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  • 04.08. Volcanology  (24)
  • Elsevier  (20)
  • Springer  (4)
  • American Institute of Physics (AIP)
  • Cambridge University Press
  • Institute of Physics
  • Periodicals Archive Online (PAO)
  • 2020-2023  (15)
  • 2015-2019  (9)
  • 1935-1939
  • 1
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    Reconstruction of the subaerial Holocene volcanic activity through paleomagnetic and 14C dating methods: El Hierro (Canary Islands) (2022)
    Elsevier
    Details
    Publication Date: 2022-04-01
    Description: Volcanic hazard assessment relies on the accurate knowledge of the eruptive style and recurrence of volcanic eruptions in the past. At El Hierro (Canary Islands) historical and prehistorical records are still poorly defined, and although the island was the location of one of the most recent eruptions (La Restinga, 2011 CE) of the Canarian archipelago, the recent subaerial volcanism is still poorly studied. Information about the age of Holocene volcanic activity as well as the stratigraphy of the deposits is scarce: few eruptions are dated so far, whereas the others are classified as pre-or Holocene events considering lava flow characteristics along the coast. Here, we report on the dating of eleven (M˜na Chamuscada, M˜na del Tesoro, Orchilla, Las Calcosas, M˜na Negra, Lomo Negro, Below Lomo Negro, Cuchillo del Roque, Malpaso Member, and M˜na del Guanche) Holocene subaerial eruptions, distributed along the three rift zones, combining paleomagnetic and 14C methods. We also provide geochemical analyses for nine of them. Results indicate that M˜na Chamuscada and M˜na del Tesoro occurred more recently than previously considered, setting them within the last two thousand years. Conversely, paleomagnetic and 14C ages found for Lomo Negro eruption are consistent with literature data (Villasante- Marcos and Pav´on-Carrasco, 2014) and constrain the occurrence of this event in the XVI century CE. Finally, for Malpaso Member deposits, the two 14C datings obtained by charcoals found below and above the trachytic layer set the eruption during the Holocene epoch, between ~7300 BCE and ~4700 BCE. For the other eruptions, in two cases (Orchilla and Las Calcosas) many possible time windows during the last 14 ka have been found, whereas a few possible ages have been obtained for the others. On the whole, the resulting chronological reconstruction of the recent activity of El Hierro indicates that eruptions occurred unevenly along the three main rifts, with nine eruptions in the WNW rift, six in the NE rift, and four in the SSE rift. We document at least two periods characterized by high eruptive frequency: an old one, between 8000 BCE and 1000 BCE, with eight eruptions, three of which characterized by more evolved compositions (phonotephrite and trachyte), and a recent one, between 1000 BCE and present day, with at least seven eruptions, mainly showing basanite compositions. The new data yield a significant improvement of Holocene eruption chronology, thus are instrumental for a correct evaluation of the volcanic hazard at El Hierro.
    Description: Published
    Description: 107526
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: Paleomagnetism ; El Hierro ; 04.05. Geomagnetism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    CO2 storage in the Antarctica Sub-Continental Lithospheric Mantle as revealed by intra- and inter-granular fluids (2022)
    Elsevier
    Details
    Publication Date: 2022-03-07
    Description: The investigation of the role played by CO2 circulating within the mantle during partial melting and metasomatic/refertilization processes, together with a re-consideration of its storage capability and re-cycling in the lithospheric mantle, is crucial to unravel the Earth's main geodynamic processes. In this study, the combination of petrology, CO2 content trapped in bulk rock- and mineral-hosted fluid inclusions (FI), and 3D textural and volumetric characterization of intra- and inter-granular microstructures was used to investigate the extent and modality of CO2 storage in depleted and fertile (or refertilized) Sub-Continental Lithospheric Mantle (SCLM) beneath northern Victoria Land (NVL, Antarctica). Prior to xenoliths entrainment by the host basalt, the Antarctic SCLM may have stored 0.2 vol% melt and 1.1 vol% fluids, mostly as FI trails inside mineral phases but also as inter-granular fluids. The amount of CO2 stored in FI varies from 0.1 μg(CO2)/g(sample) in olivine from the anhydrous mantle xenoliths at Greene Point and Handler Ridge, up to 187.3 μg/g in orthopyroxene from the highly metasomatized amphibole-bearing lherzolites at Baker Rocks, while the corresponding bulk CO2 contents range from 0.3 to 57.2 μg/g. Irrespective of the lithology, CO2 partitioning is favoured in orthopyroxene and clinopyroxene-hosted FI (olivine: orthopyroxene = 0.10 ± 0.06 to 0.26 ± 0.09; olivine: clinopyroxene = 0.10 ± 0.05 to 0.27 ± 0.14). The H2O/(H2O + CO2) molar ratios obtained by comparing the CO2 contents of FI to the H2O amount retained in pyroxene lattices vary between 0.72 ± 0.17 and 0.97 ± 0.03, which is well comparable with the values measured in olivine-hosted melt inclusions from Antarctic primary lavas and assumed as representative of the partition of volatiles at the local mantle conditions. From the relationships between mineral chemistry, thermo-, oxybarometric results and CO2 contents in mantle xenoliths, we speculate that relicts of CO2-depleted mantle are present at Greene Point, representing memory of a CO2-poor tholeiitic refertilization related to the development of the Jurassic Ferrar large magmatic event. On the other hand, a massive mobilization of CO2 took place before the (melt-related) formation of amphibole veins during the alkaline metasomatic event associated with the Cenozoic rift-related magmatism, in response to the storage and recycling of CO2-bearing materials into the Antarctica mantle likely induced by the prolonged Ross subduction.
