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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 2 (1997), S. 357-357 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 2
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 301-320 
    ISSN: 1082-5010
    Keywords: theory of porous media ; micropolar grain rotations ; liquid-saturated cohesive-frictional granular elastoplastic skeleton materials ; single-surface yield function ; non-associated flow ; shear band localization ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Elastoplastic deformations of cohesive-frictional liquid-saturated granular solid materials can be described by use of a macroscopic continuum mechanical approach within the well-founded framework of the theory of porous media (TPM). In the present contribution, the TPM formulation of the skeleton material is extended by micropolar degrees of freedom in the sense of the Cosserat brothers. Proceeding from two basic assumptions, material incompressibility of both constituents (skeleton material and pore liquid) and geometrically linear solid deformations, the non-symmetric effective skeleton stress and the couple stress tensor are determined by linear elasticity laws. In the framework of the ideal plasticity concept, the plastic yield limit is governed by a smooth and closed single-surface yield function together with non-associated flow rules for both the plastic strain rate and the plastic rate of curvature tensor. Fluid viscosity is taken into account by the drag force.The inclusion of micropolar degrees of freedom, in contrast to the usual continuum mechanical approach to the TPM, allows, on the one hand, for the determination of the local average grain rotations and, on the other hand, additionally yields a regularization effect on the solution of the strongly coupled system of governing equations when shear banding occurs. However, in the framework of the original TPM formulation of fluid-saturated porous materials, the inclusion of the fluid viscosity alone also yields a certain regularization on shear band computations. The numerical examples are solved by use of finite element discretization techniques, where, in particular, the computation of shear band localization phenomena is carried out by the example of the well-known base failure problem of geotechnical engineering. © 1997 John Wiley & Sons, Ltd.
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  • 3
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 321-337 
    ISSN: 1082-5010
    Keywords: thermal-softening behaviour ; transient evolution ; corner flow ; analytical solution ; convergence-confinement concept ; thermomechanical interaction ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A closed-form solution of deep tunnel subject to an internal pressure and to an axisymmetrical time-dependent temperature field is presented. The material is supposed to have a thermal-softening behaviour, the cohesion decreasing with the temperature. The thermal expansion generates plastic zones with face flow and corner flow, which can coexist and interact. The explicit character of the solution allows rigorous demonstrations of the evolution of such plastic zones, as well as other interesting and fundamental properties of the thermoplastic behaviour of deep tunnels. On the other hand, the causal relationship between the thermomechanical loading and the structural response (convergence, extension of rupture zones) is rendered transparent, thanks to the simplicity of the analytical solution. The consequence of thermal-softening is clearly shown by comparison with the analytical solution for a constant cohesion previously established. Quantitatively, its importance is illustrated by a restricted parametric study, to which the analytical solution is ideally suited. © 1997 John Wiley & Sons, Ltd.
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  • 4
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 339-356 
    ISSN: 1082-5010
    Keywords: biaxial tests ; combined stresses ; compressive strength ; engineering materials ; failure ; failure surfaces ; mathematical models ; tensile strength ; triaxial tests ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A general, three-dimensional failure criterion is presented. This criterion is formulated in terms of the first and third stress invariants of the stress tensor, and it involves only three independent material parameters. Although these parameters interact with one another, each parameter corresponds to one of three failure characteristics of material behaviour. These material parameters may be determined from any type of strength test, including the simplest possible, such as uniaxial compression and tension tests or biaxial tests for materials with cohesion and tensile strength, and by triaxial compression tests for materials without tensile strength. The procedure for determination of the three material parameters is demonstrated and comparisons between the failure criterion and experimental results are presented for different types of engineering materials. © 1997 John Wiley & Sons, Ltd.
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  • 5
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 31-46 
    ISSN: 1082-5010
    Keywords: block structure ; elasticity ; homogenization ; Cosserat continuum ; dynamics ; large deformation ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A continuum model for regular block structures is derived by replacing the difference quotients of the discrete equations by corresponding differential quotients. The homogenization procedure leads to an anisotropic Cosserat Continuum. For elastic block interactions the dispersion relations of the discrete and the continuous models are derived and compared. Yield criteria for block tilting and sliding are formulated. An extension of the theory for large deformation is proposed. © 1997 by John Wiley & Sons, Ltd.
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  • 6
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 1-29 
    ISSN: 1082-5010
    Keywords: numerical integration ; constitutive modelling ; frictional materials ; highly non-linear hardening functions ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Constitutive relations in elastoplasticity may be formulated in a variety of ways, and different update algorithms may be employed to solve the resulting equations. Several implicit integration schemes, although some not widely used, have been suggested in the last years. Among them, the closest point projection method (CPPM) has proven to be an effective and robust integration scheme. In order to gain maximum control of the stress projection, a two-level CPPM iteration scheme is proposed. The hardening variables are fixed during the stress projection onto consequently fixed yield surfaces, and after the stress projection, new values of the hardening variables are calculated defining new yield surfaces. The update of the hardening parameters which, in general, may be highly nonlinear functions, may be determined by a combination of a Picard Iteration (PI) on the hardening variables and an adaptative order inverse interpolation (AOII) on the difference of subsequent iterations of the hardening variables.The integration scheme has been implemented in a general constitutive driver which has been formulated independent of the selected constitutive model and easily linked to finite element codes. A third stress invariant dependent, cone-cap elastoplastic constitutive model, referred to as the MRS-Lade, with a highly non-linear hardening function has been used to show the applicability of the proposed iteration scheme. Error analyses and accuracy assessment are presented along with some representative test results. © 1997 by John Wiley & Sons, Ltd
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  • 7
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 71-92 
    ISSN: 1082-5010
    Keywords: undrained instability ; static liquefaction ; non-associated plasticity ; loss of uniqueness ; model validations ; very loose sand ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The characteristics of the loss of stability associated with the initiation of the static liquefaction phenomenon is obtained using the CJS model within the elastoplasticity framework. This model is based on the characteristic line concept. The determining factors involved in the prediction of this phenomenon and in the modelling process are identified. The importance of the elastic components is highlighted, in particular its non-linearity. The possibilities and the limits of the proposed model to describe the undrained behaviour of very loose sand are examined, taking into consideration the effects of the more or less complex stress history. Finally, the conditions leading to the appearance of the uniqueness domain are indicated. The findings of this theoretical study rely entirely on the experimental data presented in a companion paper, with emphasis on the triaxial tests on anisotropically consolidated samples. © 1997 by John Wiley & Sons, Ltd.
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  • 8
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 93-120 
    ISSN: 1082-5010
    Keywords: loose sands ; load-controlled triaxial tests ; creep tests ; instability ; theoretical interpretation ; strain-rate sensitivity ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of triaxial load-controlled tests is performed.Finite load increments are imposed. The single load-steps are followed by a time period during which the axial load is kept constant.At low stress levels the mechanical response is stable and characterized by a continuous decrease in strain rate with time. At higher stress levels, the mechanical response changes and, subsequently, the collapse takes place.The collapse is unexpected and occurs at a stress level less than that associated with the steady state, experimentally observed by performing strain triaxial controlled tests.In order to interpret such a behaviour, a theoretical discussion is introduced. This is based on a dynamical reinterpretation of the micromechani cal fabric rearrangement of granular assembly.In particular, the role played by the kinetic energy of the system, as well as that played by the anisotropy of the microstructure, have been analysed. © 1997 by John Wiley & Sons, Ltd. Mech. cohesive-frictional mater. 2, 93-120 (1997)
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  • 9
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 47-70 
    ISSN: 1082-5010
    Keywords: instability ; liquefaction ; laboratory tests ; undrained ; triaxial ; loose sand ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The undrained behavior of very loose Hostun RF sand in triaxial compression and extension tests is described. The samples are consolidated isotropically or anisotropically along constant effective stress ratio paths. Very loose sand exhibits partial liquefaction, deviator peak stress at relatively low to very low axial strain, gradual post-peak stress reduction to a small residual value at large strains, sharp loss of effective mean pressure due to generation of large pore pressure and overall volume reduction. The instability line of Lade is examined in the case of extension tests and extended for anisotropic samples. It is shown that monotonic and anisotropic consolidation strongly influences the instability concept. A higher positive anisotropic consolidation level produces a greater slope of the instability line in compression and a reverse trend can occur in extension. Complex stress history can develop a fossilized instability line depending on the amount of axial strain attained. Effective strain ratio increment at peak has an asymptotic stabilization effect. © 1997 by John Wiley & Sons, Ltd.
