Publikationsdatum:
2020
Beschreibung:
〈p〉Publication date: 1 March 2020〈/p〉
〈p〉〈b〉Source:〈/b〉 Solar Energy, Volume 198〈/p〉
〈p〉Author(s): Xiaojuan Liu, Pan Ding, Zhihua Yuan, Hui Tian, Youzhou Jiao, Samira Agbolaghi〈/p〉
〈div xml:lang="en"〉
〈h5〉Abstract〈/h5〉
〈div〉〈p〉Morphological, electrochemical, and photovoltaic stabilities of the poly[benzodithiophene-bis(decyltetradecyl-thien) naphthothiadiazole] (PBDT-DTNT):phenyl-C61-butyric acid methyl ester (PC71BM) solar cells were promoted by the pre-designed supramolecules on the basis of reduced graphene oxide (rGO) nanosheets. Nanostructures consisted of the pristine rGO, grafted-rGO/PBDT-DTNT, rGO-polythiophene (GPTh) electrospun nanofiber, grafted-rGO/PBDT-DTNT electrospun nanofiber and rGO/PBDT-DTNT samples. The reduction in photovoltaic characteristics during air aging was the steepest for the unmodified PBDT-DTNT:PC71BM solar cells. From rGO based photovoltaics towards the rGO/PBDT-DTNT modified ones possessing the well-patterned PBDT-DTNT nanofibers, the slopes of graphs decreased. The most stabilized devices were fabricated on the basis of PBDT-DTNT:PC71BM:rGO/PBDT-DTNT active layers (power conversion efficiency (PCE) from 6.09% for upon-fabricated to 4.87% for 1 month aged systems) for having the most red-shifted and intensified absorbance, the largest phase separation, the lowest impedance responses and the highest photovoltaic characteristics during 1 month air aging (short circuit current density (J〈sub〉sc〈/sub〉) of 12.09 mA/cm〈sup〉2〈/sup〉, fill factor (FF) of 63%, open circuit voltage (V〈sub〉oc〈/sub〉) of 0.64 V, hole mobility (µ〈sub〉h〈/sub〉) of 5.3 × 10〈sup〉–5〈/sup〉 cm〈sup〉2〈/sup〉/V s, electron mobility (µ〈sub〉e〈/sub〉) of 7.9 × 10〈sup〉–4〈/sup〉 cm〈sup〉2〈/sup〉/V s, charge transfer resistance (R〈sub〉tr〈/sub〉) of 431 Ω cm〈sup〉2〈/sup〉 and PCE of 4.87%). The GPTh/PBDT-DTNT/PC71BM (J〈sub〉sc〈/sub〉 = 10.31 mA/cm〈sup〉2〈/sup〉, FF = 49%, V〈sub〉oc〈/sub〉 = 0.55 V, R〈sub〉tr〈/sub〉 = 796 Ω cm〈sup〉2〈/sup〉 and PCE = 2.78%) and grafted-rGO/PBDT-DTNT/PBDT-DTNT (J〈sub〉sc〈/sub〉 = 10.98 mA/cm〈sup〉2〈/sup〉, FF = 56%, V〈sub〉oc〈/sub〉 = 0.60 V, R〈sub〉tr〈/sub〉 = 539 Ω cm〈sup〉2〈/sup〉 and PCE = 3.69%) electrospun nanofibers also imparted the stabilization of devices within 1 month.〈/p〉〈/div〉
〈/div〉
〈div xml:lang="en"〉
〈h5〉Graphical abstract〈/h5〉
〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0038092X20300396-ga1.jpg" width="286" alt="Graphical abstract for this article" title=""〉〈/figure〉〈/p〉〈/div〉
〈/div〉
Print ISSN:
0038-092X
Digitale ISSN:
1471-1257
Thema:
Energietechnik
,
Physik
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