    Description: Published
    Description: 106643
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: JCR Journal
    Keywords: CO2 storage ; Sub-Continental Lithospheric Mantle ; Alkaline metasomatism ; Fluid inclusions ; Synchrotron X-ray microtomography ; Inter-granular fluids ; 04.01. Earth Interior ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Chemical variability in volcanic gas plumes and fumaroles along the East African Rift System: New insights from the Western Branch (2022)
    Elsevier
    Details
    Publication Date: 2022-03-15
    Description: The origin of magmatic fluids along the East African Rift System (EARS) is a long-lived field of debate in the scientific community. Here, we investigate the chemical composition of the volcanic gas plume and fumaroles at Nyiragongo and Nyamulagira (Democratic Republic of Congo), the only two currently erupting volcanoes set on the Western Branch of the rift. Our results are in line with earlier conceptual models proposing that volcanic gas emissions along the EARS mainly reflect variable contributions of either a Sub-Continental Lithospheric Mantle (SCLM) component or a Depleted Morb Mantle (DMM) component, and deeper fluid. At Nyiragongo and Nyamulagira, our study discards a major contribution of a high 3He/4He mantle plume component in the genesis of volcanic fluids beneath the area. High CO2/3He in fumaroles of both volcanoes is thought to reflect carbonate metasomatism in the lithospheric mantle source. As inferred by previous results obtained on the lava chemistry, this carbonate metasomatism would be more pronounced beneath Nyiragongo. This supports the idea of the presence of distinct metasomes within the lithospheric mantle beneath the Western Branch of the rift.
    Description: Published
    Description: 120811
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: East African Rift System ; Volcano ; Gas chemistry ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Modeling the multi-level plumbing system of the Changbaishan caldera from geochemical, mineralogical, Sr-Nd isotopic and integrated geophysical data (2022)
    Elsevier
    Details
    Publication Date: 2022-03-21
    Description: Changbaishan, an intraplate volcano, is characterized by an approximately 6 km wide summit caldera and last erupted in 1903. Changbaishan experienced a period of unrest between 2002 and 2006. The activity developed in three main stages, including shield volcano (basalts), cone-construction (trachyandesites to trachytes with minor basalts), and caldera-forming stages (trachytes to comendites). This last stage is associated with one of the more energetic eruptions of the last millennium on Earth, the 946 CE, VEI 7 Millennium Eruption (ME), which emitted over 100 km3 of pyroclastics. Compared to other active calderas, the plumbing system of Changbaishan and its evolution mechanisms remain poorly constrained. Here, we merge new whole-rock, glass, mineral, isotopic, and geobarometry data with geophysical data and present a model of the plumbing system. The results show that the volcano is characterized by at least three main magma reservoirs at different depths: a basaltic reservoir at the Moho/lower crust depth, an intermediate reservoir at 10–15 km depth, and a shallower reservoir at 0.5–3 km depth. The shallower reservoir was involved in the ME eruption, which was triggered by a fresh trachytic melt entering a shallower reservoir where a comenditic magma was stored. The trachytes and comendites originate from fractional crystallization processes and minor assimilation of upper crust material, while the less evolved melts assimilate lower crust material. Syn-eruptive magma mingling occurred during the ME eruption phase. The magma reservoirs of the caldera-forming stage partly reactivate those of the cone-construction stage. The depth of the magma storage zones is controlled by the layering of the crust. The plumbing system of Changbaishan is vertically extensive, with crystal mush reservoirs renewed by the replenishment of new trachytic to trachyandesitic magma from depth. Unlike other volcanoes, evidence of a basaltic recharge is lacking. The interpretation of the signals preceding possible future eruptions should consider the multi-level nature of the Changbaishan plumbing system. A new arrival of magma may destabilize a part of or the entire system, thus triggering eruptions of different sizes and styles. The reference model proposed here for Changbaishan represents a prerequisite to properly understand periods of unrest to potentially anticipate future volcanic eruptions and to identify the mechanisms controlling the evolution of the crust below volcanoes.
    Description: National Natural Science Foundation of China (Grant Nos. 41972313 and 41790453), Engineering Research Center of Geothermal Resources Development Technology and Equipment, Ministry of Education, Jilin University, China, INGV Ricerca Libera.
    Description: Published
    Description: 101171
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Aeromagnetism (2022)
    Elsevier
    Details
    Publication Date: 2022-02-10
    Description: The airborne magnetic method was established a few decades ago, as a strong tool in mining and petroleum exploration. Several economically relevant discoveries are often credited to aeromagnetism. Geological reconnaissance and mapping, deep crustal and upper mantle studies, environmental characterization, and national and international security issues can greatly benefit from the aeromagnetic method, as compared with other geophysical prospecting schemes. The rapid rate of coverage and the low cost per unit area explored represent just a few among the many advantages of the technique. Consequently, large-scale airborne magnetic surveys have been carried out in various parts of the globe. The amount of direct discoveries of ore bodies by means of aeromagnetism is impressive. Large magnetic iron deposits found in the early 1960s are in Southern California, Missouri, Nevada, Pennsylvania, Quebec, Ontario, and elsewhere. In the field of petroleum exploration, the method has also been used, although with less direct application. Depth to magnetic basement estimation in sedimentary basins narrows down areas of interest where to conduct exploration surveys in detail by means of more costly methods. The most relevant use of airborne magnetic results is crustal imaging and characterization. Nowadays, geology is interpreted in three dimensions using a digital aeromagnetic map.
