ALBERT

Beschreibung: We determined the coordination environment of Zn2+ in aqueous Cl- brines at 25 °C and 300 °C using ab initio molecular dynamics simulations. The ZnCl+ and ZnCl2 complexes exist as pseudo-octahedral ZnClm(H2O)6-m clusters at 25 °C but occur as pseudo-tetrahedral ZnClm(H2O)4-m clusters at 300 °C. The ZnCl3- complex occurs as the pseudo-tetrahedral ZnCl3(H2O)- cluster at 25 and 300 °C. The tetrahedral ZnCl42- complex, however, is the dominant Zn−Cl complex at 25 °C, at least in highly concentrated (7.4 m) Cl- brines. The change in hydration number with temperature for the ZnCl+ and ZnCl2 complexes will complicate extrapolations of solvation energies to hydrothermal conditions using a Born-model-based equation of state.

Beschreibung: Oceanic ecosystems altered by interdecadal climate variability may provide a feedback to the physical climate by phytoplankton affecting heat fluxes into the upper ocean and dimethylsulfide fluxes into the atmosphere

Beschreibung: Breaking waves markedly increase the rates of air–sea transfer of momentum, energy and mass. In light to moderate wind conditions, spilling breakers with short wavelengths are observed frequently. Theory and laboratory experiments have shown that, as these waves approach breaking in clean water, a ripple pattern that is dominated by surface tension forms at the crest. Under laboratory conditions and in theory, the transition to turbulent flow is triggered by flow separation under the ripples, typically without leading to overturning of the free surface15. Water surfaces in nature, however, are typically contaminated by surfactant films that alter the surface tension and produce surface elasticity and viscosity16, 17. Here we present the results of laboratory experiments in which spilling breaking waves were generated mechanically in water with a range of surfactant concentrations. We find significant changes in the breaking process owing to surfactants. At the highest concentration of surfactants, a small plunging jet issues from the front face of the wave at a point below the wave crest and entraps a pocket of air on impact with the front face of the wave. The bubbles and turbulence created during this process are likely to increase air–sea transfer.

Beschreibung: Intrinsic oscillations of stable geophysical surface frontal currents of the unsteady, nonlinear, reduced-gravity shallow-water equations on an f plane are investigated analytically and numerically. For frictional (Rayleigh) currents characterized by linear horizontal velocity components and parabolic cross sections, the primitive equations are reduced to a set of coupled nonlinear ordinary differential equations. In the inviscid case, two periodic analytical solutions of the nonlinear problem describing 1) the inertially reversing horizontal displacement of a surface frontal current having a fixed parabolic cross section and 2) the cross-front pulsation of a coastal current emerging from a motionless surface frontal layer are presented. In a linear and in a weakly nonlinear context, analytical expressions for field oscillations and their frequency shift relative to the inertial frequency are presented. For the fully nonlinear problem, solutions referring to a surface frontal coastal current are obtained analytically and numerically. These solutions show that the currents oscillate always superinertially, the frequency and the amplitude of their oscillations depending on the magnitude of the initial disturbance and on the squared current Rossby number. In a linear framework, it is shown that disturbances superimposed on the surface frontal current are standing waves within the bounded region, the frequencies of which are inertial/superinertial for the first mode/higher modes. In the same frame, a zeroth mode, which could be interpreted as the superposition of an inertial wave on a background vorticity field, would formally yield subinertial frequencies. For surface frontal currents affected by Rayleigh friction, it is shown that the magnitude of the mean current decays according to a power law and that the oscillations decay faster, because this decay follows an exponential law. Implications of the intrinsic oscillations and of their rapid dissipation for the near-inertial motion in an active ambient ocean are discussed.

Beschreibung: Aspects of the dynamics of warm-core eddies evolving in a deep ocean are investigated using the results of laboratory experiments and numerical simulations. The vortices, produced experimentally in a system brought to solid body rotation by rapidly lifting a bottomless cylinder containing freshwater immersed in a salty ambient fluid, show clearly the presence of inertial oscillations: deepenings and contractions, shoalings and expansions, alternate during an exact inertial period. These pulsations, though predicted analytically and simulated numerically, had never been measured before for surface eddies having aspect ratios, as well as Rossby and Burger numbers, typical of geophysical warm-core eddies. The spatial structure of the vortex radial and tangential velocity components is analyzed using the experimental results and numerical simulations carried out by means of a layered, nonlinear, reduced-gravity frontal model. It is found that, while the dependence of the vortex radial velocity on the vortex radius evolves toward linearity as time elapses, different spatial structures seem to be possible for the vortex tangential velocity dependence. This behavior, which strongly differs from the “pulson” dynamics, is instead consistent with recently found analytical solutions of the nonlinear, reduced-gravity shallow-water equations describing the dynamics of warm-core eddies on an f plane.

