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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 359-363 
    ISSN: 0392-6737
    Schlagwort(e): X- and γ-rays instruments and techniques ; γ-rays ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary In the present work we report an investigation on cultures of the human osteosarcoma cell line «MG-63» and the human osteoblastic cell line «HOBIT». We have examined the combined effects of hematin and 14.4keV gamma-radiation from a Mössbauer source. Preliminary results seem to confirm the trend already observed for the bone marrow system. Different degrees of growth inhibition were observed when hematin alone and hematin plus gamma-rays were administered to the cultures. It was previously found that hematin has no toxic effects on normal cells up to a concentration of 10−4 M, but the same concentration produces various degrees of inhibition on cultures of tumor cells. While no significant effect could be attributed to irradiation alone, hematin plus irradiations show a larger inhibition than that expected for pure additive effects.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 381-384 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Phonons and vibrations in crystal lattices ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary The phonon energy spectra of a polycrystalline α-Fe foil were observed at 150 K and 300 K by using the nuclear resonant scattering of synchrotron radiation. In each spectrum, inelastic scattering was observed at both sides of the elastic peak. It was found that the ratio of the elastic-scattering component and the asymmetry of the intensity of the side bands observed at 150 K are larger than those observed at 300 K, respectively. The observed temperature-dependent spectra are in good agreement with the spectra calculated from the phonon energy distribution function. One of the advantageous features of this method is that the excitation of only a specific element is possible. Our results show that this method is applicable to the study of lattice dynamics and opens a new field of the nuclear resonant scattering spectroscopy.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 163-180 
    ISSN: 0392-6737
    Schlagwort(e): Fine particle systems ; PACS 76.80 ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Mössbauer spectroscopy is well known to be a very sensitive technique for studying small magnetic particles: small variations in the dynamic properties often manifest themselves as rather large changes in the spectra. However, anay detailed investigation is limited by the complexity of the phenomena and also by the line shape problem. As a result, variations in Mössbauer features between samples can always be interpreted in several ways. Utilization of other techniques to support the conclusions in indispensable. This will be emphasized in the case of γ-Fe2O3 nanoparticles, the dynamic properties of which have been studied over a very wide time range using measurements of the zero-field-cooled magnetization, thermoremanent magnetization, and a.c. susceptibility at various frequencies, in addition to Mössbauer spectroscopy. After a survey of the basic laws of superparamagnetic relaxation and the effects of interparticle interactions, this paper will show how the approximations usually made for interpreting Mössbauer data can lead to misinterpretation of the phenomena.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 227-230 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer spectra ; Mössbauer effect ; other γ-ray spectroscopy ; Crystalline state (including molecular motions in solids) ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary C60 (Buckminsterfullerene) is isolated from organic solvents above 260 K as an f.c.c. solid with complete orientational disorder. The rotational dynamics are diffuse and isotropic, with a short (12 ps) correlation time at 300 K. Below 260 K, the solid forms in a simple cubic lattice withPa3 symmetry. The librational motion occurs by activated jumps with a correlation time of about 60 ns at 200 K. To gain further insight into the dynamics of C60, the compound C60Fe(CO)4 (I) (generously made available to us by A. Stephens and M. Green of Oxford University) has been studied by57Fe Mössbauer spectroscopy. As expected, the resonance at 90 K consists of a doublet with an isomer shift (relative to metallic iron) of 0.034(1) mm s−1 and a quadrupole splitting of 1.607(5) mm s−1. There is no significant temperature-dependent, intensity asymmetry of the doublet. The temperature dependence of the effect magnitude is well fit by a linear regression over the range 85〈T〈210 K. To elucidate the relationship of these results to the effect of the C60 moiety in I, further lattice dynamical Mössbauer studies have been carried out on (maleic anhydride) Fe(CO)4 (II), one of the few isolatable tetracarbonyl complexes of iron. For (II), the quadrupole splitting is 1.371(5) mm s−1 at 90 K, and the temperature, dependence of the isomer shift is smaller than it is for (I), while the temperature dependence of the recoil-free fraction is significantly larger in (I) than in (II).
