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  • Angiosperms
  • Gas chromatography
  • Springer  (22)
  • American Association for the Advancement of Science
  • Springer Nature
  • 2010-2014
  • 2005-2009
  • 1980-1984  (22)
  • 1935-1939
  • 1925-1929
  • 1980  (22)
Collection
Publisher
  • Springer  (22)
  • American Association for the Advancement of Science
  • Springer Nature
  • Wiley-Blackwell  (57)
Years
  • 2010-2014
  • 2005-2009
  • 1980-1984  (22)
  • 1935-1939
  • 1925-1929
Year
  • 1
    ISSN: 1432-0878
    Keywords: Preputial glands ; Nude mice ; Ultrastructure ; Gas chromatography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The preputial glands of male nude (nu/nu) mice were analyzed by a combination of electron microscopy and gas chromatography to determine whether or not they are affected, like developing hairs and nails, by the nu/nu genotype. Results of the analyses revealed no differences between the glands of nude and normal male mice in either their ultrastructural characteristics or lipid secretory products.
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  • 2
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    Plant systematics and evolution 134 (1980), S. 11-21 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Daucus ; Petroselinum ; Acer ; rRNA ; transcription ; precursors of less than 2.5 × 106 daltons ; processing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Actively dividing cells from parsley (Petroselinum crispum) and carrot (Daucus carota) (bothApiaceae) andAcer pseudoplatanus (Aceraceae) were used to detect the primary gene product of the rDNA in plant cells. Parsley and carrot cells were labelled with [32P] orthophosphate. In both cases only one high molecular weight rRNA precursor was present on polyacrylamide gels under non-denaturing conditions. Its molecular weight did not exceed 2.5 × 106 daltons. The component emerged from the heterogenous material after a labelling period of 5–10 min. In parsley cells 45 min after onset of incubation labelled mature rRNA (25S and 18S) arrived in the cytoplasm. InAcer pseudoplatanus (incubation period 60 min) two rapidly labelled components did emerge from polyacrylamide gels; their molecular weights were 2.3 and 3.2− 3.4 × 106 daltons. After electrophoresis under denaturing conditions the larger component was no longer present, thus indicating that it was an aggregate of different RNA molecules. The molecular weights of the rRNA precursors ofD. carota andP. crispum determined after electrophoresis in formamide gels were about 2.1 × 106 daltons. From these results we have no evidence for the existence of rRNA precursors exceeding the molecular weight of 2.5 × 106 daltons.
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  • 3
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    Plant systematics and evolution 135 (1980), S. 11-39 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Winteraceae ; Drimys brasiliensis ; Development of inflorescences ; flowers and fruits ; reproductive biology ; pollination ; seed dispersal ; vegetative propagation ; early Angiosperm evolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract From field observations onDrimys brasiliensis, principally in the Botucatu region of São Paulo State, Brazil, new data on the reproductive biology, the rhythm of growth, and the development of lateral cymose inflorescences, flowers and fruits are presented. Pollination accelerates the rate of flower-development for about 4–6 days. Pollination experiments show thatD. brasiliensis is not self-sterile; because of mechanical devices the sticky pollen grains do not normally come into contact with the stigmata unless an animal pollen vector is involved. The pollinators are diurnalColeoptera, Diptera andThysanoptera which eat from the pollen, lick from the stigmatic exudates and (in case of the flies) probably also from the staminal glands. Fruit- and seedeaters are birds which seem to be the main dispersal agents. Establishment of new individuals normally is through seedlings, but also by vegetative propagation through plagiotropous branches which may root and separate from the mother plant. The morphological, developmental and reproductive aspects inD. brasiliensis are discussed in a wider context, compared with data from otherMagnoliidae, and related to aspects of early Angiosperm evolution.