Beschreibung: Two large-scale free-drifting isobaric-floats experiments, “SOFARGOS”/Marine Science and Technology Programme, phase 2 (MAST2) and Mass Transfer and Ecosystem Response (MATER)/MAST3, undertaken in 1994–95 in the northwestern Mediterranean Sea and in 1997–98 in the Algerian Basin, respectively, have revealed for the first time that Western Mediterranean Deep Water, newly formed by deep convection in the Gulf of Lion (the so-called Medoc site), can be advected several hundreds of kilometers away from the formation area by anticyclonic submesoscale coherent vortices (SCVs). This behavior implies that SCVs participate actively in the large-scale thermohaline circulation and deep ventilation of the western Mediterranean Sea. These SCVs are characterized by small radius (5 km), very low potential vorticity, high aspect ratio (0.1), and extended lifetime (〉0.5 yr).

Beschreibung: Bulk properties of the Denmark Strait overflow (DSO) plume observed in velocity and hydrography surveys undertaken in 1997 and 1998 are described. Despite the presence of considerable short-term variability, it is found that the pathway and evolution of the plume density anomaly are remarkably steady. Bottom stress measurements show that the pathway of the plume core matches well with a rate of descent controlled by friction. The estimated entrainment rate diagnosed from the rate of plume dilution with distance shows a marked increase in entrainment at approximately 125 km from the sill, leading to a net dilution consistent with previous reports of a doubling of overflow transport measured by current meter arrays. The entrainment rate increase is likely related to the increased topographic slopes in the region, compounded by a decrease in interface stratification as the plume is diluted and enters a denser background.

Beschreibung: Noble-gas geochemistry is an important tool for understanding planetary processes from accretion to mantle dynamics and atmospheric formation. Central to much of the modelling of such processes is the crystal–melt partitioning of noble gases during mantle melting, magma ascent and near-surface degassing5. Geochemists have traditionally considered the 'inert' noble gases to be extremely incompatible elements, with almost 100 per cent extraction efficiency from the solid phase during melting processes. Previously published experimental data on partitioning between crystalline silicates and melts has, however, suggested that noble gases approach compatible behaviour, and a significant proportion should therefore remain in the mantle during melt extraction. Here we present experimental data to show that noble gases are more incompatible than previously demonstrated, but not necessarily to the extent assumed or required by geochemical models. Independent atomistic computer simulations indicate that noble gases can be considered as species of 'zero charge' incorporated at crystal lattice sites. Together with the lattice strain model9, 10, this provides a theoretical framework with which to model noble-gas geochemistry as a function of residual mantle mineralogy.

Beschreibung: High-performance liquid chromatography-electrospray ionization mass spectrometry was applied to the detection of the iron(III) complexes of the hydroxamate siderophores rhodotoluric acid, deferrioxamine B, and deferrichrome. Separation of the iron(III) complexes was obtained using a polystyrene-divinylbenzene stationary phase. The retention and responses of ferrioxamine and ferrichrome were optimal when a gradient elution program with methanol and 0.1% (v/v) formic acid as the mobile phases was used. These conditions were also suitable for the retention and separation of the uncomplexed ligands. Retention of iron(III) rhodotoluate was improved when formic acid was replaced by the ion-pairing reagent heptafluorobutyric acid (0.1%). Detection limits for the ferric complexes, defined as 3 SD of the lowest determined standard, were 26 nM for iron(III) rhodotoluate, 0.23 nM for ferrioxamine, and 0.40 nM for ferrichrome. A protocol for the solid-phase extraction of these hydroxamate siderophores from seawater was developed and applied to the extraction of siderophores from enriched incubated seawater samples.

