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  • Articles  (39)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (23)
  • 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring  (11)
  • Mt. Etna  (9)
  • 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes
  • CO2
  • Elsevier Science Limited  (30)
  • IEEE  (4)
  • EGU  (3)
  • American Institute of Physics (AIP)
  • Copernicus
  • 2010-2014  (39)
  • 1995-1999
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  • Articles  (39)
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  • 1
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: In this work we show that the main springs of the central Apennine transport a total amount of heat of ∼2.2 109 J s−1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values 4300 mWm−2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.
    Description: Published
    Description: 65–74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: heat flux ; CO2 Earth degassing ; central Apennine ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: The shallow thermal aquifer at Vulcano Island is strongly affected by deep volcanic fluids. The most significant variations were observed during the 1989–1996 crisis due to a large input of steam and acidic gases from depth. Besides chemical variations related to the input of deep fluids, the record of the water-table elevation at monitored wells has provided remarkable insights into the pressure conditions of the volcano-hydrothermal system. After the pressure drop due to the extensive vaporization of the hydrothermal aquifer, occurred after 1993, the volcano-hydrothermal system has been re-pressurized since 2001, probably because of the contribution of volatiles from the hydrothermal-magmatic source. The increase in fluid pressure may have caused reopening of fractures (which had self-seated during the previous period of cooling) and the onset of a phase of higher vapor output in the fumarole field later in 2004. The fracture opening would have promoted further vapor separation from the deep fluid reservoir (hypothesized at 0.5–1.5 km depth) and finally the drainage of S-rich fluids into the shallow thermal aquifer (found out at few tens of meters of depth). The monitoring of both the water chemistry and the water-table elevation provides insights into the eventual pressurization of the volcano-hydrothermal system that precedes the fracture opening and the extensive drainage of deep fluids. The findings of this study could represent crucial information about the stability of the volcano edifice, and lead to reliable techniques for determining the risk of or even predicting phreatic explosions.
    Description: Published
    Description: 70-80
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrothermal system ; Vulcano Island ; Fluid pressure ; Thermal wells ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2024-05-09
    Description: Copahue volcano is part of the Caviahue–Copahue Volcanic Complex (CCVC),which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina–Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe–Ofqui strike slip and the northern Copahue–Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from −8.8‰ to −6.8‰ vs. V-PDB), δ15N values (+5.3‰ to +5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°–220 °C. On the contrary, rock–fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006–2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and isotope variations were likely related to injection of mafic magma that likely triggered the 2000 eruption. Therefore, changes affecting the magmatic systemhad a delayed effect on the chemistry of the CCVC gases due to the presence of the hydrothermal reservoir. However, geochemical monitoring activities mainly focused on the behavior of inert gas compounds (N2 and He), should be increased to investigate the mechanism at the origin of the unrest started in 2011.
    Description: Published
    Description: 44–56
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Copahue volcano ; Fumarolic fluid ; Hydrothermal reservoir ; Volcanic unrest ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2024-05-09
    Description: Measurements of soil fluxes of hydrothermal gases, with special emphasis on C6H6, as well as chemical composition of mono-aromatic compounds in fumaroles and air, were carried out in April 2012 at the Solfatara crater (Campi Flegrei, Southern Italy) to investigate the distribution and behavior of these species as they migrate through the soil from their deep source to the atmosphere. Soil fluxes of CO2, CH4 and C6H6 exhibit good spatial correlation, suggesting that diffuse degassing is mainly controlled by local fractures. The calculated total output of diffuse C6H6 from Solfatara is 0.10 kg day 1, whereas fluxes of CO2 and CH4 are 79 103 and 1.04 kg day 1, respectively. A comparison between soil gas fluxes and fumarole composition reveals that within the crater soil CH4 is significantly affected by oxidation processes, which are more efficient for low gas fluxes, being dependent on the residence time of the uprising hydrothermal gases at shallow depth. Benzene degradation, mainly proceeding through oxidation via benzoate, seems to be strongly controlled by the presence of a shallow SO2 4 -rich aquifer located in the central and southwestern sectors of the crater, suggesting that the process is particularly efficient when SO2 4 acts as terminal electron acceptor (SO4 reduction). Relatively high C6H6/C7H8 ratios, typical of hydrothermal fluids, were measured in air close to the main fumarolic field of Solfatara crater. Here, C6H6 concentrations, whose detection limit is 0.1 lgm 3, are more than one order of magnitude higher than the limit value for ambient air (5 lgm 3). This suggests that hydrothermal fluids have a strong impact on air quality in the immediate surroundings of the fumarolic vents. Significant concentrations of endogenous mono-aromatics were also detected in air samples collected from the northern and western sides of the crater, where these gas compounds are mostly fed by diffuse degassing through the crater bottom soil.
    Description: Published
    Description: 142–153
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal gases ; Solfatara crater ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2020-12-15
    Description: determined for evaluating its possible use as an isotopic tracer of the local groundwater recharge. These spot measures were compared with a longer series of local rain and spring compositions and with other samples taken, under different hydrogeological conditions, in caves of the Harz Mountains (Northern Germany). The slow flowing dripwater from Sicily showed d18O/dD ratios similar to those of local rain and groundwater, demonstrating that these three are all parent waters. A parallel similarity was found in the vertical isotopic gradient (Dd18O) of the three groups of water, accounting for their common meteoric origin. In the colder Harz Region, dripwater, spring water and rain have the same d18O/dD ratio but fast flowing dripwater, infiltrating through open cracks, is significantly enriched in lighter isotopes and representative of short residence time percolation. These results lead to the conclusion that dripwater, even if collected as spot samples, can be considered as a good isotopic marker of the average local groundwater recharge on the condition that only slow, diffused drips due to seepages are sampled.
