ALBERT

Description: 〈b〉Thermogeodynamic manifestations in the Caucasus and their genesis〈/b〉〈br〉 G. E. Gugunava, J. K. Kiria, and T. B. Bochorishvili〈br〉 eEarth Discuss., 4, 77-89, doi:10.5194/eed-4-77-2009, 2009〈br〉 〈b〉Publication in eE not foreseen〈/b〉 (discussion: closed, 2 comments)〈br〉 In the work two aspects of thermal character are considered: first of all this is the connection of subduction phenomena with thermal life of the Caucasus on the basis of over interpreted data of magnetotelluric sounding, and secondly, origin of thermostressed condition of the Caucasus and its geological aspects which is manifested in the following: 〈br〉〈br〉 1. in the zones of anomalous thermodisplacements thermofaults should occur (Le Pishon et al., 1977). These thermofaults are in good correlation with deep faults which are distinguished by geological and seismic methods, these thermofaults may be earthquake sources (Spitak, Racha, etc. earthquakes), also may be channels through which magma derivates (giving mineral deposits) may penetrate on surface (Gugunava and Gijeishvili, 1989); 〈br〉〈br〉 2. in the body of sedimentary complex thermostressed seals and seal failures occur, which are apparently traps for oil-gas fluids. Good correlation of thermodense anomalies with oil deposits of the Caucasus is shown (Alexidze et al., 1985; Gugunava, 1980). 〈br〉〈br〉 Everything above mentioned was carried out within frames of stationary thermal model which did not allow us to reveal time characteristics of interconnection of geological medium and thermal field. 〈br〉〈br〉 Now investigations are being carried out within the frames of stationary thermal model and its interconnection with geological environment.

Description: 〈b〉Holocene evolution and sedimentation rate of Alikes Lagoon, Zakynthos island, Western Greece: preliminary results〈/b〉〈br〉 P. Avramidis and N. Kontopoulos〈br〉 eEarth, 4, 23-29, doi:10.5194/ee-4-23-2009, 2009〈br〉 In the present study we present preliminary results from Alikes lagoon in Zakynthos island, an area that is one of the most seismically active regions of Greece. In order to estimate – interpret the Holocene evolution of the area and to reconstruct the palaeoenvironmental changes, we based on data derived from a 21 m sediment core. Sediment types, structure, colour, as well as contact depths and bed characteristics were recorded in the field. Standarised sedimentological analysis was carried out, on 46 samples including grain size analysis, calculation of moment measures, and micro- and molluscan fossils of 17 selected samples. Moreover, radiocarbon age determinations have been made on individual 〈i〉Cardium〈/i〉 shells from two horizons and whole – core Magnetic Susceptibility (MS) measurements were taken. The interpretation of depositional environments suggests a coastal environment (restricted-shallow) with reduced salinity such as a lagoon margin and in a tidal flat and/or marsh particularly. The maximum age of the studied sediments is about 8500 BP. The rate of sedimentation between 8280 BP while 5590 BP was 5.3 mm/yr and between 5590 BP and modern times is on the order of 1.03 mm/yr. These sedimentation rates results are similar to other coastal areas of western Greece.

Description: 〈b〉Morphology of the pore space in claystones – evidence from BIB/FIB ion beam sectioning and cryo-SEM observations〈/b〉〈br〉 G. Desbois, J. L. Urai, and P. A. Kukla〈br〉 eEarth, 4, 15-22, doi:10.5194/ee-4-15-2009, 2009〈br〉 The morphology of pore space has a strong effect on mechanical and transport properties of mudrocks and clay-rich fault gouge, but its characterization has been mostly indirect. We report on a study of Boom clay from a proposed disposal site of radioactive waste (Mol site, Belgium) using high resolution SEM at cryogenic temperature, with ion beam cross-sectioning to prepare smooth, damage free surfaces. Pores commonly have crack-like tips, preferred orientation parallel to bedding and power law size distribution. We define a number of pore types depending on shape and location in the microstructure: large jagged pores in strain shadows of clastic grains, high aspect ratio pores between similarly oriented phyllosilicate grains and crescent-shaped pores in saddle reefs of folded phyllosilicates. 3-D reconstruction by serial cross-sectioning shows 3-D connectivity of the pore space. These findings offer a new insight into the morphology of pores down to nano-scale in comparison to traditional pore size distributions calculated from mercury Injection experiments, explain slaking of clays by successive wetting and drying and provide the basis for microstructure-based models of transport in clays.