Beschreibung: High-performance liquid chromatography-electrospray ionization mass spectrometry was applied to the detection of the iron(III) complexes of the hydroxamate siderophores rhodotoluric acid, deferrioxamine B, and deferrichrome. Separation of the iron(III) complexes was obtained using a polystyrene-divinylbenzene stationary phase. The retention and responses of ferrioxamine and ferrichrome were optimal when a gradient elution program with methanol and 0.1% (v/v) formic acid as the mobile phases was used. These conditions were also suitable for the retention and separation of the uncomplexed ligands. Retention of iron(III) rhodotoluate was improved when formic acid was replaced by the ion-pairing reagent heptafluorobutyric acid (0.1%). Detection limits for the ferric complexes, defined as 3 SD of the lowest determined standard, were 26 nM for iron(III) rhodotoluate, 0.23 nM for ferrioxamine, and 0.40 nM for ferrichrome. A protocol for the solid-phase extraction of these hydroxamate siderophores from seawater was developed and applied to the extraction of siderophores from enriched incubated seawater samples.

Beschreibung: A new shipboard current profiler, a 75-kHz ocean surveyor, was operationally used during two research cruises in the tropical Atlantic and the subpolar North Atlantic, respectively. Here, a report is presented on the first experience with this instrument in two very different current regimes, in the Tropics with large vertical shears, and in the subpolar regime with mainly barotropic flow. The ocean surveyor continuously measured currents in the upper ocean from near the surface to about 500–700-m depth. The measurement range showed a dependence on the regional and temporal variations of scattering particles and on the intensity of swell and wind waves. Statistical comparisons are performed with on-station lowered acoustic Doppler current profiler (LADCP) profiles and underway measurements by classic shipboard acoustic Doppler current profiler (ADCP) measurements. Accuracy estimates for hourly averaged ocean surveyor currents result in errors of about 1 cm s–1 for on-station data and of 2–4 cm s–1 for underway measurements, depending on the regional abundance of scatterers and on the weather conditions encountered.

Beschreibung: A new mechanism is proposed that explains two key features of the observed El Niño–Southern Oscillation (ENSO) phenomenon—its irregularity and decadal amplitude changes. Using a low-order ENSO model, the authors show that the nonlinearities in the tropical heat budget can lead to bursting behavior characterized by decadal occurrences of strong El Niño events. La Niña events are not affected, a feature that is also seen in ENSO observations. One key result of this analysis is that decadal variability in the Tropics can be generated without invoking extratropical processes or stochastic forcing. The El Niño bursting behavior simulated by the low-order ENSO model can be understood in terms of the concept of homoclinic and heteroclinic connections. It is shown that this new model for ENSO amplitude modulations and irregularity, although difficult to prove, might explain some features of ENSO dynamics seen in more complex climate models and the observations.

Beschreibung: Processes that influence the volume and heat transport across the Greenland–Scotland Ridge system are investigated in a numerical model with ° horizontal resolution. The focus is on the sensitivity of cross-ridge transports and the reaction of the subpolar North Atlantic Ocean circulation to changes in wind stress and buoyancy forcing on seasonal to interannual timescales. A general relation between changes in wind stress or cross-ridge density contrasts and the overturning transport of Greenland–Iceland–Norwegian Seas source water is established from a series of idealized experiments. The relation is used subsequently to interpret changes in an experiment over the years 1992–97 with realistic forcing. On seasonal and interannual timescales there is a clear correlation between heat flux and wind stress curl variability. The realistic model suggests a steady decrease in the strength of the cyclonic subpolar gyre of the North Atlantic with a corresponding decrease in heat transport during the 1990s

Beschreibung: The role of mean and stochastic freshwater forcing on the generation of millennial-scale climate variability in the North Atlantic is studied using a low-order coupled atmosphere–ocean–sea ice model. It is shown that millennial-scale oscillations can be excited stochastically, when the North Atlantic Ocean is fresh enough. This finding is used in order to interpret the aftermath of massive iceberg surges (Heinrich events) in the glacial North Atlantic, which are characterized by an excitation of Dansgaard–Oeschger events. Based on model results, it is hypothesized that Heinrich events trigger Dansgaard–Oeschger cycles and that furthermore the occurrence of Heinrich events is dependent on the accumulated climatic effect of a series of Dansgaard–Oeschger events. This scenario leads to a coupled ocean–ice sheet oscillation that shares many similarities with the Bond cycle. Further sensitivity experiments reveal that the timescale of the oscillations can be decomposed into stochastic, linear, and nonlinear deterministic components. A schematic bifurcation diagram is used to compare theoretical results with paleoclimatic data.

