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  • Artikel  (13)
  • Gas hydrate  (7)
  • Climate change  (6)
  • American Geophysical Union  (13)
  • American Institute of Physics (AIP)
  • Wiley
  • 2010-2014  (13)
  • 1995-1999
  • 2010  (13)
  • 1996
  • 1
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    Impact of ocean carbon system variability on the detection of temporal increases in anthropogenic CO2 (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): C03019, doi:10.1029/2007JC004153.
    Beschreibung: Estimates of temporal trends in oceanic anthropogenic carbon dioxide (CO2) rely on the ability of empirical methods to remove the large natural variability of the ocean carbon system. A coupled carbon-climate model is used to evaluate these empirical methods. Both the ΔC* and multiple linear regression (MLR) techniques reproduce the predicted increase in dissolved inorganic carbon for the majority of the ocean and have similar average percent errors for decadal differences (24.1% and 25.5%, respectively). However, this study identifies several regions where these methods may introduce errors. Of particular note are mode and deep water formation regions, where changes in air-sea disequilibrium and structure in the MLR residuals introduce errors. These results have significant implications for decadal repeat hydrography programs, indicating the need for subannual sampling in certain regions of the oceans in order to better constrain the natural variability in the system and to robustly estimate the intrusion of anthropogenic CO2.
    Beschreibung: We would like to acknowledge funding from NSF (OCE02-23869), NCAR, the WHOI Ocean Climate Institute, a Linden Earth Systems Graduate Fellowship (MIT), and a National Defense Science and Engineering Graduate Fellowship. NCAR is sponsored by the National Science Foundation. R.W. is supported by the Office of Oceanic and Atmospheric Research at NOAA.
    Schlagwort(e): Carbon dioxide ; Ocean carbon sink ; Climate change
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  • 2
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    Volume change associated with formation and dissociation of hydrate in sediment (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 11 (2010): Q03007, doi:10.1029/2009GC002667.
    Beschreibung: Gas hydrate formation and dissociation in sediments are accompanied by changes in the bulk volume of the sediment and can lead to changes in sediment properties, loss of integrity for boreholes, and possibly regional subsidence of the ground surface over areas where methane might be produced from gas hydrate in the future. Experiments on sand, silts, and clay subject to different effective stress and containing different saturations of hydrate formed from dissolved phase tetrahydrofuran are used to systematically investigate the impact of gas hydrate formation and dissociation on bulk sediment volume. Volume changes in low specific surface sediments (i.e., having a rigid sediment skeleton like sand) are much lower than those measured in high specific surface sediments (e.g., clay). Early hydrate formation is accompanied by contraction for all soils and most stress states in part because growing gas hydrate crystals buckle skeletal force chains. Dilation can occur at high hydrate saturations. Hydrate dissociation under drained, zero lateral strain conditions is always associated with some contraction, regardless of soil type, effective stress level, or hydrate saturation. Changes in void ratio during formation-dissociation decrease at high effective stress levels. The volumetric strain during dissociation under zero lateral strain scales with hydrate saturation and sediment compressibility. The volumetric strain during dissociation under high shear is a function of the initial volume average void ratio and the stress-dependent critical state void ratio of the sediment. Other contributions to volume reduction upon hydrate dissociation are related to segregated hydrate in lenses and nodules. For natural gas hydrates, some conditions (e.g., gas production driven by depressurization) might contribute to additional volume reduction by increasing the effective stress.
    Beschreibung: This research was initially supported by the Chevron Joint Industry Project on Methane Hydrates under contract DE‐FC26‐01NT41330 from the U.S. Department of Energy to Georgia Tech. Additional support was provided to J. Y. Lee by KIGAM, GHDO, and MKE and J. C. Santamarina by the Goizueta Foundation.
    Schlagwort(e): Gas hydrate ; Hydrate-bearing sediment ; Phase transformation ; Strain
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  • 3
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    Assessing sedimentary records of paleohurricane activity using modeled hurricane climatology (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q09V10, doi:10.1029/2008GC002043.
