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  • Articles  (8)
  • Other Sources  (14)
  • Geochemistry
  • Laboratory measurements
  • American Geophysical Union  (18)
  • Kluwer  (4)
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  • Articles  (8)
  • Other Sources  (14)
  • 1
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in German, C., Baumberger, T., Lilley, M., Lupton, J., Noble, A., Saito, M., Thurber, A., & Blackman, D. Hydrothermal exploration of the southern Chile Rise: sediment‐hosted venting at the Chile Triple Junction. Geochemistry Geophysics Geosystems, 23(3), (2022): e2021GC010317, https://doi.org/10.1029/2021gc010317.
    Description: We report results from a hydrothermal plume survey along the southernmost Chile Rise from the Guamblin Fracture Zone to the Chile Triple Junction (CTJ) encompassing two segments (93 km cumulative length) of intermediate spreading-rate mid-ocean ridge axis. Our approach used in situ water column sensing (CTD, optical clarity, redox disequilibrium) coupled with sampling for shipboard and shore based geochemical analyses (δ3He, CH4, total dissolvable iron (TDFe) and manganese, (TDMn)) to explore for evidence of seafloor hydrothermal venting. Across the entire survey, the only location at which evidence for submarine venting was detected was at the southernmost limit to the survey. There, the source of a dispersing hydrothermal plume was located at 46°16.5’S, 75°47.9’W, coincident with the CTJ itself. The plume exhibits anomalies in both δ3He and dissolved CH4 but no enrichments in TDFe or TDMn beyond what can be attributed to resuspension of sediments covering the seafloor where the ridge intersects the Chile margin. These results are indicative of sediment-hosted venting at the CTJ.
    Description: We acknowledge University of California Ship Funds for their support of that shiptime and the NOAA Ocean Exploration and Research Grant NA08OAR4600757 which supported the research presented here. Finally, we thank two anonymous reviewers whose important contributions helped to improve the final version of this paper. This is PMEL contribution number 5341.
    Keywords: Hydrothermal ; Geochemistry ; Chile Rise ; Chile Triple Junction ; Sediment hosted
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(4), (2021): e2020GB006895, https://doi.org/10.1029/2020GB006895.
    Description: The Amazon River drains a diverse tropical landscape greater than 6 million km2, culminating in the world's largest export of freshwater and dissolved constituents to the ocean. Here, we present dissolved organic carbon (DOC), organic and inorganic nitrogen (DON, DIN), orthophosphate (PO43−), and major and trace ion concentrations and fluxes from the Amazon River using 26 samples collected over three annual hydrographs. Concentrations and fluxes were predominantly controlled by the annual wet season flood pulse. Average DOC, DON, DIN, and PO43− fluxes (±1 s.d.) were 25.5 (±1.0), 1.14 (±0.05), 0.82 (±0.03), and 0.063 (±0.003) Tg yr−1, respectively. Chromophoric dissolved organic matter absorption (at 350 nm) was strongly correlated with DOC concentrations, resulting in a flux of 74.8 × 106 m−2 yr−1. DOC and DON concentrations positively correlated with discharge while nitrate + nitrite concentrations negatively correlated, suggesting mobilization and dilution responses, respectively. Ammonium, PO43−, and silica concentrations displayed chemostatic responses to discharge. Major and trace ion concentrations displayed clockwise hysteresis (except for chloride, sodium, and rubidium) and exhibited either dilution or chemostatic responses. The sources of weathered cations also displayed seasonality, with the highest proportion of carbonate- and silicate-derived cations occurring during peak and baseflow, respectively. Finally, our seasonally resolved weathering model resulted in an average CO2 consumption yield of (3.55 ± 0.11) × 105 mol CO2 km−2 yr−1. These results represent an updated and temporally refined quantification of dissolved fluxes that highlight the strong seasonality of export from the world's largest river and set a robust baseline against which to gauge future change.
    Description: This work was supported by a grant from the Harbourton Foundation to R. G. M. Spencer and R. M. Holmes. T. W. Drake was supported by ETH Zurich core funding to J. Six. R. G. M. Spencer was additionally supported by NSF OCE-1333157.
    Description: 2021-09-15
    Keywords: Amazon river ; Dissolved organic carbon ; Fluxes ; Weathering ; Geochemistry
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005414, doi:10.1029/2019JG005414.