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 237-241 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Electrochemical devices ; Crystal symmetry: models, space groups and crystalline systems and classes ; Electron microscopy and other methods ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary We present here a study carried out on In16Sn4S32 and In16Fe8S32 spinels. Electronic and local environment changes of Sn and Fe are discussed from recorded Mössbauer parameters. In the case of the tin thiospinel, a reduction process from SnIV to SnII is obvious till an amount of 8 inserted Li. For the iron thiospinel a migration of iron atoms from the octahedral to the tetrahedral sites is observed. In the region of higher lithium amounts (10– Li), in both spinels a further environment appears indicating an increase of covalency.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 1369-1377 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Proceeding from the drastic discrepancy between experimental data and theory, we show (contrary to other authors) that the relations between the Einstein's coefficients are true for transitions from any of the excited levels and theground state of the quantum system only. The relations connecting those coefficients are derived for transitions betweenany two states; the corresponding cross-sections are calculated and it is shown (contrary to other authors) that the stimulated emission cross-section may be large enough for the creation of gamma lasers. The new relation for Einstein's coefficients (and the corresponding cross-sections) are fundamentally different from those known so far (74 years after Einstein). The results are compared with experiment and the coincidence is very good. These investigations can lead to progress in the study of physical processes in star atmospheres.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 1425-1428 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Two double-layered perowskitic compounds have been investigated by XRD analysis and Mössbauer spectroscopy. The experimental data allow the conclusion that magnetization is almost parallel to the stacking planes of these layered structures.
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  • 8
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Sediment cores with different sub-bottom depths (I: 45 cm and II: 700 cm) from the Peru Basin have been investigated. From the depth profile of the relative amount of Fe(II) a redox zone is obtained which correlates with the organic carbon flux into the sediment (core I). Mössbauer parameters suggest that the iron in the sediments is mainly contained in clay minerals and to varying extent also in goethite.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 385-388 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other ψ-ray spectroscopy ; Strong field excitation of optical transitions in quantum systems multiphonon processes ; dynamic Stark shift ; Effects of internal magnetic fields ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary We have studied the time dependence of Mössbauer absorption in a magnetically soft sample of Fe18Ni82 permalloy under the influence of a radio-frequency (r.f.) magnetic field. Absorption was measured as a function of the r.f. field phase at specific gamma-ray energies. We have shown that measuring the time dependence of absorption makes it possible to differentiate between purely magnetic and magnetoacoustic modulation mechanisms even in cases where clear distinction is not visible in conventional energy domain spectra.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 145-161 
    ISSN: 0392-6737
    Schlagwort(e): Metal-insulator transitions ; High-pressure and shock-wave effects in solids ; Mössbauer effect ; other γ-ray spectroscopy ; Transition-metal compounds ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Most previous studies of magnetism in various compounds under extreme conditions have been conducted over a wide pressure range at room temperature or over a wide range of cryogenic temperatures at pressures below 20 GPa (200 kbar). We present some of the most recent studies of magnetism over an extended range of temperatures and pressures far beyond 20 GPa,i.e. in regions of pressure-temperature (P-T) space where magnetism has been largely unexplored. Recent techniques have permitted investigations of magnetism in selected 3d transition metal compounds in regions ofP-T where physical properties may be drastically modified; related effects have often been seen in selected doping studies at ambient pressures. We present57Fe and129I Mössbauer isotope studies covering the range 300–4 K to sub-megabar pressures in compounds such as Sr2FeO4, LaFeO3 and FeI2, representative of a broad class of 3d transition metal compounds. At ambient pressure the electronic structure of the transition metal atom in these antiferromagnetic insulators extends from 3d 4 to 3d 6 and has a distinct influence on the pressure evolution of their magnetic properties. Mössbauer studies of these compounds are considered in conjunction with available structural and electrical transport data at pressure.
