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  • 1
    ISSN: 1089-7666
    Quelle: AIP Digital Archive
    Thema: Physik , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: PHF online publishes articles that emphasize understanding of the physics underlying modern technology. The subject coverage includes, but is not limited to, experimental or theoretical physics applied to all aspects of materials: for example, charge and mass transport, superconductivity magnetism; surfaces, interfaces, thin films, crystal lattice defects; electrical, optical, magnetic, and structural properties; processing; ion implantation. Materials covered include semiconductors, superconductors, metals and alloys, amorphous materials, and oxides.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Nuclear Physics, Section B 373 (1992), S. 3-34 
    ISSN: 0550-3213
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Nuclear Physics, Section B 386 (1992), S. 471-492 
    ISSN: 0550-3213
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Physics Letters B 289 (1992), S. 199-210 
    ISSN: 0370-2693
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Physics Letters B 274 (1992), S. 230-238 
    ISSN: 0370-2693
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Amsterdam : Elsevier
    Physics Letters B 317 (1993), S. 474-484 
    ISSN: 0370-2693
    Quelle: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 645-647 
    ISSN: 1557-1947
    Schlagwort(e): EuBaSrCu3O7−δ superconductor ; Ca doping ; orthorhombicity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract The effect of Ca doping in EuBaSrCu3O7−δ has been investigated by X-ray diffraction, ac susceptibility, and electrical resistivity measurements. X-Ray diffraction analyses of the samples showed that up to 30 at.% Ca can be substituted for Sr in EuBaSrCu3O7−δ, which has orthorhombic symmetry. The orthorhombicity decreases with increase inx, in EuBaSr1−xCax Cu3O7−δ, the material becoming tetragonal atx=0.2. Ac susceptibility and dc electrical resistivity measurements as function of temperature from 10 to 300 K showed that the superconducting transition temperatureT c decreases monotonically from 84 to 75K as the Ca concentrationx increases from 0.0 to 0.3 The decrease inT c can be attributed to the structural change taking place in EuBaSrCu3O7 as a consequence of replacement of Sr by Ca.
    Materialart: Digitale Medien
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  • 9
    ISSN: 1557-1947
    Schlagwort(e): Superconductivity ; research opportunities ; state of the art
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract This report surveys the considerable progress made over the last five years—such as the marketing of superconducting quantum interference devices (SQUIDs), cellular wireless filter systems, and high current leads—and assesses needs and opportunities in the areas of fundamental science, materials development, thin film and device applications, and wire and bulk applications. It examines the challenges facing high-temperature superconductivity: from the need to understand the mechanism of high-temperature superconductivity and the unusual “normal” state to the need for new instrumentation for material characterization. Advances in thin film and bulk materials are reviewed, and obstacles impeding the commercialization of HTS materials are examined.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 649-655 
    ISSN: 1557-1947
    Schlagwort(e): Single crystal of Bi2Sr2CaCu2O8 ; high-resolution electron microscopy ; low-temperature electron diffraction ; lattice anomaly
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract High-resolution electron microscopy of a Bi2Sr2CaCu2O8 (Bi2212) single crystal prepared by the floating zone method shows that the single crystal is of high quality; there is no intergrowth faulting in the layered structure along thec-axis. Low-temperature selected area diffraction and convergent beam electron diffraction (CBED) studies of this high-quality single crystal show that there is no detectable change for both the point group symmetry of the basic structure and the modulated structure from room temperature to about 15 K. However, a lattice anomaly around 215 K was suggested by measuring the temperature dependence of the ratio between the cross-point distances of the HOLZ lines in high-index CBED patterns. The presence of the lattice anomaly was further confirmed by low-temperature X-ray diffraction.
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 623-643 
    ISSN: 1557-1947
    Schlagwort(e): Superconductivity ; crystal field ; rare earth ; relaxation ; gap symmetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract Neutron spectroscopy is a powerful tool to determine unambiguously the crystal-field (CF) potential in rare-earth (R) based high-T c superconducting materials. This technique provides detailed information on the electronic ground state of the R ions which is important to understand the thermodynamic magnetic properties as well as the observed coexistence between superconductivity and long-range magnetic ordering of the R ion sublattice at low temperatures. Moreover, the decay of the antiferromagnetic state of the parent compound as well as the evolution of the superconducting state upon doping can be directly and quantitatively monitored. It is found that the observed CF spectra separate into different local components whose spectral weights distinctly depend on the doping level, i.e., there is clear experimental evidence for cluster formation. The onset of superconductivity can be shown to result from percolation which means that the superconductivity is an inhomogeneous materials property. Since the linewidths of CF transitions directly probe the static electronic susceptibility, we discuss temperature-dependent experiments of the relaxation rate of CF excitations in both optimally doped and underdoped regimes. It is shown that there is clear evidence for the opening of an electronic gap in the normal state of underdoped superconductors. Furthermore, the relaxation behavior appears to be extremely dependent upon the energy at which the static susceptibility is being probed. The main observed features can be reproduced by considering a strongly anisotropic gap function.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 663-668 
    ISSN: 1557-1947
    Schlagwort(e): Thermal diffusivity ; acoustic plasmons ; cobalt substitution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract The thermal diffusivity κ(T) of the cobalt-substituted sintered YBCO system, YBa2Cu3−x Co x O7∮δ (x=0.0, 0.1), has been measured to, investigate, effects of atomic substitution and charge carrier concentration on the thermal diffusion processes. The thermal diffusivity was measured in the temperature range 35–300 K, using the transient-plane-source technique. The results show that, belowT c , the κ(T) values of the doped (x=0.1), samples are lower than the corresponding values for the undoped (x=0.0) samples. This may be due to the difference in the free-charge carrier concentrations of the two samples. A decoupling between the conducting Cu−O planes as a result, of Co-doping in the chain sites may contribute to additional decrease in the thermal diffusivity of the doped sample. An attempt was made to explain the rise in the thermal diffusivity belowT c by adopting a recent theoretical model based on the existence of weakly damped collective electron excitations of Bose type, with acoustic dispersion relation, (acoustic plasmons) inside the superconducting gap.
    Materialart: Digitale Medien
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  • 13
    ISSN: 1557-1947
    Schlagwort(e): High-T c superconductors ; order parameter ; Josephson junctions ; Josephson critical current ; pair symmetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract An intrinsic gap depression at the superconductor-insulator interface due to the very short value of the coherence length in high-T c superconductors [HTS] is considered in the framework of a mixed (s+id)-wave pair symmetry for the order parameter ranging from pures to pured-wave. This gap depression acts as the main physical agent causing the relevant reduction ofI c (T)R n (T) values with respect to BCS expectations in HTS SIS Josephson junctions. Good agreement with various experimental data is obtained with both pures-wave and pured-wave symmetries of the order parameter, but with amounts of gap depression depending on the pair symmetry adopted. Regardless of the apir symmetry considered, these results prove the importance of the surface order-parameter depression in the correct interpretation of theI c (T)R n (T) data in HTS SIS junctions. In the case of a planar YBCO-based junction the use of the de Gennes condition allowed us to tentatively obtain an upper limit for the amount ofd-wave present in the gap of YBCO.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 669-672 
    ISSN: 1557-1947
    Schlagwort(e): Equation of state ; bulk modulus ; cohesive energy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract In the present paper the expression of cohesive energy and the bulk modulus as a function of volume are formulated for high-T c copper oxide superconductors. The model employed consists of long-range electrostatic Coulomb interaction and short-range overlap repulsion. The short-range overlap potential is considered in the Born-Landé inverse power form. The model, parameters of the Born-Landé model are calculated from the equilibrium condition and data of bulk modulus at room temperature. The computed values of pressure derivatives of bulk modulus atP=0 and the values of bulk modulus are found to be in very close agreement with experimental values for high-T c copper oxide and their nonsuperconducting parent compounds. It is also found that the quantity ΔU/U(V o) of these compounds increases with increasing hydrostistic pressure.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Journal of superconductivity and novel magnetism 10 (1997), S. 673-675 
    ISSN: 1557-1947
    Schlagwort(e): Cuprates ; van Hove singularity ; pseudo-gap
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Abstract Several experimental features in the normal state of cuprates have been interpreted using a “pseudogap”. We show that these results may be explained by the band structure of the CuO2 planes in the metallic region, which exhibits, saddle points (van Hove singularities).