Beschreibung: More than 50% of the Earth' s surface is sea floor below 3,000 m of water. Most of this major reservoir in the global carbon cycle and final repository for anthropogenic wastes is characterized by severe food limitation. Phytodetritus is the major food source for abyssal benthic communities, and a large fraction of the annual food load can arrive in pulses within a few days1, 2. Owing to logistical constraints, the available data concerning the fate of such a pulse are scattered3, 4 and often contradictory5, 6, 7, 8, 9, 10, hampering global carbon modelling and anthropogenic impact assessments. We quantified (over a period of 2.5 to 23 days) the response of an abyssal benthic community to a phytodetritus pulse, on the basis of 11 in situ experiments. Here we report that, in contrast to previous hypotheses5, 6, 7, 8, 9, 10, 11, the sediment community oxygen consumption doubled immediately, and that macrofauna were very important for initial carbon degradation. The retarded response of bacteria and Foraminifera, the restriction of microbial carbon degradation to the sediment surface, and the low total carbon turnover distinguish abyssal from continental-slope ‘deep-sea’ sediments.

Beschreibung: The shells of the planktonic foraminifer Neogloboquadrina pachyderma have become a classical tool for reconstructing glacial–interglacial climate conditions in the North Atlantic Ocean1, 2, 3. Palaeoceanographers utilize its left- and right-coiling variants, which exhibit a distinctive reciprocal temperature and water mass related shift in faunal abundance both at present and in late Quaternary sediments1, 2, 4, 5. Recently discovered cryptic genetic diversity in planktonic foraminifers6, 7, 8 now poses significant questions for these studies. Here we report genetic evidence demonstrating that the apparent ‘single species’ shell-based records of right-coiling N. pachyderma used in palaeoceanographic reconstructions contain an alternation in species as environmental factors change. This is reflected in a species-dependent incremental shift in right-coiling N. pachyderma shell calcite δ18O between the Last Glacial Maximum and full Holocene conditions. Guided by the percentage dextral coiling ratio, our findings enhance the use of δ18O records of right-coiling N. pachyderma for future study. They also highlight the need to genetically investigate other important morphospecies to refine their accuracy and reliability as palaeoceanographic proxies.

Beschreibung: Synoptic-scale variability in the air–sea turbulent fluxes in the areas of midlatitudinal western boundary currents is analyzed. In the Gulf Stream area, ocean–atmosphere fluxes on synoptic time- and space scales are clearly coordinated with the propagating synoptic-scale atmospheric transients. The statistical analysis of 6-hourly resolution sea level pressure and surface turbulent fluxes from the NCEP–NCAR reanalysis for the period from 1948 to 2000 in the area of strong sea surface temperature gradients in the Gulf Stream gives strong proof for the association between the propagating cyclones and synoptic patterns of surface turbulent fluxes. It is shown that sea–air interaction in this area is controlled by the sharpness of surface temperature gradients in the ocean and by the intensity of the advection of the air masses in different parts of cyclones during the cold-air and warm-air outbreaks. A simple parameter based on the joint consideration of the characteristics of sea surface temperature and sea level pressure fields is used to characterize the synoptic variability of air–sea turbulent fluxes. The effectiveness of the relationship between surface temperature and surface pressure on one side and air–sea flux anomalies on the other vary from year to year in phase with variability in the frequencies of deep atmospheric cyclones in the Gulf Stream area. The limits of applicability of the approach, its sensitivity to higher-resolution sea surface temperature data, and the possibility of its further applications are discussed.

