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  • kinetics  (727)
  • 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
  • 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
  • Springer  (752)
  • AGU  (15)
  • Nature Publishing Group
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  • 1
    Publikationsdatum: 2017-04-04
    Beschreibung: In this paper, we describe the 1809 eruption of Mt. Etna, Italy, which represents one historical rare case in which it is possible to observe details of the internal structure of the feeder system. This is possible thanks to the presence of two large pit craters located in the middle of the eruptive fracture field that allow studying a section of the shallow feeder system. Along the walls of one of these craters, we analysed well-exposed cross sections of the uppermost 15–20 m of the feeder system and related volcanic products. Here, we describe the structure, morphology and lithology of this portion of the 1809 feeder system, including the host rock which conditioned the propagation of the dyke, and compare the results with other recent eruptions. Finally, we propose the dynamic model of the magma behaviour inside a laterally-propagating feeder dyke, demonstrating how this dynamic triggered important changes in the eruptive style (from effusive/Strombolian to phreatomagmatic) during the same eruption. Our results are also useful for hazard assessment related to the development of flank eruptions, potentially the most hazardous type of eruption from basaltic volcanoes in densely urbanized areas, such as Mt. Etna.
    Beschreibung: Published
    Beschreibung: 1-11
    Beschreibung: 2T. Tettonica attiva
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: 3V. Dinamiche e scenari eruttivi
    Beschreibung: 4V. Vulcani e ambiente
    Beschreibung: 6A. Monitoraggio ambientale, sicurezza e territorio
    Beschreibung: N/A or not JCR
    Beschreibung: open
    Schlagwort(e): feeder dyke ; basaltic volcanoes ; flank eruptions ; Etna ; volcanic hazards ; sill ; volcanic rift ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2020-02-24
    Beschreibung: The communication process between the geoscientists and native communities in risk areas can significantly affect disaster prevention and land use planning. In Peru, the problem of disaster prevention is a fundamental policy due to unfamiliarity and deficiency of the associate information on the population. It is possible that talk of disaster prevention it will be an unlikely ideal in a country where most towns have settled on unplanned projects by the constant change and the lack of interest from the authorities in such topics. However, it is anachronistic that the rural communities and towns continue to live without a plan to enable them to improve their quality of life. The correct use of geoscience information in the mass media can help in this work. The characteristics of the enterprise in Peru require more training by professionals in the geosciences and support communication specialists. In this paper, we analyze the problem of communication for disaster prevention in Peru, with the aim of contributing to the articulation of a disaster prevention strategy.
    Beschreibung: Published
    Beschreibung: 81-83
    Beschreibung: 3T. Pericolosità sismica e contributo alla definizione del rischio
    Beschreibung: 4V. Vulcani e ambiente
    Beschreibung: 6A. Monitoraggio ambientale, sicurezza e territorio
    Beschreibung: reserved
    Schlagwort(e): Communication process ; Disaster prevention ; Risk management ; Peru ; Geoethics ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results from this work suggest new prospects for strengthening geochemical monitoring of volcanic activity and for improving the constraints in the construction of a “geochemical model”, this being a necessary condition to better understand the functioning of volcanic systems.
    Beschreibung: Published
    Beschreibung: 1859-1863
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: 4V. Vulcani e ambiente
    Beschreibung: 5V. Sorveglianza vulcanica ed emergenze
    Beschreibung: 1R. Reti di monitoraggio e Osservazioni
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Vulcano Island ; Geochemical monitoring ; CO2 flux ; CO2 fumaroles ; SO2 flux ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2021-01-27
    Beschreibung: The Sciara del Fuoco (SdF) landslides that occurred at the end of December 2002 prompted researchers to install geodetic networks to monitor deformations related to potential new slope failures. With this aim, an integrated multiparametric monitoring system was designed and deployed. In particular, this complex monitoring system is composed of four single systems: an electronic distance measurement network, installed immediately after the landslide events, a realtime GPS network, a ground-based interferometric linear synthetic aperture radar (GB-InSAR), and an automated topographic monitoring system (named Theodolite Robotic Observatory of Stromboli, or THEODOROS); the three last systems provided a continuous monitoring of selected points or sectors of the SdF. Data acquired from different systems have been jointly analyzed to reach a better understanding of the SdF dynamics. Displacement data obtained from the topographic systems are compared with those obtained from GB-InSAR, and the results of the comparison are analyzed and discussed. Furthermore, in this chapter, an example of a warning system that can detect slope instability precursors on the SdF based on a statistical analysis of the data collected by the THEODOROS system is reported.
    Beschreibung: Published
    Beschreibung: 183-199
    Beschreibung: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Beschreibung: reserved
    Schlagwort(e): Flank instability ; Slope failure ; Terrestrial geodesy ; Ground Based InSAR ; Continuous GPS ; Landslide monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: Using a lava flow emplacement model and a satellite-based land cover classification, we produce a map to allow assessment of the type and quantity of natural, agricultural and urban land cover at risk from lava flow invasion. The first step is to produce lava effusion rate contours, i.e., lines linking distances down a volcano’s flank that a lava flow will likely extend if fed at a given effusion rate from a predetermined vent zone. This involves first identifying a vent mask and then running a downhill flow path model from the edge of every pixel around the vent mask perimeter to the edge of the DEM. To do this, we run a stochastic model whereby the flow path is projected 1,000 times from every pixel around the vent mask perimeter with random noise being added to the DEM with each run so that a slightly different flow path is generated with each run. The FLOWGO lava flow model is then run down each path, at a series of effusion rates, to determine likely run-out distance for channel-fed flow extending down each path. These results are used to plot effusion rate contours. Finally, effusion rate contours are projected onto a land classification map (produced from an ASTER image of Etna) to assess the type and amount of each land cover class falling within each contour. The resulting maps are designed to provide a quick look-up capability to assess the type of land at risk from lava extending from any location at a range of likely effusion rates. For our first (2,000 m) vent zone case used for Etna, we find a total of area of ~680 km2 is at risk from flows fed at 40 m3 s−1, of which ~6 km2 is urban, ~150 km2 is agriculture and ~270 km2 is grass/woodland. The model can also be run for specific cases, where we find that Etna’s 1669 vent location, if active today, would likely inundate almost 11 km2 of urban land, as well as 15.6 km2 of agricultural land, including 9.5 km2 of olive groves and 5.2 km2 of vineyards and fruit/nut orchards.
    Beschreibung: Published
    Beschreibung: 1001-1027
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Lava flow ; Risk ; FLOWGO ; ASTER image ; Land classification ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2017-04-04
    Beschreibung: In recent decades, geophysical investigations have detected wide magma reservoirs beneath quiescent calderas. However, the discovery of partially melted horizons inside the crust is not sufficient to put constraints on capability of reservoirs to supply cataclysmic eruptions, which strictly depends on the chemical-physical properties of magmas (composition, viscosity, gas content etc.), and thus on their differentiation histories. In this study, by using geochemical, isotopic and textural records of rocks erupted from the high-risk Campi Flegrei caldera, we show that the alkaline magmas have evolved toward a critical state of explosive behaviour over a time span shorter than the repose time of most volcanic systems and that these magmas have risen rapidly toward the surface. Moreover, similar results on the depth and timescale of magma storage were previously obtained for the neighbouring Somma-Vesuvius volcano. This consistency suggests that there might be a unique long-lived magma pool beneath the whole Neapolitan area.
    Beschreibung: Published
    Beschreibung: article 712
    Beschreibung: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: N/A or not JCR
    Beschreibung: open
    Schlagwort(e): magma ; campi flegrei caldera ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2012-02-03
    Beschreibung: The Kasatochi 2008 eruption was detected by several infrared satellite sensors including Moderate Resolution Imaging Spectroradiometer (MODIS), Advanced Very High Resolution Radiometer (AVHRR), and Atmospheric Infrared Sounder (AIRS). In this work a comparison between the volcanic cloud SO2 and ash retrievals derived from these instruments has been undertaken. The SO2 retrieval is carried out by using both the 7.3 and 8.7 micron absorption features while ash retrieval exploits the 10–12 micron atmospheric window. A radiative transfer scheme is also used to correct the volcanic ash effect on the 8.7 micron SO2 signature. As test cases, three near‐contemporary images for each sensor, collected during the first days of the eruption, have been analyzed. The results show that the volcanic SO2 and ash are simultaneously present and generally collocated. The MODIS and AVHRR total ash mass loadings are in good agreement and estimated to be about 0.5 Tg, while the AIRS retrievals are slightly lower and equal to about 0.3 Tg. The AIRS and MODIS 7.3 micron SO2 mass loadings are also in good agreement and vary between 0.3 and 1.2 Tg, while the MODIS ash corrected 8.7 micron SO2 masses vary between 0.4 and 2.7 Tg. The mass increase with time confirms the continuous SO2 injection in the atmosphere after the main explosive episodes. Moreover the difference between the 7.3 and 8.7 micron retrievals suggests a vertical stratification of the volcanic cloud. The results also confirm the importance of the ash correction; the corrected 8.7 micron SO2 total masses are less than 30–40% of the uncorrected values.
    Beschreibung: Published
    Beschreibung: D00L21
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Remote sensing ; ash retrieval ; SO2 retrieval ; multispectral satellite instruments ; MODIS ; AVHRR ; AIRS ; hyperspectral satellite instruments ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2017-04-04
    Beschreibung: During its 1800-year-long persistent activity the Stromboli volcano has erupted a highly porphyritic (HP) volatile-poor scoriaceous magma and a low porphyritic (LP) volatile-rich pumiceous magma. The HP magma is erupted during normal Strombolian explosions and lava effusions, while the LP one is related to more energetic paroxysms. During the March–April 2003 explosive activity, Stromboli ejected two typologies of juvenile glassy ashes, namely highly vesicular LP shards and volatile-poor HP shards. Their textural and in situ chemical characteristics are used to unravel mutual relationships between HP and LP magmas, as well as magma dynamics within the shallow plumbing system. The mantle-normalized trace element patterns of both ash types show the typical arc-lava pattern; however, HP glasses possess incompatible element concentrations higher than LP glasses, along with Sr and Eu negative anomalies. HP shards are generally characterized by higher Li contents (to ~20 ppm) and lower δ7Li values (+1.2 to −3.8‰) with respect to LP shards (Li contents of 7–14 ppm and δ7Li ranging between +4.6 and +0.9‰). Fractional crystallization models based on major and trace element compositions, combined with a degassing model based on open-system Rayleigh distillation and on the assumption that melt/fluidDLi 〉 1, show that abundant (~30%) plagioclase precipitation and variable degrees of degassing can lead the more primitive LP magma to evolve toward a differentiated (isotopically lighter) HP magma ponding in the upper conduit and undergoing slow continuous degassing-induced crystallization. This study also evidences that in March 2003 Stromboli volcano poured out a small early volume of LP magma that traveled slower within the conduit with respect to later and larger volumes of fast ascending LP magma erupted during the April 5 paroxysm. The different ascent rates and cooling rates of the two LP magma batches (i.e., pre- and post-paroxysm) resulted in small, but detectable, differences in their chemical signatures. Finally, this study highlights the high potential of in situ investigations of juvenile glassy ashes in petrologic and geochemical monitoring the volcanic activity and of Li isotopes as tracers of degassing processes within the shallow plumbing system.
    Beschreibung: Published
    Beschreibung: 541-561
    Beschreibung: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Beschreibung: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Stromboli ; Volcanic ash ; Lithium isotopes ; Degassing-induced crystallization ; Petrologic monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: Destructive volcaniclastic flows are among the most recurrent and dangerous natural phenomena in volcanic areas. They can originate not only during or shortly after an eruption (syn-eruptive) but also during a period of volcanic quiescence (inter-eruptive), when heavy and/or persistent rains remobilize loose pyroclastic deposits. The area in Italy most prone to such flows is that of the Apennine Mountains bordering the southern Campania Plain. These steep slopes are covered by pyroclastic material of variable thickness (a few cm to several m) derived from the explosive activity of the Somma-Vesuvius and Campi Flegrei volcanoes a few tens of kilometers to the west. The largest and most recent devastating event occurred on May 5, 1998, causing the death of more than 150 people and considerable damage to villages at the foot of the Apennine Mountains. This tragic event was only the most recent of a number of volcaniclastic flows affecting the area in both historical and prehistoric times. Historical accounts report that more than 500 events have occurred in the last five centuries and that more than half of these occurred in the last 100 years, causing hundreds of deaths. In order to improve volcaniclastic flow hazard zonation and risk mitigation in the study area, we produced a zonation map that identifies the drainage basins potentially prone to disruption. This map was obtained by combining morphological characteristics (concavity and basin shape factor) and the mean slope distribution of drainage basins derived from a digital elevation model with a 10-m resolution. These parameters allowed for the classification of 1,069 drainage basins, which have been grouped into four different classes of proneness to disruption: low, moderate, high and very high. The map compiled in a GIS environment, as well as the linked database, can be rapidly queried.