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 17-31 
    ISSN: 1436-3259
    Schlagwort(e): Bivariate density ; meta-Gaussian density ; normal quantile transform ; likelihood ratio dependence ; correlation coefficient
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Convenient bivariate densities found in the literature are often unsuitable for modeling hydrologic variates. They either constrain the range of association between variates, or fix the form of the marginal distributions. The bivariate meta-Gaussian density is constructed by embedding the normal quantile transform of each variate into the Gaussian law. The density can represent a full range of association between variates and admits arbitrarily specified marginal distributions. Modeling and estimation can be decomposed into i) independent analyses of the marginal distributions, and ii) investigation of the dependence structure. Both statistical and judgmental estimation procedures are possible. Some comparisons to recent applications of bivariate densities in the hydrologic literature motivate and illustrate the model.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 33-50 
    ISSN: 1436-3259
    Schlagwort(e): Unit hydrograph ; uncertainty analysis ; linearly constrained Monte-Carlo simulation ; reliability analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Unit hydrographs (UHs), along with design rainfalls, are frequently used to determine the discharge hydrograph for design and evaluation of hydraulic structures. Due to the presence of various uncertainties in its derivation, the resulting UH is inevitably subject to uncertainty. Consequently, the performance of hydraulic structures under the design storm condition is uncertain. This paper integrates the linearly constrained Monte-Carlo simulation with the UH theory and routing techniques to evaluate the reliability of hydraulic structures. The linear constraint is considered because the water volume of each generated design direct runoff hydrograph should be equal to that of the design effective rainfall hyetograph or the water volume of each generated UH must be equal to one inch (or cm) over the watershed. For illustration, the proposed methodology is applied to evaluate the overtopping risk of a hypothetical flood detention reservoir downstream of Tong-Tou watershed in Taiwan.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 1-16 
    ISSN: 1436-3259
    Schlagwort(e): Nash cascade reservoir model ; rainfall-runoff ; EM algorithm ; filtering ; maximum likelihood estimation ; martingale estimating function
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Abstract: Linear continuous time stochastic Nash cascade conceptual models for runoff are developed. The runoff is modeled as a simple system of linear stochastic differential equations driven by white Gaussian and marked point process noises. In the case of d reservoirs, the outputs of these reservoirs form a d dimensional vector Markov process, of which only the dth coordinate process is observed, usually at a discrete sample of time points. The dth coordinate process is not Markovian. Thus runoff is a partially observed Markov process if it is modeled using the stochastic Nash cascade model. We consider how to estimate the parameters in such models. In principle, maximum likelihood estimation for the complete process parameters can be carried out directly or through some form of the EM (estimation and maximization) algorithm or variation thereof, applied to the observed process data. In this research we consider a direct approximate likelihood approach and a filtering approach to an algorithm of EM type, as developed in Thompson and Kaseke (1994). These two methods are applied to some real life runoff data from a catchment in Wales, England. We also consider a special case of the martingale estimating function approach on the runoff model in the presence of rainfall. Finally, some simulations of the runoff process are given based on the estimated parameters.
    Materialart: Digitale Medien
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 173-192 
    ISSN: 1436-3259
    Schlagwort(e): Uncertainty analysis ; unit hydrograph ; regression analysis ; probabilistic point estimation methods
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Hydrologic model parameters obtained from regional regression equations are subject to uncertainty. Consequently, hydrologic model outputs based on the stochastic parameters are random. This paper presents a systematic analysis of uncertainty associated with the two parameters, N and K, in Nash's IUH model from different regional regression equations. The uncertainty features associated with N and K are further incorporated to assess the uncertainty of the resulting IUH. Numerical results indicate that uncertainty of N and K from the regional regression equations are too significant to be ignored.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 145-171 
    ISSN: 1436-3259
    Schlagwort(e): Hydrologic regionalization ; unit hydrograph ; regression analysis ; multivariate regression ; seemingly unrelated regression ; validation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Hydrologic regionalization is a useful tool that allows for the transfer of hydrological information from gaged sites to ungaged sites. This study developed regional regression equations that relate the two parameters in Nash's IUH model to the basin characteristics for 42 major watersheds in Taiwan. In the process of developing the regional equations, different regression procedures including the conventional univariate regression, multivariate regression, and seemingly unrelated regression were used. Multivariate regression and seeming unrelated regression were applied because there exists a rather strong correlation between the Nash's IUH parameters. Furthermore, a validation study was conducted to examine the predictability of regional equations derived by different regression procedures. The study indicates that hydrologic regionalization involving several dependent variables should consider their correlations in the process of establishing the regional equations. The consideration of such correlation will enhance the predictability of resulting regional equations as compared with the ones from the conventional univariate regression procedure.
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 193-210 
    ISSN: 1436-3259
    Schlagwort(e): Turbulence ; sediment ; fluvial ; river ; bursting process ; statistics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Entrainment of sediment particles from channel beds into the channel flow is influenced by the characteristics of the flow turbulence which produces stochastic shear stress fluctuations at the bed. Recent studies of the structure of turbulent flow has recognized the importance of bursting processes as important mechanisms for the transfer of momentum into the laminar boundary layer. Of these processes, the sweep event has been recognized as the most important bursting event for entrainment of sediment particles as it imposes forces in the direction of the flow resulting in movement of particles by rolling, sliding and occasionally saltating. Similarly, the ejection event has been recognized as important for sediment transport since these events maintain the sediment particles in suspension. In this study, the characteristics of bursting processes and, in particular, the sweep event were investigated in a flume with a rough bed. The instantaneous velocity fluctuations of the flow were measured in two-dimensions using a small electromagnetic velocity meter and the turbulent shear stresses were determined from these velocity fluctuations. It was found that the shear stress applied to the sediment particles on the bed resulting from sweep events depends on the magnitude of the turbulent shear stress and its probability distribution. A statistical analysis of the experimental data was undertaken and it was found necessary to apply a Box-Cox transformation to transform the data into a normally distributed sample. This enabled determination of the mean shear stress, angle of action and standard error of estimate for sweep and ejection events. These instantaneous shear stresses were found to be greater than the mean flow shear stress and for the sweep event to be approximately 40 percent greater near the channel bed. Results from this analysis suggest that the critical shear stress determined from Shield's diagram is not sufficient to predict the initiation of motion due to its use of the temporal mean shear stress. It is suggested that initiation of particle motion, but not continuous motion, can occur earlier than suggested by Shield's diagram due to the higher shear stresses imposed on the particles by the stochastic shear stresses resulting from turbulence within the flow.
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 211-227 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The principle of maximum entropy (POME) was employed to derive a new method of parameter estimation for the 2-parameter generalized Pareto (GP2) distribution. Monte Carlo simulated data were used to evaluate this method and compare it with the methods of moments (MOM), probability weighted moments (PWM), and maximum likelihood estimation (MLE). The parameter estimates yielded by POME were comparable or better within certain ranges of sample size and coefficient of variation.
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 1-2 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 523-547 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Kernel density estimators are useful building blocks for empirical statistical modeling of precipitation and other hydroclimatic variables. Data driven estimates of the marginal probability density function of these variables (which may have discrete or continuous arguments) provide a useful basis for Monte Carlo resampling and are also useful for posing and testing hypotheses (e.g bimodality) as to the frequency distributions of the variable. In this paper, some issues related to the selection and design of univariate kernel density estimators are reviewed. Some strategies for bandwidth and kernel selection are discussed in an applied context and recommendations for parameter selection are offered. This paper complements the nonparametric wet/dry spell resampling methodology presented in Lall et al. (1996).
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 11 (1997), S. 459-482 
    ISSN: 1436-3259
    Schlagwort(e): Karhunen-Loéve expansion ; Empirical Orthogonal Functions ; stochastic simulation ; gaussian fields ; analytical covariance functions ; eigenfunctions ; kriging
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 5-25 
    ISSN: 1436-3259
    Schlagwort(e): Solute transport ; Heterogeneity ; Dispersion
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Macrodispersion is spreading of a substance induced by spatial variations in local advective velocity at field scales. Consider the case that the steady-state seepage velocity and the local dispersion coefficients in a heterogeneous formation may be modeled as periodic in all directions in an unbounded domain. The equations satisfied by the first two spatial moments of the concentration are derived for the case of a conservative non-reacting solute. It is shown that the moments can be calculated from the solution of well-defined deterministic boundary value problems. Then, it is described how the rate of increase of the first two moments can be calculated at large times using a Taylor-Aris analysis as generalized by Brenner. It is demonstrated that the second-order tensor of macrodispersion (or effective dispersion) can be computed through the solution of steady-state boundary-value problems followed by the determination of volume averages. The analysis is based solely on volume averaging and is not limited by the assumption that the fluctuations are small. The large-time results are valid when the system is in a form of equilibrium in which a tagged particle samples all locations in an appropriately defined “phase space” with equal probability.
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 89-101 
    ISSN: 1436-3259
    Schlagwort(e): Detention storage ; Pollution control ; Non-point pollutant runoff
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A simple expression is presented on the capability of storage-treatment systems to reduce non-point pollutant runoff load to natural waters. Their efficiency depends on the capacities of the facilities and probabilistic properties of runoff, such as interval, duration, volume, and concentration of runoff events. Assuming the compound Poisson process for runoff time series, the exact expressions of the ratio of treated load in terms of storage and treatment capacities are theoretically derived on the neighbourhoods of all boundaries of the domain on which the problem is defined. Then, an approximate expression over the whole domain is presented, of which the value and the first-order derivative coincide with those of the exact derived expressions near the boundaries. Accuracy is checked by Monte Carlo simulations.