    Description: Published
    Description: 675-688
    Description: 1T. Struttura della Terra
    Description: 4T. Sismicità dell'Italia
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare
    Description: 5A. Ricerche polari e paleoclima
    Description: 7A. Geofisica per il monitoraggio ambientale
    Description: 1TR. Georisorse
    Description: 2TR. Ricostruzione e modellazione della struttura crostale
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Keywords: aeromagnetism ; potential fields ; magnetic anomaly ; 04.02. Exploration geophysics ; 04.05. Geomagnetism ; 04.07. Tectonophysics ; 04.08. Volcanology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 6
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    Synthetic benchmarking of concentrated pyroclastic current models (2022)
    Springer
    Details
    Publication Date: 2022-02-16
    Description: Validation and benchmarking of pyroclastic current (PC) models is required to evaluate their performance and their reliability for hazard assessment. Here, we present results of a benchmarking initiative built to evaluate four models commonly used to assess concentrated PC hazard: SHALTOP, TITAN2D, VolcFlow, and IMEX_SfloW2D. The benchmark focuses on the simulation of channelized flows with similar source conditions over five different synthetic channel geometries: (1) a flat incline plane, (2) a channel with a sharp 45° bend, (3) a straight channel with a break-in-slope, (4) a straight channel with an obstacle, and (5) a straight channel with a constriction. Several outputs from 60 simulations using three different initial volume fluxes were investigated to evaluate the performance of the four models when simulating valley-confined PC kinematics, including overflows induced by topographic changes. Quantification of the differences obtained between model outputs at t = 100 s allowed us to identify (1) issues with the Voellmy-Salm implementation of TITAN2D and (2) small discrepancies between the three other codes that are either due to various curvature and velocity formulations and/or numerical frameworks. Benchmark results were also in agreement with field observations of natural PCs: a sudden change in channel geometries combined with a high-volume flux is key to generate overflows. The synthetic benchmarks proved to be useful for evaluating model performance, needed for PC hazard assessment. The overarching goal is to provide an interpretation framework for volcanic mass flow hazard assessment studies to the geoscience community.
    Description: Published
    Description: 75
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: benchmarking ; pyroclastic current ; numerical modeling ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Hydrothermal pressure-temperature control on CO2 emissions and seismicity at Campi Flegrei (Italy) (2022)
    Elsevier
    Details
    Publication Date: 2022-02-11
    Description: Fluids supplied by stored magma at depth are causal factors of volcanic unrest, as they can cause pressurization/ heating of hydrothermal systems. However, evidence for links between hydrothermal pressurization, CO2 emission and volcano seismicity have remained elusive. Here, we use recent (2010−2020) observations at Campi Flegrei caldera (CFc) to show hydrothermal pressure, gas emission and seismicity at CFc share common source areas and well-matching temporal evolutions. We interpret the recent escalation in seismicity and surface gas emissions as caused by pressure-temperature increase at the top of a vertically elongated (0.3–2 km deep) gas front. Using mass (steam) balance considerations,we showhydrothermal pressurization is causing energy transfer from the fluids to the host rocks, ultimately triggering low magnitude earthquakes within a seismogenetic volume containing the hydrothermal system. This mechanism is probably common to other worldwide calderas in similar hydrothermal activity state.
    Description: MIUR project n. PRIN2017-2017LMNLAW“Connect4Carbon”
    Description: Published
    Description: 107245
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: CO2 emission ; Campi Flegrei ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Tracking the summit activity of Mt. Etna volcano between July 2019 and January 2020 by integrating petrological and geophysical data (2022)
    Elsevier
    Details
    Publication Date: 2022-02-11
    Description: The evolution of volcanic activity observed at the New South East Crater (NSEC) and Voragine (VOR) between July 2019 and January 2020 has been deciphered by taking into account the changes of textures and chemical zoning of plagioclase and olivine crystals from the erupted lavas and tephra. The petrological observations have been integrated with analyses of the amplitude and source location of volcanic tremor and infrasound data. Characteristics of crystals erupted on July 2019 at the NSEC reflect protracted intrusions of magma into the mid-upper section of the plumbing system, approximately within 290–120 MPa, which acted as the main zone of magma accumulation and crystallization before the beginning of the eruptive activity. Textures and compositions of crystals erupted at VOR emphasize the beginning of volcanic activity driven by recharge/discharge phases that mostly affect the shallowest portion of the Mt. Etna plumbing system (〈40 MPa). At the end of 2019, mineral compositions and zoning patterns changed again in accordance with eruption dynamics. The observed changes reflect the transition from an early phase, between November and December 2019, characterized by substantial equilibrium during magma storage and transport toward higher disequilibrium conditions and eruptive frequency, in January 2020. This has been associated to episodes of deep replenishment of mafic magmas displacing the resident one. Diffusion chronometry applied to zoned olivines shows that most of the episodes of magma intrusion correlate temporally with changes in the features of both volcanic tremor and infrasonic events in terms of amplitude and source location, providing evidence that such geophysical signals are directly related to the magma dynamics in the upper plumbing system.
    Description: Published
    Description: 107350
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Modified shallow water model for viscous fluids and positivity preserving numerical approximation (2022)
    Elsevier
    Details
    Publication Date: 2022-02-14
    Description: Shallow water equations are widely used in the simulation of those geophysical flows for which the flow horizontal length scale is much greater than the vertical one. Inspired by the example of lava flows, we consider here a modified model with an additional transport equation for a scalar quantity (e.g., temperature), and the derivation of the shallow water equations from depth-averaging the Navier-Stokes equations is presented. The assumption of constant vertical profiles for some of the model variables is relaxed allowing the presence of vertical profiles, and it follows that the non-linearity of the flux terms results in the introduction of appropriate shape coefficients. The space discretization of the resulting system of hyperbolic partial differential equations is obtained with a modified version of the finite volume central-upwind scheme introduced by Kurganov and Petrova in 2007. The time discretization is based on an implicit-explicit Runge-Kutta method which couples properly the hyperbolic part and the stiff source terms, avoiding the use of a very small time step; the use of complex arithmetic increases accuracy in the implicit treatment of stiff terms. The whole scheme is proved to preserve the positivity of flow thickness and the stationary steady-states. Some numerical experiments are performed to validate the proposed method and to show the incidence on the numerical solutions of shape coefficients introduced in the model.