    Beschreibung: Published
    Beschreibung: 371-387
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Volcaniclastic flow hazard ; GIS ; Vesuvian area ; Southern Campania Plain ; Slope instability ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2017-04-04
    Beschreibung: Accepted for publication in Reviews of Geophysics. Copyright (2010) American Geophysical Union
    Beschreibung: Greigite (Fe3S4) is an authigenic ferrimagnetic mineral that grows as a precursor to pyrite during early diagenetic sedimentary sulfate reduction. It can also grow at any time when dissolved iron and sulfide are available during diagenesis. Greigite is important in paleomagnetic, environmental, biological, biogeochemical, tectonic, and industrial processes. Much recent progress has been made in understanding its magnetic properties. Greigite is an inverse spinel and a collinear ferrimagnet with antiferromagnetic coupling between iron in octahedral and tetrahedral sites. The crystallographic c-axis is the easy axis of magnetization, with magnetic properties dominated by magnetocrystalline anisotropy. Robust empirical estimates of the saturation magnetization, anisotropy constant, and exchange constant for greigite have been obtained recently for the first time, and the first robust estimate of the low-field magnetic susceptibility is reported here. The Curie temperature of greigite remains unknown, but must exceed 350°C. Greigite lacks a low-temperature magnetic transition. Based on preliminary micromagnetic modeling, the size range for stable single domain behavior is 17-200 nm for cubic crystals and 17-500 nm for octahedral crystals. Gradual variation in magnetic properties is observed through the pseudo-single domain size range. We systematically document the known magnetic properties of greigite (at high, ambient and low temperatures, and with alternating and direct fields) and illustrate how grain size variations affect magnetic properties. Recognition of this range of magnetic properties will aid identification and constrain interpretation of magnetic signals carried by greigite, which is increasingly proving to be environmentally important and responsible for complex paleomagnetic records, including widespread remagnetizations.
    Beschreibung: In press
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): greigite ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Publikationsdatum: 2017-04-04
    Beschreibung: On 30 December 2002, a 25-30 × 106 m3 landslide on the NW flank of Stromboli volcano produced a tsunami that caused relevant damage to the Stromboli village and to the neighboring islands of the Aeolian archipelago. The NW flank of Stromboli has been the site of several, cubic kilometer-scale, landslides during the past 13 ka. In this paper we present sedimentological and compositional data of deep-sea cores recovered from a site located about 24 km north of the island. Our preliminary results indicate that: (i) turbidity currents were effectively generated by the large-scale failures and (ii) volcanogenic turbidity current deposits retain clues of the landslide source and slope failure dynamics. By analogy with Hawaii and the Canary islands we confirm that deep-sea sediments can be effectively used to assess the age and scale of past landslide events giving an important contribution to the tsunami hazard assessment of this region.
    Beschreibung: Published
    Beschreibung: 719-731
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: reserved
    Schlagwort(e): Landslide ; turbidite ; tsunami ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    Publikationsdatum: 2017-04-04
    Beschreibung: Recent stratigraphic studies at Vesuvius have revealed that, during the past 4,000 years, long lasting,moderate to low-intensity eruptions, associated with continuous or pulsating ash emission, have repeatedly occurred. The present work focuses on the AS1a eruption, the first of a series of ash-dominated explosive episodes which characterized the period between the two Subplinian eruptions of 472 AD and 1631 AD. The deposits of this eruption consist of an alternation of massive and thinly laminated ash layers and minor well sorted lapilli beds, reflecting the pulsatory injection into the atmosphere of variably concentrated ash-plumes alternating with Violent Strombolian stages. Despite its nearly constant chemical composition, the juvenile material shows variable external clast morphologies and groundmass textures, reflecting the fragmentation of a magma body with lateral and/or vertical gradients in both vesicularity and crystal content. Glass compositions and mineralogical assemblages indicate that the eruption was fed by rather homogeneous phonotephritic magma batches rising from a reservoir located at ~ 4 km (100 MPa) depth, with fluctuations between magma delivery and magma discharge. Using crystal size distribution (CSD) analyses of plagioclase and leucite microlites, we estimate that the transit time of the magma in the conduit was on the order of ~ 2 days, corresponding to an ascent rate of around 2× 10−2 ms−1. Accordingly, assuming a typical conduit diameter for this type of eruption, the minimum duration of the AS1a event is between about 1.5 and 6 years. Magma fragmentation occurred in an inertially driven regime that, in a magma with low viscosity and surface tension, can act also under conditions of slow ascent.
    Beschreibung: In press
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Ash emission activity ; Tephrite ; Vesuvius ; Stratigraphy ; Textural analyses ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Publikationsdatum: 2017-04-04
    Beschreibung: Etna’s 2001 basaltic lava flow provided a good example of the distal flow segment between the flow front and stable channel, across which the flow evolves from channel-contained to dispersed. This zone was mapped with meter precision using LIDAR data collected during 2004 and 2005. These data, supported by field mapping, show that the flow front comprised eight lobes each 10 to 20 m high. The flow front appears to have advanced not as a single unit, but as a series of lobes moving forward one lobe at a time. Primary lobes were centered on the channel axis and marginal lobes were off-axis. The lobes advanced as breakouts of low-yield-strength lava from the flow core of the stalled flow front. Marginal lobes were abandoned and contributed to marginal levees flanking the transitional channel. For Etna’s 2001 flow, the transitional channel is 140 m wide, 700 m long and fed a 240-m-long zone of dispersed flow; the change from stable to transitional channel occurred at a major reduction in slope. Above this, the stable channel is 5.2 km long, 55 to 105 m wide and bounded by 15- to 25-m-high levees, and the stable channel is located over a previous channel. In a final stage of activity, lava ponding at the break-in-slope that marks the terminus of the stable channel put pressure on the eastern levee, causing it to fail. Liberated lava then fed a final break-out to the east. Similar flow front-features occur at other volcanoes, indicating that similar processes are characteristic of dispersed flow zones.
    Beschreibung: Published
    Beschreibung: 119-127
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Basalt lava ; Channelised lava flow ; Flow front ; Zone of dispersed flow ; Flow dynamics ; LIDAR ; Etna ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 14
    Publikationsdatum: 2017-04-04
    Beschreibung: Changes of the susceptibility to lava flow invasion at Mount Etna are quantified by using lava flow simulations on four Digital Elevation Models documenting the morphostructural modifications of the volcano in the time interval 1986–2007. The probabilistic code DOWNFLOW is used to derive the areas invaded by several thousands of lava flows obtaining, for each DEM, maps of the susceptibility to lava flow invasion and of the lava flow hazard. These maps show, for the first time, the evolution of these surficial properties with time, and render a quantitative image of the effects of topographic changes on the preferential lava flow drainage paths. The results illustrate how the emplacement of new lava flows and the growth of scoria cones affect the probability of inundation by lava flows. We conclude that the persistent activity of this volcano requires a frequent updating of the topography for a reliable lava flow hazard assessment.
    Beschreibung: Published
    Beschreibung: 537-546
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Lava flow simulation ; Digital Elevation Model ; Lidar ; Time series ; Lava flow hazard maps ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 15
    Publikationsdatum: 2021-07-14
    Beschreibung: Hydrothermal alteration may weaken volcanic rocks, causing the gravitational instability of portions of active volcanoes with potentially hazardous collapses. Here we show high‐resolution multibeam, magnetic and gravity surveys of the Marsili seamount, the largest active volcano of Europe located in the southern Tyrrhenian back‐arc basin. These surveys reveal zones with exceptionally low densities and with vanishing magnetizations, due probably to the comminution of basalts during hyaloclastic submarine eruptions and to their post‐eruptive hydrothermal alteration. The location of these regions correlates with morphological data showing the occurrence of past collapses. Similar evidence has been obtained from pre existing data at Vavilov Seamount, another older volcanic system in the Tyrrhenian back‐arc basin. Here a large volume of at least 50 km3 may have collapsed in a single event from its 40 km long western flank. Given the similarities between these volcanoes, a large collapse event may also be expected at Marsili.
    Beschreibung: Published
    Beschreibung: L03305
    Beschreibung: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Beschreibung: 3.4. Geomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Marsili Seamount ; Gravity anomalies ; Magnetic anomalies ; Tyrrhenian Sea ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 16
    Publikationsdatum: 2017-04-04
    Beschreibung: We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An60-28 plagioclase, Fe–Mn-rich olivines (Fo68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (〈0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.
    Beschreibung: Published
    Beschreibung: 795-813
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Basalt ; Subvolcanic crystallization ; Dolerite ; Magmatic breccia ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 17
    Publikationsdatum: 2017-04-04
    Beschreibung: On 30 December 2002, a 25-30 × 106 m3 landslide on the NW flank of Stromboli volcano produced a tsunami that caused relevant damage to the Stromboli village and to the neighboring islands of the Aeolian archipelago. The NW flank of Stromboli has been the site of several, cubic kilometer-scale, landslides during the past 13 ka. In this paper we present sedimentological and compositional data of deep-sea cores recovered from a site located about 24 km north of the island. Our preliminary results indicate that: (i) turbidity currents were effectively generated by the large-scale failures and (ii) volcanogenic turbidity current deposits retain clues of the landslide source and slope failure dynamics. By analogy with Hawaii and the Canary islands we confirm that deep-sea sediments can be effectively used to assess the age and scale of past landslide events giving an important contribution to the tsunami hazard assessment of this region.
    Beschreibung: Unpublished
    Beschreibung: -
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: reserved
    Schlagwort(e): Landslide ; turbidite ; tsunami ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
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  • 18
    Publikationsdatum: 2020-02-24
    Beschreibung: A multidisciplinary geological and compositional investigation allowed us to reconstruct the occurrence of flank eruptions on the lower NE flank of Stromboli volcano since 15 ka. The oldest flank eruption recognised is Roisa, which occurred at ~15 ka during the Vancori period, and has transitional compositional characteristics between the Vancori and Neostromboli phases. Roisa was followed by the San Vincenzo eruption that took place at ~12 ka during the early stage of Neostromboli period. The eruptive fissure of San Vincenzo gave rise to a large scoria cone located below the village of Stromboli, and generated a lava flow, most of which lies below sea level. Most of the flank eruptions outside the barren Sciara del Fuoco occurred in a short time, between ~9 and 7 ka during the Neostromboli period, when six eruptive events produced scoria cones, spatter ramparts and lava flows. The Neostromboli products belong to a potassic series (KS), and cluster in two differently evolved groups. After an eruptive pause of ~5,000 years, the most recent flank eruption involving the NE sector of the island occurred during the Recent Stromboli period with the formation of the large, highly K calc-alkaline lava flow field, named San Bartolo. The trend of eruptive fissures since 15 ka ranges from N30°E to N55°E, and corresponds to the magma intrusions radiating from the main feeding system of the volcano.
    Beschreibung: The mapping of Stromboli was supported by a grant to S. Calvari (Project V2/01, 2005–2007, funded by the Istituto Nazionale di Geofisica e Vulcanologia and by the Italian Civil Protection). This work was partly supported by INGV through a research grant financed by MIUR-FIRB to G. Norini. We wish to thank the former Director of INGV-Sezione di Catania, A. Bonaccorso, for making additional funds available for field trip and datings.
    Beschreibung: In press
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Stromboli ; flank fissures ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 19
    Publikationsdatum: 2017-04-04
    Beschreibung: Volcanic and geothermal areas are one of the major natural sources of H2S to the atmosphere. Its environmental impact is often the main cause of the opposition to the development of geothermal energy exploitation programs. In this paper we analyze the air concentrations and dispersion pattern of naturally emitted H2S at the geothermal area of Sousaki (Corinthia, Greece). Measurements, made with a network of passive samplers, evidence a rapid decrease of concentration values away from the emission points. The fact that the decrease is more pronounced in the summer with respect to the winter indicates that it is not only due to a dilution effect, but also to redox reactions favoured by higher temperatures and intense sunlight typical of the summer period.
    Beschreibung: Published
    Beschreibung: 1723-1728
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Hydrogen sulphide ; Environmental impact of volcanic activity ; Gas hazard ; Passive samplers ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 20
    Publikationsdatum: 2017-04-04
    Beschreibung: An edited version of this paper was published by AGU. Copyright (2009) American Geophysical Union.
