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  • 1
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    Univ.-Verl. Göttingen, Göttingen
    Publication Date: 2021-03-29
    Description: Rock fractures play a major role in many geological processes, such as plate tectonics, earthquakes, volcanic eruptions and fluid transport in the earthś crust. The present volume contains the abstracts of all presentations of the symposium Rock Fractures in Geological Processes, held on 26-27 November 2013 in London honouring the 60th birthday of Ágúst Guðmundsson, chair in Structural Geology, Royal Holloway University of London, a leading expert in the field and author of a well known text book of the same title. The symposium covered all topics related to fractures in the earthś crust, e.g., crustal stresses, rock mechanical properties, field analysis of fractures - from joints and faults to mineral veins and dykes - , analytical, analogue and numerical models of fractures and related fluid transport, as well as the activity of faults and volcanoes including calderas, and economic aspects such as exploration and exploitation of hydrocarbons and geothermal energy.
    Description: research
    Description: conference
    Keywords: 551 ; Festschriften {Geologische Wissenschaften} ; Festschriften {Geophysik} ; Strukturelle Erscheinungen {Strukturgeologie} ; Übertragungsmedien {Seismologie} ; Gesteinsdeformation {Strukturgeologie} ; Bruch ; Klüftung
    Language: English
    Type: anthology , publishedVersion
    Format: PDF-Datei: 73 S., ca. 4 MB
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  • 2
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    Universitätsverlag Göttingen, Göttingen
    Publication Date: 2021-03-29
    Description: Dieser Band enthält Beiträge zur Geologie des Harzes und seines Umfeldes, die anlässlich des 5. Workshops Harzgeologie am Geowissenschaftlichen Zentrum der Georg-August-Universität Göttingen vorgestellt wurden. Der Band umfasst die Kurzfassungen der Vorträge und Poster und den Exkursionsführer zu dieser zweitägigen Veranstaltung.
    Description: conference
    Description: excursionguide
    Keywords: 554.3 ; 551 ; Harz und seine Vorländer {Geologie} ; Kongress ; Geologie ; Geologie ; Exkursion ; Führer
    Language: English
    Type: anthology , publishedVersion
    Format: 117 Seiten
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  • 3
    Publication Date: 2019-07-24
    Description: The Global Stocktake (GST) takes a central role within the architecture of the Paris Agreement, with many hoping that it will become a catalyst for increased mitigation ambition. This paper outlines four governance functions for an ideal GST: pacemaker, ensurer of accountability, driver of ambition and provider of guidance and signal. The GST can set the pace of progress by stimulating and synchronizing policy processes across governance levels. It can ensure accountability of Parties through transparency and public information sharing. Ambition can be enhanced through benchmarks for action and transformative learning. By reiterating and refining the long term visions, it can echo and amplify the guidance and signal provided by the Paris Agreement. The paper further outlines preconditions for the effective performance of these functions. Process-related conditions include: a public appraisal of inputs; a facilitative format that can develop specific recommendations; high-level endorsement to amplify the message and effectively inform national climate policy agendas; and an appropriate schedule, especially with respect to the transparency framework. Underlying information provided by Parties complemented with other (scientific) sources needs to enable benchmark setting for collective climate action, to allow for transparent assessments of the state of emissions and progress of a low-carbon transformation. The information also needs to be politically relevant and concrete enough to trigger enhancement of ambition. We conclude that meeting these conditions would enable an ideal GST and maximize its catalytic effect.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 4
    Publication Date: 2019-11-06
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 5
    Publication Date: 2019-07-12
    Description: Sustainable Development Goals and the Paris Agreement stand as milestone diplomatic achievements. However, immense discrepancies between political commitments and governmental action remain. Combined national climate commitments fall far short of the Paris Agreement's 1.5/2°C targets. Similar political ambition gaps persist across various areas of sustainable development. Many therefore argue that actions by nonstate actors, such as businesses and investors, cities and regions, and nongovernmental organizations (NGOs), are crucial. These voices have resonated across the United Nations (UN) system, leading to growing recognition, promotion, and mobilization of such actions in ever greater numbers. This article investigates optimistic arguments about nonstate engagement, namely: (a) "the more the better"; (b) "everybody wins"; (c) "everyone does their part"; and (d) "more brings more." However, these optimistic arguments may not be matched in practice due to governance risks. The current emphasis on quantifiable impacts may lead to the under-appreciation of variegated social, economic, and environmental impacts. Claims that everybody stands to benefit may easily be contradicted by outcomes that are not in line with priorities and needs in developing countries. Despite the seeming depoliticization of the role of nonstate actors in implementation, actions may still lead to politically contentious outcomes. Finally, nonstate climate and sustainability actions may not be self-reinforcing but may heavily depend on supporting mechanisms. The article concludes with governance risk-reduction strategies that can be combined to maximize nonstate potential in sustainable and climate-resilient transformations.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 6
    Publication Date: 2019-05-17
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 7
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2021-04-06
    Description: On 26 January 2019, the Commission on Growth, Structural Change and Employment recommended that no more coal-fired power plants would be operated in Germany by 2038 at the latest. In this paper the Wuppertal Institute comments on the results of the Commission and makes recommendations for the current necessary steps for the climate and innovation policy in Europe, Germany and North Rhine-Westphalia.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: workingpaper , doc-type:workingPaper
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  • 8
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2020-01-27
    Description: Digitalisation is in full swing and it is changing and influencing the world of the 21st century as no other dynamics of change has done before. Dealing with its impacts and at the same time shaping digitalisation itself is therefore a core task for achieving a globally sustainable transformation (German Advisory Council on Global Change - WGBU, 2019). But which direction should digitalisation take to ensure that it makes e ective contributions to globally sustainable development? And what is the specific approach needed to steer digitalisation in the right direction?
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 9
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    Wuppertal : Wuppertal Institute for Climate, Environment and Energy
    Publication Date: 2021-04-20
    Description: The new mechanism under Article 6.4 of the Paris Agreement is to be supervised by a body designated by the Conference of the Parties serving as the Meeting of the Parties to the Paris Agreement (CMA). However, so far there is no clarity what role exactly the supervisory body (Body) is to play. Against this background, this JIKO Policy Paper analyses different governance options for Art. 6.4. The paper first reflects the objectives of the new mechanism and on what the role of the mechanism as a whole should be. The paper then summarises what has already been agreed on the functioning of the mechanism and elaborates what steps will be needed to generate transferrable emission reductions under the Article 6.4 mechanism. On this basis, the paper develops criteria for how to decide what role the Body should have, and then discusses what role the Body and the other actors that are involved in the mechanism could have in each of the steps of the activity cycle.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 10
    Publication Date: 2021-08-06
    Description: Before linking emissions trading systems, there should be a good understanding of the expected economic implications: How could linking affect the development of the common allowance price, the development of emissions or industrial production, capital flows or liquidity? Answering these questions requires a multitude of data and assumptions and therefore usually the use of economic models. This report gives an overview of various economic models that are suitable for assessing the economic effects of linking. It analyses the economic indicators relevant for the assessment of the effects of linking, formulates requirements for economic models to answer this question, discusses the advantages and disadvantages of different modelling approaches and gives an assessment of which models are suitable in principle for the assessment of linking. Five models were selected for a more detailed description: E3ME, GEM-E3, PACE, POLES, and TIMES-MARKAL.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 11
    Publication Date: 2021-08-06
    Description: The implementation of energy efficiency improvement actions not only yields energy and greenhouse gas emission savings, but also leads to other multiple impacts such as air pollution reductions and subsequent health and eco-system effects, resource impacts, economic effects on labour markets, aggregate demand and energy prices or on energy security. While many of these impacts have been studied in previous research, this work quantifies them in one consistent framework based on a common underlying bottom-up funded energy efficiency scenario across the EU. These scenario data are used to quantify multiple impacts by energy efficiency improvement action and for all EU28 member states using existing approaches and partially further developing methodologies. Where possible, impacts are integrated into cost-benefit analyses. We find that with a conservative estimate, multiple impacts sum up to a size of at least 50% of energy cost savings, with substantial impacts coming from e.g., air pollution, energy poverty reduction and economic impacts.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 12
    Publication Date: 2019-05-17
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 13
    Publication Date: 2021-04-20
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 14
    Publication Date: 2021-05-18
    Description: The need for sustainable energy management at the municipal level is growing, in order to meet EU climate goals. Multiple initiatives have been launched to support municipalities in energy planning and strategy development process. Despite available support, research shows mixed results about implementation of plans and strategies. This research paper analyses what targets municipalities set, how they monitor implementation of their sustainable energy action plans (SEAPs) and searches for the most important factors that have enabled or hindered the implementation of local SEAPs at Latvia. The article shows that, in some cases, there is evidence that SEAP development is a project-based activity, supported by external experts. From municipal personnel point of view, it is a project that ends with approved SEAP, but not a part of their future daily routine. Eventually implementation of the plan is difficult, because municipalities lack experience in daily management of energy data, distribution of responsibilities and implementation of procedures. Municipalities also tend to exclude important stakeholders in their SEAPs, like, private sector, household sector and transport sector, which lead to lower targets and lower achievements in GHG reduction.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 15
    Publication Date: 2021-04-20
    Description: With the adoption of Article 6 of the Paris Agreement, former debates about generating carbon credits on the basis of national policies have resurged. National policies have not been eligible as project activities under the Kyoto Protocol's flexible mechanisms. The Paris Agreement opens the possibility for such policy crediting but also provides an entirely new context: Universal participation, ambitious long-term targets and nationally defined contributions (NDCs) that are to be made more ambitious over time. As this paper shows, these changes in the framework conditions add an additional layer of complexity to policy-based cooperation. The paper explores the potential for policy-based cooperation by first briefly presenting the regulatory basis provided by the Paris Agreement before outlining a prototype for policy-based cooperation and its key challenges.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 16
    Publication Date: 2021-04-20
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 17
    Publication Date: 2021-04-20
    Description: The Paris Agreement requires mitigation contributions from all Parties. Therefore, the determination of additionality of activities under the market mechanisms of its Article 6 will need to be revisited. This paper provides recommendations on how to operationalize additionality under Article 6. We first review generic definitions of additionality and current approaches for testing of additionality before discussing under which conditions additionality testing of specific activities or policies is still necessary under the new context of the Paris Agreement, that is, in order to prevent increases of global emissions. We argue that the possibility of "hot air" generation under nationally-determined contributions (NDCs) requires an independent check of the NDC's ambition. If the NDC of the transferring country does contain "hot air", or if the transferred emission reductions are not covered by the NDC, a dedicated additionality test should be required. While additionality tests of projects and programmes could continue to be done through investment analysis, for policy instruments new approaches are required. They should be differentiated according to type of policy instrument. For regulation, we suggest calculating the resulting pay-back period for technology users. If the regulation generates investments exceeding a payback period threshold, it could be deemed additional. Similarly, carbon pricing policies that generate a carbon price exceeding a threshold could qualify; for trading schemes an absence of over-allocation needs to be shown. The threshold should be differentiated according to country categories and rise over time.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 18
    Publication Date: 2022-02-18
    Description: Combating climate change requires a fundamental simultaneous transformation of various sectoral systems that are key to the functioning of our economies and societies, such as energy, industry, transport, housing, and agriculture. This report by the COP21 RIPPLES project examines sector-specific challenges to decarbonisation and what contribution international governance could make to overcoming these challenges. Taking a sectoral perspective, the report identifies the key governance challenges that exist internationally towards the deep transformations required, and specifies the resulting key governance functions to be fulfilled by means of international cooperation/international institutions. To this end, the report first clarifies a number of key concepts, including international (climate) governance, international and transnational institutions, institutional complexes and poly-centricity. It then derives a number of functions that international institutions can fulfil from the relevant literature: providing guidance and signals, setting rules, providing transparency and accountability, providing capacity building, technology and finance, and facilitating knowledge and learning. This is the basis for an investigation into the key governance challenges and the potential of international governance in 14 key sectoral systems.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 19
    Publication Date: 2022-02-18