    Materialart: Digitale Medien
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 55-68 
    ISSN: 1436-3259
    Schlagwort(e): Drought severity ; Drought duration ; Renewal-reward process
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract This research study focused on the hypothesis that extreme drought and high streamflow events come from different independent populations with different probability distributions which need to be studied separately, rather than considering the streamflow population as a whole. The inability of traditional streamflow generator models to consistently reproduce the frequency of occurrence of severe droughts observed in the historical record has been questioned by many researchers. Our study focused on the development of astochastic event generator model which would be capable of doing so. This was accomplished in a two-step process by first generating the drought event, and then deriving the streamflows which comprised that event. The model considered for this analysis was an alternating renewal-reward procedure that cycles between eventon andoff times, and is representative of drought or high streamflow event duration. The reward gained while the event ison oroff represents drought severity or high streamflow surplus. Geometric and gamma distributions were considered for drought duration and deficit respectively. Model validation was performed using calculated required capacities from the sequent peak algorithm.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 103-121 
    ISSN: 1436-3259
    Schlagwort(e): Probabilistic model ; Sensitivity ; Contaminant transport
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A reliability approach is used to develop a probabilistic model of two-dimensional non-reactive and reactive contaminant transport in porous media. The reliability approach provides two important quantitative results: an estimate of the probability that contaminant concentration is exceeded at some location and time, and measures of the sensitivity of the probabilistic outcome to likely changes in the uncertain variables. The method requires that each uncertain variable be assigned at least a mean and variance; in this work we also incorporate and investigate the influence of marginal probability distributions. Uncertain variables includex andy components of average groundwater flow velocity,x andy components of dispersivity, diffusion coefficient, distribution coefficient, porosity and bulk density. The objective is to examine the relative importance of each uncertain variable, the marginal distribution assigned to each variable, and possible correlation between the variables. Results utilizing a two-dimensional analytical solution indicate that the probabilistic outcome is generally very sensitive to likely changes in the uncertain flow velocity. Uncertainty associated with dispersivity and diffusion coefficient is often not a significant issue with respect to the probabilistic analysis; therefore, dispersivity and diffusion coefficient can often be treated for practical analysis as deterministic constants. The probabilistic outcome is sensitive to the uncertainty of the reaction terms for early times in the flow event. At later times, when source contaminants are released at constant rate throughout the study period, the probabilistic outcome may not be sensitive to changes in the reaction terms. These results, although limited at present by assumptions and conceptual restrictions inherent to the closed-form analytical solution, provide insight into the critical issues to consider in a probabilistic analysis of contaminant transport. Such information concerning the most important uncertain parameters can be used to guide field and laboratory investigations.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 191-207 
    ISSN: 1436-3259
    Schlagwort(e): Hydrodynamic dispersion ; Fokker-Planck equation ; backward equation ; boundary layer ; complex potential function ; fraction of contaminated particles that enter a well
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract In this paper we describe the transport of pollution in groundwater in the neighbourhood of a well in a uniform background flow. We compute the rate at which contaminated particles reach the well as a function of the place of the source of pollution. The motion of a particle in a dispersive flow is seen as a random walk process. The Fokker-Planck equation for the random motion of a particle is transformed using the complex potential for the advective flow field. The resulting equation is solved asymptotically after a stretching transformation. Finally, the analytical solution is compared with results from Monte Carlo simulations with the random walk model. The method can be extended to arbitrary flow fields. Then by a numerical coordinate transformation the analytical results can still be employed.
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 255-269 
    ISSN: 1436-3259
    Schlagwort(e): Emprical Orthogonal Functions ; interpolating runoff ; kriging
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The method of Empirical Orthogonal Functions (EOF method) is combined with an objective interpolation technique, kriging, to generate runoff series at ungauged locations. In a case study the results are compared to series interpolated by a combination of EOF analysis and regression using catchment characteristics as independent variables. The results are also compared to linear weighting of an existing runoff series, a commonly used method for spatial interpolation. The influence of altitude on the runoff is studied comparing kriging based on 2 and 3 coordinates. The study showed that the capacity of EOF analysis combined with kriging is as good as the traditionally used linear weighting. The results, when altitude is included in the kriging, are improved.
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 270-288 
    ISSN: 1436-3259
    Schlagwort(e): Periodicities ; hydraulic cycle ; spectral methods
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Periodicites in hydrologic data are frequently estimated and studied. In some cases the periodic components are subtracted from the data to obtain the stochastic components. In other cases the physical reasons for the occurrence of these periodicities are investigated. Apart from the annual cycle in the hydrologic data, periods corresponding to the 11 year sunspot cycle, the Hale cycle and others have been detected. The conclusions from most of these studies depend on the reliability and robustness of the methods used to detect these periodicities. Several spectral analysis methods have been proposed to investigate periodicities in time series data. Several of these have been compared to each other. The methods by Siddiqui and Wang and by Damsleth and Spjotvoll, which are stepwise procedures of spectrum estimation, have not been evaluated. Two of the methods of spectral analysis proposed by Siddiqui and Wang and by Damsleth and Spjotvoll are investigated in this study by using generated and observed data. Siddiqui and Wang's method is found to be superior to the Damsleth and Spjotvoll's method.
    Materialart: Digitale Medien
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 6 (1992), S. 289-303 
    ISSN: 1436-3259
    Schlagwort(e): Stream flow series ; shot-noise model ; sadolle-point approximation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract In this paper we consider the shot-noise model of streamflow series. We show how design discharge can be obtained by the stochastic intensity of thinned Poisson processes describing the peaks over a threshold. The main result concerns the stationary distribution of peaks. We derive an explicit expression for this limit distribution in terms of its Laplace transform. Approximation formulas are developed making use of the saddle point method for the asymptotic evaluation of contour integrals and the Post-Widder formula for inversion of Laplace transforms. We illustrate this methods on the case of Gamma-distributed shots. The stationary peak distribution is used to approximate the maximum value distribution for larger time intervals.
    Materialart: Digitale Medien
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  • 34
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Telechelically bis(hydrodimethylsilyl)-functionalized oligo(dimethylsiloxane)s or aromatics were found to give polymers constituting of alternating disilylene and oligodimethylsiloxane or 4,4′-diylaromatics as repeating units by dehydrogenative coupling reaction in the presence of palladium dibenzylideneacetone complex. The same catalyst gave polysilylenes with trisiloxane pendant from 1,1-dihydro-1,3,3,5,5,7,7,7-octamethyltetrasiloxane.
    Materialart: Digitale Medien
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 23-25 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Hybrid particles have been synthesized from methyltriethoxysilane (MTEOS) by the sol-gel process. The particle size, size distribution, particle surface morphology conductivity and pH of the reaction solution at different reaction times were determined. Compared with tetraethyl orthosilicate (TEOS) and p-(chloromethyl)phenyl-trimethoxysilane (CMPTOS), MTEOS has a slower hydrolysis rate.
    Materialart: Digitale Medien
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  • 36
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Polymerization of 4-n-alkylstyrenes (alkyl side group; methyl, ethyl, propyl and buthyl) was carried out with the η-C5(CH3)5TiCl3-methylaluminoxane (MAO) and TiCl3-triethylaluminum (TEA) catalyst systems. When the η-C5(CH3)5TiCl3-MAO catalyst was used, the stereoregularity of resulting polymers markedly depended on the length of substituted alkyl groups, i.e., the catalyst gave highly syndiotactic poly(4-methylstyrene), but produced atactic polymers for the monomers with ethyl, propyl and buthyl substituents. On the other hand, all the poly(4-n-alkylstyrene)s obtained with the TiCl3-TEA catalyst were highly isotactic. As a result, a large difference was observed in the thermal properties of polymers obtained between the two catalyst systems.
    Materialart: Digitale Medien
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 49-53 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Peptide synthesis in the aqueous polymer two-phase system was examined. Water soluble polymers adopted were dextran and polyethyleneglycol (PEG). By the modification of a proteolytic enzyme, trypsin, with dextran carrying a very small number of carboxyl groups, a separation of the enzyme from its peptide product, N-benzoyl-L-arginine glycinamide, which is relatively more soluble in a PEG phase could be realized. This separation drastically reduced a so-called "mass-law" effect, and increased the yield of the reaction product. The aqueous polymer two-phase system would be useful to enhance the usefulness of biocatalysts in organic syntheses.
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  • 38
    ISSN: 1436-2449
    Schlagwort(e): Key words: Poly(2-hydroxyethyl methacrylate) (PHEMA) – 5-fluorouracil (5-FU) – 1,1,1-trimethylolpropane trimethacrylate (TPT) – hydrogel – controlled release – diffusion coefficient
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The aim of this study is to examine the influence of crosslinking density on 5-Fluorouracil release from poly(2-hydroxyethyl methacrylate) (PHEMA) hydrogels crosslinked with 1,1,1-trimethylolpropane trimethacrylate (TPT). PHEMA hydrogels were synthesized by bulk polymerization with different proportions of TPT (1 – 10 wt%) as crosslinker agent and ammonium persulphate as initiator, enabling polymerization in the feed mixture in the presence of water. As a result, 5-FU could be trapped by including it as a sodium salt in the feed mixture of polymerization. Discs with 5-FU loads between 1 – 16 mg/disc were obtained. Swelling and 5-FU release kinetics studies were carried out in saline solution at 310 K. The diffusion studies were in accordance with Fick's second law during the initial stages, enabling the diffusion coefficients of the process to be determined. The time required for discs to reach total 5-FU release was between 35 h and 160 h and was a function of crosslinking density of the gels and 5-FU load of the discs.
    Materialart: Digitale Medien
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  • 39
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Oscillatory shear, shear relaxation and viscosity experiments have been carried out on semidilute solutions of chitosan and on a hydrophobically modified analogue (HM-chitosan) in 1% acetic acid. This was done in the presence of various amounts of cetyltrimethylammonium bromide (CTAB) and at different pH values. All the rheological measurements on the HM-chitosan solutions revealed significant polymer-surfactant interaction and pH effects. The observed rheological effects were least pronounced at pH ≈ 4, while a strong viscoelastic response was found at pH values of 1 and 5 in HM-chitosan solutions of low surfactant concentration. At these conditions, significant shear-thinning effects were observed. In semidilute solutions of unmodified chitosan, the influence of pH, surfactant concentration and shear rate on the rheological properties was moderate or insignificant.
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  • 40
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The electrical resistivity and mechanical properties of carbon black (CB)-filled polystyrene (PS)/styrene-butadiene block copolymer (SB) blends have been studied. Good electrical performance was achieved with pure SB and PS/SB blends indicating an inhomogeneity of these materials and the heterogeneous micro-dispersion of the CB particles. The percolation threshold of the filler inside SB or PS/SB blends is around 3.6 wt%, which is lower than that expected for incompatible PS/PBD blend. The addition of small amount CB decreases the elongation at break of PS/SB blends indicating some disturbance at the interface of these compatible material.
