanied by a decrease in 129I/I ratios from 6490 × 10− 15 to 663 × 10− 15. The exceptionally high 129I/I ratios at the near-shore locations reflect the presence of fissiogenic 129I, produced in situ by spontaneous fission of 238U within terrigenous sediments and released into pore water during clay mineral diagenetic processes. The observed 129I/I and halogen trends, together with similar changes in 87Sr/86Sr ratios, indicate a progressive seaward transition from inorganic-terrigenous to organic-marine fluid sources. Comparison of our results with literature data for varying geological settings reveals a general relationship between fissiogenic 129I, radiogenic 87Sr and the lithology or provenance of rocks and sediments, respectively. While 129I/I ratios in continental rock-hosted aquifers and terrigenous sedimentary systems are dominated by in situ production of fissiogenic 129I, iodine isotopes in oceanic settings or volcanogenic marine sediments reflect the release of ‘old’ iodine from deeply buried organic matter. The Gulf of Cadiz represents the full transition between these continental and oceanic 129I/I and 87Sr/86Sr end members. This is the first systematic investigation of fissiogenic 129I production in marine sedimentary environments.
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  • 44
    Publication Date: 2019-09-23
    Description: Lithium concentration and isotope data (δ7Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ7Li (δ7Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ7Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite–illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a−1) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.
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  • 45
    Publication Date: 2019-09-23
    Description: The Arctic Ocean has wide shelf areas with extensive biological activity including a high primary productivity and an active microbial loop within the surface sediment. This in combination with brine production during sea ice formation result in the decay products exiting from the shelf into the deep basin typically at a depth of about 150 m and over a wide salinity range centered around S not, vert, similar33. We present data from the Beringia cruise in 2005 along a section in the Canada Basin from the continental margin north of Alaska towards the north and from the International Siberian Shelf Study in 2008 (ISSS-08) to illustrate the impact of these processes. The water rich in decay products, nutrients and dissolved inorganic carbon (DIC), exits the shelf not only from the Chukchi Sea, as has been shown earlier, but also from the East Siberian Sea. The excess of DIC found in the Canada Basin in a depth range of about 50–250 m amounts to 90±40 g C m−2. If this excess is integrated over the whole Canadian Basin the excess equals 320±140×1012 g C. The high DIC concentration layer also has low pH and consequently a low degree of calcium carbonate saturation, with minimum aragonite values of 60% saturation and calcite values just below saturation. The mean age of the waters in the top 300 m was calculated using the transit time distribution method. By applying a future exponential increase of atmospheric CO2 the invasion of anthropogenic carbon into these waters will result in an under-saturated surface water with respect to aragonite by the year 2050, even without any freshening caused by melting sea ice or increased river discharge.
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  • 46
    Publication Date: 2019-09-23
    Description: Several known gas seep sites along the Hikurangi Margin off the east coast of New Zealand were surveyed by marine controlled source electromagnetic (CSEM) experiments. A bottom-towed electric dipole–dipole system was used to reveal the occurrence of gas hydrate and methane related to the seeps. The experiments were part of the international multidisciplinary research program “New Vents” carried out on German R/V Sonne in 2007 (cruise SO191) to study key parameters controlling the release and transformation of methane from marine cold vents and shallow gas hydrate deposits. Two CSEM lines have been surveyed over known seep sites on Opouawe Bank in the Wairarapa region off the SE corner of the North Island. The data have been inverted to sub-seafloor apparent resistivity profiles and one-dimensional layered models. Clearly anomalous resistivities are coincident with the location of two gas seep sites, North Tower and South Tower on Opouawe Bank. A layer of concentrated gas hydrate within the uppermost 100 m below the seafloor is likely to cause the anomalous resistivities, but free gas and thick carbonate crusts may also play a role. Seismic data show evidence of fault related venting which may also indicate the distribution of gas hydrates and/or authigenic carbonate. Geochemical profiles indicate an increase of methane flux and the formation of gas hydrate in the shallow sediment section around the seep sites. Takahe is another seep site in the area where active venting, higher heat flow, shallow gas hydrate recovered from cores, and seismic fault planes, but only moderately elevated resistivities have been observed. The reasons could be a) the gas hydrate concentration is too low, even though methane venting is evident, b) strong temporal or spatial variation of the seep activity, and c) the thermal anomaly indicates rather temperature driven fluid expulsion that hampers the formation of gas hydrate beneath the vent.
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  • 47
    Publication Date: 2020-08-07
    Description: We have generated 104-year long (1895–1999) monthly δ18O and Sr/Ca time series from a fast-growing Diploria strigosa coral core drilled off Guadeloupe Island, Lesser Antilles. Coral Sr/Ca reliably records interannual to decadal surface air temperature (SAT) variations in the region and shows a pronounced warming of approximately 1.5 °C since 1950, with the strongest warming (1.2 °C) occurring since 1975. This warming is also evident in SAT measured at Guadeloupe, which ends in 1951. Thus, our Sr/Ca series extends the air temperature record by 56 years. We find that the past few decades are the warmest years over the entire period of record. The accelerated warming since 1950 is accompanied by a pronounced decrease in regional precipitation. This dampens the warming signal indicated by coral δ18O, which is too low (only 0.7– 0.8 °C since 1951). Consistently, δ18Osw estimated from the coral proxies also shows a strong decrease since 1950. Our data suggest an inverse relationship between SAT and precipitation (i.e. warmer and drier) for the latter half of the 20th century with the strongest trends since the mid-1970s. This is consistent with recent observational and model data, which report that while over the tropical oceans rainfall has increased due to an increase in sea surface temperatures, precipitation over land regions is reduced. A continuation of this warming and drying trend over Caribbean land regions would have severe societal consequences, especially in the context of anthropogenic warming. The El Niño Southern-Oscillation (ENSO) and the North Atlantic Oscillation (NAO) are the two major climate modes affecting large-scale SST variability in the northern tropical Atlantic. Both Sr/Ca and δ18O show a close relationship to ENSO and the NAO. A quantitative comparison between extremes in mean March–May coral δ18O and the Nino3 and NAO indices imply that climate variability in the northern tropical Atlantic is mainly forced by tropical Pacific and North Atlantic variability. Spectral analysis suggests that the relative importance of ENSO and the NAO is frequency dependent, with ENSO dominating at interannual, and the NAO dominating at interdecadal time scales.
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  • 48
    Publication Date: 2017-08-08
    Description: Fluid escape structures on the Nile Deep Sea Fan were investigated during the MEDIFLUX MIMES expedition in 2004. Mud volcanoes, pockmarks and authigenic carbonate structures were surveyed for the first time with a high-resolution deep-towed 75 kHz sidescan sonar and a 2–8 kHz Chirp sediment echosounder. In combination with existing multibeam bathymetry and detailed seafloor in situ geological observations, these new data allowed detailed seep analyses. About 60 gas flares were detected acoustically in the water column from the sidescan sonar raw data atwater depths from 770 to 1700 m. These gas flares coincide at the seabed with 1) the centres of the mud volcanoes where mud is also extruded, 2) the borders of the mud volcanoes where the emitted gases contribute to the precipitation of authigenic carbonates, and 3) to the edges of broad sheets of authigenic carbonates. Subsurface sediments are commonly disturbed by ascending fluids throughout the delta, with an abundance of seep-related carbonate structures on the seafloor. The feeder channels below mud volcanoes, similar to the gas conduits below the widespread carbonate crust structures and pockmarks, are relatively narrow and, for the vast majority of them, do not exceed a few metres in diameter. The seeps on the Nile Deep Sea Fan clearly follow lineations on the seafloor that ee can relate to faults.
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  • 49
    Publication Date: 2017-08-08
    Description: Seismic attenuation across the central Costa Rican margin wedge is determined fromamplitude analysis ofwideangle seismic data. Travel time and amplitude modeling are applied to ocean bottom hydrophones along two trench-parallel profiles, located 30 km (P21) and 35 km (P18) landward of the deformation front northeast of Quepos Plateau. Tomographic inversion images a progressively thinning margin wedge from the coast to the lower slope at the trench. A 1–1.5 km thick décollement zone with seismic velocities of 3.5–4.5 km/s is sandwiched between the marginwedge and the subducting Cocos plate. For strike line P21, amplitude modeling indicates a Qp value of 50–150 for the upper margin wedge with seismic velocities ranging from 3.9 km/s to 4.9 km/s. Along strike line P18, Qp values of 50–150 are determined with velocities of 4.3–5.0 km/s in the upper margin wedge, increasing to 5.1–5.4 km/s in the lower margin wedge. Quantitative amplitude decay curves support the observed upper plate Qp values. In conjunction with earlier results from offshore Nicoya Peninsula, our study documents landward decreasing attenuation across the margin wedge, consistent with a change in lithology from the sediment-dominated frontal prism to the igneous composition of the forearc middle prism
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  • 50
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    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 395 (1-2). pp. 10-20.
    Publication Date: 2017-07-11
    Description: Predicting the relevance of initial colonization and subsequent species interactions for succession in marine sessile communities is difficult because the effects of both factors depend on highly variable environmental processes (e.g. currents, topography, upwelling and others). Depending on the successional stage at which a new species arrives, it can either rapidly colonize in large numbers or its colonization success might be suppressed by resident species. In order to assess the roles of (i) initial colonization and (ii) subsequent species interactions on community development, we examined the succession of fouling assemblages that established on artificial substrata during two different seasonal periods, i.e. austral winter/spring and spring/summer. At 16 weeks of age communities that were initiated in different seasons varied significantly in composition and diversity. During each period (winter/spring and spring/summer), multispecies fouling consortia of different ages (hereafter termed “old” and “young”) were reciprocally transplanted between two neighbouring study sites and their succession was documented. After 8 weeks of transplantation communities of different ages maintained their differences in diversity even in the face of environmental change. However, during winter/spring the spreading of the dominant species P. chilensis caused more rapid convergence between all communities at both sites. During the spring/summer period, the high initial abundances of the weak competitor Bugula neritina led to the maintenance of differences between resident and transplanted assemblages within each site. Later colonizers, including the dominant competitor P. chilensis, however, could recruit onto B. neritina and started to spread in the communities. These results suggest that the early and intermediate succession of fouling communities in highly productive marine environments such as the Humboldt Current System is driven by the temporal and spatial variability of propagule supply, while the long-term stability of these communities depends on the identity of colonizers and their competitiveness.
