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  • ddc:551.9  (32)
  • ddc:551  (29)
  • ddc:550.78  (7)
  • ddc:551.46  (7)
  • English  (75)
  • Russian
  • 2020-2023  (75)
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  • 1
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    Nitrogen and Phosphorus Control Soil Methane Uptake in Tropical Montane Forests (2021)
    Details
    Publication Date: 2022-04-04
    Description: Tropical forests contribute about one third to global annual CH4 uptake by soils. Understanding the factors that control the soil‐atmosphere exchange of CH4 at a large scale is a critical step to improve the CH4 flux estimate for tropical soils, which is presently poorly constrained. Since tropical forest degradation often involves shifts in nutrient availabilities, it is critical to evaluate how this will affect soil CH4 flux. Here, we report how nitrogen (N; 50 kg N ha−1 yr−1), phosphorus (P; 10 kg P ha−1 yr−1), and combined N + P additions affect soil CH4 fluxes across an elevation gradient of tropical montane forests. We measured soil CH4 fluxes in a nutrient application experiment at different elevations over a period of 5 years. Nutrient additions increased soil CH4 uptake after 4–5 years of treatment but effects were not uniform across elevations. At 1,000 m, where total soil P was high, we detected mainly N limitation of soil CH4 uptake. At 2,000 m, where total soil P was low, a strong P limitation of soil CH4 uptake was observed. At 3,000 m, where total P was low in the organic layer but high in mineral soil, we found N limitation of soil CH4 uptake. Our results show that projected increases of N and P depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrient status and plant‐microbial competition for N and P.
    Description: Plain Language Summary: CH4 is a potent greenhouse gas that contributes to global warming. Tropical forests are a natural sink of CH4 but increasing nutrient depositions due to industrialization may alter the sink strength of tropical forests. Our results show that projected increases of nitrogen and phosphorus depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrients and plant‐microbial competition.
    Description: Key Points: Projected increases in nitrogen and phosphorus depositions in the tropics will stimulate soil methane uptake in tropical montane forests. The direction, magnitude, and timing of nutrient deposition effects on soil methane uptake will depend on forests' nutrient status. Nutrient limitations on ecosystem processes have to be investigated in actual field conditions.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.25625/XLNKNK
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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  • 2
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    Focused methane migration formed pipe structures in permeable sandstones: Insights from uncrewed aerial vehicle‐based digital outcrop analysis in Varna, Bulgaria (2021)
    Details
    Publication Date: 2022-04-04
    Description: Focused fluid flow shapes the evolution of marine sedimentary basins by transferring fluids and pressure across geological formations. Vertical fluid conduits may form where localized overpressure breaches a cap rock (permeability barrier) and thereby transports overpressured fluids towards shallower reservoirs or the surface. Field outcrops of an Eocene fluid flow system at Pobiti Kamani and Beloslav Quarry (ca 15 km west of Varna, Bulgaria) reveal large carbonate‐cemented conduits, which formed in highly permeable, unconsolidated, marine sands of the northern Tethys Margin. An uncrewed aerial vehicle with an RGB sensor camera produces ortho‐rectified image mosaics, digital elevation models and point clouds of the two kilometre‐scale outcrop areas. Based on these data, geological field observations and petrological analysis of rock/core samples, fractures and vertical fluid conduits were mapped and analyzed with centimetre accuracy. The results show that both outcrops comprise several hundred carbonate‐cemented fluid conduits (pipes), oriented perpendicular to bedding, and at least seven bedding‐parallel calcite cemented interbeds which differ from the hosting sand formation only by their increased amount of cementation. The observations show that carbonate precipitation likely initiated around areas of focused fluid flow, where methane entered the formation from the underlying fractured subsurface. These first carbonates formed the outer walls of the pipes and continued to grow inward, leading to self‐sustaining and self‐reinforcing focused fluid flow. The results, supported by literature‐based carbon and oxygen isotope analyses of the carbonates, indicate that ambient seawater and advected fresh/brackish water were involved in the carbonate precipitation by microbial methane oxidation. Similar structures may also form in modern settings where focused fluid flow advects fluids into overlying sand‐dominated formations, which has wide implications for the understanding of how focusing of fluids works in sedimentary basins with broad consequences for the migration of water, oil and gas.
    Description: Integrated School of Ocean Sciences (ISOS) Kiel
    Description: European Union’s Horizon 2020 http://dx.doi.org/10.13039/100010661
    Description: Bulgarian Science Fund
    Keywords: ddc:551
    Language: English
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  • 3
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    Iron Exports From Catchments Are Constrained by Redox Status and Topography (2022)
    Details
    Publication Date: 2022-04-04
    Description: Fe(III) hydroxides stabilize organic carbon (OC) and P in soils. Observations of rising stream Fe concentrations are controversially posited to result from a flushing of iron‐rich deeper soil layers or a decrease of competing electron acceptors inhibiting Fe reduction (NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and SO42− $\mathrm{S}{{\mathrm{O}}_{4}}^{2-}$). Here, we argue that catchment topography constrains the release of Fe, OC, and P to streams. We therefore incubated organic topsoil and mineral subsoil and modified the availability of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$. We found that Fe leaching was highest in topsoil. Fe, OC, and P released at quantities proportional to their ratios in the source soil. Supply of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ reduced Fe leaching to 18% and increased pore water OC:Fe and P:Fe ratios. Subsoil, however, was an insignificant Fe source (〈0.5%). Here, the leached quantities of Fe, OC and P were highly disproportionate to the soil source with an excess of released OC and P. We tested if experimental findings scale up using data from 88 German catchments representing gradients in NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ concentration and topography. Average stream Fe concentrations increased with decreasing NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and were high in catchments with shallow topography where high groundwater levels support reductive processes and topsoils are hydrologically connected to streams; but Fe concentrations were low in catchments with steep topography where flow occurs primarily through subsoils. OC:Fe and P:Fe ratios in the streams similarly varied by NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and topography. This corroborates the findings from the laboratory experiment and suggests that catchment topography and competing electron acceptors constrain the formation of Fe‐reducing conditions and control the release of Fe, OC, and P to streams.
    Description: Plain Language Summary: Iron is the second most abundant metal in the crust; its cycle is tightly connected to those of carbon, oxygen, and sulfur. The oxidized form (FeIII) is almost insoluble, but Fe can be mobilized by complexation or microbial Fe reduction. Both processes depend on availability of organic C. We found that Fe concentrations in streams were constrained by the topography of catchments and NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ abundance. Shallower catchments are characterized by higher groundwater tables connecting the organic topsoils efficiently to streams. NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ suppresses Fe reduction as a competing electron acceptor to Fe. We conclude that trends in soil wetness or atmospheric N deposition can change the stability of Fe and thus the release of PO43− $\mathrm{P}{{\mathrm{O}}_{4}}^{3-}$ and harmful metals to surface waters.
    Description: Key Points: Organic topsoils leach substantial amounts of Fe when incubated in the absence of NO3, a competing electron acceptor that inhibits Fe reduction. Shallow catchments with fluvially coupled topsoils and low NO3 availability release 200 fold more Fe than steep ones with high NO3 abundance. Catchment topography and NO3 availability explain 62%–64% of the variability of Fe concentration and OC:Fe and P:Fe ratios across 88 streams.
    Description: EFRE‐Europe
    Description: https://doi.org/10.4211/hs.43601618877945c5a46b715aa98db729
    Keywords: ddc:551.9
    Language: English
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  • 4
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    Carbon Dioxide and Methane Release Following Abrupt Thaw of Pleistocene Permafrost Deposits in Arctic Siberia (2021)
    Details
    Publication Date: 2022-04-07
    Description: The decomposition of thawing permafrost organic matter (OM) to the greenhouse gases (GHG) carbon dioxide (CO2) and methane forms a positive feedback to global climate change. Data on in situ GHG fluxes from thawing permafrost OM are scarce and OM degradability is largely unknown, causing high uncertainties in the permafrost‐carbon climate feedback. We combined in situ CO2 and methane flux measurements at an abrupt permafrost thaw feature with laboratory incubations and dynamic modeling to quantify annual CO2 release from thawing permafrost OM, estimate its in situ degradability and evaluate the explanatory power of incubation experiments. In July 2016 and 2019, CO2 fluxes ranged between 0.24 and 2.6 g CO2‐C m−2 d−1. Methane fluxes were low, which coincided with the absence of active methanogens in the Pleistocene permafrost. CO2 fluxes were lower three years after initial thaw after normalizing these fluxes to thawed carbon, indicating the depletion of labile carbon. Higher CO2 fluxes from thawing Pleistocene permafrost than from Holocene permafrost indicate OM preservation for millennia and give evidence that microbial activity in the permafrost was not substantial. Short‐term incubations overestimated in situ CO2 fluxes but underestimated methane fluxes. Two independent models simulated median annual CO2 fluxes of 160 and 184 g CO2‐C m−2 from the thaw slump, which include 25%–31% CO2 emissions during winter. Annual CO2 fluxes represent 0.8% of the carbon pool thawed in the surface soil. Our results demonstrate the potential of abrupt thaw processes to transform the tundra from carbon neutral into a substantial GHG source.
    Description: Plain Language Summary: Thawing of permanently frozen soils (permafrost) in the northern hemisphere forms a threat to global climate since these soils contain large amounts of frozen organic carbon, which might be decomposed to the greenhouse gases (GHGs) carbon dioxide (CO2) and methane upon thaw. How fast these GHGs are produced is largely unknown, since field observations of greenhouse gas fluxes from thawing permafrost are too sparse. Consequently, simulations on the effect of thawing permafrost soils on future climate are highly uncertain. We measured CO2 and methane fluxes from soils affected by abrupt permafrost thaw in Siberia during two summer seasons. We used these field observations and long‐term incubation data to calibrate two models that simulate the CO2 release over a whole year. We found that greenhouse gas fluxes were dominated by CO2 and that the minor importance of methane was due to the absence of methane producing microorganisms in the Pleistocene permafrost. The CO2 release in the first year accounted for 0.8% of thawed permafrost carbon but decomposition rates decreased after the depletion of the rapidly decomposable organic matter. Abrupt permafrost thaw turned the tundra into a substantial source of CO2, of which 25%–31% was released in the non‐growing season.
    Description: Key Points: Abrupt permafrost thaw turned the tundra into a substantial annual source of CO2 of which 25%–31% were released in the non‐growing season. About 0.8% of thawed permafrost carbon was decomposed to CO2 in one year but decomposition rates declined after the loss of labile carbon. Methane contributed a minor fraction to total greenhouse gas fluxes also because of a low methanogen abundance in Pleistocene permafrost.
    Description: German Ministry for Education and Research
    Description: German Research Foundation
    Description: https://doi.org/10.5281/zenodo.5584710
    Keywords: ddc:551
    Language: English
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  • 5
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    Leaf Wax Hydrogen Isotopes as a Hydroclimate Proxy in the Tropical Pacific (2021)
    Details
    Publication Date: 2022-04-07
    Description: Hydrogen isotope ratios of sedimentary leaf waxes (δ2HWax values) are increasingly used to reconstruct past hydroclimate. Here, we add δ2HWax values from 19 lakes and four swamps on 15 tropical Pacific islands to an updated global compilation of published data from surface sediments and soils. Globally, there is a strong positive linear correlation between δ2H values of mean annual precipitation (δ2HP values) and the leaf waxes n‐C29‐alkane (R2 = 0.74, n = 665) and n‐C28‐acid (R2 = 0.74, n = 242). Tropical Pacific δ2HWax values fall within the predicted range of values based on the global calibration, and the largest residuals from the global regression line are no greater than those observed elsewhere, despite large uncertainties in δ2HP values at some Pacific sites. However, tropical Pacific δ2HWax values in isolation are not correlated with estimated δ2HP values from isoscapes or from isotope‐enabled general circulation models. Palynological analyses from these same Pacific sediment samples suggest no systematic relationship between any particular type of pollen distribution and deviations from the global calibration line. Rather, the poor correlations observed in the tropical Pacific are likely a function of the small range of δ2HP values relative to the typical residuals around the global calibration line. Our results suggest that δ2HWax values are currently most suitable for use in detecting large changes in precipitation in the tropical Pacific and elsewhere, but that ample room for improving this threshold exits in both improved understanding of δ2H variability in plants, as well as in precipitation.
    Description: Plain Language Summary: Past precipitation patterns are difficult to reconstruct, limiting our ability to understand Earth’s climate system. Geochemists reconstruct past precipitation by measuring the amount of heavy hydrogen naturally incorporated into the waxy coating of leaves, which is preserved in mud that accumulates in lakes, soils, and oceans. Heavy hydrogen in leaf waxes is strongly correlated with local precipitation, allowing us to learn about rainfall intensity, temperature, and cloud movement. However, no existing calibration studies include sites from the tropical Pacific, home to the most intense rainfall on the planet and populations that rely on rain for drinking water and farming. We measured heavy hydrogen in leaf waxes from tropical Pacific islands and show that although values are within the global calibration error, no precipitation relationship exists within the region. Plant type distributions do not explain the lack of correlation, which is best attributed to poorly constrained estimates of heavy hydrogen in local rain and the relatively small range of variability within the region. At present, heavy hydrogen from ancient leaf waxes can show large changes in past precipitation, but improved process‐level understanding is needed to use this tool to understand smaller changes in the tropical Pacific and elsewhere.
    Description: Key Points: Leaf wax 2H/1H ratios are correlated with mean annual precipitation 2H/1H ratios globally, but not in the tropical Pacific. Deviations from the global relationship between precipitation leaf wax 2H/1H ratios cannot be predicted from palynological assemblages. Small range and large uncertainties in estimates of tropical Pacific precipitation 2H/1H ratios likely account for poor correlations.
    Description: Swiss National Science Foundation
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: Natural Environment Research Council (NERC) http://dx.doi.org/10.13039/501100000270
    Description: Department of Education and Training, Australian Research Council (ARC) http://dx.doi.org/10.13039/501100000923
    Description: http://10.0.15.89/ethz-b-000412154
    Keywords: ddc:551 ; ddc:577.7
    Language: English
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  • 6
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    Water Isotopic Signature of Surface Snow Metamorphism in Antarctica (2021)
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    Publication Date: 2022-04-01
    Description: Water isotope ratios of ice cores are a key source of information on past temperatures. Through fractionation within the hydrological cycle, temperature is imprinted in the water isotopic composition of snowfalls. However, this signal of climatic interest is modified after deposition when snow remains at the surface exposed to the atmosphere. Comparing time series of surface snow isotopic composition at Dome C with satellite observations of surface snow metamorphism, we found that long summer periods without precipitation favor surface snow metamorphism altering the surface snow isotopic composition. Using excess parameters (combining D,17O, and 18O fractions) allow the identification of this alteration caused by sublimation and condensation of surface hoar. The combined measurement of all three isotopic compositions could help identifying ice core sections influenced by snow metamorphism in sites with very low snow accumulation.
    Description: Plain Language Summary: Water isotopes in ice core records are often used to reconstruct past climate temperature variations. Classically, the temperature signal is thought to be imprinted in water isotopes of precipitation, and then archived in the ice core as it falls, and in cold areas of Antarctica, piles up for very long period. Here, we show that the surface snow isotopic composition varies in between precipitation events, suggesting that there might be more than one contribution to the isotopic signal in ice core records. This is particularly important for low accumulation sites, where the snow at the surface remains exposed for very long time periods. The combined use of several isotopic ratios in surface snow helps us disentangle the processes that create this signal.
    Description: Key Points: During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. The d‐excess and 17O‐excess of the snow is a proxy of snow metamorphism for low accumulation regions.
    Description: FP7 Ideas: European Research Council (FP7 Ideas) http://dx.doi.org/10.13039/100011199
    Description: Foundation Prince Albert of Monaco
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: DFG project CLIMAIC
    Description: https://doi.pangaea.de/10.1594/PANGAEA.934273
    Keywords: ddc:551.31 ; ddc:551.9
    Language: English
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  • 7
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    Impacts of Drying and Rewetting on the Radiocarbon Signature of Respired CO2 and Implications for Incubating Archived Soils (2021)
    Details
    Publication Date: 2022-04-01
    Description: The radiocarbon signature of respired CO2 (∆14C‐CO2) measured in laboratory soil incubations integrates contributions from soil carbon pools with a wide range of ages, making it a powerful model constraint. Incubating archived soils enriched by “bomb‐C” from mid‐20th century nuclear weapons testing would be even more powerful as it would enable us to trace this pulse over time. However, air‐drying and subsequent rewetting of archived soils, as well as storage duration, may alter the relative contribution to respiration from soil carbon pools with different cycling rates. We designed three experiments to assess air‐drying and rewetting effects on ∆14C‐CO2 with constant storage duration (Experiment 1), without storage (Experiment 2), and with variable storage duration (Experiment 3). We found that air‐drying and rewetting led to small but significant (α 〈 0.05) shifts in ∆14C‐CO2 relative to undried controls in all experiments, with grassland soils responding more strongly than forest soils. Storage duration (4–14 y) did not have a substantial effect. Mean differences (95% CIs) for experiments 1, 2, and 3 were: 23.3‰ (±6.6), 19.6‰ (±10.3), and 29.3‰ (±29.1) for grassland soils, versus −11.6‰ (±4.1), 12.7‰ (±8.5), and −24.2‰ (±13.2) for forest soils. Our results indicate that air‐drying and rewetting soils mobilizes a slightly older pool of carbon that would otherwise be inaccessible to microbes, an effect that persists throughout the incubation. However, as the bias in ∆14C‐CO2 from air‐drying and rewetting is small, measuring ∆14C‐CO2 in incubations of archived soils appears to be a promising technique for constraining soil carbon models.
    Description: Plain Language Summary: Soils play a key role in the global carbon cycle by sequestering carbon from the atmosphere for decades to millennia. However, it is unclear if they will continue to do so as the climate changes. Microbial decomposition of soil organic matter returns carbon back to the atmosphere, and radiocarbon dating of this returning CO2 (∆14C‐CO2) can be used to quantify how long carbon is stored in ecosystems. Incubating archived soils could provide unique insight into soil carbon sequestration potential by quantifying the change in ∆14C‐CO2 over time. However, air‐drying, duration of archiving, and subsequent rewetting of soils may bias estimates of sequestration potential by altering the balance of younger versus older carbon leaving the soil. We compared ∆14C‐CO2 from soils incubated with and without air‐drying and archiving, and found that the air‐dried soils appeared to release slightly older carbon than soils that had never been air‐dried. The amount of time the soils were archived did not have an effect. Since the bias from air‐drying and rewetting was small, incubating archived soils appears to be a promising technique for improving our ability to model soil carbon cycling under global climate change.