    Beschreibung: This work developed a quantitative approach for evaluating the reliability of lava flow simulation codes. In particular, it applied the LavaSIM code to simulate the main lava flow emplaced on the south flank of Mount Etna (Italy) between 18 July and 9 August 2001 which represents an ideal test case for validating numerical codes. LavaSIM is the only full 3-D model and is thus able to account for the vertical variation of lava properties such as temperature, viscosity, velocity, and liquidus or solidus state. It presents the most complete description of the lava cooling, and its greatest peculiarity is the potential to discriminate between cells filled by liquid or solid lava. Thirteen simulation tests were performed varying the main input parameters, and they were checked thanks to the availability of syneruption maps, defining the lava flow planar expansion throughout its whole emplacement. Two parameters were adopted for quantitatively evaluate the agreement between real and simulated flows: the percent length ratio (PLR), here defined, and the fitness function (e1). Their joint analysis allowed checking both the simulated lateral spreading, through e1, and the flow lengthening, through PLR. The simulated flows follow a path very similar to the observed one, giving a good fitting of the lateral spreading, though the simulations are, after the second day, normally longer and thinner. The temporal evolution of the three-dimensional distribution of liquid lava and crust was also analyzed. Finally, the analysis presented here demonstrated the great capability of the LavaSIM simulation code.
    Beschreibung: Published
    Beschreibung: Q09003
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): lava flow ; quantitative assessment of simulation reliability ; 2001 Etna eruption ; LavaSIM ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 21
    Publikationsdatum: 2017-04-04
    Beschreibung: Forecasting the dispersal of ash from explosive volcanoes is a scientific challenge to modern volcanology. It also represents a fundamental step in mitigating the potential impact of volcanic ash on urban areas and transport routes near explosive volcanoes. To this end we developed a web-based early-warning modeling tool named MAFALDA (Modeling And Forecasting Ash Loading and Dispersal in the Atmosphere) able to quantitatively forecast ash concentrations in the air and on the ground. The main features of MAFALDA are: the usage of (1) a dispersal model, named VOL-CALPUFF (Barsotti et al. 2008) that couples the column ascent phase with the ash-cloud transport and (2) high-resolution weather forecasting data, the capability to run and merge multiple scenarios, and the web-based structure of the procedure that makes it suitable as an early-warning tool. MAFALDA produces plots for a detailed analysis of ash-cloud dynamics and ground deposition, as well as synthetic 2D maps of areas potentially affected by dangerous concentrations of ash. A first application of MAFALDA to the long-lasting weak plumes produced at Mt. Etna (Italy) is presented. A similar tool can be useful to civil protection authorities and volcanic observatories in reducing the impact of the eruptive events. MAFALDA can be accessed at http://mafalda.pi.ingv.it.
    Beschreibung: Published
    Beschreibung: Q12019
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): volcanic ash forecast ; numerical modeling ; early warning modeling tool ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 22
    Publikationsdatum: 2017-04-04
    Beschreibung: No abstract
    Beschreibung: Published
    Beschreibung: L08312
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): landslide tsunami ; Mt. Etna ; paleo-tsunami deposits ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 23
    Publikationsdatum: 2017-04-04
    Beschreibung: Assessment of the hazard from lava flow inundation at the active volcano of Mt. Etna (Italy) was performed by calculating the probability of lava flow inundation at each position on the volcano. A probability distribution for the formation of new vents was calculated using geological and volcanological data from past eruptions. The simulated lava flows from these vents were emplaced using a maximum expected flow length derived from geological data on previous lava flows. Simulations were run using DOWNFLOW, a DEM-based model designed to predict lava flow paths. Different eruptive scenarios were simulated by varying the elevation and probability distribution of eruptive points. Inundation maps show that the city of Catania and the coastal zone may only be impacted by flows erupted from low-altitude vents (〈 1500 m elevation), and that flank eruptions at elevations 〉 2000 m preferentially inundate the northeast and southern sectors of the volcano as well as the Valle del Bove. Eruptions occurring in the summit area (〉 3000 m elevation) pose no threat to the local population. Discrepancies between the results of simple, hydrological models and those of the DOWNFLOW model show that hydrological approaches are inappropriate when dealing with Etnean lava flows. Because hydrological approaches are not designed to reproduce the full complexity of lava flow spreading, they underestimate the catchment basins when the fluid has a complex rheology.
    Beschreibung: In press
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): lava flows ; DOWNFLOW ; hazard ; Mt. Etna ; Sicily ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 24
    Publikationsdatum: 2017-04-04
    Beschreibung: The main purpose of this paper is to introduce a Bayesian event tree model for eruption forecasting (BET_EF). The model represents a flexible tool to provide probabilities of any specific event at which we are interested in, by merging all the relevant available information, such as theoretical models, a priori beliefs, monitoring measures, and any kind of past data. BET_EF is based on a Bayesian procedure and it relies on the fuzzy approach to manage monitoring data. The method deals with short- and long-term forecasting, therefore it can be useful in many practical aspects, as land use planning, and during volcanic emergencies. Finally, we provide the description of a free software package that provides a graphically supported computation of short- to long-term eruption forecasting, and a tutorial application to the recent MESIMEX exercise at Vesuvius.
    Beschreibung: Published
    Beschreibung: 623-632
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: partially_open
    Schlagwort(e): eruption forecasting ; event tree ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 25
    Publikationsdatum: 2017-04-04
    Beschreibung: The NW submarine portion of Stromboli volcano has been investigated by deep-towed sidescan sonar, bathymetric surveys, video camera runs and dredging during two research cruises in 2002 and 2004. The surveys resulted in the identification of an extensive pillow lava field (106-107m3) at about 2300 m of water depth and 9 km from the shoreline of Stromboli Island. The pillow lavas have a unique composition that does not match any known subaerial product, although a limited affinity exists with those erupted during the Neostromboli eruptive cycle of the island (13–6 ka). This is the first finding of a submarine eruption on the northern side of Stromboli and improves the knowledge of its flank activity and volcanic hazards. This eruption is interpreted as marking the onset of a new volcanic cycle from the edifice periphery fed by a new, distinct magma mixed with traces of the previous magma that survived the emptying of the Neostromboli magma chamber.
    Beschreibung: Published
    Beschreibung: L16310
    Beschreibung: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Beschreibung: 3.5. Geologia e storia dei sistemi vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Stromboli ; flank eruption ; pillow lava ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 26
    Publikationsdatum: 2017-04-04
    Beschreibung: No abstract
    Beschreibung: Published
    Beschreibung: L02609
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Mt. Etna tsunami ; homogenite ; 365 A.D. tsunami ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 27
    Publikationsdatum: 2017-04-04
    Beschreibung: We consider the process of slow extrusion of very viscous magma that forms lava domes. Dome-building eruptions are commonly associated with hazardous phenomena, in- cluding pyroclastic flows generated by dome collapses, explosive eruptions and volcanic blasts. These eruptions commonly display fairly regular alternations between pe- riods of high and low or no activity with time scales from hours to years. Usually hazardous phenomena are asso- ciated with periods of high magma discharge rate, thus, understanding the causes of pulsatory activity during ex- trusive eruptions is an important step towards forecasting volcanic behavior, especially the transition to explosive ac- tivity when magma discharge rate increases by a few orders of magnitude. In recent years the risks have increased be- cause the population density in the vicinity of many active volcanoes has increased.
    Beschreibung: Published
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: open
    Schlagwort(e): Volcanic Eruptions ; Cyclicity ; During Lava ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
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  • 28
    Publikationsdatum: 2017-04-04
    Beschreibung: Volcanic hazard assessment is a basic ingredient for risk-based decision-making in land-use planning and emergency management. Volcanic hazard is defined as the probability of any particular area being affected by a destructive volcanic event within a given period of time (Fournier d’Albe 1979). The probabilistic nature of such an important issue derives from the fact that volcanic activity is a complex process, characterized by several and usually unknown degrees of freedom that are often linked by nonlinear relationships (e.g. Bak et al. 1988). Except in sporadic cases, the result of this complexity is an intrinsic, and perhaps unavoidable, unpredictability of the time evolution of the volcanic system from a deterministic point of view.
    Beschreibung: Published
    Beschreibung: open
    Schlagwort(e): model ; volcanic risk ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book
    Format: 137534 bytes
    Format: application/pdf
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  • 29
    Publikationsdatum: 2017-04-04
    Beschreibung: The main purpose of this paper is to introduce a Bayesian event tree model for eruption forecasting (BET EF). The model represents a flexible tool to provide probabilities of any specific event at which we are interested in, by merging all the relevant available information, such as theoretical models, a priori beliefs, monitoring measures, and any kind of past data. BET EF is based on a Bayesian procedure and it relies on the fuzzy approach to manage monitoring data. The method deals with short- and long-term forecasting, therefore it can be useful in many practical aspects, as land use planning, and during volcanic emergencies. Finally, we provide the description of a free software package that provides a graphically supported computation of short- to long-term eruption forecasting, and a tutorial application to the recent MESIMEX exercise at Vesuvius.
    Beschreibung: Published
    Beschreibung: on line first
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: partially_open
    Schlagwort(e): Eruption forecasting ; Long- and short-term volcanic hazard ; Bayesian inference ; Event tree ; Fuzzy sets ; MESIMEX ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 30
    Publikationsdatum: 2017-04-04
    Beschreibung: Hydrological and geochemical studies performed on Lake Specchio di Venere on Pantelleria island (Italy) indicate that this endorheic basin has been formed through upwelling of the water table, and that it is continuously fed by the thermal springs situated on its shores. The lake is periodically stratified both thermally and in salinity, albeit this stratification is rather unstable over time since meteorological events such as strong rain or wind can determine the mixing of its waters. Periodical analyses of the lake water chemistry show large variations of the salt content due to the yearly evaporation-rain dilution cycle. These processes are also responsible for the saline stratification during steady meteorological conditions. The mineralogical characterisation of the bottom sediments shows the almost exclusive presence of neoformation minerals, mainly carbonates, formed in response to the pH gradient between spring- (pH≈6) and lake-waters (pH≈9). Finally, the CO2 partial pressures in the lake water slightly exceeding the atmospheric one, are due to the large amounts of CO2 brought to the lake through the bubbling free gas phase of the thermal springs. Nevertheless the high pH value of the lake water, its small volume and its periodical mixing prevent dangerous built up of this gas.
    Beschreibung: Published
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Pantelleria island ; volcanic lake ; gas hazard ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
    Publikationsdatum: 2017-04-04
    Beschreibung: The use of a hand-held thermal camera during the 2002–2003 Stromboli effusive eruption proved essential in tracking the development of flow field structures and in measuring related eruption parameters, such as the number of active vents and flow lengths. The steep underlying slope on which the flow field was emplaced resulted in a characteristic flow field morphology. This comprised a proximal shield, where flow stacking and inflation caused piling up of lava on the relatively flat ground of the vent zone, that fed a medial–distal lava flow field. This zone was characterized by the formation of lava tubes and tumuli forming a complex network of tumuli and flows linked by tubes. Most of the flow field was emplaced on extremely steep slopes and this had two effects. It caused flows to slide, as well as flow, and flow fronts to fail frequently, persistent flow front crumbling resulted in the production of an extensive debris field. Channel-fed flows were also characterized by development of excavated debris levees in this zone (Calvari et al. 2005). Collapse of lava flow fronts and inflation of the upper proximal lava shield made volume calculation very difficult. Comparison of the final field volume with that expecta by integrating the lava effusion rates through time suggests a loss of ~70% erupted lava by flow front crumbling and accumulation as debris flows below sea level. Derived relationships between effusion rate, flow length, and number of active vents showed systematic and correlated variations with time where spreading of volume between numerous flows caused an otherwise good correlation between effusion rate, flow length to break down. Observations collected during this eruption are useful in helping to understand lava flow processes on steep slopes, as well as in interpreting old lava–debris sequences found in other steep-sided volcanoes subject to effusive activity.
    Beschreibung: Published
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Lava flow field ; Morphology ; Tumuli ; Lava tubes ; Effusion rate ; Rheology ; Stromboli volcano ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 32
    Publikationsdatum: 2017-04-04
    Beschreibung: A thermal modeling of the Vesuvius is presented, based on its magmatic and volcanic history. A 2D numerical scheme has been developed to evaluate the heat transfer inside and around a magma body, the latent heat of crystallization and the inputs of magma from the asthenosphere to a crustal reservoir. Assuming a ratio 〉1 between velocities of magma ascending in the conduit and magma laterally displaced in the reservoir, the results indicate that, after 40 ka, the reservoir is vertically thermally zoned. As a consequence it hosts magma batches that can individually differentiate, mix and be contaminated by the crust, and produce the spectrum of isotopic compositions of the Vesuvian products. The thermal model reproduces the geothermal gradient and the brittle-ductile transition (250– 300 C) at 6 km of depth (the maximum depth of earthquake foci) only after 0.5–1 Ma, implying a long lived magma chamber below the volcano.
    Beschreibung: Published
    Beschreibung: L17302
    Beschreibung: reserved
    Schlagwort(e): NONE ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 33
    Publikationsdatum: 2017-04-04
    Beschreibung: We model the location, geometry and density of the source of the recent geological unrest at Campi Flegrei caldera (Italy) by inverting levelling, trilateration and gravity measurements collected between 1980 and 1995. The best fitting source for the 1980–84 inflation is a horizontal penny-shaped crack with a density 142 to 1115 kg/m3. The source best fitting the deflation period (1990–95) is a vertical spheroid with density between 902 and 1015 kg/m3. These results exclude the intrusion of magma, and indicate the migration of fluid to and from the caldera hydrothermal system as the cause of ground deformation and consequent unrest.