    Description: Published
    Description: 231-239
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: restricted
    Keywords: Harz Mountains ; Isotopic composition ; Rain ; Groundwater ; Dripwater ; Sicily ; Rain ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: Considerable seepage of natural gas occurs throughout the Katakolo Bay, both at sea and on land, along the Ionian coast of Peloponnesus (Western Greece). Explosive levels of CH4 and toxic concentrations of H2S accumulating in the ground, pose a severe hazard for humans and tourist infrastructures. A wide offshore and onshore gas survey, including marine remote sensing, underwater exploration by a towed instrumented system, compositional and isotopic analyses, and flux measurements of gas, allowed us to assess that: (a) gas seepage takes place along two main normal faults; (b) offshore side-scan sonographs recorded at least 823 gas bubble plumes over an area of 94,200 m2, at depths ranging from 5.5 to 16 m; (c) offshore and onshore seeps release the same type of thermogenic gas (δ13CCH4~−34 to −36‰); (d) offshore gas showed increased stable carbon isotopic ratio of CO2 and propane, which suggests enhanced biodegradation of hydrocarbons; (e) isotopic data combined with thermogenic gas generation modeling and maturity plots, suggest that the gas is related to a deep Petroleum System with Jurassic carbonate reservoirs, Triassic source rocks, and Triassic evaporites; (f) H2S (δ34S: +2.4‰) is produced by thermochemical sulfate reduction in deep anhydrites, in contact with hydrocarbon-rich carbonates; (g) due to the shallow depth, more than 90% of CH4 released at the seabed enters the atmosphere, consistent with theoretical bubble dissolution models, with a mean plume output of 0.12 kg d−1; total offshore CH4 output was estimated in the range of 33 to 120 t y−1; and (h) in the onshore area at least 50 gas vents in the harbor and a large seep on the adjacent Faros hill, emit in total about 89 t CH4 y−1. Katakolo results to be one of the biggest thermogenic gas seepage zones in Europe.
    Description: Published
    Description: 115–126
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Gas seeps ; Thermogenic methane ; Bubble plumes ; Hydrocarbon biodegradation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: This study assessed the use of a H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
    Description: Published
    Description: 41–51
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux ; H2 monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: Mud volcanoes (MVs) are considered important methane (CH4) sources for the atmosphere; gas is not only released from macro-seepage, i.e., from craters and visible gas bubbling manifestations, but also from invisible and pervasive exhalation from the ground, named miniseepage. CH4 flux related to miniseepage was measured only in a few MVs, in Azerbaijan, Italy, Japan, Romania and Taiwan. This study examines in detail the flux data acquired in 5 MVs and 1 ‘‘dry’’ seep in SW Taiwan, and further compares with other 23 MVs in Italy, Romania and Azerbaijan. Miniseepage from the six manifestations in SW Taiwan MVs and seeps annually contribute at least 110 tons of methane directly to the atmosphere, and represents about 80% of total degassing during a quiescent period. Combining miniseepage flux and geo-electrical data from the Wu-shan-ding MV revealed a possible link between gas flux and electrical resistivity of the vadose zone. This suggests that unsaturated subsoil is a preferential zone for shallow gas accumulation and seepage to the atmosphere. Besides, miniseepage flux in Chu-huo everlasting fire decreases by increasing the distance from the main gas channeling zone and molecular fractionation (methane/ethane ratio) is higher for lower flux seepage, consistently with what observed in other MVs worldwide. Measurements from Azerbaijan, Italy, Romania, and Taiwan converge to indicate that miniseepage is directly proportional to the vent output and it is a significant component of the total methane budget of a MV. A miniseepage vs. macro-seepage flux equation has been statistically assessed and it can be used to estimate theoretically at least the order of magnitude of the flux of miniseepage for MVs of which only the flux from vents was evaluated, or will be evaluated in future. This will allow a more complete and objective quantification of gas emission in MVs, thus also refining the estimate of the global methane emission from geological sources.
    Description: Published
    Description: 3–12
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mud volcano ; Miniseepage ; Macro-seepage ; Global methane emission ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 11
    Publication Date: 2017-04-04
    Description: About 120 rainwater samples were collected through a network of five bulk collectors in the area of the Louros basin (Epirus, Greece) during the wet season from October 2008 to August 2009. They were analysed for their isotopic (δD and δ18O) and chemical (H+, Na+, K+, Mg2+, Ca2+, NH4 +, F−, Cl−, Br−, NO3 −, SO4 2 −) composition. A local meteoric water line (δD‰ = 5.80 ± 0.02 δ18O‰ + 0.02 ± 0.12) and a local isotopic lapse rate (−0.18 δ18O‰/100 m) were obtained considering the volume-weighted means of the five sampling sites. These results agree well with those obtained in nearby areas. The chemical composition of the samples allows to identify an almost entirely marine origin for chloride and sodium with decreasing deposition values at increasing distance from the coast. Nitrate and ammonium are almost completely of anthropogenic origin, calcium and potassium are overwhelmingly geogenic, sulphate has a prevailingly anthropogenic origin with a significant marine contribution and magnesium has a mixedmarine and soil dust origin. Finally, as for most of the Mediterranean area, rainwater acidity is buffered by the dissolution of the abundant geogenic carbonate aerosol.
    Description: Published
    Description: 399-410
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: Precipitation ; Neutralization ; Stable isotopes ; Chemical composition ; Bulk deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: Herein we report on the chemical and isotopic (C, H, O, and He) compositions of the fluids from La Fossa crater fumaroles of Vulcano from 1999 to 2010. Consistent with records obtained since the end of the 1980s, our data show that the geochemical features of the fumarole system have experienced several episodes of remarkable change, each lasting no more than a few months. Typical signatures of these short-term anomalies are large increments in CO2, N2, and He concentrations, coupled to increased 13C/12C isotopic ratios, but their meaning remains widely debated. Within a model of fumarolic fluids based on mixing between hydrothermal and magmatic endmembers, we have developed a novel approach to constrain chemical (He/ CO2 and N2/He) and isotopic (13C/12C, D/H, and 3He/4He) ratios of the magmatic endmember during the short-term anomalies. Although much of the geochemical variability in fumaroles results from changes in mixing proportions, the magmatic fluid unquestionably shows significant variations in time. The magmatic He/CO2, N2/He, 13C/12C, and 3He/4He values throughout 1988–1996 differed from those feeding the anomaly at the end of 2004. Early clues of the new magmatic fluid appeared in 1998–1999, far from any short-term anomaly, whereas new and old magmatic fluids coexisted after 2004. We quantitatively prove that the detected geochemical changes are consistent with the degassing path of a magma having a latitic composition, and suggest the presence of two magma ponding levels at slightly different pressures, where bubble–melt decoupling can occur. The different He-isotope compositions at these levels suggest low hydraulic connectivity typical of a complex reservoir with dike and sill structures. In this framework, the short-term geochemical anomalies are probably due to gas accumulation at the top of magma bodies followed by massive escape, or activation of new degassing levels in the reservoir, for which the stress field almost certainly plays a key role. Such a scenario explains the observed increases in both fumarole output and shallow high-frequency seismicity (due to increased pore pressure) during the anomalies, while being consistent with the concomitant absence of any deep seismicity or ground deformation, eventually related to magma movement.