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  • 10
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 121-163 
    ISSN: 1082-5010
    Keywords: granular materials ; micromechanics ; biaxial tests ; complex loading paths ; micro-macro relations ; fabric anisotropy ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper is concerned with micromechanics of Schneebeli material specimens composed of wooden roller stacks. Several laboratory tests are carried out to analyse the material behaviour under complex loading conditions, involving loading-unloading cycles and principal axes rotations. In order to characterize micromechanical deformation features and structure evolution, a series of pictures is taken during loading. Pictures are then digitized using a stereo device, obtaining the position of each roller. Starting from these data a number of computer programs, conceived for the purpose, allow us to measure micromechanical variables and to analyse their evolution.In the following, after the description of the devices employed in this research, macromechanical results are analysed to evaluate the reliability of the laboratory model. Then, local variables are introduced and the use of continuum mechanics to describe granular materials behaviour is discussed. Finally, the evolution of local kinematic variables is described, focusing interest on the evolution of specimen anisotropy. © 1997 by John Wiley & Sons, Ltd. Mech. cohesive-frictional mater. 2, 121-163 (1997)
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  • 11
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 165-183 
    ISSN: 1082-5010
    Keywords: elastoplasticity ; pressure sensitive materials ; constitutive modelling ; dilatancy ; implicit integrations ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The paper presents the derivation of a fully implicit Newton algorithm for direct integration of constitutive equations, in extended stress-internal variable space, involving hardening or softening of a general dilatant isotropic elastoplastic geomaterial. All relevant derivatives are provided in tensor notation, thus facilitating implementation. The consistent, algorithmic tangent stiffness tensor is derived. The relative accuracy of a template algorithm is assessed on a number of examples by means of iso-error maps. We present a rather simple, one-increment example concerning convergence properties of the Newton iterative scheme at the global, finite element level, associated with the consistent tangent stiffness tensor for integrating the weak form of the equilibrium equations. © 1997 by John Wiley & Sons, Ltd. Mech. Cohesive-frictional mater. 2, 165-183 (1977)
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  • 12
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 185-203 
    ISSN: 1082-5010
    Keywords: fluid-saturated porous media ; enhanced element technology ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This contribution is concerned with a new mixed finite element formulation for geometrically linear Terzaghi-Biot type fluid-saturated porous media. To this end, an extended Hu-Washizu type mixed variational principle is presented for fluid-saturated porous continua. Then, a suitable discretization and its implementation are discussed, resulting in an improved element behaviour especially in numerical localization analyses. The intriguing element performance is firstly demonstrated for the case of localization within an elastoplastic compression problem. Finally, an elastoplastic slope stability problem is examined, whereby the new element formulation proves to render more pronounced failure modes as compared with a standard element expansion. © 1997 John Wiley & Sons, Ltd.
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  • 13
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 205-221 
    ISSN: 1082-5010
    Keywords: pollutant diffusion ; advection ; porous media ; surface transfer resistance ; physical modelling ; homogenization ; model classification ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the paper, an attempt to model local equilibrium and local non-equilibrium in pollutant migration in porous media is presented. Diffusion is assumed to occur in the pores as well as in the solid porous matrix. The macroscopic models are developed using the homogenization method (asymptotic expansion technique). The resulting macroscopic equations show either a one-concentration field or two-concentration fields or memory effects. The domains of validity of all the presented models are also determined. Local cell problems are provided to compute the effective diffusion tensors. The conditions for the local mass equilibrium assumption to be valid are derived in terms of the dimensionless characteristic parameters. The effect of pollutant source distributions is also investigated. © 1997 John Wiley & Son, Ltd.
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  • 14
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 223-236 
    ISSN: 1082-5010
    Keywords: granular materials ; vortices ; discrete element method ; coherent structures ; proper orthogonal decomposition ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Discrete element models are used to investigate the formation of coherent structures within a deforming granular material. The numerical models predict the formation of coherent vortex-like structures, even when the boundary deformations introduce zero vorticity. We name these structures circulation cells because the particles instantaneously translate and rotate as a rigid body about a common centre. They occur for all the particle shapes and material properties tested. The size of these coherent structures range from approximately 20 to 600 particles, with the largest structures being limited by the test boundaries. Circulation cells are seen to play an important role in granular deformations including the formation of shear bands. © 1997 John Wiley & Sons, Ltd.
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  • 15
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 237-249 
    ISSN: 1082-5010
    Keywords: concrete ; confinement ; dilation ; fibres ; plastics ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Confinement of concrete enhances it strength and ductility by restraining lateral dilation. The accuracy of a confinement model depends on how well it captures the dilation tendency of concrete. In recent years, external confinement of concrete by fibre composites has become increasingly popular for civil infrastructure applications. This includes fibre-wrapping of existing columns or encasement of concrete in a fibre reinforced plastics (FRP) shell. A total of 54-concrete-filled FRP tubes were tested in uniaxial compression under displacement control mode. Full instrumentation of the specimens has allowed the variation of tangent Poisson's ratio for concrete to be captured. The dilation trend of confined concrete is shown to be a function of jacket stiffness. In steel-encased members, once steel yields, confining pressure becomes constant and the jacket renders itself ineffective in containing the dilation of concrete. On the other hand, for linear-elastic materials such as fibre composites, a strain reversal occurs that results in containment of dilation. A method for predicting the dilation is developed that can be easily adopted in any active confinement model. Moreover, a new confinement model for FRP-encased concrete is discussed. © 1997 John Wiley & Sons, Ltd.
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  • 16
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 279-299 
    ISSN: 1082-5010
    Keywords: constitutive model ; hypoplasticity ; plasticity ; grain contacts ; intergranular strain ; strain-space plasticity ; recent history ; small strain ; ratcheting ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In order to eliminate ratcheting a so-called intergranular strain has been added to a hypoplastic constitutive model. This additional state variable represents the deformation of the interface layer between the grains. The new concept is outlined and comparisons with and without intergranular strain are presented. Some comments on numerical implementation and determination of material constants are made. A discussion on the uniqueness of the solution and objectivity of the rate of intergranular strain is added. © 1997 John Wiley & Sons, Ltd.
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  • 17
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 251-278 
    ISSN: 1082-5010
    Keywords: Pietra Leccesse chalk ; laboratory tests ; constitutive modelling ; capillary forces ; partial saturation ; collapsible rocks ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Experiments on Pietra Leccese chalk revealed that many of the material parameters describing its mechanical behaviour, such as the Young's modulus, the uniaxial compressive strength and the plastic yield stress, depend strongly on the water saturation and the ensuing capillary suction. The experimental results show that Bishop's generalized effective stress is not by itself adequate to explain the observed behaviour and in particular the spontaneous collapse which may occur upon water injection under stress. An elastoplastic constitutive model for partially-saturated collapsible rocks is proposed where the capillary suction is assumed to affect primarily the material properties related to the intergranular cohesion, such as the elastic stiffness, the plastic tension cut-off and pressure cap parameters. The model builds upon the well- established Mohr-Coulomb theory of elastoplasticity by including a pressure cap and considering the water saturation as an internal variable. In low levels of water saturation, as is often the case in oil reservoir formations, the experimental and theoretical results demonstrate the potential significance of capillary effects on the response of reservoir rocks, a mechanism that has been largely underestimated in the petroleum industry. © 1997 John Wiley & Sons, Ltd.