    Beschreibung: Published
    Beschreibung: L01307
    Beschreibung: reserved
    Schlagwort(e): NONE ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publikationsdatum: 2017-04-04
    Beschreibung: The catastrophic events that occurred in May 1998 in the area of Sarno (Southern Italy) highlight the destructive potential of debris flows, even when they are of relatively low magnitude. More than 130 people were killed and severe property damage took place when volcaniclastic debris flows triggered by heavy rainfall inundated various towns located in piedmont areas. This work investigates the suitability of LAHARZ, a GIS-assisted method for the automatic delineation of lahar inundation areas, for reproducing the May 1998 flows at Sarno. It was found that recalibration of the empirical relationship employed by LAHARZ is required in order to realistically hind-cast the inundation areas of considered events. The potential for further improvements in prediction outputs for this type of geomorphic setting is discussed, taking into account the observed lower mobility of these small volcaniclastic debris flows as compared to lahars of similar size.
    Beschreibung: Published
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Sarno ; LAHARZ ; Debris flows ; Lahars ; Debris flow modelling ; Hazard assessment ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publikationsdatum: 2017-04-04
    Beschreibung: An immersed boundary technique suitable for the solution of multiphase compressible equations of gas–particle flows of volcanic origin over complex 2D and 3D topographies has been developed and applied. This procedure combines and extends different existing methods designed for incompressible flows. Furthermore, the extension to compressible multiphase flows is achieved through a flux correction term in the mass continuity equations of the immersed cells that accounts for density variations in the partial volumes. The technique is computationally accurate and inexpensive, if compared to the use and implementation of the finite-volume technique on unstructured meshes. The first applications that we consider are the simulations of pyroclastic density currents generated by the collapse of a volcanic column in 2D axisymmetric geometry and by a dome explosion in 3D. Results show that the immersed boundary technique can significantly improve the description of the no-slip flow condition on an irregular topography even with relatively coarse meshes. Although the net effect of the present technique on the results is difficult to quantify in general terms, its adoption is recommended any time that cartesian grids are used to describe the large-scale dynamics of pyroclastic density currents over volcano topographies.
    Beschreibung: Published
    Beschreibung: 183-198
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Pyroclastic density currents ; Compressible flows ; Cartesian grids ; Finite-volume method ; Immersed boundary method ; Numerical simulation ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 36
    Publikationsdatum: 2017-04-04
    Beschreibung: The Campania Region (southern Italy) is characterized by the frequent occurrence of volcaniclastic debris flows that damage property and loss of life (more than 170 deaths between 1996 and 1999). Historical investigation allowed the identification of more than 500 events during the last four centuries; in particular, more than half of these occurred in the last 100 years, causing hundreds of deaths. The aim of this paper is to quantify debris-flow hazard potential in the Campania Region. To this end, we compared several elements such as the thickness distribution of pyroclastic fall deposits from the last 18 ka of the Vesuvius and Phlegrean Fields volcanoes, the slopes of relieves, and the historical record of volcaniclastic debris flows from A.D. 1500 to the present. Results show that flow occurrence is not only a function of the cumulative thickness of past pyroclastic fall deposits but also depends on the age of emplacement. Deposits younger than 10 ka (Holocene eruptions) apparently increase the risk of debris flows, while those older than 10 ka (Late Pleistocene eruptions) seem to play a less prominent role, which is probably due to different climatic conditions, and therefore different rates of erosion of pyroclastic falls between the Holocene and the Late Pleistocene. Based on the above considerations, we compiled a large-scale debris-flow hazard map of the study area in which five main hazard zones are identified: very low, low, moderate, high, and very high.
    Beschreibung: Published
    Beschreibung: 157-167
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: 5.4. TTC - Sistema Informativo Territoriale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Debris flows ; Explosive eruptions ; Hazard mapping ; Vesuvius volcano ; Erosion ; Campania region ; Southern Italy ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 37
    Publikationsdatum: 2017-04-04
    Beschreibung: More than ca 100 km3 of nearly homogeneous crystal-poor phonolite and ca 100 km3 of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199 C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (102 years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.
    Beschreibung: Published
    Beschreibung: On line First
    Beschreibung: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Campanian Ignimbrite ; Super eruption ; Crystal size distribution ; Partition coefficients ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 38
    Publikationsdatum: 2022-06-08
    Beschreibung: No abstract
    Beschreibung: Published
    Beschreibung: 318
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: N/A or not JCR
    Beschreibung: partially_open
    Schlagwort(e): Probabilistic Volcanic Hazard ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 39
    Publikationsdatum: 2017-04-04
    Beschreibung: Secondary minerals of a 91 meters-thick sequence of pillow basalts cored during ODP Leg 195 (Site 1201, West Philippine Basin) were investigated to reconstruct the hydrothermal alteration history and regime. The basement was first buried by red clays, and then by a thick turbidite sequence, thereby isolating it from seawater. The basalts are primitive to moderately fractionated, texturally variable from hypocrystalline and spherulitic to intersertal, sub-ophitic and intergranular. Relic primary minerals are plagioclase, clinopyroxene and opaques. Hydrothermal alteration pervasively affected the basalts, generating secondary clay minerals (mostly glauconite, minor Al-saponite and Fe-beidellite, Na-zeolites, minor alkali-feldspar and calcite. The secondary mineral paragenesis and mutual relationships suggest that the hydrothermal alteration occurred under zeolite-facies conditions, at temperatures 100-150 C. The main phase of alteration occurred under oxidizing conditions, with a high seawater rock ratio, in an open-circulation regime, at temperatures of 30-60 C, with precipitation of abundant glauconite and iddingsite. A later stage of alteration occurred at ca. 70 C, with precipitation of abundant Na-zeolites and minor calcite, in a more restricted circulation regime as a consequence of basement burial under the sedimentary cover, which supplied an altered, Ca-rich and Magma-sulfate-poor water causing precipitation of almost pure calcite.
    Beschreibung: Published
    Beschreibung: 87-112
    Beschreibung: open
    Schlagwort(e): west Philippine ; Mineral chemistry ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
    Publikationsdatum: 2017-04-04
    Beschreibung: From early September to early November, during the 2004–2005 Mt. Etna effusive eruption, petrologic monitoring was enabled by near-vent sampling of erupting lava and onsite SEM-EDS capabilities at INGV-CT. Significant differences in composition and temperature of lava erupted from 2920–2620 m and 2820–2320 m vents, attest to variably evolved shallow magmatic conditions within a geometrically complex storage volume. The petrography and glass compositions of water-quenched samples indicate that the magma feeding the 2004–2005 activity was likely to have been stored in the shallow plumbing system during the 2000 and 2001 activity, where it experienced volatile loss and extensive crystallization. Both geophysical and petrologic data suggest that this eruption was not triggered by the intrusion of a new dike from depth, but it was more likely that existing shallow magma reservoirs were passively mobilized and erupted in response to edifice deformation.
    Beschreibung: Published
    Beschreibung: 1-5
    Beschreibung: partially_open
    Schlagwort(e): Mineralogy and Petrology: Petrography, microstructures, and textures ; Mineralogy and Petrology: Igneous petrology ; Volcanology: Eruption mechanisms and flow emplacement ; Volcanology: Volcano monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 41
    Publikationsdatum: 2017-04-04
    Beschreibung: Flank instability and collapse are observed at many volcanoes. Among these, Mt. Etna is characterized by the spreading of its eastern and southern flanks. The eastern spreading area is bordered to the north by the EW-trending Pernicana Fault System (PFS). During the 20022003 Etna eruption, ground fracturing along the PFS migrated eastward from the NE Rift, to as far as the 18 km distant coastline. The deformation consisted of dextral en-echelon segments, with sinistral and normal kinematics. Both of these components of displacement were one order of magnitude larger (~1 m) in the western, previously known, portion of the PFS with respect to the newly surveyed (~9 km long) eastern section (~0.1 m). This eastern section is located along a pre-existing, but previously unknown, fault, where displaced man-made structures give overall slip rates (11.9 cm/year), only slightly lower than those calculated for the western portion (1.42.3 cm/year). After an initial rapid motion during the first days of the 20022003 eruption, movement of the western portion of the PFS decreased dramatically, while parts of the eastern portion continued to move. These data suggest a model of spreading of the eastern flank of Etna along the PFS, characterized by eruptions along the NE Rift, instantaneous, short-lived, meter-scale displacements along the western PFS and more long-lived centimeter-scale displacements along the eastern PFS. The surface deformation then migrated southwards, reactivating, one after the other, the NNWSSE-trending Timpe and Trecastagni faults, with displacements of ~0.1 and ~0.04 m, respectively. These structures, along with the PFS, mark the boundaries of two adjacent blocks, moving at different times and rates. The new extent of the PFS and previous activity over its full length indicate that the sliding eastern flank extends well below the Ionian Sea. The clustering of seismic activity above 4 km b.s.l. during the eruption suggests a deep décollement for the moving mass. The collected data thus suggests a significant movement (volume 〉1,100 km3) of the eastern flank of Etna, both on-shore and off-shore.
    Beschreibung: Published
    Beschreibung: 417-430
    Beschreibung: partially_open
    Schlagwort(e): Volcano spreading ; Fracturing ; Mt. Etna ; Pernicana Fault System ; NE Rift ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 42
    Publikationsdatum: 2017-04-04
    Beschreibung: The 2002–2003 Mount Etna eruption and the associated deformation provide a unique possibility to study the relationships between volcanism and volcano instability. The sequence started with movement of the eastern volcano flank and was associated with earthquakes and the formation of surface ruptures. Then the eruption occurred from fissures at the north and south rift zones and was followed by additional flank movement, seismic swarms, and surface ruptures. The overall area of flank movement implicated more than 700 km2. In this paper we investigate how episodes of magmatic events (eruptions and intrusions) and flank movement interact. In three-dimensional numerical models we simulate the volcano-tectonic events and calculate changes in the static stress field. The models suggest that the 2002–2003 events are the result of interrelated processes consisting of (1) the preeruptive intrusion of magma and inflation of the volcano, which induced (2) the movement of the volcano east flank, (3) facilitated the eruption, and (4) led to the slip of a much larger part of the eastern and southeastern flanks. Understanding the precise interconnectivity of these processes may help to forecast the behavior during future volcanic crisis at Mount Etna, which is crucial in minimizing volcanic and seismic hazards on the highly populated eastern sector of the volcano.
    Beschreibung: Published
    Beschreibung: 1-12
    Beschreibung: partially_open
    Schlagwort(e): Mount Etna ; flank instability ; volcano deformation ; volcano-tectonic interaction ; elastic stress field modeling ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Adsorption 6 (2000), S. 137-147 
    ISSN: 1572-8757
    Schlagwort(e): adsorption ; kinetics ; linear driving force model ; process design
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract The Linear Driving Force (LDF) model for gas adsorption kinetics is frequently and successfully used for analysis of adsorption column dynamic data and for adsorptive process designs because it is simple, analytic, and physically consistent. Yet, there is a substantial difference in the characteristics of isothermal batch uptake curves on adsorbent particles by the LDF and the more rigorous Fickian Diffusion (FD) model. It is demonstrated by using simple model systems that the characteristics of the adsorption kinetics at the single pore or the adsorbent particle level are lost in (a) evaluating overall uptake on a heterogeneous porous solid, (b) calculating breakthrough curves from a packed adsorbent column, and (c) establishing the efficiency of separation by an adsorptive process due to repeated averaging of the base kinetic property. That is why the LDF model works in practice.
