ALBERT

Beschreibung / Inhaltsverzeichnis: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Beschreibung / Inhaltsverzeichnis: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Beschreibung / Inhaltsverzeichnis: This study investigates the possibility of providing estimates of the time of occurrence and length of the freezing season for any location in East and West Germany by using the average Januavy air temperature (AJ AT) as an index. The results indicate that reliable values of the mean freezing index can be obtained from the AJAT relationships which are developed for Germany. This association is further verified using data from the northeastern part of the U.S., and the AJ AT is then used to determine the average starting and ending dates (and hence the probable length) of the freezing season for stations in Germany. The AJ AT and the average dates of snowfall occurrence for numerous locations in the U.S. and Germany are also correlated. Interrelationships between these parameters and the average number of days with snow on the ground for stations up to 3000 m in elevation in Germany are examined. A detailed AJ AT map for East and West Germany, in which data from 134 stations, latitude, altitude and regional influences are considered, is developed in order to make the relationships usable. A historical review of the literature on snow studies in Germany and a brief discussion of snow-cover interpretation by satellite photography are included

Beschreibung / Inhaltsverzeichnis: The compressibility of wet snow is described in terms of pressure melting and nonlinear viscous deformation at grain contacts. The results of experiments with different salinities and liquid water contents are compared with computed densities. The decreasing compressibility of wet snow with increasing salinity and decreasing liquid content is quantified and explained. Simultaneous particle growth and the doubly charged layer at phase boundaries are included in the model. The results show that the density of wet snow increases approximately as a power of time but is highly dependent on the stress, initial particle size, liquid water content, and ionic impurity content of the snow.

Beschreibung / Inhaltsverzeichnis: A model investigation of drifting snow conditions was conducted in a hydraulic flume using a sand-water analog. Model results were evaluated to define modeling parameters that would allow quantitative correlation between measured prototype drift conditions and the model. The modeled structure was the standard plan snow fence designed by the Wyoming Highway Department and installed along Interstate Highway 80 in 1971. The performance of this system was documented by the Rocky Mountain Forest and Range Experiment Station of the U.S. Forest Service. Models of the fence were constructed for three heights and two geometric scales. Geometric scaling was based on terrain roughness and boundary layer thickness considerations, while velocity scaling was based on particle fall velocity and threshold of motion characteristics. Simulation of the atmospheric boundary layer was found to be of primary importance. Velocity scaling analysis suggested the use of a 'significant wind' concept based on a combination of velocity magnitude and frequency. Similarity of precipitation rate was not essential, and could be altered within limits to adjust the time scale. The response of the model to the shape of model elements was significant. Although the model is distorted and inexact similarity is achieved, it appears useful on a practical basis.

Beschreibung / Inhaltsverzeichnis: This report first discusses the general approach for calculating the horizontal forces an ice cover exerts on a structure. Ice force determination consists of two parts: (1) the analysis of the in-plane forces assuming that the ice cover remains intact and (2) the use of a failure criterion, since an ice force cannot be larger than the force capable of breaking up the ice cover. For an estimate of the largest ice force, an elastic plate analysis and a failure criterion are often sufficient. A review of the literature revealed that, in the majority of the analyses, it is assumed that the failure load is directly related to a 'crushing strength' of the ice cover. However, observations in the field and tests in the laboratory show that in some instances the ice cover fails by buckling. This report reviews the ice force analyses based on the buckling failure mechanism and points out their shortcomings. The report then presents a new method of analysis which is based on the buckling mechanism

Beschreibung / Inhaltsverzeichnis: The analytical solution and the numerical study of the eigenvalue problem for determining the buckling pressure of an infinite elastic plate floating on water and stressed uniformly along the periphery of an internal hole is presented. The boundary conditions considered are the clamped-, simple-, and free-edge conditions. Small buckling pressure occurs only for the free-edge condition. The shape of the deflection for the free-edge condition suggests that buckling is an important mechanism of failure.

Beschreibung / Inhaltsverzeichnis: Road test sections of membrane-enveloped silt and clay soils overlain with asphalt cement concrete were subjected to repetitive dynamic plate-bearing loadings to determine their strength variations during freeze-thaw cycles. The recoverable surface deformations in the load deflection bowl were continuously measured during the loading cycles and analyzed using the Chevron layered elastic computer program to obtain the in situ resilient deformation modulus of the various section layers at different stages of the freeze-thaw cycles. The resilient stiffness of the pavement system (the total load per unit of resilient load plate deflection) was also calculated for the various freeze-thaw conditions. The modulus values of the asphalt cement concrete varied inversely with its temperature by an order of magnetide (90,000 psi to 1,300,000 psi). The resilient stiffness of the pavement system varied in the same manner by nearly a factor of eight (228.4 kips/in. to 1740.2 kips/in.). Despite the wide strength variations of the sections during freeze-thaw cycles, membrane-enveloped fine-grained soils can be utilized instead of granular materials as base and subbase layers in flexible pavements in cold regions where moisture migration is a major concern. Moisture migration did not occur at saturation levels up to 75%, thus there was no strength loss during thawing.

Beschreibung / Inhaltsverzeichnis: Field observations of the growth fabrics of the fast and near-fast ice along the coasts of the Beaufort and Chukchi Seas show that, at depths of more than 60 cm below the upper ice surface, the sea ice crystals show striking alignments within the horizontal plane. At one site this alignment was well developed at a depth of 15 cm and in all cases the degree of preferred orientation increased with depth, with the strongest orientations occurring at the bottom of the ice sheet. In general the c-axes of the crystals were aligned roughly E-W parallel to the coast. In the vicinity of islands the alignment roughly paralleled the outlines of the islands and in narrow passes between islands the alignment paralleled the channel. Our observations, as well as similar observations made in the Kara Sea by Cherepanov, can be explained if it is assumed that the c-axes of the crystals are aligned parallel to the 'long-term' current direction at the sea ice/sea water interface. The alignments are believed to be the result of geometric selection among the growing crystals, with the most favored orientation being that in which the current flows normal to the (0001) plates of ice that make up the dendritic ice/water interface characteristics of sea ice. It is hypothesized that current flow in this direction reduces the thickness of the solute boundary layer as well as the salinity in the liquid at the interface. This lowered salinity allows crystals in the favored orientation to extend farther into the melt than neighboring crystals with less favored orientations. In addition the current tends to induce a continuous flux of supercooled seawater against the sides of the crystals that extend ahead of the interface.

Beschreibung / Inhaltsverzeichnis: Special environmental factors that influence the design, laying and maintenance of undersea pipelines and cables in polar waters are described. Various approaches to the protection of submarine pipes and cables are considered, and prime emphasis is given to burial techniques for shallow water. A wide range of methods for trenching and burying are discussed, and technical data are given.