    Description: Before introducing an emissions trading system, jurisdictions have to consider the ex-isting energy and climate policy framework. This report seeks to analyse and evaluate non-ETS climate policy instruments, such as carbon taxes or green certificate trading schemes, regarding their suitability to serve as a basis for establishing emission trading systems. There is a general assessment of prototypical policy instruments. Besides, the report contains insights from case studies in India and Mexico. The report is meant to inform ETS development by showing how existing policy instruments could contribute to this process and by illustrating how non-ETS policy instruments could coexist with an emissions trading system, allowing for an effective policy mix.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 20
    Publication Date: 2022-02-18
    Description: Theoretical advances suggest that international governance in general and the Paris Agreement in particular provide a strong signal guiding sociotechnical systems toward decarbonization. We assess this signal and its effects empirically, by examining the struggle of competing narratives as present in the communications of leading US fossil fuel industry associations and companies. The results are then discussed in the context of the national and international climate and energy policy debates in a study period from late 2014 until the announcement of withdrawal from the Paris Agreement in June 2017. We find that the Paris Agreement has institutionalized a narrative paradigm that is surprisingly resilient. While the election of Donald Trump and his climate and energy policy led to a narrative shift in the coal industry, the oil and gas industry remained conspicuously silent in its immediate response and maintained its narrative strategies despite its alignment with the Paris Agreement.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 21
    Publication Date: 2022-02-18
    Description: The study analyses the country background, emissions trends, ongoing activities and barriers relating to the implementation of the Nationally Determined Contribution (NDC) of Ethiopia under the UNFCCC. A special emphasis is laid on further mitigation potentials in the fields of agriculture, forestry and low-emission transport.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 22
    Publication Date: 2022-02-18
    Description: In spite of differences in energy policies and supply, Japan and Germany have to master similar challenges: To reorganize the energy supply system towards - in the long term - being reliable, affordable, low in risks and resource use, and climate-neutral. At the same time, the ecological modernization should maintain or even strengthen international competitiveness. To better address these challenges, a bi-national expert council has been established between the two high-tech countries in 2016 - the GJETC. The aim of the GJETC is to show that despite different starting points, a national energy transition can be more successful, if both countries learn from their strengths and also weaknesses, to avoid the latter. If the implementation of an energy transition in the two countries is socially and economically sound and advances technology innovation and deployment, it may not only double success, but can also serve as blue prints for other countries, especially due to learning from similarities and differences. For example: Why is per capita energy consumption higher in transport in Germany, but energy intensity higher in Japan's building sector? How can variable renewable energies be integrated in an efficient energy system at lowest costs? The Council meets twice a year, holds stakeholder dialogues and outreach events, and prepares policy papers on strategic topics of mutual interest. Four comprehensive studies, each in cooperation of a German and a Japanese research institute, have been the basis for 15 joint key recommendations during the 1st phase. The 2nd phase to 2020 will study the role of hydrogen and digitalisation for the energy transition, as well as other topics. The paper presents the findings and recommendations of the GJETC of the first phase 2016-18 as well as first results of the second phase. It also reviews the setup of the GJETC and the way it works, to assess if and how it can serve as a role model of bilateral cooperation on the energy transition.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 23
    Publication Date: 2022-02-18
    Description: While the Paris Agreement (PA) has enshrined ambitious long-term objectives, the current level of action of the Parties to the Agreement falls far short of this ambition, as is recognised in the very COP decision adopting the Agreement. The Global Stocktake (GST) established in Art. 14 of the PA is a key element to address this problem. Its purpose is to review the implementation of the PA and to assess the progress made towards the collectively agreed goals. The aim of this report is to develop recommendations on how to maximise the potential impact of the GST. The report starts from a perspective of what the GST could ideally do, irrespective of decisions already taken under the UNFCCC and other political constraints. In the second step, the report takes these limitations into account and suggests ways for how to nonetheless work towards the desired outcome.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 24
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    Stockholm : European Council for an Energy Efficient Economy
    Publication Date: 2022-02-18
    Description: The emission reduction potential of energy efficiency and energy supply in buildings is estimated in various energy and climate action plans, scenarios, and potential analyses. But the third pillar of sustainability - sufficiency - is neglected in most studies.The increasing demand of space per person in the residential sector is a trend in most European countries. Its implication on energy use, demand for resources like land, building material, equipment, and waste production is enormous. Next to the ecological impact, the distribution of space has social and societal effects. Thus, sufficiency policies in the building sector complementing efficiency and energy policy are needed for a sustainable development of the European building stock. But how can a sufficiency potential in the building sector be estimated? How much space and equipment is needed for a decent living and how much is too much? The paper proposes four areas of sufficiency in buildings: space, design and construction, equipment, and use. It presents a set of indicators, a quantitative estimate of energy savings from reduced per capita floor area, and visualises the sufficiency potential in European countries in an experimental approach. The final discussion focuses on the question: What does this mean for policy making?
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 25
    Publication Date: 2022-02-18
    Description: Much mitigation-related governance activity is evident in a range of sectoral systems, and regarding particular governance functions. However, there is a tendency for this activity to relate to the easiest functions to address, such as "learning and knowledge building", or to take place in somewhat limited "niches". Across all sectoral systems examined, the gap between identified governance needs and what is currently supplied is most serious in terms of the critical function of setting rules to facilitate collective action. A lack of "guidance and signal" is also evident, particularly in the finance, extractive industries, energy-intensive industries, and buildings sectoral systems. Of the sectoral systems examined, the power sector appears the most advanced in covering the main international governance functions required of it. Nevertheless, it still falls short in achieving critical governance functions necessary for sufficient decarbonisation. Significantly, while the signal is strong and clear for the phase-in of renewable energy, it is either vague or absent when it comes to the phase-out of fossil fuel-generated electricity. The same lack of signal that certain high-carbon activities need actively to be phased out is also evident in financial, fossil-fuel extractive industry and transport-related sectors. More effective mitigation action will need greater co-ordination or orchestration effort, sometimes led by the UNFCCC, but also from the bodies such as the G20, as well as existing (or potentially new) sector-level institutions. The EU needs to re-consider what it means to provide climate leadership in an increasingly "polycentric" governance landscape.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 26
    Publication Date: 2022-02-18
    Description: Article 6 of the Paris Agreement establishes three approaches for countries to cooperate with each other in implementing their climate protection contributions. However, Article 6 sketches out only some basic contours; the details are to be filled in by further negotiations. This article surveys the views countries have submitted so far in order to identify the main issues at stake, points of controvery and convergence and possible ways forward. The submissions reveal some sharp differences in opinions on key issues such as the scope of the new mechanisms, how to operationalise the Article 6 requirement to increase ambition, whether to have international provisions on the promotion of sustainable development, and how to protect environmental integrity in the use of Article 6. The article concludes with a number of recommendations on how to address these controversies.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 27
    Publication Date: 2022-02-18
    Description: Relevant aspects of the options and requirements for reducing and phasing out coal-fired power generation have been under debate for several years. This process has produced a range of strategies, analyses and arguments, outlining how coal use in the energy sector could be reduced and phased out in the planned time frame, and determining structural policy measures suitable to support this. This Coal Report studies the existing analyses and provides an overview of the state of debate. It is intended to provide information on facts and contexts, present the advantages and disadvantages of individual courses of action, and reveal the respective scientific backgrounds. It strives to take a scientific and independent approach, and present facts in concise language, making it easy to follow for readers who are not experts in the field, without excessive abridgements or provocative statements.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 28
    Publication Date: 2022-02-18
    Description: Improvements in energy efficiency have numerous impacts additional to energy and greenhouse gas savings. This paper presents key findings and policy recommendations of the COMBI project ("Calculating and Operationalising the Multiple Benefits of Energy Efficiency in Europe"). This project aimed at quantifying the energy and non-energy impacts that a realisation of the EU energy efficiency potential would have in 2030. It covered the most relevant technical energy efficiency improvement actions in buildings, transport and industry. Quantified impacts include reduced air pollution (and its effects on human health, eco-systems), improved social welfare (health, productivity), saved biotic and abiotic resources, effects on the energy system and energy security, and the economy (employment, GDP, public budgets and energy/EU-ETS prices). The paper shows that a more ambitious energy efficiency policy in Europe would lead to substantial impacts: overall, in 2030 alone, monetized multiple impacts (MI) would amount to 61 bn Euros per year in 2030, i.e. corresponding to approx. 50% of energy cost savings (131 bn Euros). Consequently, the conservative CBA approach of COMBI yields that including MI quantifications to energy efficiency impact assessments would increase the benefit side by at least 50-70%. As this analysis excludes numerous impacts that could either not be quantified or monetized or where any double-counting potential exists, actual benefits may be much larger. Based on these findings, the paper formulates several recommendations for EU policy making: (1) the inclusion of MI into the assessment of policy instruments and scenarios, (2) the need of reliable MI quantifications for policy design and target setting, (3) the use of MI for encouraging inter-departmental and cross-sectoral cooperation in policy making to pursue common goals, and (4) the importance of MI evaluations for their communication and promotion to decision-makers, stakeholders, investors and the general public.
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  • 29
    Publication Date: 2022-02-18
    Description: Each year, approximately one-third of the food produced for human consumption is lost or wasted worldwide. The waste of resources used for this food has significant environmental impacts in terms of land and water use as well as greenhouse gas emissions. Consequently, one of the targets of the UN sustainable development goals is to halve per capita global food waste at the retail and consumer levels and reduce food losses along production and supply chains by 2030. However, sufficient knowledge about the suitability of instruments for food waste prevention is still lacking. The purpose of this paper is therefore threefold: first, it outlines the generation and causes of food losses and waste. Second, it discusses good practices from different countries, such as laws to reduce food waste, voluntary agreements, awareness campaigns and results from behavioural economics. Finally, based on these findings, this paper identifies barriers to as well as requirements for the implementation of effective and efficient instruments.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 30
    facet.materialart.
    Unknown
    Stockholm : European Council for an Energy Efficient Economy
    Publication Date: 2022-02-18
    Description: "400,000 new homes per year are needed in German cities." This figure has been cited repeatedly in political discussions, media, and statements of different groups for a couple of years now. Living space is needed to mitigate the (further) inordinate increase of rents in some cities and regions and to ease finding appropriate flats at affordable prices for low- and medium-income households. But how to activate investors and the real estate market? Having the triangle of sustainability in mind with its ecologic, social and economic cornerstones the discussion - metaphorically spoken - currently pulls the three corners: Which should have the highest priority? The economically driven most favourable solution is lowering the requirements for new buildings such as the energy performance to make building cheaper. The social perspective prefers an increase of public social housing investments regardless of efficiency standards. And the ecological side argues that a high performance is needed to reach energy and climate targets in the buildings sector. Starting at this point of discussion, firstly, the paper reflects the assumptions behind the numbers of new homes needed against a sufficiency background. Secondly, it presents current changes in German building policies: a new legislation for energy supply and efficiency is currently in preparation. It discusses the potential to integrate sufficiency aspects in building policies, focussing specifically on the new regulation, financial incentives, and energy advice. The paper analyses if and to what extent it is likely to balance the three cornerstones of sustainability by integrating sufficiency aspects into efficiency policies. Household experiences with prepayment meters are used as an example to illustrate the potential for tapping efficiency and sufficiency potentials in low-income households considering social, economic, and ecological aspects. Based on the identified (in)consistencies, thirdly, it suggests further development in German policies to make better use of synergies between the ecologic, social and economic demands on buildings.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 31
    Publication Date: 2022-02-18
    Description: The study analyses the country background, emissions trends, ongoing activities and barriers relating to the implementation of the Nationally Determined Contribution (NDC) of the Islamic Republic of Iran under the UNFCCC. A special emphasis is laid on further mitigation potentials in the fields of demand-side efficiency through energy-price reform, upstream oil and gas efficiency (with an emphasis on gas flaring) and a sustainable energy mix (with an emphasis on renewable energies).