    Materialart: Digitale Medien
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  • 44
    ISSN: 1572-879X
    Schlagwort(e): ammonia synthesis ; kinetics ; ruthenium catalysts ; promotional effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of NH3 synthesis over carbon-based ruthenium catalysts promoted with barium or alkali was studied. Both the ammonia partial pressure dependencies of the reaction rates (T = 400°C, p = 63 bar, H2 : N2 = 3 : 1) and the pressure variations of the activity (T = 370°C, p= 4–63 bar, H2 : NN2 = 3 : 1) were found to be different for Ba and for the alkali (K, Cs). Ba–Ru/C proved to be more sensitive to the NH3 content and to the total pressure. The rate of synthesis over the alkali-promoted catalysts is, in turn, much stronger influenced by the ruthenium dispersion. TOFs of NH3 synthesis for the promoted samples at 370°C and 4 bar (Ba 0.085 1/s, Cs 0.05 1/s, K 0.035 1/s) are significantly higher than that for the Ru(0001) basal plane (0.0085 1/s results from the literature data at 370°C, 2 bar). The most active Ru/C samples (Ba or Cs) exceed significantly the fused iron catalyst, especially at high conversions.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    Topics in catalysis 11-12 (2000), S. 327-333 
    ISSN: 1572-9028
    Schlagwort(e): hydrodenitrogenation ; toluidine ; methylcyclohexylamine ; kinetics ; nickel-promoted molybdenum sulphide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The hydrodenitrogenation (HDN) of o-toluidine and its reaction intermediates was studied over a NiMo/γ-Al2O3 catalyst. The kinetics of the HDN of methylcyclohexylamine and of the hydrogenation of cyclohexene were also studied. Hydrogenation of o-toluidine alone produces methylcyclohexene and methylcyclohexane. When a sufficient quantity of cyclohexene is added during the HDN of toluidine, methylcyclohexylamine, the first intermediate in the hydrogenation of toluidine, becomes detectable. Because of its strong adsorption constant and high rate constant for reacting further to methylcyclohexene and methylcyclohexane, methylcyclohexylamine is not observed in the HDN of toluidine. Adding cyclohexene decreases the adsorption of methylcyclohexylamine, thus enabling its detection. The rate and adsorption constants of methylcyclohexylamine and cyclohexene in the HDN of methylcyclohexylamine were calculated by fitting the kinetic data to a Langmuir–Hinshelwood equation. A two-site model was used to describe the surface reactions, with one site for the methylcyclohexylamine reactions and the other for the cyclohexene reaction.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    Adsorption 6 (2000), S. 349-357 
    ISSN: 1572-8757
    Schlagwort(e): sulfadiazene ; adsorption ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract To investigate the nature of interactive forces between sulfadiazene molecules and alumina surface the experiments were performed for the adsorption of sulfadiazene (SD) from its aqueous sulution onto the alumina surfaces at 25 ± 0.2°C and the influence of factors such as increasing concentration of SD (4.0–20.0 × 10−3 mol cm−3), the time required for adsorption equilibrium, pH (2.0–12.0) and temperature (5–45°C) of the adsorption medium, the presence of ions like Cl−, SO2− 4 and PO3− 4 (0.01–0.30 M) and organic solvents (5% v/v) were observed on the course of adsorption of SD. Various adsorption and kinetic parameters such as adsorption coefficient, the rate constants for adsorption and desorption were also evaluated. The results of the above cited studies facilitated to formulate the mechanisms of interaction between SD and alumina surfaces. From application view point the present work may be a potential tool for an effective chromatographic separation of sulfa drugs from industrial effluents.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Catalysis letters 64 (2000), S. 65-75 
    ISSN: 1572-879X
    Schlagwort(e): NO reduction ; CH3OH ; La2O3 ; methyl nitrite ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Nitric oxide (NO) reduction by methanol was studied over La2O3 in the presence and absence of oxygen. In the absence of O2, CH3OH reduced NO to both N2O and N2, with selectivity to dinitrogen formation decreasing from around 85% at 623 K to 50–70% at 723 K. With 1% O2 in the feed, rates were 4–8 times higher, but the selectivity to N2 dropped from 50% at 623 K to 10% at 723 K. The specific activities with La2O3 for this reaction were higher than those for other reductants; for example, at 773 K with hydrogen a specific activity of 35 μmol NO/s m2 was obtained whereas that for methanol was 600 μmol NO/s m2. The Arrhenius plots were linear under differential reaction conditions, and the apparent activation energy was consistently near 14 kcal/mol with CH3OH. Linear partial pressure dependencies based on a power rate law were obtained and showed a near‐zero order in CH3OH and a near‐first order in H2. In the absence of O2, a Langmuir–Hinshelwood type model assuming a surface reaction between adsorbed CH3OH and adsorbed NO as the slow step satisfactorily fitted the data, and the model invoking two types of sites provided the best fit and gave thermodynamically consistent rate constants. In the presence of O2 a homogeneous gas‐phase reaction between O2, NO, and CH3OH occurred to yield methyl nitrite. This reaction converted more than 30% of the methanol at 300 K and continued to occur up to temperatures where methanol was fully oxidized. Quantitative kinetic studies of the heterogeneous reaction with O2 present were significantly complicated by this homogeneous reaction.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Catalysis letters 69 (2000), S. 103-107 
    ISSN: 1572-879X
    Schlagwort(e): dicyclopentadiene ; Wacker oxidation ; Pd(AcO)2 ; benzoquinone ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition complexation between dicyclopentadiene and tricyclodecenone with the catalytic species.
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  • 49
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 59 (2000), S. 633-642 
    ISSN: 1572-8943
    Schlagwort(e): cadmium ; dialkyldithiocarbamate ; kinetics ; thermal decomposition ; thermogravimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The thermal decomposition kinetics of the solid complexes Cd(S2 CNR2 )2 , where R =C2 H5 , n -C3 H7 , n -C4 H9 or iso -C4 H9 , was studied by using isothermal and non-isothermal thermogravimetry. The superimposed TG/DTG/DSC curves revealed that thermal decomposition reactions occur in the liquid phase. The kinetic model that best fitted the experimental isothermal TG data was the one-dimensional phase-boundary reaction-controlled process R1 . The thermal analysis data suggested the thermal stability sequence Cd(S2 CNBun 2 )2 〉Cd(S2 CNPrn 2 )2 〉Cd(S2 CNBui 2 )2 〉Cd(S2 CNEt2 )2 , which accords with the sequence of stability of the apparent activation energies.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 59 (2000), S. 807-814 
    ISSN: 1572-8943
    Schlagwort(e): facial and meridional Co(III) complexes ; kinetics ; thermodynamics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]0.5H2O complexes were investigated by means of DSC and TG techniques. It wasshown that the processes of thermal decomposition of these complexes are multi-stepdegradation processes, which can also be well separated into individual steps, depending onthe molecular symmetry. Thus, the process of thermal degradation of the meridional isomerof the above complex consists of 4 well-separated steps in the temperature interval from 100to 500°C. The corresponding kinetic and thermodynamic parameters of this process weredetermined, and a possible mechanism is discussed.
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  • 51
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 955-965 
    ISSN: 1572-8943
    Schlagwort(e): kinetics ; metal complexes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermogravimetry (TG) and differential thermal analysis (DTA) were performed on the complexes with general formula (M(DEBT)n (where M =Fe, Co, Ni, Cu or Ru; n =2, or 3 and DEBT=N,N-diethyl-N'-benzoylthiourea). Derivative thermogravimetric (DTG) curves were also recorded in order to obtain decomposition data on the complexes. The complexes of Fe(III), Co(II), Ni(II), Cu(II) and Ru(III) displayed two- or three-stage decomposition patterns when heated in a dynamic nitrogen atmosphere. Mass loss considerations relating to the decomposition stages indicated the conversion of the complexes to the sulfides or to the corresponding metal alone (Cu, Ru, NiS, CoS or FeS). Mathematical analysis of the TG and DTG data showed that the order of reaction varied between 0.395 and 0.973. Kinetic parameters such as the decomposition energy, the entropy of activation and the pre-exponential factor are reported.
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 429-433 
    ISSN: 1572-8943
    Schlagwort(e): adsorption ; fast measurement ; gravimetry ; kinetics ; sorption ; kw6
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Jäntti introduced a method to reduce the time required for the stepwise measurement of adsorption isotherms. After each pressure change he measured the adsorbed mass three times and calculated its equilibrium value at the new pressure. In the present paper, we discuss the applicability of this method in a broader scope without starting from a given combination of sorptive and adsorbent and the influence of measuring inaccuracies. The method is applied to detect whether the adsorption process is based on more than one adsorption mechanism or not.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 63 (2000), S. 375-386 
    ISSN: 1572-8943
    Schlagwort(e): activation energy ; ammonium perchlorate ; decompositon ; isothermal ; kinetics ; thermogravimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of the thermal decomposition of ammonium perchlorate at temperatures between 215 and 260°C is studied, in this work, by measuring the sample mass loss as a function of time applying the isothermal thermogravimetric method. From the maximum decomposition rate – temperature dependence two different decomposition stages, corresponding to two different structural phases of ammonium perchlorate, are identified. For the first region (215–235°C), corresponding to the orthorhombic phase, the mean value of the activation energy of 146.3 kJ mol–1, and the pre-exponential factor of 3.43⋅1014 min–1 are obtained, whereas for the second region (240–260°C), corresponding to the cubic phase, the mean value of the activation energy of153.3 kJ mol–1, and the pre-exponential factor of 4.11⋅1014 min–1 are obtained.
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  • 54
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 35-43 
    ISSN: 1572-8943
    Schlagwort(e): kinetics ; 10-methylacridinium halides ; thermodynamics ; thermogravimetric investigations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract 10-Methylacridinium chloride, bromide and iodide were prepared in crystalline forms (the first two salts as monohydrates) and subjected to thermogravimetric investigations. Decomposition of the compounds is initially accompanied by the liberation of water (in case of monohydrates), halomethanes and acridine molecules. As decomposition proceeds, side reactions occur which are reflected in a complex pattern of thermogravimetric curves. TG traces corresponding to the initial decomposition stage were used to determine the kinetic characteristics of the thermal dissociation of the salts. MNDO/d, AM1 and PM3 methods were employed independently to examine reaction pathways and to predict thermodynamic and kinetic barriers for the thermal decomposition of the compounds. These data were subsequently supplemented with theoretically determined crystal lattice energies, which enabled the relevant characteristics for the decomposition of crystalline phases to be predicted. The theoretically predicted characteristics are qualitatively comparable with those originating from thermogravimetric investigations, which allows one to believe that both are valid.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 103-110 
    ISSN: 1572-8943
    Schlagwort(e): cyanazine ; DSC ; kinetics ; thermal stability
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Cyanazine was taken as an example for investigations under the influence of different conditions on thermal decomposition of triazine herbicides. DSC measurements were carried out under atmospheric pressure and hermetically closed, under pressure 1.3 kPa. The influence of the pressure on the constant reaction rate of decomposition of cyanazine was discussed. It was also proved that the predicted reaction constant rates from isothermal and non-isothermal measurements are consistent.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 247-255 
    ISSN: 1572-8943
    Schlagwort(e): desulfuration ; gas atmosphere ; kinetics ; thermal decomposition ; titanium dioxide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The studies were devoted to determination of the effect of gas atmosphere and its pressure on the second step of decomposition of hydrated titanium dioxide (HTD) promoted by sulfate groups. It has been found that thermal decomposition of HTD at temperatures above 300°C consists of a number of processes such as dehydroxylation, desulfuration, recrystallization and sintering of solid grains, photochemical processes (if the decomposition proceeds in the presence of light) and adsorption of gas phase components (in the presence of air or SO2). Kinetic parameters characterizing this step of decomposition have been determined for processes carried out in vacuum and in argon or air atmospheres (at a pressure of 13.33hPa). The kinetic curves of decomposition carried out in the presence of gases capable of being adsorbed on the surface of partly dehydrated HTD are featured by local extrema due to simultaneous processes of decomposition and adsorption of gas components.
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 9-15 
    ISSN: 1572-8943
    Schlagwort(e): coordination compounds ; kinetics ; thermal dissociation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Physicalo-chemical importance of the quantitative study of kineticliability of coordination compounds in thermal dissociation processes is considered. Muchattention is given to the proof of the physicalo-chemical meaning and validity of kineticparameters calculated from thermoanalytical data. Experimental data (thermal dissociation ofcoordination compounds and clathrates with such a matrix) are discussed.
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  • 58
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 401-407 
    ISSN: 1572-8943
    Schlagwort(e): cross-linking ; isothermal crystallization ; kinetics ; modification ; polypropylene ; silica
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The effect of addition of silica on the parameters of isothermal crystallization of polypropylene has been investigated. It was found that the covering of the silica surface by a layer of low-density polyethylene leads to a deactivation of the filler regarding the positive effect on the polypropylene crystallization rate parameters. Cross-linking of the surface polyethylene layer results in a stronger attachment of the modifying polymer to the filler surface and the deactivation effect of the silica surface modification is more pronounced.
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  • 59
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 541-547 
    ISSN: 1572-8943
    Schlagwort(e): Cr(II) ; chromium trioxide ; kinetics ; reduction ; thermal analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The thermal behaviour of CrO3 on heating up to 600°C in dynamic atmospheres of air, N2 and H2 was examined by thermogravimetry (TG), differential thermal analysis (DTA), IR spectroscopy and diffuse reflectance spectroscopy (DRS). The results revealed three major thermal events, depending to different extents on the surrounding atmosphere: (i) melting of CrO3 near 215°C (independent of the atmosphere), (ii) decomposition into Cr2(CrO4)3 at 340–360°C (insignificantly dependent), and (iii) decomposition of the chromate into Cr2O3 at 415–490°C (significantly dependent). The decomposition CrO3 → Cr2(CrO4)3 is largely thermal and involves exothermic deoxygenation and polymerization reactions, whereas the decomposition Cr2(CrO4)3 → Cr2O3 involves endothermic reductive deoxygenation reactions in air (or N2) which are greatly accelerated and rendered exothermic in the presence of H2. TG measurements as a function of heating rate (2–50°C min−1) demonstrated the acceleratory role of H2, which extended to the formation of Cr(II) species. This could sustain a mechanism whereby H2 molecules are considered to chemisorb dissociatively, and then spillover to induce the reduction. DTA measurements as a function of the heating rate (2–50°C min−1) helped in the derivation of non-isothermal kinetic parameters strongly supportive of the mechanism envisaged.