    Description: A survey of 25 coastal‐draining rivers across the Canadian Arctic Archipelago (CAA) shows that these systems are distinct from the largest Arctic rivers that drain watersheds extending far south of the Arctic circle. Observations collected from 2014 to 2016 illustrate the influences of seasonal hydrology, bedrock geology, and landscape physiography on each river's inorganic geochemical characteristics. Summertime data show the impact of coincident gradients in lake cover and surficial geology on river geochemical signatures. In the north and central CAA, drainage basins are generally smaller, underlain by sedimentary bedrock, and their hydrology is driven by seasonal precipitation pulses that undergo little modification before they enter the coastal ocean. In the southern CAA, a high density of lakes stores water longer within the terrestrial system, permitting more modification of water isotope and geochemical characteristics. Annual time‐series observations from two CAA rivers reveal that their concentration‐discharge relationships differ compared with those of the largest Arctic rivers, suggesting that future projections of dissolved ion fluxes from CAA rivers to the Arctic Ocean may not be reliably made based on compositions of the largest Arctic rivers alone, and that rivers draining the CAA region will likely follow different trajectories of change under a warming climate. Understanding how these small, coastal‐draining river systems will respond to climate change is essential to fully evaluate the impact of changing freshwater inputs to the Arctic marine system.
    Description: This work was only possible through a network of enthusiastic and devoted collaborators. Partners included Polar Knowledge Canada and the Canadian High Arctic Research Station, the Arctic Research Foundation, the Kugluktuk Angoniatit Association, and the Canadian Arctic GEOTRACES Program. We acknowledge support from the Department of Fisheries and Oceans Canada, the Woods Hole Oceanographic Institution Coastal Ocean Institute, The G. Unger Vetlesen Foundation, Jane and James Orr, and the Woods Hole Research Center. Many thanks go to Austin Maniyogena, Angulalik Pedersen, Adrian Schimnowski, JS Moore, Les Harris, Oksana Schimnowski, as well as Barbara Adjun, Amanda Dumond, and Johnny Nivingalok, and the captains and crew of the research vessels CCGS Amundsen and R/V Martin Bergmann, all of whom supported our research and helped with sample collection. Special thanks also go to Valier Galy, Zhaohui “Aleck” Wang, Marty Davelaar, Michiyo Yamamoto‐Kawai, Hugh McLean, Mike Dempsey, Baba Pedersen, Maureen Soon, Katherine Hoering, Sean Sylva, Ekaterina Bulygina, and Anya Suslova for their invaluable contributions during field program planning, preparations, and laboratory analyses. Robert Max Holmes is thanked for many fruitful discussions. We also thank several anonymous reviewers for their helpful comments on the paper's content and structure. All of the data presented in this paper can be found at https://doi.org/10.1594/PANGAEA.908497.
    Keywords: Arctic Rivers ; Geochemistry ; Major ion chemistry ; Stable isotopes ; Northern hydrology
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 13 (2012): Q01008, doi:10.1029/2011GC003845.
    Description: We present a multiproxy geochemical analysis of two cores recovered from the Indus Shelf spanning the Early Holocene to Recent (〈14 ka). Indus-23 is located close to the modern Indus River, while Indus-10 is positioned ∼100 km further west. The Holocene transgression at Indus-10 was over a surface that was strongly weathered during the last glacial sea level lowstand. Lower Holocene sediments at Indus-10 have higher εNd values compared to those at the river mouth indicating some sediment supply from the Makran coast, either during the deposition or via reworking of older sediments outcropping on the shelf. Sediment transport from Makran occurred during transgressive intervals when sea level crossed the mid shelf. The sediment flux from non-Indus sources to Indus-10 peaked between 11 ka and 8 ka. A hiatus at Indus-23 from 8 ka until 1.3 ka indicates non-deposition or erosion of existing Indus Shelf sequences. Higher εNd values seen on the shelf compared to the delta imply reworking of older delta sediments in building Holocene clinoforms. Chemical Index of Alteration (CIA), Mg/Al and Sr isotopes are all affected by erosion of detrital carbonate, which reduced through the Holocene. K/Al data suggest that silicate weathering peaked ca. 4–6 ka and was higher at Indus-10 compared to Indus-23. Fine-grained sediments that make up the shelf have geochemical signatures that are different from the coarser grained bulk sediments measured in the delta plain. The Indus Shelf data highlight the complexity of reconstructing records of continental erosion and provenance in marine settings.
    Description: We thank NERC for funding this cruise and postcruise study. Award NSF-OCE 0623766 to LG also funded CP’s participation to the cruise and postcruise studies.
    Description: 2012-07-14
    Keywords: Arabian Sea ; Holocene paleoclimate ; Indus ; Geochemistry ; Neodymium and strontium isotopes
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 19 (2009): Q02001, doi:10.1029/2008GC002236.