    Description: Published
    Description: 158-178
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: fumarole geochemistry ; magma degassing ; thermodynamic modeling ; noble gas geochemistry ; carbon isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2017-04-04
    Description: Herein, we present a method for continuous measurement of soil CO2 flux that is completely new and distinct from existing instruments. The foremost difference is that instead of using an infrared gas analyser (IRGA), the new device measures soil CO2 flux by means of a simple pressure sensor, measuring pressure transients inside a closed polymeric tube inserted into the soil. This allows continuous measurements even in soil placed in environments that could potentially damage IRGA. In addition, due to the innovative operating principle, measurements of soil CO2 flux can be effortlessly performed also in strongly harsh weather conditions. Theoretical equations were derived for calculating soil CO2 flux solely using measured transient values. The reliability of the equations was rigorously tested with a variety of experiments. Continuous measurements over four months, acquired in a high-emission area on the Island of Vulcano, compared favourably with the data obtained using an established method.
    Description: Published
    Description: 102-109
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Soil CO2 flux measurements ; Continuous monitoring ; Methods of measurement ; Polymeric membranes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 14
    Publication Date: 2017-04-04
    Description: Our study is aimed to develop a 3D physical model of the Campi Flegrei geothermal system, in order to achieve a more accurate and comprehensive representation of the hydrothermal processes occurring in the caldera. The new model, developed by using the TOUGH2 code simulator, accounts for the caldera rocks' physical properties, bathymetry and water table topography. In particular, the computational domain is constrained by density values obtained by tomographic inversion of gravity data collected during several surveys at CF both onshore and offshore the caldera. Empirical relations between density and porosity and between porosity and permeability, derived by published data on samples cored in deep wells or collected in outcrops, allowed us to characterize the main rocks physical parameters controlling the dynamic of the CF geothermal system. We have performed and compared several simulations investigating the effects of the injection at depth, underneath Solfatara crater, of a hot gaseous mixture rich in CO2. We show that, with respect to the available literature on 2D axisymmetric models, the effects of the water table topography together with the bathymetry and the heterogeneous distribution of the rocks' physical properties, lead to important differences in the hydrothermal circulation of fluids at CF. These constraints allow the activation of convective cells with different behaviors, which produce variable patterns of temperature inside the hydrothermal system. As a consequence, the predominant effect is again represented by a central plume below the Solfatara crater, but with a non-axisymmetric structure and a wider extension. Additionally, high temperature zones are present near the coastline and in the middle part of the submerged area of the caldera with a SE–NW alignment. Moreover, our results indicate that, the submerged part of the CF caldera would deserve a more accurate study and survey, being affected by phenomenon of heating and degassing. This information could be very useful in terms of hazard assessment and volcanic risk mitigation in such an active and densely inhabited volcanic and geothermal area.
    Description: Published
    Description: 172-182
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Geothermal system ; 3D model ; Water table topography ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2017-04-04
    Description: Epidermis micromorphology of in situ Erica arborea L. exposed for generations to long-term effect of volcanic gases in Pisciarelli and Solfatara di Pozzuoli areas have been studied by X-ray analyses, SEM and TEM observations. In particular, the aim of this study is to investigate the effects of volcanic gases on extant and possibly fossil plants. Plants of the same species living in a nearby control site were also studied for comparison. SEM coupled with EDX analysis was used to localize different elements within the leaves (mesophyll, cell wall and cuticle). After conventional and cryo preparation, SEM of mature leaves ascertained that the abaxial side is more serrate in fumigated leaves and hairs, epicuticular wax alterations have also been noted. Leaves experiencing chronic fumigation display stomata more sunken with respect to the epidermal surface. TEM of transverse and longitudinal sections of cuticle showed an outer A2 granular amorphous layer and external to a B1 fibrillous layer. Significant statistical variations of ultrastructural components of the cuticle revealed a response of E. arborea to this extreme environment. At the ultrastructural level, significant variations in thickness of the cell wall plus cuticle, cell wall and A2 layer among fumigated and non-fumigated leaves have been found. In the studied localities a positive correlation between atmospheric CO2 concentration and the thickness of A2 layer also exists. The results are of interest being applicable in the understanding of plant cuticle responses during periods of normal vs. volcanic activity.
    Description: Published
    Description: 197– 206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Phlegrean Fields ; Erica arborea ; Volcanic gases ; Epidermis ; Cuticle ultrastructure ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 16
    Publication Date: 2017-04-04
    Description: We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; 〉300°C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (37Cl values ≈ 0 ± 0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (37Cl values 〉 15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, 37Cl values are not affected by magma degassing for residual fractions ≥ 0.3 in the melt, or any effect is within our data variability. Finally, 37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.