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  • 60
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 60 (2000), S. 667-674 
    ISSN: 1572-8943
    Schlagwort(e): accommodation function ; crystal growth ; glass-ceramics ; kinetics ; number of nuclei ; thermal history
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Kinetic modeling of the crystal growth from pre-existing nuclei was reexamined to obtain a fundamental information about the controlled crystallization of glasses during formation of advanced inorganic glass-ceramics. Methods of kinetic analysis were reviewed by taking account of thermal history of the sample within the temperature range of nucleation. An accommodation function depending on the thermal history was introduced in the kinetic equation. The role of the accommodation function was reinvestigated when determining the activation energy from a series of kinetic curves. The kinetic description of the crystal growth in the samples with different thermal history was generalized by extrapolating the rate behavior to infinite temperature.
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  • 61
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 60 (2000), S. 333-343 
    ISSN: 1572-8943
    Schlagwort(e): base line ; DSC ; kinetics ; modeling ; thermodynamics ; TMDSC
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The application of non-linear heating program to a heat-flux DSC apparatus has attracted much attention. From thermodynamics viewpoint, it is shown that the variation of enthalpy of a sample changing with temperature change is due, to both the true heat capacity of the sample and the enthalpy of some transformations occurring in the sample, characterized by its degree of advance. Using the simple assumption that the rate of the transformation is proportional to the distance from the thermodynamic equilibrium, an electrical model of the thermal event is given. Using the coupled cell model of the DSC apparatus, we show how to obtain the rate of transformation of the sample and heat capacity, which is directly related to the base line of the experiment.
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 759-778 
    ISSN: 1572-8943
    Schlagwort(e): decomposition temperature ; error sources ; gas-flow and vapor control ; kinetics ; thermogravimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The well-known divergence between the present ‘state of the art’ of thermogravimetry and industrial requirements is discussed. Sources of errors are analyzed and the optimization of measuring conditions is discussed regarding the problems associated with static and dynamic (flow) atmospheres, and interactions between materials and gases or vapors. Recommendations for gas-flow control systems and vapor sources are given. Thermal stability and the kinetics of gas-evolving, reversible, thermal decompositions of solids are discussed. The scope of TG-derived kinetics for practical use is examined. Some new characteristic points of TG curves are proposed and defined, e.g. ‘procedure-independent decomposition temperature’ and ‘augmented decomposition temperature’ (obtained at pseudo-equilibrium conditions).
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  • 63
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 879-886 
    ISSN: 1572-8943
    Schlagwort(e): driving force ; kinetics ; rate equation ; reversible reactions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract This paper outlines the different ways of taking the distance from thermodynamic equilibrium into account in kinetic studies based on thermoanalytical experiments. The three main approaches are: (i) avoiding or neglecting the effect of the reverse reaction, (ii) describing the influence of distance from equilibrium on apparent kinetic parameters, and (iii) incorporating a driving force factor in the rate equation. Finally, the contradiction of the microscopic nature of the processes and the macroscopic character of the usual rate equation are briefly discussed.
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  • 64
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 60 (2000), S. 943-954 
    ISSN: 1572-8943
    Schlagwort(e): CRTA ; kinetics ; self-generated atmospheric conditions ; synthetic malachite ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetic behavior of the thermal decomposition of synthetic malachite was investigated by means of CRTA under different conditions of reduced pressure, flowing gases and quasi-isobaric atmospheres. The thermal decomposition was found to proceed at lower temperatures under the influence of the self-generated gases, CO2 and H2O. From a viewpoint of chemical equilibrium, the normal and opposite effects on the overall kinetics were observed for the self-generated CO2 and H2O, respectively. The complexity of the present reaction is also reflected by the variations of the apparent kinetic parameters which depend on the applied and self-generated atmospheric conditions. The practical usefulness of CRTA when applied to a complicated thermal decomposition is discussed as exemplified by the kinetic approaches to the present reaction.
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  • 65
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 151-156 
    ISSN: 1572-8943
    Schlagwort(e): complexes ; kinetics ; TG-DTA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermal behaviour of a few lanthanide complexes of the type ML3(I) [M=Eu,Gd; HL=4,4,4-trifluoro- 1-(2-napthyl)-1,3-butanedione and EuL30.5dmm dmm=2,6-dimethylmorpholine(II)], has been investigated. From thermogravimetric(TG) curves, the decomposition pattern of the compounds has been analysed on the basis of mass loss data. The order and activation energy of the thermal decomposition reactions have been elucidated. From differential thermal analysis (DTA) studies, the heat of reaction and rate of thermal decomposition reaction have been enumerated.
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  • 66
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 239-242 
    ISSN: 1572-8943
    Schlagwort(e): kinetics ; Mannich compounds ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The authors present data concerning the evaluation of kinetic parameters of the decomposition of a Mannich compound by using the classical method of constant heating rate thermal analysis and the new one of controlled rate thermal analysis (CRTA). The data processed using the CRTA method allow to obtain more reliable kinetic parameters according to the proposed reaction mechanism.
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  • 67
    Digitale Medien
    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 437-450 
    ISSN: 1572-8943
    Schlagwort(e): crystallization ; EPDM ; kinetics ; morphology ; PP ; rubber
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The effect of the incorporation of an amorphous immiscible polymer (ethylene-propylene-diene- terpolymer) on the PP crystallization kinetics and thermodynamics is investigated by thermal analysis. The results of the investigation have shown that EPDM acts as a nucleant agent. A marked decrease of the half time of PP crystallization, τ1/2 , as well as a sensible increase of the overall crystallization rate, K n , has been observed in the presence of EPDM. Moreover, at any crystallization temperature, a minimum of τ1/2 , is obtained at 25% EPDM content in the blend. The Avrami model has been successfully applied to describe the crystallization kinetics of the blend. The kinetic curves obtained under non-isothermal conditions confirm the results obtained under isothermal conditions and demonstrate the nucleant action of the EPDM phase on the PP crystallization.
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  • 68
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 62 (2000), S. 721-727 
    ISSN: 1572-8943
    Schlagwort(e): kinetics ; metal exchange ; thermaldehydration ; zeolite
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Zeolite-4A is a hydrated aluminosilicate which becomes more hydrated when exchanged with transition metals. In this work, the dehydration kinetics of cobalt, nickel and copper(II)-exchanged zeolite-4A were studied by means of TG and DTA over the temperature range from 20 to 500°C, and the numbers of water molecules in the metal-exchanged zeolite samples were calculated. It was observed that, as the ionic radius of the hydrated metal increased, the number of water molecules also increased. The loss of water from the zeolite samples generally occurred in the temperature range 100–300°C and was manifested in the DTA graphs by an extended endothermic effect. The DTA curves demonstrated that the peak position shifted towards lower temperatures as the metal concentration increased or, in other words, the water of hydration increased. The kinetic parameters (order of reaction and activation energy) were calculated via the Coats and Redfern method. The process of dehydration was found to follow first-order kinetics.
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  • 69
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 63 (2000), S. 359-374 
    ISSN: 1572-8943
    Schlagwort(e): KEKAM equation ; kinetics ; thermal dissociation of solids
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Relationships have been established between the average conversion degree and the dissociation time for polydisperse granular material, taking its grain size distribution into account. It has been checked in which cases the kinetic curves obtained by a numerical solution can be described in terms of KEKAM equation.
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  • 70
    ISSN: 1572-8943
    Schlagwort(e): isoconversional methods ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract An analysis is presented of the consequences of the use of a one term equation containing apparent activation parameters, instead of the true rate equation to describe two successive decomposition reactions undergone by a solid compound. It is demonstrated that the apparent activation energy, obtained by means of isoconversional differential and integral methods, varies with the conversion degree for a relatively narrow temperature range and with temperature at a given value of the conversion degree. The activation energy values obtained with the isoconversional differential method are higher than the corresponding values obtained with the isoconversional integral method.
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  • 71
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 59 (2000), S. 869-875 
    ISSN: 1572-8943
    Schlagwort(e): decomposition ; kinetics ; plumbo-jarosite
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract An investigation was carried out on the kinetics of thermal decomposition of plumbo-jarosite. The kinetic models of dissociation of the compounds in the ore were identified. The results of the kinetic studies and the mechanism of the process are discussed. The thermal decomposition of plumbo-jarosite occurs in three stages: the first up to 763, the second up to 1023 and the third up to 1223 K, the corresponding activation energy values being 62.2, 60.3 and 98.0 kJ mol–1 , respectively.
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  • 72
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 805-818 
    ISSN: 1572-8943
    Schlagwort(e): aluminium ; ARC ; DSC ; kinetics ; nanometric size ; SDT ; TG
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The thermal properties of Alex, a nanosized Al powder, were determined using various techniques, including DSC, TG, simultaneous TG-DTA (SDT) and accelerating rate calorimetry (ARC). The results demonstrate that the specific heat capacities of nano and micron size Al powders are similar between 30 and 400°C. Dynamic and isothermal methods were used to determine the kinetic parameters for the oxidation reaction of Alex, which was detected at an onset temperature of 481°C. The results obtained were in good agreement with each other. From the ARC experiments, exotherms were detected near 340 and 260°C for experiments started at ambient pressure and at 0.72 MPa, respectively.
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  • 73
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 861-871 
    ISSN: 1572-8943
    Schlagwort(e): DAGN ; kinetics ; mechanism and IR spectroscopy ; TAGN ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Diaminoguanidine nitrate (DAGN) and triaminoguanidine nitrate (TAGN),potential energetic materials in emerging propulsion technology with high mass impetus at low isochoric flame temperature have been studied as regards kinetics and mechanism of thermal decomposition using thermogravimetry (TG), differential thermal analysis (DTA),infrared spectroscopy (IR) and hot stage microscopy. Kinetics of thermolysis has been followed by isothermal TG and IR. For the initial stage of thermolysis of DAGN the best linearity with a correlation coefficient of 0.9976 was obtained for the Avrami-Erofe'evequation, n=2, by isothermal TG. The activation energy was found to be 130 kJ mol–1 and logA=11.4. The initial stage of thermolysis of TAGN also obeyed the Avrami-Erofe'ev equation, n=2, with a correlation coefficient of 0.9975by isothermal TG and the kinetic parameters are E=160.0 kJ mol–1 and logA=16.0. High temperature IR spectra showed exquisite preferential loss in intensity of the NH2, NH, N–N stretching and CNN bending. Spectroscopic and other results favour deamination reaction involving the rupture of the N–N bond as the primary step in the thermal decomposition.
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  • 74
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 61 (2000), S. 979-984 
    ISSN: 1572-8943
    Schlagwort(e): kinetics ; nucleation-growth
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The author presents some applications of the fractal geometry in the kinetics of heterogeneous decomposition of solids.
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  • 75
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 59 (2000), S. 935-942 
    ISSN: 1572-8943
    Schlagwort(e): CoSO46H2O ; kinetics ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Thermogravimetry (TG-DTG), and differential thermal analysis (DTA) were used in the study of the kinetics of decomposition of cobalt sulphate hexahydrate under an air atmosphere. The kinetics of the particular stages of CoSO4 6H2 O decomposition were evaluated from the dynamic mass loss data. The values of the kinetic parameters for each stage of the thermal decomposition were calculated from the α(T) data by using the integral method, applying the Coats-Redfern approximation.
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  • 76
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    Digitale Medien
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    Journal of thermal analysis and calorimetry 62 (2000), S. 681-685 
    ISSN: 1572-8943
    Schlagwort(e): coal-burning additive ; combustion ; graphite ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The catalytic and accelerating effects of three coal-burning additives (CBA) on the burning of graphite were studied with the help of thermogravimetric (TG) analysis. The kinetic study on the catalytic oxidation of the graphite doped with CBA was carried out and the results were presented. The results show that the CBA can change the carbon oxidation/combustion course by catalytic action and change the activation energy, thus improving the combustion efficiency.
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  • 77
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 63 (2000), S. 457-463 
    ISSN: 1572-8943
    Schlagwort(e): isoconversional methods ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract It is demonstrated that, if the activation energy depends on the degree of conversion, its values obtained by isoconversional differential and integral methods are different.