    Description: Published
    Description: 482-505
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Shallow water equations ; Viscous fluids ; Finite Volume ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Forest destruction by ‘a‘ā lava flow during Etna's 2002–03 eruption: Mechanical, thermal, and environmental interactions (2022)
    Elsevier
    Details
    Publication Date: 2022-07-14
    Description: Forest destruction by ‘a‘ ̄a lava flow is common. However, mechanical and thermal interactions between the invading lava and the invaded forest are poorly constrained. We complete mapping, thermal image and sample analyses of a channel-fed ‘a‘a ̄ lava flow system that invaded forest on the NE flank of Mt. Etna (Italy) in 2002. These lava flows destroyed 231,000 trees, only 2% of which are still visible as felled trunks on the levees or at the channel-levee contact. The remaining 98% were first felled by the flow front, with the trunks then buried by the flow. Rare tree molds can be found at the rubble levee base where trees were buried by avalanching hot breccia and then burnt through, with a time scale for total combustion being a few days. Protruding trunks fell away from the flow, if felled by blocks avalanching down the levee flank, or became aligned with the flow if falling onto the moving stream. Estimated cooling rates (0.1–5.5 ◦C km− 1) are normal for well-insulated ‘a‘a ̄ flow, suggesting no thermal interaction. We find the highest phenocryst concentrations (of 50–60%, above an expected value of 30–40%) in low velocity (〈0.5 m s− 1) locations. These low velocity zones are also characterized by high trunk concentrations. Thus, the common factor behind crystal and trunk deposition is velocity. That is, when the lava slows down, crystal settling occurs and trunks are preferentially deposited. Thus, although we find no thermal or textural effects due to the presence of the forest, we do find mechanical and environmental in- teractions where the trees are consumed to become part of the flow.
    Description: This research was financed by the Agence National de la Recherche through the project LAVA (Program: DS0902 2016; Project: ANR-16 CE39-0009). We very much thank Sean I. Peters and an anonymous reviewer for their extremely constructive advice and support. This is ANR-LAVA contribution no. 23 and Laboratory of Excellence ClerVolc contribution no. 552.
    Description: Published
    Description: 107621
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Channelized ‘a‘ ̄a lava flow ; thermal imagery ; lava flows ; 2002-03 eruption ; forest destruction ; tree molds ; Etna volcano ; cooling rates ; Interaction lava and trees ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    Nitrogen, helium, and argon reveal the magmatic signature of fumarole gases and episodes of outgassing from upper-crustal magma reservoirs: The case of the Nisyros caldera (Aegean Arc, Greece) (2022)
    Elsevier
    Details
    Publication Date: 2022-09-05
    Description: The chemical composition of gases emitted by active volcanoes reflects both magma degassing and shallower processes, such as fluid-rock hydrothermal interaction and mixing with atmospheric-derived fluids. Untangling the magmatic fluid endmember within surface gas emission is therefore challenging, even with the use of well-known magma degassing tracers such as noble gases. Here, we investigate the deep magmatic fluid composition at the Nisyros caldera (Aegean Arc, Greece) by measuring nitrogen and noble gas abundances and isotopes in naturally degassing fumaroles. Gas samples were collected from 32 fumarolic vents at water-boiling temperature between 2018 and 2021. These fumaroles are admixtures of magmatic fluids typical of subduction zones, groundwater (or air saturated water, ASW), and air. The N2, He, and Ar composition of the magmatic endmember is calculated by reverse mixing modeling and shows N2/He = 31.8 ± 4.5, N2/Ar = 281.6, d15N = +7 ± 3 ‰, 3He/4He = 6.2 Ra (where Ra is air 3He/4He), and 40Ar/36Ar = 551.6 ± 19.8. Although N2/He is significantly low with respect to typical values for arc volcanoes (1,000–10,000), the contribution of subducted sediments to the Aegean Arc magma generation is reflected by the positive d15N values of Nisyros fumaroles. The low N2/He ratio indicates N2-depletion due to solubility-controlled differential degassing of an upper-crustal silicic (dacitic/rhyodacitic) melt in a high-crystallinity reservoir. We compare our 2018–2021 data with N2, He, and Ar values collected from the same fumaroles during a hydrothermal unrest following the seismic crisis in 1996–1997. Results show additions of both magmatic fluid and ASW during this unrest. In the same period, fumarolic vents display an increase in magmatic species relative to hydrothermal gas, such as CO2/CH4 and He/CH4 ratios, an increase of 50 C in the equilibrium temperature of the hydrothermal system (up to 325 C), and greater amounts of vapor separation. These variations reflect an episode of magmatic fluid expulsion during the seismic crisis. The excess of heat and mass supplied by the magmatic fluid injection is then dissipated through boiling of deeper and peripheral parts of the hydrothermal system. Reverse mixing modeling of fumarolic N2-He-Ar has therefore important ramifications not only to disentangle the magmatic signature from gases emitted during periods of dormancy, but also to trace episodes of magmatic outgassing and better understand the state of the upper crustal reservoir.
    Description: Published
    Description: 68-84
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Noble gases ; Nitrogen isotope ; Mixing modeling ; Magmatic degassing ; High-crystallinity mush ; Caldera ; Unrest ; CO2 ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    Field-based measurements of volcanic ash resuspension by wind (2021)
    Elsevier
    Details
    Publication Date: 2022-02-11
    Description: The resuspension of volcanic ash by wind is a significant source of hazard during and after volcanic eruptions. Parameterizing and modeling ash resuspension requires direct measurement of the minimum wind shear stress required to move particles, usually expressed as the threshold friction velocity U*th, a parameter that, for volcanic ash, has been measured only scarcely and always in the laboratory. Here, we report the first field measurements of U*th for volcanic ash, with a portable wind tunnel specifically developed, calibrated, and tested. Field measurements, performed on natural reworked ash deposits from Sakurajima (Japan) and Cordón Caulle (Chile) volcanoes, agree well with our laboratory determinations on ash from the same deposits, with values of U*th ranging from 0.13 to 0.38 m/s. Our results show that the median grain size of the deposit and particle shape have a stronger control on U*th than the local substratum nature and deposit texture.