    Description: Key Points: ∆14C of CO2 measured in incubations of archived soils provides additional constraints for soil carbon models. Air‐drying and rewetting soils shifted the ∆14C of respired CO2 by 10‰–20‰ independent of the duration of storage. Differences in direction and magnitude of ∆14C‐CO2 shifts between forests and grasslands depended on sampling year and system C dynamics.
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: https://doi.org/10.5281/zenodo.4959705
    Keywords: ddc:551.9 ; ddc:631.41 ; ddc:550.724
    Language: English
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  • 8
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    Do tree species affect decadal changes in soil organic carbon and total nitrogen stocks in Danish common garden experiments? (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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    Long‐Term Nitrate Trajectories Vary by Season in Western European Catchments (2021)
    Details
    Publication Date: 2022-04-05
    Description: Human alteration of nutrient cycles has caused persistent and widespread degradation of water quality around the globe. In many regions, including Western Europe, elevated nitrate (NO3−) concentration in surface waters contributes to eutrophication and noncompliance with environmental legislation. Discharge, NO3− concentrations and the vulnerability of the aquatic ecosystems to eutrophication often exhibit a distinct seasonality. Understanding spatial patterns and long‐term trends in this seasonality is crucial to improve water quality management. Here, we hypothesized that NO3− concentrations during high‐flow periods would respond faster to changes in nutrient inputs than low‐flow concentrations because of greater connectivity of shallow diffuse NO3− sources with the river network. To test this hypothesis, we compiled long‐term NO3− and discharge time series from 290 Western European catchments. To characterize the long‐term trajectories of seasonal NO3− concentration, we propose a novel hysteresis approach comparing low‐ and high‐flow NO3− concentration in the context of multi‐decadal N input changes. We found synchronous winter maxima of NO3− and discharge in 84% of the study catchments. However, contrary to our hypothesis, there were surprisingly diverse long‐term trajectories of seasonal NO3− concentration. Both clockwise (faster high‐flow NO3− response) and counterclockwise hysteresis (faster low‐flow NO3− response) occurred in similar proportions, potentially due to a high complexity in the underlying processes. Spatial variability of seasonality in NO3− concentration across the catchments was more pronounced and better predictable than its long‐term variability. This work demonstrates the value of seasonal and inter‐annual hydrochemical analysis and provides new tools for water quality monitoring and management.
    Description: Plain Language Summary: Nitrogen is an essential element of all living organisms and has thus often been used excessively as fertilizer to secure food production. However, surface waters can suffer from elevated nutrients inputs, causing toxic algal blooms and impairing drinking water quality, especially during summer low flows. To manage water quality, it is crucial to understand these seasonal variations of nitrogen and discharge and the underlying processes. We used data from 290 catchments in France and Germany to characterize average seasonality patterns and their long‐term evolution across the variety of landscapes and human influences. This allowed classifying catchment behavior and linking them to controls. As expected, both nitrogen and discharge peak during winter in most catchments (84%). However, there are well explainable deviations, for example, in mountainous regions. The long‐term evolution of seasonality was more diverse than expected suggesting a complex interplay of various processes with the long input history from fertilization and wastewater being part of the controls. We found that the differences among catchments were greater than the long‐term changes of seasonality within most catchments. By identifying catchment typologies, our study increases the understanding of nitrate seasonality patterns across a large extent and thus supports ecological water quality management.
    Description: Key Points: Spatial patterns of nitrate and discharge seasonality are linked to topography and hydroclimate with winter maxima dominating for both. After decreasing nutrient inputs, cases with decreases in river nitrate preceding during low‐ and high‐flow seasons occurred equally often. Spatial variability of nitrate seasonality is greater and more predictable from catchment characteristics than its long‐term variability.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: US National Science Foundation (NSF)
    Keywords: ddc:551
    Language: English
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    Assessing the robustness of carbonate‐associated sulfate during hydrothermal dolomitization of the Latemar platform, Italy (2021)
    Details
    Publication Date: 2022-03-30
    Description: Carbonate‐associated sulfate (CAS) is an important proxy for reconstructing marine sulfur cycling throughout Earth's history. In order to assess the impact of carbonate neomorphism on δ34SCAS data, a mineralogical‐spatial transect from early diagenetic limestone into low‐temperature hydrothermal dolostone was analyzed in the middle Triassic Latemar platform interior, northern Italy. This study addresses the yet unconstrained question whether hydrothermal dolostone preserves a marine δ34SCAS signature and, hence, might represent an archive for past seawater sulfate. In this study, δ34SCAS values were measured in low‐temperature hydrothermal dolostone and compared with data from their corresponding precursor limestone. Results shown here reveal that δ34SCAS values for dolostone and precursor limestone are indistinguishable. This points to a rock‐buffered middle Triassic marine δ34S signature not affected by hydrothermal alteration. Hence, hydrothermal dolostone represents, under favorable conditions, an archive for unraveling past marine sulfur cycling.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:552
    Language: English
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  • 11
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    Formation of chondrule analogs aboard the International Space Station (2021)
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    Publication Date: 2022-03-30
    Description: Chondrules are thought to play a crucial role in planet formation, but the mechanisms leading to their formation are still a matter of unresolved discussion. So far, experiments designed to understand chondrule formation conditions have been carried out only under the influence of terrestrial gravity. In order to introduce more realistic conditions, we developed a chondrule formation experiment, which was carried out at long‐term microgravity aboard the International Space Station. In this experiment, freely levitating forsterite (Mg2SiO4) dust particles were exposed to electric arc discharges, thus simulating chondrule formation via nebular lightning. The arc discharges were able to melt single dust particles completely, which then crystallized with very high cooling rates of 〉105 K h−1. The crystals in the spherules show a crystallographic preferred orientation of the [010] axes perpendicular to the spherule surface, similar to the preferred orientation observed in some natural chondrules. This microstructure is probably the result of crystallization under microgravity conditions. Furthermore, the spherules interacted with the surrounding gas during crystallization. We show that this type of experiment is able to form spherules, which show some similarities with the morphology of chondrules despite very short heating pulses and high cooling rates.
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Description: BIOVIA Science Ambassador program
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: NanoRacks LLC
    Description: DreamUp
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Dr. Rolf M. Schwiete Stiftung
    Keywords: ddc:549 ; ddc:550.78
    Language: English
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    The terrestrial impact crater record: A statistical analysis of morphologies, structures, ages, lithologies, and more (2021)
    Details
    Publication Date: 2022-03-30
    Description: Abstract The number of newly discovered and confirmed impact structures on earth is growing continuously. In this review paper, the main attributes of 198 confirmed impact structures and 10 further structures, for which final confirmation based on the identification of shock features is not yet entirely satisfying, are presented. The impact craters are compared statistically, with regard to their morphology, structure, and status of erosion or burial. The size– and age–frequency distributions of terrestrial impact structures are presented. Additional aspects concern target petrography and shock effects found in the craters. Based on the discovery statistics of presently known crater structures, an estimate can be made of the number of craters that await discovery. The paper is complementary to the recently published atlas of terrestrial impact structures by Gottwald et al. (2020).
    Keywords: ddc:551
    Language: English
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  • 13
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    Eemian landscape response to climatic shifts and evidence for northerly Neanderthal occupation at a palaeolake margin in northern Germany (2021)
    Details
    Publication Date: 2022-03-30
    Description: The prevailing view suggests that the Eemian interglacial on the European Plain was characterized by largely negligible geomorphic activity beyond the coastal areas. However, systematic geomorphological studies are sparse. Here we present a detailed reconstruction of Eemian to Early Weichselian landscape evolution in the vicinity of a small fingerlake on the northern margin of the Salzwedel Palaeolake in Lower Saxony (Germany). We apply a combination of seismics, sediment coring, pollen analysis and luminescence dating on a complex sequence of colluvial, paludal and lacustrine sediments. Results suggest two pronounced phases of geomorphic activity, directly before the onset and at the end of the Eemian period, with an intermediate period of pronounced landscape stability. The dynamic phases were largely driven by incomplete vegetation cover, but likely accentuated by fluvial incision in the neighbouring Elbe Valley. Furthermore, we discovered Neanderthal occupation at the lakeshore during Eemian pollen zone (PZ) E IV, which is chronologically in line with other known Eemian sites of central Europe. Our highly‐resolved spatio‐temporal data substantially contribute to the understanding of climate‐induced geomorphic processes throughout and directly after the last interglacial period. It helps unraveling the landscape dynamics between the coastal areas to the north and the loess belt to the south.
    Description: Two phases of channel incision at the Saalian‐Eemian transition and in the late Eemian. Incisions closely followed by rising water tables. Long‐lasting phase of geomorphic stability in the mid‐Eemian, characterized by: very dense forest cover. the formation of a fingerlake within the paleochannel with gradually sinking water table. no influx of clastic sediments, but deposition of peat and lake‐marl deposits.
    Description: Max‐Planck‐Gesellschaft http://dx.doi.org/10.13039/501100004189
    Keywords: ddc:554.3 ; ddc:551
    Language: English
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  • 14
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    Increased petrogenic and biospheric organic carbon burial in sub‐Antarctic fjord sediments in response to recent glacier retreat (2021)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-03-30
    Description: Fjords are recognized as hotspots of organic carbon (OC) burial in the coastal ocean. In fjords with glaciated catchments, glacier discharge carries large amounts of suspended matter. This sedimentary load includes OC from bedrock and terrigenous sources (modern vegetation, peat, soil deposits), which is either buried in the fjord or remineralized during export, acting as a potential source of CO2 to the atmosphere. In sub‐Antarctic South Georgia, fjord‐terminating glaciers have been retreating during the past decades, likely as a response to changing climate conditions. We determine sources of OC in surface sediments of Cumberland Bay, South Georgia, using lipid biomarkers and the bulk 14C isotopic composition, and quantify OC burial at present and for the time period of documented glacier retreat (between 1958 and 2017). Petrogenic OC is the dominant type of OC in proximity to the present‐day calving fronts (60.4 ± 1.4% to 73.8 ± 2.6%) and decreases to 14.0 ± 2.7% outside the fjord, indicating that petrogenic OC is effectively buried in the fjord. Beside of marine OC, terrigenous OC comprises 2.7 ± 0.5% to 7.9 ± 5.9% and is mostly derived from modern plants and Holocene peat and soil deposits that are eroded along the flanks of the fjord, rather than released by the retreating fjord glaciers. We estimate that the retreat of tidewater glaciers between 1958 and 2017 led to an increase in petrogenic carbon accumulation of 22% in Cumberland West Bay and 6.5% in Cumberland East Bay, suggesting that successive glacier retreat does not only release petrogenic OC into the fjord, but also increases the capacity of OC burial.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552 ; ddc:551.9
    Language: English
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    Papanin Ridge and Ojin Rise Seamounts (Northwest Pacific): Dual Hotspot Tracks Formed by the Shatsky Plume (2021)
    Details
    Publication Date: 2022-03-31
    Description: Although previous findings support an origin of the Shatsky Rise igneous plateau (Northwest Pacific) through interaction of a mantle plume with a mid‐ocean ridge triple junction, the evidence for the involvement of a mantle plume is equivocal. The identification of an intraplate hotspot track emanating from the plateau could solve this controversy. Here we present major and trace element geochemical data from two different bathymetric features that emanate from the youngest end of Shatsky Rise: Papanin Ridge and the Ojin Rise Seamount province. Combining our results with plate tectonic reconstructions, we conclude that Papanin Ridge represents a hotspot track formed by plume‐ridge interaction. Whereas the southwestern part was formed along the path of the retreating Pacific‐Farallon‐Izanagi triple junction, the northeastern part was built by preferential drainage into its Pacific‐Farallon branch. In contrast, the Ojin Rise Seamounts formed as a true intraplate hotspot track of the Shatsky plume tail. Our wide‐ranging study reveals systematic spatial geochemical variations, consistent with a lithospheric thickness control on magma composition derived from melting a heterogeneous plume source. The recognition of two hotspot tracks and in particular of the Ojin Rise Seamounts as an intraplate hotspot track that is directly linked to Shatsky plateau volcanism both in terms of geochemistry and plate tectonic reconstructions confirms the long‐disputed involvement of a mantle plume for the formation of Shatsky Rise.
    Description: Plain Language Summary: The origin of Shatsky Rise, a large igneous plateau in the NW Pacific, has long been debated. It could have either formed by shallow mantle melting due to its confirmed creation along a mid‐ocean ridge or with additional contribution of deeper mantle material that upwelled as so‐called mantle plume beneath the spreading ridge (“plume‐ridge interaction”). The identification of an intraplate hotspot track emanating from Shatsky Rise and related to the plateau could answer this question. Here we present major and trace element geochemical data from lava samples dredged from two different structures that arise from the youngest end of the Shatsky Rise plateau: Papanin Ridge and the Ojin Rise Seamount province. By combining our results with plate tectonic reconstructions, we conclude that Papanin Ridge formed, like the main Shatsky Rise, by continued plume‐ridge interaction. In contrast, the Ojin Rise Seamounts formed as a true intraplate hotspot track by the drift of the Pacific Plate over the stationary Shatsky hotspot (plume tail). The recognition of an intraplate hotspot track that is directly linked to the Shatsky plateau volcanism both in terms of geochemistry and plate tectonic reconstructions also confirms the involvement of a mantle plume for the formation of Shatsky Rise.
    Description: Key Points: The Ojin Rise Seamounts are identified as intraplate hotspot track of the same mantle plume that formed the Shatsky Rise oceanic plateau. Papanin Ridge formed by plume‐ridge interaction and represents the northeastern continuation of the Shatsky plateau. Linking an intraplate hotspot track to the Shatsky plateau confirms the involvement of a mantle plume for its formation.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: GEOMAR Helmholtz Centre for Ocean Research Kiel
    Description: https://doi.org/10.26022/IEDA/111976
    Keywords: ddc:551 ; ddc:552.2
    Language: English
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  • 16
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    Past and Future Climate Variability Uncertainties in the Global Carbon Budget Using the MPI Grand Ensemble (2021)
    Details
    Publication Date: 2022-03-25
    Description: Quantifying the anthropogenic fluxes of CO2 is important to understand the evolution of carbon sink capacities, on which the required strength of our mitigation efforts directly depends. For the historical period, the global carbon budget (GCB) can be compiled from observations and model simulations as is done annually in the Global Carbon Project's (GCP) carbon budgets. However, the historical budget only considers a single realization of the Earth system and cannot account for internal climate variability. Understanding the distribution of internal climate variability is critical for predicting the future carbon budget terms and uncertainties. We present here a decomposition of the GCB for the historical period and the RCP4.5 scenario using single‐model large ensemble simulations from the Max Planck Institute Grand Ensemble (MPI‐GE) to capture internal variability. We calculate uncertainty ranges for the natural sinks and anthropogenic emissions that arise from internal climate variability, and by using this distribution, we investigate the likelihood of historical fluxes with respect to plausible climate states. Our results show these likelihoods have substantial fluctuations due to internal variability, which are partially related to El Niño‐Southern Oscillation (ENSO). We find that the largest internal variability in the MPI‐GE stems from the natural land sink and its increasing carbon stocks over time. The allowable fossil fuel emissions consistent with 3 C warming may be between 9 and 18 Pg C yr−1. The MPI‐GE is generally consistent with GCP's global budgets with the notable exception of land‐use change emissions in recent decades, highlighting that human action is inconsistent with climate mitigation goals.
    Description: Key Points: We use a single‐model large ensemble to estimate uncertainties from internal climate variability in the global carbon budget. The land sink accounts for most internal climate uncertainty which may permit 9–18 Pg C yr−1 in allowable emissions by 2050 (for 3°C warming).
    Description: European Union's Horizon 2020
    Keywords: ddc:551.9 ; ddc:551.6
    Language: English
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    Assessing Volcanic Controls on Miocene Climate Change (2022)
    Details
    Publication Date: 2022-03-25
    Description: The Miocene period saw substantially warmer Earth surface temperatures than today, particularly during a period of global warming called the Mid Miocene Climatic Optimum (MMCO; ∼17–15 Ma). However, the long‐term drivers of Miocene climate remain poorly understood. By using a new continuous climate‐biogeochemical model (SCION), we can investigate the interaction between volcanism, climate and biogeochemical cycles through the Miocene. We identify high tectonic CO2 degassing rates and further emissions associated with the emplacement of the Columbia River Basalt Group as the primary driver of the background warmth and the MMCO respectively. We also find that enhanced weathering of the basaltic terrane and input of explosive volcanic ash to the oceans are not sufficient to drive the immediate cooling following the MMCO and suggest that another mechanism, perhaps the change in ocean chemistry due to massive evaporite deposition, was responsible.
    Description: Plain Language Summary: The Miocene period was much warmer than today, with the Mid Miocene Climatic Optimum (MMCO, roughly 17–15 million years ago) especially warm. Due to the high surface temperatures, comparisons to projected climatic conditions as a result of anthropogenic climate change have been drawn. However, the drivers of climate during the Miocene are not well understood. By using a new type of climate model, we investigate the impact volcanic eruptions had on the period, and link the extreme warmth of the MMCO with greenhouse gas release from the eruption of the Columbia River Basalts Group (CRBG). We find weathering of the CRBG does not explain the cooling at the end of the MMCO, and so discuss other potential explanations such as evaporite deposition.
    Description: Key Points: A new climate‐biogeochemical model allows investigation of drivers of climate change in the Miocene. Columbia River Basalt Group (CRBG) degassing is sufficient to have caused the Mid Miocene Climatic Optimum (MMCO). Weathering of CRBG insufficient to drive cooling after the MMCO. This may be linked to evaporite deposition and changes to marine chemistry.
    Description: UK Natural Environment Research Council
    Description: French Research Agency (ANR)
    Keywords: ddc:551
    Language: English
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    The Spectrum of Slip Behaviors of a Granular Fault Gouge Analogue Governed by Rate and State Friction (2021)
    Details
    Publication Date: 2022-03-25
    Description: Currently, it is unknown how seismic and aseismic slip influences the recurrence and magnitude of earthquakes. Modern seismic hazard assessment is therefore based on statistics combined with numerical simulations of fault slip and stress transfer. To improve the underlying statistical models we conduct low velocity shear experiments with glass micro‐beads as fault gouge analogue at confining stresses of 5–20 kPa. As a result, we show that characteristic slip events emerge, ranging from fast and large slip to small scale oscillating creep and stable sliding. In particular, we observe small scale slip events that occur immediately before large scale slip events for a specific set of experiments. Similar to natural faults we find a separation of scales by several orders of magnitude for slow events and fast events. Enhanced creep and transient dilatational events pinpoint that the granular analogue is close to failure. From slide‐hold‐slide tests, we find that the rate‐and‐state properties are in the same range as estimates for natural faults and fault rocks. The fault shows velocity weakening characteristics with a reduction of frictional strength between 0.8% and 1.3% per e‐fold increase in sliding velocity. Furthermore, the slip modes that are observed in the normal shear experiments are in good agreement with analytical solutions. Our findings highlight the influence of micromechanical processes on macroscopic fault behavior. The comprehensive data set associated with this study can act as a benchmark for numerical simulations and improve the understanding of observations of natural faults.