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  • 18
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Much of the information accumulated on the fire resistance of ‘dividing’ elements can be utilized in the design of buildings for fire safety, if the fire tolerance values are converted into fire resistance. Three methods of conversion, one based on the concept of equal temperature-time areas, the second on the concept of equal maximum temperatures, and the third, Law method, are critically examined and handy conversion tools presented. In the case of the ‘key’ elements of buildings, basing the fire safety design on fire resistance information is not recommended.
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  • 19
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    Fire and Materials 7 (1983), S. 38-40 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
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    Fire and Materials 7 (1983), S. 132-149 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: To assess the utility of a laboratory test for smoke and fume emission from overheated materials, six materials were heated to 500°C in larger amounts in three locations in an air-conditioned aircraft fuselage on the ground. Smoke, acidic or alkaline gases and carbon monoxide were monitored. It was shown that the laboratory test results could be a basis for predicting the smoke- and fume-emission behaviour of materials subjected to overheating, e. g. in aircraft in flight.
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  • 21
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    Fire and Materials 7 (1983), S. 128-131 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Smoke toxicity test methods which determine only lethal toxicological potency under ‘worst case’ conditions do not satisfactorily address the critical issue of relative hazard, including time-to-escape and tenability limits resulting from the fire performance of materials under comparable conditions. Since threats to escape from a fire are largely time-dependent, toxic insults produced by burning materials should also be considered as rate processes. Assessment of time thresholds exhibited by burning materials under test conditions to effect performance impairment (incapacitation) of an animal model would appear to be more relevant than lethal toxicological potencies in estimating probability of successful escape from fires. A model is advanced in which intoxication rate thresholds for materials are obtained using a rodent exposure test method. Concentration-time curves, obtained from experimentally derived concentration-time-response surfaces, are the basis for estimating rate thresholds which are distinctively different for each material and which vary as a function of test conditions. it is this performance impairment response surface which is potentially a key to the modeling of toxic hazards of smoke in perspective with other hazards presented by fire.
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  • 22
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    Fire and Materials 7 (1983), S. 157-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The term ‘bed’ has a variety of meanings in different countries. In central Europe, ‘bed’ is used for a bedstead with a mattress, a duvet and a pillow, Following clear definitions of the components of a ‘bed’ the author considers methods for testing the burning characteristics of beds and reports on experiences with model beds in fire tests.
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  • 23
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    Fire and Materials 7 (1983), S. 150-156 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A device constructed and used to determine the flammability limits of pyrolysate-air mixtures as a function of percentage weight loss on pyrolysis has been employed to investigate the pyrolysate gases generated from poly (ethylene terephthalate) both in the presence and absence of chemical flame retardants. The chemicals tripropyl phosphate (TPP), dibromopropanol (DBP) and tris (2, 3 dibromopropyl) phosphate (TRIS) all influenced both the lower and upper flammability limits, with the largest effects being obtained when both phosphorus and bromine were present, followed by bromine only and then phosphorus only. The results indicate TPP has negligible condensed phase activity with only small gas phase action. DBP has no condensed phase activity but is a very active gas phase inhibitor. In contrast, TRIS has a detrimental effect upon the condensed phase reactions in that it is responsible for the formation of a more flammable pyrolysate gas mixture. Fortunately, its gas phase inhibition reaction is capable of reducing the overall flammability.
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  • 24
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    Fire and Materials 7 (1983), S. 180-184 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Flammability tests are difficult because of the complexity of burning processes and of safety considerations. Experimental fires only give a partial view of the combustion process. Owing to the dynamic processes occurring in the flame, tests are very sensitive to external influences. Use, therefore, of flammability test methods should be made only with a clear understanding of what is being tested. Only officially standardized and recognized test methods should be sued.
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  • 25
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    Fire and Materials 7 (1983), S. 173-179 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Polymeric Dielectrics are usually chemically complex, and it is attractive to establish techniques capable of providing a general assessment of material composition and thermal behaviour. Simultaneous thermal analysis (STA) is capable of providing such an assessment and complementing flammability studies. The use of STA in both of these roles is demonstrated for a number of polymer materials used in high-voltage cables. The materials investigated include various polyethylenes, ethylene-copolymers and filled polyvinylchloride formulations. Fingerprint identification of materials and the influence of chemical structure and additives on thermal behaviour is discussed. In particular the influence of antimony trioxide-chlorinated hydrocarbon flame retardants is examined. The application of STA information in guiding flammability studies is shown by example, and some potential routes for further development are also discussed.
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  • 26
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    Fire and Materials 7 (1983), S. 185-192 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Detailed quantitative studies are reported on the kinetics of acetonitrile pyrolysis using an isothermal quartz tubular flow reactor at 720-1033 K and 1 atm. Pressure using flow rates, in nitrogen, of 2-200 ml min-1. The pyrolysis of several other nitriles (acrylonitrile, propionitrile, methacrylonitrile and benzonitrile) has also been investigated qualitatively by pyrolysis-gas chromatography.
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  • 27
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    Fire and Materials 7 (1983), S. 193-201 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fire retardants improve reaction to fire characteristics such as ignitability and flame propagation. This paper presents the toxicological results of tests performed on eleven pairs of untreated and treated materials, including woods, synthetic materials and textiles (both natural and synthetic). It is shown that the effects of fire retardants on toxicity results can be variable. In addition, the problem of the use of toxicity results is discussed more generally.
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    Fire and Materials 7 (1983), S. 210-215 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A Preliminary study of the thermal degradation of wool fabric was carried out under a wide range of oxidative degradation conditions including flaming combustion. Product collection methods and analysis conditions were designed to minimize secondary reactions. The degradation products obtained included a variety of organic nitriles and heterocyclic compounds as well as the usual aromatic and oxygenated products. Variations in moisture content and fire retardant level in the wool had little effect on the organic volatiles produced form the fabrics.
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  • 29
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    Fire and Materials 7 (1983), S. 202-209 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There is widespread concern at present about the fire risk form the use of modern materials in upholstery and other domestic articles. One of the main characteristics of fires in dwellings which start with the ignition of textiles or furniture is that they have a high casualty rate compared with other kinds of domestic fires. Most of the casualties form such fires occur in fires which start in upholstery or bedding, often accidentally ignited by smokers' materials. Asphyxiations by smoke is the commonest cause of death in ‘textile’ and ‘upholstery’ fires. This paper presents relevant statistical information on fires in dwellings attended by local authority fire brigades which result from the ignition of upholstery, bedding, other textiles or furniture and the casualties which these fires cause.
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    Fire and Materials 7 (1983), S. 216-218 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 6-9 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 1-5 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The application of the results of any fire toxicity test is extremely difficult because of the complexity of the problem and the limitations of the test. This paper will discuss the potential use of test data in the decision-making process.
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    Fire and Materials 8 (1984), S. 10-16 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The mechanisms of incapacitation resulting from exposures to the thermal decomposition products of flexible and rigid polyurethane foams (PUF) were studied over a range of different temperatures under pyrolytic or non-flaming oxidative decomposition conditions. Individual cynomolgus monkeys were exposed to atmospheres increasing in separate experiments from very low concentrations until early physiological signs of incapacitation were detected. When flexible PUF was pyrolysed at 900°C and rigid PUF was oxidized at 600°C, clear atmospheres containing CO and HCN were produced and the signs of toxicity were very similar to those produced by HCN gas alone, consisting of an episode of hyperventilation followed by a semi-conscious state. Pyrolysis of flexible PUF at 600°C and 300°C produced a dense yellow smoke but no HCN. The signs, consisting of hyperventilation throughout exposure and dyspnoea afterwards, were consistent with pulmonary irritation, Since TDI monmer is not present at 6000 C it is concluded that some as-yet unidentified but highly irritant chemical species is present in smoke from flexible PUF.