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  • 78
    Digitale Medien
    Digitale Medien
    Springer
    Journal of materials synthesis and processing 8 (2000), S. 139-144 
    ISSN: 1573-4870
    Schlagwort(e): TiO2 ; phase transformations ; mechanical alloying ; kinetics ; modeling
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract A high-pressure and high-temperature phase of TiO2 : TiO2 II is formed transiently during room-temperature high-energy ball milling of anatase TiO2 : TiO2 anatase → TiO2 II → TiO2 rutile. Rutile is the only phase present after prolonged ball milling. The present paper focuses on the influences of physical and chemical processing conditions on the transformation kinetics. The effects of two milling parameters on the kinetics of phase transformation of anatase TiO2 were investigated: the nature of milling tools and the powder-to-ball weight ratio R. Granulometric characterizations and TEM observations have demonstrated that the transformation of TiO2 anatase into TiO2 II occurs without fracturing of particles and that TiO2 II nanograins form at the surface of anatase particles. The parameter R affects only the transformation rate. For a given R, the transformation rate is the largest with alumina grinding tools, intermediate with zirconia tools, and the smallest with steel tools. The parameters involved in current models of the mechanical alloying process do not suffice to explain the differences in transformation rates observed here. A parameter, which takes into account the influence of the mechanical properties of grinding materials, is considered.
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  • 79
    Digitale Medien
    Digitale Medien
    Springer
    Journal of materials synthesis and processing 8 (2000), S. 271-277 
    ISSN: 1573-4870
    Schlagwort(e): Comminution ; kinetics ; mechanical alloying ; phase transformation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract It has been shown that structural evolution occurring in powder mixtures subjected to mechanical treatment by milling follow well-defined conversion trends as a function of milling time. Sigmoidal curves were observed in the case of the mechanical alloying of transition metal mixtures, whereas a simpler kinetic course with a progressively decreasing transformation rate was found to characterize the disordering process of intermetallic equilibrium compounds by mechanical milling. Under the stipulation that collisions are the dominant energy transfer events, a kinetic model is developed to relate the observed macrokinetic features to the discrete powder fractions, which transform at each impact. Because of its intrinsic qualities, the milling process was regarded as discrete processing. A statistical approach was followed to work out a set of differential equations, solutions of which provide a sound description of the transformation kinetics in terms of conventional rate expressions. The model allows one to reproduce the different kinetic behaviors by means of a single, unifying mathematical formalism. Furthermore, quantifying the structural evolution rate by suitable kinetic constants permits the exploration of the reactive behavior of a system treated under different milling regimes or to compare, on an absolute basis, different systems processed under similar conditions.
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  • 80
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 53 (2000), S. 351-360 
    ISSN: 1573-4889
    Schlagwort(e): Co-base superalloy ; high-temperature oxidation ; kinetics ; structure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The oxidation behavior of the Co-base superalloy DZ40M was studied in air at900–1100°C for times of up to 2000 hr. The results indicated thatthis alloy can grow a protective oxide scale at 900 and 1000°C duringisothermal oxidation, but not at 1100°C because of serious cracking andspalling of the oxide scales. Moreover, an internal-precipitate zone formedin the subsurface region of the alloy at all temperatures and times. Theprecipitates were rich in Cr in the vicinity of the alloy–scaleinterface and rich in Al deep in the alloy. The internal-precipitatemorphology changed from a granular to needlelike shape with increasingoxidation temperature.
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  • 81
    ISSN: 1573-4943
    Schlagwort(e): Aluminum ; yeast hexokinase ; preferential interactions ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The aluminum and yeast hexokinase interaction was studied. Structural changes were correlated with variations in protein functionality. Results show two different behaviors: At low metal concentrations preferential adsorption of metal (and water exclusion) induces aggregate formation. No significant changes in the protein structure occur, but there is a continuous loss of activity (from the first concentration). At large salt concentrations a monomerization process and a conformational change in the secondary structure as well as in the three-dimensional structure take place. This change reduces the percentage of α-helix conformation, gives thermal stability to the protein, and allows the exposure of some tryptophan residue and hydrophobic regions. The protein inhibition increases. Conformational change and monomerization may allow access of the metal to the substrate site, mainly the ATP site. The inhibition in any case is of mixed type with a competitive component.
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  • 82
    ISSN: 1573-4943
    Schlagwort(e): Creatine kinase ; human ; expression ; brain ; muscle ; purification ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract We report the expression of the human muscle (CK-MM) and brain (CK-BB) creatine kinases in Escherichia coli. The proteins have been purified to apparent homogeneity and several of their physical and kinetic properties investigated. In the process, we have conclusively verified the correct DNA sequence of the genes encoding the respective isozymes, and determined the correct primary structure and mass of the gene products. Alignment of the primary sequences of these two enzymes shows 81% sequence identity with each other, and no obvious gross structural differences. However, Western blot analyses demonstrated the general lack of antigenic cross-reactivity between these isozymes. Preliminary kinetic analyses show the K m and k cat values for the creatine and MgATP substrates are similar to values reported for other isozymes from various tissues and organisms. The human muscle and brain CKs do not, however, exhibit the synergism of substrate binding that is observed, for example, in rabbit muscle creatine kinase.
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  • 83
    Digitale Medien
    Digitale Medien
    Springer
    Russian chemical bulletin 49 (2000), S. 1974-1976 
    ISSN: 1573-9171
    Schlagwort(e): ammonium dinitramide ; thermal decomposition ; kinetics ; stabilization ; isotope composition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of accumulation of the main products of thermal decomposition of ammonium dinitramide in the melt was investigated. The isotope composition of nitrogen-containing gases evolved by the decomposition of 15NH4N(NO2)2 and NH4 15N(NO2)2 was found. Easily oxidized salts, amines, amides, iodides, and other compounds soluble in the melt interfere with the liquid-phase decomposition of ammonium dinitramide.
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  • 84
    ISSN: 1573-9171
    Schlagwort(e): 2-alkylthiopropenals ; Diels–Alder reaction ; kinetics ; reaction mechanism ; 2,5-dialkylthio-3,4-dihydro-2H-pyran-2-carbaldehyde ; IR spectroscopy ; ab initio calculations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The kinetics of 2-alkylthiopropenals cyclodimerization was studied in the temperature range from -7 to +42 °C in heptane and at 20 °C in various solvents. The rate constants for cyclodimerization of 2-alkylthiopropenals are four orders of magnitude higher than those for dimerization of the oxygen-containing analogs, 2-alkoxypropenals, and are independent of the solvent polarity and substituent steric constant. The activation parameters for 2-butylthiopropenal cyclodimerization were estimated. The distribution of electron density in the 2-methoxy- and 2-methylthiopropenals molecules was calculated by the ab initio method. From comparison of the HOMO and LUMO energies for these aldehydes it was concluded that the ratio between the cyclodimerization rates for 2-alkylthio-, 2-ethoxypropenals, and propenal is determined by the HOMO–LUMO gap.
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  • 85
    ISSN: 1608-3245
    Schlagwort(e): DNA ; kinetics ; oligonucleotide derivatives ; photomodification ; sensitization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Quantitative characteristics of thermodynamic and kinetic cooperativity arising in the process of photomodification of a single-stranded DNA fragment with binary systems of oligonucleotide conjugates forming an active site on the target were studied. Oligonucleotides of the binary system were complementary to adjacent segments of the DNA target, and contained arylazide (X) and perylene (S) residues covalently attached to their terminal phosphates. Upon irradiation at the perylene absorption wavelength, the target was modified by the arylazide residue, which was activated owing to the contiguity with the sensitizing perylene group in the tandem complex. Basing on the kinetic data, the constants of association of both derivatives of oligonucleotides with the target were determined: K x = 1.13 · 106 M–1, K s = 1.49 · 104 M–1. It was determined that association of both oligonucleotides with the target proceeded with a positive cooperativity characterized by parameter α = 45. The kinetic cooperativity parameter β was found to be approximately equal to 200; this characterized the acceleration of target modification in complex with the binary reagent versus that in the absence of sensitizer.
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  • 86
    ISSN: 1608-3407
    Schlagwort(e): Dunaliella salina ; lactate dehydrogenase ; kinetics ; glycerol synthesis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The dependence of the catalytic properties of lactate dehydrogenase (LDH, EC 1.1.1.27) from a halophilic alga Dunaliella salina, a glycophilic alga Chlamydomonas reinhardtii, and from porcine muscle on glycerol concentration, medium pH, and temperature was investigated. Several chemical properties of the enzyme from D. salina differentiated it from the LDH preparation obtained from C. reinhardtii and any homologous enzymes of plant, animal, and bacterial origin. (1) V max of pyruvate reduction manifested low sensitivity to the major intracellular osmolyte, glycerol. (2) The affinity of LDH for its coenzyme NADH dropped in the physiological pH region of 6–8. Above pH 8, NADH virtually did not bind to LDH, while the enzyme affinity for pyruvate did not change considerably. (3) The enzyme thermostability was extremely low: LDH was completely inactivated at room temperature within 30 min. The optimum temperature for pyruvate reduction (32°C) was considerably lower than with the enzyme preparations from C. reinhardtii (52°C) and porcine muscle (61°C). (4) NADH greatly stabilized LDH: the ratio of LDH inactivation constants in the absence of the coenzyme and after NADH addition at the optimum temperature in the preparation from D. salina exceeded the corresponding indices of LDH preparations from C. reinhardtii twelve times and from porcine muscle eight times. The authors believe that these LDH properties match the specific metabolism of D. salina which is set at rapid glycerol synthesis under hyperosmotic stress conditions. The increase of cytoplasmic pH value produced in D. salina by the hyperosmotic shock can switch off the terminal reaction of the glycolytic pathway and thus provide for the most efficient utilization of NADH in the cycle of glycerol synthesis. As LDH is destabilized in the absence of NADH, this reaction is also switched off. In the course of alga adaptation to the hyperosmotic shock, glycerol accumulation and the neutralization of intracellular pH stabilize LDH, thus creating the conditions for restoring the complete glycolytic cycle.
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  • 87
    ISSN: 1573-4986
    Schlagwort(e): β-glycosidase ; temperature dependence ; kinetics ; glucose ; transglycosylation ; (Thermus thermophilus)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A β-glycosidase of a thermophile, Thermus thermophilus, belonging to the glycoside hydrolase family 1, was cloned and overexpressed in Escherichia coli. The purified enzyme (Ttβgly) has a broad substrate specificity towards β-D-glucoside, β-D-galactoside and β-D-fucoside derivatives. The thermostability of Ttβgly was exploited to study its kinetic properties within the range 25–80[emsp4 ]°C. Whatever the temperature, except around 60[emsp4 ]°C, the enzyme displayed non-Michaelian kinetic behavior. Ttβgly was inhibited by high concentrations of substrate below 60[emsp4 ]°C and was activated by high concentrations of substrate above 60[emsp4 ]°C. The apparent kinetic parameters (k cat and K m ) were calculated at different temperatures. Both k cat and K m increased with an increase in temperature, but up to 75[emsp4 ]°C the values of k cat increased much more rapidly than the values of K m . The observed kinetics might be due to a combination of factors including inhibition by excess substrate and stimulation due to transglycosylation reactions. Our results show that the substrate could act not only as a glycosyl donor but also as a glycosyl acceptor. In addition, when the glucose was added to reaction mixtures, inhibition or activation was observed depending on both substrate concentration and temperature. A reaction model is proposed to explain the kinetic behavior of Ttβgly. The scheme integrates the inhibition observed at high concentrations of substrate and the activation due to transglycosylation reactions implicating the existence of a transfer subsite.
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  • 88
    Digitale Medien
    Digitale Medien
    Springer
    Journal of applied spectroscopy 67 (2000), S. 981-989 
    ISSN: 1573-8647
    Schlagwort(e): nonlinear regime of stimulated Raman scattering ; fluctuation ; Stokes radiation ; kinetics ; spectrum ; distribution function
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Statistical properties of the Raman scattering of an intense step pulse are investigated by numerical solution of the equations of a semi-classical theory with assignment of a random Gaussian distribution of the initial polarization over the sample. The probability density functions of the intensity, energy, delay time, and width of a Stokes pulse and also of the position, height, and width of the spectral peaks of the first incidental Stokes component with the preservation of the phase memory of scattering centers are calculated. The influence of collisional dephasing on the fluctuation of these characteristics is considered.
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  • 89
    Digitale Medien
    Digitale Medien
    Springer
    Powder metallurgy and metal ceramics 39 (2000), S. 540-544 
    ISSN: 1573-9066
    Schlagwort(e): compaction ; facing ; cumulative charge ; powder ; composite ; heterogeneous structure ; particle ; kinetics ; surface ; die ; model ; xeroradiogram
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract An experimental and numerical (finite element method) study is carried out for the effect of forming scheme on property distribution for cumulative charge facings made from composite heterogeneous powder material. An experimental procedure is developed for studying powder particle flow kinetics. It is shown that use of composite punches and partition of the moulded material into a number of sub-divisions with their successive compaction achieves a more uniform density distribution for an article. It is demonstrated how the direction of the force of friction on the die walls during compaction affects the compaction of articles with faces that are not perpendicular to the direction of the pressing. The results obtained make it possible to select the optimum compaction regime taking account of production features connected with powder material composition as well as service characteristics.