    Materialart: Digitale Medien
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  • 41
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 141-148 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Homo- and copolymerizations of 1,5-hexadiene with ethene and styrene using halfsandwich metallocene catalyst Me2Si(Me4Cp)(N-tert.-butyl)TiCl2/MAO (Cp = cyclopentadienyl, Me = methyl, MAO = methylalumoxane) were investigated. According to 13C-NMR spectroscopic microstructure analysis, cyclopolymerization of 1,5-hexadiene afforded randomly distributed cis- and trans-cyclopentane rings in the homo- and copolymer backbone. 1,5-hexadiene incorporation reached 52 mol-%. The ratio of vinyl side chains to cyclopentane rings was controlled by 1,5-hexadiene concentration, where low 1,5-hexadiene concentration promoted cyclopolymerization. Copolymer glass transition temperatures increased with increasing content of cyclic units in the backbone. Styrene was used successfully as termonomer in ethene/1,5-hexadiene polymerization, resulting in a semicrystalline terpolymer with cyclic and styrenic units in the polymer backbone.
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  • 42
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. New phospholipid polyurethanes containing phosphatidylcholine analogues in the main chains and octyl or oleyl groups in the side chains were synthesized by the addition polymerization of diols, bis[2-(2-hydroxyethyldimethylammonio)ethyl]2-octyl-1,3-propanediphosphate or bis[2-(2-hydroxyethyldimethylammonio)ethyl]2-oleyl-1,3-propanediphosphate, with diisocyanates such as 4,4′-diphenylmethane diisocyanate (MDI), hexamethylene diisocyanate (HDI), and 2,4-tolylene diisocyanate (TDI). The new phospholipid diols and polyurethanes were characterized by their IR and 1H-NMR spectral data and elemental analysis. The new phospholipid polyurethanes exhibit common polyelectrolyte viscosity behaviours revealed by viscosity measurements. Moreover, π-A isotherms for these polyurethanes were also prepared.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 165-168 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Hexamethylcyclotrisiloxane was found to undergo photoinitiated cationic ring-opening polymerization in solution and bulk, upon exposure to UV radiation, in the presence of either sulfonium or iodonium salts or an iminosulfonate derivative. Glass transition temperatures were below − 100 °C. Molecular weights, determined by size exclusion chromatography relative to polystyrene standards, increased with photolysis lamp intensity. Use of an iodonium photoinitiator afforded poly(dimethylsiloxane) with Mn = 172,000. Polymerization of hexamethylcyclotrisiloxane was accompanied by a small increase in volume (3 – 4%).
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 169-176 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. An alternating copolymer composed of 9,9′-dihexylfluorene and N-2-ethylhexyl carbazole was synthesized to use as an emissive polymer in a light-emitting diode (LED). The copolymer is soluble in organic solvents and spin-cast to make a fine film. An LED fabricated by sandwiching the alternating copolymer between indium-tin oxide and aluminum emits a white color with the full width at half maximum of 150 nm. The electroluminescence spectrum becomes simplified to have an emission peak at 460 nm for fine blue color when the copolymer is blended with poly(vinylcarbazole) with a ratio of 1 to 4 before the use as an emissive layer. The forward bias turn-on voltage for the LED is 13, and quantum efficiency is 0.002%.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 439-445 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The hydrogen bonding of LCE/DGEBA blend was studied using FT-IR. IR spectra of hydroxyl region and carbonyl region were investigated according to the content of LCE. IR spectra of LCE/DGEBA blend before and after curing were compared. Most hydroxyl group in DGEBA rich blends formed intermolecular or intramolecular hydrogen bonding after curing, while free hydroxyl group was present in LCE rich blends. Intramolecular hydrogen bonding was popular in DGEBA rich blends due to the conformational reason. Most carbonyl group was hydrogen bonded with hydroxyl or amine group after curing and the fraction of hydrogen bonded carbonyl was high in DGEBA rich blends.
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  • 46
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Hydrosilylation of N-allylimidazole hydrochloride by methyldichlorosilane (MeCl2SiH) under mild conditions leads to a high yield of N-[γ-(methyldichlorosilyl)propyl]imidazole hydrochloride – highly reactive monomer for synthesis of imidazole modified polysiloxanes. This compound was used as the substrate for the generation of new cyclooligosiloxanes with the imidazole group attached through the trimethylene bridge to a siloxane ring. The anionic ring-opening polymerization of these cyclics permits the controlled synthesis of polysiloxanes with imidazole groups pendant to the polymer chain.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 379-386 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Aliphatic polysulfoxides having sulfoxide groups in the main chain were prepared by the selective oxidation of aliphatic polysulfides using aqueous hydrogen peroxide in chloroform. Degree of oxidation to sulfoxides was calculated from the integral ratios of methylene protons adjacent to sulfur atoms in 1H-NMR spectra. Poly(hexamethylene sulfoxide) was subjected to Swern oxidation of primary or secondary alcohols, in which 1-octanol and 6-undecanol were oxidized to give octanal and 6-undecanone, respectively, in quantitative yields.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 573-577 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Polyanilinefurfural (PAF) has been prepared. Its chain contains aromatic and furan rings, but the backbone is nonconjugated. However, when treatment with iodine, the color of PAF turns metallic black, and PAF becomes electrically conductive. The electrical conductivity of I2-doped PAF can reach 10−3 S ⋅ cm−1 which is more than 10 orders of magnitude higher than what was observed at the pristine state. The effects of iodine content on the conductivity of PAF and the conductivity stability were investigated. FTIR spectra, U.v./vis absorption spectra, E.s.r. measurement and X.p.s. measurement of the undoped and doped PAF were studied. This paper will demonstrate that: if given appropriate substituents and dopants, significant charge transfer may be expected even for nonconjugated polymers and it may display electronic conductivity to a certain level.
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 555-562 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Factor analysis has been found to be suitable for the analysis NMR data of polymers which contain multiple components. Two series of ethylene/propylene copolymers have been studied by this technique. In general, the number of components that can be resolved from NMR data depends on both the quality and the quantity of available experimental data.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 609-612 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The rate lowering effect of crown ethers in the anionic polymerization of l-lactide is interpreted by the formation of activated monomer-cation complex. This interpretation is supported by molecular mechanics calculations. The formation of a 1 : 1 complex between lithium ion and l-lactide in THF was proved by 1H NMR and the formation constant was measured to be 3.8 M−1.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 601-608 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. This paper has two objectives. Firstly, to plan experimental blends (based on PVDF, PMMA and PVA) according to a statistical method proposed by Scheffé and subsequently to apply the model to the study of the spherulitic growth of PVDF with the aim of assess its suitability. In case it proved adequate, a simple method would become for the design of new materials from the polymer under study.
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 493-499 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The polycondensation of squaric acid with 1,2-(9-Ethylcarbazol-3-yl)ethene and N-ethyliminostilbene in polyphosphoric acid yielded insoluble polymers which included substituted phosphate groups on the phenyl rings. The presence of phosphorus in these polymers was identified using solid-state 31P NMR and EDAX techniques. Furthermore the phosphate groups were not ionic, hence no charge-balancing anions were present. Both polymers did not electrically conduct but exhibited dielectric breakdown values of 0.1 and 0.06 MV cm−1 respectively.
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  • 53
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. A comparative study was undertaken on well characterized HDPE and LDPE samples in order to obtain a better understanding of the morphology of the crystalline phase. Thickness of the lamellae was determined by WAXS. The melting points were calculated by empirical and Gibbs-Thomson equations, considering either folded or extended chains, and compared to DSC data. The results confirm that in HDPE the chains are folded, the segment between folds containing about 100 carbon atoms, while in LDPE, the chains are extended, with segments of about 73 carbon atoms in the crystalline core, linked to the paracrystalline layer and amorphous zones, which contain long folds and chain ends, as proposed in the 3-phase model by Vile et al.
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  • 54
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The novel poly(aryl ether ketone)s containing chloro-side group were synthesized by nucleophilic substitution reactions of 4,4′-biphenol and chlorohydroquinone with either 4,4′-difluorobenzophenone (BP/CH/DF) or 1,4-bis(p-fluorobenzoyl)benzene (BP/CH/BF) and their thermotropic liquid crystalline properties were characterized by a variety of experimental techniques. The thermotropic liquid crystalline behavior was observed in the copolymers containing 50 and 70% biphenol. Melting transition (Tm) and isotropization transition (Ti) both appeared in the DSC thermograms. A banded texture was formed after shearing the sample in the liquid crystalline state. The novel poly(aryl ether ketone)s had relatively higher glass transition temperature (Tg) in the range of 168 ∼ 200 °C and lower melting temperature (Tm) in the range of 290 ∼ 340 °C. The thermal stability (Td) was in the range of 430 ∼ 490 °C.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 635-642 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The new pyrazole-ring containing diamine monomer with amino and cyano groups, 1,3-di-p-aminophenyl-4-cyano-5-aminopyrazole (PYA), was prepared from 4-nitrobenzoyl chloride and 4-nitrophenyl hydrazine with 4 steps. The monomer was converted to polyamides with terephthaloyl chloride and isophthaloyl chloride. The amino and cyano groups on the pyrazole-ring were not affected during polymerization. The synthesized polyamides having intrinsic viscosities of 0.92 – 1.18 dL/g were amorphous, and soluble in polar aprotic solvents and boiling acetone and THF. The polymers had high glass transition temperatures and high thermal stability. 5% weight loss temperatures in nitrogen occurred around 490 °C, but these polymers are partially degraded at 300 °C in air due to the amino group on the pyrazole-ring.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 673-679 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The characterisation of fatty alcohol ethoxylate based surfactants by on-line LC-NMR coupling is described. Different surfactant mixtures were separated by a mixed exclusion-adsorption method of liquid chromatography and simultaneously characterised by 1H-NMR spectroscopy. Information about the degree of oligomerisation of the ethylene oxide chain and the chemical structure of the endgroups can be obtained in a one-step experiment.