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  • 51
    Publication Date: 2017-09-27
    Description: This study combines sediment geochemical analysis, in situ benthic lander deployments and numerical modeling to quantify the biogeochemical cycles of carbon and sulfur and the associated rates of Gibbs energy production at a novel methane seep. The benthic ecosystem is dominated by a dense population of tube-building ampharetid polychaetes and conspicuous microbial mats were unusually absent. A 1D numerical reaction-transport model, which allows for the explicit growth of sulfide and methane oxidizing microorganisms, was tuned to the geochemical data using a fluid advection velocity of 14 cm yr−1. The fluids provide a deep source of dissolved hydrogen sulfide and methane to the sediment with fluxes equal to 4.1 and 18.2 mmol m−2 d−1, respectively. Chemosynthetic biomass production in the subsurface sediment is estimated to be 2.8 mmol m−2 d−1 of C biomass. However, carbon and oxygen budgets indicate that chemosynthetic organisms living directly above or on the surface sediment have the potential to produce 12.3 mmol m−2 d−1 of C biomass. This autochthonous carbon source meets the ampharetid respiratory carbon demand of 23.2 mmol m−2 d−1 to within a factor of 2. By contrast, the contribution of photosynthetically-fixed carbon sources to ampharetid nutrition is minor (3.3 mmol m−2 d−1 of C). The data strongly suggest that mixing of labile autochthonous microbial detritus below the oxic layer sustains high measured rates of sulfate reduction in the uppermost 2 cm of the sulfidic sediment (100–200 nmol cm−3 d−1). Similar rates have been reported in the literature for other seeps, from which we conclude that autochthonous organic matter is an important substrate for sulfate reducing bacteria in these sediment layers. A system-scale energy budget based on the chemosynthetic reaction pathways reveals that up to 8.3 kJ m−2 d−1 or 96 mW m−2 of catabolic (Gibbs) energy is dissipated at the seep through oxidation reactions. The microorganisms mediating sulfide oxidation and anaerobic oxidation of methane (AOM) produce 95% and 2% of this energy flux, respectively. The low power output by AOM is due to strong bioenergetic constraints imposed on the reaction rate by the composition of the chemical environment. These constraints provide a high potential for dissolved methane efflux from the sediment (12.0 mmol m−2 d−1) and indicates a much lower efficiency of (dissolved) methane sequestration by AOM at seeps than considered previously. Nonetheless, AOM is able to consume a third of the ascending methane flux (5.9 mmol m−2 d−1 of CH4) with a high efficiency of energy expenditure (35 mmol CH4 kJ−1). It is further proposed that bioenergetic limitation of AOM provides an explanation for the non-zero sulfate concentrations below the AOM zone observed here and in other active and passive margin sediments.
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  • 52
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    Elsevier
    In:  Progress in Oceanography, 86 (3-4). pp. 337-360.
    Publication Date: 2019-09-23
    Description: We present a suite of experiments with a hierarchy of biogeochemical models of increasing complexity coupled to an offline global ocean circulation model based on the “transport matrix method”. Biogeochemical model structures range from simple nutrient models to more complex nutrient-phytoplankton–zooplankton-detritus-DOP models. The models’ skill is assessed by various misfit functions with respect to observed phosphate and oxygen distributions. While there is generally good agreement between the different metrics employed, an exception is a cost function based on the relative model-data misfit. We show that alterations in parameters and/or structure of the models – especially those that change particle export or remineralization profile – affect subsurface and mesopelagic phosphate and oxygen, particularly in the upwelling regions. Visual inspection of simulated biogeochemical tracer distributions as well as the evaluation of different cost functions suggest that increasing complexity of untuned, unoptimized models, simulated with parameters commonly used in large-scale model studies does not necessarily improve performance. Instead, variations in individual model parameters may be of equal, if not greater, importance.
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  • 53
    Publication Date: 2017-12-07
    Description: The solubility of H2O- and CO2-bearing fluids in tholeiitic basalts has been investigated experimentally at temperature of 1250 °C and pressures of 50, 100, 200, 300, 400 and 500 MPa. The concentrations of dissolved H2O and CO2 have been determined using FTIR spectroscopy with an accurate calibration of the absorption coefficients for hydrogen- and carbon-bearing species using synthesized standards of the same tholeiitic composition. The absorption coefficients are 0.65 ± 0.08 and 0.69 ± 0.08 L/(mol cm) for molecular H2O and OH groups by Near-Infrared (NIR), respectively, and 68 ± 10 L/(mol cm) for bulk H2O by Mid-Infrared (MIR). The carbonate groups determined by MIR have an absorption coefficient of 317 ± 23 L/(mol cm) for the band at 1430 cm−1.The solubility of H2O in the melt in equilibrium with pure H2O fluid increases from about 2.3 ± 0.12 wt.% at 50 MPa to about 8.8 ± 0.16 wt.% at 500 MPa, whereas the concentration of CO2 increases from about 175 ± 15 to 3318 ± 276 ppm in the melts which were equilibrated with the most CO2-rich fluids (with mole fraction of CO2 in the fluid, XflCO2, from 0.70 to 0.95). In melts coexisting with H2O- and CO2-bearing fluids, the concentrations of dissolved H2O and CO2 in basaltic melt show a non-linear dependence on both total pressure and mole fraction of volatiles in the equilibrium fluid, which is in agreement with previous studies. A comparison of new experimental data with existing numerical solubility models for mixed H2O–CO2 fluids shows that the models do not adequately predict the solubility of volatiles in basaltic liquids at pressures above 200 MPa, in particular for CO2, implying that the models need to be recalibrated. The experimental dataset presented in this study enables a quantitative interpretation of volatile concentrations in glass inclusions to evaluate the magma storage conditions and degassing paths of natural island arc basaltic systems. The experimental database covers the entire range of volatile compositions reported in the literature for natural melt inclusions in olivine from low- to mid-K basalts indicating that most melt inclusions were trapped or equilibrated at intermediate to shallow levels in magmatic systems (〈 12–15 km).
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  • 54
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    Elsevier
    In:  Ecological Economics, 69 (12). pp. 2495-2509.
    Publication Date: 2019-09-23
    Description: Reducing atmospheric carbon concentration by removing past emissions can extend our rapidly diminishing emission budgets corresponding to the target of limiting the temperature increase to 2 °C above preindustrial levels. Forestation measures to offset carbon emissions have already entered the Kyoto Protocol. Other carbon offset options like ocean iron fertilization or chemically enhanced weathering are currently being analyzed. The analysis and comparison of such options requires determination of the amount of carbon credits generated that can be used for compliance. In our analysis we assess the impact of various accounting methods applied to large-scale sink enhancement projects, taking into account the partly temporary storage characteristics arising from such projects. We apply the various accounting methods to hypothetical large-scale Southern Ocean iron fertilization projects for different durations. From an economic perspective, issuing temporary carbon credits would provide the largest number of carbon credits at an early stage. This is equivalent to the existing tCER regulation under the Kyoto Protocol. Issuing temporary carbon credits for short-term ocean iron fertilization would also benefit the environment, as all credits would have to be replaced in the next commitment period. As some carbon will be stored permanently, this reduces atmospheric carbon concentration.
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  • 55
    Publication Date: 2019-09-23
    Description: Annual variability in abundance and population structure of the copepod Eurytemora affinis was studied in the maximum turbidity zone of the Seine Estuary in 2005. An Eulerian sampling strategy was applied monthly from March to July and from September to December. Chlorophyll a and suspended particulate matter (SPM) concentration, copepod abundance and stage distribution, and phytoplankton abundance were measured in sub-surface and near-bottom water during the ebb phase. Total E. affinis abundance was at a maximum in March and April (〉200 × 103 ind. m−3), and decreased from May to September (〈25 × 103 ind. m−3). This decrease corresponds to annual increases in temperature, salinity, chlorophyll a concentration and phytoplankton abundance, which was dominated by large diatoms, and decreases in SPM and river discharge. The phenology observed in 2005 was almost two months earlier compared to previous studies in the 1990s, when E. affinis reached maximum abundance in May and June. The low proportion of nauplii (〈50%) in the population and high abundance of ovigerous females suggests that low recruitment is probably related to anomalously low temperatures in late winter (〈5 °C). Whatever the horizontal position of the population in the estuary, adult and late copepodid stages are distributed in higher salinity than naupliar stages. Overall E. affinis population abundance was driven by parameters that characterize water masses at the tidal scale and by river discharge and chlorophyll a at the annual scale. By integrating the tidal effect, the high-frequency sampling protocol used appears to be optimal for investigating annual variability of planktonic communities in megatidal estuaries.
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  • 56
    Publication Date: 2015-11-18
    Description: High resolution multi-channel seismic reflection data acquired in the offshore domain of the Krishna–Godavari (KG) Basin, provide seismic indicators of gas hydrate including bottom-simulating reflectors (BSR), and high reflectivity zones below the BSR as an indication of free gas. The recent recovery of gas hydrate by drilling across various sites in the KG Basin, together with the seismic indicators, suggests overall widespread favourable gas hydrate stability conditions. The BSRs provide indirect estimates of geothermal gradients and heat flow. A simple conductive model is used to calculate heat flow from the depth of the BSR. BSR-derived heat flow values range from about 30 to 102 mW/m2 across the KG Basin. We also modeled the base of gas hydrate stability zone (BGHSZ) to analyse the linkage between gas hydrate occurrences in the basin and its relation to the fault systems in the basin. The influence of bottom water temperature, pore water salinity and geothermal gradient variation on gas hydrate stability zone (GHSZ) thickness is analysed in relation to both geological formations and tectonics. Our analysis suggests a highly variable GHSZ in the KG Basin controlled by local variations in the parameters of stability condition and faulting. The BSR-derived heat flow increases towards deeper water depths across the basin. Consistent local variations were also observed with low heat flow values over prominent topographic highs and high heat flow values over the flanks of the topographic highs. This variation may be due to focusing and defocusing effects of the topography. However, local BSR-depths patterns may also be due to dynamic effects, including the displacement of isotherms by thrust-faulting. Additionally, recent mass-wasting events and normal faulting resulted in the BGHSZ being too shallow relative to the predicted model (which assumed equilibrium conditions). Seismic and heat flow constraints from the Krishna-Godavari Basin gas hydrate system. Mar Geol - ResearchGate. Available from: http://www.researchgate.net/publication/223314484_Seismic_and_heat_flow_constraints_from_the_Krishna-Godavari_Basin_gas_hydrate_system._Mar_Geol [accessed Nov 5, 2015].
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  • 57
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 57 (8). pp. 988-998.