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  • 4
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    Plant systematics and evolution 136 (1980), S. 247-258 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Poaceae (=Gramineae) ; Triticum ; Aegilops ; diploid species ; Starch Gel electrophoresis ; allozymic variation ; phylogenetic relationships ; evolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Twenty enzyme loci were examined in the diploid species ofTriticum andAegilops for allelic variation by starch gel electrophoresis. SectionSitopsis, including the five species,Ae. speltoides, Ae. lingissima, Ae. sharonensis, Ae. bicornis andAe. searsii form a close subgroup withAe. speltoides slightly removed from the others.T. monococcum s. lat., was found to be closest to the species of theSitopsis group.Ae. comosa, Ae. umbellulata andAe. uniaristata form a second subgroup withAe. caudata most closely related to these species.Ae. squarrosa appears almost equally related to all of the species, showing no special affinity for any one species group. Nineteen out of twenty loci examined were polymorphic with a mean of 6.7 alleles per locus. Species could be, for most loci, characterized by the presence of predominant alleles. A conspicious genetic characteristic ofTriticum-Aegilops is the sharing of these predominant alleles between species. Within species variation is characterized by a diffuse distribution of secondary alleles.
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  • 5
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    Chromatographia 13 (1980), S. 203-206 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Carrier gas purity ; Sample stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The amount of oxygen which may be present in the gas volume corresponding to a peak is investigated and compared to the sample amounts. It is shown that even with high purity carrier gases one may have a significant excess of oxygen present at low sample amounts. Attention is drawn to the possibility of impurity build-up by diffusion e.g. through the septum.
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  • 6
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    Chromatographia 13 (1980), S. 263-270 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Metal complexes ; Enantiomers ; Isotopic composition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The high selectivity of complexation gas chromatography has been employed for enantiomer resolution and isotope separation. Thus, a chiral olefin, 3-methylcyclopentene, has been resolved analytically on optically active dicarbonyl-rhodium(I)-3-trifluoroacetyl-1R-camphorate in squalane. The deuterated ethylenes C2H4−nDn have been separated on the same rhodium(I)-containing stationary phase. The chiral aliphatic oxiranes epoxypropane andtrans-2,3-epoxybutane have been resolved on optically active nickel(II)-bis-3-trifluoroacetyl-1R-camphorate in squalane.
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  • 7
    ISSN: 1612-1112
    Keywords: Gas chromatography ; On-column abstraction ; Aliphatic aldehydes ; Amine antioxidants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The selective on-column abstraction of aliphatic aldehydes by gas chromatographic stationary phases containing N-iso-propyl N′-phenyl-p-phenylenediamine is described.
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  • 8
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    Chromatographia 13 (1980), S. 35-39 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Nitromethane ; Nitroalkanes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Impurities in commercially available nitromethane have been determined by gas-liquid chromatography using six different column packings. Besides nitromethane, 1-nitropropane, 2-nitropropane, acetonitrile, methanol, small amounts of ethanol and acetaldehyde have been detected. The presence of formaldehyde, ethyl acetate and acetone is probable. Mixtures containing comparable amounts of the four nitroalkanes could be separated on all columns, but plots of logarithms of the retention times vs. carbon number or boiling points of the nitroalkanes or column temperatures were linear only in case of columns packed with Porapak R and Q.
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  • 9
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    Plant systematics and evolution 134 (1980), S. 23-31 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Poaceae ; Agrostis tenuis ; Copper tolerance ; Selection ; gene flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The copper tolerance of both adult plants and their seedlings, ofAgrostis tenuis from sites within and outside, but neighbouring the Parys Mountain mine (North Wales) were studied. Intensive sampling was carried out along a line starting from the mine boundaries to a distance of five miles away in the direction of the prevailing wind, and of two miles in an upwind direction. The test have shown that mine populations are very tolerant. In outside populations on soils with reduced of very low copper content the mean tolerance level of the seedlings is considerably higher than that of corresponding adult plants, while both show a gradual decrease in tolerance with distance from the mine. The gene flow moves in the direction of the prevailing wind transfering tolerant characters from the mine to the normal populations. The selective pressures on the toxic soil of the mine are quite strong and permit ± tolerant plants only, while on normal soils these pressures are not so severe, so that populations may be rather heterogenous regarding their tolerance towards copper.