    Description: Ocean intraplate volcanoes (OIVs) are formed in a sequence of stages, from large to small, that involve a systematic progression in mantle melting in terms of volumes and melt fractions with concomitant distinct mantle source signatures. The Hawaiian volcanoes are the best-known example of this type of evolution, even though they are extraordinarily large. We explore the Pb-Sr-Nd-Hf isotopic evolution of much smaller OIVs in the Fieberling-Guadalupe Seamount Trail (FGST) and small, near-ridge generated seamounts in the same region. In particular, we investigate whether we can extend the Hawaiian models to Jasper Seamount in the FGST, which displays three distinct volcanic stages. Each stage has characteristic variations in Pb-Sr-Nd-Hf isotopic composition and trace element enrichment that are remarkably similar to the systematics observed in Hawaii: (1) The most voluminous, basal “shield building” stage, the Flank Transitional Series (FTS), displays slightly isotopically enriched compositions compared to the common component C and the least enriched trace elements (143Nd/144Nd: 0.512866–0.512909, 206Pb/204Pb: 18.904–19.054; La/Sm: 3.71–4.82). (2) The younger and substantially less voluminous Flank Alkalic Series (FAS) is comparatively depleted in Sr, Nd, and Hf isotope compositions plotting on the side of C, near the least extreme values for the Austral Islands and St. Helena. Trace elements are highly enriched (143Nd/144Nd: 0.512912–0.512948, 206Pb/204Pb: 19.959–20.185; La/Sm: 9.24). (3) The Summit Alkalic Series (SAS) displays the most depleted Sr, Nd, and Hf isotope ratios and is very close in isotopic composition to the nearby near-ridge seamounts but with highly enriched trace elements (143Nd/144Nd: 0.512999–0.513050, 206Pb/204Pb: 19.080–19.237; La/Sm: 5.73–8.61). These data fit well with proposed multicomponent melting models for Hawaii, where source lithology controls melt productivity. We examine the effect of melting a source with dry peridotite, wet peridotite, and pyroxenite, calculating melt productivity functions with depth to evaluate the effect of potential temperature and lithospheric thickness. This type of melting model appears to explain the isotopic variation in a range of small to large OIVs, in particular for OIVs occurring far from the complicating effects of plate boundaries and continental crust, constraining their geodynamic origin.
    Description: JBT acknowledges financial support from the French Institut National des Sciences de l’Univers. The isotope work at SDSU was made possible by NSF and Keck grants to BBH.
    Keywords: Jasper Seamount ; Geochemistry ; Isotope ; Melting model
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2017-04-04
    Description: The 5 April 2003 explosive eruption at Stromboli emplaced typical basaltic scoria, pumice, and lithic blocks. This paper reports a detailed set of mineralogical, geochemical, and isotopic data on the juvenile ejecta and fresh subvolcanic blocks, including micro-Sr isotope analyses and major and dissolved volatile element contents in olivine-hosted melt inclusions. The juvenile ejecta have compositions similar to those of their analogs from previous paroxysms; the 2003 pumice, however, does not contain stable high-MgO olivine, usually typical of large-scale paroxysms and has lower compatible element contents. Texture, composition, and Sr isotope disequilibrium of crystals in pumice indicate that most of them are inherited from the shallow crystal-rich magma and/or crystal mush. The most primitive magma is recorded as rare melt inclusion in olivine Fo85–86. It has a typical S/Cl (1.1) and a total volatile content of 3.1 wt % from which the total fluid pressure was evaluated ≥240 MPa. Hence, moderate pressure conditions can be envisaged for the mechanism triggering the April 2003 paroxysm. The subvolcanic blocks are shoshonitic basalts with 45–50 vol % of phenocrysts (plagioclase + clinopyroxene + olivine). The late-stage crystallization of the crystal-rich magma lead to the formation of Na-sanidine with plagioclase An60–25 + olivine Fo68–49 + Timagnetite ± apatite ± phlogopite ± ilmenite assemblage. Mineralogy, chemistry, and Sr–Nd isotopic signatures of the subvolcanic blocks indicate they represent the slowly cooled equivalents of batches of crystal-rich basaltic magma stored in the uppermost subvolcanic feeding system. Cooling might be facilitated by short breaks in the summit crater activity.
    Description: Unpublished
    Description: 17
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: open
    Keywords: Stromboli volcano ; Paroxysmal activity ; Basaltic pumice ; Volatile content ; Mineralogy ; Geochemistry ; Sr isotope ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 111 (2006): G04016, doi:10.1029/2005JG000097.