Description: 〈b〉Syn- and post-orogenic exhumation of metamorphic rocks in North Aegean〈/b〉〈br〉 R. Lacassin, N. Arnaud, P. H. Leloup, R. Armijo, and B. Meyer〈br〉 eEarth, 2, 51-63, doi:10.5194/ee-2-51-2007, 2007〈br〉 The Olympos-Ossa-Pelion (OOP) ranges, in NW Aegean, encompass Greece highest summit and are located near the extremity of the North Anatolian Fault (NAF). Structural and thermochronological data gathered in the OOP ranges show that the main exhumation of metamorphic nappes occurred in the Eocene, at ca. 43–39 Ma. This early exhumation, associated with ductile, then brittle-ductile normal faulting with northeastward transport, is coeval with orogenic shortening in the close area. Cooling rates, and likely exhumation, have been low between ~40 Ma and ~20 Ma. 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar crystallization ages (between 20 and 15 Ma) appears related to brittle-ductile normal faulting and likely associated with Neogene Aegean back-arc extension. The dating of a diabase dyke, and the geometry of associated brittle jointing, of onshore and offshore active normal faults suggest a shift in extension direction after 4Ma, possibly in relation with the propagation of the NAF in northern Aegean.

Description: 〈b〉Impact vesiculation – a new trigger for volcanic bubble growth and degassing〈/b〉〈br〉 D. A. Rothery, J. M. Sumner, O. Spieler, and D. B. Dingwell〈br〉 eEarth Discuss., 2, 151-167, doi:10.5194/eed-2-151-2007, 2007〈br〉 〈b〉Revised manuscript has not been submitted〈/b〉 (discussion: closed, 3 comments)〈br〉 We highlight a potentially important trigger for bubble growth and degassing in volcanic bombs. We have successfully triggered bubble growth in previously unvesiculated samples of silicate melt during experiments to simulate volcanic bomb impact, by firing pellets at, and dropping weights onto, melt samples. We call this phenomenon "impact vesiculation". Further work is required on real volcanic bombs to establish the extent to which impact vesiculation occurs in nature. However, our experiments are sufficient to demonstrate that impact vesiculation is a viable processes and should be borne in mind in analysis of bubble populations and degassing histories of bombs and spatter-fed lava flows. Degassing caused by impact vesiculation can occur only at ground-level, so any attempt to calculate the amount of erupted gas available for transport high into the atmosphere by convection above the source of a fountain-fed lava flow that is based on subtracting the volatile content of fluid inclusions from the volatile content of the resulting lava flow would be an overestimate if significant impact vesiculation has occurred.