Beschreibung: The Messinian salinity crisis—the desiccation of the Mediterranean Sea between 5.96 and 5.33 million years (Myr) ago1—was one of the most dramatic events on Earth during the Cenozoic era2. It resulted from the closure of marine gateways between the Atlantic Ocean and the Mediterranean Sea, the causes of which remain enigmatic. Here we use the age and composition of volcanic rocks to reconstruct the geodynamic evolution of the westernmost Mediterranean from the Middle Miocene epoch to the Pleistocene epoch (about 12.1–0.65 Myr ago). Our data show that a marked shift in the geochemistry of mantle-derived volcanic rocks, reflecting a change from subduction-related to intraplate-type volcanism, occurred between 6.3 and 4.8 Myr ago, largely synchronous with the Messinian salinity crisis. Using a thermomechanical model, we show that westward roll back of subducted Tethys oceanic lithosphere and associated asthenospheric upwelling provides a plausible mechanism for producing the shift in magma chemistry and the necessary uplift (approx1 km) along the African and Iberian continental margins to close the Miocene marine gateways, thereby causing the Messinian salinity crisis.

Beschreibung: An excellent sediment record from the Arabian Sea traces recent patterns in the activity of the Asian monsoon. It reveals both variability in monsoon strength and links with climatic events elsewhere. The monsoon is the main determinant of environmental conditions over much of Asia, and so affects the most densely populated region on Earth. Differential heating of the north Indian Ocean and the northwest Pacific, and of the Asian land-mass, cause the seasonal reversal of monsoon winds. In summer, these winds blow northwards over the northern Indian Ocean, carrying huge amounts of moisture over the neighbouring land. The ensuing heavy rainfall can have devastating consequences for human life and livelihood. Conversely, agriculture in Asia depends on monsoon rains; and the seasonal upwelling of nutrient-laden subsurface waters, driven by monsoon winds, is essential to the success of coastal fisheries.

Beschreibung: A high-resolution mapping and sampling study of the Gakkel ridge was accomplished during an international ice-breaker expedition to the high Arctic and North Pole in summer 2001. For this slowest-spreading endmember of the global mid-ocean-ridge system, predictions were that magmatism should progressively diminish as the spreading rate decreases along the ridge, and that hydrothermal activity should be rare. Instead, it was found that magmatic variations are irregular, and that hydrothermal activity is abundant. A 300-kilometre-long central amagmatic zone, where mantle peridotites are emplaced directly in the ridge axis, lies between abundant, continuous volcanism in the west, and large, widely spaced volcanic centres in the east. These observations demonstrate that the extent of mantle melting is not a simple function of spreading rate: mantle temperatures at depth or mantle chemistry (or both) must vary significantly along-axis. Highly punctuated volcanism in the absence of ridge offsets suggests that first-order ridge segmentation is controlled by mantle processes of melting and melt segregation. The strong focusing of magmatic activity coupled with faulting may account for the unexpectedly high levels of hydrothermal activity observed.

Beschreibung: Recent observational studies have shown that the centers of action of interannual variability of the North Atlantic Oscillation (NAO) were located farther eastward during winters of the period 1978–97 compared to previous decades of the twentieth century. In this study, which focuses on the winter season (December–March), new diagnostics characterizing this shift are presented. Further, the importance of this shift for NAO-related interannual climate variability in the North Atlantic region is discussed. It is shown that an NAO-related eastward shift in variability can be found for a wide range of different parameters like the number of deep cyclones, near-surface air temperature, and turbulent surface heat flux throughout the North Atlantic region. By using a near-surface air temperature dataset that is homogenous with respect to the kind of observations used, it is shown that the eastward shift is not an artifact of changes in observational practices that took place around the late 1970s. Finally, an EOF-based Monte Carlo test is developed to quantify the probability of changes in the spatial structure of interannual NAO variability for a relatively short (20 yr) time series given multivariate “white noise.” It is estimated that the likelihood for differences in the spatial structure of the NAO between two independent 20-yr periods, which are similar (as measured by the angle and pattern correlation between two NAO patterns) to the observed differences, to occur just by chance is about 18%. From the above results it is argued that care has to be taken when conclusions about long-term properties of NAO-related climate variability are being drawn from relatively short recent observational data (e.g., 1978–97).

Beschreibung: A 20-Myr record of creation of oceanic lithosphere is exposed along a segment of the central Mid-Atlantic Ridge on an uplifted sliver of lithosphere. The degree of melting of the mantle that is upwelling below the ridge, estimated from the chemistry of the exposed mantle rocks, as well as crustal thickness inferred from gravity measurements, show oscillations of ∼3–4 Myr superimposed on a longer-term steady increase with time. The time lag between oscillations of mantle melting and crustal thickness indicates that the mantle is upwelling at an average rate of ∼25 mm yr-1, but this appears to vary through time. Slow-spreading lithosphere seems to form through dynamic pulses of mantle upwelling and melting, leading not only to along-axis segmentation but also to across-axis structural variability. Also, the central Mid-Atlantic Ridge appears to have become steadily hotter over the past 20 Myr, possibly owing to north–south mantle flow.