    Description: The presence, diversity, and distribution of a key group of subseafloor archaea, the Thermococcales, was examined in multiple diffuse flow hydrothermal vents at Axial Seamount, an active deep-sea volcano located in the northeast Pacific Ocean. A polymerase chain reaction (PCR) approach was used to determine if this group of subseafloor indicator organisms showed any phylogenetic distribution that may indicate distinct subseafloor communities at vents with different physical and chemical characteristics. Targeted primers for the Thermococcales 16S rRNA (small subunit ribosomal RNA) gene and intergenic transcribed spacer (ITS) region were designed and applied to organisms filtered in-situ directly from a variety of diffuse flow vents. Thermococcales were amplified from 9 of 11 samples examined, and it was determined that the ITS region is a better phylogenetic marker than the 16S rRNA in defining consistent groups of closely related sequences. Results show a relationship between environmental clone distribution and source vent chemistry. The most highly diluted vents with elevated iron and alkalinity contained a distinct group of Thermococcales as defined by the ITS region, suggesting separate subseafloor Thermococcales populations at diffuse vents within the Axial caldera.
    Description: This work was supported by Washington Sea Grant (NA76RG0119), National Science Foundation (OCE 9816491), NSF IGERT (DGE- 9870713), NASA Astrobiology Institute through the Carnegie Geophysical Institute, the NOAA/PMEL Vents Program, NOAA West Coast and Polar Undersea Research Center, and by the Joint Institute for the Study of the Atmosphere and Ocean under NOAA Cooperative Agreement No. NA117RJ1232.
    Keywords: Subseafloor ; Hydrothermal vent ; Intergenic Transcribed Spacer (ITS) region ; Geochemistry ; Diffuse flow vent
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q09016, doi:10.1029/2005GC000963.
    Description: Tephra layers recovered by Ocean Drilling Program from the forearc and trench regions offshore the Nicoya Peninsula of Costa Rica allow the temporal evolution of the volcanic arc to be reconstructed since 2.5 Ma. Major and trace element analyses by microprobe methods reveal a dominant tholeiitic character and a provenance in the Costa Rican area. The tephra show long-term coherent variability in geochemistry. One tephra dated at 1.45 Ma shows minimum values in ɛ Nd and maximum Li/Y consistent with very high degrees of sediment recycling at this time. However, overall Li/Y and δ7Li increase with SiO2 content, suggesting addition of heavy Li through forearc tectonic erosion and crustal assimilation. Peak values in δ7Li starting at 1.45 Ma and lasting ∼0.5 m.y. indicate enhanced tectonic erosion of the forearc possibly caused by subduction of a seamount at 1.45 Ma. The tephra record indicates significant temporal variability in terms of sediment subduction, reconciling the geologic evidence for long-term tectonic erosion and geochemical evidence for recent sediment accretion in the modern Central American arc.
    Description: Financial support for the analytical work was gratefully received from JOI-USSAC. The lithium isotope work was supported in part by National Science Foundation grant OCE-990554 to L.H.C.
    Keywords: Costa Rica ; Subduction ; Geochemistry ; Tephra
    Repository Name: Woods Hole Open Access Server
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  • 9
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    Kluwer
    In:  Bull., Polar Proj. OP-O3A4, Integration of Earth Science Research on the Turkish and Greek 1999 Earthquakes, Dordrecht, Kluwer, vol. 46, no. XVI:, pp. 61-85, (ISBN: 3-540-23712-7)
    Publication Date: 2002
    Keywords: Geochemistry ; Tectonics ; Fault zone ; NAF ; Hydraulic fracturingSWEEP ; PARASOUND ; samples ; Kuscu ; Pekdeger ; Goeruer ; Gorur ; Turkey
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  • 10
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    Kluwer
    In:  Earthquake Hazard and Seismic Risk Reduction, Dordrecht, Kluwer, vol. 37, no. 16, pp. 169-209, (ISBN 0080419208)
    Publication Date: 2000
    Keywords: Earthquake hazard ; Earthquake precursor: prediction research ; Project report/description ; Seismicity ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Geochemistry ; Geomagnetics ; Strong motions
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  • 11
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    Kluwer
    In:  Bull., Open-File Rept., Earthquake Hazard and Seismic Risk Reduction, Dordrecht, Kluwer, vol. 65, no. 1, pp. 403-411, (ISBN 0080419208)
    Publication Date: 2000
    Keywords: Earthquake risk ; Project report/description ; Earthquake engineering, engineering seismology ; Laboratory measurements ; ELSA
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  • 12
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    Kluwer
    In:  Dordrecht, 336 pp., Kluwer, vol. 31, no. 3, pp. 2-203, (ISBN 0-7923-5692-6)
    Publication Date: 1999
    Keywords: Textbook of geophysics ; Physical properties of rocks ; Laboratory measurements ; Elasticity
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  • 13
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    American Geophysical Union
    In:  Washington, D.C., American Geophysical Union, vol. 1, (ISBN 0-521-81734-X)
    Publication Date: 1995
    Keywords: Handbook of mineralogy ; Rock mechanics ; Physical properties of rocks ; Handbook of physics ; Geochemistry
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  • 14
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    American Geophysical Union
    In:  Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 37, pp. 64-97, (ISBN 3-540-24988-5)
    Publication Date: 1995
    Keywords: Laboratory measurements ; Physical properties of rocks ; Review article ; Mineralogy
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  • 15
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    American Geophysical Union
    In:  Bull., Open-File Rept., Mineral Physics & Crystallography - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 24, no. 16, pp. 303-331, (ISBN 1-86239-165-3, vi + 330 pp.)