    Publication Date: 2015-10-19
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  • 58
    Publication Date: 2015-01-27
    Description: Multibeam swath bathymetry data from the Northwestern part of the Gulf of Cadiz revealed the existence of several intriguing kilometric crescentic depressions lying between -4300 m and -4700 m, never before reported to occur at such great depths. Morphological parameterization of these features, coupled with a detailed analysis of multi-channel and middle resolution seismic profiles, showed that these crescent-shaped features were formed due to the existence of specific time-recurrent interaction between: a) regional active thrusts, which portray the overall tectonic scenario in the area, and on top of which most crescentic depressions are carved; and b) tectonically induced scouring comprising localized erosion and simultaneous progradational sedimentation, produced by downslope currents of probable turbiditic origin. The obtained results also suggest a possible contribution of fluid migration and extrusion processes, such as mud volcanism and associated pockmark formation, besides gravity driven landslides and slumping, in the development of the studied crescentic depressions
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  • 59
    Publication Date: 2015-07-03
    Description: Chemical investigation of Indonesian marine sponges Agelas linnaei and A. nakamurai afforded 24 alkaloid derivatives representing either bromopyrrole or diterpene alkaloids. A. linnaei yielded 16 bromopyrrole alkaloids including 11 new natural products with the latter exhibiting unusual functionalities. The new compounds include the first iodinated tyramine-unit bearing pyrrole alkaloids, agelanesins A-D. These compounds exhibited cytotoxic activity against L5178Y mouse lymphoma cells with IC(50) values between 9.25 and 16.76 muM. Further new compounds include taurine acid substituted bromopyrrole alkaloids and a new dibromophakellin derivative. A. nakamurai yielded eight alkaloids among them are three new natural products. The latter include the diterpene alkaloids (-)-agelasine D and its oxime derivative and the new bromopyrrole alkaloid longamide C. (-)-Agelasine D and its oxime derivative exhibited cytotoxicity against L5178Y mouse lymphoma cells (IC(50) 4.03 and 12.5 microM, respectively). Furthermore, both agelasine derivatives inhibited settling of larvae of Balanus improvisus in an anti-fouling bioassay and proved to be toxic to the larvae. (-)-Agelasine D inhibited the growth of planktonic forms of biofilm forming bacteria S. epidermidis (MIC〈0.0877 microM) but did not inhibit biofilm formation whereas the oxime derivative showed the opposite activity profile and inhibited only biofilm formation but not bacterial growth. The structures of the isolated secondary metabolites were elucidated based on extensive spectroscopic analysis involving one- and two-dimensional NMR as well as mass spectrometry and comparison with literature data.
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  • 60
    Publication Date: 2015-09-25
    Description: Here we provide a detailed qualitative and quantitative insight on recent sediment composition and facies distribution of a cold-water coral (CWC) mound using the example of the Propeller Mound on the Irish continental margin (Hovland Mound Province, Porcupine Seabight). Five facies types on Propeller Mound are defined: (1) living coral framework, (2) coral rubble, (3) dropstone, (4) hardground, representing the on-mound facies, and (5) hemipelagic sediment facies, which describes the off-mound area. This facies definition is based on already published video-data recorded by Remotely Operated Vehicle (ROV), photo-data of gravity cores, box cores, and dredges from sediment surfaces as well as on the composition of the sediment fraction coarser than 125 μm, which has been analyzed on five selected box cores. Sediment compositions of the living coral framework and coral rubble facies are rather similar. Both sediment types are mainly produced by corals (34 and 35 wt%, respectively), planktonic foraminifers (22 and 29 wt%, respectively), benthic foraminifers (both 7 wt%), and molluscs (21 and 10 wt%, respectively), whereas the living coral framework characteristically features additional brachiopods (6 wt%). Hardgrounds are well-lithified coral rudstones rich in coral fragments (〉30 surf%), foraminifers, echinoderms, and bivalves. The dropstone facies and the hemipelagic sediment typically carry high amounts of lithoclasts (36 and 53 wt%, respectively) and planktonic foraminifers (35 and 32 wt%, respectively); however, their faunal diversity is low compared with the coral-dominated facies (12 and 〈2 wt% coral fragments, 7 and 6 wt% benthic foraminifers, and 4 and 0 wt% balanids). Using the maximum likelihood algorithm within ArcGIS 9.2, spatial prediction maps of the previously described mound facies are calculated over Propeller Mound and are based on mound morphology parameters, ground-truthed with the sedimentary and faunal information from box cores, photographs, and video-data. This method is tested for the first time for CWC ecosystems and provides areal estimates of the predicted facies, as well as suggests further occurrences of living coral frameworks, coral rubble, and dropstones, which are not discovered in the area yet. Thus, sediment composition analysis combined with facies prediction mapping might provide a potential new tool to estimate living CWC occurrences and sediment/facies distributions on CWC mounds, which is an important prerequisite for budget calculations and definition of marine protected areas, and which will improve our understanding of CWC mound formation.
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  • 61
    Publication Date: 2015-10-08
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  • 62
    Publication Date: 2015-09-21
    Description: Neodymium (Nd) concentrations and isotopic signatures of living and fossil deep-sea coral species Lophelia pertusa, Desmophyllum dianthus and Madrepora oculata from the northeast Atlantic Ocean have been investigated in order to test the ability of deep-sea corals to reconstruct the seawater Nd isotopic signature and past changes of ocean circulation in the eastern North Atlantic. Small quantities of Nd—less than 45 ng/g—are incorporated into the aragonite skeleton of living deep-sea corals that dwell at upper intermediate depths throughout the Northeast Atlantic. Rigorous cleaning techniques are needed in order to avoid Nd contamination from manganese-oxide and iron hydroxide coatings. Moreover, Nd isotopic compositions have been measured using thermal ionization mass spectrometry (TIMS) by Nd-oxide method. Our data indicate that the isotopic signatures of modern corals are similar to those of adjacent water masses, implying that deep-sea corals can serve as an archive of the seawater Nd isotopic compositions in the past. The first results from few fully-cleaned fossils corals collected within the Porcupine Seabight and the southwest Rockall Bank reveal significantly higher εNd for corals dated between 150 ± 40 and 3060 ± 90 yrs than those of the living corals located in similar areas. This suggests rapid hydrological variations along the eastern margin of the North Atlantic Ocean at intermediate water depth with higher contribution of the Mediterranean Overflow Waters (MOW) or other temperate Atlantic mid-depth water masses (ENACW or NAC) in the past.
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  • 63
    Publication Date: 2020-06-03
    Description: Based on geomorphological, lithological, and facial characteristics of the East Arctic continental margin, we studied the main factors controlling the Late Cenozoic supply of organic matter (OM) to the bottom sediments of the Central Arctic rises of the Arctic Ocean. Complex analysis of dispersed OM in the samples taken during the expeditions of the R/V “Akademik Fedorov” in 2000 and 2005 showed a significant difference between the sediments of the Lomonosov Ridge and Mendeleev Rise. The bottom sediments of the latter are strongly transformed and lack terrigenous components, as evidenced results from the main geochemical characteristics (contents of Corg, Ccarb, Norg, bitumens, and humic acids) and the composition and distribution of hydrocarbon molecular markers (alkanes, saturated and aromatic cyclanes). The obtained data evidence that ancient sedimentary rocks containing genetically uniform deeply transformed (up to mesocatagenesis) OM played a significant role in the formation of the Pleistocene–Holocene sediments of the axial part of the Mendeleev Rise.
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  • 64
    Publication Date: 2015-11-18
    Description: Gas hydrate was discovered in the Krishna–Godavari (KG) Basin during the India National Gas Hydrate Program (NGHP) Expedition 1 at Site NGHP-01-10 within a fractured clay-dominated sedimentary system. Logging-while-drilling (LWD), coring, and wire-line logging confirmed gas hydrate dominantly in fractures at four borehole sites spanning a 500 m transect. Three-dimensional (3D) seismic data were subsequently used to image the fractured system and explain the occurrence of gas hydrate associated with the fractures. A system of two fault-sets was identified, part of a typical passive margin tectonic setting. The LWD-derived fracture network at Hole NGHP-01-10A is to some extent seen in the seismic data and was mapped using seismic coherency attributes. The fractured system around Site NGHP-01-10 extends over a triangular-shaped area of ∼2.5 km2 defined using seismic attributes of the seafloor reflection, as well as “seismic sweetness” at the base of the gas hydrate occurrence zone. The triangular shaped area is also showing a polygonal (nearly hexagonal) fault pattern, distinct from other more rectangular fault patterns observed in the study area. The occurrence of gas hydrate at Site NGHP-01-10 is the result of a specific combination of tectonic fault orientations and the abundance of free gas migration from a deeper gas source. The triangular-shaped area of enriched gas hydrate occurrence is bound by two faults acting as migration conduits. Additionally, the fault-associated sediment deformation provides a possible migration pathway for the free gas from the deeper gas source into the gas hydrate stability zone. It is proposed that there are additional locations in the KG Basin with possible gas hydrate accumulation of similar tectonic conditions, and one such location was identified from the 3D seismic data ˜6 km NW of Site NGHP-01-10.
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  • 65
    Publication Date: 2019-09-23
    Description: Between 2007 and 2009, 132,178 cephalopods were sampled in the North Sea during ICES International Bottom Trawl Surveys. Most abundant were the long-finned squids Alloteuthis subulata (124,751 animals) and Loligo forbesii (3415 animals). Short-finned squids such as Todaropsis eblanae, Todarodes sagittatus and Illex coindetii were rare (195 animals). During winter, A. subulata individuals, mostly immature and maturing, were concentrated in the central and northern parts of the North Sea. In summer, the abundance of A. subulata, mostly maturing and mature, increased in the southeastern part suggesting a southward migration to spawning grounds. L. forbesii individuals, some fully mature, were abundant in the northwestern part of the North Sea during winter indicating spawning areas in this region. In summer, L. forbesii individuals, mostly immature, occurred in lower numbers throughout the North Sea. Our data provide new information on abundance, distribution, migration, and possible recruitment areas of North Sea cephalopods.
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  • 66
    Publication Date: 2019-09-23
    Description: Model drift in the Labrador Sea in eddy permitting model simulations is examined using a series of configurations based on the NEMO numerical framework. There are two phases of the drift that we can identify, beginning with an initial rapid 3-year period, associated with the adjustment of the model from its initial conditions followed by an extended model drift/adjustment that continued for at least another decade. The drift controlled the model salinity in the Labrador Sea, over-riding the variability. Thus, during this initial period, similar behavior was observed between the inter-annually forced experiments as with perpetual year forcing. The results also did not depend on whether the configuration was global, or regional North Atlantic Ocean. The inclusion of an explicit sea-ice component did not seem to have a significant impact on the interior drift. Clear cut evidence for the drift having an advective nature was shown, based on two separate currents/flow regimes. We find, as expected, the representation of freshwater in the sub-polar gyre’s boundary currents important. But this study also points out another, equally important process and pathway: the input of high salinity mode water from the subtropical North Atlantic. The advective regime is dependent on the details of the model, such as the representation of the freshwater transport in the model’s East Greenland Current being very sensitive to the strength of the local sea surface salinity restoring (and the underlying field that the model is being restored to).