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 38 (1997), S. 651-655 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The direct polycondensations of cubane-1,4-dicarboxylic acid with 1,4-phenylenediamine (2 a), 4,4′-oxydianiline (2 b), 4,4′-sulfonyldianiline (2 c), and 9,9′-bis(4-aminophenyl)florene (2 d) were carried out in N-methyl-2-pyrrolidone/pyridine containing triphenylphosphite and lithium chloride at 110 °C for 9 h. Polyamide 3 a obtained from 2 a was scarcely soluble in organic solvent even during heating, and was soluble only in conc-H2SO4, whereas 3 c and 3 d derived from 2 c and 2 d, respectively, were readily soluble in N-methyl-2-pyrrolidone, N,N-dimethylacetamide, N,N-dimethylformamide, and dimethylsulfoxide. After treating polyamide 3 d with the rhodium complex catalyst in NMP, cubane units were quantitatively converted into cyclooctatetraenes.
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  • 58
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The characterization of a block copolymer consisting of blocks of tetrahydrofuran, THF, and methyl methacrylate, MMA, was attempted with the aid of liquid chromatography, LC, at the critical adsorption point, CAP. The conditions applying to the CAP at 30 °C for the homopolymers are: PTHF: eluent composition: THF : acetonitrile = 50 : 50, w/w; column: Nucleosil C18. PMMA: eluent composition: THF : n-hexane = 81.8 : 18.2, w/w; column: bare silica gel. The presence of homo PTHF and of homo PMMA in the crude block copolymer was evidenced. Moreover, chromatography at the CAP for PMMA showed that the block copolymer contains multiblock (triblock) fractions. The formation of triblock copolymer is expected when the polymerization of MMA is terminated (partially) by combination. In conclusion, LC at the CAP is a powerful tool to characterize block copolymers regarding the presence of homopolymer and multiblock (triblock) fractions.
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  • 59
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. A new process for the sequential copolymerization of olefins has been devised (Multicatalysts Reactor Granule Technology); it allows the synthesis of thermoplastic polyolefin elastomers having polypropylene from Ti-based catalysts and ethylene-propylene rubbers from metallocenes. Such new materials have been cured with peroxides and the relevant mechanical properties measured in comparison with those of heterophasic copolymers synthesized with traditional catalysts. It resulted that the new materials present an improved balance between strength and elasticity, especially at high temperature.
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  • 60
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Graft copolymers with poly(2-nonyl-2-oxazoline) and poly(2-phenyl-2-oxazoline) graft arms have been synthesized using the "grafting from" method. Slightly branched statistical copolymers of isobutene and (m,p)-chloromethylstyrene, synthesized cationically, as well as linear homo-poly((m,p)-chloromethylstyrene) have been used as macroinitiators for the ring-opening polymerization of the substituted oxazolines. The graft copolymerizations were carried out in bulk and in benzonitrile solutions with and without addition of potassium iodide. The influence of the reaction conditions on the rate of polymerization and the different reactivities of 2-nonyl-2-oxazoline and 2-phenyl-2-oxazoline were discussed.
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  • 61
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The thermal degradation of a series of poly(methacrylic acid)s (PMADs) with different tacticities has been investigated under inert atmosphere. All the samples showed two main degradation stages. The first decomposition process of isotactic PMAD consisted of the formation of anhydride groups, almost quantitatively, by dehydration. In the case of PMADs with lower isotactic content, the elimination of water between neighboring carboxylic groups is less favored and the anhydridization shifts at higher temperatures where other degradation reactions may take place at the same time. The temperatures of maximum volatilization rates at the second step of decomposition increased in the order isotactic 〉 atactic 〉 syndiotactic.
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 117-124 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Natural rubber/butadiene rubber/cellulose II blends (NR/BR/CEL II) have been obtained by coprecipitation of the rubber latex-cellulose xanthate mixtures through acidulation. The elastomer ratio NR/BR has been varied from 100/0 to 25/75 and the cellulose content from 0 to 25 phr. The cure behavior of the compositions has been investigated by a Monsanto Oscillating Disk Rheometer. The results are a function of cellulose filler, NR, and BR contents. Some compositions were also analysed by equilibrium swelling in order to investigate polymer-filler interaction. The results show that composites with higher BR contents exhibit higher elastomer-filler attachment.
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  • 63
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Poly(amide-carbonate)s and poly(amide-thiocarbonate)s derived from the diphenol-amides N-(2,6-dichloro-4-nitrophenyl)-2,2-bis(hydroxyphenyl)-propylamide (I), N-(2,6-dichloro-4-nitrophenyl)-3,3-bis(hydroxyphenyl)-butylamide (II), and N-(2,6-dichloro-4-nitrophenyl)-4,4-bis(hydroxyphenyl)-pentylamide (III), and phosgene or thiophosgene, have been synthesized under phase transfer conditions using several quaternary ammonium salts as phase transfer catalysts. Benzyltriethylammonium chloride (BTEAC) was effective in practically all cases due the hydrophilicity of this catalysts.
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  • 64
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Interpolymer complex formations between Form II helical poly(l-proline) [PLP(II)] and Form I helical poly(l-proline) [PLP(I)] and poly(carboxylic acids) such as polyacrylic acid (PAA), atatic polymethacrylic acid (at-PMAA), and syndiotatic polymethacrylic acid (st-PMAA) have been studied by FT-IR, X-ray diffraction, and light scattering measurements. It was found that the interpolymer complexes were formed via hydrogen bonding. The helical PLP(II) formed polymer complex more favorably with PAA and at-PMAA having a disordered structure than with st-PMAA having a ordered structure. In contrast, the helical PLP(I) formed polymer complex more favorably with st-PMAA than with PAA and at-PMAA. In addition, PLP(II) helix was destroyed on the complexation with PAA and at-PMAA, but the PLP(II) helix was perserved on the complexation with st-PMAA. However, the PLP(I) helix was all perserved on the complexation with poly(carboxylic acids). These findings could be explained in terms of molecular conformation of the complementary polymers associated with the complex formation.
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  • 65
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Poly(methyl methacrylate) (PMMA) gels labeled at crosslinks with anthracene were prepared. Anthracene fluorescence depolarization was monitored to probe the local motion of crosslinks for PMMA gels at different equilibrium swelling states. The relaxation times and the activation energies of local motion were measured for PMMA gels at the swollen states in various solvents through fluorescence anisotropy decays. The local motion of PMMA gel at crosslinks became faster with the increase of swelling ratio. When the swelling ratios were almost the same, the mobility of crosslinks was the same irrespective of the molecular weights between crosslinks. These results indicate that the local motion of crosslinks for PMMA gel is mainly governed by the segment density of network chains in the vicinity of crosslinks.
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  • 66
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Polyacrylamide homopolymers and graft copolymers of poly(acrylamide-g-ethylene oxide) and poly(acrylamide-g-propylene oxide) were synthesized, characterized by SEC, FTIR and 13C-NMR and the behavior of their aqueous solutions was evaluated by surface tension measurements. By using the macromonomer technique, it is more difficult to incorporate poly(propylene oxide) branches than poly(ethylene oxide) branches. Graft copolymers of polyacrylamide and poly(propylene oxide) showed higher reduction of surface tension than poly(acrylamide-g-ethylene oxide) since they present a structure made up of hydrophilic and hydrophobic segments. Poly(acrylamide-g-propylene oxide) exhibits surfactant behavior, and the surface tension of its aqueous solution depends on the poly(propylene oxide) graft chain length and amount.
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  • 67
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 179-184 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Liquid crystalline poly(heptene sulphone)s containing cholesteryl undecylenic ester and cholestanyl undecylenic ester were synthesized. The polymers displayed cholesteric mesophases during thermal transition. The clearing temperatures were from 114 to 172 °C depending on the molar ratio of mesogenic esters in the polymers.
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  • 68
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 257-263 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The rotational isomeric state (RIS) model was used to calculate the molecular dimensions of poly(ethylene isophthalate) (PEI) and poly(ethylene naphthalene-2,6-dicarboxylate) (PEN) by introducing new description for aromatic segments and by adopting the statistical weight parameters of PET. The mean square dimension ratios ((〈r2〉0/M)∞) of PEN and PEI were 0.653 and 1.167, respectively, and the entanglement molecular weight (Me) of PEI and PEN were 1850 and 1810, respectively.
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  • 69
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. A series of polyacrylamide (PAAm) gels were prepared by free-radical crosslinking copolymerization of acrylamide and N,N′-methylenebis(acrylamide) (BAAm) in water at various crosslinker (BAAm) and chain transfer agent (isopropyl alcohol, IPA) concentrations. It was shown that only 5% of the crosslinker used in the feed forms effective crosslinks in the final hydrogels. At BAAm contents as high as 3 mole%, the equilibrium swelling ratio of the gels in water is independent of the crosslinker content in the feed. This is due to the prevailing multiple crosslinking reactions during the gel formation process. At a fixed crosslinker content, the onset of gelation is shifted towards higher conversions and reaction times as the amount of IPA increases. Addition of IPA in the monomer mixture also increases the equilibrium swelling ratio of PAAm gels. It was shown that the gel crosslinking density increases on rising IPA concentration in the feed due to the increasing rate of intermolecular crosslinking reactions.