    Beschreibung: Patterns of overwash deposition observed within back-barrier sediment archives can indicate past changes in tropical cyclone activity; however, it is necessary to evaluate the significance of observed trends in the context of the full range of variability under modern climate conditions. Here we present a method for assessing the statistical significance of patterns observed within a sedimentary hurricane-overwash reconstruction. To alleviate restrictions associated with the limited number of historical hurricanes affecting a specific site, we apply a recently published technique for generating a large number of synthetic storms using a coupled ocean-atmosphere hurricane model set to simulate modern climatology. Thousands of overwash records are generated for a site using a random draw of these synthetic hurricanes, a prescribed threshold for overwash, and a specified temporal resolution based on sedimentation rates observed at a particular site. As a test case we apply this Monte Carlo technique to a hurricane-induced overwash reconstruction developed from Laguna Playa Grande (LPG), a coastal lagoon located on the island of Vieques, Puerto Rico in the northeastern Caribbean. Apparent overwash rates in the LPG overwash record are observed to be four times lower between 2500 and 1000 years B.P. when compared to apparent overwash rates during the last 300 years. However, probability distributions based on Monte Carlo simulations indicate that as much as 65% of this drop can be explained by a reduction in the temporal resolution for older sediments due to a decrease in sedimentation rates. Periods of no apparent overwash activity at LPG between 2500 and 3600 years B.P. and 500–1000 years B.P. are exceptionally long and are unlikely to occur (above 99% confidence) under the current climate conditions. In addition, breaks in activity are difficult to produce even when the hurricane model is forced to a constant El Niño state. Results from this study continue to support the interpretation that the western North Atlantic has exhibited significant changes in hurricane climatology over the last 5500 years.
    Beschreibung: Funding for this research was provided by the Earth Systems History Program of the National Science Foundation, Risk Prediction Initiative, National Geographic Society, Coastal Ocean Institute at WHOI, and the Andrew W. Mellon Foundation Endowed Fund for Innovative Research.
    Schlagwort(e): Tropical cyclones ; Paleotempestology ; Paleoclimate ; Holocene ; Climate change ; Sedimentology
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  • 4
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    Sediment and nutrient delivery from thermokarst features in the foothills of the North Slope, Alaska : potential impacts on headwater stream ecosystems (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): G02026, doi:10.1029/2007JG000470.
    Beschreibung: Permafrost is a defining characteristic of the Arctic environment. However, climate warming is thawing permafrost in many areas leading to failures in soil structure called thermokarst. An extensive survey of a 600 km2 area in and around the Toolik Lake Natural Research Area (TLNRA) revealed at least 34 thermokarst features, two thirds of which were new since ∼1980 when a high resolution aerial survey of the area was done. Most of these thermokarst features were associated with headwater streams or lakes. We have measured significantly increased sediment and nutrient loading from thermokarst features to streams in two well-studied locations near the TLNRA. One small thermokarst gully that formed in 2003 on the Toolik River in a 0.9 km2 subcatchment delivered more sediment to the river than is normally delivered in 18 years from 132 km2 in the adjacent upper Kuparuk River basin (a long-term monitoring reference site). Ammonium, nitrate, and phosphate concentrations downstream from a thermokarst feature on Imnavait Creek increased significantly compared to upstream reference concentrations and the increased concentrations persisted over the period of sampling (1999–2005). The downstream concentrations were similar to those we have used in a long-term experimental manipulation of the Kuparuk River and that have significantly altered the structure and function of that river. A subsampling of other thermokarst features from the extensive regional survey showed that concentrations of ammonium, nitrate, and phosphate were always higher downstream of the thermokarst features. Our previous research has shown that even minor increases in nutrient loading stimulate primary and secondary production. However, increased sediment loading could interfere with benthic communities and change the responses to increased nutrient delivery. Although the terrestrial area impacted by thermokarsts is limited, the aquatic habitat altered by these failures can be extensive. If warming in the Arctic foothills accelerates thermokarst formation, there may be substantial and wide-spread impacts on arctic stream ecosystems that are currently poorly understood.