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    Fire and Materials 8 (1984), S. 17-19 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Flame-retardant paints have been developed which can considerably upgrade the performance of combustible substrates in surface spread of flame test, but there is uncertainty as to their benefit in a real fire situation. This is partly owing to the lack of agreement on laboratory test methods and even of their value. Flame-retardant paints commercially available in the United Kingdom are of two types, the intumescent type and the antimony oxide type, and their mechanism of action is discussed.
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    Fire and Materials 8 (1984), S. 20-27 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The Swedisn box apparatus was modified to include an oxygen analysis of the exhaust gases to be compared with the conventional exhaust gas temperature measurement. A slow-burning material shows good correlation between the temperature measurement and the rate of heat release. A fast-burning material, however, consumes all the available oxygen, and the temperature measurement becomes a measure of only the thermal properties of the material.
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    Fire and Materials 8 (1984), S. 28-39 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A theoretical and experimental study of buoyant, axisymmetric, turbulent, diffusion flames is described. Measurements included profiles of mean velocity, mean temperature and mean concentrations of major species for flames having heat release rates of 1.67 and 8.51 kW. An integral model was developed and calibrated with both present and earlier measurements. Empirical constants account for flow entrainment and rates of fuel consumption. Overall, the integral model provided satisfactory predictions of bulk velocity, temperature and concentrations in both combusting and non-combusting plumes.
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    Fire and Materials 8 (1984), S. 40-48 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Progress in the field of theoretical prediction of fire resistance has been rapid in recent years. A procedure has been developed at the National Research Council of Canada for calculation of the fire resistance of structural members. The various steps in the construction of a mathematical model to calculate temperatures, deformations and strength are shown using as an example the calculation of the fire resistance of a cylindrical tubular steel column filled with concrete. A comparison of results calculated using the model with those of a fire test is also discussed.
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    Fire and Materials 8 (1984), S. 55-56 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 49-53 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The Fire Precautions Act 1971, in contrast with previous legislation, is directed exclusively to the provision of fire precautions in buildings after occupation. The system of control is by fire certificate and can be applied to a class of premise (listed in Section 1) by means of a designating order. In the case of any particular use of premise, the Secretary of State, under Section 12, may by Regulation, make provision as to precautions which are to be taken in relation to the risk to persons in case of fire.
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    Fire and Materials 8 (1984), S. 54-55 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 8 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 8 (1984), S. 64-68 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: More than 700 standardized rules for fire testing are used round the world in order to assess the fire safety of materials, products and constructions in different technical fields. This article discusses the reasons for this variety of test methods and evaluation systems and the attempts to create systematic models in this special field of material testing, including new suggestions and developments in ISO and CIB for future approaches.
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    Fire and Materials 8 (1984), S. 57-63 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Laboratory tests have been developed that evaluate realistically the protective performance of clothing materials and garments. Test conditions are chosen to stress the high temperature resistance of materials in the same manner as in an industrial flash fire exposure. A second degree burn in human tissue is used as the criteria to ate performance of materials. Test results have been correlated between the small-scale lab swatch test and a full-scale instrumented manikin garment test, and these results related to industrial experience. The TPP lab test has been found useful in evaluating the performance of candidate materials as replacement for existing materials with known acceptable protective performance. It can be used to specify the level of protection needed in a garment when the intensity of the exposure hazard is known. Also, the test is especially useful for developing new materials and selecting candidates for additional field testing.
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    Fire and Materials 8 (1984), S. 77-80 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Normalized heart load, obtained by dividing heat absorption by thermal inertia, is a quantity useful in building design for relating fire severity in fully developed compartment fires to fire severity in standard fire resistance tests. Harmathy has shown how normalized heat load may be used for determining required fire resistance in projected buildings. The present work describes how effective values of thermal inertia can be calculated for such important materials as brick and concrete, both normal and lightweight, for which thermal properties depend strongly upon temperature.
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    Fire and Materials 8 (1984), S. 69-76 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Some examples of the application of fire tests to hazard and risk assessment and some of the problems to be encountered are described. Reference is made to theoretical studies designed to show how to obtain basic data on material properties from ignitability and flame spread tests, and recent correlations of the rate of heat release required to cause flashover are presented. Progress in predicting fire growth from theory for certain idealized conditions will increasingly condition the choice of which processes shall be the subject of tests.
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    Fire and Materials 8 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 49
    ISSN: 0308-0501
    Keywords: Combustion of plastics ; combustion properties ; fire tests ; heat of combustion ; ignitability ; oxygen consumption ; rate of heat release ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A new bench-scale rate of heat release calorimeter utilizing the oxygen consumption principle has been developed for use in fire testing and research. Specimens may be of uniform or composite construction and may be tested in a horizontal, face-up orientation, or, for those which do not melt, in a vertical orientation. An external irradiance of zero to over 100 kW m-2 may be imposed by means of a temperature-controlled radiant heater. The rate of heat release is determined by measuring combustion product gas flow and oxygen depletion, while the mass loss is also recorded simultaneously. The instrument has been designed to be capable of higher accuracy than existing instruments and yet to be simple to operate and moderate in construction cost. The instrument is thermed a ‘cone calorimeter’ because of the geometric arrangement of the electric heater.
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    Fire and Materials 8 (1984), S. 96-104 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: ‘Normalized heat load’ is a quantifier of the destructive potential of fires, real-world compartment fires and test fires alike. For real-world fires it is subject to some uncertainties owing to the random nature of two of the variables it depends on: ventilation and fire load. For test fires also it is subject to uncertainties owing to a moderate degree of randomness that characterizes the results of test fires. A procedure is described for predicting the failure probability in fire of the boundaries of a compartment designed for fire resistance on the basis of information concerning the characteristics of the compartment and the design value of the fire load. The procedure is essentially deterministic, employing statistical considerations only as far as required by the nature of some of the input variables. With the aid of second-moment analysis, it is possible, furthermore, to design the compartment boundaries for appropriate target failure probabilities.
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    Fire and Materials 8 (1984), S. 105-111 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An interactive computer program for simulating the early fire growth in an enclosure is described. The enclosure is assumed to be divided into distinct homogeneous zones. The rate of heat release is defined for the fire and the conservation equations are solved for the zones, yielding the temperature and radiant heat conditions in the fire room. The purpose of the work was to develop a computer program to be used by people working with fire engineering applications and having little experience in computer calculations. The user converses with the program via a terminal connected to the computer. The dialogue is governed by commands adapted to the concepts of the user. Results of the computer model are compared with measured data of the burning of wood and plastic cribs in an enclosure, showing a good agreement between measured and calculated results.
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    Fire and Materials 8 (1984), S. 113-124 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The general nature of fire problems on energy-conservative passenger trains is described, including a description of vehicle structures and lightweight design. Effects of high energy demand, tunnels and high maximum speeds on fire safety are outlined. The considerations used in design analysis are described, beginning with the development of a ‘worst-case fire scenario’. Typical combustible materials are considered and some of the reasons for choices are given. Notes on cavity and chimney effects emphasize the importance of clear objectives. Structural fire resistance is examined, and the basis of conventional recommendations analysed. The application of British Standard 6336 guidelines on fire tests and hazard assessment is examined. Limitation of fire load density is described, and some problems of calorific value determination outlined. Sources of ignition and hazards from passengers are defined. Flammability and flame-spread control are discussed, and rate of heat release is referred to in the context of fire behaviour. Problems of passenger escape linked to flashover, smoke and combustion gases are dealt with briefly.