    Description: Published
    Description: 116684
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: wind resuspension ; wind tunnel ; detachment threshold ; volcanic ash ; Sakurajima volcano ; Cordon Caulle volcano ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Assessment of a low-enthalpy geothermal resource and evaluation of the natural CO2 output in the Tor di Quinto area (Rome city, Italy) (2021)
    Elsevier
    Details
    Publication Date: 2021-12-09
    Description: Rome Capital City is located in a high heat flux area of central Italy, suitable for low-enthalpy geothermal exploitation. In the central-northern part of the city, near Tor di Quinto hippodrome close to Tiber River, a wide undeveloped area occurs, which is a possible future urban development site. We present the results of a geochemical and geophysical study aimed at assessing the presence in this zone of a low-enthalpy geothermal aquifer and at evaluating its depth, thickness and the physico-chemical characteristics of the geothermal water. Furthermore the natural CO2 output of this zone has been investigated. A soil CO2 flux survey with 551 measurements over a surface of 3.09 km2 revealed the presence of parallel NW-SE trending positive flux anomalies. The total CO2 output was estimated to 87.77 t*day-1, most of which (85 %) of endogenous or mixed origin. An Electrical Resistivity Tomography survey, consisting of five parallel 355 m long and 100 m spaced profiles, allowed the reconstruction of the stratigraphy of the underground sediments, which are fluvial deposits of the near Tiber River. The geothermal water is hosted in a low-resistivity layer, corresponding to the Tiber base gravels, which are here 20 m thick and whose top is 40 m below the surface. The water has a nearly constant temperature of 17.5 °C, a relatively high salinity and an appreciable content in dissolved gas. This low-enthalpy resource is suitable for direct uses, e.g. individual and district heating/cooling, sanitary hot water, spa facilities for swimming and bathing.
    Description: This work was partially supported by the INGV AMUSED research project (CUP D59C19000100005)
    Description: Published
    Description: 102298
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Low enthalpy geothermal aquifer Rome ; water chemistry ; diffuse soil CO2 output ; Electrical Resistivity Tomography ; 04.08. Volcanology ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
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    Validation of a two-layer depth-averaged model by comparison with an experimental dilute stratified pyroclastic density current (2021)
    Springer
    Details
    Publication Date: 2021-12-15
    Description: Numerical results of a two-layer depth-averaged model of pyroclastic density currents (PDCs) were compared with an experimental PDC generated at the international eruption simulator facility (the Pyroclastic flow Eruption Large-scale Experiment (PELE)) to establish a minimal dynamical model of PDCs with stratification of particle concentrations. In the present two-layer model, the stratification in PDCs is modeled as a voluminous suspended-load layer with low particle volume fractions ( ≲ 10−3) and a thin basal bed-load layer with higher particle volume fractions ( ∼ 10−2 ) on the basis of the source condition in the experiment. Numerical results for the suspended load quantitatively reproduce the time evolutions of the front position and flow thickness in the experimental PDC. The numerical results of the bed-load and deposit thicknesses depend on an assumed value of settling speed at the bottom of the bed load ( WsH ). We show that the thicknesses of bed load and deposit in the simulations agree well with the experimental data, when WsH is set to about 1.25 × 10−2 m/s. This value of the settling speed is two orders of magnitude smaller than that predicted by a hindered-settling model. The small value of WsH is considered to result from decreasing in the effective deposition speed due to the erosion process accompanied by saltating/rolling of particles at the bottom of the bed load.
    Description: Published
    Description: 73
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Pyroclastic density current ; Two-layer model ; Experimental validation ; Pyroclastic surge ; Bed load ; Sedimentation process Introduction ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
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    The 1986–2021 paroxysmal episodes at the summit craters of Mt. Etna: Insights into volcano dynamics and hazard (2021)
    Elsevier
    Details
    Publication Date: 2021-12-22
    Description: Despite Mt. Etna's long-standing reputation as an effusive volcano, since 1986 there has been an evident increase in mid-intensity explosive eruptions from its summit craters, with more than 240 episodes, better known as paroxysms (otherwise called paroxysmal episodes). These are characterized by strong Strombolian to lava fountaining activity that lasts from tens of minutes to a few days, producing some km-high volcanic plumes and tephra fallouts up to hundreds of km on the ground. Most paroxysms give life to sequences which are clustered like “episodic” eruptions for periods of a few days to a few months, their frequent recurrence causing hazard to air traffic and impacting densely inhabited areas. Nonetheless, a list containing the dates and data of these eruptions is lacking. In this paper, we tried to fill this gap by compiling a complete record, including master data (date, crater), eruption style and seismic parameters for identifying, characterizing and quantifying both the individual episodes and the entire period. This information comes from a critical review of surveillance reports, raw-data analysis and scientific literature. A retrieval of homogenous and comparable seismic data was possible only for episodes after 2006 following the renewal of seismic stations. The eruption list provides a complete picture of the 1986–2021 paroxysms, allowing to evaluate their temporal distribution, make a statistical analysis of their time-interval, and undertake a comprehensive investigation of the features of volcanic tremor. The results show a high probability (72%) of having a paroxysmal episode in the 10 days following the previous one. Moreover, a scaling relationship associated with the number-size distribution of the amplitude increases of volcanic tremor accompanying the explosive activities has been constrained. During sequences of paroxysms, combining these outputs can help improve the hazard assessment in terms of frequency of the associated tephra fallouts, and predict the duration of the entire sequence.