    Publication Date: 1995
    Keywords: NMR ; Spectrum ; Spectral analysis ; Geochemistry ; Physical properties of rocks ; Review article
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  • 16
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    American Geophysical Union
    In:  Bull., Open-File Rept., U.S. National Report to International Union of Geodesy and Geophysics 1991 - 1994, Washington, D.C., American Geophysical Union, vol. 65, no. 1, pp. 23-40, (ISBN 0080419208)
    Publication Date: 1995
    Keywords: Review article ; Seismology ; Tectonics ; Plate tectonics ; Volcanology ; Earthquake hazard ; Earthquake precursor: prediction research ; Earth rotation ; Geochemistry ; Nuclear explosion ; Source ; Deep seismic sounding (espec. cont. crust) ; GeodesyY ; Chaotic behaviour ; Crustal deformation (cf. Earthquake precursor: deformation or strain) ; Rock mechanics ; remote ; sensing ; Mineralogy ; Geodesy ; Global Positioning System ; Very Long Baseline Interferometry ; Satellite Laser Ranging ; Gravimetry, Gravitation ; Planetology
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  • 17
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    American Geophysical Union
    In:  Washington, American Geophysical Union, vol. 1, (ISBN 0-521-81734-X)
    Publication Date: 1995
    Keywords: Handbook of geophysics ; Plate tectonics ; TIDES ; Geomagnetics ; Geothermics ; Seismology ; Geoelectrics ; Earth model, also for more shallow analyses ! ; Gravimetry, Gravitation ; Paleomagnetism ; isotopes ; Geochemistry ; Oceanography ; Volcanology ; physical ; constants
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  • 18
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    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Rock Physics & Phase Relations - A Handbook of Physical Constants, Washington, D.C., American Geophysical Union, vol. 1, no. 4, pp. 127-147, (ISBN 0080419208)
    Publication Date: 1995
    Keywords: Rock mechanics ; Geochemistry ; Physical properties of rocks ; Mineralogy ; Review article
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  • 19
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    American Geophysical Union
    In:  Professional Paper, Flow and Fracture of Rocks, Washington, D. C., American Geophysical Union, vol. 16, no. 16, pp. 109-115, (ISBN 0080419208)
    Publication Date: 1972
    Keywords: Fluids ; Physical properties of rocks ; Laboratory measurements ; Rock mechanics
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  • 20
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    American Geophysical Union
    In:  Professional Paper, Flow and Fracture of Rocks, Washington, D. C., American Geophysical Union, vol. 16, no. 16, pp. 265-273, (ISBN 0080419208)
    Publication Date: 1972
    Keywords: Fluids ; Physical properties of rocks ; Rock mechanics ; Laboratory measurements
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  • 21
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    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Flow and Fracture of Rocks, Washington, D. C., American Geophysical Union, vol. 16, no. XVI:, pp. 243-258, (ISBN: 3-540-23712-7)
    Publication Date: 1972
    Keywords: Rock mechanics ; Laboratory measurements ; Inelastic ; Physical properties of rocks
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  • 22
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    American Geophysical Union
    In:  Bull., Polar Proj. OP-O3A4, Flow and Fracture of Rocks, Washington, D. C., American Geophysical Union, vol. 16, no. XVI:, pp. 29-53, (ISBN: 3-540-23712-7)
    Publication Date: 1972
    Keywords: Rheology ; Physical properties of rocks ; Inelastic ; Laboratory measurements ; Rock mechanics
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