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 32
    Publication Date: 2022-02-18
    Description: Today more than 45 % of all energy-related CO2 emissions come from burning coal. Thus, reducing CO2 emissions from coal use is a necessity for reaching the targets of the Paris Agreement. This will not only pose challenges for coal consumers (restructuring of the energy system), but also for countries whose economy is strongly depending on the production of coal. This paper examines the role of coal in three countries, which are or were in recent years among the top coal exporters: Indonesia, Colombia and Vietnam. Understanding challenges and possible transition pathways in these countries will help to develop global strategies to reduce CO2 emissions from coal in the short to mid-term.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 33
    Publication Date: 2022-02-18
    Description: The twenty-third Conference of the Parties (COP-23) of the United Nations Framework Convention on Climate Change (UNFCCC) was held in Bonn on 6-17 November 2017, under the presidency of Fiji. COP-23 focused, in particular, on developing rules to implement the 2015 Paris Agreement and on raising ambition for climate protection. Since this was the first "Oceanic" COP, special attention was given to supporting the countries of the Global South in their efforts to reduce emissions, adapt to climate change, and deal with the unavoidable impacts of climate change. This article summarizes the main developments and results of COP-23.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 34
    Publication Date: 2022-02-18
    Description: With the "Energiewende", the German term for the transformation of the national energy system, the German government pursues ambitious goals, primarily but not only to reflect the climate change challenge and to react to the risks associated with the use of nuclear power plants. After launching the energy concept in mid-2011, which describes the "Energiewende" goals, Germany was perceived as an international pioneer in energy transition for many years and has been acknowledged for its braveness to combine ambitious greenhouse gas (GHG) mitigation targets with a phase out program for nuclear power plants. In this context, this article asks where Germany’s energy transition currently stands, what is planned next and how far the set targets have been achieved or where more action is required to stick to this pathway.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 35
    Publication Date: 2022-02-18
    Description: Last year's conference of the global climate change regime took place from 2 until 15 December 2018 in Katowice, Poland. The conference had two main objectives: operationalising the Paris Agreement by adopting detailed rules for its implementation, and starting the process of strengthening Parties' climate protection contributions. This article covers the negotiations on these two sets of issues and also includes a discussion of other recent climate activities by Parties and non-Party actors. Success of the negotiations in Katowice was far from assured, but in the end COP24 concluded with the adoption of the "Katowice Climate Package" setting out detailed guidelines on how to implement its various elements. However, the conference fell short on the first objective, none of the major emitting countries was ready to step up its climate ambition. The most important aspect of the Katowice outcome is therefore that it has brought the wrangling about implementation procedures to a close, making way for the true task at hand: the strengthening of national and international activities to protect the climate and the implementation of the existing pledges. Arguably, a key factor that has been slowing down climate policy is the power of entrenched interests. The article therefore concludes with a reflection on how such barriers to climate action may be overcome and what role future COPs may play in this regard.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 36
    Publication Date: 2022-02-18
    Description: Article 6 of the Paris Agreement establishes mechanisms for Parties to "pursue voluntary cooperation in the implementation of their nationally determined contributions to allow for higher ambition in their mitigation and adaptation actions [...]" (Article 6.1). I. e. the mechanisms are explicitly designed to foster higher ambition. However, without additional guidance and rules, the economic incentives of carbon markets may work against increasing host country ambition. For example, setting ambitious NDC targets may directly reduce the amount of mitigation outcomes that go beyond the NDC target and that a host country can transfer abroad. The report presents four options on how the risks can be ad-dressed and ambition can be increased: (1) Strengthening reporting, transparency and comparability; (2) Reconciling the design of the Article 6.4 mechanism with ambition raising of host countries; (3) Supporting the host country to raise ambition through the Article 6.4 mechanism; (4) Fostering the acquiring country to raise ambition through the Article 6.4 mechanism. These options are assessed and recommendations are provided on how they could be implemented.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: workingpaper , doc-type:workingPaper
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  • 37
    Publication Date: 2022-02-18
    Description: Article 6.4 of the Paris Agreement establishes a new mechanism for Parties to cooperate in achieving their nationally determined contributions (NDCs). One key innovation of the Article 6.4 mechanism is its objective to "deliver an overall mitigation in global emissions" (Art. 6.4(d)). This report develops recommendations on how to implement this objective. A key difficulty lies in the fact that even basics of how the mechanism is supposed to function have so far not been clarified by the Parties. The report therefore first sketches out what has so far been agreed and discussed on the mechanism’s activity cycle. Second, as the concept of overall mitigation has so far also not been clearly defined by Parties, the report derives a working definition from the language that was agreed in the Paris Agreement. In the next step, the report provides a survey of the options to achieve overall mitigation that have so far been discussed in the relevant literature and in the Article 6 negotiations. Many of these options were developed in the context of the Kyoto mechanisms. The report therefore discusses to what extent the options are also applicable under the Paris Agreement or whether adjustments need to be made. In the following, the options that are applicable under the Agreement are assessed on the basis of a number of criteria. The report concludes with a summary of the main findings and recommendations.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 38
    Publication Date: 2022-02-18
    Description: This report explores the future role of the voluntary carbon market and its potential to contribute to raising the ambition of climate policy. For this purpose, desk research was complemented by interviews with voluntary carbon market representatives. The report finds that the current roles of the voluntary market are set to change fundamentally due to the Paris Agreement. For the future of the voluntary market as an investor, three roles were identified, each of which is associated with specific challenges: The market may maintain its current role of buyer of carbon neutrality credits, it may become a supporter of NDC implementation, or it may become a driver of ambition. With regard to the future role of private certification standards, the Paris Agreement may hold the possibility of using such standards in the context of compliance activities. Overall, the findings indicate that the voluntary market has some potential to contribute to ambition raising. Whether this potential will actually be unlocked depends on how the concept of ambition raising will be operationalized under the Paris Agreement and to what degree it can be integrated into the voluntary market's activities and business models.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 39
    facet.materialart.
    Unknown
    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-11-10
    Description: Europe needs a new vision of progress. An energy transition has this potential. It can give the "European idea" a future-oriented content. The goal for 2050 is clear: a Europe without fossil and nuclear energy! This is not a utopia. Studies, resolutions of the EU and some member states prove that this vision is feasible and has many advantages: more jobs, more security of supply, fewer premature deaths due to air pollution, reduction of resource conflicts, falling energy costs. New green lead markets for renewable energies and resource efficiency are emerging. A European energy transition requires an alliance, ideally fuelled by neighbours France and Germany. Many are hoping for Germany as a driver of nuclear and coal phase-out. But deciding on "revolutionary goals" is not enough: finally implementing them is what Germany and Europe are waiting for. This report shows which concrete steps can advance this vision of progress.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 40
    Publication Date: 2021-03-29
    Keywords: gas hydrate-bearing sediments; in situ synchrotron-tomography data ; 551
    Language: English
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  • 41
    Publication Date: 2021-03-29
    Description: A series of various readily water-soluble carbamates were synthesized with good yields. These compounds are useful chemical tracers for assessing the cooling progress in a georeservoir during geothermal power plant operation. Acylation of primary amines was carried out as well as using a solution of sodium bicarbonate and without the presence of salt. Products were characterized by 1H-NMR and 13C-NMR. Purity was confirmed through elemental analysis.
    Description: Open Access Publikationsfonds 2015
    Keywords: chloroformates; primary amines; carbamates; thermo-sensitive tracers; urethanes ; 551
    Language: English , English
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  • 42
    Publication Date: 2021-03-29
    Description: The combination of scanning electron microscope–cathodoluminescence (CL), fluid inclusion analysis and high-resolution electron probe microanalysis of Al, Ti, K and Fe in vein quartz has yielded results permitting a greater understanding of the complex mineralisation of the Central Oyu Tolgoi and Zesen Uul porphyry-style deposits, southern Mongolia. These data demonstrate the relationship between quartz precipitation, dissolution and ore deposition as the mineralising fluid chemistry changed through time. Four major quartz generations are identified in the A-type veins from the stockworks of both the Central Oyu Tolgoi (OTi to OTiv) and Zesen Uul deposits (ZUi to ZUiv). Despite differences in the associated alteration and mineralisation style, the observed CL textures and trace element signatures of the quartz generations are comparable between deposits. The OTi and ZUi stage formed both the primary network of A-type veins and pervasive silicification of the host rock. Using the Ti-in-quartz geothermometer, crystallisation temperatures for OTi and ZUi of between 598°C and 880°C are indicated. The main stage of sulphide mineralisation was accompanied by the dissolution of pre-existing quartz (OTi and ZUi) and precipitation of a weakly luminescent generation of quartz (OTii and ZUii) with a low Ti content, reflected in a calculated temperature drop from approximately 700°C to 340°C in Central Oyu Tolgoi and 445°C in Zesen Uul. OTii and ZUii stage quartzes show high and variable Al concentrations. The next stage of quartz in both deposits (OTiii and ZUiii) forms a fine network of veins in cracks formed in pre-existing quartz. OTiii and ZUiii quartz contain measurable fluid inclusions of moderate salinity (3–17.1 wt.% NaCl eq.), entrapped in the temperature range 256°C to 385°C. OTiii and ZUiii are not related to any sulphide mineralisation. The final OTiv and ZUiv stages are characterised by quartz–calcite micro-breccias that penetrate the A-type veins. Based on the calculated entrapment temperatures, the OTiv/ZUiv stage crystallised between 212°C and 335°C, and the quartz is characterised by elevated but variable Al and Fe contents. The CL and trace element signatures of the OTi to OTiii and ZUi to ZUiii stages of the two Mongolian porphyries show similar features to those observed in porphyry-style deposits from other regions. This suggests that a common sequence of quartz crystallisation occurs during the formation of early veins in many porphyry copper systems.
    Keywords: Copper porphyry; Quartz; Cathodoluminescence; Fluid inclusion; Trace elements; Mongolia ; 551
    Language: English
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  • 43
    Publication Date: 2021-03-29
    Description: Chemical reduction has long dominated the thinking about the mechanism of aqueous contaminant removal in the presence of metallic iron (e.g. Fe0/H2O systems). However, a large body of experimental evidence indicates that chemical reduction is not adequate to explain satisfactorily the efficiency of Fe0/H2O systems for several substances or classes of substances. By contrast, the alternative approach, that contaminants are fundamentally adsorbed and co-precipitated by iron corrosion products seems to provide a better explanation of observed efficiency. The new approach is obviously not really understood. The present communication aims at clarifying this key issue. It seems that a paradigm shift is necessary for the further development of the iron technology.