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  • 67
    Publication Date: 2017-07-26
    Description: The newly developed P-Cable 3D seismic system allows for high-resolution seismic imaging to characterize upper geosphere geological features focusing on geofluid expressions (gas chimneys), shallow gas and gas hydrate reservoirs. Seismic imaging of a geofluid system of an Arctic sediment drift at the Vestnesa Ridge, offshore western Svalbard, provides significantly improved details of internal chimney structures from the seafloor to not, vert, similar500 m bsf (below seafloor). The chimneys connect to pockmarks at the seafloor and indicate focused fluid flow through gas hydrated sediments. The pockmarks are not buried and align at the ridge-crest pointing to recent, topography-controlled fluid discharge. Chimneys are fuelled by sources beneath the base of gas hydrate stability zone (GHSZ) that is evident at not, vert, similar160–170 m bsf as indicated by a bottom-simulating reflector (BSR). Conduit centres that are not vertically straight but shift laterally by up to 200 m as well as discontinuous internal chimney reflections indicate heterogeneous hydraulic fracturing of the sediments. Episodically active, pressure-driven focused fluid flow could explain the hydro-fracturing processes that control the plumbing system and lead to extensive pockmark formation at crest of the Vestnesa Ridge. High-amplitude anomalies in the upper 50 m of the chimney structures suggest formations of near-surface gas hydrates and/or authigenic carbonate precipitation. Acoustic anomalies, expressed as high amplitudes and amplitude blanking, are irregularly distributed throughout the deeper parts of the chimneys and provide evidence for the variability of hydrate and/or carbonate formation in space and time.
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  • 68
    facet.materialart.
    Unknown
    Elsevier
    In:  [Talk] In: Active Tephra in Kyushu, International Field Conference and Workshop on Tephrochronology, Volcanism, and Human Activity, 09.05.-17.05.2010, Kirishima, South Kyushu, Japan . Quaternary Internationl .
    Publication Date: 2012-02-23
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  • 69
    Publication Date: 2019-09-23
    Description: Quantifying the spatial and temporal sea surface temperature (SST) and salinity changes of the Indo-Pacific Warm Pool is essential to understand the role of this region in connection with abrupt climate changes particularly during the last deglaciation. In this study we reconstruct SST and seawater δ18O of the tropical eastern Indian Ocean for the past 40,000 years from two sediment cores (GeoB 10029-4, 1°30′S, 100°08′E, and GeoB 10038-4, 5°56′S, 103°15′E) retrieved offshore Sumatra. Our results show that annual mean SSTs increased about 2–3 °C at 19,000 years ago and exhibited southern hemisphere-like timing and pattern during the last deglaciation. Our SST records together with other Mg/Ca-based SST reconstructions around Indonesia do not track the monsoon variation since the last glacial period, as recorded by terrestrial monsoon archives. However, the spatial SST heterogeneity might be a result of changing monsoon intensity that shifts either the annual mean SSTs or the seasonality of G. ruber towards the warmer or the cooler season at different locations. Seawater δ18O reconstructions north of the equator suggest fresher surface conditions during the last glacial and track the northern high-latitude climate change during the last deglaciation. In contrast, seawater δ18O records south of the equator do not show a significant difference between the last glacial period and the Holocene, and lack Bølling Allerød and Younger Dryas periods suggestive of additional controls on annual mean surface hydrology in this part of the Indo-Pacific Warm Pool.
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  • 70
    Publication Date: 2016-09-16
    Description: As the planet cooled from peak warmth in the early Cenozoic, extensive Northern Hemisphere ice sheets developed by 2.6 Ma ago, leading to changes in the circulation of both the atmosphere and oceans. From not, vert, similar2.6 to not, vert, similar1.0 Ma ago, ice sheets came and went about every 41 ka, in pace with cycles in the tilt of Earth’s axis, but for the past 700 ka, glacial cycles have been longer, lasting not, vert, similar100 ka, separated by brief, warm interglaciations, when sea level and ice volumes were close to present. The cause of the shift from 41 ka to 100 ka glacial cycles is still debated. During the penultimate interglaciation, not, vert, similar130 to not, vert, similar120 ka ago, solar energy in summer in the Arctic was greater than at any time subsequently. As a consequence, Arctic summers were not, vert, similar5 °C warmer than at present, and almost all glaciers melted completely except for the Greenland Ice Sheet, and even it was reduced in size substantially from its present extent. With the loss of land ice, sea level was about 5 m higher than present, with the extra melt coming from both Greenland and Antarctica as well as small glaciers. The Last Glacial Maximum (LGM) peaked not, vert, similar21 ka ago, when mean annual temperatures over parts of the Arctic were as much as 20 °C lower than at present. Ice recession was well underway 16 ka ago, and most of the Northern Hemisphere ice sheets had melted by 6 ka ago. Solar energy reached a summer maximum (9% higher than at present) not, vert, similar11 ka ago and has been decreasing since then, primarily in response to the precession of the equinoxes. The extra energy elevated early Holocene summer temperatures throughout the Arctic 1–3 °C above 20th century averages, enough to completely melt many small glaciers throughout the Arctic, although the Greenland Ice Sheet was only slightly smaller than at present. Early Holocene summer sea ice limits were substantially smaller than their 20th century average, and the flow of Atlantic water into the Arctic Ocean was substantially greater. As summer solar energy decreased in the second half of the Holocene, glaciers re-established or advanced, sea ice expanded, and the flow of warm Atlantic water into the Arctic Ocean diminished. Late Holocene cooling reached its nadir during the Little Ice Age (about 1250–1850 AD), when sun-blocking volcanic eruptions and perhaps other causes added to the orbital cooling, allowing most Arctic glaciers to reach their maximum Holocene extent. During the warming of the past century, glaciers have receded throughout the Arctic, terrestrial ecosystems have advanced northward, and perennial Arctic Ocean sea ice has diminished. Here we review the proxies that allow reconstruction of Quaternary climates and the feedbacks that amplify climate change across the Arctic. We provide an overview of the evolution of climate from the hot-house of the early Cenozoic through its transition to the ice-house of the Quaternary, with special emphasis on the anomalous warmth of the middle Pliocene, early Quaternary warm times, the Mid Pleistocene transition, warm interglaciations of marine isotope stages 11, 5e, and 1, the stage 3 interstadial, and the peak cold of the last glacial maximum.
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  • 71
    Publication Date: 2019-07-05
    Description: The Water Framework Directive (WFD) and the Marine Strategy Framework Directive (MSFD) are the European umbrella regulations for water systems. It is a challenge for the scientific community to translate the principles of these directives into realistic and accurate approaches. The aim of this paper, conducted by the Benthos Ecology Working Group of ICES, is to describe how the principles have been translated, which were the challenges and best way forward. We have tackled the following principles: the ecosystem-based approach, the development of benthic indicators, the definition of ‘pristine’ or sustainable conditions, the detection of pressures and the development of monitoring programs. We concluded that testing and integrating the different approaches was facilitated during the WFD process, which led to further insights and improvements, which the MSFD can rely upon. Expert involvement in the entire implementation process proved to be of vital importance.
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  • 72
    facet.materialart.
    Unknown
    Elsevier
    In:  [Talk] In: 20. Annual Goldschmidt Conference: Earth, Energy and Environment, 13.06.-19.06.2010, Knoxville, Tennessee, USA . Geochimica et Cosmochimica Acta ; A322 .
    Publication Date: 2012-02-23
    Description: Although most Central American magmas have a depleted MORB-source mantle (fluxed by subduction-derived fluids), magmas in southern Central America have isotopic and trace element compositions with a Galapagos affinity. How Galapagos-influenced signature was introduced into the Central American mantle is at the heart of conflicting theories [e.g. 1, 2, 3]. Our new data for Costa Rica suggest that this signature has a relatively recent origin (~6 Ma) [4, 5]. REE inverse modelling [6] results indicate that garnet is not present in the distal back-arc region. In contrast, adakites from Central America, as well as volcanic front lavas and alkaline lavas from central Costa Rica (Fig. 1) and Panama, require garnet in the source. Garnet-present sources (〈6 Ma) close to the volcanic front in Costa Rica and Panama suggest that the Galapagos-related reservoir can be either asthenospheric or recycled (subducting Galapagos tracks). The garnet-free source (〉12 Ma) in the distal back-arc suggests that there is another enriched reservoir stored in the lithosphere, predating any recent subduction-generated or asthenospheric flow
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  • 73
    facet.materialart.
    Unknown
    Elsevier
    In:  [Talk] In: Active Tephra in Kyushu, International Field Conference and Workshop on Tephrochronology, Volcanism and Human Activity, 09.05.-17.05.2010, Kirishima, South Kyushu, Japan . Quaternary International .
    Publication Date: 2012-02-23
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  • 74
    Publication Date: 2017-08-07
    Description: During the ‘New Vents’ SO191 cruise in 2007, the activity and distribution of seep sites on the gas-hydrate-bearing Hikurangi Margin, off northeastern New Zealand, were subjected to a highly detailed interdisciplinary study. Here we report on the visual observations and in situ measurements of physical properties performed with a ROV (remotely operated vehicle) and other video-guided platforms at two seep sites in the Rock Garden area; Faure Site and LM-3. The ROV allowed first ever visual observations of bubble-releasing methane seeps at the Hikurangi Margin. At Faure Site, bubble release was monitored during 4 dives, up to periods of 20 min. During the first dive, this resulted in the observation of six violent outbursts, each lasting 1 min over a three minute interval. These outbursts were accompanied by the displacement and resuspension of sediment grains, and the formation of small depressions, with a maximum diameter of 50 cm and depth of 15 cm, showing what is possibly an initial stage of pockmark formation. During subsequent dives at this bubble site, bubble release rates were rather constant and the previously observed outbursts could no longer be witnessed. At LM-3, the strongest manifestation of seep activity was a large platform (100 m2), consisting of fresh authigenic carbonates, which was covered by seep fauna (live Bathymodiolus sp. mussels, Calyptogena sp. shells and live Lamellibrachia sp. tubeworms). Bubble activity near this platform was less prominent than at Faure Site. Our observations suggest that the two seep environments result from different types of methane release; mainly by bubble release at Faure Site and rather diffusive at LM-3. We propose a conceptual model where the different ways of methane release and seep environments may be explained by the depth of underlying hydrate occurrences and different tectonic histories of both seep sites.
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  • 75
    facet.materialart.
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    Elsevier
    In:  Earth and Planetary Science Letters, 296 (1/2). pp. 34-44.