    Description: Published
    Description: 103686
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Mt. Etna ; Summit craters ; Paroxysmal episodes ; Volcanic tremor ; Statistical analysis ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
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    The effects of environmental parameters on diffuse degassing at Stromboli volcano: Insights from joint monitoring of soil CO2 flux and radon activity (2019)
    Elsevier
    Details
    Publication Date: 2021-06-30
    Description: Soil CO2 flux and 222Rn activity measurements may positively contribute to the geochemicalmonitoring of active volcanoes. The influence of several environmental parameters on the gas signals has been substantially demonstrated. Therefore, the implementation of tools capable of removing (or minimising) the contribution of the atmospheric effects from the acquired time series is a challenge in volcano surveillance. Here, we present 4 years-long continuousmonitoring (fromApril 2007 to September 2011) of radon activity and soil CO2 flux collected on the NE flank of Stromboli volcano. Both gases record higher emissions during fall–winter (up to 2700 Bq * m−3 for radon and 750 g m−2 day−1 for CO2) than during spring–summer seasons. Short-time variations on 222Rn activity aremodulated by changes in soil humidity (rainfall), and changes in soil CO2 flux that may be ascribed to variations in wind speed and direction. The spectral analyses reveal diurnal and semi-diurnal cycles on both gases, outlining that atmospheric variations are capable to modify the gas release rate fromthe soil. The long-termsoil CO2 flux shows a slow decreasing trend, not visible in 222Rn activity, suggesting a possible difference in the source depth of the of the gases, CO2 being deeper and likely related to degassing at depth of the magma batch involved in the February–April 2007 effusive eruption. To minimise the effect of the environmental parameters on the 222Rn concentrations and soil CO2 fluxes, two different statistical treatments were applied: the Multiple Linear Regression (MLR) and the Principal Component Regression (PCR). These approaches allow to quantify theweight of each environmental factor on the two gas species and showa strong influence of some parameters on the gas transfer processes through soils. The residual values of radon and CO2 flux, i.e. the values obtained after correction for the environmental influence, were then compared with the eruptive episodes that occurred at Stromboli during the analysed time span (2007–2011) but no clear correlations emerge between soil gas release and volcanic activity. This is probably due to i) the distal location of the monitoring stations with respect to the active craters and to ii) the fact that during the investigated period no major eruptive phenomena (paroxysmal explosion, flank eruption) occurred. Comparison of MLR and PCR methods in time-series analysis indicates thatMLR can bemore easily applied to real time data processing in monitoring of open conduit active volcanoes (like Stromboli) where the transition to an eruptive phase may occur in relatively short times.
    Description: This researchwas partly funded by ItalianMinistry of University and Research (MIUR) and by University of Torino-Fondazione Compagnia di San Paolo. Additional fundswere provided by the Italian “Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile (DPC)” through the DEVnet Project (a cooperative program between the Departments of Earth Sciences of the University of Torino and the University of Florence) and through the “Potenziamento Monitoraggio Stromboli” project. Additional funds for improving our computing hardware were provided by Fondazione Cassa di Risparmio di Torino.
    Description: Published
    Description: 65-78
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano ; Continuous geochemical monitoring ; Soil CO2 flux ; Radon activity ; Environmental parameters ; Time series analyses ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
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    Vapour discharges on Nevado del Ruiz during the recent activity: Clues on the composition of the deep hydrothermal system and its effects on thermal springs (2018)
    Elsevier
    Details
    Publication Date: 2021-03-16
    Description: The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, stillmaintains amoderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600–5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated themass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl ~1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent “Nereidas” (3600 m asl) is hypothesized to be separated from a high temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, aswell as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t= 315 °C, P= 15 MPa, NaCl = 10 wt%, CO2=5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300mg/l. Changes in the magmatic input into the hydrothermal system couldmodify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.
    Description: Published
    Description: 40-53
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Nevado del Ruiz ; Water isotopes ; Geothermal system ; Equilibrium modelling ; Water chemistry ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
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    Retrieval and intercomparison of volcanic SO2 injection height and eruption time from satellite maps and ground-based observations (2018)
    Elsevier
    Details
    Publication Date: 2021-03-19
    Description: Syneruptive gas flux time series can, in principle, be retrieved from satellite maps of SO2 collected during and immediately after volcanic eruptions, and used to gain insights into the volcanic processes which drive the volcanic activity. Determination of the age and height of volcanic plumes are key prerequisites for such calculations. However, these parameters are challenging to constrain using satellite-based techniques. Here, we use imagery from OMI and GOME-2 satellite sensors and a novel numerical procedure based on back-trajectory analysis to calculate plume height as a function of position at the satellite measurement time together with plume injection height and time at a volcanic vent location. We applied this new procedure to three Etna eruptions (12 August 2011, 18 March 2012 and 12 April 2013) and compared our results with independent satellite and ground-based estimations. We also compare our injection height time-series with measurements of volcanic tremor, which reflects the eruption intensity, showing a good match between these two datasets. Our results are a milestone in progressing towards reliable determination of gas flux data from satellite-derived SO2 maps during volcanic eruptions, which would be of great value for operational management of explosive eruptions.