    Keywords: Contaminant removal; Paradigm shift; Removal mechanism; Water treatment; Zerovalent iron ; 551
    Language: English
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  • 44
    Publication Date: 2021-03-29
    Keywords: Adsorption; Contaminant removal; Mechanisms; Reduction; Zerovalent metals ; 551
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  • 45
    Publication Date: 2021-03-29
    Keywords: Interdisciplinary approach; Peer-review system; Permeable reactive barrier; Water treatment; Zero-valent iron ; 551
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  • 46
    Publication Date: 2021-03-29
    Description: A detailed electrochemical, photophysical and theoretical study is presented for various new thienyl and furyl derivatives of pyrene. Their optical properties are described based on UV-VIS absorption and both steady-state and time-resolved fluorescence spectroscopy. DFT and TDDFT calculations are also presented to support experimental data. The calculations results show that HOMO-LUMO orbitals are delocalized uniformly between aromatic core and aryl substituents. Good electrochemical stability of thienyl and furyl hybrids of pyrene confirm their potential application for light emitting electrochemical cells or spintronics mainly due to their beneficial optical and charge transport properties in electrochromic devices. In order to demonstrate this potential, an OLED device is presented. Synthesized compounds included in this OLED device both facilitate electron transport and act as a light emitting layer.
    Keywords: thienyl; furyl derivatives; pyrene ; 551
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  • 47
    Publication Date: 2021-04-25
    Description: An external skeleton is an essential part of the body plan of many animals and is thought to be one of the key factors that enabled the great expansion in animal diversity and disparity during the Cambrian explosion. Molluscs are considered ideal to study the evolution of biomineralization because of their diversity of highly complex, robust and patterned shells. The molluscan shell forms externally at the interface of animal and environment, and involves controlled deposition of calcium carbonate within a framework of macromolecules that are secreted from the dorsal mantle epithelium. Despite its deep conservation within Mollusca, the mantle is capable of producing an incredible diversity of shell patterns, and macro- and micro-architectures. Here we review recent developments within the field of molluscan biomineralization, focusing on the genes expressed in the mantle that encode secreted proteins. The so-called mantle secretome appears to regulate shell deposition and patterning and in some cases becomes part of the shell matrix. Recent transcriptomic and proteomic studies have revealed marked differences in the mantle secretomes of even closely-related molluscs; these typically exceed expected differences based on characteristics of the external shell. All mantle secretomes surveyed to date include novel genes encoding lineage-restricted proteins and unique combinations of co-opted ancient genes. A surprisingly large proportion of both ancient and novel secreted proteins containing simple repetitive motifs or domains that are often modular in construction. These repetitive low complexity domains (RLCDs) appear to further promote the evolvability of the mantle secretome, resulting in domain shuffling, expansion and loss. RLCD families further evolve via slippage and other mechanisms associated with repetitive sequences. As analogous types of secreted proteins are expressed in biomineralizing tissues in other animals, insights into the evolution of the genes underlying molluscan shell formation may be applied more broadly to understanding the evolution of metazoan biomineralization.
    Keywords: Biomineralization; Mollusc; Mantle; Shell; Shell matrix proteins; Co-option; Lineage-specific novelties; Repetitive low complexity domain ; 551
    Language: English , English
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  • 48
    Publication Date: 2021-03-29
    Description: This study aims to evaluate quantitatively the land surface temperature (LST) derived from MODIS (Moderate Resolution Imaging Spectroradiometer) MOD11A1 and MYD11A1 Collection 5 products for daily land air surface temperature (Ta) estimation over a mountainous region in northern Vietnam. The main objective is to estimate maximum and minimum Ta (Ta-max and Ta-min) using both TERRA and AQUA MODIS LST products (daytime and nighttime) and auxiliary data, solving the discontinuity problem of ground measurements. There exist no studies about Vietnam that have integrated both TERRA and AQUA LST of daytime and nighttime for Ta estimation (using four MODIS LST datasets). In addition, to find out which variables are the most effective to describe the differences between LST and Ta, we have tested several popular methods, such as: the Pearson correlation coefficient, stepwise, Bayesian information criterion (BIC), adjusted R-squared and the principal component analysis (PCA) of 14 variables (including: LST products (four variables), NDVI, elevation, latitude, longitude, day length in hours, Julian day and four variables of the view zenith angle), and then, we applied nine models for Ta-max estimation and nine models for Ta-min estimation. The results showed that the differences between MODIS LST and ground truth temperature derived from 15 climate stations are time and regional topography dependent. The best results for Ta-max and Ta-min estimation were achieved when we combined both LST daytime and nighttime of TERRA and AQUA and data from the topography analysis.
    Description: Open-Access-Publikationsfonds 2016
    Keywords: land surface temperature (LST); MODIS LST products; northern Vietnam ; 551
    Language: English
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  • 49
    Publication Date: 2021-03-29
    Description: Groundwater from the La Paz arid coastal aquifer in Baja California, Mexico, is essentially the only source of drinking water for the local population and tourists, as well as irrigation water for agricultural needs. The intensive exploitation of the aquifer and water cycling has resulted in groundwater abatement (up to 10 m) and high salinity (up to *5800 mg l-1). A study using hydrochemistry, isotopic (deuterium, oxygen-18 and carbon- 14) and gaseous tracers (chlorofluorocarbons CFC-11, CFC-12, CFC-113), as well as multivariate statistics, was developed to elucidate groundwater composition, flow and occurrence. Groundwater is of meteoric origin, and a large proportion is subject to evaporation. The primary natural recharge is generated in the El Novillo and Las Cruces ranges, and groundwater subsequently flows in a SE–NW direction toward the coast. The initial water type is the result of discordant dissolution of silicate minerals and ion exchange on soils. In the lower plain portion, the aquifer system is recharged from irrigation return flow and seawater intrusion, which significantly affects groundwater chemistry. Nitrate and chloride concentrations indicate that groundwater is highly affected by an overuse of fertilizers in agricultural activities, but there is little effect from urban activities. Seawater intrusion has progressed rapidly during the past decade, and the impact currently extends 13 km inland. Radiocarbon residence time calculations suggest that groundwater is modern, with the exception of Chametla and El Centerario sites in the central and western lowlands with ages of up to *5000 years. These waters indicate an additional recharge source for the upconing of fossil groundwater or regional flow.
    Keywords: Coastal aquifers; Hydrogeochemistry; Arid regions; Isotope hydrology; Contamination ; 551
    Language: English
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  • 50
    Publication Date: 2021-03-29
    Description: Dada la importancia que revisten los suelos en los procesos que ocurren en la zona crítica (zona de interacción entre agua, suelo, aire, organismos), en este trabajo presentamos la distribución temporal y espacial de una secuencia de paleosuelos arcillosos con carbonatos secundarios (capas de caliches y carbonatos diseminados) en el sector nororiental de la Cuenca de México, particularmente en el valle de Teotihuacán. El propósito de este trabajo consiste en reconstruir la distribución temporal y espacial de la cubierta de suelos del pasado para entender su relación con la estructura actual de suelos y sedimentos en este sector semiárido de la cuenca de México. Con esta información, determinar la participación de estos materiales en la Zona Crítica (ZC). Para ello, se ha llevado a cabo un transecto de dirección norte-sur, que inicia en las elevaciones del Cerro Gordo, cruza el valle de Teotihuacán y termina en la Sierra Patlachique, describiendo perfiles de suelo en diferentes posiciones geomorfológicas. El marco cronológico se ha establecido con base en fechamientos de radiocarbono realizados en las capas de caliches. De acuerdo a la cronología, al tipo y grado de pedogénesis, y a los procesos de sedimentación, se han reconocido cuatro unidades. La primera unidad, denominada Paleosuelos del Pleistoceno, fase I (50000 – 20000 años AP), está compuesta de paleosuelos arcillosos, los cuales son Luvisoles crómicos y estágnicos, dependiendo de su posición en el paisaje. Estos paleosuelos muestran tanto carbonatos secundarios diseminados y en fracturas, como capas de caliches. En la segunda unidad, Paleosuelos del Pleistoceno, fase II (20000 –10000 años AP), dominan los sedimentos sobre los suelos; únicamente en el fondo del Valle, se han encontrado Gleysoles cortados por canales aluviales. La unidad, Paleosuelos del Holoceno, fase I (10000 a 1000 años AP) se caracteriza por presentar suelos poligenéticos (Vertisoles), fuertemente modificados por los procesos antrópicos, durante las diversas fases de ocupación pre-hispánica. La última unidad, Suelos del Holoceno, fase II, abarca el último milenio, en donde se destacan procesos de erosión e inestabilidad del paisaje. La tendencia principal en la distribución espacial de los paleosuelos es la siguiente: las unidades antiguas (Luvisoles, capas de caliches y Vertisoles) están sepultadas profundamente en el fondo del valle. Sin embargo, en los taludes y elevaciones montañosas, pueden aparecer cerca o directamente sobre la superficie, siendo incorporados en el manto de suelos actual. Las interrelaciones entre los diferentes paleosuelos a lo largo del transecto estudiado, junto con las observaciones micromorfológicas, apoyan la hipótesis de una relación evolutiva entre los Luvisoles pleistocénicos y los Vertisoles del Holoceno. Consideramos que estas diferentes unidades repercuten en los procesos hidrológicos en el valle y que las capas de caliche formadas en los ambientes pleistocénicos pueden afectar la geoquímica del agua subterránea así como sus firmas isotópicas.
    Description: As soils are important elements for the processes involved in the critical zone (the zone of interaction between water, soil, air, and organisms), in this work we present the temporal and spatial distribution of a clayey-paleosol sequence with secondary carbonates (layers of caliche and disseminated carbonates) in the northeast sector of the Mexico Basin, particularly in the Teotihuacan Valley. The goal of this paper is the temporal and spatial reconstruction of the past soil cover to understand its relationship with the present day soils and sediments in this semiarid sector of the Mexico Basin. With this information the involvement of these materials in the critical zone could be determined. To comply with these objectives, a north-south transect was carried out, starting in the Cerro Gordo, crossing the Teotihuacan valley and ending in the Sierra Patlachique, describing soil profiles located in different geomorphological positions. The chronological framework has been established with radiocarbon dates of the caliche layers. According to this chronology, the type and degree of pedogenesis, as well as the sedimentation processes, four units have been recognized. The first unit is named the Pleistocene Paleosols, phase I (50000 – 20000 years BP), and is composed of clayey paleosols, chromic and stagnic Luvisols, depending on their position in the landscape. These paleosols contain pedogenic carbonates, disseminated and in fractures, and caliche layers. In the second unit, the Pleistocene Paleosols, phase II (20000 –10000 years BP), sediments predominate over soils; only in the valley floor some Gleysols are found to be cut by alluvial channels. The unit, Paleosols of the Holocene Paleosols unit, phase I (10000 to 1000 years BP), is characterized by polygenetic soils (Vertisols) strongly modified by anthropic processes during distinct phases of pre-hispanic occupation. The last unit, the Holocene Soils, phase II, covers the last millennium when erosional processes and unstable landscape dominate. The paleosols (Luvisols, caliche layers, and Vertisols) are deeply buried at the bottom of the valley. However, on the slopes and hilltop positions, they can appear close to or directly on the surface, being incorporated in the present day soil mantle. Spatial interrelations of different paleosols along the studied transect together with micromorphological observations support the hypothesis of an evolutionary link between the Pleistocene Luvisols and the Holocene Vertisols. We propose that these different units are involved in the hydrological processes in the valley and that the caliche layers, formed in the Pleistocene environments, can affect the geochemistry of the groundwater as well as its isotopic signatures.