    Publication Date: 2019-09-23
    Description: Hydration of the oceanic lithosphere is an important and ubiquitous process which alters both the chemical and physical properties of the affected lithologies. One of the most important reactions that affect the mantle is serpentinization. The process of serpentinization results in a drastic decrease in the density (up to 40%), seismic velocity and brittle strength as well as water uptake of up to 13 wt.% of the ultramafic rock. In this paper, we use numerical models to study the amount and extent of serpentinization that may occur at mid-ocean ridges and its effects on fluid flow within the lithosphere. The two dimensional, FEM model solves three coupled, time-dependent equations: (i) mass-conserving Darcy flow equation, (ii) energy conserving heat transport equation and (iii) serpentinization rate of olivine with feedbacks to temperature (exothermic reaction), fluid consumption and variations in porosity and permeability (volume changes). The thermal structure of the ridge is strongly influenced by rock permeability in addition to the spreading velocity of the ridge. Increased rock permeability enhances hydrothermal convection and results in efficient heat mining from the lithosphere whereas higher spreading velocities result in a higher thermal gradient. Serpentinization of the oceanic mantle, in turn, depends on the aforementioned, competing processes. However, serpentinization of mantle rocks is itself likely to result in strong variations of rock porosity and permeability. Here we explore the coupled feedbacks. Increasing rates of serpentinization lead to large volume changes and therefore, rock fracturing thereby increasing rock porosity/permeability while as serpentinization reaches completion, the open pore space in the rock is reduced due to the relative dominance of mineral precipitation. Although, variations in the relation between porosity and permeability and serpentinization before the reaction reaches completion do not significantly affect the degree of serpentinization, we find that unreasonably large portions of the mantle would be serpentinized if rock closure does not occur at the final reaction stage. The amount of water trapped as hydrous phases within the mantle shows a strong dependency on the spreading velocity of the ridge with water content ranging from 0.18 × 105 kg/m2 to 2.52 × 105 kg/m2. Additionally, two distinct trends are observed where the water content in the mantle at slow-spreading ridges drops dramatically with an increase in spreading velocity. The amount of water trapped in the mantle at fast-spreading ridges, on the other hand, is lower and does not significantly depend on spreading velocity.
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  • 76
    Publication Date: 2013-06-10
    Description: We evaluate different hypotheses concerning the formation of a peculiar, flat-topped ridge at Rock Garden, offshore of the North Island of New Zealand. The coincidence of the ridge bathymetry with the depth at which gas hydrate stability intersects the seafloor has been previously used to propose that processes at the top of gas hydrate stability may cause seafloor erosion, giving rise to the flat ridge morphology. Two mechanisms that lead to increased fluid pressure (and sediment weakening) have previously been proposed: (1) periodic formation (association) and dissociation of gas hydrates during seafloor temperature fluctuations; and (2) dissociation of gas hydrates at the base of gas hydrate stability during ridge uplift. We use numerical models to test these hypotheses, as well as to evaluate whether the ridge morphology can develop by tectonic deformation during subduction of a seamount, without any involvement from gas hydrates. We apply a commonly-used 1D approach to model gas hydrate formation and dissociation, and develop a 2D mechanical model to evaluate tectonic deformation. Our results indicate that: (1) Tectonics (subduction of a seamount) may cause a temporary flat ridge morphology to develop, but this evolves over time and is unlikely to provide the main explanation for the ridge morphology; (2) Where high methane flux overwhelms the anaerobic oxidation of methane via sulphate reduction near the seafloor, short-period temperature fluctuations (but on timescales of years, not months as proposed originally) in the bottom water can lead to periodic association and dissociation of a small percentage of gas hydrate in the top of the sediment column. However, the effect of this on sediment strength is likely to be small, as evidenced by the negligible change in computed effective pressure; (3) The most likely mechanism to cause sediment weakening, leading to seafloor erosion, results from the interaction of gas hydrate stability with tectonic uplift of the ridge, provided bulk permeability strongly decreases with increasing hydrate content. Rather than overpressure developing from dissociation of hydrates at the base of gas hydrate stability (as previously thought), we found that the weakening is caused by focusing of gas hydrate formation at shallow sediment levels. This creates large fluid pressures and can lead to negative effective pressures near the seafloor, reducing the sediment strength.
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  • 77
    Publication Date: 2013-06-10
    Description: New high-resolution swath bathymetry data show a complex seafloor morphology from the Rock Garden area, offshore Hikurangi Margin, that coincides with the subduction of a seamount presently located beneath the summit of Rock Garden. Another ridge-shaped lower plate feature is initially colliding with Rock Garden, forming a re-entrant at its seaward flank. The slopes of the accretionary ridges are steeper than 10° and often more than 20° regionally. Slumping mostly occurs on the trench-ward slopes, with individual slumps affecting areas up to several km2. Critical taper analysis, using realistic wedge geometries and fluid pressures scenarios, shows that much of the seaward slopes in the region are most likely outside the stability field and therefore subject to failure. The most prominent feature revealed by seafloor maps is the trench-ward flank of Rock Garden with a height of 1800 to 2000 m and an average slope of more than 10°. Extensional faults arranged in two sub-circular arcs indicate that Rock Garden may be on the verge of failure. Critical taper analysis also supports this claim and shows that if basal fluid pressure approaches lithostatic pressure, e.g. during a large Mw 〉 8 earthquakes, then a complete failure of the entire trench-ward flank of Rock Garden would potentially affect an area as large as 150 km2 and a rock volume of 150 to 170 km3. This worst case scenario would generate a tsunami wave some tens of meters high. Therefore, the observation that a number of seamounts are buried beneath the outer Hikurangi accretionary wedge suggests that a thorough assessment of these features needs to be undertaken and its results incorporated into tsunami hazard models for the East Coast of New Zealand's North Island.
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  • 78
    Publication Date: 2020-07-23
    Description: Methane concentrations and carbon stable isotopic ratios (δ13CCH4), oxygen concentrations and hydrographic parameters (CTD) were investigated in the water column of the north-western Black Sea during the summers of 2003 and 2004. Water samples were collected along a transect which crosses three methane seep areas in 90, 220, and 600 m water depth. These active seeps strongly influence methane distribution in the overlying anoxic and oxic water column. Methane concentration and stable isotope (δ13CCH4) patterns indicate that water column stratification and microbial methane oxidation efficiently hamper the transfer of methane to the sea surface. Only the shelf seep site in 90 m water depth acts as a direct source of atmospheric methane. Microbial methane oxidation and/or gas stripping seem to cause oxygen depletion above the two shallower seep areas. The methane flux from the 90 m site into the water column is estimated to have been 0.599 × 106 mol yr− 1 (9.6 t yr− 1) in 2003 and 0.347 × 106 mol yr− 1 (5.6 t yr− 1) in 2004. Comparison of results from the two years shows different water column methane inventories in the deep part of the transect, implying a variable methane source strength at the 600 m deep site. The flux from this area is estimated to have been 11.35 × 106 mol yr− 1 in 2003.
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  • 79
    facet.materialart.
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    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 395 (1-2). pp. 223-231.
    Publication Date: 2017-07-11
    Description: Increasing levels of environmental stress due to global warming and eutrophication, and concerns about an unparalleled global diversity loss, have triggered new interest in the question whether the stability of ecosystem properties depends on population dynamics of dominant species or on compensatory growth of rare species. Recent meta-analyses suggest that compensatory dynamics are rare in natural systems. Experimental results, however, indicate that the interdependence of stressor regime, species traits, and species richness determines which mechanisms stabilise communities. Stability will depend on population dynamics of dominant species, if they remain the best performers regardless of disturbance. If dominant species become rare or lost, compensatory growth of rare species will insure natural communities against complete failure. Salinity is an important stressor governing growth and distribution of phytoplankton in brackish ecosystems, and its impact on coastal aquatic ecosystems is likely to change due to global warming. We performed two short-term experiments to investigate the effects of salinity stress on community structure and biomass production of natural phytoplankton communities collected in tidally influenced and polymictic Lake Waihola (New Zealand). The lake was brackish when the inoculum for the first experiment was collected. The inoculum for the second experiment originated from a fresh water situation. In both experiments, the phytoplankton assemblage was exposed to a salinity gradient ranging from 0 to 5. To assess the importance of dominance and compensatory growth, we determined biomass production, species richness, diversity, evenness and dominance indices, and species specific growth rates. Biomass production in our experiments was determined by dominant species. Anabaena flos-aquae dominated in the first experiment, and Asterionella formosa in the second experiment. Despite the importance of these species, we found significant growth responses of rare and abundant species. Even if these species showed high growth rates, biomass production was carried by the dominant species as long as the salinity level allowed them to grow. When the salinity level was detrimental to the growth of the dominant species, reduced dominance and increased diversity indices emphasised the importance of compensatory growth of rare species. The salinity stress applied in our experiments was strong enough to change the hierarchy of successful functional traits, which affected community structure and biomass production of the plankton communities. If the predicted sea water rise, increasing frequency of storm tides, rising water temperatures, and altered precipitation and run-off cause the salinity of coastal aquatic ecosystems to change, major changes in community composition, diversity and dominance structure of planktonic primary producers might be expected.
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  • 80
    Publication Date: 2019-09-23
    Description: We present and evaluate AquaMaps, a presence-only species distribution modelling system that allows the incorporation of expert knowledge about habitat usage and was designed for maximum output of standardized species range maps at the global scale. In the marine environment there is a significant challenge to the production of range maps due to large biases in the amount and location of occurrence data for most species. AquaMaps is compared with traditional presence-only species distribution modelling methods to determine the quality of outputs under equivalently automated conditions. The effect of the inclusion of expert knowledge to AquaMaps is also investigated. Model outputs were tested internally, through data partitioning, and externally against independent survey data to determine the ability of models to predict presence versus absence. Models were also tested externally by assessing correlation with independent survey estimates of relative species abundance. AquaMaps outputs compare well to the existing methods tested, and inclusion of expert knowledge results in a general improvement in model outputs. The transparency, speed and adaptability of the AquaMaps system, as well as the existing online framework which allows expert review to compensate for sampling biases and thus improve model predictions are proposed as additional benefits for public and research use alike. © 2009 Elsevier B.V. All rights reserved.
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  • 81
    Publication Date: 2019-09-23
    Description: Diffuse and focused low-temperature fluids emanate at 9°33′S (Mid-Atlantic Ridge) and precipitate Fe–Sioxyhydroxides that form chimneys, mounds and flat-lying deposits. This extensive vent field, named Lilliput, lies at the axial zone of a spreading segment with a significantly thickened crust (~11 km). Theoretically much more heat needs to be removed from a thick-crust spreading center compared to a spreading center with typical thickness of ~6 km. Therefore, settings with thickened crust should be favourable for supporting very powerful hydrothermal systems capable of producing large mineral deposits. This is the first report on the composition of seafloor hydrothermal deposits at abnormally thickened oceanic crust due to hotspot–ridge interaction. Our studies revealed that generally the Lilliput hydrothermal deposits are very similar in morphology, structure, composition and lateral extent to other low-temperature hydrothermal deposits of mid-ocean ridges and intraplate volcanoes. Deposits at the Lilliput vent field are composed of Si-containing goethite and ferrihydrite, have very low contents of a number of transition and rare earth elements and show REE distribution patterns with negative Ce and Eu anomalies. The speciation and precipitation of the main deposit-forming elements, Fe and Si, at the hydrothermal field appear to be partially controlled by live microbes and exuded organic compounds. The δ18O values of the precipitated silica-containing Feoxyhydroxides point to low-temperature formation and Sr–Nd–Pb–isotope variations suggest that the hydrothermal precipitates scavenged metals predominantly from the ambient seawater. These findings are in agreement with the biogeochemical scenario for their precipitation.