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  • 10
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    Plant systematics and evolution 134 (1980), S. 127-131 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Labiatae =Lamiaceae ; Eremostachys codonocalyx ; E. stenocalycina ; E. salangensis ; E. freitagii ; E. andersii ; new species ; Flora of Afghanistan and Iran
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Five new species are described:Eremostachys codonocalyx from NE. Iran (related toE. subspicata),E. stenocalycina from NE. Afghanistan (related toE. alberti andE. hissarica),E. salangensis from NE. Afghanistan (close toE. bamianica),E. freitagii from E. Afghanistan (similar but not closely related toE. vulnerans), andE. andersii from E. Afghanistan (similar but not closely related toE. vulnerans), andE. andersii from NE. Afghanistan of isolated systematic position.
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  • 11
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    Plant systematics and evolution 134 (1980), S. 173-182 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Poaceae ; Agrostis tenuis ; Tolerance to toxic heavy metals ; Cu ; Zn ; and combinations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The toxicity of various Cu and Zn concentrations, as well as their mutual influence upon tolerant and non-tolerant clones ofAgrostis tenuis originating from soils of different metal content has been studied. Specific resistance has been clearly established. Co-existence of toxic metals causes an increase in toxicity. Uptake of metals (Cu and Zn) obviously occurs rather independently, and the toxic activity of the one is not affected competitively by the presence of the other. Above normal concentrations of Cu and Zn negatively affect cell division and growth in roots of non-tolerant genotypes. There is less ability to store metals than in tolerant genotypes.
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  • 12
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    Plant systematics and evolution 136 (1980), S. 267-273 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Daucus andPetroselinum (Apiaceae) ; Datura (Solanaceae) ; DNA ; reassociation kinetics ; DNA hybridization between varieties of the same species ; and genera of the same and of different families
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Reassociation kinetics ofDaucus carota andPetroselinum crispum (Apiaceae), andDatura innoxia (Solanaceae) are presented. Hybridization of3H-labelled DNA of two carrot cultivars indicate strong qualitative homologies of DNA sequences; nevertheless, certain quantitative differences in some Cotregions seem to exist. However, homologous sequences ofDaucus DNA with DNA ofDatura, and, suprisingly, even with DNA ofPetroselinum are very restricted: between 8% in the repeated regions and ca. 7–9% in the unique regions.
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  • 13
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    Chromatographia 13 (1980), S. 686-692 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Micropacked columns in GC ; Microparticles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Porous silica microparticles designed for modern liquid chromatography have proven effective in gas chromatography. Columns of 35–50 cm gave plate heights as low as 3.3 particle diameters and speeds of 2400 theoretical plates per second or 500 effective theoretical plates per second. Inlet pressures up to 70 atmospheres were required using hydrogen as carrier gas. The particles as received were too retentive for fast chromatography and gave asymmetric peaks. A coating of fluorosilicone oil overcame both problems. Other coatings were less effective. Bonded phases proved less satisfactory on both counts and also gave substantially less efficient columns and greater flow resistance. Column efficiency and flow resistance were sharply dependent on physical properties of the particles. The most efficient packing was clearly spherical particles of 5–10 μm diameter with narrow size distribution, pore diamters about 50 nm, BET surface areas of 25–50 m2/g and surfaces modified with trifluoropropyl silicone. A six-component hydrocarbon sample was separated in 33 s with a resolution of 4 for the most difficult pair and in 2.6 s with a minimal resolution. Performance was limited by end effects and by available pressure so that much better performance can be expected from longer columns and higher pressures.
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  • 14
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    Chromatographia 13 (1980), S. 752-754 
    ISSN: 1612-1112
    Keywords: Xylenol isomers ; Gas chromatography ; Polyols and polyethers as stationary phase ; Hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Xylenol isomers can be resolved on most polyols (sugars or sugar alcohols) and polyethers (polyethylene glycol or polypropylene glycol) with hydrogen-bonding interaction. They are separated on vinical polyols which have more hydroxy hydrogen than tetrol, and even on vicinal triol when its hydroxy hydrogen is acidic (stronger proton donor). The stronger is the hydrogen bonding interaction between xylenols and the liquid phase, the better is the separation of 2,4- and 2,5-xylenol, and the poorer the separation of 2,4-and 2,3-xylenol.