    Description: Published
    Description: 134-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; chlorine isotope ; plume ; fumarole ; degassing ; mantle source ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: On 13 May 2008, an eruption began at Mt. Etna from an eruptive fissure that opened on the upper eastern flank of the volcano. During 12-13 May, 157 infrasonic events, together with the related seismic transients, were collected. We carried out several analyses to obtain dominant frequencies, pseudospectrograms, peak-to-peak amplitudes, source locations and time lags between infrasonic and seismic events. Spectra of the infrasonic events show two main spectral peaks in the frequency bands ~0.4-0.7 Hz and 1.5-2.0 Hz, respectively. Both infrasonic and seismic events were separately located below the North-East Crater, where no eruptive activity was observed. Moreover, significant changes in infrasound spectral content, as well as in the infrasonic-seismic lags, were found a few hours before the beginning of the eruption. On the basis of the collected information the infrasound source mechanism was modelled as a superposition of pipe and Helmholtz resonance, also leading to outline the geometry of the shallower portion of the North-East Crater plumbing system. The occurrence of these seismo-infrasonic events together with other geological and geophysical evidences, led us to inferring a direct link between North-East Crater activity and the eruptive fissure. Further, based on variations over time of both spectral features and seismicinfrasonic time lag, shallowing phenomena of the free magma column inside North-East Crater conduit were hypothesized. Such an uprise of magma was likely caused by a pressure increase inside the plumbing system occurring before the beginning of the 2008-2009 eruption.
    Description: Published
    Description: 53-68
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: open
    Keywords: infrasound ; Helmholtz resonator ; plumbing system geometry ; seismo-acoustic studies ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 18
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 19
    Publication Date: 2017-04-04
    Description: We report the results of a geochemical study of gas emissions along a NE–SW transect in southern Italy in order to test the hypothesis that the region around Monte Vulture is affected by degassing of mantle-derived fluids through a lithospheric discontinuity. We also investigated lavas from the Monte Vulture volcano displaying 3He/4He (up to ~6.0 Ra) and Sr isotopes that are consistent with an origin inmantle that has hadminimal pollution from subducted Adriatic slab. Similar 3He/4He in fluids from around Mt. Vulture indicate that the deep volcanic systemis still degassing. Mantle-derived He occurs in fluids along the length of the Vulture line, reinforcing the hypothesis that it is a deep tectonic discontinuity along which mantle fluids and/or melts advect to the surface. The CO2/3He ratios are highly variable (2.7×108–2.15×1011) in response to processes such as gas dissolution into aquifers, addition of crustal gases and degassing fractionation.
    Description: Published
    Description: 65-74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: nonle gases ; mantle degassing ; tectonics ; Mt. Vulture ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 20
    Publication Date: 2017-04-04
    Description: Commenton “CO2 variabilityinmid-oceanridge basalts fromsyn-emplacementdegassing: Constraintsoneruptiondynamics”
    Description: Published
    Description: 251-253
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: non-equilibrium degassing, modeling, CO2, bubble growth, MORB, gas geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 21
    Publication Date: 2017-10-06
    Description: Themajor elements, trace elements and Sr and Nd isotopes of selected Etnean primitive rocks (b15 ky BP) were studied in order to characterize their mantle source. The noble-gas geochemistry of fluid inclusions in minerals fromthe same lavaswas also investigated. Themajor element compositions ofwhole rocks and minerals showed that these products are among the most primitive atMt. Etna, comprising 6.3–17.5 wt.% MgO. The variable LREE (Light Rare Earth Elements) enrichment relative to MORB (Mid-Ocean Ridge Basalt) (Lan/Ybn = 11–26), togetherwith the patterns of certain trace-element ratios (i.e., Ce/Yb versus Zr/Nb and Th/Y versus La/Yb), can be attributed to varying degrees of melting of a common mantle source. Numerical simulations performed with the MELTS program allowed the melting percentages associated with each product to be estimated. This led us to recalculate the hypothetical parental trace-element content of the Etneanmantle source, whichwas common to all of the investigated rocks. The characteristics of the Sr, Nd and He isotopes confirmed the primitive nature of the rocks,with themost-depleted and primitive lava being that ofMt. Spagnolo (SPA; 143Nd/144Nd = 0.512908 87Sr/ 86Sr = 0.703317–0.703325 and 3He/4He = 7.6 Ra), and highlighted the similarity of the mantle sources feeding the volcanic activity of Mt. Etna and the Hyblean Plateau (a region to the south of Mt. Etna and characterized by oldermagmatismthan Mt. Etna). The coupling of noble gases and trace elements suggests an origin for the investigated Etnean lavas from melting of a Hyblean-like mantle, consisting of a two-component source where a peridotitic matrix is veined by 10% pyroxenite. A variable degree of mantle contamination by crustal-like fluids, probably related to subduction, is proposed to explain the higher Sr-isotope and lowerNd-isotope values in some rocks (143Nd/144Nd up to 0.512865 and 87Sr/86Sr up to 0.703707). This process probably occurred in the source prior tomagma generation, refertilizing some portions of themantle. Accordingly, the estimated degree of melting responsible for each magma appears to be related to its 87Sr/86Sr enrichment. In contrast, the decoupling between 3He/4He and 87Sr/86Sr ratios requires the occurrence in the crustal reservoirs of further processes capable of shifting the He isotope ratio towards slightly more radiogenic values, such as magma aging or a contribution of shallow fluid. Therefore, different residence times in the Etnean reservoir and/or various rates of magma ascent could be key parameters for preserving the original He isotope marker of the Etnean mantle source.