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  • 82
    Publication Date: 2016-09-16
    Description: The Late Glacial and Holocene history of environmental changes in the western Laptev Sea is reconstructed on the basis of continuous records of ice-rafted debris (IRD) and Atlantic water indicative subpolar planktic foraminifers and benthic foraminifer Cassidulina neoteretis from the two AMS14C dated sediment cores, one from the upper continental slope and another from the Khatanga paleoriver valley on the outer shelf. Since seasonal sea ice cover is a permanent feature in this high Arctic region the prominent IRD-rich intervals in the oldest (〉15.4 ka) and youngest (〈7.2 ka) sediment units are attributed to iceberg-rafting. Rock types like phyllites are used as indicators of sediment material supplied by icebergs from local ice caps of the Severnaya Zemlya Archipelago. Authigenic concretions of vivianite and rhodochrosite found in the basal, IRD-rich core section on the slope, point to strong water stratification likely caused by meltwater inputs. The oldest Late Glacial IRD peaks provide evidence for iceberg production by the local ice caps on Severnaya Zemlya. Subsequent meltwater influence is tentatively related to the freshwater release from a retreating Barents–Kara ice sheet in the northeastern Kara Sea. Already prior to 15.4 ka Atlantic-derived waters intermittently reached the western Laptev Sea continental slope probably facilitated by upwelling in coastal polynyas. While subsurface Atlantic-derived waters were constantly present at the continental slope between 15.4 and 12 ka, the disappearance of C. neoteretis together with reduced abundance of subpolar planktic foraminifers after 12 ka suggests establishment of a freshened shelf water mass on the flooded outer shelf which affected the water mass structure on the continental slope. After 7 ka climate cooling and enhanced Atlantic-derived water inflow caused re-growth of ice caps on Severnaya Zemlya leading to a recurrence of IRD. Peaks of this renewed IRD input are centered at 7.2, 6.4, 5.4, 3, and 2 ka, implying that this millennial-scale variability in the IRD input might be related to an overregional changes in atmospheric circulation patterns.
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  • 83
    Publication Date: 2019-09-23
    Description: Barrow, the northernmost point in Alaska, is one of the most intensively studied areas in the Arctic. However, paleoenvironmental evidence is limited for northern Alaska for the Lateglacial-Holocene transition. For a regional paleoenvironmental reconstruction, we investigated a permafrost ice-wedge tunnel near Barrow, Alaska. The studied site was first excavated in the early 1960s and intercepts a buried ice-wedge system at 3e6 m depth below the surface. A multi-methodological approach was applied to this buried ice-wedge system and the enclosing sediments, which in their combination, give new insight into the Late Quaternary environmental and climate history. Results of geochronological, sedimentological, cryolithological, paleoecological, isotope geochemical and microbiological studies reflect different stages of mid to late Wisconsin (MW to LW), Allerød (AD), Younger Dryas (YD), Preboreal (PB), and Late Holocene paleoenvironmental evolution. The LWage of the site is indicated by AMS dates in the surrounding sediments of 21.7 kyr BP at the lateral contact of the ice-wedge system as well as 39.5 kyr BP below the ice-wedge system. It is only recently that in this region, stable isotope techniques have been employed, i.e. to characterize different types of ground ice. The stable isotope record (oxygen: δ18O; hydrogen: δD) of two intersecting ice wedges suggests different phases of the northern Alaskan climate history from AD to PB, with radiocarbon dates from 12.4 to 9.9 kyr BP (ranging from 14.8 to 10.6 kyr cal BP). Stable isotope geochemistry of ice wedges reveals winter temperature variations of the Lateglacial-Holocene transition including a prominent YD cold period, clearly separated from the warmer AD and PB phases. YD is only weakly developed in summer temperature indicators (such as pollen) for the northern Alaska area, and by consequence, the YD cold stadial was here especially related to the winter season. This highlights that the combination of winter and summer indicators comprehensively describes the seasonality of climate-relevant processes in discrete time intervals. The stable isotope record for the Barrow buried ice-wedge system documents for the first time winter climate change at the Lateglacial-Holocene transition continuously and at relatively high (likely centennial) resolution.
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  • 84
    facet.materialart.
    Unknown
    Elsevier
    In:  Marine Chemistry, 120 (1-4). pp. 4-13.
    Publication Date: 2017-08-22
    Description: The fraction of atmospherically deposited iron which dissolves in seawater, or becomes available to phytoplankton for growth, is a key determinant of primary productivity in many open ocean regions. As such this parameter plays an important part in the global oceanic cycles of iron and carbon, and yet the factors that control iron dissolution from aerosol are very poorly understood. In this manuscript we seek to synthesise the available knowledge of these factors, which operate in the atmosphere and in seawater. A conceptual model of the overall aerosol iron solubility is presented, in which we liken the various controls on iron solubility to sets of parallel electrical resistors. We also discuss experimental methods for the determination of iron solubility and make recommendations for future studies in this area.
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  • 85
    Publication Date: 2019-09-23
    Description: Despite large uncertainties in the fertilization efficiency, natural iron fertilization studies and some of the purposeful iron enrichment studies have demonstrated that Southern Ocean iron fertilization can lead to a significant export of carbon from the sea surface to the ocean interior. From an economic perspective the potential of ocean iron fertilization (OIF) is far from negligible in relation to other abatement options. Comparing the range of cost estimates to the range of estimates for forestation projects they are in the same order of magnitude, but OIF could provide more carbon credits even if high discount rates are used to account for potential leakage and non-permanence. However, the uncertainty about undesired adverse effects of purposeful iron fertilization on marine ecosystems and biogeochemistry has led to attempts to ban commercial and, to some extent, scientific experiments aimed at a better understanding of the processes involved, effectively precluding further consideration of this mitigation option. As regards the perspective of public international law, the pertinent agreements dealing with the protection of the marine environment indicate that OIF is to be considered as lawful if and to the extent to which it represents legitimate scientific research. In this respect, the precautionary principle can be used to balance the risks arising out of scientific OIF activities for the marine environment with the potential advantages relevant to the objectives of the climate change regime. As scientific OIF experiments involve only comparatively small negative impacts within a limited marine area, further scientific research must be permitted to explore the carbon sequestration potential of OIF in order to either reject this concept or integrate it into the flexible mechanisms contained in the Kyoto Protocol.
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  • 86
    Publication Date: 2020-08-07
    Description: NW African climate shows orbital and millennial-scale variations, which are tightly connected to changes in marine productivity. We present an organic-walled dinoflagellate cyst (dinocyst) record from a sediment core off Cape Yubi at about 27°N in the Canary Basin covering the time period from 47 to 3 ka before present (BP). The dinocyst record reflects differences in upwelling intensity and seasonality as well as the influence of fluvial input. Sea-level changes play an important role for the upwelling pattern and productivity signals at the core site. Within the studied time interval, four main phases were distinguished. (1) From 45 to 24 ka BP, when sea-level was mostly about 75 m lower than today, high relative abundances of cysts of heterotrophic taxa point to enhanced upwelling activity, especially during Heinrich Events, while relatively low dinocyst accumulation rates indicate that filament activity at the core location was strongly reduced. (2) At sea-level lowstand during the LGM to H1, dinocyst accumulation rates suggest that local filament formation was even more inhibited. (3) From the early Holocene to about 8 ka BP, extraordinary high accumulation rates of most dinocyst species, especially of Lingulodinium machaerophorum, suggest that nutrient supply via fluvial input increased and rising sea-level promoted filament formation. At the same time, the upwelling season prolongated. (4) A relative increase in cysts of photoautotrophic taxa from about 8 ka BP onwards indicates more stratified conditions while fluvial input decreased. Our study shows that productivity records can be very sensitive to regional features. From the dinocyst data we infer that marine surface productivity off Cape Yubi during glacial times was within the scale of modern times but extremely enhanced during deglaciation.
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  • 87
    Publication Date: 2019-09-23
    Description: This study investigates the land–ocean interactions along the northern margin of the Gulf of Cadiz in the vicinity of the Guadiana River. Benthic foraminifera and sedimentological characteristics were analysed in a sedimentary sequence spanning ca. 5000 years (core 8, 22 m water depth) retrieved from the inner shelf prodeltaic wedge. The analyses were integrated in a temporal framework based on accelerated mass spectrometry radiocarbon dating. Paleoenvironmental changes and sediment transfer mechanisms from the continent to the shelf were investigated and related to climatic oscillations and anthropogenic impact in the region. The results allowed the identification of two main periods of deposition. The first period, from ca. 5150 cal. BP (core base) to 1500–1200 cal. BP, is characterised by a mix of fine and coarse sediments, relatively constant percentages of terrigenous and bioclasts, and benthic foraminifera species characteristic of coastal environments. These features indicate an environment strongly influenced by discharge from the Guadiana River. The second period, from ca. 1500–1200 cal. BP to ca. 200 cal. BP (core top), is characterised by silt-clay fraction dominated sediments, an increase in terrigenous sediment towards the top, and benthic foraminifera species characteristic of environments with low levels of energy. An increase in the level of human occupation associated with changes in climate led to widespread erosion and soil loss to the continental shelf during this period, with possible silting up of the Guadiana eastern distributary, allowing the transport of high amounts of sediment to the shelf by the western distributary that led to the enhancement of fine sedimentation and the formation of the prodeltaic wedge in the area of the studied core.
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  • 88
    Publication Date: 2019-09-23
    Description: The strength of the North Atlantic Meridional Overturning Circulation during climatically highly variable Marine Isotope Stage (MIS) 3 has attracted much attention in recent years. Here we present highresolution Nd isotope compositions of past seawater derived from authigenic Fe-Mn oxyhydroxides recovered from drift sediments on the Blake Ridge in the deep western North Atlantic (ODP Leg 172, Site 1060, 3481 m water depth). The data cover the period from 45 to 35 ka BP, tracing circulation changes during major Heinrich iceberg discharge event 4 (H4, ~40-39kaBP), The Nd isotope record suggests that there was no northern source water (NSW) mass like modern NADW at the deeper part of Blake Ridge at any time between 45 and 35 ka. This is fundamentally different from the hydrographic situation during the Holocene where NADW extends below 4500 m at this location. The εNd of past deep water recorded in the Blake Ridge sediments was least radiogenic during Dansgaard/Oeschger (D/O) Interstadial (IS) 8 (εNd = -11.3)and most radiogenic immediately preceding IS 9 (εNd = -9.8). More radiogenic compositions were also recorded during H4 (-10.2 ≤ εNd ≤ 9.9). The Nd isotope variability in MIS 3 matches that of a physical bottom current strength reconstruction from the same location. Neither record follows the pattern of Northern Hemisphere D/O climatic cycles. In our record, reduced mixing with northern source waters started in stadial 12 and lasted until after H4 in stadial 9, followed by a rapid increase in NSW contribution thereafter. This major change in the Nd isotope record predates the iceberg discharge event Heinrich 4 by more than 3 ka indicating a shallowing of the water mass boundary between Glacial North Atlantic Intermediate Water and Southern Source Water beneath. This early change in bottom water properties at the deep Blake Ridge suggests that North Atlantic deep water advection may already have decreased several thousand years before the actual iceberg discharge event and associated freshening of the surface waters in the North Atlantic. The change can thus not be attributed to climatic events in the North Atlantic but may be related to changes in flux of deep water from the South.