    Description: Plain Language Summary: Earthquakes occur when two continental plates slide past each other. The motion is concentrated at the interface of the two plates which is called a fault. In many cases the fault is filled with granular material, called gouge, that supports the pressure between the plates. Therefore, the properties of this gouge determine how fast and how large an earthquake can be. It also has an influence on the time between earthquakes. In our study, we examine a simplified version of a fault gouge in a simple small‐scale model. Instead of rock material we use glass beads and measure how different conditions affect the motion of the model. We find that our model reproduces features of fault gouge because it shows similar behavior. When there is no motion our model fault becomes stronger with a rate equal to fault gouge. Also, the type of strengthening is analogous to fault gouge. During slip, the glass beads become weaker as the slip velocity increases in a similar manner as in natural faults. These results improve the understanding of computer simulations and natural observations.
    Description: Key Points: Slip modes in granular gouge are akin to natural fault slip. Glass beads are a suitable granular analogue for fault gouge and show rate‐and‐state dependent friction. Enhanced creep and small scale events are signals for imminent failure and indicate fault criticality.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: 亥姆霍兹联合会致力, Helmholtz‐Zentrum Potsdam ‐ Deutsches GeoForschungsZentrum GFZ (GFZ) http://dx.doi.org/10.13039/501100010956
    Keywords: ddc:550.78
    Language: English
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  • 19
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    Last Glacial central Mediterranean hydrology inferred from Lake Trasimeno’s (Italy) calcium carbonate geochemistry (2021)
    Details
    Publication Date: 2022-03-24
    Description: There is still a paucity of hydrological data explaining the relationship between (rapid, millennial‐scale) climate forcing and Mediterranean rainfall since the Last Glacial. We show that distinct lake‐level fluctuations at Lake Trasimeno (Italy) are associated with changing aridity in the central Mediterranean during the last ~47 800 years. The lake‐level fluctuations are reconstructed based on carbonate mineral content and carbonate mineral species, as well as the stable oxygen and carbon isotope (δ18O and δ13C) geochemistry of endogenic carbonates. Low lake levels are linked to high carbonate, Mg‐calcite and aragonite contents, and high δ18O and δ13C values. Inferred hydrological changes are linked to glacial–interglacial and, tentatively within the limitations of our chronology, to millennial‐scale climate variability as well as the intensity of the Atlantic Meridional Overturning Circulation (AMOC). Prior to the Last Glacial Maximum (LGM), during intervals equivalent to Marine Isotope Stage 3 (MIS 3), a stronger AMOC associated with Greenland interstadial periods (Dansgaard/Oeschger (D/O) warm periods) and stronger Asian monsoon probably coincide with increased precipitation in central Italy as inferred from high lake levels at Lake Trasimeno. Periods of weak AMOC intensity such as during Greenland stadials (D/O cold periods), during Heinrich events, and weak Asian monsoons are correlated with lake level lowstands, which imply relatively dry conditions in central Italy. Lake Trasimeno’s water level during the LGM and the Lateglacial (MIS 2) is relatively stable, with recorded changes showing distinct similarities to orbital configurations. Although muted, high latitude climate forcing is still evident in the data during peak glacial conditions. The transition from D/O‐like hydrological variability at Lake Trasimeno during MIS 3 to orbitally controlled fluctuations during the Lateglacial to Holocene transition coincides with an increasing amplitude in local winter and summer insolation, probably indicating increasing seasonality and a larger temperature gradient between low‐ and high‐latitude settings.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Keywords: ddc:551.9
    Language: English
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  • 20
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    Detrital apatite geochemistry and thermochronology from the Oligocene/Miocene Alpine foreland record the early exhumation of the Tauern Window (2021)
    Details
    Publication Date: 2022-03-24
    Description: The early exhumation history of the Tauern Window in the European Eastern Alps and its surface expression is poorly dated and quantified, partly because thermochronological and provenance information are sparse from the Upper Austrian Northern Alpine Foreland Basin. For the first time, we combine a single‐grain double‐dating approach (Apatite Fission Track and U‐Pb dating) with trace‐element geochemistry analysis on the same apatites to reconstruct the provenance and exhumation history of the late Oligocene/early Miocene Eastern Alps. The results from 22 samples from the Chattian to Burdigalian sedimentary infill of the Upper Austrian Northern Alpine Foreland Basin were integrated with a 3D seismic‐reflection data set and published stratigraphic reports. Our highly discriminative data set indicates an increasing proportion of apatites (from 6% to 23%) with Sr/Y values 〈0.1 up‐section and an increasing amount of apatites (from 24% to 38%) containing 〉1,000 ppm light rare‐earth elements from Chattian to Burdigalian time. The number of U‐Pb ages with acceptable uncertainties increases from 40% to 59% up‐section, with mostly late Variscan/Permian ages, while an increasing number of grains (10%–27%) have Eocene or younger apatite fission track cooling ages. The changes in the apatite trace‐element geochemistry and U‐Pb data mirror increased sediment input from an ≥upper amphibolite‐facies metamorphic source of late Variscan/Permian age – probably the Ötztal‐Bundschuh nappe system – accompanied by increasing exhumation rates indicated by decreasing apatite fission track lag times. We attribute these changes to the surface response to upright folding and doming in the Penninic units of the future Tauern Window starting at 29–27 Ma. This early period of exhumation (0.3–0.6 mm/a) is triggered by early Adriatic indentation along the Giudicarie Fault System.
    Description: Science Foundation Ireland http://dx.doi.org/10.13039/501100001602
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.701 ; ddc:551.9
    Language: English
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    Evolution of Sea Surface Hydrology Along the Western Australian Margin Over the Past 450 kyr (2021)
    Details
    Publication Date: 2022-03-24
    Description: We collected a suite of core top samples during R/V Sonne Cruise SO257 in May 2017 along the southwestern front of the Indo‐Pacific Warm Pool (IPWP) to monitor the variability of Southern Hemisphere tropical and subtropical sea surface hydrology and to assess temperature and salinity reconstructions with data sets reflecting conditions in the post‐monsoonal season. In our core top samples, a steep increase in planktic δ18O, associated with a decrease in sea surface temperature (SST), indicates that the southwestern front of the IPWP is located between 23° and 24°S during austral fall. We additionally reconstructed SST, sea surface salinity ,and δ18O seawater (δ18Osw) over the last 450 kyr in two sediment successions located within and beyond the monsoonal rain belt. Our records show that SST was highly coherent and phase‐locked with atmospheric pCO2 during the last 450 kyr. The regional differences in the δ18Osw records reveal that the Western Australian Margin north of 15°S remained seasonally under the influence of IPWP water masses, even during glacials. The temporal variability in upper ocean hydrology along the Western Australian Margin is not directly coupled to local monsoonal precipitation, but is strongly affected by advective mixing of Indonesian Throughflow derived water masses.
    Description: Key Points: Southwest front of modern Indo‐Pacific Warm Pool (IPWP) during austral fall is located between 23° and 24°S. Western Australian Margin north of 15°S remained seasonally influenced by IPWP throughout past 450 kyr. Upper ocean hydrology off Western Australia represents an integrated signal of monsoonal precipitation and advective mixing.
    Description: China Scholarship Council
    Description: German Federal Ministry of Education and Research
    Keywords: ddc:551.46
    Language: English
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    Tephra Deposition and Bonding With Reactive Oxides Enhances Burial of Organic Carbon in the Bering Sea (2021)
    Details
    Publication Date: 2022-03-24
    Description: Preservation of organic carbon (OC) in marine sediments exerts a major control on the cycling of carbon in the Earth system. In these marine environments, OC preservation may be enhanced by diagenetic reactions in locations where deposition of fragmental volcanic material called tephra occurs. While the mechanisms by which this process occurs are well understood, site‐specific studies of this process are limited. Here, we report a study of sediments from the Bering Sea (IODP Site U1339D) to investigate the effects of marine tephra deposition on carbon cycling during the Pleistocene and Holocene. Our results suggest that tephra layers are loci of OC burial with distinct δ13C values, and that this process is primarily linked to bonding of OC with reactive metals, accounting for ∼80% of all OC within tephra layers. In addition, distribution of reactive metals from the tephra into non‐volcanic sediments above and below the tephra layers enhances OC preservation in these sediments, with ∼33% of OC bound to reactive phases. Importantly, OC‐Fe coupling is evident in sediments 〉700,000 years old. Thus, these interactions may help explain the observed preservation of OC in ancient marine sediments.
    Description: Plain Language Summary: The burial of organic carbon (OC) in marine sediments is one of the major carbon sinks on Earth, meaning that it removes carbon dioxide from the ocean‐atmosphere system. However, the speed at which burial occurs varies across the globe, and is dependent on a range of factors, from the amount of nutrients in the water column, to the type of sediment. Despite evidence suggesting that when tephra is deposited to the seafloor carbon burial is enhanced, very little work has been done to investigate this process. We have therefore analyzed sediments from the Bering Sea, where volcanoes from the Aleutian Islands and Kamchatka regularly deposit tephra in the ocean. We found that OC burial is indeed associated with ash deposition, and importantly, that OC is preserved in the ash layers themselves. We show here that this carbon is preserved effectively because of chemical reactions between the OC and reactive iron, which is released by the ash, creating conditions which preserve carbon for hundreds of thousands of years.
    Description: Key Points: Tephra layers are loci of marine organic carbon (OC) burial with distinct carbon isotopic compositions. Preservation primarily linked to association of OC with reactive iron phases, accounting for ∼80% of all OC in tephra layers. OC‐reactive Fe coupling is observed in sediments 〉700,000 years old, indicating long‐term persistence of these complexes.
    Description: NERC
    Keywords: ddc:551.9
    Language: English
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    The Heligoland Glacitectonic Complex in the southeastern North Sea: indicators of a pre‐ or early‐Elsterian ice margin (2021)
    Details
    Publication Date: 2022-03-28
    Description: Glacial landforms are abundant in the North Sea basin and are often used to reconstruct the impact and dynamics of ice sheets during the Pleistocene. Geophysical methods have allowed the mapping and structural analysis of glacial landforms at the surface and in the subsurface to estimate the position of former ice margins in the North Sea. However, the glacial history of the southeastern North Sea remains underexplored. In this study, we present a structural analysis of Late Pliocene to Late Pleistocene sediments based on a dense grid of 2D high‐resolution multi‐channel reflection seismic data from the German sector of the southeastern North Sea. We show that the Heligoland Glacitectonic Complex (HGC) is larger than previously assumed (700 km2, 32×22 km) and characterized by three distinct zones of thrusting and deformation on two décollements. The kinematic restoration of seismic cross‐sections and dip measurements of thrust faults demonstrate that the HGC was formed by an ice lobe advancing from the southeast. To explain the origin of the HGC, we provide alternative models for its formation during a single ice advance or two ice advances in the study area. Furthermore, we validate the early or pre‐Elsterian age of the HGC based on nearby Elsterian tunnel valleys, and conclude that salt structures in the subsurface may have influenced its location.
    Description: Schleswig‐Holstein Agency for Coastal Defence, National Park and Marine Conservation (LKN.SH) and the State Agency for Agriculture, Environment and Rural Areas of Schleswig‐Holstein (LLUR)
    Keywords: ddc:551
    Language: English
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  • 24
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    Effects of CO2 and Ocean Mixing on Miocene and Pliocene Temperature Gradients (2022)
    Details
    Publication Date: 2022-03-28
    Description: Cenozoic climate changes have been linked to tectonic activity and variations in atmospheric CO2 concentrations. Here, we present Miocene and Pliocene sensitivity experiments performed with the climate model COSMOS. The experiments contain changes with respect to paleogeography, ocean gateway configuration, and atmospheric CO2 concentrations, as well as a range of vertical mixing coefficients in the ocean. For the mid‐Miocene, we show that the impact of ocean mixing on surface temperature is comparable to the effect of the possible range in reconstructed CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv enable global‐mean surface, deep‐water, and meridional temperature characteristics representative of mid‐Miocene Climatic Optimum (MMCO) reconstructions. The Miocene climate shows a reduced meridional temperature gradient and reduced seasonality. In the case of enhanced mixing, surface and deep ocean temperatures show significant warming of up to 5–10°C and an Arctic temperature anomaly of 〉12°C. In the Pliocene simulations, the impact of vertical mixing and CO2 is less important for the deep ocean, which we interpret as a different sensitivity dependence on the background state and mixed layer dynamics. We find a significant reduction in surface albedo and effective emissivity for either a high level of atmospheric CO2 or increased vertical mixing. Our mixing sensitivity experiments provide a warm deep ocean via ocean heat uptake. We propose that the mixing hypothesis can be tested by reconstructions of the thermocline and seasonal paleoclimate data indicating a lower seasonality relative to today.
    Description: Plain Language Summary: Cenozoic climate changes have been associated with tectonic changes and altered atmospheric CO2 concentrations. Here, we present Miocene and Pliocene computer simulations where we changed paleogeography, ocean gateways, and atmospheric CO2 concentrations as well as vertical mixing in the ocean. We show that the effect of ocean mixing on temperature is comparable to the respective effect of a possible range of CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv allow surface and deep‐water temperatures representative for reconstructions of the climate optimum of the mid‐Miocene. In the Pliocene simulations, the influence of vertical mixing and CO2 is less important than in the Miocene. We provide a possible mechanism of ocean heat absorption, albedo, and emissivity changes including a deeper oceanic mixing layer and a lower seasonality in the Miocene compared to today.
    Description: Key Points: Miocene experiment with standard mixing and atmospheric CO2 of 600 ppm captures large‐scale temperature characteristics of the mid‐Miocene. With enhanced ocean mixing the temperature characteristics and meridional temperature gradient can be reproduced with a CO2 level of 450 ppm. Miocene shows a strong warming at polar latitudes and reduced seasonality, vertical mixing, and CO2 are less important for the Pliocene.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI) http://dx.doi.org/10.13039/501100003207
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: Helmholtz Climate Initiative RE‐KLIM
    Keywords: ddc:550.78
    Language: English
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    Chemical Evolution of the Exceptional Arctic Stratospheric Winter 2019/2020 Compared to Previous Arctic and Antarctic Winters (2021)
    Details
    Publication Date: 2022-03-28
    Description: The winter 2019/2020 showed the lowest ozone mixing ratios ever observed in the Arctic winter stratosphere. It was the coldest Arctic stratospheric winter on record and was characterized by an unusually strong and long‐lasting polar vortex. We study the chemical evolution and ozone depletion in the winter 2019/2020 using the global Chemistry and Transport Model ATLAS. We examine whether the chemical processes in 2019/2020 are more characteristic of typical conditions in Antarctic winters or in average Arctic winters. Model runs for the winter 2019/2020 are compared to simulations of the Arctic winters 2004/2005, 2009/2010, and 2010/2011 and of the Antarctic winters 2006 and 2011, to assess differences in chemical evolution in winters with different meteorological conditions. In some respects, the winter 2019/2020 (and also the winter 2010/2011) was a hybrid between Arctic and Antarctic conditions, for example, with respect to the fraction of chlorine deactivation into HCl versus ClONO2, the amount of denitrification, and the importance of the heterogeneous HOCl + HCl reaction for chlorine activation. The pronounced ozone minimum of less than 0.2 ppm at about 450 K potential temperature that was observed in about 20% of the polar vortex area in 2019/2020 was caused by exceptionally long periods in the history of these air masses with low temperatures in sunlight. Based on a simple extrapolation of observed loss rates, only an additional 21–46 h spent below the upper temperature limit for polar stratospheric cloud formation and in sunlight would have been necessary to reduce ozone to near zero values (0.05 ppm) in these parts of the vortex.
    Description: Key Points: The Arctic stratospheric winter 2019/2020 showed the lowest ozone mixing ratios ever observed and was one of the coldest on record. Chemical evolution of the Arctic winter 2019/2020 was a hybrid between typical Arctic and typical Antarctic conditions. Only an additional 21–46 h below PSC temperatures and in sunlight would have been necessary to reduce ozone to near zero locally.
    Description: International Multidisciplinary Drifting Observatory for the Study of the Arctic Climate (MOSAiC)
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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    Volume Transport Time Series and Variability of the North Atlantic Eastern Boundary Current at Goban Spur (2021)
    Details
    Publication Date: 2022-03-23
    Description: The Eastern Boundary Current is an essential part of the water mass exchange between the subtropical and subpolar North Atlantic. Here, we study the offshore branch of the European Shelf Current (ESC) over the Goban Spur slope area off Ireland. Our analysis is based on current measurements obtained from a multiyear mooring effort, complemented by ship‐board observations along a hydrographic section, satellite‐derived estimates of absolute dynamic topography with geostrophic currents, and float trajectories. These data serve to quantify the offshore branch of the ESC on intraannual to interannual timescales. From the moored observations, we derive a mean poleward along‐slope volume flux of 3.7 ± 0.7 Sv for the period 2017–2019. Using a multilinear regression model and geostrophic surface velocities, we extend the time series to the period 1993–2019 and obtain a long‐term mean transport of 3.2 ± 0.4 Sv. Both time series show strong variability ranging from −7.5 to 15.7 Sv. The variability is linked to a dynamic eddy field, especially a stationary cyclonic circulation pattern near the mooring array, and meandering of current branches originating from the North Atlantic Current. We find no evidence of a consistent deep boundary current extending from the shelf break to the position of the offshore mooring (4,500 m depth), but confirm a persistent along‐slope flow at the shallower slope (1,500 m depth). Geostrophic surface velocities and float trajectories reveal that the offshore branch of the ESC does not follow a clear northward path from the eastern subtropical regions but rather indicate the intermittent character of the flow.
    Description: Plain Language Summary: In this study, we describe the European Shelf Current (ESC) in the eastern North Atlantic. The study area is the deeper part of the Goban Spur area off Ireland. We use current measurements of instruments deployed in the water column from 2016 to 2019 combined with satellite observations of surface circulation and drifting float paths. We aim to quantify the contribution of the offshore branch to the ESC system. We calculate a poleward volume transport following the slope that is on average 3.7 ± 0.7 Sverdrup (Sv; 1 Sv = 1 million cubic meter per second) for the period 2017–2019. We use a mathematical relation between mooring data and satellite observations to extend the time series to the period 1993–2019 and obtain an average transport of 3.2 ± 0.4 Sv. There occur strong changes over time ranging from −5 to 15 Sv. These changes are caused by rotating vortices (eddies), especially a counter‐clockwise rotating circulation pattern near the moorings, and changing positions of currents branching from the North Atlantic Current. We find that the offshore branch of the ESC does not follow a clear northward path from the eastern subtropical regions of the North Atlantic. Instead, the flow is of rather unsteady character.