Description: 〈b〉Late Pleistocene palaeoproductivity patterns during the last climatic cycle in the Guyana Basin as revealed by calcareous nannoplankton〈/b〉〈br〉 G.-E. López-Otálvaro, J. A. Flores, F. J. Sierro, I. Cacho, J.-O. Grimalt, E. Michel, E. Cortijo, and L. Labeyrie〈br〉 eEarth, 4, 1-13, doi:10.5194/ee-4-1-2009, 2009〈br〉 Variations in the assemblage and abundance of coccoliths reveal changes in oceanic and atmospheric dynamics in the Guyana Basin over the last climatic cycle, mainly linked to latitudinal variations in the ITCZ (Intertropical Convergence Zone). Records of the N ratio (a palaeoproductivity index of coccolithophores) allowed us to monitor nutri-thermocline fluctuations. Nannofossil accumulation rates (NAR) vary closely with the N ratio, indicating a strong correlation between these two palaeoproductivity proxies. Decreases in the N ratio and NAR values suggest lower palaeoproductivity during glacial substages, indicating a deep nutri-thermocline (deep stratification of the mixed layer) as a consequence of the piling up of warm water dragged by the NEC. This setting was favoured by the southern shift of the ITCZ and Trade winds which blew perpendicular to the Guyana coast. By contrast, increases in the N ratio and NAR values revealed higher palaeoproductivity during interglacial substages, suggesting a shoaling of the nutri-thermocline. This scenario is favoured by a northward displacement of the ITCZ with the southeast Trade winds blowing alongshore. Additionally, palaeoproductivity changes during substages of Marine Isotope Stage (MIS) 6-5 are of much higher amplitude than those recorded in substages of MIS 4-2 and the early Holocene. Similarities between the palaeoproductivity and the 65° N summer insolation records, suggest a link between the depth of nutri-thermocline, the latitudinal migration of the ITCZ and ice-sheet changes in the Northern Hemisphere.

Description: The strontium isotope composition of seawater is strongly influenced on geological time scales by changes in the rates of continental weathering relative to ocean crust alteration. However, the potential of the seawater 87Sr/86Sr curve to trace globally integrated chemical weathering rates has not been fully realised because ocean 87Sr/86Sr is also influenced by the isotopic evolution of Sr sources to the ocean. A preliminary attempt is made here to normalise the seawater 87Sr/86Sr curve to plausible trends in the 87Sr/86Sr ratios of the three major Sr sources: carbonate dissolution, silicate weathering and submarine hydrothermal exchange. The normalised curve highlights the Neoproterozoic-Phanerozoic transition as a period of exceptionally high continental influence, indicating that this interval was characterised by a transient increase in global weathering rates and/or by the weathering of unusually radiogenic crustal rocks. Close correlation between the normalised 87Sr/86Sr curve, a published seawater δ34S curve and atmospheric pCO2 models is used here to argue that elevated chemical weathering rates were a major contributing factor to the steep rise in seawater 87Sr/86Sr from 650 Ma to 500 Ma. Elevated weathering rates during the Neoproterozoic-Cambrian interval led to increased nutrient availability, organic burial and to the further oxygenation of Earth's surface environment. Use of normalised seawater 87Sr/86Sr curves will, it is hoped, help to improve future geochemical models of Earth System dynamics.

Description: To study the effect of stress-activated positive hole (p-hole) charge carriers on the infrared (IR) emission from rocks, we subjected a portion (~10 vol.%) of a large (30×60×7.5 cm3) block of anorthosite, a nearly monomineralic (Ca-rich feldspar) igneous rock, to uniaxial deviatory stress up to failure. We measured the IR emission from a flat surface ≈40 cm from the stressed rock volume over the 800–1300 cm−1 (7.7–12.5 μm) range. Instantly, upon loading, the emission spectrum and intensity change. At first narrow bands appear at 930 cm−1 (10.75 μm), 880 cm−1 (11.36 μm), 820 cm−1 (12.4 μm) plus additional narrow bands in the 1000–1300 cm−1 (7.7–10.0 μm) range. The 10.75–12.4 μm bands are thought to arise from vibrationally excited O-O stretching modes, which form when p-hole charge carriers, which spread from the stressed rock volume into the unstressed rock, recombine at the surface. They radiatively decay, giving rise to "hot" bands due to transitions between excited states. Before failure the broad emission bands at 1170 cm−1 and 1030 cm−1 (8.7 and 9.7 μm) also increase slightly in intensity, suggesting a small increase in temperature due to thermalization of the energy deposited into the surface through p-hole recombination. Stimulated IR emission due to hole-hole recombination and its follow-on effects may help understand the enhanced IR emission seen in night-time satellite images of the land surface before major earthquakes known as "thermal anomalies".