    Description: Published
    Description: 243-258
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Hyblean Plateaux ; Primitive magma ; Mantle metasomatism ; Peridotite ; Pyroxenite ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 22
    Publication Date: 2021-03-01
    Description: In this work, we tackle the problem of seismic hazard at Etna deriving from the recurrent seismogenic activity of local faults, by adopting two independent methods based on probabilistic approaches. We assess the hazard in terms of macroseismic intensity and represent the occurrence probability calculated for different exposure times both on maps and at fault scale. Seismic hazard maps obtained by applying the “site approach” through the SASHA code and a new probabilistic attenuation model, indicate the eastern flank of the volcano as the most hazardous, with expected intensity (Iexp) in 50 years (i.e. the standard exposure time adopted in the seismic regulations) ranging from degrees IX to X EMS. In shorter exposure periods (20, 10, 5 years), values of Iexp up to IX are also reached in the same area, but they are clearly determined by the earthquakes generated by the Timpe fault system. In order to quantify the contribution of local seismogenic sources to the hazard of the region, we reconstruct the seismic history of each fault and calculate with SASHA the probability that earthquakes of a given intensity may be generated in different exposure times. Results confirm the high level of hazard due to the S. Tecla, Moscarello and Fiandaca faults especially for earthquakes of moderate intensity, i.e. VI≤I0≤VII, with probabilities respectively exceeding 50% and 20% in 10 years, and 30% and 10% in 5 years. Occurrence probability of major events (I0≥VIII) at the fault scale has also been investigated by statistics on intertimes. Under stationary assumptions we obtain a probability of 6.8% in 5 years for each structure; by introducing the time-dependency (time elapsed since the last event occurred on each fault) through a BPT model, we identify the Moscarello and S. Tecla faults as the most probable sources to be activated in the next 5 years (2013–2017). This result may represent a useful indication to establish priority criteria for actions aimed at reducing seismic risk at a local scale.
    Description: Published
    Description: 158-169
    Description: 4.2. TTC - Modelli per la stima della pericolosità sismica a scala nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Macroseismic intensity ; Seismic history ; Occurrence probability ; Time-dependent renewal process ; Individual sources ; Seismic hazard ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 23
    Publication Date: 2021-03-01
    Description: In this paper, we apply a probabilistic procedure to model the attenuation of the macroseismic intensity in the Mt. Etna region, which allows estimating probabilistic seismic scenarios. Starting from the local earthquake catalogue, we select a dataset of 47 events having epicentral intensity I0 from VI to IX–X EMS, and update the model parameters previously achieved for Italy according to the Bayesian paradigm. For each class of epicentral intensity I0, we then estimate the probability distribution of the intensity at a site conditioned on the epicentre-site distance through a binomial-beta model, under the assumption of a point seismic source and isotropic decay (circular). The mode of the distribution is taken as the expected intensity Is at that site. Since the strongest earthquakes show a preferential propagation of shaking along the fault strike and a rapid decrease in the perpendicular direction, we also consider the anisotropic decay (elliptical) of the intensity due to a linear source (finite fault). We therefore transform the plane so that the ellipse has the length of the fault rupture as maximum axis and its strike as azimuth is changed into a circle with fixed diameter; then we apply the probabilistic model obtained for the isotropic case to the modified data. The entire calculation procedure is implemented in the software PROSCEN which, given the location and the epicentral intensity (and eventually the fault parameters) of the earthquake to be simulated, generates the probabilistic seismic scenario according to the isotropic and anisotropic models of attenuation. The results can be plotted on grid maps representing (1) the intensity that can be exceeded with a fixed probability, or (2) the probability of exceeding a fixed intensity value. The first representation may also find application in seismic monitoring at Etna volcano, in order to produce real-time intensity ShakeMaps based on the instrumental parameters calculated by the automatic earthquake processing system.
    Description: Published
    Description: 149-157
    Description: 4.2. TTC - Modelli per la stima della pericolosità sismica a scala nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Macroseismic intensity ; Attenuation Probability distribution ; Source models ; Seismic scenario ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 24
    Publication Date: 2017-04-03
    Description: Fluorine adsorption experiments were performed on 28 samples of the first 5 cm of topsoil collected on the flanks of Mt. Etna. The soil samples were equilibrated with F-rich rainwater (3.25 mg/L) at a soil/water weight ratio of 1/25. Aliquots of the supernatant were collected after 1, 7, 72, 720 and 5640 h and analysed for F content. The soil samples could be subdivided into three groups based on their F-adsorption behaviours after 1 h and at the end of the experiment: (1) negative adsorption (F released from the soil to the solution) after 1 h and negative or moderately positive adsorption at the end, (2) from negative after 1 h to strongly positive adsorption at the end, and (3) always strong positive adsorption. The adsorption capacity of the soils was positively correlated with the soil pH, the contents of finer granulometric fractions (clay and silt) and the weathering stage (as quantified by the chemical alteration index). The most F adsorbing soils are found at the periphery of the volcano where aquifers are more vulnerable to contamination due to the shallower depth of the water table. This study further evidences the importance of the Etnean soils in protecting groundwater from an excessive magmatic F input.
    Description: Published
    Description: 1179–1188
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic soils ; fluoride adsorption ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 25
    Publication Date: 2017-04-04
    Description: From October 2008 to November 2009, soil CO2, radon and structural field surveys were performed on Mt. Etna, in order to acquire insights into active tectonic structures in a densely populated sector of the south-eastern flank of the volcano, which is involved in the flank dynamics, as highlighted by satellite data (InSAR). The studied area extends about 150 km2, in a sector of the volcano where InSAR results detected several lineaments that were not well-defined from previous geological surveys. In order to validate and better constrain these features with ground data evidences, soil CO2 and soil radon measurements were performed along transects roughly orthogonal to the newly detected faults, with measurement points spaced about 100 m. In each transect, the highest CO2 values were found very close to the lineaments evidenced by InSAR observations. Anomalous soil CO2 and radon values were also measured at old eruptive fractures. In some portions of the investigated area soil gas anomalies were rather broad over transects, probably suggesting a complex structural framework consisting of several parallel volcano-tectonic structures, instead of a single one. Soil gas measurements proved particularly useful in areas at higher altitude on Mt. Etna (i.e. above 900 m asl), where InSAR results are not very informative/ are fairly limited, and allowed recognizing the prolongation of some tectonic lineaments towards the summit of the volcano. At a lower altitude on the volcanic edifice, soil gas anomalies define the active structures indicated by InSAR results prominently, down to almost the coastline and through the northern periphery of the city of Catania. Coupling InSARwith soil gas prospectingmethods has thus proved to be a powerful tool in detecting hidden active structures that do not show significant field evidences.