    Description: 1) European Research Council under the European Union's Seventh Framework Programme (FP/2.007-2013)/ERC Grant Agreement no. 279802, project 283 CO2Volc. 2) MEDiterranean SUpersite Volcanoes 280 (MED-SUV) WP 3.3.3
    Description: Published
    Description: 79-91
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Volcanic SO2 ; Trajectory modelling ; Remote sensing ; Volcanic tremor ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
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    Transient numerical model of magma ascent dynamics: application to the explosive eruptions at the Soufrière Hills Volcano (2018)
    Elsevier
    Details
    Publication Date: 2021-06-30
    Description: Volcanic activity exhibits a wide range of eruption styles, from relatively slow effusive eruptions that produce lava flows and lava domes, to explosive eruptions that can inject large volumes of fragmented magma and volcanic gases high into the atmosphere. Although controls on eruption style and scale are not fully understood, previous research suggests that the dynamics of magma ascent in the shallow subsurface (〈 10 km depth) may in part control the transition from effusive to explosive eruption and variations in eruption style and scale. Here we investigate the initial stages of explosive eruptions using a 1D transient model for magma ascent through a conduit based on the theory of the thermodynamically compatible systems. The model is novel in that it implements finite rates of volatile exsolution and velocity and pressure relaxation between the phases. We validate the model against a simple two-phase Riemann problem, the Air-Water Shock Tube problem, which contains strong shock and rarefaction waves. We then use the model to explore the role of the aforementioned finite rates in controlling eruption style and duration, within the context of two types of eruptions at the Soufrière Hills Volcano, Montserrat: Vulcanian and sub-Plinian eruptions. Exsolution, pressure, and velocity relaxation rates all appear to exert important controls on eruption duration. More significantly, however, a single finite exsolution rate characteristic of the Soufrière Hills magma composition is able to produce both end-member eruption durations observed in nature. The duration therefore appears to be largely controlled by the timescales available for exsolution, which depend on dynamic processes such as ascent rate and fragmentation wave speed.
    Description: Published
    Description: 110-139
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Magma ascent ; Conduit dynamics ; Soufrière Hills Volcano ; Finite-rate exsolution ; Pressure relaxation ; Velocity relaxation ; 04.08. Volcanology ; Numerical modeling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
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    Changes in heat released by hydrothermal circulation monitored during an eruptive cycle at Mt. Etna (Italy) (2018)
    Springer
    Details
    Publication Date: 2019-03-26
    Description: The shallow vertical temperature profile has been measured in the proximity of an eruptive fissure far about 4 km north-northeast from Mt. Etna central craters. The monitoring site was a steam-heated soil lying between a group of flank fractures on the upper northeast flank of Mt. Etna (Italy), i.e., on the northeast rift. We chose this area because it was close to an eruptive fissure, that opened in 2002 and extended from about 2500 to about 1500 m a.s.l., with our aim being to determine a connection between this fracture system and the ongoing volcanic activity. Heat flux anomalies from the ground from September 2009 to September 2012 were evaluated. Changes in the hydrothermal release—which can be related to variations in volcanic activity—are discussed and compared to the published geophysical data. The heat flux ranges varied during the pre-eruptive (from about 7 to 38 W×m−2), syn-eruptive (from about 3 to 49W×m−2), and post-eruptive phases, with the heat released being lowest at the latter phase (from about 1 to 20 W×m−2). Moreover, the heat flux time variation was strongly correlated with the eruption rate from the new southeast crater between January 2011 and April 2012. The migration of magma through active conduits acts as a changing heating source for steam-heated soils located above the active fractures. Our findings suggest that tracking the heat flux above active fractures constitutes a useful investigation field for low-cost thermal monitoring of volcanic activity. Time variations in their emissions could highlight the relationship between a hydrothermal circuit and the local network of fractures, possibly indicating variation in the structural weakness of a volcanic edifice. Continuous monitoring of heat flux, combined with a realistic model, would contribute to multidisciplinary investigations aimed at evaluating changes in volcano dynamics.
    Description: National Department of Civil Protection
    Description: Published
    Description: 31
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Volcanic activity ; Ground temperature ; Heat flux ; Continuous monitoring ; 04.08. Volcanology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
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    Supporting the Development of Procedures for Communications During Volcanic Emergencies: Lessons Learnt from the Canary Islands (Spain) and Etna and Stromboli (Italy) (2017)
    Springer
    Details
    Publication Date: 2020-11-18
    Description: Volcanic crises are complex and especially challenging to manage. Volcanic unrest is characterised by uncertainty about whether an eruption will or will not take place, as well as its possible location, size and evolution. Planning is further complicated by the range of potential hazards and the variety of disciplines involved in forecasting and responding to volcanic emergencies. Effective management is favoured at frequently active volcanoes, owing to the experience gained through the repeated ‘testing’ of systems of communication. Even when plans have not been officially put in place, the groups involved tend to have an understanding of their roles and responsibilities and those of others. Such experience is rarely available at volcanoes that have been quiescent for several generations. Emergency responses are less effective, not only because of uncertainties about the volcanic system itself, but also because scientists, crisis directors, managers and the public are inexperienced in volcanic unrest. In such situations, tensions and misunderstandings result in poor communication and have the potential to affect decision making and delay vital operations. Here we compare experiences on communi- cating information during crises on volcanoes reawakening after long repose (El Hierro in the Canary Islands) and in frequent eruption (Etna and Stromboli in Sicily). The results provide a basis for enhancing commu- nication protocols during volcanic emergencies.