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  • 70
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. New heterophasic copolymers with high rubber content have been synthesized by combining heterogeneous Ti-based catalysts with metallocenes. The molecular, morphological and mechanical features of these materials were evaluated: it was pointed out that the new copolymers, having more than 60 Wt.% of rubber, perform as reinforced elastomers whereas traditional ones show a more plastomeric behaviour. This suggests that new polyolefin materials can augment rather than compete with the traditional ones.
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  • 71
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 133-140 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. Ethylene-propylene copolymers have been prepared by using Ziegler-Natta catalysts based on TiCl4, MgCl2, PCl3 and (n-Bu)3PO4. The catalysts TiCl4/MgCl2/PCl3 and TiCl4/MgCl2/(n-Bu)3PO4 were prepared by reacting TiCl4 with pretreated MgCl2. The support was prepared by ball milling of MgCl2 with varied amounts of PCl3 or (n-Bu)3PO4. The addition of PCl3 has remarkably increased the MgCl2 surface area in comparison with (n-Bu)3PO4. The effects of PCl3 and (n-Bu)3PO4 on ethylene homopolymerization, ethylene-propylene copolymerization and on copolymer properties were evaluated. The catalyst system containing PCl3 permitted to synthesize propylene-ethylene copolymers with up to 75% (w/w) of propylene and provided control of copolymer crystallinity. The reduction of the copolymer molecular weight distribution suggested that PCl3 acted as an internal donor, poisoning some active catalytic sites.
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  • 72
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 489-494 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. In order to obtain films of liquid crystalline polymers, a commercial polyethylene film was grafted with acryloyl chloride using γ-irradiation, and two tolane-containing alcohols were reacted with the chloride to obtain the corresponding acrylates. The morphology changes were studied by DSC, X-ray diffractometry and optical microscopy. The crystallinity of polyethylene films decreased by grafting, and mesophase with spherulites was observed over a wide temperature range.
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  • 73
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 519-526 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The nature of intermolecular interaction in PVC/EVA system was investigated. Bathochromic shifts in infrared region revealed that not only EVA carbonyl but the ester group participates on interaction with PVC chain. These shifts were proportional to acetate content in the copolymer and the composition of EVA in the blend. The PVC group that effectively participates on interaction was not elucidated by infrared spectrometry, but molecular modeling of low molecular weight analogues indicated that hydrogen bonding is the most probable kind of intermolecular interaction present in this system.
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  • 74
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 527-534 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. A thermodynamic association model was applied to the PVC/EVA system. In this model the enthalpy component is related quantitatively to intermolecular interaction forces. Molecular modeling was applied to obtain the parameters related with interaction forces. The phase diagrams showed lower critical solution temperature (LCST) behavior and also biphasic regions in PVC rich compositions.
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  • 75
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 445-452 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The synthesis of a water-insoluble adsorbent resin was carried out by radical polymerization of [2-(methacryloyloxy)ethyl] trimethyl ammonium chloride by using ammonium peroxydisulfate as initiator and N,N′-methylene-bis-acrylamide (MBA) as crosslinking reagent. The adsorbent was characterized by elemental analyses, and FT-IR spectroscopy. The thermal stability was studied in the presence of Hg(II). The ability to bind Hg(II), Cd(II), Zn(II), Pb(II), Cu(II), Cr(III), and U(VI) as well as the maximum adsorption capacity, and elution of the Hg(II) from the loaded resin was studied. At pH 2 the adsorbent retained 95% of Hg(II) from an aqueous solution containing 1 g/L in Hg(II). The retention of other metal ions was lower than 15%. Sorption selectivity from the binary mixtures Hg(II)-Cd(II), Hg(II)-Zn(II), Hg(II)-Pb(II), and Hg(II)-Cr(III) was studied at the optimum sorption pH value.
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  • 76
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 399-406 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. 1-[(2-Vinyloxy)ethoxy]ethyl acetate (1) was prepared by the addition reaction between ethylene glycol divinyl ether and acetic acid. 1 contains both a cationically polymerizable C=C double bond and a dormant initiating moiety for cationic polymerization. It can, therefore, undergo self condensing cationic polymerization in the presence of a Lewis acid activator, such as zinc chloride. Using this procedure, a novel dendritic polymer consisting of vinyl ether was prepared and its hyperbranched molecular structure confirmed by FT-IR and 1H NMR spectra.
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  • 77
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 639-646 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The release of the extrinsic charges produced when applying an electric stress has been studied for four polypropylene samples of distinct well controlled molecular microstructure by Thermal Stimulated Discharge Current (TSDC), with the aim of stating the correlation between the ρ relaxation (intensity and temperature) and the tacticity induced polymer microstructure, and of, demonstrating that the traps of space charges are not chain defects as usually proposed but that they relate to some normal local chain configurations. The results are discussed in the light of the space charge distributions as measured in earlier recent work.
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  • 78
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. β-d-Galactoside branches have been introduced into chitosan and chitin regioselectively through a series of controlled modification reactions based on N-phthaloyl-chitosan. The glycosylation reaction between a chitosan derivative having a reactive group only at C-6 and an orthoester of d-galactose proceeded efficiently to give a protected product with a degree of substitution up to about 0.5. Deprotection gave a branched chitosan, and the subsequent N-acetylation afforded a branched chitin. Unlike chitosan and chitin, the resulting nonnatural branched polysaccharides were characterized by high affinity for solvents and readily soluble in neutral water. Furthermore, branched chitin was easily degraded by lysozyme.
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  • 79
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The novel dialkylanilinium salts of pentacoordinate Martin-type silicates were prepared. They were found to be air stable catalysts for polymerization of cyclohexene oxide. The preparation of those silicates bearing a bulky substituent such as mesityl group was not successful.
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  • 80
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 701-705 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The molecular packing of poly(azomethine)s having (n-alkyloxy)methyl side chains in films was studied by wide-angle X-ray scattering. Solution-cast films on silicon wafer and melt-sheared films show the same type of molecular packing, i.e. the main chain layers are aligned parallel to the film surface but the main chains are macroscopically isotropic in the film surface plane. In the melt-sheared films, the shear does not orient the main chains but the main chain layers, which can be easily understood by their geometric shapes.
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  • 81
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. When a benzene/cyclohexane mixture was permeated through poly(dimethyl acrylamide-random-methyl methacrylate) (DMAA-r-MMA) and poly(dimethyl acrylamide)-graft-poly(methyl methacrylate) (DMAA-g-MMA) membranes by pervaporation, the benzene-permselectivity of the DMAA-r-MMA membrane changed from the diffusivity selectivity to the solubility selectivity with increasing DMAA content but DMAA-g-MMA membranes with a high DMAA content had the higher apparent diffusivity selectivity than the apparent solubility selectivity. Furthermore, the apparent solubility selectivity for a benzene/cyclohexane mixture between the DMAA-r-MMA membrane and the DMAA-g-MMA membrane with a high DMAA content was remarkably different. These results were attributed to the difference of structure between the copolymers.
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  • 82
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 39 (1997), S. 761-765 
    ISSN: 1436-2449
    Schlagwort(e): metal/polymer interface – friction transfer – ultra-thin films
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract. The vapour deposition of tin on highly uniaxially oriented PTFE causes an oriented overgrowth of tin islands. The origin of this orientation is not clear. Classic epitaxy as well as graphoepitaxy seems to be an explanation for the occurring orientation. The appearance of this orientation was observed in a temperature range from −80 °C to 90 °C. An orientation by crystallization from the melt could not be achieved so far. In this short communication, a metal/polymer system is introduced which offers new possibilities to investigate the origin of oriented overgrowth.
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  • 83
    Digitale Medien
    Digitale Medien
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    Meteorology and atmospheric physics 47 (1992), S. 107-115 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary A number of cut-off processes are investigated, with the Alpine region in most cases lying at the margins of these upper lows. Our aim was to determine whether the thermal front parameter (TFP) can be used to objectively define the areas of bad weather from analysis charts and prognostic charts. An attempt is made to formulate two synoptic “guidelines”, for the eastern Alpine region, on front-sides and northern margins of upper lows, into objective synoptic rules.
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  • 84
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 127-144 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary This study examined ECMWF operational analyses of the outflow layer of two tropical cyclones (Allen, 1980; Elena, 1985) during their passage across the Atlantic and Caribbean. Wind fields and related derived quantities were compared to those from objective analyses of specialized data sets. Errors in center position and storm motion from the ECMWF analyses were also evaluated. Analyses of wind and angular momentum flux in 1985, subsequent to upgrading of the operational model, were superior to those from 1980. High-resolution, uninitialized analyses from 1985, however, provided no advantages over lower resolution, initialized analyses for the same time period. For all ECMWF analyses, azimuthally averaged (mean) tangential velocity, and thus mean vorticity, were well represented. Mean radial velocity and mean divergence were poorly represented. Problems with the latter arose primarily due to underestimation of outflow, especially in the 1980 analyses. Azimuthaleddy fluxes of angular momentum in the ECMWF analyses quantitatively differed from but qualitatively resembled, the control analyses. Vorticity maxima at 850 mb in the operational analyses most accurately defined the center position of the storms, with a mean error less than or equal to one grid point. In contrast, surface pressure minima failed to provide reliable estimates. Over open ocean and at early stages of storms, analysis quality was uneven, with occasional large position errors and widely varying locations of vorticity maxima in the vertical. Nevertheless, in regions surrounded by even a few rawinsondes, such as the Caribbean or Gulf of Mexico, ECMWF analyses contained sufficient information to allow individual case studies of the tropical cyclone environment. In the same regions, estimates of the eddy flux convergence of angular momentum were found to be accurate enough to aid in operational hurricane intensity prediction. Enhancements in resolution and model initialization at ECMWF since 1985 should further improve operational analyses of the tropical cyclone environment.