    Description: This work was funded by the DPC-INGV project “Flank”
    Description: Published
    Description: 27-40
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 ; Radon ; InSAR ; Faults ; Etna ; Volcano-tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 26
    Publication Date: 2017-04-04
    Description: Since January 2008, several geophysical parameters have evidenced a recharging phase at Mt. Etna volcano culminating with an effusive eruption that began on May 13, 2008. Seismic activity recorded at Mt. Etna from January 2007 to May 2008 was analyzed in order to provide seismological constraints to the volcano dynamics leading to the eruption. A total of 336 selected earthquakes, withML≥1.5, were used as data source for this study. Specifically, we calculated 3D velocity and attenuation tomography, including a 3D relocation of the events, and we computed 53 selected fault plane solutions (FPSs) that were used for stress tensor inversion. The most important result obtained from the joint analysis of VP, VP/VS and P-wave attenuation is an anomalous zone with normal to high VP (values between 3.5 and 4.5 km/s) and low VP/VS (values≤1.64), which partially overlaps with a low QP (values≤50) volume located along a NS trending channel beneath the central crater. This can be interpreted as a shallow volume characterized by high temperature where the magma is located with the presence of supercritical fluids. The analysis of seismic stress tensor evidenced an extensional regime in the depth range 3–13 km with a vertically oriented σ1. This finding may suggest an extensional stress regime, probably related to the kinematic response of the volcanic edifice to both a deep magmatic intrusion and a condition of decreased regional compressive stress facilitated by sliding processes of the eastern flank of the volcano.
    Description: Published
    Description: 50–63
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Volcanic eruptions ; Stress Tensor ; Velocity tomography ; Attenuation tomography ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 27
    Publication Date: 2017-04-04
    Description: We analyzed crater SO2 fluxes from Mt Etna, together with soil CO2 effluxes from the volcano's flanks, in the period from 2001 to 2005. Between the 2001 and 2002–2003 eruptions, persistently low values of both parameters suggest that no new gas-rich magma was accumulating at shallow depth (b5 km) within Etna's central conduit, whereas very high SO2 sin-eruptive fluxes during the two eruptions indicated sudden decompression of an un-degassed magma rising along newly-formed eccentric conduits. In November 2003, soil CO2 data indicate migration of gas-rich magma from deep (〉10 km) to shallow (b5 km) portions of the feeding conduits, preceded by an increase in crater SO2 fluxes. A similar behavior was observed also during and after the following 2004–2005 eruption. This degassing style matches a period of increased structural instability of the volcanic edifice caused by acceleration of spreading that affected both its eastern and southern flanks. Spreading could have triggered progressively deeper depressurization in the central conduit, inducing release of the more soluble gas (SO2) first, and then of CO2, contrary to what was observed before the 2001 eruption. This suggests that the edifice has depressurized, promoting ascent of fresh-magma and increasing permeability favouring release of CO2 flux. By integrating geochemical and structural data, previous degassing models developed at Mt. Etna have been updated to advance the understanding of eruptive events that occurred in recent years.
    Description: This work was funded by grants from the Istituto Nazionale di Geofisica e Vulcanologia (INGV) and from the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 90-97
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemical modeling ; volcano monitoring ; volcanic gases ; Tectonics and magmatism ; flank collapse ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 28
    Publication Date: 2017-04-04
    Description: Cuticle micromorphology together with epidermal and epistomatal wax, in both current- and first-year-old needles of conifer Pinus halepensis (Aleppo pine) trees growing under volcanic gas fumigation was analysed in Pisciarelli area, Campi Flegrei, Southern Italy. As a control, current- and first-year-old needles growing far from volcanic gas emission were also sampled. Using a multidisciplinary approach with SEM, TEM and X-ray, volcanic gases were shown to cause degradation on epicuticular and epistomatal waxes. Significant statistical variations of ultrastructural components of the cuticle, with 30 measurements, including total thickness of the cuticle, and details and proportions of all different layers, and use of confidence interval, revealed a high degree of sensitivity of Aleppo pine to this extreme environment. In the present study, non-significant thickness variations of the cell wall plus cuticle among current- and first-year-old needles of both fumigated and non fumigated trees have been found. However, at the ultrastructural level, significant variations in cell wall and total cuticle thickness, especially within the three zones of B1 fibrillar layer, revealed different equilibria for each of the four types of material. Using energy dispersive X-ray microanalysis, no sulphur was found in either cuticle or epidermal cells, but the presence of H2S in the fumarole gas is suspected to cause indirect and/or direct cuticle alterations of wax structure. Ultrastructural characters of plant cuticles related to emission of volcanic gases during the geological past are also discussed. Among these considerations, an identification key enabling distinction between non fumigated and fumigated materials with 9 characters, provides a good tool detecting the influence of volcanism for extant and fossil plants.
    Description: Published
    Description: 1–17
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Volcanic gases ; Pinus halepensis ; Hydrogen sulphide (H2S) ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2017-04-04
    Description: The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3He/4He (22 Ra) and low in 4He/40Ar ( 1), reflecting input of deep mantle components. The other water is characterized by 4He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4He source. Consideration of CO2–CH4–CO–H2O–H2 gas equilibrium reactions indicates equilibration temperatures from 170 C to 310 C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is 170 C whereas the MC is hotter, at 340 C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4He-rich component, equilibrated at temperatures around 170 C, is necessary to explain the range in fumarole gas chemistry.