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  • 89
    Publication Date: 2017-08-08
    Description: This paper is an introduction to and an overview of papers presented in the Special Issue of Marine Geology “Methane seeps at the Hikurangi Margin, New Zealand”. In 2006 and 2007, three research cruises to the Hikurangi Margin at the east coast of New Zealand's North Island were dedicated to studying methane seepage and gas hydrates in an area where early reports suggested they were widespread. Two cruises were carried out on RV TANGAROA and one on RV SONNE using the complete spectrum of state-of-the-art equipment for geophysics (seismic, sidescan, controlled source electromagnetics, ocean bottom seismometers and hydrophones, singlebeam and multibeam), seafloor observations (towed camera systems, ROV), sediment and biological sampling (TV-guided multi-corer, gravity-corer, grab, epibenthic sled), deployment of in-situ observatories (landers) as well as water column sampling and oceanographic studies (CTD, moorings). The scientific disciplines involved ranged from geology, geophysics, petrography, geochemistry, to oceanography, biology and microbiology. These cruises confirmed that a significant part of the Hikurangi Margin has been active with locally intense methane seepage at present and in the past, with the widespread occurrence of dead seep faunas and knoll-forming carbonate precipitations offshore and on the adjacent land. A close link to seismically detected fluid systems and the outcropping of the base of the gas hydrate stability zone can be found at some places. Pore fluid and free gas release were found to be linked to tides. Currents as well as density layers modulate the methane distribution in the water column. The paper introduces the six working areas on the Hikurangi Margin, and compiles all seep locations based on newly processed multibeam and multibeam backscatter data, water column hydroacoustic and visual data that are combined with results presented elsewhere in this Special Issue. In total, 32 new seep sites were detected that commonly show chemoherm-type carbonates or carbonate cemented sediment with fissures and cracks in which calyptogenid clams and bathymodiolid mussels together with sibloglinid tube worms live. White bacterial mats of the genus Beggiatoa and dark gray beds of heterotrophic ampharetid polychaetes typically occur at active sites. Bubble release has frequently been observed visually as well as hydroacoustically (flares) and geochemical analyses show that biogenic methane is released. All seep sites, bubbling or not, were inside the gas hydrate stability zone. Gas hydrate itself was recovered at three sites from the seafloor surface or 2.5 m core depth as fist-sized chunks or centimeter thick veins. The strong carbonate cementation that in some cases forms 50 m high knolls as well as some very large areas being paved with clam shells indicates very strong and long lasting seep activity in the past. This activity seems to be less at present but nevertheless makes the Hikurangi Margin an ideal place for methane-related seep studies in the SW-Pacific.
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  • 90
    Publication Date: 2017-09-12
    Description: We present major element and PGE (platinum-group-element) abundances in addition to Re–Os isotope data for 11 spinel-facies whole rock peridotites from a single maar from the Middle Atlas Mountains, Morocco. Major element systematics of these xenoliths are generally correlated with indices of depletion. FeO–MgO systematics appear to suggest spinel-facies melting in the range of 5 to 25%. However, Al2O3 abundances in these xenoliths appear elevated relative to primitive mantle (Prima). The Al2O3 abundances in conjunction with other major elements require distinct re-enrichment of the Middle Atlas continental mantle root due to melt/rock reaction and precipitation of amphibole and/or clinopyroxene from passing silicate melts akin to MORB or OIB that evolved in reverse direction along the melting curves in e.g. FeO–MgO space. Sc and V confirm the range of apparent depletion and also indicate that the currently preserved fO2 in these peridotites is distinctly different from fO2 conditions observed in subduction zones. The majority of these xenoliths have low Os and Ir (I-PGEs) concentrations relative to Prima and modelled sulphide- and clinopyroxene-depleted residues of mantle melting under low fO2, mid-ocean ridge-like conditions. Moreover, Pt and Pd (P-PGE) abundances are elevated when compared to their expected abundances after substantial melt extraction. Importantly, the systematically low Ir abundances in the majority of samples show well-correlated trends with Al2O3, MgO and Cu that are inconsistent with established melting trends. Os isotopes in the Middle Atlas xenoliths range from 187Os/188Os = 0.11604 to 0.12664 although most samples are close to chondritic. The Os isotope ratios are decoupled from 187Re/188Os but, together with Re abundances, also exhibit a good correlation with Al2O3, MgO and Cu. The major element, I-PGE and Os isotope correlations suggest that the initial melt depletion led to the exhaustion of sulphide and clinopyroxene (20 to 30%) without significant stabilization of I-PGE-rich alloys. During later modal metasomatism of the refractory Middle Atlas continental mantle root with silicate melts akin to MORB or OIB the introduction of clinopyroxene/amphibole reduced the volume of the melt inducing sulphur saturation in these melts causing precipitation of secondary sulphides. This coupled crystallization of pyroxenes and sulphides (chalcopyrite) resulted in the two-component mixing systematics exhibited by I-PGEs, Os isotopes with major elements and Cu preserved in the Middle Atlas continental mantle root.
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  • 91
    Publication Date: 2017-08-07
    Description: The concentration and carbon isotope values of dissolved methane were measured in the water column at Rock Garden, Omakere Ridge and Wairarapa areas in the first dedicated cold seep investigation along the Hikurangi Margin of New Zealand. These measurements provide a high resolution impression of the methane distribution in the water column and show that these seep sites are actively venting methane with varying intensity. The highest concentrations (up to 3500 nM) measured in water samples obtained from Conductivity–Temperature–Depth (CTD) operations were at Faure Site of Rock Garden. Here, seafloor bubble release was observed by ROV. The Omakere Ridge area is actively venting over almost its entire length (not, vert, similar 25 km), in particular at Bear's Paw, a newly discovered seep site. In the Wairarapa area another new seep site called Tui was discovered, where methane measurements often exceeded 500 nM. No evidence was obtained from water column or sea surface measurements along the Hikurangi Margin to indicate that methane from seeps is reaching the sea surface. In fact, a consistent upper boundary was observed at a density of 26.85 kg/m3, which occurs at about 500 m below sea surface, above which methane decreased to background concentrations. No obvious oceanographic feature is associated with this 500 m CH4 boundary. Bubble dissolution calculations show that about 500 m was also the model-derived maximum bubble rise height. A wide range of δ13CCH4 values from − 71 to − 19‰ (VPDB) were measured, with the highest CH4 concentrations having the lowest δ13CCH4 values of about − 71 to − 68‰. Simple mixing and isotope fractionation calculations show that changes of δ13CCH4 values are predominantly caused by the dilution of seep fluids with the seawater, with some anaerobic oxidation also occurring.
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  • 92
    Publication Date: 2019-09-23
    Description: Favourable sea-ice conditions gave way to an acoustic survey offshore NE Greenland during RV Polarstern ARK-XXIV/3 leg in 2009. The acquired data set clearly depicts sediment ridges in an area of app. 18 × 9 km. The ridges are found in water depths between 270 and 350 m. The sediment ridges are 2.5–9 km long, 50–250 m wide and 5–25 m high. In profile, most of these ridges are characterized by steep slopes towards Northwest and gentle slopes towards Southeast. Their internal structure, imaged by parametric echo-sounding data, shows that they are positive sedimentation features rather than erosive remnant structures. Arcuate shape, joint orientation and position on a basal till are indicative for end moraines. Because they are positioned within the Westwind Trough on a basal till that extends further east, we consider these ridges end moraines of the Westwind ice stream reported by Evans et al. (2009), Marine geophysical evidence for former expansion and flow of the Greenland Ice Sheet across the north-east Greenland continental shelf. Journal of Quaternary Science (2008), doi: 10.1002/jqs.1231.). Based on our hydro-acoustic data, we interpret these end moraines to be formed by short-lived re-advances during an overall recession of the ice margin. However, they could also be deposited during halts of the grounding line (comparable to De Geer moraines) though their morphological characteristics are slightly different from most published De Geer moraines. The ages for the moraine deposition can be inferred from a thin sedimentary drape indicating timing between Lateglacial and early Holocene. This set of end moraines is direct evidence for a dynamic behaviour of the marine-based ice stream during the last deglaciation on the NE Greenland shelf.
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  • 93
    Publication Date: 2020-08-05
    Description: Gulf of Mexico cold seeps characterized by variable compositions and magnitudes of hydrocarbon seepage were sampled in order to investigate the effects of natural oils, methane, and non-methane hydrocarbons on microbial activity, diversity, and distribution in seafloor sediments. Though some sediments were characterized by relatively high quantities of oil, which may be toxic to some microorganisms, high rates of sulfate reduction (SR, 27.9714.7 mmol m2 d1), anaerobic oxidation of methane (AOM, 16.276.7 mmol m2 d1), and acetate oxidation (2.7470.76 mmol m2 d1) were observed in radiotracer measurements. In many instances, the SR rate was higher than the AOM rate, indicating that non-methane hydrocarbons fueled SR. Analysis of 16S rRNA gene clone libraries revealed phylogenetically diverse communities that were dominated by phylotypes of sulfate-reducing bacteria (SRB) and anaerobic methanotrophs of the ANME-1 and ANME-2 varieties. Another group of archaea form a Gulf of Mexico-specific clade (GOM ARC2) that may be important in brine-influenced, oil-impacted sediments from deeper water. Additionally, species grouping within the uncultivated Deltaproteobacteria clades SEEP-SRB3 and -SRB4, as well as relatives of Desulfobacterium anilini, were observed in relatively higher abundance in the oil-impacted sediments, suggesting that these groups of SRB may be involved in or influenced by degradation of higher hydrocarbons or petroleum byproducts.
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  • 94
    facet.materialart.
    Unknown
    Elsevier
    In:  , ed. by Greinert, J., Bialas, J., Lewis, K. and Suess, E. Marine Geology - Special issue, 272 . Elsevier, Amsterdam, 336 pp.