    Keywords: paleosuelos; Teotihuacán; caliches; Luvisoles; Vertisoles; cuenca de México; paleosols; Teotihuacan; caliches; Luvisols; Vertisols; Basin of Mexico ; 551
    Language: Spanish
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  • 51
    Publication Date: 2021-03-29
    Description: A new method to correlate intrinsic reactivity and treatability efficiency of metallic iron (Fe0) was evaluated. A 2.0 mg L-1 methylene blue (MB) solution was used in gravity fed column experiments. The intrinsic reactivity of nine Fe0 materials (ten samples) was characterized using the EDTA test. Three commercial Fe0 materials ZVI1 (0.40 - 0.80 mm), ZVI9 (0.50 mm) and ZVI10 (0.45 - 0.55 mm) were tested in column experiments. A layer containing 100 g of Fe0 was sandwiched between 19.0 to 20.0 cm upper coarse sand (1.6 - 2.0 mm) and 8.0 cm lower fine sand (0.25 - 0.30 mm). 500 mL of the MB solution was daily filtered through each column for one month. Effluent solutions were characterized for MB and Fe concentrations. The columns were also characterized by the evolution of the hydraulic conductivity (k values). Results showed (i) quantitative MB removal (〉 88 %) and (ii) limited Fe release for all three columns. After about 25 days, the Fe levels were constantly less than 1.0 mg L-1. The most significant difference was observed in the evolution of the k value and was attributed to the different material sorting. Less sorted ZVI1 exhibited the lowest initial k value (8.0 vs 43.0 mm min-1 for ZVI9 and ZVI10) and most significant permeability loss. Results confirmed the usefulness of the tested protocol as a reliable method to assess the efficiency of Fe0 materials in short term column experiments. Well-sorted Fe0 materials are recommended for long term efficient Fe0 filtration systems.
    Keywords: Intrinsic reactivity; Methylene blue; Reactive filtration; Treatability efficiency; Zerovalent iron ; 551
    Language: English
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  • 52
    Publication Date: 2021-04-25
    Keywords: 551 ; VKB 350 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 186-209
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  • 53
    Publication Date: 2021-03-29
    Description: In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a 〉10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.
    Keywords: Fluid/rock interaction; Elemental transfer; Isotopic fractionation; Subduction and exhumation; Sulu ; 551 ; Earth Sciences; Mineralogy; Mineral Resources; Geology
    Language: English
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  • 54
    Publication Date: 2021-03-29
    Description: The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeirão Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeirão Neisse (arkosic sandstones and siltites), and Ribeirão do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, São Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaquã Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.
    Keywords: Dom Feliciano Belt; Ediacaran; Foreland basin; U–Pb SHRIMP ages; Provenance ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 55
    Publication Date: 2021-03-29
    Description: In the crystal structure of the title compound [systematic name: 5H-dibenzo[a,d]cycloheptatriene-5-carboxamide–1,4- dioxane (2/1)], 2C16H13NO C4H8O2, the cytenamide molecules form a hydrogen-bonded R2 2(8) dimer. The solvent molecule is located between two adjacent cytenamide dimers and forms N—H O hydrogen bonds with one cytenamide molecule from each dimer.
    Keywords: single-crystal X-ray study; T = 160 K; mean (C–C) = 0.004 A° ; R factor = 0.069; wR factor = 0.122; data-to-parameter ratio = 13.5. ; 551
    Language: English
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  • 56
    Publication Date: 2021-03-29
    Keywords: Adsorption; Decontamination; Reduction; Remediation; Zerovalent iron ; 551
    Language: English
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  • 57
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    Publication Date: 2021-03-29
    Keywords: letter; apology letter ; 551 ; Chlorine ; Iron ; Lindane ; Palladium ; Water Pollutants, Chemical ; Water Purification
    Language: English , English
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  • 58
    Publication Date: 2021-03-29
    Keywords: Environmental remediation; Material reactivity; Nanoscale iron; Roll-front; Zerovalent iron ; 551 ; Environment; Atmospheric Protection/Air Quality Control/Air Pollution; Climate Change; Environment, general; Soil Science & Conservation; Hydrogeology; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
    Language: English
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  • 59
    Publication Date: 2021-03-29
    Description: Basaltic dyke swarms in the southern continental part of the Cameroon Volcanic Line (Bangangte, Dschang, Manjo areas) are tholeiitic in composition with 46 to 50 wt.% SiO 2 and have moderate Mg-numbers (53–59), medium TiO 2 contents (1.48–2,05 wt.%), and flat to mildly enriched incompatible trace element patterns. Comparison with trace element patterns of representative Cenozoic basaltic rocks of the Cameroon Volcanic Line (Bana anorogenic complex, Mt. Bambouto, Adamawa Plateau basalts) indicates that these dykes are less enriched in light REE and show different incompatible trace element ratios (La/Yb: 5.7 to 8.6; Zr/Nb: 7.6 to 12.0; Ba/Th: 87.7 to 93.3). The trace element patterns of the dykes and their Sr- and Nd- isotope compositions, however, are similar to those of the pre-Cenozoic volcanic rocks of the Benue Trough in Nigeria. Our data therefore suggest that these dykes represent the magmatic history related to the break-up of Africa and South America and are unrelated to the Tertiary volcanism of the Cameroon Line.
    Keywords: Basalt dykes; Tholeiites; Phanerozoic; Cameroon volcanic line; West Gondwana ; 551
    Language: English
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  • 60
    Publication Date: 2021-03-29
    Description: The arborescent lycophyte group known as the sigillarians bore pedunculate fructifications, including Sigillariostrobus Schimper, which has a known propensity to disaggregate, making comparisons of cones and in situ spores often difficult if not impossible. Sigillariostrobus is monosporangiate, containing either megaspores or microspores. Two new species of Sigillariostrobus with megaspores are described from the British Coal Measures. Two cones of Sigillariostrobus saltwellensis sp. nov. are described from Langsettian–Duckmantian strata of Great Britain, containing in situ Laevigatisporites glabratus (Zerndt) Potonié and Kremp spores, making this the first British Sigillariostrobus species described containing such spores. Sigillariostrobus barkeri sp. nov. is given here to the previously described cone with in situ Tuberculatisporites brevispiculus (Schopf) Potonié and Kremp spores. This is the first Sigillariostrobus cone with this megaspore species in situ, and thus shows that T. brevispiculus and T. mamillarius (Bartlett) Potonié and Kremp are not conspecific as others have previously suggested.
    Description: Open-Access Publikationsfonds 2015
    Keywords: Sigillariostrobus Schimper; megasporangiate; British Coal Measures ; 551
    Language: English
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  • 61
    Publication Date: 2021-04-27
    Description: he fossil record of lichens is scarce and many putative fossil lichens do not show an actual physiological relationship between mycobionts and photobionts or a typical habit, and are therefore disputed. Amber has preserved a huge variety of organisms in microscopic fidelity, and so the study of amber fossils is promising for elucidating the fossil history of lichens. However, so far it has not been tested as to how amber inclusions of lichens are preserved regarding their internal characters, ultrastructure, and chemofossils. Here, we apply light microscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and Raman spectroscopy to an amber-preserved Eocene lichen in order to gain information about the preservation of the fossil. The lichen thallus displays lifelike tissue preservation including the upper and lower cortex, medulla, photobiont layer, apothecia, and soredia. SEM analysis revealed globular photobiont cells in contact with the fungal hyphae, as well as impressions of possible former crystals of lichen compounds. EDX analysis permitted the differentiation between halite and pyrite crystals inside the lichen which were likely formed during the later diagenesis of the amber piece. Raman spectroscopy revealed the preservation of organic compounds and a difference between the composition of the cortex and the medulla of the fossil.
    Description: Open Access Publikationsfonds 2015
    Keywords: Lichen; amber; morphology; ultrastructure; chemofossils; taphonomic alteration ; 551
    Language: English
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  • 62
    Publication Date: 2021-03-29
    Description: Fungi have been recognized as a frequent colonizer of subseafloor basalt but a substantial understanding of their abundance, diversity and ecological role in this environment is still lacking. Here we report fossilized cryptoendolithic fungal communities represented by mainly Zygomycetes and minor Ascomycetes in vesicles of dredged volcanic rocks (basanites) from the Vesteris Seamount in the Greenland Basin. Zygomycetes had not been reported from subseafloor basalt previously. Different stages in zygospore formation are documented in the studied samples, representing a reproduction cycle. Spore structures of both Zygomycetes and Ascomycetes are mineralized by romanechite-like Mn oxide phases, indicating an involvement in Mn(II) oxidation to form Mn(III,VI) oxides. Zygospores still exhibit a core of carbonaceous matter due to their resistance to degradation. The fungi are closely associated with fossiliferous marine sediments that have been introduced into the vesicles. At the contact to sediment infillings, fungi produced haustoria that penetrated and scavenged on the remains of fragmented marine organisms. It is most likely that such marine debris is the main carbon source for fungi in shallow volcanic rocks, which favored the establishment of vital colonies.
    Keywords: Fungal structure; Fungi; Vesicles; Sediment; Fossils; Zygomycetes; Seamounts; Marine geology ; 551
    Language: English , English
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  • 63
    Publication Date: 2021-03-29
    Description: Despite two decades of intensive research on using metallic iron (Fe0) for environmental remediation and water treatment, basic concerns about their efficiency still prevail. This communication presents the basic idea of the view that challenges the prevailing paradigm on the operating mode of Fe0/H2O systems. The alternative paradigm is in tune with the mainstream science on aqueous iron corrosion. Its large scale adoption will enable a scientifically based system design and increase the acceptance of this already proven efficient technology.
    Keywords: Adsorption; Co-precipitation; Filtration; Water treatment; Zero-valent iron ; 551
    Language: English
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  • 64
    Publication Date: 2021-04-27
    Description: Open-Access-Publikationsfonds 2016
    Keywords: Fossils; Leaves; Paleobiology; Mosses, Plant fossils; Eocene epoch, Bryology; Nonvascular plants ; 551
    Language: English , English
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  • 65
    Publication Date: 2021-03-29
    Keywords: methane hydrate; NGH; gas transport; self-preservation; LNG; CNG; pipeline; methane hydrate carrier; risk analysis ; 551
    Language: English
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  • 66
    Publication Date: 2021-03-29
    Description: The temperature dependence of H-Uiso in N-acetyl-l-4-hydroxyproline monohydrate is investigated. Imposing a constant temperature-independent multiplier of 1.2 or 1.5 for the riding hydrogen model is found to be inaccurate, and severely underestimates H-Uiso below 100 K. Neutron diffraction data at temperatures of 9, 150, 200 and 250 K provide benchmark results for this study. X-ray diffraction data to high resolution, collected at temperatures of 9, 30, 50, 75, 100, 150, 200 and 250 K (synchrotron and home source), reproduce neutron results only when evaluated by aspherical-atom refinement models, since these take into account bonding and lone-pair electron density; both invariom and Hirshfeld-atom refinement models enable a more precise determination of the magnitude of H-atom displacements than independent-atom model refinements. Experimental efforts are complemented by computing displacement parameters following the TLS+ONIOM approach. A satisfactory agreement between all approaches is found.
    Keywords: riding hydrogen model; QM/MM computations; neutron diffraction; invariom refinement; Hirshfeld-atom refinement; synchrotron radiation ; 551
    Language: English
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  • 67
    Publication Date: 2021-03-29
    Keywords: soil respiration ; 551
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  • 68
    Publication Date: 2021-03-29
    Description: This letter presents an improved discussion of the data provided in a recent article on EDTA removal from aqueous solutions using elemental iron (Fe(0)) by O. Gyliene and his co-workers. It is shown that the authors have furnished a brilliant validation of the concept that dissolved contaminants are primary removed in Fe(0)/H(2)O systems by adsorption onto iron corrosion products and co-precipitation with iron corrosion products. It is reiterated that "contaminant removal" and "contaminant reduction" should not be interchanged randomly.