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    Fire and Materials 8 (1984), S. 137-147 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Measurements of the limits of flaming and smoldering combustion and relative rates of burning under elevated temperatures and oxygen-depleted conditions have been used to characterize the fire behaviour of polymeric materials using a semi-empicical approach (based on scientific theory) in terms of Power Law Indices. The work was based on modified current tests; namely the Limiting Oxygen Index (ASTM D2863) at elevated temperatures and the Setchkin Flash and Self-Ignition Test (ASTM D1929) modified to operate in oxygen-depleted atmospheres and to record rate of weight loss. Results show that the relative flammability and rate of burning of materials can change markedly with fire environment, and confirms the need to test materials lunder conditions representative of those of the anticipated end-use hazard.
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    Fire and Materials 8 (1984), S. 224-226 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The vague meaning of the word ‘burning’ has long created communication difficulties among fire scientists, and has to unwarranted conclusions. It is suggested that the word ‘burning’ be used as an umbrella term, covering up to three dissimilar types of reactions: pyrolysis or gasification, (gas-phase) combustion, and char-oxidation.
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    Fire and Materials 8 (1984), S. 206-216 
    ISSN: 0308-0501
    Keywords: building materials ; fire tests ; heat release rate ; oxygen consumption ; spectral energy distribution ; weight measurement ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Equipment has been developed for measuring the rate of heat release from building materials in an open test arrangement. The method is based on an oxygen consumption technique. A vertical sample is placed under an open hood in which the combustion gases and a certain amount of air are collected. The decrease in oxygen concentration and the mass flow of the gases are measured in the exhaust duct. The rate of heat release is then calculated. The equipment has been calibrated with good agreement between input and measured effects. The total response time for the system is 10s. The method has been used for testing building materials at radiation intensities up to 5W Cm-2. It is able to distinguish between different board materials, and the repeatability is good, The paper describes the equipment, including the weighing of a burning sample and the selection of test condition. Smoke and gas analysis can be added when desirable. Some test results with building materials are also presented.
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  • 56
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    Fire and Materials 21 (1997), S. 7-16 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The modelling of the spread of fire and its extinguishment still represents a significant challenge. As part of a combined experimental and computational study of fires we have developed a general Computational Fluid Dynamics (CFD) model of fire spread and extinguishment. The primary objective was to produce a flexible computational tool which can be used by engineers and scientists for design or research purposes. The present paper deals with the description and validation of a solid pyrolysis model which has been applied, as a sub-model, in this general computer fire code. The pyrolysis model has been formulated using the heat-balance integral method. The model can be applied to slabs of char forming solids, such as wood, as well as non-charring thermoplastic materials, such as PMMA. Results are compared with analytical solutions, numerical simulations and experimental data. In all cases the integral model performs well. © 1997 by John Wiley & Sons, Ltd.
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  • 57
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    Fire and Materials 21 (1997), S. 17-22 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation of cone calorimeter test procedures was performed using two types of mattress composites with various specimen preparations and equipment configurations. The objective was to discover suitable procedures for testing mattress composites. Concurrent with this work a much larger and more sophisticated project known as CBUF was underway in Europe. One of CBUF's secondary objectives was to provide an appropriate test protocol for testing upholstered furniture composites, including mattresses. Most of the CBUF protocol was available at the time of this study and a modified form of the specimen preparation technique was used in this investigation. Preliminary tests found unacceptable test performance with some configurations. Subsequent testing examined variations of the established test protocols and other test procedures. The data sample was small, but observations of the data indicate trends that might be attributable to the use of the different procedures. Significantly it was determined that the edge frame used to hold specimens in place during the test does affect the test results. A modified CBUF protocol proved to be the best procedure, but it requires extensive experience with the CBUF specimen preparation method in order to be able to produce satisfactory specimens. © 1997 by John Wiley & Sons, Ltd.
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  • 58
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    Fire and Materials 21 (1997), S. 1-6 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of melting behaviour on upward flame spread of thermoplastic materials when subjected to small ignition sources and considered to suffer no external flux was studied using large-scale tests. For moderate fire conditions the cone calorimeter was utilized, with the sample set in a vertical orientation to study the melting behaviour of the specimens. Under these conditions the results indicate that the melting behaviour significantly affects upward flame spread behaviour. A pool of the melt which formed at the base of the vertically oriented sample tested creates a pool fire which then controls the fire growth and flame spread. In contrast, it was found that some thermoplastic materials which have higher glass transition temperatures or undergo a special pyrolysis process such as depolymerization, intumescing or charring do not experience significant melting behaviour when exposed to the same thermal insult. As a result, they behave very differently in terms of upward flame spread. The study also indicates that the melting behaviour of thermoplastic materials is an important characteristic in fires which should be taken into account in the development of modelling, in particular for upward flame spread models. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 51-51 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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  • 60
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    Fire and Materials 21 (1997), S. 33-39 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of 37 cigarettes were analysed to develop a model, based on cigarette physical properties, to predict the ignition propensity of the cigarettes towards cellulosic fabrics. The properties used were: cigarette circumference (in mm), tobacco packing density (in g cm-2), paper permeability (in CORESTA units) and the presence or absence of citrate additives in the paper (used independent of concentration, although typical additions range from 0.5 to 0.8 wt%). Two empirical models were developed, one for low and medium paper permeabilities, and one for very high paper permeabilities (above 50 CORESTA units). The latter exceed the paper permeability of most commercial cigarettes, and have medium to high ignition propensities. Thus, they are probably only of interest from the point of view of a mathematical curiosity. The former model, however, addresses cigarettes in the range where commercial cigarettes are potentially viable. The resulting ignition propensities exhibited cover the entire feasible range, from 0% to 100%. Both models predicted the ignition propensities of the tested cigarettes quite well, within an error range which did not exceed 30% for any cigarette. Physical rationales are presented for the effects of the variables used. However, the rationale for the discontinuity in ignition propensity found for the cigarettes with extremely high paper permeability is less clear. One explanation is that there is probably excess oxygen present so that a fuel/oxygen mixture is obtained with a ratio which is less than the lower flammability limits and is too lean to support combustion. However, further analysis of this issue is warranted. The empirical model for low and medium paper permeability cigarettes is potentially useful for developing cigarettes with lower ignition propensity, since it is a practical way of combining the individual properties that most heavily affect cigarette ignition propensity. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 53-65 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire hazard assessments must be primarily driven by life safety variables. Concern is often highly focused on toxicity issues, since fire deaths, in the majority of cases, are found (in whole or in part) to be due to toxic gas inhalation. Procedures have recently been published by ISO, wherein the toxicity assessment of fire products is focused primarily on bench-scale testing for toxic potency (the ‘per-gram toxicity’). Yet hazards of products with regards to fire toxicity may be determined much more by their differences in burning rates than by any differences in toxic potency. Burning rates are not assessed in the pertinent standards (ISO 13344 and ISO TR 9122). For most product categories, techniques for predicting full-scale burning rates from bench-scale data are not yet in hand. Thus, today the best means of comparing actual, full-scale toxic fire hazards is the full-scale fire test, equipped with additional gas measuring instrumentation. Such an approach is not among the recommended methods of the international standards, yet it is the only one with innate validity. In the present work, a series of sandwich panel products were tested in a full-scale room configuration. Bench-scale comparison was made to the ISO 5660 Cone Calorimeter and the DIN 53436 tube furnace. The toxic gases were quantified in all cases by chemical analysis. The product which showed the best performance in the full-scale tests (rock wool insulated sandwich panel) did not achieve a good fire toxicity performance due to minimization of toxic potency. Instead, the successful performance was attributed wholly to reduction of burning rate. Bench-scale measurements of toxic potency were shown to lack relevance to reality in such cases where even the full-scale toxic potency is not a determining factor. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 179-185 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Zinc hydroxystannate (ZHS), at levels of 2-5 phr, and the hydrated fillers, magnesium hydroxide (MH) and alumina trihydrate (ATH), at levels of 20-50 phr, are effective flame retardants and smoke suppressants for flexible PVC. Novel ZHS-coated hydrated fillers are found to exhibit markedly improved fire-retardant properties, particularly with regard to increasing LOI values, reducing heat release rates and suppressing smoke generation, when compared with conventional uncoated forms. The ZHS coating appears to change the filler particle morphology and there is evidence that the coating is largely retained on the filler surface after melt processing into the PVC. The improved dispersion of the active tin compound in the polymer matrix leads to enhanced fire retardancy and this, in turn, allows significant reductions to be made in overall filler loading, with no loss in flame-retardant or smoke-suppressant performance. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 95-105 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the EC-sponsored CBUF (Combustion Behaviour of Upholstered Furniture) study three different models were developed for using Cone Calorimeter results to predict full-scale furniture burning. Model I is a correlation-based approach and has the most comprehensive coverage of styles and furniture types. Model II is based on area-convolution. It has been developed, so far, for several of the common upholstered furniture styles. Model III is based on an extension of a thermal flame spread model and is here developed only for mattresses. Models II and III offer the prediction of the burning item's time history, while Model I computes the peak HRR, the time to peak, and several other primary characteristics. The predictability of all three models is good. At present, the models presented do not consider furniture with plastic frames, and only a limited predictability is offered for office-type furnitures items which contain a hard-plastic shell. The models offer a very significant improvement over the existing state of the art. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 277-282 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A correlation has been developed between closed-cup flash points and normal boiling points for silicone compounds. In addition, a more general correlation has been developed between these two properties for the general organic compounds, including silicone compounds. The closed-cup flash points can be predicted using empirical equations. The standard errors of estimate are 11.06 and 11.66°C for silicone compounds and general organic compounds (including silicone compounds), respectively. © 1997 John Wiley & Sons, Ltd.