    Beschreibung: The results presented in this report are based upon work supported by the U.S. National Science Foundation under grants to the Arctic Hyporheic project (OPP- 0327440) and the Arctic Long-Term Ecological Research Program (DEB- 9810222).
    Schlagwort(e): Arctic ; Climate change ; Streams ; Ecosystem dynamics ; Sediment ; Thermokarst ; Water quality
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  • 5
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    Detection of change in the Arctic using satellite and in situ data (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2003. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 108, C12 (2003): 3384, doi:10.1029/2002JC001347.
    Beschreibung: The decade of the 1990s was the warmest decade of the last century, while the year 1998 was the warmest year ever observed by modern techniques, with 9 out of 12 months of the year being the warmest months. Satellite ice cover and surface temperature data, European Centre for Medium-Range Weather Forecasts (wind), and ocean hydrographic data are examined to gain insights into this warming phenomenon. Areas of ice-free water in both western and eastern regions of the Arctic are found to have followed a cyclical pattern with approximately decadal period but with a lag of about 3 years between the eastern and western regions. The pattern was interrupted by unusually large anomalies in 1993 and 1998 in the western region and in 1995 in the eastern region. The area of open water in 1998 was the largest ever observed in the western region and occurred concurrently with large surface temperature anomalies in the area and adjacent regions. This also occurred at a time when the atmospheric circulation changed from predominantly cyclonic in 1996 to anticyclonic in 1997 and 1998. Detailed hydrographic measurements over the same general area in April 1996 and April 1997 indicate a warming and significant freshening in the top layer of the ocean, suggesting increases in ice melt and/or river runoff. Continuous ocean temperature and salinity data from ocean buoys at depths of 8, 45, and 75 m confirm these results and show large interannual changes during the 1996–1998 period. Surface temperature data show a general warming in the region that is highly correlated with observed decline in summer sea ice, while hydrographic data suggest that in 1997 and 1998, the upper part of the ocean was unusually fresh and warm compared to available data between 1956 and 1996.
    Beschreibung: Deployments of the IOEB were supported by the Japanese Marine Science and Technology Center (JAMSTEC).
    Schlagwort(e): Arctic Sea ice ; Climate change ; Surface temperature ; Wind ; Buoy ; Hydrography
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  • 6
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    Effects of tropospheric ozone pollution on net primary productivity and carbon storage in terrestrial ecosystems of China (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): D22S09, doi:10.1029/2007JD008521.
    Beschreibung: We investigated the potential effects of elevated ozone (O3) along with climate variability, increasing CO2, and land use change on net primary productivity (NPP) and carbon storage in China's terrestrial ecosystems for the period 1961–2000 with a process-based Dynamic Land Ecosystem Model (DLEM) forced by the gridded data of historical tropospheric O3 and other environmental factors. The simulated results showed that elevated O3 could result in a mean 4.5% reduction in NPP and 0.9% reduction in total carbon storage nationwide from 1961 to 2000. The reduction of carbon storage varied from 0.1 Tg C to 312 Tg C (a decreased rate ranging from 0.2% to 6.9%) among plant functional types. The effects of tropospheric O3 on NPP were strongest in east-central China. Significant reductions in NPP occurred in northeastern and central China where a large proportion of cropland is distributed. The O3 effects on carbon fluxes and storage are dependent upon other environmental factors. Therefore direct and indirect effects of O3, as well as interactive effects with other environmental factors, should be taken into account in order to accurately assess the regional carbon budget in China. The results showed that the adverse influences of increasing O3 concentration across China on NPP could be an important disturbance factor on carbon storage in the near future, and the improvement of air quality in China could enhance the capability of China's terrestrial ecosystems to sequester more atmospheric CO2. Our estimation of O3 impacts on NPP and carbon storage in China, however, must be used with caution because of the limitation of historical tropospheric O3 data and other uncertainties associated with model parameters and field experiments.
    Beschreibung: This research is funded by NASA Interdisciplinary Science Program (NNG04GM39C).
