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  • 1
    Publication Date: 2014-01-03
    Print ISSN: 0895-0695
    Electronic ISSN: 1938-2057
    Topics: Geosciences
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  • 2
    Publication Date: 2012-04-01
    Print ISSN: 1478-3967
    Electronic ISSN: 1478-3975
    Topics: Biology , Physics
    Published by Institute of Physics
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  • 3
    Publication Date: 2014-01-01
    Print ISSN: 0895-0695
    Electronic ISSN: 1938-2057
    Topics: Geosciences
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  • 4
    Publication Date: 2007-09-13
    Description: Earthquakes are feared because they often strike so suddenly. Yet, there are innumerable reports of pre-earthquake signals. Widespread disagreement exists in the geoscience community how these signals can be generated in the Earth's crust and whether they are early warning signs, related to the build-up of tectonic stresses before major seismic events. Progress in understanding and eventually using these signals has been slow because the underlying physical process or processes are basically not understood. This has changed with the discovery that, when igneous or high-grade metamorphic rocks are subjected to deviatoric stress, dormant electronic charge carriers are activated: electrons and defect electrons. The activation increases the number density of mobile charge carriers in the rocks and, hence, their electric conductivity. The defect electrons are associated with the oxygen anion sublattice and are known as positive holes or pholes for short. The boundary between stressed and unstressed rock acts a potential barrier that lets pholes pass but blocks electrons. Therefore, like electrons and ions in an electrochemical battery, the stress-activated electrons and pholes in the "rock battery" have to flow out in different directions. When the circuit is closed, the battery currents can flow. The discovery of such stress-activated currents in crustal rocks has far-reaching implications for understanding pre-earthquake signals.
    Print ISSN: 1561-8633
    Electronic ISSN: 1684-9981
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 5
    Publication Date: 2007-09-13
    Description: When rocks are subjected to stress, dormant electronic charge carriers are activated. They turn the stressed rock volume into a battery, from where currents can flow out. The charge carriers are electrons and defect electrons, also known as positive holes or pholes for short. The boundary between stressed and unstressed rock acts as a potential barrier that lets pholes pass but blocks electrons. One can distinguish two situations in the Earth's crust: (i) only pholes spread out of a stressed rock volume into the surrounding unstressed rocks. This is expected to lead to a positive surface charge over a wide area around the future epicenter, to perturbations in the ionosphere, to stimulated infrared emission from the ground, to ionization of the near-ground air, to cloud formation and to other phenomena that have been reported to precede major earthquakes. (ii) both pholes and electrons flow out of the stressed rock volume along different paths, sideward into the relatively cool upper layers of the crust and downward into the hot lower crust. This situation, which is likely to be realized late in the earthquake preparation process, is necessary for the battery circuit to close and for transient electric currents to flow. If burst-like, these currents should lead to the emission of low frequency electromagnetic radiation. Understanding how electronic charge carriers are stress-activated in rocks, how they spread or flow probably holds the key to deciphering a wide range of pre-earthquake signals. It opens the door to a global earthquake early warning system, provided resources are pooled through a concerted and constructive community effort, including seismologists, with international participation.
    Print ISSN: 1561-8633
    Electronic ISSN: 1684-9981
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 2006-07-24
    Description: To study the effect of stress-activated positive hole (p-hole) charge carriers on the infrared (IR) emission from rocks, we subjected a portion (~10 vol.%) of a large (60×30×7.5 cm3) block of anorthosite, a nearly monomineralic (Ca-rich feldspar) igneous rock, to uniaxial deviatory stress up to failure. We measured the IR emission from a flat surface ≈40 cm from the stressed rock volume over the 800–1300 cm−1 (7.7–12.5 μm) range. Upon loading, the intensity and spectrum of the IR emission change. Narrow bands near instantly appear at 930 cm−1 (10.75 μm), 880 cm−1 (11.36 μm), 820 cm−1 (12.4 μm) plus additional bands in the 1000–1300 cm−1 (10.0–7.7 μm) range. Upon further loading the bands broaden and shift. Their intensities increase but also fluctuate. Near the emission maxima at 300 K, at 1150 cm−1 and 1030 cm−1 (8.7 and 9 μm), barely any intensity increase occurs suggesting that the temperature of the surface does not actually increase. We propose that the observed narrow IR emission bands arise from vibrationally excited O-O stretching modes which form when p-hole charge carriers (activated in the stressed rock) spread into the unstressed portion of the rock to the surface, where they recombine and radiatively decay. The effect, stimulated IR emission due to hole-hole recombination, may help explain the enhanced IR emission seen in night-time satellite images of the land surface before major earthquakes known as "thermal anomalies''.