    Description: Key Points: The analysis of multiplatform observational efforts is used to study the circulation at the North Atlantic Eastern Boundary. The volume transport of the offshore branch of the European Shelf Current is on average 3.2 ± 0.4 Sv for the period 1993–2019. Transport variability is in the range of −7.5–15.7 Sv and induced by eddies and meandering North Atlantic Current branches.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    The Transpolar Drift Influence on the Arctic Ocean Silicon Cycle (2021)
    Details
    Publication Date: 2022-03-23
    Description: During most of the year, diatom production in the ice‐covered Central Arctic Ocean (CAO) is limited by light availability and nutrient supply. Therefore, biological production is thought to be generally low, with higher biological production at the sea ice edge and over partially ice‐free shelf areas. The major surface ocean current in the CAO is the Transpolar Drift (TPD), which transports sea ice and water from the rivers and shelves of the Laptev and the East Siberian Seas across the CAO toward the Fram Strait, carrying high amounts of terrestrial‐derived material over long distances. We used Si isotopes (δ30Si) to better understand the difference between lower and higher biological production areas and how the TPD potentially affects the Si cycle in the CAO. Our data show low dissolved Si concentrations ([DSi]) paired with high values of δ30Si‐DSi in all surface samples indicating fractionation by diatoms. Specifically, outside the TPD influence, all nutrients were depleted and supply was limited due to stratified conditions, thus preventing further phytoplankton growth in the area during the sampling time in late summer‐early fall. In contrast, under the TPD influence, diatom primary production was limited by low nitrate and strongly limited by light due to the presence of sea ice, even though [DSi] values were much higher than outside the TPD. Based on δ30Si, we could identify low but measurable DSi utilization in the TPD, potentially highlighting the importance of sea ice‐attached diatoms transported to the CAO via the TPD for the Si cycle in this region.
    Description: Plain Language Summary: The growth of siliceous microalgae (diatoms) in the ice‐covered Central Arctic Ocean (CAO) can be limited by light and nutrient availability. Due to the limiting conditions, diatom growth is considered to be generally low, with highest growth rates at the sea ice edge and over partially ice‐free coastal areas. The major surface water current in the CAO is the Transpolar Drift (TPD), carrying ice and water from rivers and coastal areas across the CAO to the major outflow area, the Fram Strait. We used silicon isotopes to better understand how the TPD potentially influences the silicon cycle in the CAO. Our data show that diatom growth was taking place in all areas studied here, despite different growth limiting factors outside and under the TPD influence. In the area outside the TPD influence, nutrient availability was very low and its supply was limited, which prevented further diatom growth. Under the TPD influence, even with additional nutrient supply from the TPD, only low diatom growth was observed, most likely limited by light availability.
    Description: Key Points: Primary production and silicon utilization outside the Transpolar Drift are higher than under its influence due to more light availability. Primary production and lateral water transport under the Transpolar Drift influence were identified from silicon isotope composition. The Transpolar Drift delivers high dissolved silicon to the surface Arctic Ocean, a unique feature not seen in any other open ocean.
    Description: MCTI, Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) http://dx.doi.org/10.13039/501100003593
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    Atmospheric Wind Biases: A Challenge for Simulating the Arctic Ocean in Coupled Models? (2021)
    Details
    Publication Date: 2022-03-23
    Description: Many state‐of‐the‐art climate models do not simulate the Atlantic Water (AW) layer in the Arctic Ocean realistically enough to address the question of future Arctic Atlantification and its associated feedback. Biases concerning the AW layer are commonly related to insufficient resolution and excessive mixing in the ocean component as well as unrealistic Atlantic‐Arctic Ocean exchange. Based on sensitivity experiments with FESOM1.4, the ocean–sea‐ice component of the global climate model AWI‐CM1, we show that even if all impediments for simulating AW realistically are addressed in the ocean model, new biases in the AW layer develop after coupling to an atmosphere model. By replacing the wind forcing over the Arctic with winds from a coupled simulation we show that a common bias in the atmospheric sea level pressure (SLP) gradient and its associated wind bias lead to differences in surface stress and Ekman transport. Fresh surface water gets redistributed leading to changes in halosteric height distribution. Those changes lead to strengthening of the anticyclonic surface circulation in the Canadian Basin, so that the deep counterflow carrying warm AW gets reversed and a warm bias in the Canadian Basin develops. The SLP and anticyclonic wind bias in the Nordic Seas weaken the cyclonic circulation leading to reduced AW transport into the Arctic Ocean through Fram Strait but increased AW transport through the Barents Sea Opening. These effects together lead to a cold bias in the Eurasian Basin. An underestimation of sea ice concentration can significantly amplify the induced ocean biases.
    Description: Plain Language Summary: Coupled global climate models are used to predict anthropogenic climate change along with its impacts. The Arctic has experienced amplified warming in the recent decades compared to global mean warming and therefore is one region of intense climate research. In this context Atlantification of the Arctic Ocean has become a high priority topic. Atlantification describes the increasing impact of oceanic heat from the Atlantic Water (AW) layer of the Arctic Ocean on the sea ice cover. In climate models, the direction and strength of simulated AW circulation around the Arctic Ocean is known to be sensitive to ocean grid resolution, parametrization, boundary and surface forcing or a combination thereof. Here we show that biases in the atmospheric component of climate models can interrupt and even reverse the simulated AW circulation at depth. Such biases can be further amplified by a negative bias in simulated sea ice cover. This study shows how these surface biases can negatively impact the deep ocean circulation.
    Description: Key Points: Many state‐of‐the‐art climate models fail to simulate the properties of the Atlantic Water layer in the Arctic Ocean realistically. Biases in Arctic sea level pressure and surface winds in atmosphere models can reverse Atlantic Water circulation. The underestimation of sea‐ice cover amplifies this problem further.
    Description: European Union's Horizon 2020 Research and Innovation program
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551.46
    Language: English
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    Late Holocene Climate Changes in the Altai Region Based on a First High‐Resolution Biomarker Isotope Record From Lake Khar Nuur (2021)
    Details
    Publication Date: 2022-03-29
    Description: The Late Holocene marks a substantial cultural and economic transition in the eastern Eurasian Steppe and Altai Region with the dispersal of nomadic pastoralism. So far, paleoclimate conditions during this time remain unclear and controversial. Here, we present a high‐resolution 4.2 ka paleoclimate record from Lake Khar Nuur in the Mongolian Altai that is based on lake sediment proxies and biomarker compound‐specific δ2H analyses. Our results document increased aridity before ∼3.7 cal. ka BP, followed by two pronounced phases of warm and wet conditions from ∼3.5–2.8 to ∼2.3–1.5 cal. ka BP, and a strong increase in aridity since ∼1.5 cal. ka BP. Phases of warmer and wetter conditions coincide with a negative North Atlantic Oscillation, which has been responsible for advecting moisture into the region by more southerly‐displaced Westerlies and possibly favored the expansion of mobile nomadic pastoralism in the region.
    Description: Plain Language Summary: Nomadic pastoralism is the dominant subsistence practice in the eastern Eurasian Steppe and Altai Region since the Late Bronze Age. Whether this had climatic reasons is one of the most intriguing question, because former climatic conditions are poorly understood in this important but understudied region. To address this issue, we established a hydrological record for the last ∼4.2 ka from a high‐altitude lake in the Mongolian Altai. Our findings provide evidence of exceptionally warm and wet conditions from ∼3.5–2.8 and ∼2.3–1.5 cal. ka BP. Those favorable climate conditions likely favored productive grasslands and the widespread dispersal of nomadic pastoralism in the eastern Eurasian Steppe and Altai Region.
    Description: Key Points: A high‐resolution 4.2 ka paleoclimate record from Lake Khar Nuur in the Mongolian Altai, based on biomarker compound‐specific δ2H analyses. Our hydrological proxies record distinct changes in warm/wet and cold/dry conditions during the Late Holocene in the Altai Region: Pronounced warm/wet conditions from ∼3.5 to 2.8 cal. ka BP probably favored the widespread dispersal of nomadic pastoralism in the region.
    Description: Ernst Abbe Stiftung
    Description: https://doi.org/10.1594/PANGAEA.936512
    Keywords: ddc:551
    Language: English
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    Investigating the Basal Shear Zone of the Submarine Tuaheni Landslide Complex, New Zealand: A Core‐Log‐Seismic Integration Study (2022)
    Details
    Publication Date: 2022-03-29
    Description: Although submarine landslides have been studied for decades, a persistent challenge is the integration of diverse geoscientific datasets to characterize failure processes. We present a core‐log‐seismic integration study of the Tuaheni Landslide Complex to investigate intact sediments beneath the undeformed seafloor as well as post‐failure landslide deposits. Beneath the undeformed seafloor are coherent reflections underlain by a weakly‐reflective and chaotic seismic unit. This chaotic unit is characterized by variable shear strength that correlates with density fluctuations. The basal shear zone of the Tuaheni landslide likely exploited one (or more) of the low shear strength intervals. Within the landslide deposits is a widespread “Intra‐debris Reflector”, previously interpreted as the landslide's basal shear zone. This reflector is a subtle impedance drop around the boundary between upper and lower landslide units. However, there is no pronounced shear strength change across this horizon. Rather, there is a pronounced reduction in shear strength ∼10–15 m above the Intra‐debris Reflector that presumably represents an induced weak layer that developed during failure. Free gas accumulates beneath some regions of the landslide and is widespread deeper in the sedimentary sequence, suggesting that free gas may have played a role in pre‐conditioning the slope to failure. Additional pre‐conditioning or failure triggers could have been seismic shaking and associated transient fluid pressure. Our study underscores the importance of detailed core‐log‐seismic integration approaches for investigating basal shear zone development in submarine landslides.
    Description: Plain Language Summary: Submarine landslides move enormous amounts of sediment across the seafloor and have the potential to generate damaging tsunamis. To understand how submarine landslides develop, we need to be able to image and sample beneath the seafloor in regions where landslides have occurred. To image beneath the seafloor we generate sound waves in the ocean and record reflections from those waves, enabling us to produce “seismic images” of sediment layers and structures beneath the seafloor. We then use scientific drilling to sample the sediment layers and measure physical properties. In this study, we combine seismic images and drilling results to investigate a submarine landslide east of New Zealand's North Island. Drilling next to the landslide revealed a ∼25 m‐thick layer of sediment (from ∼75–95 m below the seafloor) that has strong variations in sediment strength and density. We infer that intervals of relatively low strength within this layer developed into the main sliding surface of the landslide. Additionally, results from within the landslide suggest that the process of landslide emplacement has induced a zone of weak sediments closer to the seafloor. Our study demonstrates how combining seismic images and drilling data helps to understand submarine landslide processes.
    Description: Key Points: We integrate scientific drilling data with seismic reflection data to investigate the submarine Tuaheni Landslide Complex. Basal shear zone of the landslide likely exploited a relatively low shear strength interval within an older (buried) mass transport deposit. Landslide emplacement seems to have induced an additional weak zone that is shallower than the interpreted base of the landslide deposit.
    Description: Marsden Fund (Royal Society of New Zealand Marsden Fund) http://dx.doi.org/10.13039/501100009193
    Description: European Consortium for Ocean Research Drilling
    Description: International Ocean Drilling Program, Science Support Program
    Description: New Zealand Ministry for Business Innovation and Employment
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.pangaea.de/10.1594/PANGAEA.928073
    Keywords: ddc:622.15 ; ddc:551
    Language: English
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    Continental Break‐Up Under a Convergent Setting: Insights From P Wave Radial Anisotropy Tomography of the Woodlark Rift in Papua New Guinea (2022)
    Details
    Publication Date: 2022-12-05
    Description: To explore the dynamic mechanism of continental rifting within a convergent setting, we determine the first P wave radial anisotropic tomography beneath the Woodlark rift in southeastern Papua New Guinea, which develops within the obliquely colliding zone between the Australian and southwest Pacific plates. The rift zone is depicted as localized low‐velocity anomalies with positive radial anisotropy, which rules out a dominant role of active mantle upwelling in promoting the rift development and favors passive rifting with decompression melting as main processes. Downwelling slab relics in the upper mantle bounding the rift zone are revealed based on observed high‐velocity anomalies and negative radial anisotropy, which may contribute to the ultra‐high pressure rock exhumations and rift initiation. Our observations thus indicate that the Woodlark rift follows a passive model and is mainly driven by slab pull from the northward subduction of the Solomon plate.
    Description: Plain Language Summary: The Woodlark rift in Papua New Guinea develops within the shear zone between the Australian and southwest Pacific plates and is one of the youngest and most rapidly extending continental rifts in the world. In this work, we analyze teleseismic P wave arrivals to study both 3‐D velocity and radial anisotropy structures of the upper mantle, offering new evidence to understand rift initiation under a generally convergent setting. Slab remnants in the upper mantle bordering the rift zone are detected and sinking into the deeper mantle. Downwelling of these slab segments may induce small scale return flows in the mantle and contribute to exhumation of the ultra‐high pressure rocks and rift development. Significant low‐velocity anomalies are revealed beneath the rift zone and have consistently positive radial anisotropy, which indicates a dominant strain in the horizontal plane and supports a passive rifting model, where mantle material is brought to shallower depths simply as a result of the extension of the lithosphere and melt is produced due to the lowered melting point at reduced pressure (decompression melting). Tensional stresses transferred from slab pull of the northward Solomon subduction are probably driving the rifting.
    Description: Key Points: P wave radial anisotropic structure beneath the young and highly extended Woodlark rift is constrained from teleseismic tomography. Downwelling of slab relics bordering the rift zone may contribute to ultra‐high pressure rock exhumation and rift development. Slab‐pull drives rift initiation and induces decompression melting in the upper mantle under the rift zone by horizontal stress transfer.
    Description: National Natural Science Foundation of China (NSFC) http://dx.doi.org/10.13039/501100001809
    Description: National Science Foundation (NSF) http://dx.doi.org/10.13039/100000001
    Description: MEXT | Japan Society for the Promotion of Science (JSPS) http://dx.doi.org/10.13039/501100001691
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: https://doi.org/10.7914/SN/XD_1999
    Description: https://doi.org/10.7914/SN/ZN_2010
    Keywords: ddc:551 ; Woodlark rift ; radial anisotropy ; decompression melting ; slab‐pull ; slab downwelling ; ultra‐high pressure rock
    Language: English
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    The Synergy of Data From Profiling Floats, Machine Learning and Numerical Modeling: Case of the Black Sea Euphotic Zone (2022)
    Details
    Publication Date: 2022-12-05
    Description: Data from profiling floats in the Black Sea revealed complex temporal and spatial relationships between physical variables and oxygen, chlorophyll and the backscattering coefficient at 700 nm, as well as some limits in understanding the details of biogeochemistry dynamics. To account for different interdependences between physical and biogeochemical properties, a feedforward backpropagation neural network (NN) was used. This NN learns from data recorded by profiling floats and predicts biogeochemical states using physical measurements only. The performance was very high, particularly for oxygen, but it decreased when the NN was applied to older data because the interrelationships between the physical and biogeochemical properties have changed recently. The biogeochemical states reconstructed by the NN using physical data produced by a coupled physical–biogeochemical operational model were better than the biogeochemical outputs of the same coupled model. Therefore, the use of data from profiling floats, physical properties from numerical models and NNs appears to be a powerful approach for reconstructing the 4D dynamics of the euphotic zone. Basin‐wide patterns and temporal variabilities in oxygen, backscattering coefficient and chlorophyll were also analyzed. Of particular interest is the reconstruction of short‐lived biogeochemical features, particularly in coastal anticyclone areas, which are difficult to observe with available floats at the basin scale.
    Description: Plain Language Summary: This study addresses the biogeochemical dynamics of the euphotic layer in the Black Sea. Observations are provided from profiling floats, and the observed biogeochemical parameters include oxygen, the backscattering coefficient at 700 nm and chlorophyll‐a. Data analysis showed complex temporal and spatial relationships between physical and biogeochemical variables and some limits in understanding the details of biogeochemical dynamics. A feedforward backpropagation neural network was developed, which can be considered an input–output mapping in which the neurons combine the input data in such a way that the output can be considered a nonlinear combination of input data. When applied to older data, the reconstruction performance decreases, suggesting a change in the dependency of biogeochemical characteristics on physical drivers caused by known climate change. A comparison with simulations from a coupled operational biogeochemical model shows that the neural network outperforms the numerical model. The newly proposed method, combining data from profiling floats, physical properties from numerical models and a backpropagation neural network, allows us to reconstruct the 4D dynamics of the euphotic layer over the period 2013–2020.
    Description: Key Points: Machine learning helps identify fundamental biogeochemical mechanisms in the Black Sea. A feedforward backpropagation neural network performs better than a coupled physical‐biogeochemical model. Data from profiling floats, physical data from numerical models and machine learning enabled the analysis of 4D biogeochemical dynamics.
    Description: MASRI
    Description: National Roadmap for Scientific Infrastructure
    Description: European Horizon 2020 project DOORS
    Description: https://resources.marine.copernicus.eu/product-detail/BLKSEA_MULTIYEAR_PHY_007_004/INFORMATION
    Description: https://resources.marine.copernicus.eu/product-detail/BLKSEA_REANALYSIS_BIO_007_005/INFORMATION
    Description: http://www.coriolis.eu.org/Data-Products/Data-selection
    Description: https://zenodo.org/record/6860705
    Keywords: ddc:551 ; biogeochemistry ; neural networks ; profiling floats ; euphotic zone
    Language: English
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    Determination of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl in Geological Reference Materials and Chondrites by Isotope Dilution ICP-MS (2020)
    Details
    Publication Date: 2022-11-28
    Description: Mass fractions of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl were determined via isotope dilution quadrupole ICP-MS in twenty-one geological reference materials (RMs) and the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3). The RMs comprise basaltic/mafic (BCR-2, BE-N, BHVO-1, BHVO-2, BIR-1, BRP-1, JB-2, OKUM, W-2, WS-E), intermediate/felsic (AGV-2, G-2, JA-2, RGM-1), ultramafic (DTS-2b, MUH-1, PCC-1, UB-N) and sedimentary (MAG-1, OU-6) rocks. Pressure digestion was applied for nonbasaltic samples to ensure effective sample digestion. For basaltic RMs, hot plate digestion was found to be sufficient for a quantitative recovery of the target elements. To minimise interferences and increase ion beam intensities during isotope ratio analyses by ICP-MS, separation of the target elements was carried out from single sample aliquots using a novel anion exchange procedure. The intermediate precision (2s) estimated from two to four replicate analyses was usually 〈 4% and results are in agreement with literature data, where available. Especially for Ag and Tl, the intermediate precision was compromised, likely due to low ion beam intensities and, hence, higher background and blank contributions. For ultramafic RMs, nugget effects and incomplete digestion might compromise the intermediate precision. Results for the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3) agree well with previously reported data.