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  • 65
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    Notes: The incorporation of two brominated compounds/antimony trioxide blends into a PP-PE copolymer were studied. Both brominated trimethylphenyl indane (FR 1808) and poly(pentabromobenzyl acrylate) (FR 1025) confer good flame retardancy at 40% loading. A comparison was made with the incorporation of magnesium hydroxide at higher loadings (up to 64%) in the same copolymer. The mineral filler improves both fire resistance and stiffness of the copolymer, nevertheless the high loading causes a dramatic decrease in impact resistance. Moreover, the necessary surface treatment of the filler significantly lowers the maximal tensile strength. In order to maximize both fire resistance and mechanical properties, we combined each brominated flame-retardant system (20% in weight) with magnesium hydroxide or talc (20% in weight). Talc is used as reference. These composites show interesting fire-retardant properties in comparison with the copolymers containing only 40% of the brominated flame-retardant systems. In addition, the mechanical properties are on the whole improved. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 271-276 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results are presented of a project to evaluate the combustibility and surface flammability of building interior finish materials commonly used in Taiwan. The project was conducted at the Fire Laboratory of the Architecture and Building Research Institute in Taipei. Eighteen different wall-covering materials were tested according to Chinese National Standard (CNS) 6532, which is equivalent to Japanese Industry Standard (JIS) 1321, and according to ASTM E 1354-92 (Cone calorimeter). A comparison of test results is presented, and a qualitative relationship is developed between the performance in the two methods. The classification system for degrees of combustibility developed in Canada by Richardson and Brooks was hereby used to group materials based in performance in the ASTM test method. © 1997 John Wiley & Sons, Ltd.
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  • 67
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    Fire and Materials 2 (1978), S. 184-184 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 2 (1978), S. 173-176 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Various celloulosic materials were evaluated for ignitability and flash-fire propensity, using screening test methods developed at the University of San Francisco. Time to ignition, using radiation from a high-temperature radiant source without a pilot flame, appeared to be primarily a function of heat flux and material density, rather than of type of wood or celloulosic board. At heat flux levels from 5.8 to 10.5 W cm-2, time to ignition was shortest for cellulose fiberboard with a density of 0.2225 g ml-1, followed by western red cedar at 0.314 g ml-1, eastern white pine at 0.348 g ml-1, southern yellow pine at 0.422 g ml-1, Douglas fir at 0.565 g ml -1, and longest for hardboard at 0.878 g ml-1. For the cotton and rayon woven-pile upholstery fabrics, time to ignition appeared to increase with increasing fabric weight.For Cellulose insulation treated with boron-containing additives, flash-fire magnitude decreased with increasing additive content. Flash-fire magnitude decreased more that could be accounted for by decreasing weight loss alone, indication reduction in the combustibility of the volatiles produced. Reduction in flash-fire propensity of cotton bating by treatment with boron-containing additives was also observed.
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  • 69
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    Notes: The Australian Children's Nightwear Standards have been accepted as the basis of legislation in all States of Australia and by the Commonwealth Government. The standards are based on the philosophy that garment design as well as combustion characteristics of the material is an important consideration in assessing the fire hazard of nightwear. Using this approach a classification system has been devised which place children's nightwear into three categories of potential fire hazard. If a garment cannot be classified then it cannot be legally sold in Australia. The combustion characteristics tested are ease of ignition, rate of flame propagation and surface burn properties. For classification all materials used for children's nightwear must pass the latter test. The design of the standard test methods, criteria for classification and the concepts of safe design were developed by collection data from burns accidents and burnt clothing from accident victims from the burns research unit of a large children's hospital and by the study of the burning behavior of clothing on a manikin. The combustion criteria are not so stringent as to require the use of inherently flame resist materials or the use of flame retardant finishes. This approach in combination with safe design criterial enable commercially available textiles to meet the legislative requirements for children's nightwear. This mean that the nightwear standards are inexpensive to attain and do not require a sophisticated textile technology. A consumer labeling system has been designed to describe the three categories but yet there is no evidence to suggest that this had had any effect in reducing the number of burns accidents - consumers apparently regrading safe nightwear as a low priority. An inconsistent aspect of the calssification system is the incorporation into the standards in 1977 of criteria to prevent the classification of cotton flannelette nightdresses and the incorporation of arbitrary requirements for other nightdress containing cotton. These inconsistencies have been caused fundamentally by a problem which continues to bedevil the writing of good standards in Australia - that is, the lack of nationwide statistics on burns accidents.
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    Fire and Materials 2 (1978), S. 177-183 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A Collaborative Programme of work was carried out by two laboratories to asscess a procedure for identifying paint systems which possess poor ‘in service’ lives by virtue of being repeatedly washed. The small scale surface spread of flame apparatus as described in BS 476 part 7 was used to measure any change in the surface spread of flame characteristic of eight coating system, applied to two substrates, as a result of washing the coated surfaces. The results indicate that both laboratories ranked the paints in the same order and the reproducibility of the proposed washing procedure was good. The most consistent results were obtained when the coating systems were applied to standard hardboard. It is suggested that flame retardant coating system having poor resistance to washing would be identified if a limit of changes of average spread of flame were set at 75 mm. This investigation was carried out in support of the activities of BSI committee PVC/12, Fire Retardant Paints.
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    Fire and Materials 2 (1978), S. iii 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 72
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    Fire and Materials 7 (1983) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 7 (1983), S. 1-24 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This review concerns the mathematical modeling of fire phenomena. The fire is treated as a head and mass source driving a fluid flow process. Combustion is not included. It deals in detail with the field modeling approach incorporating the effects of turbulence, strong buoyancy and variable density on the transport of momentum, heat and mass. For the sake of simplicity, other effects such as those due to the interactions of the above mechanisms with the wall, radiation, etc., which may be crucial to the dynamics of the fire phenomenon, are not dealt with in this review. These effects will be the subject of future work.