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  • 85
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 205-227 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary This paper describes the evolution of two thunderstorms which developed over northeastern Colorado on 23 July 1983, and more significantly discusses the possible causal relationship between them. In particular, a disturbance apparently created by the first thunderstorm, which developed over the eastern slopes of the Rocky mountains, seems to have triggered the second thunderstorm, which developed further east over the high plains. We present evidence that suggests that the disturbance is a rapidly propagating gravity wave (possibly a solitary wave of depression) that occupied most of the troposphere and was generated by the explosive convective development of the first thunderstorm. Detailed observations of the interactions between these two storms were possible because both storms developed over a dense network of automated weather stations that provided high temporal and spatial resolution surface measurements of pressure, temperature, precipitation, and horizontal wind velocity. Also located within this mesonetwork was a high power 915 MHz wind profiler that provided radial velocities throughout most of the troposphere. These measurements were supplemented with GOES visible and infrared satellite imagery and operational data from National Weather Service rawinsondes and weather radars.
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  • 86
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 237-245 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary Problems of turbulent dissipation of a cold air lake (CAL) and the inversion layer bordering CAL on the upper boundary are presented and studied with the compound model. In wintertime such cold air lakes can persist for days even if rather strong winds are blowing above them. The required conditions for CAL dissipation are removed processes of its formation or maintenance, as well as a sufficiently strong invasion of turbulence in the inversion layer from above down-wards. By this, the inversion layer at first becomes stronger and dissipation is stopped, until the increase of turbulent kinetic energy of the upper flow enables further dissipation. Such turbulent dissipation process is shown by the model for typical conditions and for different initial values of the relevent variables.
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  • 87
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 47 (1992), S. 259-265 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary THETAPLOT is a diagram useful for the display and analysis of atmospheric thermodynamic soundings, particularly in relation to conditionally and convectively instable summertime weather situations. The basic coordinates of THETAPLOT are the equivalent potential temperature and the negative logarithm of pressure. The body of the diagram contains families of curves of constant potential temperature, mixing ratio and temperature. From any given sounding, three curves are plotted on the diagram: 1) Theta-ed, the equivalent potential temperature of air saturated at its dew point temperature; 2) Theta-e, equivalent potential temperature; and 3) Theta-es, the saturated equivalent potential temperature. The winds are plotted along the margin of the diagram.
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  • 88
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 49 (1992), S. 187-207 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary This paper is concerned with the simulation of deep convection for the CCOPE 19 July 1981 case study. Clark's three-dimensional (3D) cloud model modified to use the bulk water parameterization scheme of Lin et al. has been used in the simulation of the CCOPE 19 July 1981 case in coarse mesh, fine mesh, and interactive grid nested schemes, respectively. Comparisons with observations show this 3D grid nested cloud model is capable of both capturing both the dynamic and microphysical properties of the cloud. In the nested grid fine mesh model simulation, the timing and mode of cloud growth, the diameter of liquid cloud, the cloud top rate of rise, the maximum cloud water content, and the altitude of first radar echo are consistent with observations. The simulated thunderstorm begins to dissipate, after precipitation reaches the ground as indicated by the decreasing values of maximum updraft and maximum liquid cloud water content, and ends as a precipitating anvil as was observed in the actual thunderstorm. The model precipitation developed through ice phase processes consistent with the analysis of observations from the actual thunderstorm. Qualitative comparisons of the actual radar RHIs with simulated reflectively patterns from the 3D model show remarkable similarity, especially after the mature stage is reached. Features of the actual RHI patterns, such as the weak echo region, upshear anvil bulge, strong upwind reflectivity gradients, and the upwind outflow region near the surface are reproduced in the simulation. Comparison of the actual radar PPIs with horizontal cross sections of radar reflectivity simulated by the 3D model, however, show modest differences in the storm size with the 3D simulated thunderstorm being 1–2 km longer in the west-east direction than the actual thunderstorm. The model-predicted maximum updraft speed is smaller than the 2D model-predicted maximum updraft speed, but still greater than what was observed. Comparisons among the nested grid fine mesh model (MB), nested grid coarse mesh model (MA), fine mesh model (FM), coarse mesh model (CM), and 2D model results previously published show that the nested grid fine mesh model (MB) gives the best simulation result. The various 3D model simulation results are generally similar to each other except for the difference in the domain maximum values. The domain maximum values in the fine mesh models (MB and FM) are generally higher than the coarse mesh models as a result of averaging over a smaller area.
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  • 89
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary The Penn State University/National Center for Atmospheric Research (PSU/NCAR) mesoscale model is a widely used research tool that has been applied in a wide variety of real-data, mesoalpha-scale applications. Recently a nonhydrostatic version of this model has been developed by Dudhia (1993). It is the purpose of this paper to illustrate the capabilities of this modeling system by describing four examples of mesobeta-scale simulations: two of the cases involve maritime processes and two deal with continental weather events. All utilize fully three-dimensional sets of initial conditions that are based on real data, both standard data and from special measurements programs. One case employs the model in a data-assimilation configuration, wherein Newtonian relaxation terms are used in the equations to assimilate data from a variety of platforms. This example of nonhydrostatic four-dimensional data assimilation (FDDA) is performed for the purpose of generating a dynamically consistent four-dimensional data-set, however the same procedure can be used for model initialization. The first case, described in section 2, involves the simulation of a coastal front that forms offshore near the western edge of the Gulf Stream. In the second case, described in section 3, the model is used in the FDDA mode to define the mesobeta-scale windfield over the complex terrain of the region around Grand Canyon, Arizona. In sections 4 and 5 will be described the mesobeta-scale structure of cold fronts, one within a marine cyclone, and another near the Rocky Mountains.
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  • 90
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary Hydrostatic and nonhydrostatic simulation models are employed to study the intensification of a terrain drag-induced dryline. The study develops a multi-stage theory for the evolution of the dryline including the concentration of potential vorticity accompanying meso-gamma scale dryline “bulges”. The numerical simulations indicate three fundamental stages of dryline intensification all of which are either directly or indirectly a result of the terrain-drag on the mid/upper-tropospheric jet stream by the Front Range of the Colorado Rocky Mountains. The first stage involves the downward momentum flux accompanying a large amplitude hydrostatic mountain wave which induces a downslope windstorm along the lee slopes. The surge of momentum (i.e., the dry, warm air associated with the downslope windstorm) propagates down the leeslope and modifies an existing weak dryline boundary. As the downslope windstorm initiates an undular bore along the lee slopes, the high momentum gradient which propagates downstream accompanying the bore, as well as the strong lower tropospheric sinking motions ahead of the bore, contract the scale of the surface moisture boundary between the dry air from above the leeslope and the moist air over the High Plains. This process further strengthens the dryline. The second stage involves the coupling of the terrain drag-induced along-stream ageostrophic front within the midtroposphere to the boundary layer through a thermally-indirect circulation. As the along-stream ageostrophic circulation intensifies within the middle troposphere down-stream from the mountain wave, sinking air parcels originating above 40 kPa descend to below 60 kPa over the High Plains where surface pressures are, only ∼85 kPa. These descending air parcels within the upstream branch of the along-stream ageostrophic thermally-indirect circulation contain high values of momentum and very low dewpoint values. As the planetary boundary layer (PBL) deepens due to surface warming during the morning hours, momentum and dry air from the midtropospheric along-stream ageostrophic front are entrained into the PBL. This process amplifies the bore-induced hydrostatic dryline bulge via low-level ageostrophic confluence. Finally, regions of low Richardson number (arising from strong vertical shears) within the amplifying midtropospheric along-stream ageostrophic thermally-indirect circulation become preferred regions for the development of non-hydrostatic evanescent internal gravity waves. These waves are embedded within the hydrostatic along-stream front above the low-level dryline and are accomapanied by very significant values of vertical momentum flux which act to focus the meso-gamma scale structure of the dryline into smaller scale bulges where low-level winds and vorticities are very high. This meso-gamma scale process follows the hydrostatic tilting and vortex tube stretching which creates meso-beta scale maxima of mid-lower tropospheric vorticity. The turbulent momentum fluxes accompanying wavebreaking within the nonhydrostatic dryline bulge create very large (i.e., stratospheric values of) potential vorticity near 70 kPa due to the nonconservation of potential vorticity on isentropic surfaces.
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  • 91
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 49 (1992), S. 229-254 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary A nonhydrostatic numerical simulation of a tropical cyclone is performed with explicit representation of cumulus on a meso-β scale grid and for a brief period on a meso-γ scale grid. Individual cumulus plumes are represented by a combination of explicit resolution and a 1.5 level closure predicting turbulent kinetic energy (TKE). The results demonstrate a number of expected and unexpected important scale interaction processes. Within the central core of the developing cyclone, meso-β convective regions grow and breakdown into propagating inertiagravity waves throughout the lifecycle of the cyclone. In the early stages, the amplitude of pressure fluctuations associated with the meso-β scale convection exceed the central pressure of the cyclone and strongly modulate its intensity. With each meso-β scale pulsation, the cyclone core increases in strength, measured by the central pressure deficit. The increasingly strong inertial frequency of the storm core acts to increasingly trap the convection induced heating within the core by balancing the tangential wind against the low central pressure, before the meso-β scale convection breaks down and sends the warmth away as a propagating wave. Eventually, the slow manifold's amplitude exceeds the amplitude of the meso-β scale oscillations and a stable eye region is formed. As inertial instability increases, increasingly high thermal warmth can be protected in the core, allowing persistent subsidence to form and to clear out the cyclone eye. On the outside of the eye wall, strong inertial stability gradients in the troposphere cause convective warming to split the inflow to the eye wal! and spawn outwardly propagating inertia gravity waves. These waves carry away all of the heating forced by convection that is not inertially trapped by the eye wall and act as a moderating influence on storm intensity. Inertia gravity waves are also spawned in the stratosphere at the top of the eye wall by the revolution of asymmetric cumulus structures. In all instances, the tropospheric waves are coupled to the propagating stratospheric waves which both move at 35 ms−1, although there are many instances where the stratospheric waves seem to have no tropospheric counterpart. Hence the anvil top forcing and low level breakdown are linked. The outwardly propagating inertia gravity waves act to initiate outer bands of convection. This initiation is with the assistance of low level boundary layer variations of density related to previous convection and to virga falling from the anvil which moistens and destabilizes the mid levels ofθ e minimum. The convection initiated by these waves does not move substantially outward with the wave, although may appear to develop outward discontinuously.