    Keywords: ddc:551.9 ; isotope dilution ; chalcophile elements ; geological reference materials ; chondrites ; Q-ICP-MS
    Language: English
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    Chemical Geodynamics Insights From a Machine Learning Approach (2022)
    Details
    Publication Date: 2022-12-07
    Description: The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional (87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 208,207,206Pb/204Pb), it is important to examine isotopic affinities in multi‐dimensional data space. Here, we apply t‐distributed stochastic neighbor embedding (t‐SNE), a multi‐variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t‐SNE results show that the apparent overlap of MORB‐OIB data trends in 2‐3D isotope ratios diagrams does not exist in multi‐dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB‐OIB mantle sources on a global scale. Rather, MORB‐OIB sample stochastically distributed small‐scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t‐SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off‐ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t‐SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”
    Description: Plain Language Summary: The isotopic heterogeneity of basalts erupted at mid ocean ridges (MORB) and ocean islands (OIB) reflects the chemical evolution of Earth's mantle. The visual inspection of various 2D isotope ratio diagrams has fueled a four decade‐long discussion whether basalt heterogeneity reflects melting of only a small number of mantle components, and in particular, whether the apparent overlap of local data trends in global 2D isotope ratio diagrams indicates that melting of a common mantle component contributes to most MORB‐OIB. Here, we use multi‐variate statistical data analysis to show that the apparent overlap of MORB‐OIB data trends in 2D isotope ratio diagrams does not exist in multi‐dimensional isotope data space. Our finding invalidates any inference made for mantle compositional evolution based on the previously proposed existence of a common mantle component, its potential nature or distribution within the mantle. Rather, global MORB‐OIB sample small‐scale isotopic heterogeneities that are distributed stochastically in the Earth's mantle. Yet, MORB‐OIB with the same isotopic affinity, as identified by our multi‐variate data analysis, delineate several globally distributed regional domains. Within the regional geodynamic context, this discovery forms a fundamentally new basis for relating isotopic variations in MORB‐OIB to mantle geodynamics.
    Description: Key Points: Multi‐variate statistical data analysis (t‐distributed stochastic neighbor embedding) identifies global Sr‐Nd‐Hf‐Pb isotopic affinities of oceanic basalts. There is no “common mantle component;” rather, global mid ocean ridge‐ocean island basalts sample stochastically distributed small‐scale isotopic heterogeneities. Globally distributed regional domains of isotopically alike oceanic lavas define a new basis for relating isotopic variations to geodynamics.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: DAAD, German Academic Exchange Service
    Description: https://doi.org/10.25625/0SVW6S
    Description: https://doi.org/10.25625/BQENGN
    Keywords: ddc:551.9 ; mantle heterogeneity ; MORB ; OIB ; geodynamics ; t‐SNE ; radiogenic isotopes ; machine learning
    Language: English
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    Reversals in Temperature‐Precipitation Correlations in the Northern Hemisphere Extratropics During the Holocene (2022)
    Herzschuh, Ulrike ; Böhmer, Thomas ; Li, Chenzhi ; [et al.]
    Details
    Publication Date: 2022-12-07
    Description: Future precipitation levels remain uncertain because climate models have struggled to reproduce observed variations in temperature‐precipitation correlations. Our analyses of Holocene proxy‐based temperature‐precipitation correlations and hydrological sensitivities from 2,237 Northern Hemisphere extratropical pollen records reveal a significant latitudinal dependence and temporal variations among the early, middle, and late Holocene. These proxy‐based variations are largely consistent with patterns obtained from transient climate simulations (TraCE21k). While high latitudes and subtropical monsoon areas show mainly stable positive correlations throughout the Holocene, the mid‐latitude pattern is temporally and spatially more variable. In particular, we identified a reversal from positive to negative temperature‐precipitation correlations in the eastern North American and European mid‐latitudes from the early to mid‐Holocene that mainly related to slowed down westerlies and a switch to moisture‐limited convection under a warm climate. Our palaeoevidence of past temperature‐precipitation correlation shifts identifies those regions where simulating past and future precipitation levels might be particularly challenging.
    Description: Plain Language Summary: Predicting future precipitation levels reliably is more challenging than predicting temperature change. Accordingly, we need to understand the relationship between temperature and precipitation and its changes in space and time. We used climate proxy‐data derived from 2,237 pollen records from lake sediments and peats from the Northern Hemisphere extratropics for the early, middle, and late Holocene (i.e., 12,000–8,000, 8,000–4,000, 4,000–0 years before present, respectively). Our results reveal a significant latitudinal dependence and temporal variation of the temperature‐precipitation relationship. These proxy‐based variations are largely consistent with patterns obtained from simulations using climate models. While high latitudes and subtropical monsoon areas show mainly stable positive correlations throughout the Holocene (i.e., warm conditions co‐occur with wet conditions), the mid‐latitude pattern is temporally and spatially more variable. In particular, we identified a reversal to negative temperature‐precipitation correlations in the eastern North American and European mid‐latitudes from the early to middle Holocene. We hypothesize that weak westerly circulation, warm climate, and climate‐soil feedbacks limited evaporation and as such reduced convection during the middle Holocene which led to a negative relationship between temperature and precipitation. Our analysis of past temperature‐precipitation correlation shifts identifies regions where past changes in the temperature‐precipitation relationships are variable and thus where predicting precipitation might be particularly challenging in a warming climate.
    Description: Key Points: We analyzed Holocene temperature‐precipitation correlations and hydrological sensitivities using climate proxy (pollen) and model data from Northern Hemisphere extratropics. We found reversals to negative temperature‐precipitation correlations from the cold early Holocene to the warm mid‐Holocene likely related to moisture‐limited convection. Correlations and hydrological sensitivities were mostly stable positive in polar and extratropical monsoon‐areas.
    Description: EC European Research Council http://dx.doi.org/10.13039/501100000781
    Description: PALMOD
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: https://doi.pangaea.de/10.1594/PANGAEA.930512
    Description: https://doi.org/10.5281/zenodo.5910989
    Description: https://zenodo.org/record/7038402%23.YxBL1uzP3V8
    Keywords: ddc:551 ; ddc:561 ; Holocene ; pollen ; Northern Hemisphere ; temperature-precipation correlations
    Language: English
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    Stochastic Modeling Approach to Identify Uncertainties of Karst Conduit Networks in Carbonate Aquifers (2022)
    Details
    Publication Date: 2022-12-07
    Description: The characterization of the karst conduit network is an essential task to understand the complex flow system within karst aquifers. However, this task is challenging and often associated with uncertainty. Equivalent porous media approaches for modeling flow in karst aquifers fall short of capturing the hydraulic effect of individual karst features, while process‐oriented karst evolution models imply major computational efforts. In this study, we apply the Stochastic Karst Simulator (SKS) developed by Borghi et al. (2012) to generate karst conduit networks at a regional scale of a highly karstified carbonate aquifer located in the Eastern Mediterranean region and extensively used for water supply. The SKS generates conduit network geometries reasonably quick, using a mathematical proxy that mimics conduit evolution. The conduit simulation is based on a conceptual model of the genesis of the aquifer, consisting of different karstification phases. The stochastic approach of the algorithm enables us to generate an ensemble of conduit network realizations and to represent the uncertainties of these simulations in a Karst Probability Map. With only soft input information to constrain conduit evolution, multiple equivalent realizations yield similar resulting network geometries, indicating a robust approach. The presented methodology is numerically efficient, and its input can be easily adjusted. Subsequently, the resulting stochastic spatial distribution of conductivities can be employed for the parametrization of regional karst groundwater models.
    Description: Key Points: We statistically generate multiple sets of karst conduit network geometries using input data based on soft information. The resulting Karst Probability Map accounts for uncertainty in the spatial distribution of the karst conduit network. Our approach can assist in the integration of soft information into the parametrization of karst groundwater models.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: https://doi.org/10.14279/depositonce-16021
    Keywords: ddc:551 ; karst conduit modeling ; stochastic modeling ; structural uncertainty ; karst probability mapping ; groundwater modeling
    Language: English
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    Pore Space Topology Controls Ultrasonic Waveforms in Dry Volcanic Rocks (2022)
    Details
    Publication Date: 2022-12-06
    Description: Pore space controls the mechanical and transport properties of rocks. At the laboratory scale, seismic modeling is usually performed in relatively homogeneous settings, and the influence of the pore space on the recorded wavefields is determined by rock‐fluid interactions. Understanding this influence in dry rocks is instrumental for assessing the impact of pore topology on waves propagating in heterogeneous environments, such as volcanoes. Here, we simulated the propagation of shear waves as a function of pore space parameters in computational models built as proxies for volcanic rocks. The spectral‐element simulations provide results comparable with ultrasonic experiments, and the outcome shows that the size, shape, volume, and location of pores impact amplitudes and phases. These variations intensify in waveform coda after multiple scattering. Our results confirm that pore topology is one of the primary regulators of the propagation of elastic waves in dry rocks regardless of porosity.
    Description: Plain Language Summary: Pores control the non‐elastic behavior and, in general, the petrophysical and mechanical properties of rocks. Such properties are essential to assess potential resources such as aquifers and reservoirs or hazards posed by earthquakes, volcanoes, and constructions. The factors controlling the elasticity of rocks are texture, pore space and the fluids filling the pores. While volcanoes represent a key target for rock characterization, measuring and modeling these factors in volcanic rocks remains challenging due to their intrinsic heterogeneities. In this study, we analyzed how pore space parameters influence the overall elastic properties of rocks by changing one parameter at a time. We created synthetic samples and performed computational simulations that show the individual contribution of the amount, size, location, and shape on waveform phases and amplitudes. The findings demonstrate that we can constrain the pore space in heterogeneous rocks in simple but realistic scenarios. Our results are the first step to provide computationaly‐driven forward models of seismic signals in heterogeneous volcanic media, necessary to predict the responses of volcanic rocks to stress.
    Description: Key Points: Computational modeling quantifies the influence of pore space topology on S‐wave propagation in volcanic rocks. Amount, size and location of pores impact ultrasonic wave propagation in dry rocks independently of porosity. Path effects dominate the waveforms and depend on the location of the pores.
    Description: https://doi.org/10.17632/b5p54xtvv9.3
    Keywords: ddc:550.78 ; volcanic rocks ; pore space topology ; S-wave propagation ; computational modeling
    Language: English
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    Denitrification‐Driven Transcription and Enzyme Production at the River‐Groundwater Interface: Insights From Reactive‐Transport Modeling (2022)
    Details
    Publication Date: 2022-12-06
    Description: Molecular‐biological data and omics tools have increasingly been used to characterize microorganisms responsible for the turnover of reactive compounds in the environment, such as reactive‐nitrogen species in groundwater. While transcripts of functional genes and enzymes are used as measures of microbial activity, it is not yet clear how they are quantitatively related to actual turnover rates under variable environmental conditions. As an example application, we consider the interface between rivers and groundwater which has been identified as a key driver for the turnover of reactive‐nitrogen compounds, that cause eutrophication of rivers and endanger drinking water production from groundwater. In the absence of measured data, we developed a reactive‐transport model for denitrification that simultaneously predicts the distributions of functional‐gene transcripts, enzymes, and reaction rates. Applying the model, we evaluate the response of transcripts and enzymes at the river‐groundwater interface to stable and dynamic hydrogeochemical regimes. While functional‐gene transcripts respond to short‐term (diurnal) fluctuations of substrate availability and oxygen concentrations, enzyme concentrations are stable over such time scales. The presence of functional‐gene transcripts and enzymes globally coincides with the zones of active denitrification. However, transcript and enzyme concentrations do not directly translate into denitrification rates in a quantitative way because of nonlinear effects and hysteresis caused by variable substrate availability and oxygen inhibition. Based on our simulations, we suggest that molecular‐biological data should be combined with aqueous geochemical data, which can typically be obtained at higher spatial and temporal resolution, to parameterize and calibrate reactive‐transport models.
    Description: Plain Language Summary: Molecular‐biological tools can detect how many enzymes, functional genes, and gene transcripts (i.e., precursors of enzyme production) associated with a microbial reaction exist in a sample from the environment. Although these measurements contain valuable information about the number of bacteria and how active they are, they do not directly say how quickly a contaminant like nitrate disappears. Nitrate, from agriculture and other sources, threatens groundwater quality and drinking water production. In the process of denitrification, bacteria can remove nitrate by converting it into harmless nitrogen gas using specialized enzymes. The interface between rivers and groundwater is known as a place where denitrification takes place. In this study, we use a computational model to simulate the coupled dynamics of denitrification, bacteria, transcripts, and enzymes when nitrate‐rich groundwater interacts with a nearby river. The simulations yield complex and nonunique relationships between the denitrification rates and the molecular‐biological variables. While functional‐gene transcripts respond to daily fluctuations of environmental conditions, enzyme concentrations and genes are stable over such time scales. High levels of functional‐gene transcripts therefore provide a good qualitative indicator of reactive zones. Quantitative predictions of nitrate turnover, however, will require high‐resolution measurements of the reacting compounds, genes, and transcripts.
    Description: Key Points: We simulate the distributions of functional‐gene transcripts and enzymes related to denitrification at the river‐groundwater interface. Functional‐gene transcripts respond quickly to diurnal fluctuations of substrate and oxygen concentrations. Substrate limitation and oxygen inhibition impede the direct prediction of denitrification rates from transcript or enzyme concentrations.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.5281/zenodo.6584591
    Description: https://gitlab.com/astoeriko/nitrogene
    Description: https://doi.org/10.5281/zenodo.6584641
    Description: https://gitlab.com/astoeriko/adrpy
    Description: https://doi.org/10.5281/zenodo.5213947
    Description: https://github.com/aseyboldt/sunode
    Keywords: ddc:551 ; reactive‐transport modeling ; denitrification ; groundwater‐river interface ; functional genes ; transcripts ; molecular biology
    Language: English
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    On the Role of Rheological Memory for Convection‐Driven Plate Reorganizations (2022)
    Details
    Publication Date: 2022-12-10
    Description: Understanding the temporal variability of plate tectonics is key to unraveling how mantle convection transports heat, and one critical factor for the formation and evolution of plate boundaries is rheological “memory,” that is, the persistence of weak zones. Here, we analyze the impact of such damage memory in global, oceanic‐lithosphere‐only models of visco‐plastic mantle convection. Self‐consistently‐formed weak zones are found to be reactivated in distinct ways, and convection preferentially selects such damaged zones for new plate boundaries. Reactivation of damage zones increases the frequency of plate reorganizations, and hence reduces the dominant periods of surface heat loss. The inheritance of distributed lithospheric damage thus dominates global surface dynamics over any local boundary stabilizing effects of weakening. In nature, progressive generation of weak zones may thus counteract and perhaps overcome any effects of reduced convective vigor throughout planetary cooling, with implications for the frequency of orogeny and convective transport throughout Wilson cycles.
    Description: Plain Language Summary: Understanding how and why the motion of the lithosphere changes over time is important since this is telling us how planets with a plate tectonic style of heat transport evolve by thermo‐chemical mantle convection. One important factor for the evolution of plate boundaries is hysteresis, that is, memory of past deformation. Inherited weak zones, such as sutures, and progressive weakening are well documented in the geological record. Convection with damage shows dynamical behavior that is different from pure plastic failure without memory, or homogenous lithosphere that is being newly broken. We analyze the impact of damage with global, oceanic‐lithosphere‐only models of plate‐like mantle convection. Weak zones that are formed in an initially homogenous material are found to be reactivated subsequently in distinct ways. Within our tectonic system model, convection preferentially selects pre‐damaged zones for new, active plate boundaries. This reactivation increases the frequency of plate reorganizations compared to models without damage, and also changes the time‐dependence of cyclic surface heat loss. In nature, the progressive generation of weak zones over planetary history may counteract and perhaps overcome any effects of reduced convective vigor during cooling. This has implications for the frequency of mountain building and understanding Wilson cycles.
    Description: Key Points: Results from global, plate‐generating convection models with damage. Self‐consistently formed persistent weak zones lead to more frequent plate reorganizations. Accumulation of weak zones might counteract decrease in convective vigor for tectonic variability.
    Description: NSF EAR
    Description: Division of Earth Sciences http://dx.doi.org/10.13039/100000160
    Description: https://geodynamics.org/resources/citcoms
    Description: https://doi.org/10.5281/zenodo.6546322
    Keywords: ddc:551 ; plate tectonics ; visco-plastic convection models
    Language: English
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    Imaging the Absorbing Feeding and Eruptive Pathways of Deception Island, Antarctica (2022)
    Details
    Publication Date: 2022-12-10
    Description: Deception Island is one of the most active and best‐documented volcanoes in Antarctica. Since its last eruption in 1970, several geophysical surveys have targeted reconstructing its magmatic systems. However, geophysics fails to reconstruct the pathways magma and fluids follow from depth to erupt at the surface. Here, novel data selection strategies and multi‐frequency absorption inversions have been framed in a Geographical Information System, using all available geological (vents and faults distribution), geochemical and geophysical knowledge of the volcano. The result is the detection of these eruptive pathways. The model offers the first image of the magma and associated fluids pathways feed the 1967, 1969, and 1970 eruptions. Results suggest that future ascending paths might lead to active research bases and zones of planned helicopter rescue. The connection between seismic absorption, temperature, and fluid content makes it a promising attribute for detecting and monitoring eruptions at active calderas.
    Description: Plain Language Summary: Deception Island is the gateway for tourists to Antarctica and a laboratory to understand ice‐capped volcanoes and their eruptions. While the Island has been the target of many geophysical studies, no clear tomographic model shows how deep eruptive pathways of its last eruptions have reached the surface in the 1960s and 1970s. This is a recurrent topic in volcano geophysics: dikes and fluid migrations develop across structures considered too small to be detected by tomographic techniques. This paper demonstrates that seismic absorption has sufficient sensitivity to temperature and fluid content to detect these pathways. Once integrated within a Geographical Information System with all the information we have on the volcano, the models resolve the feeding systems of these eruptions, from a tectonically deformed deep magma chamber to shallow cold dyke intrusions and fluid migrations still feeding the volcano today. The correlation between seismic absorption, temperature, and fluid content offers a new tool for detecting and monitoring shallow volcanic hazards.
    Description: Key Points: High absorption detects deep eruptive pathways from the caldera center to its rim. Absorption imaging reconstructs shallow pathways of hazardous materials. Seismic absorption is sensitive to thermal anomalies at depth.