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    Fire and Materials 7 (1983), S. 25-31 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Studies have been made of the influence on smoke generation from polystyrene of the incorporation of a number of apparently inert solids, the smoke-producing tendency being expressed in terms of the maximum specific optical density of smoke per unit weight of polymer consumed. Of the compounds investigated, by far the most efficient smoke suppressant is pyrogenic silica, the effect of which is, over a wide range, directly proportional to the total surface area of the material introduced. Examination of partially burned polystyrene-pyrogenic silica composites reveals the presence at the surface of a hard rigid skin, which is not observer with polystyrene alone of with polymer samples containing other additives. The formation of a protective skin is also indicated by the kinetics of forced burning of these composites where the weight loss is a linear function of log time and by measurements of the rate of change of thickness of polymer samples during combustion. Thermogravimetric experiments in which polystyrene and pyrogenic silica are heated in contact with one another show that the silica encourages the formation of a carbon residue from the polymer. A mechanism of skin production is proposed which involves the build-up of layers of tangential spherical silica particles cemented together by cross-linked polystyrene.
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    Fire and Materials 7 (1983), S. 32-37 
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    Notes: Raman scattering is a possible technique for analysing gas mixtures. In the work here described Raman scattering was used for detection of gases extracted from different model fires, where wood, polymethylmetachrylate (PMMA) and polystyrene were used as test materials. Raman spectra of gas samples from differently ventilated model fires are presented as well as the variation of O2, CO2 and CO concentrations as a function of time with an effective time constant of less than 5 s. The sensitivity of the experimental set-up was estimated to be about 1000 ppm, but suggestions are given how to reach a detection limit of about 1 ppm. The feasibility of the technique and various ways of improving it are briefly discussed.
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    Fire and Materials 7 (1983) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fire and Materials 7 (1983), S. 49-61 
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    Notes: Fourteen mathematical models of post-flashover compartment fires are classified on the basis of fourteen principal modeling aspects. Expressions are presented for the potential of fire to spread by destruction and convection. The assessment of the fire resistance requirements for the compartment boundaries is discussed and measures to counter the potential of fires to spread by convection are outlined.
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    Fire and Materials 7 (1983), S. 41-48 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study has been made of the effect of molybdenum trioxide on the thermal degradation of a series of chlorinated and brominated polyester thermosets. Like antimony oxide, it showed flame retardant activity in all the halogenated polyesters. It was shown to affect the char yield, and the temperature and weight loss of each degradation step. X-Ray diffraction studies of the degraded dibromoneopentyl glycol polyesters showed that in air a near-quantitative yield of molybdenum trioxide was present above 550 °C. Some dioxide was present before the final char oxidation step occurred. In a nitrogen atmoshphere the trioxide was reduced to the dioxide at first, but this finally reacted to give the carbide at around 900 °C. Infrared spectroscopy showed that inclusion of the molybdenum trioxide resulted in structural changes in the high-temperature polyester residues which were more prominent when bromine was present. Elemental analysis of the residues indicated that the presence of the trioxide in the brominated polyesters accelerated the release of bromine at high temperatures and confirmed its char-promoting tendencies.
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    Fire and Materials 7 (1983), S. 62-66 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The conversion of fuel-N species to NOx in diffusion flames has been studied by adding acetonitrile to the fuel flow for a methane-Oxygen-argon diffusion flame burning in excess oxygen. It is shown that the conversion is significantly lower than that obtained in a ‘corresponding’ pre-mixed flame, although the observed concentrations of NOx are still much higher than the appropriate thermodynamic equilibrium concentrations. The effect of initial concentration of acetonitrile, flame temperature and amount of excess oxygen on the conversion can all be explained in terms of the basic structure of a diffusion flame. This enables molecular nitrogen to be formed in the reducing atmosphere which exists on the fuel side of the flame through reaction of cyanide radicals with nitric oxide. The latter diffuses back from the oxygen side of the flame where it is formed, but the overall result is that a proportion of the fuel-N is converted to molecular nitrogen before it can be converted to nitric oxide.
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  • 80
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    Fire and Materials 7 (1983), S. 73-78 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Two models of creep, one proposed by Harmathy1, the other empirical, have been fitted to published measurements of creep in seven steels. The data have been selected so as to cover the range needed for predicting the survival of protected steel or reinforced concrete buildings exposed to fire.
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  • 81
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    Fire and Materials 7 (1983), S. 67-72 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of fire deaths in the Glasgow area has been extended to the rest of the United Kingdom in order to assess the applicability of the conclusions reached in the Glasgow study to the whole country. With assistance from pathologists in a number of other areas, 71 cases were included in the study, covering both pathology and toxicology of the deaths where possible. In both the Glasgow and UK studies, most of the fire deaths occurred in dwelling-house fires. These and other demographic characteristics were in agreement with national fire statistics. The principal features of pathology in this study were burns (79 per cent of cases), respiratory system injury (72 per cent of cases) and soot deposition in the respiratory tract (96 per cent of cases), and these reflected a similar incidence in Glasgow study. Carbon monoxide was considered to be the cause of death in 51 per cent of the deaths in this study and to be implicated in the death of 37 per cent of the other cases (54 per cent and 31 per cent respectively in Glasgow). Cyanide was estimated to be a significant factor in 33 per cent of the deaths in the UK study (24 per cent in Glasgow). Alcoholic intoxication was found to be a significant additional factor in Glasgow but was much less prominent in the other areas of the UK. It concluded that, with the exception of alcohol, the results of the Glasgow study are valid for the UK as a whole.
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  • 82
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    Fire and Materials 7 (1983), S. 96-97 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 83
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    Fire and Materials 7 (1983), S. 98-99 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 84
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    Fire and Materials 7 (1983), S. 89-95 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reviews the current literature on the behaviour of thermoset polymers under fire conditions. These polymers are important and widely used materials. They are generally infusible and insoluble, and consist, on the molecular scale, of extensive cross-linked networks rather than discrete macromolecules. Materials in this class include phenol-formaldehydes, epoxides, cross-linked polyester, amino resins and polyurethanes. As the use of plastics generally has grown, so there have been changes in the conditions prevailing in modern fires, and such changes are described, together with the potential fire hazards arising from the varying uses of the individual thermosets. Subsequently, literature on the pyrolytic and combustion characteristics of these materials is reviewed in order to assess their probable behaviour in real fires. Finally, existing approaches towards improving their fire behaviour are described.
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  • 85
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    Fire and Materials 7 (1983), S. 79-88 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There are two major fire processes, an understanding of which is essential for effective fire safety design: (1) the conditions under which a combustible material may become involved in flaming combustion, and (2) the rate at which such a material, once involved, will provide an output of heat, smoke, toxic gases, etc., which can endanger people and property. The first process may be regarded as covering both ignition and spread of fire on materials; its complement is the way in which fire may become extinguished. It is necessary for such processes to bring in a characteristic of the basic combustion reaction which, directly or indirectly, expresses the reactivity of the combustion process. Thus pilot ignition is usually associated with an approximate surface fuel temperature. More basically, it is associated with a critical flow rate of volatiles and a critical heat loss from the flame, the latter being influenced by ambient oxygen and temperatures conditions as well as heat lost and gained by the fuel itself. The most important factor governing the production of dangerous product is the rate at which volatiles first (fuel controlled fires) and later air (air controlled fires) are fed into the flames. The reactivity is of less importance, although it may be one of the factors which control combustion efficiency. In general, the more efficient is the combustion the more heat is produced, but the less smoke and toxic gases are produced. Some of the main advances in the above areas are reviewed in this paper.