    Print ISSN: 1815-3836
    Electronic ISSN: 1815-3844
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2007-01-10
    Description: To study the effect of stress-activated positive hole (p-hole) charge carriers on the infrared (IR) emission from rocks, we subjected a portion (~10 vol.%) of a large (30×60×7.5 cm3) block of anorthosite, a nearly monomineralic (Ca-rich feldspar) igneous rock, to uniaxial deviatory stress up to failure. We measured the IR emission from a flat surface ≈40 cm from the stressed rock volume over the 800–1300 cm−1 (7.7–12.5 μm) range. Instantly, upon loading, the emission spectrum and intensity change. At first narrow bands appear at 930 cm−1 (10.75 μm), 880 cm−1 (11.36 μm), 820 cm−1 (12.4 μm) plus additional narrow bands in the 1000–1300 cm−1 (7.7–10.0 μm) range. The 10.75–12.4 μm bands are thought to arise from vibrationally excited O-O stretching modes, which form when p-hole charge carriers, which spread from the stressed rock volume into the unstressed rock, recombine at the surface. They radiatively decay, giving rise to "hot" bands due to transitions between excited states. Before failure the broad emission bands at 1170 cm−1 and 1030 cm−1 (8.7 and 9.7 μm) also increase slightly in intensity, suggesting a small increase in temperature due to thermalization of the energy deposited into the surface through p-hole recombination. Stimulated IR emission due to hole-hole recombination and its follow-on effects may help understand the enhanced IR emission seen in night-time satellite images of the land surface before major earthquakes known as "thermal anomalies".
    Print ISSN: 1815-381X
    Electronic ISSN: 1815-3828
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2018-06-06
    Description: We measured the infrared (IR) nu(sub CH) absorption bands around 3.4 microns (2800 - 3000 cm(sup -1) in large laboratory-grown magnesium oxide (MgO) and natural olivine single crystals that crystallized from CO/CO2/H2O saturated melts. These bands are very similar to those from many astronomical sources, such as from dust in the diffuse interstellar medium (ISM), from the outflow of evolved stars, etc., and they are characteristic of aliphatic -CH2- and -CH3 entities. In our laboratory single crystals the VCH bands arise from C-H entities that were introduced by a solid solution process, and that are imbedded in the mineral matrix in form of polyatomic C(sub n) entities with C atoms bonded to O and to H. Heating breaks the C-H bonds, causing hydrogen to disperse in the mineral matrix. C-H bonds are re-established rapidly during annealing. We propose that dust grains probably contain the same type of internal C(sub n)-H entities in solid matrix rather than an external organic layer covering the grain surfaces. Thermodynamical arguments show that the concentration of organics in solid solution in small grains can be comparable to that found in astronomical environments.
    Keywords: Astrophysics
    Type: Proceedings of the NASA Laboratory Astrophysics Workshop; 204-207; NASA/CP-2002-211863
    Format: application/pdf
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  • 9
    Publication Date: 2018-06-06
    Description: The reported infrared (IR) emission spectra from 1999 Leonid fireballs show a 3.4 micron C-H emission band and unidentified bands at longer wavelengths. Upon atmospheric entry, the Leonid meteorites were flash-heated to temperatures around 2400K, which would destroy any organics on the surface of the meteorite grains. We propose that the nu(sub )CH emission band in the Leonid emission spectra arises from matrix-embedded C(sub n)-H-O entities that are protected from instant pyrolysis. Our model is based on IR absorption nu(sub )CH bands, which we observed in laboratory-grown MgO and natural olivine single crystals, where they arise from C(sub n)-H-O units imbedded in the mineral matrix, indicative of aliphatic -CH2- and -CH3 organics. Instead of being pyrolyzed, the C(sub n)-H-O entities in the Leonid trails become vibrationally excited to higher levels n = 1, 2, 3 etc. During de-excitation they emit at 3.4 microns, due to the (0 =〉 1) transition, and at longer wavelengths, due to hot bands. As a first step toward verifying this hypothesis we measured the C-H vibrational manifold of hexane (C6H14). The calculated positions of the (2 =〉 l ) , (3 =〉 2), and possibly (4 =〉 3) hot bands agree with the Leonid emission bands at 3.5, 3.8 and 4.l microns.
    Keywords: Astronomy
    Type: Proceedings of the NASA Laboratory Astrophysics Workshop; 245-248; NASA/CP-2002-211863
    Format: application/pdf
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