    Description: https://doi.org/10.5281/zenodo.6561124
    Description: https://zenodo.org/badge/latestdoi/493744216
    Keywords: ddc:551 ; seismic absorption ; seismic tomography ; Deception Island ; Volcanology ; remote sensing
    Language: English
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    Numerical Modeling of Structurally Controlled Ore Formation in Magmatic‐Hydrothermal Systems (2022)
    Details
    Publication Date: 2022-12-10
    Description: Faults and fractures can be permeable pathways for focused fluid flow in structurally controlled ore‐forming hydrothermal systems. However, quantifying their role in fluid flow on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study introduces a modified numerical representation of m‐scale fault zones using lower‐dimensional elements (here, one‐dimensional [1D] elements in a 2D domain) to resolve structurally controlled fluid flow with coarser mesh resolutions and apply the method to magmatic‐hydrothermal ore‐forming systems. We modeled horizontal and vertical structure‐controlled magmatic‐hydrothermal deposits to understand the role of permeability and structure connectivity on ore deposition. The simulation results of vertically extended porphyry copper systems show that ore deposition can occur along permeable vertical structures where ascending, overpressured magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location control the distribution of ore grades. In highly permeable structures, the mineralization can span up to 3 km vertically, resulting in heat‐pipe mechanisms that promote the ascent of a magmatic vapor phase to an overlying structurally controlled epithermal system. Simulations for the formation of subhorizontal vein‐type deposits suggest that the major control on fluid flow and metal deposition along horizontal structures is the absence of vertical structures above the injection location but their presence at greater distances. Using a dynamic permeability model mimicking crack‐seal mechanisms within the structures leads to a pulsating behavior of fracture‐controlled hydrothermal systems and prevents the inflow of ambient fluids under overpressured conditions.
    Description: Plain Language Summary: Faults and fractures can serve as permeable pathways for focused fluid flow in the subsurface and therefore be essential geological features for the formation of economic mineral deposits. However, quantifying their role in the hydrothermal systems on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study presents a modified numerical representation of m‐scale fault zones with variable orientations to understand the hydrology of magmatic‐hydrothermal ore‐forming systems. The vertically extended systems simulation results show that ore deposition can occur along permeable vertical structures where ascending magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location can directly control the distribution of ore grades. In contrast, mineralization in horizontal structures requires the absence of vertical structures above the injection location of metal‐bearing magmatic volatiles but their presence at greater distances. Our model also shows how dynamic opening and closing of the structures in response to magmatic degassing can lead to a pulsating behavior and prevent the downflow of ambient fluids.
    Description: Key Points: We describe structurally controlled fluid flow by representing faults and fractures as one‐dimensional line elements within a 2D modeling domain. Vertical structures are efficient pathways for focused fluid flow and formation of high‐grade mineralization. Ore formation in horizontal fractures requires a hydraulic connection to distal vertical fault zones.
    Description: German Federal Ministry of Education and Research
    Description: Deutsche Forschungsgemeinschaft, DFG http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Recruitment Initiative
    Keywords: ddc:551 ; magmatic‐hydrothermal systems ; ore deposits ; fluid flow ; numerical simulations ; faults and fractures
    Language: English
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    Probability Distributions of Radiocarbon in Open Linear Compartmental Systems at Steady‐State (2022)
    Details
    Publication Date: 2022-06-26
    Description: Radiocarbon (14C) is commonly used as a tracer of the carbon cycle to determine how fast carbon moves between different reservoirs such as plants, soils, rivers, or oceans. However such studies mostly emphasize the mean value (as Δ14C) of an unknown probability distribution. We introduce a novel algorithm to compute Δ14C distributions from knowledge of the age distribution of carbon in linear compartmental systems at steady‐state. Our results demonstrate that the shape of the distributions might differ according to the speed of cycling of ecosystem compartments and their connectivity within the system, and might contain multiple peaks and long tails. The distributions are also sensitive to the variations of Δ14C in the atmosphere over time, as influenced by the counteracting anthropogenic effects of fossil‐fuel emissions (14C‐free) and nuclear weapons testing (excess 14C). Lastly, we discuss insights that such distributions can offer for sampling and design of experiments aiming to capture the precise variance of Δ14C values present in the multi‐compartmental ecosystems.
    Description: Plain Language Summary: Radiocarbon (14C) is a radioactive isotope of carbon prominent in environmental sciences for tracing the dynamics of ecosystems, especially as recent changes in atmospheric radiocarbon allow tracking excess 14C created by nuclear weapons testing in the atmosphere on timescales shorter than what can be determined using radioactive decay. For climate change mitigation, a crucial uncertainty is the time carbon captured through photosynthesis spends in ecosystems before being released. For this purpose, radiocarbon can be valuable as a biological tracer; however, it is necessary to accurately link the real age of carbon and its radiocarbon age, as they usually differ. Forests and soils are open systems, connecting components with intrinsically different cycling timescales, so that the mean age comes from an age distribution that is usually unknown. Here, we developed an algorithm to compute the 14C contents for models consisting of multiple interconnected carbon pools. Our approach offers more accurate estimations of the mean 14C content of the system and computations of the distribution of 14C within the system at different points in time. Results obtained from this method can provide additional insights on the dynamics of the carbon cycle in multiple compartments, and can help to better interpret observations.
    Description: Key Points: Probability distributions of radiocarbon in ecosystem compartments can be derived from carbon age distributions. The shape of these distributions vary according to the speed of carbon cycling and the year of observation. Probability distributions of radiocarbon provide insights to study carbon dynamics and to interpret radiocarbon data.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Max‐Planck‐Gesellschaft (MPG) http://dx.doi.org/10.13039/501100004189
    Description: https://doi.org/10.5281/zenodo.6373329
    Keywords: ddc:551.9
    Language: English
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    A Combined Cosmogenic Nuclides Approach for Determining the Temperature‐Dependence of Erosion (2022)
    Details
    Publication Date: 2022-06-26
    Description: Physical weathering in cold, steep bedrock hillslopes occurs at rates that are thought to depend on temperature, but our ability to quantify the temperature‐dependence of erosion remains limited when integrating over geomorphic timescales. Here, we present results from a 1D numerical model of in‐situ cosmogenic 10Be, 14C, and 3He concentrations that evolve as a function of erosion rate, erosion style, and ground surface temperature. We used the model to explore the suitability of these nuclides for quantifying erosion rates in areas undergoing non‐steady state erosion, as well as the relationship between bedrock temperature, erosion rate, and erosional stochasticity. Our results suggest that even in stochastically eroding settings, 10Be‐derived erosion rates of amalgamated samples can be used to estimate long‐term erosion rates, but infrequent large events can lead to bias. The ratio of 14C to 10Be can be used to evaluate erosional stochasticity, and to determine the offset between an apparent 10Be‐derived erosion rate and the long‐term rate. Finally, the concentration of 3He relative to that of 10Be, and the paleothermometric interpretations derived from it, are unaffected by erosional stochasticity. These findings, discussed in the context of bedrock hillslopes in mountainous regions, indicate that the 10Be‐14C‐3He system in quartz offers a method to evaluate the temperature‐sensitivity of bedrock erosion rates in cold, high‐alpine environments.
    Description: Plain Language Summary: All mountains erode, but not all mountains erode in the same way and at the same rate. In cold mountainous landscapes, temperature is thought to be an important control on erosion. Previous research suggests that rocks fracture by frost most effectively at temperatures between −3°C and −8°C, and that the warming and thawing of permanently frozen ground (permafrost) destabilizes hillslopes and leads to more and larger rockfalls. However, our ability to test these hypotheses is limited, due to difficulties in measuring or estimating erosion rates and linking them with the temperatures that rocks experience. In this paper we present the results of a computer modeling study that tests the suitability of geochemical tools as measures of erosion rate, erosion style, and long‐term bedrock temperature. We find that these geochemical tracers, called cosmogenic nuclides, can be used to determine erosion rates, even in places that are prone to rare rockfalls, together with the long‐term bedrock temperature. They are therefore uniquely suitable for evaluating the link between temperatures and erosion rates in cold bedrock hillslopes over long timescales.
    Description: Key Points: Cosmogenic 10Be, 14C, and 3He is used to determine erosion rates, erosion styles, and bedrock temperatures in cold regions. 14C/10Be ratios of surface samples reflect the depth at which material was previously eroded, allowing for determination of erosion style. 14C/10Be ratios combined with 10Be‐derived erosion rates improve erosion rate estimates in stochastically eroding environments.
    Description: European Research Council Horizon 2020
    Description: https://doi.org/10.5880/GFZ.3.3.2022.001
    Keywords: ddc:551
    Language: English
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    Multi‐Band Raman Analysis of Radiation Damage in Zircon for Thermochronology: Partial Annealing and Mixed Signals (2022)
    Details
    Publication Date: 2022-06-24
    Description: Four zircon Raman bands were previously calibrated to give consistent estimates of the accumulated self‐irradiation α‐dose in unannealed volcanic samples. Partial annealing of radiation damage produces inconsistent values because of differences in the relative annealing sensitivities. The damage estimates based on the external rotation band (DER) at ∼356 cm−1 and that based on the ν2(SiO4) band (D2) at ∼438 cm−1 are the most and least sensitive to damage annealing. The D2/DER‐ratio thus provides a numerical estimate of the extent of geologic annealing that a zircon sample has experienced. This ratio characterizes the thermal history of a zircon sample but also its state of radiation damage during the course of its geologic history, and thus the manner in which this state influences other thermochronologic methods. Meaningful interpretation of the zircon Raman age requires that the spectra are free of measurement artifacts. The major artifacts result from micrometer‐scale gradients of the damage densities within a zircon grain due to uranium and thorium zoning. The micrometer‐sized sampled volume may span different densities, producing overlapping spectra, causing apparent peak broadening, overestimated damage densities, and zircon Raman ages. The D3/D2‐ratio of the damage densities calculated from the ν3(SiO4) and ν2(SiO4) bands, most and least affected by overlap, is an efficient indicator of a meaningless signal. It reveals overlap in annealed and unannealed samples, because the used bands have similar responses to annealing. Multi‐band Raman maps can be converted to damage‐ratio maps for screening zircon mounts, and selecting spots for thermochronologic investigations.
    Description: Plain Language Summary: Radioactive processes cause damage to the lattice of zircon crystals. This damage can be measured with a Raman instrument. Such measurements are important for methods determining the ages and thermal histories of zircon grains in rocks. Thus, the Raman measurements must be reliable and meaningful. This work proposes tools for detecting effects that hinder the interpretation of zircon Raman data. These effects are mixed signals and loss of damage due to exposure to elevated temperatures in the geologic environment. Zircon Raman spectra have different bands that respond differently to mixed signals and temperature. The ratio of the damage estimates from the least and most temperature‐sensitive bands thus indicates partial annealing. Raman spectra of zoned zircons often straddle areas with different lattice damage. Their overlapping signals cause artificial band broadening, and a damage overestimation. The ratio of the damage estimated from the least and the most affected bands identifies mixed signals and allows to reject unsuitable samples. The damage ratios can also be plotted in maps for damage screening and for selecting optimal spots for measurements.
    Description: Key Points: Annealing and inhomogeneous damage are two main factors hindering radiation‐damage estimation for zircon Raman dating. Comparison of internal and external Raman bandwidths allows to detect partial annealing of radiation damage in zircon. Comparison of internal Raman bandwidths allows to detect artifactual broadening in zoned zircon.
    Description: Studienstiftung des Deutschen Volkes (Studienstiftung) http://dx.doi.org/10.13039/501100004350
    Description: http://dx.doi.org/10.25532/OPARA-155
    Keywords: ddc:549 ; ddc:551.9
    Language: English
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    The Subducting Slab as a Chromatographic Column: Regimes of Sub‐Solidus Mass Transport as a Function of Lithospheric Hydration State, With Special Reference to the Fate of Carbonate (2022)
    Details
    Publication Date: 2022-06-24
    Description: We investigate the chemical budget of subduction zones at sub‐solidus conditions using a thermodynamic‐numerical simulation in which all major rock components are treated as soluble and potentially mobile in aqueous fluids. This new strategy significantly improves the accuracy of predicted fluid‐rock equilibrium compositions in open petrological systems. We show that all slabs release volatiles and nonvolatiles to the mantle wedge, contributing to its refertilization. But some mobile constituents, such as alkali and alumina, may be trapped along layer boundaries or traverse without interaction depending on chemical contrasts between adjacent lithologies. The accumulation of igneous alumina and silica in the limestones of the central‐eastern Pacific slabs drives their decarbonation and is marked by metasomatic garnet growth. Those slabs are also predicted to lose much of their alkalis before sub‐arc depth. Even when they are produced in the altered mafic and ultramafic layers, fluids reach the slab/mantle wedge interface with distinct compositional signatures that are typical of the sedimentary cover. We distinguished supply and transport limited regimes of element subduction by testing the sensitivity of our mass balance to changes in slab hydration state (HS). Transport limited slabs sensitive to HS include notably a hotspot of carbon release to the mantle wedge (e.g., Costa Rica). Finally, we show that the quantitative budgets do depend on the geometry of fluid flows, and on assuming that slabs are mechanically continuous structures, which is questionable. Taken together, these insights will help better constrain the long‐term chemical evolution of the shallow planetary interior, and the thermomechanical behavior of the subduction interface.
    Description: Plain Language Summary: Subduction zones return chemical elements from the surface to the deep Earth. But quantifying this transfer has been challenging. Here, we present a model where all major elements are partly mobile in the fluid phase, enabling us to compile a chemical budget for subduction zones in which only fluids mediate mass transport. We identify transport and supply regimes of element subduction as a function of lithospheric hydration state, rock compositions, and slab temperature. We show that the transport of many rock‐forming elements such as SiO2, CaO, and Al2O3, within and out of the slab, modifies rock composition and contributes to the efficiency of slab decarbonation. Our model of subduction fluid and rock compositions has important implications to understand the role of slab‐derived metasomatic fluid in modifying the composition of the mantle wedge over time, the mechanical properties of deeply subducted rocks, and it will inform future investigations for the high‐pressure petrology of rocky planets in general.
    Description: Key Points. Inter dependence of element transfers in subduction zones. Thermodynamics of intra‐slab metasomatism of major elements. Transport‐ and supply limited regimes of carbonate subduction.
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: Branco Weiss Fellowship—Society in Science
    Description: Swiss National Science Foundation
    Description: https://osf.io/y84d2/
    Keywords: ddc:551
    Language: English
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    Electrochemical Properties of Peat Particulate Organic Matter on a Global Scale: Relation to Peat Chemistry and Degree of Decomposition (2022)
    Details
    Publication Date: 2022-06-22
    Description: Methane production in peatlands is controlled by the availability of electron acceptors for microbial respiration, including peat dissolved organic matter (DOM) and particulate organic matter (POM). Despite the much larger mass of POM in peat, knowledge on the ranges of its electron transfer capacities—electron accepting capacity (EAC), and electron donating capacity (EDC)—is scarce in comparison to DOM and humic and fulvic acids. Moreover, it is unclear how peat POM chemistry and decomposition relate to its EAC and EDC. To address these knowledge gaps, we compiled peat samples with varying carbon contents from mid to high latitude peatlands and analyzed their EACPOM and EDCPOM, element ratios, decomposition indicators, and relative amounts of molecular structures as derived from mid infrared spectra. Peat EACPOM and EDCPOM are smaller (per gram carbon) than EAC and EDC of DOM and terrestrial and aquatic humic and fulvic acids and are highly variable within and between sites. Both are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. Element ratio‐based models failed to predict EACPOM and EDCPOM, while mid infrared spectra‐based models can predict peat EACPOM to a large extent, but not EDCPOM. We suggest a conceptual model that describes how vegetation chemistry and decomposition control polymeric phenol and quinone contents as drivers of peat EDCPOM and EACPOM. The conceptual model implies that we need mechanistic models or spatially resolved measurements to understand the variability in peat EDCPOM and EACPOM and thus its role in controlling methane formation.
    Description: Plain Language Summary: Peatlands accumulated large amounts of carbon via photosynthesis and slow decomposition of senesced plant material. Microorganisms within the peat form methane. For this reason, peatlands are important global sources of the greenhouse gas methane and therefore can contribute to climate change. In order to produce methane, the microorganisms have to transfer electrons between compounds in respiration processes. Only recently, it has been found that the peat itself can reversibly transfer electrons and that its capacities to reversibly accept electron accepting capacity (EAC) and reversibly donate electron donating capacity (EDC) electrons are large. We investigated which conditions favor large or small EAC and EDC of peat so that we can better explain methane formation. We argue that vegetation and decomposition control the amount of phenols and quinones—molecules in the peat that presumably are responsible for most of the peat's EAC and EDC. The EAC and EDC probably are largest for peat formed from vegetation rich in quinones and phenols, such as shrubs, and smaller for other vegetation types, for example, certain mosses. Intense decomposition may reduce both the EAC and EDC.
    Description: Key Points: Peat particulate organic matter electron accepting and donating capacities per grams of carbon are smaller than for humic and fulvic acids. Both capacities are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. We explain these patterns with parent vegetation chemistry and conditions during decomposition.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: CAS | Youth Innovation Promotion Association (YIPA) http://dx.doi.org/10.13039/501100012492
    Description: https://github.com/henningte/redoxpeat
    Keywords: ddc:551.9
    Language: English
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    Impact of Spreading Rate and Age‐Offset on Oceanic Transform Fault Morphology (2022)
    Details
    Publication Date: 2022-06-22
    Description: Oceanic transform faults (OTFs) are an inherent part of seafloor spreading and plate tectonics, whereas the process controlling their morphology remains enigmatic. Here, we systematically quantify variations in transform morphology and their dependence on spreading rate and age‐offset, based on a compilation of shipborne bathymetric data from 94 OTFs at ultraslow‐ to intermediate‐spreading ridges. In general, the length, width and depth of OTFs scale systematically better with age‐offset rather than spreading rate. This observation supports recent geodynamic models proposing that cross‐transform extension scaling with age‐offset, is a key process of transform dynamics. On the global scale, OTFs with larger age‐offsets tend to have longer, wider, and deeper valleys. However, at small age‐offsets (〈5 Myr), scatters in the depth and width of OTFs increase, indicating that small age‐offset OTFs with weak lithospheric strength are easily affected by secondary tectonic processes.