    Keywords: Adsorption; Co-precipitation; EDTA; Iron corrosion; Zerovalent iron; ; 551
    Language: English
    Type: article , submittedVersion
    Format: 7
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  • 69
    Publication Date: 2021-03-29
    Description: The intrinsic reactivity of four metallic iron materials (Fe0) was investigated in batch and column experiments. The Fe0 reactivity was characterized by the extent of aqueous fixation of in-situ leached arsenic (As). Air-homogenized batch experiments were conducted for 1 month with 10.0 g/ℓ of an As-bearing rock (ore material) and 0.0 or 5.0 g/ℓ of Fe0. Column experiments were performed for 2 and 3 months. Each dynamic experiment was made up of 2 glass columns in series. The first column contained 2.5 or 5.0 g of the ore material and the second column 0.0 or 5.0 g of a Fe0 material. Results showed no significant reactivity difference in batch studies for all 4 materials, ZVI2 was by far the most reactive material in column experiments. This observation was attributed to the relative kinetics of production of aqueous As and Fe species under the experimental conditions and their impact on the formation of a protective film on Fe0. Accordingly, no protective film could be built at the surface of the least reactive materials. The results corroborated the urgent need for unified experimental procedures to characterize Fe0 materials.
    Keywords: Column study; Intrinsic reactivity; Ore mineral; Water treatment; Zerovalent iron ; 551
    Language: English
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  • 70
    Publication Date: 2021-04-25
    Description: During the last few years, the analysis of microbial diversity in various habitats greatly increased our knowledge on the kingdom Archaea. At the same time, we became aware of the multiple ways in which Archaea may interact with each other and with organisms of other kingdoms. The large group of euryarchaeal methanogens and their methane oxidizing relatives, in particular, take part in essential steps of the global methane cycle. Both of these processes, which are in reverse to each other, are partially conducted in a symbiotic interaction with different partners, either ciliates and xylophagous animals or sulfate reducing bacteria. Other symbiotic interactions are mostly of unknown ecological significance but depend on highly specific mechanisms. This paper will give an overview on interactions between Archaea and other organisms and will point out the ecological relevance of these symbiotic processes, as long as these have been already recognized.
    Keywords: Archaea; Symbioses; ; 551
    Language: English
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  • 71
    Publication Date: 2021-03-29
    Description: Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.
    Keywords: Sandstones; Pore space; Prediction; Weathering behavior; Compressive strength ; 551 ; Earth Sciences; Geology
    Language: English
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  • 72
    Publication Date: 2021-03-29
    Description: Attenuation of micro-contaminants is a very complex field in environmental science and evidence suggests that biodegradation rates of micro-contaminants in the aqueous environment depend on the water matrix. The focus of the study presented here is the systematic comparison of biotransformation rates of caffeine, carbamazepine, metoprolol, paracetamol and valsartan in river water microcosms spiked with different proportions of treated effluent (0%, 0.1%, 1%, and 10%). Biotransformation was identified as the dominating attenuation process by the evolution of biotransformation products such as atenolol acid and valsartan acid. Significantly decreasing biotransformation rates of metoprolol were observed at treated effluent proportions ≥0.1% whereas significantly increasing biotransformation rates of caffeine and valsartan were observed in the presence of 10% treated effluent. Potential reasons for the observations are discussed and the addition of adapted microorganisms via the treated effluent was suggested as the most probable reason. The impact of additional phosphorus on the biodegradation rates was tested and the experiments revealed that phosphorus-limitation was not responsible.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: biodegradation; pharmaceuticals; caffeine; river water; treated effluent; valsartan acid ; 551
    Language: English , English
    Type: article , publishedVersion
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  • 73
    Publication Date: 2021-03-29
    Description: A high-resolution multiproxy geochemical approach was applied to the sediments of Laguna Potrok Aike in an attempt to reconstruct moist and dry periods during the past 16 000 years in southeastern Patagonia. The age–depth model is inferred from AMS 14C dates and tephrochronology, and suggests moist conditions during the Lateglacial and early Holocene (16 000–8700 cal. BP) interrupted by drier conditions before the beginning of the Holocene (13 200–11 400 cal. BP). Data also imply that this period was a major warm phase in southeastern Patagonia and was approximately contemporaneous with the Younger Dryas chronozone in the Northern Hemisphere (12 700–11 500 cal. BP). After 8650 cal. BP a major drought may have caused the lowest lake level of the record. Since 7300 cal. BP, the lake level rose and was variable until the ‘Little Ice Age’, which was the dominant humid period after 8650 cal. BP.
    Keywords: Holocene ; Younger Dryas ; Lateglacial ; `Little Ice Age' ; lacustrine sediments ; geochemistry ; tephrochronology ; multiproxy approach ; Patagonia ; Argentina. ; 551
    Language: English
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  • 74
    Publication Date: 2021-03-29
    Description: The spatio-temporal variability of trends in vegetation greenness in dryland areas is a well-documented phenomenon in remote sensing studies at global to regional scales. The underlying causes differ, however, and are often not well understood. Here, we analyzed the trends in vegetation greenness for a semi-arid area in northeastern Brazil (NEB) and examined the relationships between those dynamics and climate anomalies, namely the El Nino Southern Oscillation (ENSO) for the period 1982 to 2010, based on annual Normalized Difference Vegetation Index (NDVI) values from the latest version of the Global Inventory Modeling and Mapping Studies (GIMMS) NDVI dataset (NDVI3g) dataset. Against the ample assumption of ecological and socio-economic research, the results of our inter-annual trend analysis of NDVI and precipitation indicate large areas of significant greening in the observation period. The spatial extent and strength of greening is a function of the prevalent land-cover type or biome in the study area. The regression analysis of ENSO indicators and NDVI anomalies reveals a close relation of ENSO warm events and periods of reduced vegetation greenness, with a temporal lag of 12 months. The spatial patterns of this relation vary in space and time. Thus, not every ENSO warm event is reflected in negative NDVI anomalies. Xeric shrublands (Caatinga) are more sensitive to ENSO teleconnections than other biomes in the study area.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: NDVI3g; GIMMS; AVHRR; El Nino; inter-annual trends; teleconnections ; 551
    Language: English
    Type: article , publishedVersion
    Format: 18
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  • 75
    Publication Date: 2021-03-29
    Description: The relation of two well-known ancient carbonate deposits to hydrocarbon seepage was confirmed by this study. Archaea are found to be associated with the formation of Oxfordian seep carbonates from Beauvoisin and with a Miocene limestone from Marmorito ("tube-worm limestone"). Carbonates formed due to a mediation by archaea exhibit extremely positive or extremely negative 813Ccarbonate values, respectively. Highly positive values (+ 15%0) reflect the use of 13C-enriched CO2 produced by methanogenesis. Low 813C values of the Marmorito carbonates (-30%0) indicate the oxidation of seepagederived hydrocarbons. Likewise, the 813C content of specific tail-to-tail linked isoprenoids, biomarkers for archaea, was found to be strikingly depleted in these sampies (as low as -115%0). The isotopic signatures corroborate that archaea were involved in the cycling of seepage-derived organic carbon at the ancient localities. Another Miocene limestone ("Marmorito li mestone") shows a strong imprint of methanotrophic bacteria as indicated by 813C va lues of carbonate as low J. Peckmann (IEI) . J. Reitner Institut und Museum für Geologie und Paläontologie, Georg-August-Universität. Goldschmidtstrasse 3, D-37077 Göttingen, Germany e-mail: jpeckma@gwdg.de. Fax: + 49-551-397918 V. Thiel, W. Michaelis Institut für Biogeochemie und Meereschemie, Universität Hamburg, Bundesstrasse 55, D-20146 Hamburg, Germany P. Clari, L. Martire Dipartimento di Scienze della Terra, via Accademia delle Scienze 5, 1-10123 Torino, Italy C. Gaillard UFR des Sciences de la Terre, UMR 5565 Centre de Paleontologie stratigraphique et Paleoecologie, Universite Claude Bemard, Lyon 1, 27-43 Boulevard du 11 Novembre, F-69622 Villeurbanne Cedex, France as -40%0 and biomarker evidence. Epifluorescence microscopy and field-emission scanning electron microscopy revealed that bacterial biofilms were involved in carbonate aggregation. In addition to lucinid bivalves previously reported from both localities, we infer that sponges from Beauvoisin and tube worms from Marmorito depended on chemosynthesis as weil. Low 813C values of nodules related to sponge taphonomy (-27%0) indicate that sponges might have been Iinked to an enhanced hydrocarbon oxidation. Tube worm fossils from Marmorito closely resemble chemosynthetic pogonophoran tube worms from Recent cold seeps and are embedded in isotopically light carbonate (813C -300/00).
    Keywords: Paläontologie: Allgemeines ; 551 ; VU 000 ; 38.20 ; 38.2
    Language: English
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  • 76
    Publication Date: 2021-03-29
    Description: Widefield deconvolution epifluorescence microscopy (WDEM) combined with fluorescence in situ hybridization (FISH) was performed to identify and characterize single bacterial cells within sections of the mediterranean sponge Chondrosia reniformis. Sponges were embedded in paraffin wax or plastic prior to the preparation of thin sections, in situ hybridization and microscopy. Serial digital images generated by widefield epifluorescence microscopy were visualized using an exhaustive photon reassignment deconvolution algorithm and three-dimensional rendering software. Computer processing of series of images taken at different focal planes with the deconvolution technique provided deblurred three-dimensional images with high optical resolution on a submicron scale. Results from the deconvolution enhanced widefield microscopy were compared with conventional epifluorescent microscopical images. By the application of the deconvolution algorithm on digital image data obtained with widefield epifluorescence microscopy after FISH, the occurrence and spatial arrangement of Desulfovibrionaceae closely associated with micropores of Chondrosia reniformis could be visualized.
    Keywords: Widefield deconvolution epifluorescence microscopy; FISH; 16S rRNA oligonucleotide probes; Sponge associated bacteria; Chondrosia reniformis ; 551
    Language: English
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  • 77
    Publication Date: 2021-03-29
    Description: A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.
    Description: Open-Access-Publikationsfonds 2015
    Keywords: sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics ; 551
    Language: English , English
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  • 78
    Publication Date: 2021-03-29
    Description: Lower Saxony, with a total land area of about 46 500 km2, constitutes one of the most important agricultural areas in Germany and thus within Europe. Roughly one third of its agricultural area is used for maize cultivation and as of today only few information exist on how a future changing climate will affect its local growing conditions. Thus the newly developed carbon-based crop model BioSTAR and a high-resolution regional climate data-set (Wettreg) were used to evaluate the change in biomass yields of an early, medium and late maize variety. The climate input data is based on the SRES A1B scenario, with a potential fertilization effect or better still, an increased water use efficiency due to rising CO2 levels, taken into account. The biomass yield for all varieties was calculated for each year from 2001 until 2099 on a total of 91 014 sites. The results suggest clearly differentiated development paths of all varieties. All three show a significant positive trend until the end of the century. However the medium variety shows a statistical significant decline of 5% during the first 30 years and only a slight recovery towards +5% around the century's end. The late variety has the clearest and strongest positive trend, with partially more than 30% increase of biomass yields around the end of the century or +25% mean increase in the last three decades. The early variety can be seen as in-between, with no negative but also not an as strong positive development path. All varieties have their strongest increase in yields after the mid of the 21st century. Statistical evaluation of these results suggests that the shift from a summer rain to a winter rain climate in Germany will be the main limiting factor for all varieties. In addition summer temperatures will become less optimal for all maize crops. Only if the plants can supply themselves sufficiently with water outside of the increasingly dry summer months, when also temperatures are much more favorable, an increase in biomass yields is feasible. As the data suggests the increasing atmospheric CO2 concentrations will play a critical role in reducing the crops water uptake, thus enabling yield increases in the first place.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: Lower Saxony; Maize varieties; climate; Biomass yield development ; 551
    Language: English
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  • 79
    Publication Date: 2021-03-29
    Description: As has been demonstrated in recent years, the heterogeneities of coeval magmas can be more successfully revealed by zoned megacrysts rather than by analysis of the whole rocks hosting them. Here, the geochemical heterogeneities of feldspar megacrysts from the Karkonosze granite, Poland, are investigated by LA-ICP-MS. The crystals are the product of migration and growth in regions of poorly mixed magmas. 3D-modeling of the Ba, Sr, and Rb distributions emphasizes the importance of micro-domain growth morphologies. Two models of element behavior—a relative concentration model and a composition gradient model—provide a potentially effective tool for tracking the mixing process on a microscale. Measured concentrations of elements of different mobilities do not agree with what might be expected from the mixing of two end-member magmas. If mixing was the only process occurring, linear correlations between the concentrations of any two elements should be observed; this, however, is not the case. For combinations of any two of the three elements, modeling reveals differing non-linear correlations between concentrations. The megacryst heterogeneities provide an insight into how mixing magmas are chaotically advected to growing crystals and the degree of inter-magma element exchange between the magmas.