    Description: Published
    Description: 265–278
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal fluids ; Yellowstone Plateau ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2017-04-04
    Description: NEMO-SN1, located in the central Mediterranean Sea, Western Ionian Sea, off Eastern Sicily Island (Southern Italy) at 2100 m water depth, 25 km from the harbour of the city of Catania, is a prototype of a cabled deep-sea multiparameter observatory and the first operating with real-time data transmission in Europe since 2005. NEMO-SN1 is also the first-established node of EMSO (European Multidisciplinary Seafloor Observatory, http://emso-eu.org), one of the incoming European large-scale research infrastructure included since 2006 in the Roadmap of the ESFRI (European Strategy Forum on Research Infrastructures, http://cordis.europa.eu/esfri/roadmap.htm), which will specifically address long-term monitoring of environmental processes related to Marine Ecosystems, Climate Change and Geo-hazards. NEMO-SN1 has been deployed and developed over the last decade thanks to Italian resources and to the EC project ESONET-NoE (European Seas Observatory NETwork - Network of Excellence, 2007-2011) that funded the LIDO-DM (Listening to the Deep Ocean - Demonstration Mission) and a technological interoperability test (http://www.esonet-emso.org/esonet-noe/). NEMO-SN1 is performing geophysical and environmental long-term monitoring by acquiring seismological, geomagnetic, gravimetric, accelerometric, physico-oceanographic, hydro-acoustic, bioacoustic measurements specifically related to earthquakes and tsunamis generation and ambient noise characterisation in term of marine mammal sounds, environmental and anthropogenic sources. A further main feature of NEMO-SN1 is to be an important test-site for the construction of KM3NeT (Kilometre-Cube Underwater Neutrino Telescope, http://www.km3net.org/), another large-scale research infrastructure included in the ESFRI Roadmap constituted by a large volume neutrino telescope. The description of the observatory and the most recent data acquired will be presented and framed in the general objectives of EMSO.
    Description: Published
    Description: Tokio, 5-8 April 2011
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: 4.6. Oceanografia operativa per la valutazione dei rischi in aree marine
    Description: restricted
    Keywords: NEMO-SN1 cabled observatory ; Geo-hazards ; Bio-acoustics ; High-energy astrophysics ; EMSO ; KM3NeT ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 31
    Publication Date: 2022-05-04
    Description: Springwater chemistry and carbon cycling in our study mainly depend on geological composition of the aquifer. The investigated Alpine springs in Slovenia represent waters strongly influenced by chemicalweathering ofMesozoic limestone and dolomite, only one spring was located in Permo-Carboniferous shales. The carbon isotopic composition of dissolved inorganic carbon (DIC) and suspended organic carbon (POC) as well as major solute concentrations yielded insights into the origin of carbon in Alpine spring waters. The major solute composition was dominated by carbonic acid dissolution of calcite. Waters were generally close to saturation with respect to calcite, and dissolved CO2 was up to fortyfold supersaturated relative to the atmosphere. δ13 C of DIC indicates the portion of soil CO2 contributed in water and is related with soil thickness of infiltrating water in aquifer and could be therefore used as a tool for vulnerability assessment. The δ13 C of DIC ranged from−15.8‰ to −1.5‰ and indicated less and more vulnerable aquifers. Mass balances of carbon for spring waters draining carbonate rocks suggest that carbonate dissolution contributes from approximately 49% to 86% and degradation of organic matter from 13.7% to 51.4%, depending on spring and its relation with rock type, soil environment, and geomorphic position. Stable oxygen isotope composition of water (δ18OH2O), and tritium values range from −12.2 to −9.3‰and from6.4 to 9.8 TU, respectively and indicate recharge frommodern precipitation. According to active decay of tritiumand tritiumin modern precipitation the age of spring waters are estimated to be about 2.6 years for springs located in Julian Alps, about 5 years for springs located in Karavanke and about 5 years for springs located in Kamniško–Savinjske Alps.
    Description: Published
    Description: 40-54
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogeochemistry ; Stable isotopes ; Carbon ; Oxygen ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2017-04-04
    Description: On August 11, 2008 a paroxysmal eruption occurred at Santa Barbara mud volcano (MV), located close to Caltanissetta, one of the most densely populated cities of Sicily (Italy). An associated minor event took place on August, 2009. Both the events caused severe damages to civil infrastructures located within a range of about 2 km from the eruptive vent. Geomorphological, geochemical and seismological investigations were carried out for framing the events in the appropriate geodynamic context. Geomorphological surveys recognized, in the immediate surrounding of the main emission point, two different families of processes and landforms: ground deformations and changes in morphology and number of the fluid emitting vents. These processes were associated to a wider network of fractures, seemingly generated by the shock wave produced by the gas blast occurred at the main paroxysm. Geochemical characterization allowed to estimate the source of the fluids, or at least their last standing, at about 3 km depth. Finally, the close time relationships observed between anomalous increments of seismic activity and the two main paroxysmal events, accounted for a common possible trigger for both the phenomena, even if with a different timing due to the very different initial conditions and characteristics of the two processes, i.e. seismogenesis and gas overloading.
    Description: Published
    Description: 1545-1557
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: mud volcanoes ; geomorphology ; geochemistry ; seismology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 33
    Publication Date: 2017-04-04
    Description: An integrated study, concerning the experimental observations, was performed during the oceanographic cruises on-board the two NURC research vessels, in the period between 2008 and 2010 in the Marine Protected Area of Cinque Terre (North-West Mediterranean Sea, Italy). The aim of the research is to describe the environmental features using both hydrological parameters and AUV navigation tracks, acquired respectively by a multi-parametric platform (MEDUSA) and AUV MUSCLE. The innovative contribution of this work is the possibility to evaluate the bottom stream without direct current measurements, but using the navigation data recorded by AUV. This work is a complementary analysis to environmental support of the ENI S.p.A. Exploration and Production Division project.
    Description: Unpublished
    Description: Seattle, USA
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: restricted
    Keywords: Hydrology ; AUV ; Cinque Terre ; Ligurian Sea ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 34
    Publication Date: 2017-04-04
    Description: The integrated study, concerning the experimental observations, was performed during the oceanographic cruises on-board the two NURC research vessels, in the period between 2008 and 2010 in the Marine Protected Area of Cinque Terre (North-West Mediterranean Sea, Italy). The aim of the research is to describe the environmental features using both hydrological parameters and AUV navigation tracks, acquired respectively by a multi-parametric platform (MEDUSA) and AUV MUSCLE. The innovative contribution of this work is the possibility to evaluate the bottom stream without direct current measurements, but using the navigation data recorded by AUV. This work is a complementary analysis to environmental support of the ENI S.p.A. Exploration and Production Division project.