    Schlagwort(e): Air pollution ; Carbon storage ; China ; Climate change ; Net primary productivity ; Tropospheric ozone
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  • 7
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    Thermal conductivity of hydrate-bearing sediments (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): B11103, doi:10.1029/2008JB006235.
    Beschreibung: A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate–saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate–bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces.
    Beschreibung: This work was supported by the Chevron Joint Industry Project on Methane Hydrates under contract DE-FC26- 01NT41330 to Georgia Institute of Technology from the U.S. Department of Energy’s National Energy Technology Laboratory. J.C.S. received additional support from the Goizueta Foundation. C.R. thanks the Petroleum Research Fund of the American Chemical Society under AC8–31351 for early support of thermal conductivity research on hydrate-bearing sediments at Georgia Institute of Technology.
    Schlagwort(e): Gas hydrate
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  • 8
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    Elastic wave speeds and moduli in polycrystalline ice Ih, sI methane hydrate, and sII methane-ethane hydrate (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 114 (2009): B02212, doi:10.1029/2008JB006132.
    Beschreibung: We used ultrasonic pulse transmission to measure compressional, P, and shear, S, wave speeds in laboratory-formed polycrystalline ice Ih, sI methane hydrate, and sII methane-ethane hydrate. From the wave speed's linear dependence on temperature and pressure and from the sample's calculated density, we derived expressions for bulk, shear, and compressional wave moduli and Poisson's ratio from −20 to −5°C and 22.4 to 32.8 MPa for ice Ih, −20 to 15°C and 30.5 to 97.7 MPa for sI methane hydrate, and −20 to 10°C and 30.5 to 91.6 MPa for sII methane-ethane hydrate. All three materials had comparable P and S wave speeds and decreasing shear wave speeds with increasing applied pressure. Each material also showed evidence of rapid intergranular bonding, with a corresponding increase in wave speed, in response to pauses in sample deformation. There were also key differences. Resistance to uniaxial compaction, indicated by the pressure required to compact initially porous samples, was significantly lower for ice Ih than for either hydrate. The ice Ih shear modulus decreased with increasing pressure, in contrast to the increase measured in both hydrates.
    Beschreibung: This work was supported by NSF grant OCE-97-10506, DOE grants DE-FG0386ER 13601 and DE-FG07-96ER 14723, DOE/LLNL contract W-7405-ENG-48, GRI grant 5094-210-3235- 1, NEDO, as well as by the U.S. Geological Survey’s Coastal and Marine Geology and Eastern Region Gas Hydrate Programs.
    Schlagwort(e): Wave speed ; Elastic moduli ; Gas hydrate
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  • 9
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    Large-scale responses of complex-shaped coastlines to local shoreline stabilization and climate change (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): F03033, doi:10.1029/2009JF001486.
    Beschreibung: When modeling the large-scale (〉 km) evolution of coastline morphology, the influence of natural forces is not the only consideration; ongoing direct human manipulations can substantially drive geomorphic change. In this paper, we couple a human component to a numerical model of large-scale coastline evolution, incorporating beach “nourishment” (periodically placing sand on the beach, also called “beach replenishment” or “beach fill”). Beach nourishment is the most prevalent means humans employ to alter the natural shoreline system in our case study, the Carolina coastline. Beach nourishment can cause shorelines adjacent to those that are nourished to shift both seaward and landward. When we further consider how changes to storm behaviors could change wave climates, the magnitude of morphological change induced by beach nourishment can rival that expected from sea level rise and affect the coast as far as tens of kilometers away from the nourishment site. In some instances, nonlocal processes governing large-scale cuspate-cape coastline evolution may transmit the human morphological “signal” over surprisingly large (hundreds of kilometer) distances.
    Beschreibung: The National Science Foundation (DEB 0507987) and the Duke University Center on Global Change supported this work.
    Schlagwort(e): Coastline evolution ; Beach nourishment ; Climate change
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  • 10
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    Physical properties of hydrate-bearing sediments (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 47 (2009): RG4003, doi:10.1029/2008RG000279.