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  • 90
    Digitale Medien
    Digitale Medien
    Springer
    Pharmaceutical research 17 (2000), S. 701-706 
    ISSN: 1573-904X
    Schlagwort(e): vapor sorption ; molar heat of adsorption ; kinetics ; isothermal microcalorimetry ; recrystallization ; hydration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Purpose. In this study, instrumentation for measuring vapor sorptionenthalpies and sorption uptakes simultaneously with an isothermalmicrocalorimeter is introduced. Various pharmaceutical modelsubstances undergoing phase transitions when exposed to humid conditions(25°C), were employed to evaluate the usefulness and sensitivity ofthe constructed experimental method. Methods. The sample is placed in the sample vessel of a RH cell andthe moisture content of the air flow is controlled. From the RH cellthe air flow is conducted into a subsequent perfusion cell in which asaturated salt solution has been loaded. The RH cell and perfusioncells are positioned in the sample sides of two twin calorimetric units.Depending on the moisture content in the outlet flow leaving thepreceding RH cell, the heat flow signal from the subsequent perfusioncell will vary. By means of blank measurement with identical settings,the rate of water sorption can be calculated and, by integration, theamount of sorbed water is obtained. Results. Amorphous lactose and cefadroxil undergo recrystallizationwhen the moisture level in the surroundings exceeds the thresholdvalues specific to each compound. During the sorption phase, heat isevolved fairly linearly as a function of consumed moisture, and alsoafter the recrystallization, the heats indicate linear behavior. The heatvalues for the desorption phase of amorphous lactose and the adsorptionof crystalline lactose coincide. With the different anhydrous forms oftheophylline, the hydration takes place more rapidly in the metastableform I, and generally, the process is more energetic in form I. In allcases, the gravimetric results agree with the water sorption uptakescalculated from the calorimetric data. Conclusions. The technique introduced offers a rapid and sensitivemethod to gain new insights into the transitions in which vapors areinvolved. In addition, different kinds of surfaces with various energeticscan now be studied more closely.
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  • 91
    ISSN: 1573-515X
    Schlagwort(e): gaseous ; kinetics ; mercury ; methods ; speciation ; waters
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Mercury evasion from water is commonly modeled using measurements of dissolved gaseous mercury (DGM). We developed a method using a recently available automated field-ready mercury vapor analyzer to rapidly measure the concentrations of DGM in surface waters. We summarize here results of laboratory tests of the method, field intercomparisons with a manual method, and selected data from recent sampling campaigns in Florida and Michigan. The method uses the 1.5 lpm flow of a Tekran® Model 2537A mercury analyzer to purge and analyze discrete water samples, generating near real time (5-min) data on DGM in samples and blanks. Application of the Tekran allowed for detailed analysis of DGM removal kinetics and short-term diel studies characterizing the influence of sunlight and precipitation on DGM production in surface waters. Gas removal kinetics for dozens of samples indicates a first-order rate constant, and supports a 20-min. purge time for surface water samples from Florida (40-min for Michigan samples). Blanks are measured during a second such purge. Our results indicate that DGMs determined by both automated and manual methods are generally comparable, and that DGM in Florida samples is unstable during storage (loss rate constant ∼0.1--0.2 h-1), probably due to oxidation. This suggests that rapid in-field analysis is preferred to storage with delayed analysis. Our data indicate that DGM at the Florida site is influenced by inputs of reactive Hg in rainwater, and by production of surface DGM during photoreduction of oxidized Hg in the water column.
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Genetica 108 (2000), S. 229-237 
    ISSN: 1573-6857
    Schlagwort(e): autoregulation ; dimerization ; kinetics ; post-transcriptional regulation ; transposable elements (TEs)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Kinetic modeling of the self-regulatory mechanisms of transposable elements (TEs) involving interactions of one or a few gene products makes predictions that are often at odds with observed results. In particular, explanations of TE autorepression at high copy number that invoke a decrease in number of active monomers through dimerization, amyloidization, and protein-mRNA binding to create an inactive state are not supported by analysis of the corresponding kinetic models. This is also true for similar mRNA–mRNA binding models. Self-repression in marineras well as other TEs can, however, be explained by a host-independent model in which inactive dimers compete with monomers for TE binding sites at the ends of the element. This model would also allow heterodimer poisoning to down-regulate transposition in the presence of divergent nonautonomous elements, since nondivergent monomers would be required at both TE ends for transposition.
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  • 93
    Digitale Medien
    Digitale Medien
    Springer
    Journal of bioenergetics and biomembranes 32 (2000), S. 91-96 
    ISSN: 1573-6881
    Schlagwort(e): Permeability transition ; ADP/ATP translocase ; kinetics ; adenosine diphosphate ; carboxya tractyloside ; bongkekic acid ; mitochondria
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie , Physik
    Notizen: Abstract Low levels of ADP binding at the ADP/ATP translocase caused inhibition of the Ca2+-inducedpermeability transition of the mitochondrial inner membrane, when measured using the shrinkage assay on mitochondria, which have already undergone a transition. Inhibition was preventedby carboxyatractyloside, but potentiated by bongkrekic acid, which increased the affinity forinhibition by ADP. This suggests that inhibition was related to the conformation of thetranslocase. Ca2+ addition was calculated to remove most of the free ADP. Ca2+ added after ADPinduced a slow decay of the inhibition, which probably reflected the dissociation of ADP fromthe translocator. We conclude that the probability of forming a permeability transition pore(PTP) is much greater when the translocase is in the CAT conformation than in the BKAconformation, and, in the absence of CAT and BKA, the translocator is shifted between theBKA and CAT conformations by ADP binding and removal, even in deenergized mitochondria with no nucleotide gradients.
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  • 94
    Digitale Medien
    Digitale Medien
    Springer
    Journal of clinical monitoring and computing 16 (2000), S. 219-222 
    ISSN: 1573-2614
    Schlagwort(e): Neuromuscular relaxants ; rocuronium ; kinetics ; distribution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Informatik , Medizin
    Notizen: Abstract Objective.To determine the relationship between the rate ofrocuronium injection and the onset time of neuromuscular block. Methods.After intravenous induction, 60 female patients (ASA I–II) wereassigned randomly into 3 groups for rocuronium administration within1–15, 15–30 or 30–60 seconds. Acceleromyography of the thumbwas performed using train-of-four (TOF) stimulation. Times to 50% and 90%twitch depression of the first twitch of the TOF stimulation (T1) wererecorded. Results.Injection time significantly influences time to 50%relaxation, but not time to 90% relaxation. Body mass index is negativelycorrelated with time to 50% and 90% relaxation. Conclusions.Weconclude that rate of injection influences only the initial phase ofdevelopment of the block and that slower injection times do not significantlyaffect time to 90% relaxation at the adductor pollicis muscle.
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Journal of clinical monitoring and computing 16 (2000), S. 351-360 
    ISSN: 1573-2614
    Schlagwort(e): carbon dioxide ; oxygen ; kinetics ; non-steady state ; cardiac output ; PEEP ; pulmonary embolism ; pulmonary gas exchange monitoring
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Informatik , Medizin
    Notizen: Abstract Traditionally, the study of CO2 and O2 kinetics in the body has been mostly confined to equilibrium conditions. However, the peri-anesthesia period and the critical care arena often involve conditions of non-steady state. The detection and explanation of CO2 kinetics during non-steady state pathophysiology have required the development of new methodologies, including the CO2 expirogram, average alveolar expired PCO2, and CO2 volume exhaled per breath. Several clinically relevant examples of non-steady state CO2 kinetics perturbations are examined, including abrupt decrease in cardiac output, application of positive end-expiratory pressure during mechanical ventilation, and occurrence of pulmonary embolism. The lesser known area of non-steady state O2 kinetics is introduced, including the measurement of pulmonary O2 uptake per breath. Future directions include the study of the respiratory quotient per breath, where the anaerobic threshold during anesthesia is identified by increasing respiratory quotient.
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  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Water resources management 14 (2000), S. 417-434 
    ISSN: 1573-1650
    Schlagwort(e): adsorption ; feldspar ; industrial effluent ; pollution control ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Geographie
    Notizen: Abstract Feldspar, among many natural substances such as termitemount-clay, saw-dust, kaolinite and dolomite, offers asignificant removal ability for sulfate, phosphate, and coloredsubstances. Optimization of experimental parameters such assolution pH and flow rate reveals, that the maximum efficiency forremoval of phosphate, sulfate, and colored substances is about42, 52, and 73% respectively. X-ray diffraction, adsorptionisotherm and recovery studies suggest, that the removal processof anions occurs via ion exchange in conjunction with surfaceadsorption. Furthermore, reaction rate studies indicate thatthe removal of the selected pollutants by feldspar follows first-order kinetics. Although the percent removal, under the optimized conditions, is higher for laboratory prepared solutions, efficiency is a little less for industrial effluentsdue to interferent effects.
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 353-363 
    ISSN: 1572-8943
    Schlagwort(e): controlled environment ; high-T c superconductors ; kinetics ; microgravimetric investigations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Many properties of oxide superconductors depend on the oxygen concentration and its distribution in the samples. The microgravimetric method is very useful to study of oxide superconductors, as it allows investigations in vacuum and controlled environments in classical applications: thermogravimetric analysis for the study of solid-state reactions, determinations of oxygen contents in redox reactions and the combined measurement of mass and additional parameters, e.g. evolved gas analysis etc. Single-phase samples of high-temperature superconductors were synthesized from stoichiometric mixtures of high-purity oxides and carbonates. Appropriate amounts of the precursor powders were homogenized manually or by a mechanical ball mill and subsequently calcined at temperatures in the 800 to 950°C range with intermediate grinding to ensure homogenous reaction. The lattice parameters of all preparations were controlled, in both initial and final experiments, by the X-ray powder method (CuKα radiation), using a Stadi P (Stoe) diffractometer with a position-sensitive detector. It is well known that temperature and mass can be measured with an accuracy higher by orders of magnitude than it is still possible for the thermoanalyst to determine the transformation temperatures or the mass changes due to overlapping partial reactions. Applications of Cahn microbalance to study of high-temperature superconductors are presented.
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  • 98
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 747-755 
    ISSN: 1572-8943
    Schlagwort(e): benzoic acid ; europium complex ; kinetics ; non-isothermal ; thermal decomposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The thermal decomposition of Eu2(BA)6(bipy)2 (BA=C2H5N– 2, benzoate; bipy=C10H8N2, 2,2'-bipyridine)and its kinetics were studied under the non-isothermal condition by TG-DTG, IR and SEM methods. The kinetic parameters were obtained from analysis of the TG-DTG curves by the Achar method, the Madhusudanan-Krishnan-Ninan (MKN) method, the Ozawa method and the Kissinger method. The most probable mechanism function was suggested by comparing the kinetic parameters. The kinetic equation for the first stage can be expressed as: dα/dt=Aexp(–E/RT)3(1–α)2/3.
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  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 63 (2000), S. 397-413 
    ISSN: 1572-8943
    Schlagwort(e): Cu–5 at%Zn ; DSC ; F.C.C. (Face Centered Cubic) ; kinetics ; short-range-order ; solute-vacancy complexes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A modified first order kinetic law, which describes the roles of bound and unbound vacancies, is proposed in order to predict defect decay and short-range-order kinetics of quenched binary alloys during linear heating experiments. The model has been applied to differential scanning calorimetry (DSC) curves of Cu–5 at%Zn quenched from different temperatures. Activation energy for migration of solute-vacancy complexes was also assessed from the kinetics of short-range-order using DSC traces. A value of 89.5±0.32 kJ mol–1 was obtained. The relative contribution of bound and unbound vacancies to the ordering process as influenced by quenching temperature was determined. In conjunction, a parametric study of the initial total defect concentration and effective energy for defect migration was performed in order to envisage their influence on the calculated DSC profiles.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 60 (2000), S. 25-33 
    ISSN: 1572-8943
    Schlagwort(e): DSC ; kinetics ; thermal decomposition ; 2,4,6-trinitrotoluene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract An autocatalytic model involving the limited solubility of volatile catalytic products was applied to the thermal decomposition of 2,4,6-trinitrotoluene. The critical supersaturation of the thermal decomposition products with the catalytic properties was higher at a low heating rate. Decrease of the sample mass led to an increased critical supersaturation of the decomposition products. This is probably a result of the greater contribution of products adsorption on the aluminium pan surface. It is presumed that the differences observed in the rate constant are connected with the uncontrolled critical supersaturation of the volatile thermal decomposition products.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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