    Description: Plain Language Summary: In the past 5 decades, studies on oceanic transform faults (OTFs) have revealed significant complexity in their morphology, which calls for detailed quantitative analysis to study the processes controlling the morphology of OTFs. Using the most complete and advanced compilation of bathymetric data from ultraslow‐ to intermediate‐spreading ridges, we parameterized the morphological characteristics of OTFs and extracted length, width and depth for each transform fault from the compiled bathymetric data. Moreover, correlations between these morphological parameters and related tectonic factors (e.g., spreading rate, age‐offset) were investigated in this study. We find that correlations between morphological features and spreading rate are rather weak. Comparison of correlations suggests that age‐offset scales better with the morphological parameters, along with scatters mostly at small age‐offsets, indicating small‐age‐offset OTFs are unstable due to their weak lithospheric strength. Our observation evidences extensional tectonics at OTFs.
    Description: Key Points: We compiled multibeam bathymetric data of 94 oceanic transform faults (OTFs) to quantify their morphological characteristics. Morphology of OTFs is dominated by age‐offset rather than spreading rate. Transform valleys get systematically deeper and wider with increasing age‐offset, implying extensional tectonics at OTFs.
    Description: China Scholarship Council
    Description: http://doi.org/10.5281/zenodo.4774185
    Keywords: ddc:551
    Language: English
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    Thermolab: A Thermodynamics Laboratory for Nonlinear Transport Processes in Open Systems (2022)
    Details
    Publication Date: 2022-06-28
    Description: We developed a numerical thermodynamics laboratory called “Thermolab” to study the effects of the thermodynamic behavior of nonideal solution models on reactive transport processes in open systems. The equations of the state of internally consistent thermodynamic data sets are implemented in MATLAB functions and form the basis for calculating Gibbs energy. A linear algebraic approach is used in Thermolab to compute Gibbs energy of mixing for multicomponent phases to study the impact of the nonideality of solution models on transport processes. The Gibbs energies are benchmarked with experimental data, phase diagrams, and other thermodynamic software. Constrained Gibbs minimization is exemplified with MATLAB codes and iterative refinement of composition of mixtures may be used to increase precision and accuracy. All needed transport variables such as densities, phase compositions, and chemical potentials are obtained from Gibbs energy of the stable phases after the minimization in Thermolab. We demonstrate the use of precomputed local equilibrium data obtained with Thermolab in reactive transport models. In reactive fluid flow the shape and the velocity of the reaction front vary depending on the nonlinearity of the partitioning of a component in fluid and solid. We argue that nonideality of solution models has to be taken into account and further explored in reactive transport models. Thermolab Gibbs energies can be used in Cahn‐Hilliard models for nonlinear diffusion and phase growth. This presents a transient process toward equilibrium and avoids computational problems arising during precomputing of equilibrium data.
    Description: Plain Language Summary: The behavior of Earth materials, rocks, minerals, melts, fluids, and gases is important to predict physical processes in the Earth with computer models. The purpose of this is to study how the changes of variables such as fluid and solid composition influence the diffusion, fluid flow, and reaction in rocks. Here, we present a set of computer codes, called Thermolab, to calculate important physical properties such as density and chemical composition of solids, fluids, and melts in chemical equilibrium. The calculations are based on the Gibbs energy that exists for every material. We use computer codes, written in MATLAB/OCTAVE language, to show how this Gibbs energy is calculated and used to compute chemical equilibrium and find the physical properties such as density and chemical composition. We discuss techniques for accurate calculation of chemical equilibrium and physical properties in real rocks. Finally, we use Thermolab to formulate a computer model of fluids reacting with rocks. We find that chemical composition of the fluid and rock strongly affects the speed and shape of the boundary between reacted and unreacted rock. Thermolab can be used in phase growth models to investigate the way in which rocks develop toward equilibrium.
    Description: Key Points: Thermolab: a set of MATLAB codes is presented to perform equilibrium and nonequilibrium thermodynamic calculations. Local thermodynamic equilibrium is used to study effects of nonideality of solution models on nonlinear transport processes. Nonlinear diffusion processes are investigated with Thermolab providing a transient natural physical process toward equilibrium.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Russian Ministry of Science and Higher Education
    Description: https://hansjcv.github.io/Thermolab/
    Description: https://doi.org/10.5281/zenodo.6383253
    Keywords: ddc:551.9 ; ddc:541.36
    Language: English
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    Toward Reconciling Radiocarbon Production Rates With Carbon Cycle Changes of the Last 55,000 Years (2022)
    Details
    Publication Date: 2022-06-28
    Description: Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches.
    Description: Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Swedish Research Concil
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.1594/PANGAEA.871273
    Description: https://www.ncdc.noaa.gov/paleo-search/study/31772
    Description: https://doi.org/10.1594/PANGAEA.914500
    Description: https://www.iceandclimate.nbi.ku.dk/data/
    Description: https://doi.org/10.1594/PANGAEA.932965
    Keywords: ddc:551.9
    Language: English
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    Precipitation and Lake Water Evaporation Recorded by Terrestrial and Aquatic n‐Alkane δ2H Isotopes in Lake Khar Nuur, Mongolia (2022)
    Details
    Publication Date: 2022-06-28
    Description: The compound‐specific hydrogen isotopic composition (δ2H) of n‐alkanes is a valuable proxy to investigate hydrological conditions in lake sediments. While terrestrial n‐alkanes reflect the isotopic signal of the local precipitation, aquatic n‐alkanes incorporate the isotopic signal of the lake's water, which can be strongly modulated by evaporative enrichment. So far, the spatial distribution of the terrestrial and aquatic δ2H signal within lakes have not systematically been investigated. Here, we present compound‐specific δ2H results of terrestrial (δ2HC31) and aquatic (δ2HC23) n‐alkanes of surface sediment samples from Lake Khar Nuur, a semi‐arid and high‐altitude lake in the Mongolian Altai, and additionally investigate the δ2H signal of topsoils from the catchment. Our results show that the majority of the n‐alkane δ2H values from the catchment topsoils correspond well with modeled local growing season precipitation (JJAS). However, few samples in the northern catchment show more positive δ2H values possibly due to increased evapo(transpi)ration by southward exposition and shallower soils there. The only small variability of δ2HC31 in the surface sediments is in the range of most topsoils δ2H from the catchment, and thus, well reflects local growing season precipitation. δ2HC23 in surface sediment samples from the central and deepest parts of the lake, that is, the lake's sediment accumulation zones, shows distinctly more positive δ2HC23 values due to evaporative lake water enrichment. Consequently, Δaq‐terr, which is the isotopic offset between δ2HC23 and δ2HC31, indicates distinct lake water enrichment in the lake's accumulation zones and is a valuable proxy to investigate past hydrological changes.
    Description: Key Points: The hydrogen isotopic composition of terrestrial C31 n‐alkanes reflects the local growing season precipitation at Lake Khar Nuur. Aquatic C23 n‐alkanes incorporate the isotopic signal of the lake's water, which is strongly modulated by evaporative enrichment. The isotopic offset between C23 and C31 is a valuable proxy for evaporation in the lake and past hydrological changes in the catchment.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.940115
    Keywords: ddc:551.9
    Language: English
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    Formation of fused aggregates under long‐term microgravity conditions aboard the ISS with implications for early solar system particle aggregation (2022)
    Koch, Tamara E. ; Spahr, Dominik ; Tkalcec, Beverley J. ; [et al.]
    Details
    Publication Date: 2022-10-13
    Description: In order to gain further insights into early solar system aggregation processes, we carried out an experiment on board the International Space Station, which allowed us to study the behavior of dust particles exposed to electric arc discharges under long‐term microgravity. The experiment led to the formation of robust, elongated, fluffy aggregates, which were studied by scanning electron microscopy, electron backscatter diffraction, and synchrotron micro‐computed tomography. The morphologies of these aggregates strongly resemble the typical shapes of fractal fluffy‐type calcium‐aluminum‐rich inclusions (CAIs). We conclude that a small amount of melting could have supplied the required stability for such fractal structures to have survived transportation and aggregation to and compaction within planetesimals. Other aggregates produced in our experiment have a massy morphology and contain relict grains, likely resulting from the collision of grains with different degrees of melting, also observed in some natural CAIs. Some particles are surrounded by igneous rims, which remind in thickness and crystal orientation of Wark–Lovering rims; another aggregate shows similarities to disk‐shaped CAIs. These results imply that a (flash‐)heating event with subsequent aggregation could have been involved in the formation of different morphological CAI characteristics.
    Description: BIOVIA
    Description: Nordlicht GmbH
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: NanoRacks LLC
    Description: Dr. Rolf M. Schwiete Stiftung http://dx.doi.org/10.13039/501100020027
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: DreamUp
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Keywords: ddc:550.78
    Language: English
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    Microbially promoted calcite precipitation in the pelagic redoxcline: Elucidating the formation of the turbid layer (2022)
    Details
    Publication Date: 2022-10-12
    Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CONACYT‐FONCICYT‐DADC
    Description: https://doi.org/10.11588/data/TMYLWS
    Description: https://doi.org/10.11588/data/GYLDH5
    Keywords: ddc:551.9
    Language: English
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    Geostandards and Geoanalytical Research Bibliographic Review 2020 (2022)
    Weis, Ulrike ; Stoll, Brigitte ; Förster, Michael W. ; [et al.]
    Details
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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    A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride (2022)
    Details
    Publication Date: 2022-08-04
    Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.
    Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912
    Keywords: ddc:551.9
    Language: English
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
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    Role of Poroelasticity During the Early Postseismic Deformation of the 2010 Maule Megathrust Earthquake (2022)
    Peña, Carlos ; Metzger, Sabrina ; Heidbach, Oliver ; [et al.]
    Details
    Publication Date: 2022-09-29
    Description: Megathrust earthquakes impose changes of differential stress and pore pressure in the lithosphere‐asthenosphere system that are transiently relaxed during the postseismic period primarily due to afterslip, viscoelastic and poroelastic processes. Especially during the early postseismic phase, however, the relative contribution of these processes to the observed surface deformation is unclear. To investigate this, we use geodetic data collected in the first 48 days following the 2010 Maule earthquake and a poro‐viscoelastic forward model combined with an afterslip inversion. This model approach fits the geodetic data 14% better than a pure elastic model. Particularly near the region of maximum coseismic slip, the predicted surface poroelastic uplift pattern explains well the observations. If poroelasticity is neglected, the spatial afterslip distribution is locally altered by up to ±40%. Moreover, we find that shallow crustal aftershocks mostly occur in regions of increased postseismic pore‐pressure changes, indicating that both processes might be mechanically coupled.
    Description: Plain Language Summary: Large earthquakes modify the state of stress and pore pressure in the upper crust and mantle. These changes induce stress relaxation processes and pore pressure diffusion in the postseismic phase. The two main stress relaxation processes are postseismic slip along the rupture plane of the earthquake and viscoelastic deformation in the rock volume. These processes decay with time, but can sustain over several years or decades, respectively. The other process that results in volumetric crustal deformation is poroelasticity due to pore pressure diffusion, which has not been investigated in detail. Using postseismic surface displacement data acquired by radar satellites after the 2010 Maule earthquake, we show that poroelastic deformation may considerably affect the vertical component of the observed geodetic signal during the first months. Poroelastic deformation also has an impact on the estimation of the postseismic slip, which in turn affects the energy stored at the fault plane that is available for the next event. In addition, shallow aftershocks within the continental crust show a good, positive spatial correlation with regions of increased postseismic pore‐pressure changes, suggesting they are linked. These findings are thus important to assess the potential seismic hazard of the segment.
    Description: Key Points: A poro‐viscoelastic deformation model improves the geodetic data misfit by 14% compared to an elastic model that only accounts for afterslip. Poroelastic deformation mainly produces surface uplift and landward displacement patterns on the coastal forearc region. Neglecting poroelastic effects may locally alter the afterslip amplitude by up to ±40% near the region of maximum coseismic slip.
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551
    Language: English
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    The detection of bacterial exometabolites in marine dissolved organic matter through ultrahigh‐resolution mass spectrometry (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-01
    Description: Bacteria play a key role in sustaining the chemodiversity of marine dissolved organic matter (DOM), yet there is limited direct evidence of a major contribution of bacterial exometabolites to the DOM pool. This study tests whether molecular formulae of intact exometabolites can be detected in natural DOM via untargeted Fourier‐transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS). We analyzed a series of quantitative mixtures of solid‐phase extracted DOM from the deep ocean, of a natural microbial community and selected model strains of marine bacteria. Under standard instrument settings (200 broadband scans, mass range 92–1000 Da), 77% of molecular formulae were shared between the mesocosm and marine DOM. However, there was 〈 10% overlap between pure bacterial exometabolome with marine DOM, and in mixing ratios closest to mimicking natural environments (1% bacterial DOM, 99% marine DOM), only 4% of the unique bacterial exometabolites remained detectable. Further experiments with the bacterial exometabolome DOM mixtures using enhanced instrument settings resulted in increased detection of the exometabolites at low concentrations. At 1000 and 10,000 accumulated scans, 23% and 29% of the unique molecular formulae were detectable at low concentrations, respectively. Moreover, windowing a specific mass range encompassing a representative fraction of exometabolites tripled the number of unique detected formulae at low concentrations. Routine FT‐ICR‐MS settings are thus not always sufficient to distinguish bacterial exometabolome patterns from a seawater DOM background. To observe these patterns at higher sensitivity, we recommend a high scan number coupled with windowing a characteristic region of the molecular fingerprint.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46 ; ddc:579.3 ; ddc:
    Language: English
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    Tides, Stratification, and Counter Rotation: The German Bight ROFI in Comparison to Other Regions of Freshwater Influence (2022)
    Details
    Publication Date: 2022-10-01
    Description: The characteristics of tidal velocity profiles and their relation to stratification are investigated based on high‐resolution field data collected at four locations in the German Bight Region of Freshwater Influence (ROFI) in the North Sea. The deployments each include two to three tidal cycles and were conducted during field campaigns in August 2016 and May 2018. The depth‐averaged semidiurnal tidal motion is dominated by a standing wave directed toward the coast, but modified by a smaller, coast‐parallel progressive wave contribution. The time series of the tidal velocity profiles consistently show tidal asymmetries with higher flood than ebb velocities near the surface and counter‐clockwise rotation of the velocity trajectories at depth. Near the surface, phase‐locked periodic changes in the sense of rotation within the tidal cycle are evident for three deployments, resulting in periodic counter‐rotation of the upper and lower layer. During these episodes, stratification of the water column is observed. Counter‐rotation is initiated after a sudden decoupling developing from the surface downward, with subsequent rapid development of stratification and velocity shear. The observed decoupling is most likely triggered by advection of the plume‐induced lateral surface density gradient by weakly sheared ebb currents toward the study site. Due to the dominance of the standing wave in the German Bight ROFI, the observed intra‐tidal variations of stratification are more similar to the Liverpool Bay and differ significantly from the Rhine ROFI, where the tidal dynamics are controlled by a progressive Kelvin wave.
    Description: Plain Language Summary; The water velocities in the German Bight are strongly influenced by river freshwater input and semidiurnal tides. While the freshwater input from the rivers has a stratifying effect, tidal motion as well as wind and waves induce mixing. These forces compete in controlling the state of the water column in a complex manner. In theory, tidal motion should describe elliptical paths. However, in reality, these ellipses can be modified for example, by periodically occurring stratification. To assess the characteristics of the semidiurnal tidal velocity profile and its variability, four instruments to measure current velocity profiles were deployed in the German Bight during August 2016 and May 2018. Measurements were carried out for the duration of up to three tidal cycles, accompanied by parallel profiles of water temperature and salinity taken from the anchored ship nearby. Results show that periodic stratification related to the river freshwater plume is associated with periodically counter‐rotating tidal currents during the tidal cycle. The measurement position relative to the location of the density front of the plume appears to be critical for the occurrence of counter‐rotation. The observed dynamics are qualitatively compared to two other well‐studied coastal ocean regions of freshwater influence.
    Description: Key Points: High‐resolution velocity and density data from the German Bight Region of Freshwater Influence are used to assess M2 tidal properties and intra‐tidal variability. M2 tidal motion is a hybrid of standing and progressive waves, with the standing wave contribution dominating. Periodic counter‐rotation of upper‐ and lower‐layer current trajectories during the tidal cycle is related to water column stratification.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.919168
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943958
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943955
    Description: https://doi.org/10.1594/PANGAEA.897214
    Keywords: ddc:551.46
    Language: English
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    Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons (2022)
    de Graaf, Stefan ; Vonhof, Hubert B. ; Reijmer, John J. G. ; [et al.]
    Details
    Publication Date: 2022-10-01
    Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.
    Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.
    Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246
    Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106
    Keywords: ddc:551.9
    Language: English
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    Temporal evolution of headwall erosion rates derived from cosmogenic nuclide concentrations in the medial moraines of Glacier d'Otemma, Switzerland (2022)
    Details
    Publication Date: 2022-10-04
    Description: Climate change affects the stability and erosion of high‐alpine rock walls above glaciers (headwalls) that deliver debris to glacier surfaces. Since supraglacial debris in the ablation zone alters the melt behaviour of the underlying ice, the responses of debris‐covered glaciers and of headwalls to climate change may be coupled. In this study, we analyse the beryllium‐10 (10Be)‐cosmogenic nuclide concentration history of glacial headwalls delivering debris to the Glacier d'Otemma in Switzerland. By systematic downglacier‐profile‐sampling of two parallel medial moraines, we assess changes in headwall erosion through time for small, well‐defined debris source areas. We compute apparent headwall erosion rates from 10Be concentrations ([10Be]), measured in 15 amalgamated medial moraine debris samples. To estimate both the additional 10Be production during glacial debris transport and the age of our samples we combine our field‐based data with a simple model that simulates downglacier debris trajectories. Furthermore, we evaluate additional grain size fractions for eight samples to test for stochastic mass wasting effects on [10Be]. Our results indicate that [10Be] along the medial moraines vary systematically with time and consistently for different grain sizes. [10Be] are higher for older debris, closer to the glacier terminus, and lower for younger debris, closer to the glacier head. Computed apparent headwall erosion rates vary between ~0.6 and 10.8 mm yr−1, increasing over a maximum time span of ~200 years towards the present. As ice cover retreats, newly exposed headwall surfaces may become susceptible to enhanced weathering and erosion, expand to lower elevations, and contribute formerly shielded bedrock of likely different [10Be]. Hence, we suggest that recently lower [10Be] reflect the deglaciation of the debris source areas since the end of the Little Ice Age.
    Description: In glacial landscapes, systematic downglacier‐sampling of medial moraine debris holds the potential to assess changes in headwall erosion through time. Cosmogenic beryllium‐10 (10Be) concentrations within the medial moraines of Glacier d'Otemma, Switzerland, broadly increase downglacier and translate into increasing headwall erosion rates towards the present. These trends may reflect processes associated with the exposure of new bedrock surfaces across recently deglaciating source headwalls.
    Description: European Research Council (ERC) H2020‐EU.1.1.