    Description: Published
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: N/A or not JCR
    Description: restricted
    Keywords: Hydrology ; AUV ; Cinque Terre ; Ligurian Sea ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2017-04-04
    Description: The integrated study, concerning the experimental observations, was performed during the oceanographic cruises on-board the two NURC research vessels, in the period between 2008 and 2010 in the Marine Protected Area of Cinque Terre (North-West Mediterranean Sea, Italy). The aim of the research is to describe the environmental features using both hydrological parameters and AUV navigation tracks, acquired respectively by a multi-parametric platform (MEDUSA) and AUV MUSCLE. The innovative contribution of this work is the possibility to evaluate the bottom stream without direct current measurements, but using the navigation data recorded by AUV. This work is a complementary analysis to environmental support of the ENI S.p.A. Exploration and Production Division project.
    Description: Unpublished
    Description: Seattle, USA
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: restricted
    Keywords: Hydrology ; AUV ; Cinque Terre ; Ligurian Sea ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 36
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 37
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 38
    Publication Date: 2017-04-04
    Description: Studies on volcanic degassing have recently shown the important role of volatile release from active volcanoes in understanding magmatic processes prior to eruptions. Here we present and discuss the evolution of magmatic degassing that preceded and accompanied the 2008 Mt. Etna eruption. We tracked the ascent of magma bodies by high-temporal resolution measurements of SO2 emission rates and discrete sampling of SO2/HCl and SO2/HF molar ratios in the crater plume, as well as by periodic measurement of soil CO2 emission rates. Our data suggest that the first signs of upward migration of gas-rich magma before the 2008 eruption were observed in June 2007, indicated by a strong increase in soil CO2 efflux followed by a slow declining trend in SO2 flux and halogens. This degassing behavior preceded the mid-August 2007 summit activity culminated with the September 4th paroxysmal event. Five months later, a new increase in both soil CO2 and SO2 emission rates occurred before the November 23rd paroxysm, to drop down in late December. In the following months, geochemical parameters showed high variability, characterized by isolated sudden increases occurred in early December 2007 and late March 2008. In early May soil CO2, SO2 emission rates and S/Cl molar ratio gradually increased. Crater degassing peaked on May 13th marking the onset of the eruption. Eruptive activity was accompanied by a general steady-state of SO2 flux characterized by two main degassing cycles. These cycles preceded explosive activity at the eruptive vents, indicating terminal new-arrival of deep gas-rich magma bodies in the shallow plumbing system of Mt Etna. Conversely, halogens described a slight increasing trend till the end of 2008. These observations suggest an impulsive syn-eruptive dynamics of magma transfer from depth to the surface. Differently from the SO2 emission rates, the S/Cl ratio and the soil CO2 efflux values showed an increasing trend from mid-April to mid-July 2008, indicating steady-increasing input of deeper, gas-rich magma. Since August, geochemical parameters decreased, suggesting that new magma has not arrived from depth. According to our interpretation, both the CO2 efflux and the S/Cl ratio increases observed in early November may indicate a new input of fresh magma form depth. Finally, the estimated volume of degassing magma showed substantial equilibrium between degassed and erupted magma suggesting an “eruptive” steady-state of the volcano.
    Description: INGV, Sezione di Catania; INGV, Sezione di Pisa; University of Cambridge, Cambridge, UK
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; plume gases ; soil CO2 ; eruption ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 39
    Publication Date: 2017-04-04
    Description: Concurrent measurement of soil radon, soil thoron and soil CO2 efflux is based on the method developed by Giammanco et al. (Geochem. Geophys. Geosys., 8(10), Q 10001, doi:10.1029/2007GC001644, 2007). An empirical relationship links the 222Rn/220Rn ratio to the CO2 efflux: deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. This relationship is more constraining on the type and depth of the gas source than using the 222Rn/220Rn ratio alone.We studied the temporal variation of the ratio between CO2 efflux and (222Rn/220Rn), that we define as a Soil Gas Disequilibrium Index (SGDI). Since June 2006, periodical measurements of the SGDI were carried out in ten sites located on the flanks of Mt. Etna, with sampling frequency of about ten days. Remarkable variations in this parameter were recorded during the period 2006-2008 likely associated with changes in the activity level of Mt. Etna. In particular, one of the sites located in the area called Primoti (on the lower east flank of the volcano) has shown significant anomalous changes of the SGDI in time, possibly correlated with the eruptive/tectonic activity. For this reason, in this site we set up an automatic monitoring station made of a Radon/Thoron monitor (model RTM 2100, SARAD GmbH, Germany) coupled with a soil CO2 efflux station (model ACE, ADC BioScientific Ltd., UK). The sampling frequency was set at 30 minutes, in order to allow for a sufficient decay equilibration in the radon isotopes. Air temperature and barometric pressure were recorded as well, with the same sampling rate as for the soil gases. The site chosen for testing the monitoring station is located on the east flank of Mt. Etna at an altitude of about 520 a.s.l., in an area known for widespread diffuse emissions of CO2 and other gases of magmatic origin. The preliminary data acquired so far showed an average soil CO2 efflux of 10 g m􀀀2 d􀀀1 (std dev of about 7 g m􀀀2 d􀀀1) and average 222Rn and 220Rn activities of about 3.3 103 Bq/m3 (std dev of about 1140 Bq/m3) and about 2.0 103 Bq/m3 (std dev of about 620 Bq/m3), respectively. The corresponding values of the SGDI thus obtained varied in the range from about -1.5 to about 70.1, with an average of about 7 and standard deviation of about 6.3. The apparent baseline of the parameter is around the value of 3, and daily variations are clearly detected due to the combined influence of air temperature and barometric pressure. No clear influence from rainfall was observed. Some spikes were also detected, whose origin has to be studied by correlating the SGDI with other environmental parameters as well as with changes in the volcanic/tectonic activity of Mt. Etna.
    Description: INGV, Sezione di Catania
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; soil radon ; CO2 ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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