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  • 86
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    Fire and Materials 7 (1983) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 87
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    Fire and Materials 7 (1983), S. 99-99 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 88
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    Fire and Materials 7 (1983), S. 101-110 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The smoke propensity of plastics as measured in the NBS Smoke Chamber method has been rationalized in terms of the influence of specimen thickness and resolved in a relation between mass optical density (MOD) and mass loss, which gives two parameters for characterizing behaviour, a maximum MOD for thin specimens and an asymptotic MOD for thicker ones. Data have been obtained for unplasticized piolyvinylchloride formulations and compared to that obtained by the Arapahoe Smoke Chamber and the Australian Standard method (AS 1530 Part 3). Although correlation coefficients between the methods were generally poor, the same formulations were ranked as the best performers in each method and the improvement over a standard formulation was potentially important in terms of wider acceptance under Australian building regulations.
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    Fire and Materials 7 (1983), S. i 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 90
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    Fire and Materials 7 (1983), S. 163-168 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A test chamber for performing complete investigation of the dangerous effects of thermal degradation products of polymeric materials has been designed. The tow-chamber system with separated combustion chamber and smoke chamber has a steep temperature gradient between both chambers and enables continuous analysis of combustion products of the tested polymeric material for carbon monoxide and carbon dioxide to be performed, to monitor the oxygen content in the chamber during testing and to perform tests of biological toxicity on mice as test animals. The function of the test chamber was verified on combustion of polyethylene, polypropylene, polystyrene and polyamide samples.
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  • 91
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    Fire and Materials 7 (1983), S. 169-172 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A chamber has been designed which allows total assessment of products formed during the thermal stressing of polymer material samples. The chamber is of oval shape and creates an infinite track for the movement of products formed in the course of the thermal degradation process. It allows the complete analysis of the products to be carried out to monitor the contents of the most important of them, to determine the oxygen content, to measure the optical density of smoke and to measure the temperature inside the chamber in the course of the experiment. The chamber was used for testing the combustion products of polyethylene, polypropylene, polystyrene and polyamide.
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  • 92
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    Fire and Materials 8 (1984), S. 196-198 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Small samples of poly(methyl methacrylate), red oak and possibly low-density polyethylene ignite under the influence of thermal radiation with a propensity that increases with the area irradiated, consistent with ignition requiring that the lower flammability limit of pyrolysis gases be reached. The time to self-extinction of small samples of charring, burning materials (low-density polyethylene, red oak and possibly polycarbonate) in the absence of external radiant flux increases with burning area, suggesting that the increased absorptivity of char increases the importance of radiative feedback.
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    Fire and Materials 8 (1984), S. 183-195 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The overall flammability hazard of Zirpro wool protective clothing, carpets and upholstery with regard to national and international standards is summarized. Protective clothing against heat and flames has to be evaluated not only for flame-retardance by a vertical flame test but also for heat transfer from convective (flames), radiant and conductive (molten metal) heat exposure to ensure a realistic assessment of the potential protective offered and required. Textile furnishings (carpets, upholstery, curtains) have to be evaluated for flame-retardance, heat release, smoke emission and toxicity of combustion products to assess the overall flammability hazard. Evaluation and consideration of only on e flammability parameter, e.g. toxicity of combustion products, can lead to misleading conclusions about the flammability hazard of a material.
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    Fire and Materials 8 (1984), S. 199-205 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The traditional methods used for the identification and assessment of hazards in the chemical industry are based on experience, but increased economic and environmental restrictions on its operations have required the development of other methods to ensure that an acceptable level of safety is maintained. The present paper briefly reviews the traditional methods, describes in mire detail the basis of the newer methods, namely hazard and operability studies and hazard analysis, and considers how they might be more widely used in assessing fire hazards.
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  • 95
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    Fire and Materials 8 (1984), S. 217-223 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A method of increasing the speed of measurement of surface temperature is described. This would possibly be suitable for improving the determination of temperature of the unexposed face of specimens subjected to a British 476 (part 8) fire-resistance test. A simple electronic circuit used in conjunction with a disc-mounted thermocouple allows ‘hot spots’ to be quickly identified. The technique may also find application in other similar standards such as ISO 834.
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  • 96
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    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Silica gel combined with potassium carbonate is an effective fire retardant for a wide variety of common polymers (at mass fraction of only 10% total additive) such as polypropylene, nylon, polymethylmethacrylate, poly(vinyl alcohol), cellulose, and to a lesser extent polystyrene and styrene-acrylonitrile. The peak heat release rate is reduced by up to 68% without significantly increasing the smoke or carbon monoxide levels during the combustion. © 1997 by John Wiley & Sons, Ltd.
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  • 97
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    Fire and Materials 21 (1997), S. 41-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Flame-retarded epoxy composites and phenolic composites containing fiberglass, aramid (Kevlar® 49), and graphite fiber-reinforcements were tested using the NASA upward flame propagation test, the controlled-atmosphere cone calorimeter test, and the liquid oxygen (LOX) mechanical impact test. The upward flame propagation test showed that phenolic/graphite had the highest flame resistance and epoxy/graphite had the lowest flame resistance. The controlled-atmosphere cone calorimeter was used to investigate the effect of oxygen concentration and fiber reinforcement on the burning behavior of composites. The LOX mechanical impact test showed that epoxy/fiberglass had the lowest ignition resistance and phenolic/aramid had the highest ignition resistance in LOX. The composites containing epoxy resin and/or aramid fiber reinforcement reacted very violently in LOX upon mechanical impact. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 75-83 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Melamine and its salts added to polyamide 6 (PA-6, nylon 6) improve its fire retardancy as measured by oxygen index and UL94 tests. The mechanism of the fire-retardant action of the additives was studied using thermogravimetry, kinetics of thermal decomposition and characterization of solid residues and evolved high-boiling products. It was found that melamine, melamine oxalate, melamine phthalate and melamine cyanurate facilitate thermal decomposition of PA-6 with increasing evolution of oligomeric chain fragments instead of caprolactam, which is the principal product evolved from the nonfire-retarded PA-6. These additives promote non-combustible flow dripping and help extinguishment of the flame. The observed increase in solid residue from the thermal decomposition of the formulations or the endothermic cooling due to melamine evaporation might give an additional but less important contribution to fire retardancy. In the case of dimelamine phosphate and melamine pyrophosphate, PA-6 reacts with liberated phosphoric acids producing phosphoric esters which give char upon further thermal decomposition. The fire-retardant effect of these two salts is mostly attributed to polymer mass retention and intumescent layer protection mechanisms. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 107-114 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The National Building Code of Canada provides architects, engineers and builders with a simple, practical calculation method for assigning fire-resistance ratings to wood-frame and steel-frame wall, floor and roof-ceiling assemblies. It was originally devised in the early 1960s and is commonly known as the Component Additive Method (CAM). A collaborative industry-government research program was carried out recently at the National Research Council Canada to develop new fire-resistance ratings for gypsum-board protected walls. Forintek Canada Corp. and the Canadian Wood Council participated in that program on behalf of Canada's wood industry. As part of the research program, a number of full-size fire-endurance tests were carried out on wood-frame and steel-frame walls. The results of those fire tests have allowed us to revisit those sections of the Component Additive Method which are applicable to light-frame walls lined with gypsum board. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 115-121 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Tests were conducted on two fabrics intended for use in protective clothing: an aramid (used extensively in firefighter gear) and a modified viscose cellulosic fabric. Both were exposed to very high heat (temperatures above 400°C) and their performance as thermal insulators was assessed by the temperature transmitted through the fabric, both in their dry state and after being exposed to a water spray. Both fabrics performed satisfactorily, but the modified viscose fabric improved its thermal insulation properties when damp, while the aramid fabric remained unaffected (or perhaps negatively affected) by the water spray. Overall, the modified viscose fabric seemed a better thermal insulator than the aramid. © 1997 John Wiley & Sons, Ltd.
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