    Beschreibung: Methane gas hydrates, crystalline inclusion compounds formed from methane and water, are found in marine continental margin and permafrost sediments worldwide. This article reviews the current understanding of phenomena involved in gas hydrate formation and the physical properties of hydrate-bearing sediments. Formation phenomena include pore-scale habit, solubility, spatial variability, and host sediment aggregate properties. Physical properties include thermal properties, permeability, electrical conductivity and permittivity, small-strain elastic P and S wave velocities, shear strength, and volume changes resulting from hydrate dissociation. The magnitudes and interdependencies of these properties are critically important for predicting and quantifying macroscale responses of hydrate-bearing sediments to changes in mechanical, thermal, or chemical boundary conditions. These predictions are vital for mitigating borehole, local, and regional slope stability hazards; optimizing recovery techniques for extracting methane from hydrate-bearing sediments or sequestering carbon dioxide in gas hydrate; and evaluating the role of gas hydrate in the global carbon cycle.
    Beschreibung: This work is the product of a Department of Energy (DOE)–sponsored Physical Property workshop held in Atlanta, Georgia, 16–19 March 2008. The workshop was supported by Department of Energy contract DE-AI21-92MC29214. U.S. Geological Survey contributions were supported by the Gas Hydrate Project of the U.S. Geological Survey's Coastal and Marine Geology Program. Lawrence Berkeley National Laboratory contributions were supported by the Assistant Secretary for Fossil Energy, Office of Oil and Natural Gas, through the National Energy Technology Laboratory of the U.S. DOE under contract DE-AC02-05CH11231. Georgia Institute of Technology contributions were supported by the Goizueta Foundation, DOE DE-FC26-06NT42963, and the DOE-JIP administered by Chevron award DE-FC26-610 01NT41330. Rice University contributions were supported by the DOE under contract DE-FC26-06NT42960.
    Schlagwort(e): Physical properties ; Hydrate-bearing sediment ; Gas hydrate
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  • 11
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    Mechanical properties of sand, silt, and clay containing tetrahydrofuran hydrate (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): B04106, doi:10.1029/2006JB004484.
    Beschreibung: The mechanical behavior of hydrate-bearing sediments subjected to large strains has relevance for the stability of the seafloor and submarine slopes, drilling and coring operations, and the analysis of certain small-strain properties of these sediments (for example, seismic velocities). This study reports on the results of comprehensive axial compression triaxial tests conducted at up to 1 MPa confining pressure on sand, crushed silt, precipitated silt, and clay specimens with closely controlled concentrations of synthetic hydrate. The results show that the stress-strain behavior of hydrate-bearing sediments is a complex function of particle size, confining pressure, and hydrate concentration. The mechanical properties of hydrate-bearing sediments at low hydrate concentration (probably 〈 40% of pore space) appear to be determined by stress-dependent soil stiffness and strength. At high hydrate concentrations (〉50% of pore space), the behavior becomes more independent of stress because the hydrates control both stiffness and strength and possibly the dilative tendency of sediments by effectively increasing interparticle coordination, cementing particles together, and filling the pore space. The cementation contribution to the shear strength of hydrate-bearing sediments decreases with increasing specific surface of soil minerals. The lower the effective confining stress, the greater the impact of hydrate formation on normalized strength.
    Beschreibung: This research was sponsored by a contract to C.R. and J.C.S. from the Joint Industry Project for Methane Hydrate, administered by ChevronTexaco with funding from award DE-FC26- 01NT41330 from DOE’s National Energy Technology Laboratory. The Goizueta Foundation at Georgia Tech also provided support for this work. The research was completed while C.R. was on assignment at and wholly supported by the National Science Foundation (NSF).
    Schlagwort(e): Gas hydrate ; Sediment strength ; Elasticity ; Mechanical behavior ; Stiffness
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  • 12
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    Parametric study of the physical properties of hydrate-bearing sand, silt, and clay sediments : 1. Electromagnetic properties (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): B11104, doi:10.1029/2009JB006669.