    Description: Published
    Description: 1-17
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: N/A or not JCR
    Keywords: Etna volcano ; Stromboli volcano ; Canary Islands ; volcanic emergencies ; communication ; volcanic crisis ; Procedures for Communications During Volcanic Emergencies ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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    Geochemistry and volatile content of magmas feeding explosive eruptions at Telica volcano (Nicaragua) (2017)
    Elsevier
    Details
    Publication Date: 2017-09-11
    Description: Telica volcano, in north-west Nicaragua, is a young stratovolcano of intermediate magma composition producing frequent Vulcanian to phreatic explosive eruptions. The Telica stratigraphic record also includes examples of (pre)historic sub-Plinian activity. To refine our knowledge of this very active volcano, weanalyzedmajor element composition and volatile content of melt inclusions fromsomestratigraphically significant Telica tephra deposits. These include: (1) the Scoria Telica Superior (STS) deposit (2000 to 200 years Before Present; Volcanic Explosive Index, VEI, of 2–3) and (2) pyroclasts from the post-1970s eruptive cycle (1982; 2011). Based on measurements with nanoscale secondary ion mass spectrometry, olivine-hosted (forsterite [Fo] N 80) glass inclusions fall into 2 distinct clusters: a group of H2O-rich (1.8–5.2 wt%) inclusions, similar to those of nearby Cerro Negro volcano, and a second group of CO2-rich (360–1700 μg/g CO2) inclusions (Nejapa, Granada). Model calculations show that CO2 dominates the equilibrium magmatic vapor phase in the majority of the primitive inclusions (XCO2 N 0.62–0.95). CO2, sulfur (generally b2000 μg/g) and H2O are lost to the vapor phase during deep decompression (P N 400 MPa) and early crystallization of magmas. Chlorine exhibits a wide concentration range (400–2300 μg/g) in primitive olivine-entrapped melts (likely suggesting variable source heterogeneity) and is typically enriched in the most differentiated melts (1000–3000 μg/g). Primitive, volatile-rich olivine-hosted melt inclusions (entrapment pressures, 5–15 km depth) are exclusively found in the largest-scale Telica eruptions (exemplified by STS in our study). These eruptions are thus tentatively explained as due to injection of deep CO2-rich mafic magma into the shallow crustal plumbing system. More recent (post-1970), milder (VEI 1–2) eruptions, instead, do only exhibit evidence for low-pressure (P b 50–60 MPa), volatile-poor (H2O b 0.3–1.7 wt%; CO2 b 23–308 μg/g) magmatic conditions. These are manifested as andesitic magmas, recording multiple magma mixing events, in pyroxene inclusions.Wepropose that post-1970s eruptions are possibly related to the high viscosity of resident magma in shallow plumbing system (b2.4 km), due to crystallization and degassing
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Telica, Nicaragua ; 04.08. Volcanology
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  • 23
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    Dissolved Carbon in Groundwater versus Gas Emissions from the Soil: The Two Sides of the Same Coin (2017)
    Elsevier
    Details
    Publication Date: 2017-12-13
    Description: This study focuses on the interaction among deep volcanic/hydrothermal gases, groundwater and soil gases at Vulcano Island (Aeolian Archipelago, Italy). The chemical-physical parameters of the groundwater, the total dissolved inorganic carbon (TDIC) and the isotopic composition of the CO2 dissolved in groundwater are reported and discussed. Furthermore, a comparison between soil gases and groundwater indicates that groundwater and soil gases show the same qualitative information, giving a good overall picture of the main degassing zones of a volcanic system, whereas the soil gas discharge provides an evaluation of the mass released by the deep feeding system. This approach can be a useful tool both to characterize mixing and/or interaction processes among different sources and for a monitoring of degassing activity of a volcanic system.
    Description: Published
    Description: 116-119
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: N/A or not JCR
    Keywords: Soil CO2 flux ; Dissolved gases ; Isotope composition of CO2 ; Groundwaters ; Vulcano Island ; 03.02. Hydrology ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
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    Fractionation processes affecting the stable carbon isotope signature of thermal waters from hydrothermal/volcanic systems: The examples of Campi Flegrei and Vulcano Island (southern Italy) (2017)
    Elsevier
    Details
    Publication Date: 2024-05-09
    Description: The carbon isotopic composition of dissolved C-bearing species is a powerful tool to discriminate the origin of carbon in thermal waters from volcanic and hydrothermal systems. However, the δ13C values of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) are often different with respect to the isotopic signature that characterizes the potential carbon primary sources, i.e. deep hydrothermal reservoirs, magmatic gases and organic activity. The most commonly invoked explanation for such isotopic values is related to mixing processes between deep and shallow end-members. Nevertheless, experimental and empirical investigations demonstrated that isotopic fractionation due to secondary processes acting on the uprising fluids from the hydrothermal reservoirs is able to reproduce the measured isotopic values. In this paper,we investigated the chemistry of thermalwaters, collected at Campi Flegrei and Vulcano Island (southern Italy),whose origin is related to interaction processesamongmagmatic gases, meteoric water, seawater and hosting rocks. A special focus was dedicated to the δ13C values of dissolved CO2 (δ13CCO2(aq)) and total dissolved inorganic carbon (δ13CTDIC). The δ13CCO2(aq) and δ13CTDIC values in the water samples fromboth these systems ranged from(i) those measured in fumarolic gases, likely directly related to the deep hydrothermal-magmatic reservoir, and (ii) those typically characterizing biogenic CO2, i.e. produced by microbially-driven degradation of organic matter. A simple mixingmodel of the two end-members, apparently explaining these intermediate carbon isotopic values, contrastswith the chemical composition of the dissolved gases. On the contrary, isotopic fractionation due to secondary processes, such as calcite precipitation, affecting hydrothermal fluids during their underground circulation, seems to exhaustively justify both the chemical and isotopic data. If not recognized, these processes, which frequently occur in volcanic and hydrothermal systems, may lead to an erroneous interpretation of the carbon source, causing an underestimation of the contribution of the hydrothermal/magmatic fluids to the dissolved carbon species. These results pose extreme caution in the interpretation of intermediate δ13CCO2(aq) and δ13CTDIC values for the assessment of the carbon budget of hydrothermal- volcanic systems.
    Description: Published
    Description: 46–57
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Thermal waters ; Carbon isotopes ; Dissolved CO2 ; TDIC ; Volcanic-hydrothermal systems ; Secondary fractionation processes ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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