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 299-304 
    ISSN: 0392-6737
    Schlagwort(e): Layer structures: multilayers, and superlattices (growth structure, and nonelectronic properties) ; Magnetism in interface structures (including layer and superlattice structures) ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary The synthesis of a new BCT Fe phase was performed in Fe/Ir(100) superlattices grown by MBE. Magnetic properties of57Fe/Ir(100) superlattices with 4 ml Fe and variable Ir thickness (2–30 Å) are investigated by57Fe conversion electron Mössbauer spectroscopy in the 4.2–300 K temperature range. Two spectral components are evidence, related, respectively, to Fe atoms involved in the central part of the iron layers and at the interface between iron and iridium layers. The appearance of a high magnetic hyperfine splitting in the iron BCT structure above a volume threshold of 12 Å3 is evidenced. Marked differences are observed between the mean magnetic properties and the local ones suggesting strong relaxation effects.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 181-198 
    ISSN: 0392-6737
    Schlagwort(e): Impurities: concentration, distribution, and gradients ; Doping and impurity implantation in germanium and silicon ; Interaction between different crystal defects ; gettering effect ; Calculations of total electronic binding energy ; Elemental semiconductors ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Experimental results are presented on the study of Sb-H complexes in crystalline silicon, employing119Sb→119Sn source Mössbauer spectroscopy and a low-energy H implantation technique. In addition to a visible component, we observe a large decrease of the Mössbauer intensity associated with the trapping of hydrogen, even at low temperatures. This is interpreted as the formation of a component with a negligible recoilless fraction. The different Mössbauer components were studied as a function of H dose, H-implantation temperature and annealing temperature. The data show that the visible component is associated with the well-known SbH complex, whereas the invisible component is associated with the formation of SbH n (n≥2) complexes. We show that these complexes are in thermal equilibrium with a larger hydrogen reservoir (H 2 * ), which governs their thermal stability. No Sb-H complexes are observed inp-type Si after H-implantation, in agreement with the current belief that hydrogen has a deep donor level in the gap. The microscopic structure of the various Sb-H and Sn-H complexes was studied with first-principles calculations using the pseudopotentialdensity-functional approach. The structure of the Sb-H complex is found to be similar to the P-H complex, with the H in an antibonding site of a Si atom neighbouring the Sb impurity. For SbH2 three configurations are found with energies differing by less than ≈ 0.1 eV. We find that the reaction SbH+H≠SbH2 is exothermic. We argue that the SbH2 complexes are shallow donors, irrespective of the structure. Therefore, the formation of SbH2 may depassivate the sample.
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 991-994 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; Neutron determination of structures ; X-ray determination of structures
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Samples of FePO4 and (Al0.67Fe0.33)PO4 have been investigated by Mössbauer spectroscopy. The data obtained on quadruple splittings are in agreement with neutron scattering and XRD data on (Al, Fe)O4 tetrahedra structures.
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 157-163 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Two approximate formulae to calculate the eigenvalues of pure quadrupole interaction in Mössbauer effect studies have been proposed and the eigenvalue coefficients in the formulae have been given for various excited states and ground states of the nucleus with different spin. All the eigenvalues of pure quadrupole interaction between both excited state and ground state of nucleus with spinI=3/2÷9/2 and the electric-field gradient with different asymmetry parameter (η=0÷1.0) have been calculated by these formulae. The results show that the accuracies in all the calculations are more satisfactory or same in comparison with those obtained by the formula of Shenoy and Dunlap, especially when the asymmetry parameter of electric-field gradient is larger than 0.8 for the nucleus with spinI=5/2.
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 329-336 
    ISSN: 0392-6737
    Schlagwort(e): Kinetics of defect formation and annealing ; Alloys ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Point defects in annealed B2-phase FeAl samples in the range 47–53 at.% Fe were studied using57Fe Mössbauer spectroscopy. Spectra were analyzed using local environment models according to which point defects in atomic shells close to probe atoms induce shifts in the nuclear monopole interaction. For well-annealed samples, better results were obtained assuming only the presence of FeAl antisite and VFe vacancy defects, and not of AlFe antisite defects. Monopole interactions of57Fe probes on the Fe and Al sublattices having no defects in the first two shells were about +0.27 and −0.03 mm s−1, respectively, with respect to Fe in alpha-Fe metal. The shifts induced by FeAl and VFe defects in the first shells of Fe probes on the Fe and Al sublattices were −0.15 and −0.24 mm s−1, respectively, and, in the second shells, +0.06 and +0.011 mm s−1. In addition to structural defects needed to accommodate deviations from stoichiometry, annealed samples were found to contain several percents of FeAl and VFe defects due to lattice disorder, with greater disorder in Fe-deficient alloys.