    Beschreibung: The marked decrease in bulk electrical conductivity of sediments in the presence of gas hydrates has been used to interpret borehole electrical resistivity logs and, to a lesser extent, the results of controlled source electromagnetic surveys to constrain the spatial distribution and predicted concentration of gas hydrate in natural settings. Until now, an exhaustive laboratory data set that could be used to assess the impact of gas hydrate on the electromagnetic properties of different soils (sand, silt, and clay) at different effective stress and with different saturations of hydrate has been lacking. The laboratory results reported here are obtained using a standard geotechnical cell and the hydrate-formed tetrahydrofuran (THF), a liquid that is fully miscible in water and able to produce closely controlled saturations of hydrate from dissolved phase. Both permittivity and electrical conductivity are good indicators of the volume fraction of free water in the sediment, which is in turn dependent on hydrate saturation. Permittivity in the microwave frequency range is particularly predictive of free water content since it is barely affected by ionic concentration, pore structure, and surface conduction. Electrical conductivity (or resistivity) is less reliable for constraining water content or hydrate saturation: In addition to fluid-filled porosity, other factors, such as the ionic concentration of the pore fluid and possibly other conduction effects (e.g., surface conduction in high specific surface soils having low conductivity pore fluid), also influence electrical conductivity.
    Beschreibung: This research was initially supported by the Chevron Joint Industry Project on Methane Hydrates under contract DE‐FC26‐01NT41330 from the U.S. Department of Energy. Additional support was provided to J.C.S. by the Goizueta Foundation at Georgia Tech, to J.Y.L. by KIGAM, and to C. Ruppel by the USGS.
    Schlagwort(e): Gas hydrate ; Electromagnetic properties ; Resistivity
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  • 13
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    Parametric study of the physical properties of hydrate-bearing sand, silt, and clay sediments : 2. Small-strain mechanical properties (2010)
    American Geophysical Union
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    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): B11105, doi:10.1029/2009JB006670.
    Beschreibung: The small-strain mechanical properties (e.g., seismic velocities) of hydrate-bearing sediments measured under laboratory conditions provide reference values for calibration of logging and seismic exploration results acquired in hydrate-bearing formations. Instrumented cells were designed for measuring the compressional (P) and shear (S) velocities of sand, silts, and clay with and without hydrate and subject to vertical effective stresses of 0.01 to 2 MPa. Tetrahydrofuran (THF), which is fully miscible in water, was used as the hydrate former to permit close control over the hydrate saturation Shyd and to produce hydrate from dissolved phase, as methane hydrate forms in most natural marine settings. The results demonstrate that laboratory hydrate formation technique controls the pattern of P and S velocity changes with increasing Shyd and that the small-strain properties of hydrate-bearing sediments are governed by effective stress, σ′v and sediment specific surface. The S velocity increases with hydrate saturation owing to an increase in skeletal shear stiffness, particularly when hydrate saturation exceeds Shyd≈ 0.4. At very high hydrate saturations, the small strain shear stiffness is determined by the presence of hydrates and becomes insensitive to changes in effective stress. The P velocity increases with hydrate saturation due to the increases in both the shear modulus of the skeleton and the bulk modulus of pore-filling phases during fluid-to-hydrate conversion. Small-strain Poisson's ratio varies from 0.5 in soft sediments lacking hydrates to 0.25 in stiff sediments (i.e., subject to high vertical effective stress or having high Shyd). At Shyd ≥ 0.5, hydrate hinders expansion and the loss of sediment stiffness during reduction of vertical effective stress, meaning that hydrate-rich natural sediments obtained through pressure coring should retain their in situ fabric for some time after core retrieval if the cores are maintained within the hydrate stability field.
    Beschreibung: Initial support for this research to J.C.S. and C.R. at Georgia Tech was provided by the Chevron Joint Industry Project on Methane Hydrates under contract DE‐FC26‐01NT41330 from the U.S. Department of Energy. Additional support to J.C.S. was provided by the Goizueta Foundation at Georgia Tech and to J.Y.L. by KIGAM, GHDO, and MKE.
    Schlagwort(e): Gas hydrate ; Mechanical properties ; Seismic velocity
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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