Description: In the present study we present preliminary results from Alikes lagoon in Zakynthos island, an area that is one of the most seismically active regions of Greece. In order to estimate – interpret the Holocene evolution of the area and to reconstruct the palaeoenvironmental changes, we based on data derived from a 21 m sediment core. Sediment types, structure, colour, as well as contact depths and bed characteristics were recorded in the field. Standarised sedimentological analysis was carried out, on 46 samples including grain size analysis, calculation of moment measures, and micro- and molluscan fossils of 17 selected samples. Moreover, radiocarbon age determinations have been made on individual Cardium shells from two horizons and whole – core Magnetic Susceptibility (MS) measurements were taken. The interpretation of depositional environments suggests a coastal environment (restricted-shallow) with reduced salinity such as a lagoon margin and in a tidal flat and/or marsh particularly. The maximum age of the studied sediments is about 8500 BP. The rate of sedimentation between 8280 BP while 5590 BP was 5.3 mm/yr and between 5590 BP and modern times is on the order of 1.03 mm/yr. These sedimentation rates results are similar to other coastal areas of western Greece.

Description: Variations in the assemblage and abundance of coccoliths reveal changes in oceanic and atmospheric dynamics in the Guyana Basin over the last climatic cycle, mainly linked to latitudinal variations in the ITCZ (Intertropical Convergence Zone). Records of the N ratio (a palaeoproductivity index of coccolithophores) allowed us to monitor nutri-thermocline fluctuations. Nannofossil accumulation rates (NAR) vary closely with the N ratio, indicating a strong correlation between these two palaeoproductivity proxies. Decreases in the N ratio and NAR values suggest lower palaeoproductivity during glacial substages, indicating a deep nutri-thermocline (deep stratification of the mixed layer) as a consequence of the piling up of warm water dragged by the NEC. This setting was favoured by the southern shift of the ITCZ and Trade winds which blew perpendicular to the Guyana coast. By contrast, increases in the N ratio and NAR values revealed higher palaeoproductivity during interglacial substages, suggesting a shoaling of the nutri-thermocline. This scenario is favoured by a northward displacement of the ITCZ with the southeast Trade winds blowing alongshore. Additionally, palaeoproductivity changes during substages of Marine Isotope Stage (MIS) 6-5 are of much higher amplitude than those recorded in substages of MIS 4-2 and the early Holocene. Similarities between the palaeoproductivity and the 65° N summer insolation records, suggest a link between the depth of nutri-thermocline, the latitudinal migration of the ITCZ and ice-sheet changes in the Northern Hemisphere.

Description: The morphology of pore space has a strong effect on mechanical and transport properties of mudrocks and clay-rich fault gouge, but its characterization has been mostly indirect. We report on a study of Boom clay from a proposed disposal site of radioactive waste (Mol site, Belgium) using high resolution SEM at cryogenic temperature, with ion beam cross-sectioning to prepare smooth, damage free surfaces. Pores commonly have crack-like tips, preferred orientation parallel to bedding and power law size distribution. We define a number of pore types depending on shape and location in the microstructure: large jagged pores in strain shadows of clastic grains, high aspect ratio pores between similarly oriented phyllosilicate grains and crescent-shaped pores in saddle reefs of folded phyllosilicates. 3-D reconstruction by serial cross-sectioning shows 3-D connectivity of the pore space. These findings offer a new insight into the morphology of pores down to nano-scale in comparison to traditional pore size distributions calculated from mercury Injection experiments, explain slaking of clays by successive wetting and drying and provide the basis for microstructure-based models of transport in clays.