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 375-379 
    ISSN: 0392-6737
    Schlagwort(e): Phonons and vibrations in crystal lattices ; Nuclear resonance fluorescence ; Synchrotrons ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary The Nuclear-Resonance Beamline at ESRF is dedicated to the excitation of nuclear levels by synchrotron radiation. The source of radiation and optical elements are optimized to provide an intense, highly monochromatic, collimated and stable X-ray beam of small cross-section at the Mössbauer transition energies between 6 keV and 30 keV. The set-up of the beamline allows to perform studies in diffraction, small-angle scattering, forward scattering and incoherent scattering. Equipment is available to maintain the sample at variable temperature and magnetic field. Fast detectors and timing electronics serve to separate the delayed nuclear scattering from the «prompt» electronic scattering and to measure the time spectra of nuclear radiation with sub-nanosecond resolution. The general layout and the parameters of the beamline are reported. Typical domains of applications are discussed and illustrated by first experimental results.
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 1463-1468 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; X-ray diffraction and scattering
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary A systematic investigation on the properties of synthetic iron-substituted leucite-like silicates has been performed by Mössbauer spectroscopy. The obtained data on the isomeric shifts indicate that along the chains of tetrahedra present in the anionic framework of these silicates a readjustement of the bond lengths takes place, due to the large ionic radius of iron which exceeds those of silicon and aluminum.
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 213-220 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; X- and γ-ray instruments and techniques ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary The use of synchrotron radiation to excite low-lying nuclear resonances is a rapidly developing field showing great promise for hyperfine spectroscopy, phonon spectroscopy and kinetic studies, crystallography, and fundamental physics experiments. Recent technical advances in synchrotron sources, optics, and fast detectors have drastically increased signal rates and expanded the range of samples that can be studied. A typical experiment today uses a high-brightness synchrotron source having X-ray pulses well-separated in time, a meV-bandpass monochromator using perfect crystals of silicon or germanium, a sample containing resonant nuclei, and an avalanche photodiode timing detector. Both coherent and incoherent scattering can be observed; the coherent scattering is used for hyperfine spectroscopy and studies of diffraction interference phenomena, and the incoherent-scattering signal promises to be very useful for phonon spectroscopy and other studies of excitations in condensed systems. At this point seven nuclear isotopes have been used to resonantly scatter synchrotron radiation, but the number is rapidly increasing.
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 253-257 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Fe and its alloys ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Magnetic properties of Fe nitrides have been re-examined by57Fe Mössbauer spectroscopy. Hyperfine magnetic fields for α″-Fe16N2 are 30, 31 and 39T at 298K, but the averaged hyperfine field is 33T and nearly equal to the value of pure α-Fe. σ-Fe2 N is an antiferromagnet below 9K having a small magnetic moment less than 0.1 μB, although γ′-Fe4N and ε-Fe3–2N are ferromagnets. ZnS-type FeN is non-magnetic at 4.2K. Mössbauer spectra obtained from NaCl-type FeN are complex and some Fe atoms in this nitride show a surprisingly large hyperfine magnetic field of 49T.
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 269-273 
    ISSN: 0392-6737
    Schlagwort(e): Spin density waves ; Antiferromagnetics ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary A new iterative procedure for a numerical analysis of Mössbauer spectra in terms of higher-order harmonics is used to study spin-and charge-density waves in single-crystal and polycrystalline samples of chromium and chromium-vanadium alloys.
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 281-285 
    ISSN: 0392-6737
    Schlagwort(e): Fine particle systems ; Mössbauer effect ; other γ-ray spectroscopy ; Structural acoustics and vibration ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Iron particles, encapsulated by graphite layers, were produced by means of the Kratschmer arc discharge method in an iron pentacarbonyl atmosphere. The Mössbauer effect is dominated by the vibration of the particles as a whole. Superparamegnetism is dominant for iron oxide particles. No endohedral iron fullerenes were observed, contrary to a previous report.