    Keywords: Mixing; Element mobility; Diffusion; Alkali feldspar; 3D-depiction; Cut-off value models; Gradient models; Probabilistic models; Geochemical heterogeneity; Karkonosze granite ; 551
    Language: English
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  • 80
    Publication Date: 2021-03-29
    Description: The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.
    Keywords: Neutron diffraction; Lattice-preferred orientation; Shape-preferred orientation; Magmatic flow; Podlesí granite; Meissen Massif ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 81
    Publication Date: 2021-03-29
    Keywords: loess; loess-like deposits; Pleistocene; Weichselian; spatial analysis; NW Germany ; 551
    Language: English
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  • 82
    Publication Date: 2021-03-29
    Description: The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580–510 Ma) Pampean, the late Cambrian–Ordovician (500–440 Ma) Famatinian and the Devonian-Carboniferous (400–350 Ma) Achalian orogenies. Geochronological and Sm–Nd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm–Nd results for the metamorphic basement suggest that the TDM age interval of 1.8–1.7 Ga, which is associated with the less radiogenic values of εNd(540) (−6 to −8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger TDM age and a more positive εNd(540) value. Pampean pre-540 Ma granitoids form two clusters, one with TDM ages between 2.0 and 1.75 Ga and another between 1.6 and 1.5 Ga. Pampean post-540 Ma granitoids exhibit more homogenous TDM ages ranging from 2.0 to 1.75 Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. TDM values for the Ordovician Famatinian granitoids define a main interval of 1.8–1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger TDM ages ranging from 1.3 to 1.0 Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic εNd(540) values that range between 0.5 and −4 and TDM ages younger than 1.3 Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.
    Keywords: Magmatism-metamorphism; Sm–Nd systematics; Tectonic evolution; Neoproterozoic-early Paleozoic orogenies; Eastern Sierras Pampeanas ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 83
    Publication Date: 2021-03-29
    Description: The expansion processes that develop in building stones upon changes of moisture content may be an important contributing factor for their deteriorations. Until recently, few data could be found in the literature concerning this parameter and weathering processes. Moreover, the processes that may be responsible for the moisture related expansion of natural building stones are not yet completely understood. To further elucidate this process, extensive mineralogical, petrophysical and fabric investigations were performed on eight German sandstones in order to obtain more information regarding the weathering process and its dependence on the rock fabric. The analysed sandstones show a wide range of pore size distributions and porosities. A positive correlation with the fabric and the pore space can be found for all studied petrophysical parameters. The intensity of the expansion and related swelling pressure cannot be attributed only to the swelling of clay minerals. The investigations suggest that the micropores and the resulting disjoining pressure during wet/dry cycles also play an important role. The results obtained suggest that the mechanism is related to the presence of liquid water within the porous material.
    Keywords: Sandstone weathering; Moisture expansion; Hygric and hydric wetting; Swelling clay minerals ; 551 ; Earth Sciences; Geology
    Language: English
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  • 84
    facet.materialart.
    Unknown
    Springer-Verlag | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: The profitable production of dimension stone mainly depends on the extractable block size. The regularity and volume of the blocks are of critical importance, and are controlled by the three-dimensional pattern of the discontinuity system. Therefore, optimization of block size has to be the aim when quarrying for natural stone. This is mainly connected to the quantification of joints and fractures, i.e., their spacing and orientation. The problem of finding unfractured blocks within arbitrarily oriented and distributed planes can be solved effectively by a numerical algorithm. The main effects of joint orientations on block sizes and shapes will be presented in this article. Quantification of unfractured blocks with the aim of optimization is illustrated by detailed studies on several quarries. The algorithm used in this study can be applied as a powerful tool in the planning of a quarry and the future exploitation of dimension stone. Application of the described approach is demonstrated on practical examples of quarrying natural stones, namely, sandstone, granite, rhyolite, etc. Block quarrying can be optimized by using the new 3D-BlockExpert approach. The quantification of unfractured rock masses is also shown to contribute to a more ecological protection and the sustainable use of natural resources.
    Keywords: Production of dimension stones; Joints and fractures; Block sizes; Optimization ; 551 ; Earth Sciences; Geology
    Language: English
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  • 85
    Publication Date: 2021-03-29
    Description: Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.
    Keywords: Freeze–thaw action; Natural building stones; Microfabric; Pore space properties ; 551 ; Earth Sciences; Geology
    Language: English
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  • 86
    Publication Date: 2021-03-29
    Description: Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.
    Keywords: Stone decay; Cologne Cathedral; Compatibility of building materials; Requirements for replacement stones ; 551 ; Earth Sciences; Geology
    Language: English
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  • 87
    Publication Date: 2021-03-29
    Keywords: Groundwater; Bangladesh ; 551
    Language: English
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  • 88
    Publication Date: 2021-04-27
    Description: The range of substrates that the bone-eating marine worm Osedax is able to consume has important implications for its evolutionary history, especially its potential link to the rise of whales. Once considered a whale specialist, recent work indicates that Osedax consumes a wide range of vertebrate remains, including whale soft tissue and the bones of mammals, birds and fishes. Traces resembling those produced by living Osedax have now been recognized for the first time in Oligocene whale teeth and fish bones from deep-water strata of the Makah, Pysht and Lincoln Creek formations in western Washington State, USA. The specimens were acid etched from concretions, and details of the borehole morphology were investigated using micro-computed tomography. Together with previously published Osedax traces from this area, our results show that by Oligocene time Osedax was able to colonize the same range of vertebrate remains that it consumes today and had a similar diversity of root morphologies. This supports the view that a generalist ability to exploit vertebrate bones may be an ancestral trait of Osedax.
    Keywords: Deep-sea; Trace fossil; Osedax; Whale; Fish; Micro-CT; Tiefsee; Spurenfossil; Osedax; Wal; Fisch; Micro-CT ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 89
    Publication Date: 2021-03-29
    Description: Despite two decades of intensive laboratory investigations, several aspects of contaminant removal from aqueous solutions by elemental iron materials (e.g., in Fe(0)/H2O systems) are not really understood. One of the main reasons for this is the lack of a unified procedure for conducting batch removal experiments. This study gives a qualitative and semi-quantitative characterization of the effect of the mixing intensity on the oxidative dissolution of iron from two Fe(0)-materials (materials A and B) in a diluted aqueous ethylenediaminetetraacetic solution (2 mM EDTA). Material A (fillings) was a scrap iron and material B (spherical) a commercial material. The Fe(0)/H2O/EDTA systems were shaken on a rotational shaker at shaking intensities between 0 and 250 min(-1) and the time dependence evolution of the iron concentration was recorded. The systems were characterized by the initial iron dissolution rate (k(EDTA)). The results showed an increased rate of iron dissolution with increasing shaking intensity for both materials. The increased corrosion through shaking was also evidenced through the characterization of the effects of pre-shaking time on k(EDTA) from material A. Altogether, the results disprove the popular assumption that mixing batch experiments is a tool to limit or eliminate diffusion as dominant transport process of contaminant to the Fe(0) surface.
    Keywords: Co-precipitation; EDTA; corrosion products; Reactivity; Zerovalent iron ; 551 ; Chelating Agents ; Corrosion ; Edetic Acid ; Iron ; Kinetics ; Metals ; Oxidation-Reduction ; Rotation ; Solubility ; Solutions
    Language: English , English
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  • 90
    Publication Date: 2021-03-29
    Keywords: Thiobencarb; Herbicides; Zero valent iron (ZVI); Removal; Wastewater treatment ; 551 ; Iron ; Magnesium ; Thiocarbamates ; Water Pollutants, Chemical ; Water Purification ; Zinc
    Language: English , English
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  • 91
    Publication Date: 2021-03-29
    Description: Geological mapping and detailed structural investigations combined with geochronological and stratigraphic data, as well as fissiontrack age dating carried out on the northern part of the Pelagonian basement and the adjacent Vardar/Axios sedimentary and metamorphic sequences in the Hellenic Alps (northwestern Greece and Former Yugoslavian Republic of Macedonia) allow us to reconstruct the geometry, kinematics and deformation history of the Pelagonian nappe pile during the Alpine orogeny. We distinguish seven deformational events (D and D to D ). Deformation started in Middle to Late Jurassic time and was associated with inneroceanic HP 1 6 thrusting, ophiolite obduction, and NW- to WNW-directed nappe stacking of the Lower and Upper Pelagonian unit (D ). The lower unit 1 was metamorphosed under greenschist to amphibolite facies conditions with relatively high pressures (T=450-620°C, P=8-12,5 kb). Blueschist-facies metamorphic assemblages (D , T=450-500°C, P〉12,5 kb) are restricted to the boundary zone between both Pela- HP gonian units. Transgressive Late Jurassic to Early Cretaceous shallow-water limestones and clastic sediments on top of the obducted ophiolites are probably related to extension and basin formation simultaneously with nappe stacking and metamorphism in the Pelagonian nappes beneath. Contractional tectonics with the same kinematics as during D continued in Aptian-Albian time and was asso- 1 ciated with intense retrogression (D , T=280-380°C, P=4-5 kb). Low-angle mylonitic extensional shear zones of low-grade metamor- 2 phism with top-to-NE sense of movement (D ) developed simultaneously with basin formation and sedimentation of shallow-water 3 limestones and flysch-like sediments in Late Cretaceous to Paleocene times. Intense imbrication under semi-ductile to brittle conditions of all tectonic units occurred during Paleocene to Eocene time with SW-directed movement towards the foreland (D ). A large 4 Pelagonian antiformal structure formed during D shortening. In Oligocene to recent time, D and D created brittle low- and high- 4 5 6 angle normal faults, respectively.