Beschreibung: The speed at which mid-ocean ridges grind out new ocean floor varies considerably. The slowest-spreading ridges are especially tough to study — but the latest data show that they are especially intriguing.

Beschreibung: A new type of ocean general circulation model with simplified physics is described and tested for various simple wind-driven circulation problems. The model consists of the vorticity balance of the depth-averaged flow and a hierarchy of equations for “vertical moments” of density and baroclinic velocity. The first vertical density moment is the (vertically integrated) potential energy, which is used to describe the predominant link between the barotropic and the baroclinic oceanic flow in the presence of sloping topography. Tendency equations for the vertical moments of density and baroclinic velocity and an appropriate truncation of the coupled hierarchy of moments are derived that, together with the barotropic vorticity balance, yield a closed set of equations describing the barotropic–baroclinic interaction (BARBI) model of the oceanic circulation. Idealized companion experiments with a numerical implementation of the BARBI model and a primitive equation model indicate that wave propagation properties and baroclinic adjustments are correctly represented in BARBI in midlatitudes as well as in equatorial latitudes. Furthermore, a set of experiments with a realistic application to the Atlantic/Southern Ocean system reproduces important aspects that have been previously reported by studies of gyre circulations and circumpolar currents using full primitive equation models

Beschreibung: Serious concerns have been raised about the ecological effects of industrialized fishing1, 2, 3, spurring a United Nations resolution on restoring fisheries and marine ecosystems to healthy levels4. However, a prerequisite for restoration is a general understanding of the composition and abundance of unexploited fish communities, relative to contemporary ones. We constructed trajectories of community biomass and composition of large predatory fishes in four continental shelf and nine oceanic systems, using all available data from the beginning of exploitation. Industrialized fisheries typically reduced community biomass by 80% within 15 years of exploitation. Compensatory increases in fast-growing species were observed, but often reversed within a decade. Using a meta-analytic approach, we estimate that large predatory fish biomass today is only about 10% of pre-industrial levels. We conclude that declines of large predators in coastal regions5 have extended throughout the global ocean, with potentially serious consequences for ecosystems5, 6, 7. Our analysis suggests that management based on recent data alone may be misleading, and provides minimum estimates for unexploited communities, which could serve as the 'missing baseline'8 needed for future restoration efforts.

Beschreibung: A simple stochastic atmosphere model is coupled to a realistic model of the North Atlantic Ocean. A north–south SST dipole, with its zero line centered along the subpolar front, influences the atmosphere model, which in turn forces the ocean model by surface fluxes related to the North Atlantic Oscillation. The coupled system exhibits a damped decadal oscillation associated with the adjustment through the ocean model to the changing surface forcing. The oscillation consists of a fast wind-driven, positive feedback of the ocean and a delayed negative feedback orchestrated by overturning circulation anomalies. The positive feedback turns out to be necessary to distinguish the coupled oscillation from that in a model without any influence from the ocean to the atmosphere. Using a novel diagnosing technique, it is possible to rule out the importance of baroclinic wave processes for determining the period of the oscillation, and to show the important role played by anomalous geostrophic advection in sustaining the oscillation.

Beschreibung: The dehydration of subducting oceanic crust and upper mantle has been inferred both to promote the partial melting leading to arc magmatism and to induce intraslab intermediate-depth earthquakes, at depths of 50–300 km. Yet there is still no consensus about how slab hydration occurs or where and how much chemically bound water is stored within the crust and mantle of the incoming plate. Here we document that bending-related faulting of the incoming plate at the Middle America trench creates a pervasive tectonic fabric that cuts across the crust, penetrating deep into the mantle. Faulting is active across the entire ocean trench slope, promoting hydration of the cold crust and upper mantle surrounding these deep active faults. The along-strike length and depth of penetration of these faults are also similar to the dimensions of the rupture area of intermediate-depth earthquakes.