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 275-280 
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Magnetically ordered materials: other intrinsic properties ; Magnetic phase boundaries (including magnetic transitions, metamagnetism etc) ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary Dilute57Fe Mössbauer-spectroscopy studies of RMn2X2 (X=Si and/or Ge, R=La, Ce, Pr, Nd, Sm, Eu and Gd) at 4.2 to 650 K yield the following results: Fe in RMn2X2 does not carry a magnetic moment. It reveals the magnetic order in the Mn and R sublattices through transferred hyperfine fields (∼100 kOe). The compounds LaMn2Si2, LaMn2Ge2, CeMn2Ge2, PrMn2Ge2, NdMn2Ge2 and SmMn2Ge2, known to be ferromagnets withT c=300–350 K, are antiferromagnetically ordered above their correspondingT c. TherT N values extend from 385 K (SmMn2Ge2) to 470 K (LaMn2Si2). At the ferromagnetic-antiferromagnetic phase transition, a sharp reorientation of the Mn magnetic moments relative to the crystalline axes occurs. In RMn2Si2−x Ge x with intermediatex values, the Ge is much more dominant in determining the magnetic properties of the Mn sublattice. While PrMn2Si2 is an antiferromagnet (T N=365 K) and PrMn2Ge2 is a ferromagnetantiferromagnet (T c=328 K,T N=415 K), we find that in PrMn2SiGe, the magnetic behaviour is similar to that in pure PrMn2Ge2,T c=305 K andT N=395 K.
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 319-323 
    ISSN: 0392-6737
    Schlagwort(e): Magnetism in interface structures (including layer and superlattice structures) ; Magnetic properties of monolayers and overlayers ; Interfacial magnetic properties ; Mössbauer effect ; other γ-ray spectroscopy ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary A series of ultrathin Fe/Pt multilayers, prepared by magnetron sputtering, were studied by CEMS and transmission MS. The Fe-layer thickness varied from 3 to 12.5 Å and that of Pt from 5 Å to 39 Å. The 3 Å/9 Å Pt sample displays magnetic hyperfine structure at RT, while the 3 Fe/19 Pt sample is paramagnetic at RT, demonstrating the effect of interlayer interaction. Both samples display out-of-plane magnetic anisotropy with 39° angle with respect to the vertical for the former and nearly 0° angle for the latter. The analysis of the spectra of samples with thickness larger than one monolayer of Fe is done with components assigned to individual Fe monolayers. In all these cases a component appears with a hyperfine field larger by ∼ 10% at RT and 17% at L.He than the corresponding values of α-Fe. This component is attributed to the first monolayer below the Fe/Pt interface in accordance with similar results in the Fe/Pd system and with theoretical predictions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    ISSN: 0392-6737
    Schlagwort(e): Mössbauer effect ; other γ-ray spectroscopy ; Other topics in biophysics and medical physics ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary This paper describes a preliminary investigation of the mechanisms of Fe(II) oxidation and storage of Fe(III) in the bacterioferritin ofEscherichia coli (EcBFR). Using Mössbauer spectroscopy to examine the initial oxidation of iron by EcBFR we have confirmed that this ferritin exhibits «ferroxidase» activity and have shown that dimeric and monomeric iron species are produced as intermediates. We compare the characteristics of ferroxidase activity in EcBFR with those of human H-chain ferritin (HuHF) and discuss the different Mössbauer parameters of their dimeric iron with reference to the structures of their di-metal sites. In addition, we present preliminary findings suggesting that after an initial «burst», the rate of oxidation is greatly reduced, possibly due to blockage of the ferroxidase centre by bound iron. A new component, not found in HuHF and probably representing a small cluster of Fe(III) atoms, is reported.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 25
    ISSN: 0392-6737
    Schlagwort(e): Molecular dynamics and conformational changes ; Mössbauer effect ; other γ-ray spectroscopy ; Brillouin and Rayleigh scattering ; other light scattering ; Conference proceedings
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary The classical model system poly-L-glutamic acid (poly-Glu), was investigated in a disordered coil state (atpH=7.0) and in helix state (atpH=2.0) by the RSMR technique. By considering that the coil state of poly-Glu models unfolded (random coil) state and α-helix state models the fluctuating secondary structure (during consequent folding of protein), a comparative analysis of the dynamical properties of poly-Glu in different states with the dynamical properties of different proteins in the native state (α-helical myoglobin and HSA, partially β-sheet lysozyme) and in intermediate (molten globule) state (α-lactalbumin) was performed. This comparison brings some unpredicted results: native α-helical proteins behave close to random coil, native partially β-sheet proteins behave close to fluctuating secondary structure (α-helix) and the dynamic behaviour of molten-globule state (partially β-sheet α-lactalbumin) is not different from the behaviour of lysozyme and much more rigid than that of native α-helical proteins.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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