    Description: Im nördlichen Teil des Pelagonischen Kristallins und in den metamorphen und sedimentären Gesteinsfolgen der angrenzenden Vardar/Axios-Zone der Helleniden (NW-Griechenland und Frühere Jugoslawische Republik Mazedonien) wurde eine geologische Kartierung und ausführliche strukturgeologische Untersuchungen durchgeführt. Verbunden mit geochronologischen und stratigraphischen Daten erlauben unsere Ergebnisse, die Geometrie, Kinematik und Deformationsgeschichte des pelagonischen Deckenlandes während der alpidischen Gebirgsbildung zu rekonstruieren. Wir haben sieben Deformationsereignisse (D und D bis D ) HP 1 6 unterschieden. Die Deformationsgeschichte begann im Mittleren bis Späten Jura mit intra-ozeanischer Überschiebung, Ophiolith- Obduktion und NW- bis WNW-gerichteter Deckenstapelung der Unteren und Oberen Pelagonischen Einheit (D ). Die untere Einheit 1 wurde unter den Bedingungen der Grünschiefer- bis Amphibolitfazies bei relativ hohem Druck metamorph überprägt (T 450-620°C, P 8-12,5 kb). Blauschieferfazielle Paragenesen sind in der tektonischen Kontaktzone zwischen den beiden pelagonischen Einheiten erhalten (D : T 450-500°C, P 〉12,5 kb). Transgressiv auf obduzierten Ophiolithen abgelagerte oberjurassische bis unterkretazische HP Flachwasserkalke und klastische Sedimente sind wahrscheinlich mit Extension und Beckenbildung im obersten Krustenstockwerk und gleichzeitiger Deckenstapelung und Metamorphose in den unteren pelagonischen Decken verbunden. Im Aptium-Albium setzte sich die Einengungstektonik mit derselben Kinematik wie während D fort und ging mit intensiver retrograder Metamorphose einher 1 (D : T 280-380°C, P 4-5 kb). Flach einfallende mylonitische Abscherungszonen, die unter schwachen grünschieferfaziellen Metamor- 2 phosebedingungen NE-gerichteten Schersinn anzeigen (D ), entwickelten sich während der Oberen Kreide und des Paleozäns, 3 gleichzeitig mit Beckenbildung und Sedimentation von Flachwasserkalken und Flysch. Intensive Verkürzung und Imbrikation aller tektonischen Einheiten (D ) fand unter semiduktilen bis spröden Bedingungen und nach SW (gegen das Vorland) gerichteter Haupt- 4 bewegung während des Paleozäns bis Eozäns statt. Eine große Antiform bildete sich im Pelagonikum während dieser Einengungsphase. Vom Oligozän bis heute bildeten sich spröde, flach oder steil geneigte Abschiebungen (D und D ) 5 6 _______________________________________________________________________________ .
    Keywords: Vardar/Axios Zone; Pelagonian nappe; compression; Hellenides; extension ; 551
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  • 92
    Publication Date: 2021-03-29
    Description: Ice in polar ice sheets undergoes deformation during its flow towards the coast. Deformation and recrystallization microstructures such as subgrain boundaries can be observed and recorded using high-resolution light microscopy of sublimation-edged sample surfaces (microstructure mapping). Subgrain boundaries observed by microstructure mapping reveal characteristic shapes and arrangements. As these arrangements are related to the basal plane orientation, full crystallographic orientation measurements are needed for further characterization and interpretation of the subgrain boundary types. X-ray Laue diffraction measurements validate the sensitivity of different boundary types with sublimation used by microstructure mapping for the classification. X-ray Laue diffraction provides misorientation values of all four crystal axes. Line scans across a subgrain boundary pre-located by microstructure mapping can determine the rotation axis and angle. Together with the orientation of the subgrain boundary this yields information on the dislocation types. Tilt and twist boundaries composed of dislocations lying in the basal plane, and tilt boundaries composed of nonbasal dislocations were found. A statistical analysis shows that nonbasal dislocations play a significant role in the formation of all subgrain boundaries.
    Keywords: Subgrain boundaries; Antarctic, Ice; X-ray; diffraction ; 551
    Language: English
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  • 93
    Publication Date: 2021-03-29
    Keywords: Uranyl(VI) hydrolysis; Time-resolved laser-induced fluorescence spectroscopy; Speciation; Relative fluorescence yield ; 551
    Language: English
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  • 94
    Publication Date: 2021-03-29
    Keywords: Contaminant removal; Point of use; Safe water; Water filtration; Zerovalent iron ; 551
    Language: English
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  • 95
    Publication Date: 2021-03-29
    Description: A central aspect of the contaminant removal by elemental iron materials (Fe0 or Fe0 materials) is that reduction reactions are mediated by the iron surface (direct reduction). This premise was introduced by the pioneers of the reactive wall technology and is widely accepted by the scientific community. In the meantime enough evidence has been provided to suggest that contaminant reduction through primary corrosion products (secondary reductants) does indeed occur (indirect reduction). It was shown for decades that iron corrosion in the pH range of natural waters (4-9) inevitably yields an obstructive oxide film of corrosion products at the metal surface (oxide film). Therefore, contaminant adsorption on to corrosion products and contaminant co-precipitation with corrosion products inevitably occurs. For adsorbed and coprecipitated contaminants to be directly reduced the oxide film should be electronic conductive. This study argues through a literature review a series of points which ultimately lead to the conclusion that, if any quantitative contaminant reduction occurs in the presence of Fe0 materials, it takes place within the matrix of corrosion products and is not necessarily a direct reduction. It is concluded that Fe0 materials act both as source of corrosion products for contaminant adsorption/coprecipitation and as a generator of FeII and H2 (H) for possible catalytic contaminant reduction.
    Keywords: Adsorption; Co-precipitation; Elemental Iron; Groundwater; Remediation ; 551 ; Adsorption ; Corrosion ; Iron ; Oxidation-Reduction ; Water ; Water Pollutants
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  • 96
    Publication Date: 2021-03-29
    Description: Indentation of rigid blocks into rheologically weak orogens is generally associated with spatiotemporally variable vertical and lateral block extrusion. The European Eastern and Southern Alps are a prime example of microplate indentation, where most of the deformation was accommodated north of the crustal indenter within the Tauern Window. However, outside of this window only the broad late-stage exhumation pattern of the indented units as well as of the indenter itself is known. In this study we refine the exhumational pattern with new (U–Th–Sm)/He and fission-track thermochronology data on apatite from the Karawanken Mountains adjacent to the eastern Periadriatic fault and from the central-eastern Southern Alps. Apatite (U–Th–Sm)/He ages from the Karawanken Mountains range between 12 and 5 Ma and indicate an episode of fault-related exhumation leading to the formation of a positive flower structure and an associated peripheral foreland basin. In the Southern Alps, apatite (U–Th–Sm)/He and fission-track data combined with previous data also indicate a pulse of mainly Late Miocene exhumation, which was maximized along thrust systems, with highly differential amounts of displacement along individual structures. Our data contribute to mounting evidence for widespread Late Miocene tectonic activity, which followed a phase of major exhumation during strain localization in the Tauern Window. We attribute this exhumational phase and more distributed deformation during Adriatic indentation to a major change in boundary conditions operating on the orogen, likely due to a shift from a decoupled to a coupled system, possibly enhanced by a shift in convergence direction.
    Keywords: Southern and Eastern Alps; Low-temperature thermochronology; Adria indentation; Exhumation ; 551
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  • 97
    Publication Date: 2021-03-29
    Description: The Toba eruption that occurred some 74 ka ago in Sumatra, Indonesia, is among the largest volcanic events on Earth over the last 2 million years. Tephra from this eruption has been spread over vast areas in Asia, where it constitutes a major time marker close to the Marine Isotope Stage 4/5 boundary. As yet, no tephra associated with Toba has been identified in Greenland or Antarctic ice cores. Based on new accurate dating of Toba tephra and on accurately dated European stalagmites, the Toba event is known to occur between the onsets of Greenland interstadials (GI) 19 and 20. Furthermore, the existing linking of Greenland and Antarctic ice cores by gas records and by the bipolar seesaw hypothesis suggests that the Antarctic counterpart is situated between Antarctic Isotope Maxima (AIM) 19 and 20. In this work we suggest a direct synchronization of Greenland (NGRIP) and Antarctic (EDML) ice cores at the Toba eruption based on matching of a pattern of bipolar volcanic spikes. Annual layer counting between volcanic spikes in both cores allows for a unique match. We first demonstrate this bipolar matching technique at the already synchronized Laschamp geomagnetic excursion (41 ka BP) before we apply it to the suggested Toba interval. The Toba synchronization pattern covers some 2000 yr in GI-20 and AIM- 19/20 and includes nine acidity peaks that are recognized in both ice cores. The suggested bipolar Toba synchronization has decadal precision. It thus allows a determination of the exact phasing of inter-hemispheric climate in a time interval of poorly constrained ice core records, and it allows for a discussion of the climatic impact of the Toba eruption in a global perspective. The bipolar linking gives no support for a long-term global cooling caused by the Toba eruption as Antarctica experiences a major warming shortly after the event. Furthermore, our bipolar match provides a way to place palaeoenvironmental records other than ice cores into a precise climatic context.
    Keywords: Greenland; Antarctic ice cores; Toba eruption ; 551
    Language: English
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  • 98
    Publication Date: 2021-03-29
    Description: This letter challenges the concept that the metallic iron (Fe0) surface contributes directly to the process of micro-organism inactivation in aqueous solutions. It is shown that any antimicrobial properties of Fe0 is related to the cycle of expansion/contraction accompanying aqueous iron corrosion. This demonstration corroborates the concept that aqueous contaminant removal in the presence of Fe0 mostly occurs at the Fe-oxide/water interface or within the oxide-film on Fe0.
    Keywords: Adsorption; Antimicrobial agent; Co-precipitation; Zerovalent iron ; 551
    Language: English
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  • 99
    Publication Date: 2021-03-29
    Description: Zerovalent iron (ZVI) has been proposed as reactive material in permeable in-situ walls for contaminated groundwater. An economically feasible ZVI reactive wall requires cheap but efficient iron materials. From an uranium treatability study and results of iron dissolution in 0.002 M EDTA by five selected ZVI materials, it is shown that current research and field implementation is not based on a rational selection of application-specific iron metal sources. An experimental procedure is proposed which could enable a better material characterization. This procedure consists in mixing ZVI materials and reactive additives including contaminant releasing materials (CRM) in long term batch experiments and characterise the contaminant concentration over the time.
    Keywords: contaminant; groundwater; in-situ remediation; zerovalent iron; uranium ; 551
    Language: English
    Type: article , submittedVersion
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  • 100
    Publication Date: 2021-03-29
    Description: Forests in lowland Bolivia suffer from severe deforestation caused by different types of agents and land use activities. We identify three major proximate causes of deforestation. The largest share of deforestation is attributable to the expansion of mechanized agriculture, followed by cattle ranching and small-scale agriculture. We utilize a spatially explicit multinomial logit model to analyze the determinants of each of these proximate causes of deforestation between 1992 and 2004. We substantiate the quantitative insights with a qualitative analysis of historical processes that have shaped land use patterns in the Bolivian lowlands to date. Our results suggest that the expansion of mechanized agriculture occurs mainly in response to good access to export markets, fertile soil, and intermediate rainfall conditions. Increases in small-scale agriculture are mainly associated with a humid climate, fertile soil, and proximity to local markets. Forest conversion into pastures for cattle ranching occurs mostly irrespective of environmental determinants and can mainly be explained by access to local markets. Land use restrictions, such as protected areas, seem to prevent the expansion of mechanized agriculture but have little impact on the expansion of small-scale agriculture and cattle ranching. The analysis of future deforestation trends reveals possible hotspots of future expansion for each proximate cause and specifically highlights the possible opening of new frontiers for deforestation due to mechanized agriculture. Whereas the quantitative analysis effectively elucidates the spatial patterns of recent agricultural expansion, the interpretation of long-term historic drivers reveals that the timing and quantity of forest conversion are often triggered by political interventions and historical legacies.
    Keywords: Bolivia; Amazon; Deforestation; Proximate causes; Spatial analysis; Multinomial logistic regression ; 551 ; Environment; Geology; Geography (general); Regional/Spatial Science; Climate Change; Nature Conservation; Oceanography
    Language: English
    Type: article , publishedVersion
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