    Publication Date: 2013-07-18
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  • 95
    Publication Date: 2019-09-23
    Description: Three new metabolites, 5-hydroxy-3,7-dimethoxyflavone-4′-O-β-glucopyranoside (1), 2β,19-epoxy-3β,14β-dihydroxy-19-methoxy-5α-card-20(22)-enolide (4) and β-anhydroepidigitoxigenin-3β-O-glucopyranoside (5), along with two known compounds, uzarigenine (2) and β-anhydroepidigitoxigenin (3), were isolated from Calotropis procera (Asclepiadaceae). The structure elucidation was accomplished mainly by nuclear magnetic resonance (NMR) spectroscopic and mass spectrometric methods. To examine putative antimicrobial or cytotoxic activities, various bioassays were performed. Uzarigenine (2) demonstrated moderate cytotoxicity.
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  • 96
    Publication Date: 2019-01-22
    Description: The carbonate chemistry of the world’s oceans, including their pH, has been remarkably constant for hundreds of thousands of years (Pearson and Palmer, 2000), with typical surface ocean variations between ice ages and warm phases of no more than 0.2 pH units ([Sanyal et al., 1995], [Hönisch and Hemming, 2005] and [Foster, 2008]). However, since the beginning of the industrial revolution, the oceans have taken up approximately 30% of the CO2 produced from fossil fuel burning, cement manufacture and land use changes (Sabine et al., 2004). While the invasion of CO2 into the ocean removes this greenhouse gas from the atmosphere and thereby dampens global warming, it forms carbonic acid in seawater and lowers ambient surface ocean pH (Broecker and Peng, 1982). Ocean acidification is the direct consequence of the excessive addition of CO2 to seawater (Broecker and Takahashi, 1977) and is therefore inherently more predictable than temperature and precipitation changes due to rising CO2 in the atmosphere. Changes are already measurable today ([Bates, 2001], [Bates et al., 2002], [Takahashi et al., 2003], [Keeling et al., 2004] and [Santana-Casiano et al., 2007]) and will become more pronounced as humankind emits more CO2 into the atmosphere, with surface ocean pH expected to decline by a further 0.3 pH units by the end of the century, corresponding to an approximately 100% increase in ocean acidity (hydrogen ion concentration [H+]), on top of the not, vert, similar0.1 pH unit decline to date ([Caldeira and Wickett, 2003], [Orr et al., 2005] and Solomon et al., 2007 In: S. Solomon et al., Editors, Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Fourth Assessment Report of the IPCC, Cambridge University Press, Cambridge (2007).[Solomon et al., 2007]) (Fig. 1). Such a rapid change in ocean pH has very likely not happened since the time the dinosaurs went extinct 65 million years ago ([van der Burgh et al., 1993], [Pearson and Palmer, 2000] and [Pagani et al., 2005]). While the dissolution of carbonate sediments on the bottom of the ocean and the weathering of rocks on land coupled with mixing of surface and deeper waters will eventually restore ocean pH to its pre-industrial state, this process will take up to a million years to complete ([Archer, 2005] and [Ridgwell and Zeebe, 2005]).
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  • 97
    Publication Date: 2021-06-24
    Description: We present strontium (Sr) isotope ratios that, unlike traditional 87Sr/86Sr data, are not normalized to a fixed 88Sr/86Sr ratio of 8.375209 (defined as δ88/86Sr = 0 relative to NIST SRM 987). Instead, we correct for isotope fractionation during mass spectrometry with a 87Sr–84Sr double spike. This technique yields two independent ratios for 87Sr/86Sr and 88Sr/86Sr that are reported as (87Sr/86Sr*) and (δ88/86Sr), respectively. The difference between the traditional radiogenic (87Sr/86Sr normalized to 88Sr/86Sr = 8.375209) and the new 87Sr/86Sr* values reflect natural mass-dependent isotope fractionation. In order to constrain glacial/interglacial changes in the marine Sr budget we compare the isotope composition of modern seawater ((87Sr/86Sr*, δ88/86Sr)Seawater) and modern marine biogenic carbonates ((87Sr/86Sr*, δ88/86Sr)Carbonates) with the corresponding values of river waters ((87Sr/86Sr*, δ88/86Sr)River) and hydrothermal solutions ((87Sr/86Sr*, δ88/86Sr)HydEnd) in a triple isotope plot. The measured (87Sr/86Sr*, δ88/86Sr)River values of selected rivers that together account for not, vert, similar18% of the global Sr discharge yield a Sr flux-weighted mean of (0.7114(8), 0.315(8)‰). The average (87Sr/86Sr*, δ88/86Sr)HydEnd values for hydrothermal solutions from the Atlantic Ocean are (0.7045(5), 0.27(3)‰). In contrast, the (87Sr/86Sr*, δ88/86Sr)Carbonates values representing the marine Sr output are (0.70926(2), 0.21(2)‰). We estimate the modern Sr isotope composition of the sources at (0.7106(8), 0.310(8)‰). The difference between the estimated (87Sr/86Sr*, δ88/86Sr)input and (87Sr/86Sr*, δ88/86Sr)output values reflects isotope disequilibrium with respect to Sr inputs and outputs. In contrast to the modern ocean, isotope equilibrium between inputs and outputs during the last glacial maximum (10–30 ka before present) can be explained by invoking three times higher Sr inputs from a uniquely “glacial” source: weathering of shelf carbonates exposed at low sea levels. Our data are also consistent with the “weathering peak” hypothesis that invokes enhanced Sr inputs resulting from weathering of post-glacial exposure of abundant fine-grained material.
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  • 98
    facet.materialart.
    Unknown
    Elsevier
    In:  Ocean Modelling, 34 (3-4). pp. 150-165.
    Publication Date: 2019-01-23
    Description: The sensitivity of the meridional overturning circulation (MOC) of the Southern Ocean (SO) to wind stress changes is discussed. Using an idealised SO model in both non- and eddy-permitting configurations, we assess the effects of both, coarsening the horizontal resolution and implementing different parameterisations for the lateral eddy diffusivity appropriate to the Gent and McWilliams (1990) parameterisation, K. We find that the MOC is characterised by an eddy-driven part ψ* which generally opposes the wind-driven part and that the increase of the MOC diminishes with amplifying winds, with the possibility that the MOC in the SO may become completely insensitive to wind stress changes. However, for moderate wind stress, the MOC is still significantly increasing in our configuration. The diagnosed lateral eddy diffusivity K in the eddy-permitting version shows strong spatial variability and is increasing with increasing wind stress. Similar to the MOC (but in contrast to ψ*) the increase of K diminishes with amplifying winds. It turns out that a small increase in the isopycnal slopes is also relevant in order to capture the correct sensitivity of ψ* on wind stress. This relation also holds in model configurations with coarser but still eddy-permitting horizontal resolution: decreasing the horizontal resolution decreases K, but increases the isopycnal slopes such that the strength of the MOC including its sensitivity to wind stress is almost unchanged. The parameterisations are able to reproduce the MOC for certain wind stresses, but all parameterisations underestimate the sensitivity of K and thus overestimate the sensitivity of the MOC on wind stress. Our results show that it is indispensable to incorporate the correct sensitivity of K into climate models in order to reproduce the correct sensitivity of the MOC to wind stress and that up-to-date parameterisations for K are only partially successful.
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  • 99
    Publication Date: 2017-07-26
    Description: Mass wasting processes are a common phenomenon along the continental margin of NW-Africa. Located on the high-upwelling regime off the Mauritanian coastline, the Mauritania Slide Complex (MSC) is one of the largest events known on the Atlantic margin with an affected area of not, vert, similar30 000 km2. Understanding previous failure events as well as its current hazard potential are crucial for risk assessment with respect to offshore installations and tsunamis. We present the results of geotechnical measurements and strain analyses on sediment cores taken from both the stable and the failed part of the MSC and compare them to previously published geophysical and sedimentological data. The material originates from water depths of 1500–3000 m and consists of detached slide deposits separated by undisturbed hemipelagic sediments. While the hemipelagites are characterized by normal consolidation with a downward increase in bulk density and shear strength (from 1.68 to 1.8 g/cm3, 2–10 kPa), the slid deposits of the uppermost debris flow event preserve constant bulk density values (1.75 and 1.8 g/cm3) with incisions marking different flow events. These slid sediments comprise three different matrix types, with normal consolidation at the base (OCR = 1.04), strong overconsolidation (OCR = 3.96) in the middle and normal consolidation to slight overconsolidation at the top (OCR = 0.91–1.28). However, the hemipelagic sediments underlying the debris flow units, which have been 14C dated at 〈24 ka BP, show strong to slight underconsolidation (OCR = 0.65–0.79) with low friction coefficients of μ = 0.18. Fabric analyses show deformation intensities R ≥ 4 (ratio σ1/σ3) in several of the remobilized sediments. Such high deformation is also attested by observed disintegrated clasts from the underlying unit in the youngest debrites (14C-age of 10.5–10.9 ka BP). These clasts show strong consolidation and intense deformation, implying a pre-slide origin and amalgamation into the mass transport deposits. While previous studies propose an emplacement by retrogressive failure for thick slide deposits separated by undisturbed units, our new data on geotechnical properties, strain and age infer at least two different source areas with a sequential failure mechanism as the origin for the different mass wasting events.
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  • 100
    Publication Date: 2017-12-07
    Description: Brachiopod shells are widely used as an archive to reconstruct elemental and isotopic composition of seawater. Studies, focused on oxygen and carbon isotopes over the last decades, are increasingly extending to the emerging calcium isotope system. To date, only little attention has been paid to test the reliability of fossil brachiopods on their modern counterparts. In this context, the present study investigates two modern brachiopods, Terebratulina septentrionalis (eastern Canada, 5–30 m depth, 7.1 °C seasonal temperature variation, two-layer shell) and Gryphus vitreus (northern Mediterranean, 200 m depth, constant all-year round temperature, three-layer shell). Both species were sampled along the ontogenetic growth direction and calcium, oxygen, and carbon isotopes as well as elemental concentration were measured. Calcium isotopes were analyzed on TIMS. The elemental composition was analyzed by LA-ICP-MS and ICP-AES. The results indicate an intra-specimen δ44/40Ca variation ranging from 0.16 to 0.33‰, pointing to a fairly homogenous distribution of calcium isotopes in brachiopod shells. However, in the light of the suggested 0.7‰ increase in calcium isotopes over the Phanerozoic such intra-specimen variations constrain ocean reconstruction. δ44/40Ca values of T. septentrionalis do not seem to be affected by growth rate. Calcium isotopic values of G. vitreus are heavy in the central part of the shell and trend towards lighter values in peripheral areas approaching the maximum isotopic composition of T. septentrionalis. The maximum inter-species δ44/40Ca difference of 0.62‰ between T. septentrionalis and G. vitreus indicates that care should be taken when using different taxa, species with different strontium content or brachiopods with specialized shell structure, such as G. vitreus, for ocean water reconstruction in terms of Ca isotopic composition. T. septentrionalis may record Ca isotopic fractionation related to seasonal seawater temperature variations in its shell but this is difficult to resolve at the current analytical precision. Average δ18O-derived temperatures of the two investigated species are close to on-site measured temperatures.
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