Description: Nine ERS-1 and ERS-2 descending orbit data acquired over Aira Caldera between June 1995 and November 1998 were used to create 36 differential interferograms. Although the interferograms exhibit a relatively low level of coherence, even for couples sampling short time intervals (6 months), Synthetique Aperture Radar (SAR) observations reveal a distinct range change pattern over Kokubu urban area whose amplitude increases with the time separation between SAR images. The analysis of the ground deformation time series relative to the earliest ERS images showed a maximum uplift of about 20 mm between the north and the south of the urban area during the period covered by our satellite observations. Taking the reduced surface of the coherent area into account, we performed a simple modeling of the deformation field assuming an inflating spherical source within an elastic half-space medium located beneath the centre of the Aira Caldera. This simple model predicts a maximum volume increase of 20–30×106 m3 between 1995 and 1998, which would produce an inflation of about 70 mm at the centre of the Aira Caldera and 40 mm in the Kokubu south urban area. These results are in good agreement with other geophysical observations carried out on the Aira caldera during this period. Despite the limited spatial extent of the coherent areas around the Aira Caldera, this study shows that DinSAR method using data collected in C band can be successfully used to detect subtle ground displacement changes of the volcanic complex and thus provides complementary information to ground-based geodetic monitoring of dynamic processes of the Aira Caldera and Sakurajima volcano.

Description: We report gravel of the River Euphrates, capped by basalt that is Ar-Ar dated to ~9 Ma, at Shireen in northern Syria. This gravel, preserved by the erosion-resistant basalt, allows us for the first time to reconstruct the history of this major river during the Late Miocene. In response to progressive regional surface uplift, the Euphrates extended SE by ~800 km between the early Middle Miocene, when the coast was near Kahramanmaraş in southern Turkey, and the Pliocene, when it lay in western Iraq, east of the Arabian Platform uplands.

Description: We have performed fall-experiments with basaltic andesite rock samples from Merapi volcano, using an apparatus designed to analyze samples heated up to 850°C. Relative pressure changes during impact and fragmentation of the samples were measured by a pressure transducer. From 200°C, dynamic pressure waves were formed on impact and fragmentation. Peak and duration of the pressure signal, and degree of fragmentation were found to strongly increase with increasing temperature of rock samples. The pressure waves are most likely generated by sudden heating of air forcing it to expand. We propose that the observed pressure changes are analogues to pyroclastic surges that may be generated on impact and fragmentation of large blocks during passage of a pyroclastic flow over a steep cliff. We infer that rock temperatures of ca. 400°C are sufficient for this process to occur, a temperature common in pyroclastic flows even in distal reaches.

Description: The Lunar cratering record is consistent with the occurrence of a late heavy bombardment (LHB), which marked the end of terrestrial planet accretion 3.8 billion years ago. However, clear evidence of a LHB on Earth has not yet been identified. Based on a volatile budget of the terrestrial mantle, the atmosphere and hydrosphere we propose that the LHB did indeed occur on Earth and that we are breathing its aftermaths. The terrestrial atmosphere and hydrosphere is enriched in noble gases relative to the abundance of volatiles in the mantle. This enrichment is consistent with the mass delivered to Earth during the LHB, as recently proposed from dynamical modelling (Gomez et al., 2005), if this material comprised a few Kuiper-belt (cometary) objets (KBOs) mixed in with a population of largely chondritic (i.e. asteroidal) impactors. The fraction of KBOs necessary to account for the atmospheric composition is, however, much lower (〈1%) than the one (~50%) inferred from modelling.

Description: The Olympos-Ossa-Pelion (OOP) ranges, in NW Aegean, encompass Greece highest summit and are located near the extremity of the North Anatolian Fault (NAF). Structural and thermochronological data gathered in the OOP ranges show that the main exhumation of metamorphic nappes occurred in the Eocene, at ca. 43–39 Ma. This early exhumation, associated with ductile, then brittle-ductile normal faulting with northeastward transport, is coeval with orogenic shortening in the close area. Cooling rates, and likely exhumation, have been low between ~40 Ma and ~20 Ma. 40Ar/39Ar crystallization ages (between 20 and 15 Ma) appears related to brittle-ductile normal faulting and likely associated with Neogene Aegean back-arc extension. The dating of a diabase dyke, and the geometry of associated brittle jointing, of onshore and offshore active normal faults suggest a shift in extension direction after 4Ma, possibly in relation with the propagation of the NAF in northern Aegean.