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  • 15
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    Chromatographia 13 (1980), S. 651-660 
    ISSN: 1612-1112
    Keywords: Capillary columns, glass ; Gas chromatography ; Column preparation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Glass capillary column chromatography is the most rapidly growing part of gas chromatography. There are many complex new analytical tasks and they require special capillary columns. Fortunately there is a wide range of column preparation methods available, and they make the preparation of glass capillary columns a more varied job than that of packed columns. In this paper these methods are reviewed and suggestions are given for making task-oriented columns.
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  • 16
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    Chromatographia 13 (1980), S. 73-84 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Gas hold-up time ; Dead time
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The two approaches used for the calculation of the gas hold-up time and thus, the adjusted retention time are outlined, first for the restricted case when the carbon numbers of the three homologues used for the calculation are evenly spaced (c3−c2=c2−c1) and then, for the general case when (c3−c2) differs from (c2−c1). The basic difference in the philosophy of the two approaches is shown.
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  • 17
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Column characterization ; Oxidation ; Stationary phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The on-column oxidation of hydrocarbons commonly used as stationary phases in column characterization is investigated. In each case significant shifts of retention are observed, which may be negative or positive depending upon the polarity of the test solutes and the adsorptivity of the support material. In order to reduce the consequent uncertainties in the Rohrschneider [1] and McReynolds [2] polarity values, a new method of column characterization is proposed. The applicability of the new method is illustrated by a consideration of a range of silicone liquid phases.
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  • 18
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    Chromatographia 13 (1980), S. 207-208 
    ISSN: 1612-1112
    Keywords: Trace determination ; Hydrogen chloride ; Ethylene oxide ; Gas chromatography ; Chlorinated solvents
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A method is described for the determination of small quantities of hydrochloric acid in two chlorinated organic solvents (CHCl3 and CCl4). An excess of gaseous ethylene oxide is added to a liquid sample; the 2-chloroethanol formed is then analyzed by gas chromatography. The procedure is simpler and more sensitive in comparison with other conventional methods. It can be modified for other organic solvents.
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  • 19
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    Chromatographia 13 (1980), S. 567-571 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Helium detector
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Four main factors which determine the shape and the polarity of the helium detector signal are discussed. All possible responses of this detector, both in elution and in vacancy chromatography, are presented and special attention is drawn to the intermediate region. The idea of ionization vacancy is introduced for the specific case of two components which are unresolved by the column and to which the detector responds with different sensitivity.
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  • 20
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    Chromatographia 13 (1980), S. 574-575 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Xylenol isomers ; Sugar derivatives as liquid phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Adenosine, guanosine and inosine used as liquid phases in gas chromatography permits the separation of all six xylenol isomers.
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  • 21
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    Chromatographia 13 (1980), S. 61-67 
    ISSN: 1612-1112
    Keywords: Optimization ; Carrier gas velocity ; Gas chromatography ; Influence of temperature on optimum velocity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Zusammenfassung Die Wahl der mittleren, linearen Trägergasgeschwindigkeit bei der Analyse von Mehrkomponentengemischen unter isothermen und temperaturprogrammierten Bedingungen wird diskutiert. Es wird gezeigt, daß stets eine Trägergasgeschwindigkeit gewählt werden sollte, die mindestens gleich, besser jedoch höher ist, als die optimale Gasgeschwindigkeit für den ersten Peak, gemessen bei der Starttemperatur (Temperaturprogramm) oder bei der eingestellten Ofentemperatur (isotherme Fahrweise).
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  • 22
    ISSN: 1612-1112
    Keywords: Configuration ; Chiral phases ; Gas chromatography ; Isovaline
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The D-(resp. R) configuration of isovaline (=2-ethylalanine) was proved for the peptide antibiotics antiamoebin, Tü 165 (CBS 382.62), stilbellin, samarosporin (=emerimicin IV), suzukacillin B (A), trichotoxin A-40 and A-50. This contradicts the previously reported L-configuration for isovaline in antiamoebin and emerimicin IV. The configuration was determined by GC of the N-trifluoroacetyl-isovaline n-propyl ester on glass capillary columns coated with the chiral stationary phase N-propionyl-L-valine tert.-butylamide polysiloxane (Chirasil Val). The D-configuration of the isovaline from trichotoxin A-40 was also established independently using GC of N-pentafluoro-propionyl-isovaline (+)-3-methyl-2-butyl esters on glass capillary columns coated with OV 17.
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