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 75-88 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary The set of fully compressible nonhydrostatic equations governing a broad spectrum of atmospheric motion was transformed fromz coordinates to sigma coordinates under a hydrostatic base state. The hydrostatic base state may be either time-independent, such as a hydrostatic balance with-out motion or with motion such as a thermal wind balance, or time-dependent such as might be obtained from the result of integrating a hydrostatic model. The transformed set of equations can be used to predict and study all scales of at mospheric phenomena. The set of perturbation equations was also derived under the same condition. The computational sensitivity in computation of pressure gradient force in sigma coordinate can be improved by computing the pressure gradient interms of perturbations under a certain hydrostatic state. The hydrostatic regional spectral model developed by Juang and Kanamitsu (1991) was modified to be a nonhydrostatic spectral model based on the nonhydrostatic equations in sigma coordinates with time-dependent hydrostatic base states. A semi-implicit time integration scheme was used. Two experiments were performed to test this nonhydrostatic spectral model with acceptable results.
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  • 93
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 61-73 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary Most finite-difference numerical weather prediction models employ vertical discretizations that are staggered, and are low-order (usually second-order) approximations for the important terms such as the derivation of the geopotential from the hydrostatic equation, and the calculation of the vertically integrated divergence. In a sigma-coordinate model the latter is used for computing both the surface pressure change and the vertical velocity. All of the above-mentioned variables can diminish the accuracy of the forecast if they are not calculated accurately, and can have an impact on related quantities such as precipitation. In this study various discretization schemes in the vertical are compared both in theory and in practice. Four different vertical grids are tested: one unstaggered and three staggered (including the widely-used “Lorenz” grid). The comparison is carried out by assessing the accuracy of the grids using vertical numerics that range from second-order up to sixth-order. The theoretical part of the study examines how faithfully each vertical grid reproduces the vertical modes of the governing equations linearized with a basic state atmosphere. The performance of the grids is evaluated for 2nd, 4th and 6th-order numerical schemes based on Lagrange polynomials, and for a 6th-ordercompact scheme. Our interpretation of the results of the theoretical study is as follows. The most important result is that the order of accuracy employed in the numerics seems to be more significant than the choice of vertical grid. There are differences between the grids at second-order, but these differences effectively vanish as the order of accuracy increases. The sixth-order schemes all produce very accurate results with the grids performing equally well, and with the compact scheme significantly outperforming the Lagrange scheme. A second major result is that for the number of levels typically used in current operational forecast models, second-order schemes (which are used almost universally) all appear to be relatively poor, for other than the lowest modes. The theoretical claims were confirmed in practice using a large number (100) of forecasts with the Australian Bureau of Meteorology Research Centre's operational model. By comparing “test” model forecasts using the four grids and the different orders of numerics with very high resolution “control” model forecasts, the results of the theoretical study seem to be corroborated.
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  • 94
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 127-142 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary Convective to planetary scale processes govern the motion and structure of tropical storms. A model with a high resolution and a large domain is required for accurate prediction of a storm's track and intensity. A series of integrations are performed using a primitive equation model and an initial state that defines a tropical storm that later developed into a hurricane in the real atmosphere. Increasing the horizontal resolution or domain of the model improves the forecast track. However only the increase in the horizontal resolution produces a better hurricane structure. Banded structure in the vertical motion field, asymmetries in the low tropospheric winds similar to those observed and upper tropospheric cyclonic outflow develop in high horizontal resolution experiments. It is shown that horizontal advection and pressure gradient terms produce wind tendencies in the low troposphere that displace the vortex in the observed direction. A high pressure area surrounding the central low pressure area appears in the upper troposphere. Around this high pressure area large pressure gradients develop that induce outflow winds in the distal storm area.
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 105-126 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary In this paper we present some recent work on typhoon prediction with a high resolution global model. The emphasis of this paper is on typhoon recurvature. Here we include examples of successful typhoon recurvature track forecasts made from a very high resolution global spectral model. The main objective of this study however is to go beyond the forecasts, i.e. to interrogate the history tapes and to diagnose residue-free budgets of the divergence and vorticity. The premise of this paper is that the recurvature of the typhoons depends on both the usual advection of vorticity by the layer mean winds and the advection of divergence in the outflow layers of the storm. The region immediately outside the heavy rain area of the storm experiences large values of divergent outflows which contribute a significant advection of divergence. Through the Dine's compensation this region must, in consort, experience an enhancement of low level convergence and of deep convection, thus contributing to the storm motion. We distinguish two facets of storm motion and recurvature, one based on the conventional steering that invokes the advection of vorticity by a vertical integrated flow, the other is the generation mechanism proposed here. During recurvature the storm appears to move in a direction which is influenced by the rotational and the divergent flow dynamics. Increased vertical resolution in the outflow layer is shown to resolve stronger amplitudes in the outflow layer divergence and thus to contribute to improved forecasts of recurvature. A number of processes seem to simultaneously evolve, these include the strong advection of divergence part of the wind, enhancement of cumulus convection over this region, an enhancement of lower tropospheric convergence, generation of vorticity of the lower troposphere and the attendant recurvature.
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  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 143-163 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary A number of forecast experiments were performed in order to assess the capability of reproducing, by means of a limited-area numerical model, the highly structured mesoscale circulations occurring in the Po Valley of Northern Italy during a north-westerly cold front passage across the Alpine chain, with particular attention to the modelling of the effects of organized convection. The case-study occurred during summer 1987 and the model used throughout was the 1989 version of the UB/NMC Limited Area Model (University of Belgrade, National Meteorological Centre of Washington). The model was integrated both with eta, η, and sigma, ϑ, as vertical coordinates and ECMWF initialized analyses were always used as initial conditions. ECMWF initialized analysis or operational forecast fields were also used for updating in time the lateral boundary conditions. Experiments show qualitative and quantitative agreement with observations, both in upper-air geopotential height fields, in MSLP and in cumulated precipitation. Several modelling issues were also investigated, e.g. sensitivity of the results to horizontal and vertical model resolution and to the influence of the lateral boundaries poitioning, finding large effects of the latter on quantitative precipitation fields. Difficulties in modelling very localized mesoscale phenomena, e.g. organized convective thunderstorms in the Po Valley and Alpine North Foehn in the Milan area, were generally encounted.
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 165-174 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary In this paper we present a methodology for evaluating rain rates from a mix of satellite and surface based observations. The component data sets include the outgoing longwave radiation (OLR), microwave radiometric data from the special sensor microwave imager (SSM/I) and surface raingauge data from the World Weather Watch. We have noted some deficiencies in the SSM/I algorithm-based rain rate over land areas; the OLR-based rain rates exhibit a larger lateral spread and lower intensities than the observed rainfall structures. The proposed combined method assimilates these three data sets to provide improved fields of global tropical rainfall.
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  • 98
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 175-187 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary The Kuo-type cumulus parameterization and rainfall rate scheme is extended by including the outgoing longwave radiation (OLR), the local time rate of change of OLR, and the horizontal Laplacian of OLR to include the additional source of mesoscale moisture supply. The extended scheme remains simple and efficient. A series of 5-day forecasts of the 1979 monsoon for the tropical belt between the Arabian Sea and the western Pacific Ocean show improvement in the 3-day forecast in the daily accumulated precipitation in both the amount and location. Further RMS error analyses indicate that using OLR and the Laplacian of OLR also produces a significant improvement in a 3-day forecast. Additional tests of the extended scheme for the 1987 and 1988 monsoons produced consistent and characteristic areal rainfall rates in the tropics. The improvement in the “OLR model” forecasts is attributed to the improved skill of OLR forecast in the forecast model as the RMS errors for 5 consecutive days in the 6 experimental forecasts are smaller than those of the 3 control forecasts.
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  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 189-195 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Summary A special analytical solution is derived for the classical orographic configuration of two-dimensional, stratified, linear, non-hydrostatic and dry model (without friction and Coriolis force). The well-known differential equation for the vertical velocity involves the vertical distribution of the Scorer parameterl 2(z) and in this casel 2 is specified such that the lower atmosphere has a stable duct near the surface and is capped by a layer which acts as a good reflector. Examination of the solution for the vertical amplitude in the vicinity of singularities indicates the dominant lee wavelength and observations confirm that in comparable settings resonant trapped gravity waves develop in the lee of mountains. Comparison with a real atmospheric lee-wave events gives good predictions for the wavelength and wave drag, but, as in other linear models, the amplitude is underestimated.
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  • 100
    Digitale Medien
    Digitale Medien
    Springer
    Meteorology and atmospheric physics 50 (1992), S. 237-238 
    ISSN: 1436-5065
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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