    Description: https://doi.org/10.5880/GFZ.3.3.2021.007
    Keywords: ddc:551
    Language: English
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    Benthic Carbon Remineralization and Iron Cycling in Relation to Sea Ice Cover Along the Eastern Continental Shelf of the Antarctic Peninsula (2022)
    Details
    Publication Date: 2022-10-04
    Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.
    Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.
    Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207
    Description: https://doi.org/10.1594/PANGAEA.942455
    Keywords: ddc:551.9
    Language: English
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    Basin‐scale estimates of greenhouse gas emissions from the Mara River, Kenya: Importance of discharge, stream size, and land use/land cover (2022)
    Mwanake, Ricky M. ; Gettel, Gretchen M. ; Ishimwe, Clarisse ; [et al.]
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-04
    Description: Greenhouse gas fluxes (CO2, CH4, and N2O) from African streams and rivers are under‐represented in global datasets, resulting in uncertainties in their contributions to regional and global budgets. We conducted year‐long sampling of 59 sites in a nested‐catchment design in the Mara River, Kenya in which fluxes were quantified and their underlying controls assessed. We estimated annual basin‐scale greenhouse gas emissions from measured in‐stream gas concentrations, modeled gas transfer velocities, and determined the sensitivity of up‐scaling to discharge. Based on the total annual CO2‐equivalent emissions calculated from global warming potentials (GWP), the Mara basin was a net greenhouse gas source (294 ± 35 Gg CO2 eq yr−1). Lower‐order streams (1–3) contributed 81% of the total fluxes, and higher stream orders (4–8) contributed 19%. Cropland‐draining streams also exhibited higher fluxes compared to forested streams. Seasonality in stream discharge affected stream widths (and stream area) and gas exchange rates, strongly influencing the basin‐wide annual flux, which was 10 times higher during the high and medium discharge periods than the low discharge period. The basin‐wide estimate was underestimated by up to 36% if discharge was ignored, and up to 37% for lower stream orders. Future research should therefore include seasonality in stream surface areas in upscaling procedures to better constrain basin‐wide fluxes. Given that agricultural activities are a major factor increasing riverine greenhouse gas fluxes in the study region, increased conversion of forests and agricultural intensification has the possibility of increasing the contribution of the African continent to global greenhouse gas sources.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: IHE Delft Institute for Water Education
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: TERENO Bavarian Alps/ Pre‐Alps Observatory
    Keywords: ddc:551
    Language: English
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    Deepening the Late Quaternary's Deep Ocean Carbon Mysteries (2022)
    Details
    Publication Date: 2022-10-04
    Description: Changes to the carbon content of the deep ocean, the largest reservoir in the surficial carbon cycle, are capable of altering atmospheric carbon dioxide concentrations and thereby Earth's climate. While the role of the deep ocean's carbon inventory in the last ice age has been thoroughly investigated, comparatively little is known about whether the deep ocean contributed to the change in the pacing and intensity of ice ages around 1 million years ago during the Mid‐Pleistocene Transition (MPT). Qin et al. (2022, https://doi.org/10.1029/2021GL097121) provide new reconstructions of deep ocean carbonate ion saturation, a proxy for carbon content, from the deep Pacific Ocean across the MPT. Intriguingly, their results show that a reduction in deep Pacific carbonate ion saturation across the MPT occurred at different intervals from carbonate ion saturation decline in the deep Atlantic Ocean. These results suggest a more nuanced contribution of whole‐ocean carbon sequestration to the climate changes reconstructed across the MPT.
    Description: Plain Language Summary: Earth's periodic ice ages became longer and more intense around 1 million years ago. While the underlying reasons for this climate change remain debated, it is widely understood that the deep ocean may have played an important role by storing the potent greenhouse gas carbon dioxide away from the atmosphere. New research by Qin et al. (2022, https://doi.org/10.1029/2021gl097121) shows that the deep Pacific Ocean did indeed accumulate additional carbon around the time of this million‐year old climate transition. However, the new results also show that Pacific Ocean accumulated carbon over different intervals than the Atlantic Ocean, deepening the mystery around how and why this carbon uptake occurred.
    Description: Key Points: The deep Atlantic and Pacific Oceans accumulated carbon at different intervals during the mid‐Pleistocene transition.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1029/2021GL097121
    Keywords: ddc:551
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    Variability in the Concentration of Lithium in the Indo‐Pacific Ocean (2022)
    Details
    Publication Date: 2022-10-04
    Description: Lithium has limited biological activity and can readily replace aluminium, magnesium and iron ions in aluminosilicates, making it a proxy for the inorganic silicate cycle and its potential link to the carbon cycle. Data from the North Pacific Ocean, tropical Indian Ocean, Southern Ocean and Red Sea suggest that salinity normalized dissolved lithium concentrations vary by up to 2%–3% in the Indo‐Pacific Ocean. The highest lithium concentrations were measured in surface waters of remote North Pacific and Indian Ocean stations that receive relatively high fluxes of dust. The lowest dissolved lithium concentrations were measured just below the surface mixed layer of the stations with highest surface water concentrations, consistent with removal into freshly forming aluminium rich phases and manganese oxides. In the North Pacific, water from depths 〉2,000 m is slightly depleted in lithium compared to the initial composition of Antarctic Bottom Water, likely due to uptake of lithium by authigenically forming aluminosilicates. The results of this study suggest that the residence time of lithium in the ocean may be significantly shorter than calculated from riverine and hydrothermal fluxes.
    Description: Key Points: Li/Na ratios vary by up to 2%–3% in the Indian and Pacific Oceans. Authigenic formation of aluminosilicates slightly deplete deep‐water lithium concentrations in the North Pacific. The residence time of lithium in the ocean is 240,000 ± 70,000 years, based on removal from North Pacific deep‐water.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: MoES, Indian National Centre for Ocean Information Services http://dx.doi.org/10.13039/501100004814
    Description: National Science Foundation USA
    Description: https://doi.pangaea.de/10.1594/PANGAEA.941888
    Keywords: ddc:551
    Language: English
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    Arctic – Atlantic Exchange of the Dissolved Micronutrients Iron, Manganese, Cobalt, Nickel, Copper and Zinc With a Focus on Fram Strait (2022)
    Details
    Publication Date: 2022-10-04
    Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.
    Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.
    Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.
    Description: German Research Foundation
    Description: Netherlands Organization for Scientific Research
    Description: https://doi.pangaea.de/10.1594/PANGAEA.859558
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.868396
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://www.bco-dmo.org/dataset/718440
    Description: https://doi.org/10.1594/PANGAEA.936029
    Description: https://doi.org/10.1594/PANGAEA.936027
    Description: https://doi.pangaea.de/10.1594/PANGAEA.927429
    Keywords: ddc:551.9
    Language: English
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    Holocene variability in sea‐ice conditions in the eastern Baffin Bay‐Labrador Sea – A north–south biomarker transect study (2022)
    Saini, Jeetendra ; Stein, Ruediger ; Fahl, Kirsten ; [et al.]
    Details
    Publication Date: 2022-10-05
    Description: Reconstructions of sea‐surface conditions during the Holocene were achieved using three sediment cores from northeastern Baffin Bay (GeoB19948‐3 and GeoB19927‐3) and the Labrador Sea (GeoB19905‐1) along a north–south transect based on sea‐ice IP25 and open‐water phytoplankton biomarkers (brassicasterol, dinosterol and HBI III). In Baffin Bay, sea‐surface conditions in the Early Holocene were characterized by extended (early) spring sea ice cover (SIC) prior to 7.6 ka BP. The conditions in the NE Labrador Sea, however, remained predominantly ice‐free in spring/autumn due to the enhanced influx of Atlantic Water (West Greenland Current, WGC) from 11.5 until ~9.1 ka BP, succeeded by a period of continued (spring–autumn) ice‐free conditions between 9.1 and 7.6 ka BP corresponding to the onset of Holocene Thermal Maximum (HTM)‐like conditions. A transition towards reoccurring ice‐edge and significantly reduced SIC conditions in Baffin Bay is evident in the Middle Holocene (~7.6–3 ka BP) probably caused by the variations in the WGC influence associated with the ice melting and can be characterized as HTM‐like conditions. These HTM‐like conditions are predominantly recorded in the NE Labrador Sea area shown by (spring–autumn) ice‐free conditions from 5.9–3 ka BP. In the Late Holocene (last ~3 ka), our combined proxy records from eastern Baffin Bay indicate low in‐situ ice algae production; however, enhanced multi‐year (drifted) sea ice in this area was possibly attributed to the increased influx of Polar Water mass influx and may correlate with the Neoglacial cooling. The conditions in the NE Labrador Sea during the last 3 ka, however, continued to remain (spring–autumn) ice‐free. Our data from the Baffin Bay–Labrador Sea transect suggest a dominant influence of meltwater influx on sea‐ice formation throughout the Holocene, in contrast to sea‐ice records from the Fram Strait area, which seem to follow predominantly the summer insolation trend.
    Description: image
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    Strain Signals Governed by Frictional‐Elastoplastic Interaction of the Upper Plate and Shallow Subduction Megathrust Interface Over Seismic Cycles (2022)
    Details
    Publication Date: 2022-10-06
    Description: The behavior of the shallow portion of the subduction zone, which generates the largest earthquakes and devastating tsunamis, is still insufficiently constrained. Monitoring only a fraction of a single megathrust earthquake cycle and the offshore location of the source of these earthquakes are the foremost reasons for the insufficient understanding. The frictional‐elastoplastic interaction between the megathrust interface and its overlying wedge causes variable surface strain signals such that the wedge strain patterns may reveal the mechanical state of the interface. To contribute to this understanding, we employ Seismotectonic Scale Modeling and simplify elastoplastic megathrust subduction to generate hundreds of analog seismic cycles at a laboratory scale and monitor the surface strain signals over the model's forearc across high to low temporal resolutions. We establish two compressional and critical wedge configurations to explore the mechanical and kinematic interaction between the shallow wedge and the interface. Our results demonstrate that this interaction can partition the wedge into different segments such that the anelastic extensional segment overlays the seismogenic zone at depth. Moreover, the different segments of the wedge may switch their state from compression/extension to extension/compression domains. We highlight that a more segmented upper plate represents megathrust subduction that generates more characteristic and periodic events. Additionally, the strain time series reveals that the strain state may remain quasi‐stable over a few seismic cycles in the coastal zone and then switch to the opposite mode. These observations are crucial for evaluating earthquake‐related morphotectonic markers and short‐term interseismic time series of the coastal regions.
    Description: Key Points: Analog earthquake cycle experiments provide observations to evaluate the surface strain signals from the shallow megathrust. The extensional segment of the forearc overlays the seismogenic zone at depth. The strain state may remain quasi‐stable over a few seismic cycles in the coastal zone.
    Description: SUBITOP Marie Sklodowska‐Curie Action project from the European Union's EU Framework Programme
    Description: Deutsche Forschungsgemeinschaft (CRC 1114) “Scaling Cascades in Complex Systems”
    Description: https://doi.org/10.5880/fidgeo.2022.015
    Keywords: ddc:551.8 ; ddc:550.78
    Language: English
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    Growth of microaerophilic Fe(II)‐oxidizing bacteria using Fe(II) produced by Fe(III) photoreduction (2022)
    Details
    Publication Date: 2022-06-17
    Description: Iron(II) (Fe(II)) can be formed by abiotic Fe(III) photoreduction, particularly when Fe(III) is organically complexed. Light‐influenced environments often overlap or even coincide with oxic or microoxic geochemical conditions, for example, in sediments. So far, it is unknown whether microaerophilic Fe(II)‐oxidizing bacteria are able to use the Fe(II) produced by Fe(III) photoreduction as electron donor. Here, we present an adaption of the established agar‐stabilized gradient tube approach in comparison with liquid cultures for the cultivation of microaerophilic Fe(II)‐oxidizing microorganisms by using a ferrihydrite‐citrate mixture undergoing Fe(III) photoreduction as Fe(II) source. We quantified oxygen and Fe(II) gradients with amperometric and voltammetric microelectrodes and evaluated microbial growth by qPCR of 16S rRNA genes. We showed that gradients of dissolved Fe(II) (maximum Fe(II) concentration of 1.25 mM) formed in the gradient tubes when incubated in blue or UV light (400–530 nm or 350–400 nm). Various microaerophilic Fe(II)‐oxidizing bacteria (Curvibacter sp. and Gallionella sp.) grew by oxidizing Fe(II) that was produced in situ by Fe(III) photoreduction. Best growth for these species, based on highest gene copy numbers, was observed in incubations using UV light in both liquid culture and gradient tubes containing 8 mM ferrihydrite‐citrate mixtures (1:1), due to continuous light‐induced Fe(II) formation. Microaerophilic Fe(II)‐oxidizing bacteria contributed up to 40% to the overall Fe(II) oxidation within 24 h of incubation in UV light. Our results highlight the potential importance of Fe(III) photoreduction as a source of Fe(II) for Fe(II)‐oxidizing bacteria by providing Fe(II) in illuminated environments, even under microoxic conditions.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Ministerium für Wissenschaft, Forschung und Kunst Baden‐Württemberg http://dx.doi.org/10.13039/501100003542
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:579.317 ; ddc:551.9
    Language: English
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    Simulated Future Trends in Marine Nitrogen Fixation Are Sensitive to Model Iron Implementation (2022)
    Details
    Publication Date: 2022-06-17
    Description: Biological nitrogen fixation is an important oceanic nitrogen source, potentially stabilizing marine fertility in an increasingly stratified and nutrient‐depleted ocean. Iron limitation of low latitude primary producers has been previously demonstrated to affect simulated regional ecosystem responses to climate warming or nitrogen cycle perturbation. Here we use three biogeochemical models that vary in their representation of the iron cycle to estimate change in the marine nitrogen cycle under a high CO2 emissions future scenario (RCP8.5). The first model neglects explicit iron effects on biology (NoFe), the second utilizes prescribed, seasonally cyclic iron concentrations and associated limitation factors (FeMask), and the third contains a fully dynamic iron cycle (FeDyn). Models were calibrated using observed fields to produce near‐equivalent nutrient and oxygen fits, with productivity ranging from 49 to 75 Pg C yr−1. Global marine nitrogen fixation increases by 71.1% with respect to the preindustrial value by the year 2100 in NoFe, while it remains stable (0.7% decrease in FeMask and 0.3% increase in FeDyn) in explicit iron models. The mitigation of global nitrogen fixation trend in the models that include a representation of iron originates in the Eastern boundary upwelling zones, where the bottom‐up control of iron limitation reduces export production with warming, which shrinks the oxygen deficient volume, and reduces denitrification. Warming‐induced trends in the oxygen deficient volume in the upwelling zones have a cascading effect on the global nitrogen cycle, just as they have previously been shown to affect tropical net primary production.
    Description: Plain Language Summary: Phytoplankton need nutrients to grow. Two of those nutrients are nitrogen and iron. Climate change projections suggest that in the future there could be less nitrogen supplied to the surface ocean, which might reduce phytoplankton growth. Less phytoplankton growth could impact a wide range of ocean services, like fishing and fossil carbon draw‐down. However, some phytoplankton have the ability to add “new” nitrogen to the surface ocean directly from the atmosphere. In this study, we explore how this biological fixation of new nitrogen might change into the future using three models. These models differ in how iron is represented, but all do equally well in representing the observed nutrient and oxygen distribution. Biological nitrogen fixation slightly decreases with climate change in the very complex iron model and the moderately complex iron model, but it increases strongly (by more than 70% by the year 2100) in the model that does not include iron effects on biology. Our study addresses the importance of iron models and how they can change our view of how the ocean responds to climate change.
    Description: Key Points: Models performing similarly with respect to global NO3, PO4, and O2 distributions yield diverse responses in marine N2 fixation to warming. Marine N2 fixation trends are sensitive to whether iron limits primary production in upwelling regions, for example, the Eastern Tropical Pacific.
    Description: Helmholtz Research School for Ocean System Science and Technology
    Description: New Zealand Ministry of Business, Innovation and Employment
    Description: https://data.geomar.de/downloads/20.500.12085/673e7de0-20ab-4dd3-afe9-c4bfb00b1faf/
    Keywords: ddc:551.9
    Language: English
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    Analytical Solutions for Gravity Changes Caused by Triaxial Volumetric Sources (2022)
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    Publication Date: 2022-06-17
    Description: Volcanic crises are often associated with magmatic intrusions or the pressurization of magma chambers of various shapes. These volumetric sources deform the country rocks, changing their density, and cause surface uplift. Both the net mass of intruding magmatic fluids and these deformation effects contribute to surface gravity changes. Thus, to estimate the intrusion mass from gravity changes, the deformation effects must be accounted for. We develop analytical solutions and computer codes for the gravity changes caused by triaxial sources of expansion. This establishes coupled solutions for joint inversions of deformation and gravity changes. Such inversions can constrain both the intrusion mass and the deformation source parameters more accurately.
    Description: Plain Language Summary: Volcanic crises are usually associated with magmatic fluids that intrude and deform the host rocks before potentially breaching the Earth's surface. It is important to estimate how much fluid (mass and volume) is on the move. Volume can be determined from the measured surface uplift. Mass can be determined from surface gravity changes. The fluid intrusion increases the mass below the volcano, thereby increasing the gravity and pressurizing the rocks. This dilates parts of the host rock and compresses other parts, changing the rock density and redistributing the rock mass. This causes secondary gravity changes, called deformation‐induced gravity changes. The measured gravity change is always the sum of the mass and deformation‐induced contributions. Here, we develop mathematical equations for the rapid estimation of these deformation‐induced gravity changes caused by arbitrary intrusion shapes. This way we can take the mass contribution apart from the deformation contribution. We show that by using this solution not only the intrusion mass, but also other intrusion parameters, including the volume, depth, and shape can be calculated more accurately.
    Description: Key Points; We develop analytical solutions for gravity changes due to the point Compound Dislocation Model simulating triaxial expansions. Rapid coupled inversions of deformation and gravity changes, accounting for deformation‐induced gravity changes are now possible. For shallow sources, estimation errors in the chamber volume change may lead to large biases in the simulated gravity changes.
    Description: EU Horizon 2020 programme NEWTON‐g project, under the FETOPEN‐ Grant Agreement No.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://volcanodeformation.com/onewebmedia/pCDMgravity.zip
    Keywords: ddc:551
    Language: English
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    The Arctic Ocean in CMIP6 Models: Biases and Projected Changes in Temperature and Salinity (2022)
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    Publication Date: 2022-06-17
    Description: We examine the historical evolution and projected changes in the hydrography of the deep basin of the Arctic Ocean in 23 climate models participating in the Coupled Model Intercomparison Project Phase 6 (CMIP6). The comparison between historical simulations and observational climatology shows that the simulated Atlantic Water (AW) layer is too deep and thick in the majority of models, including the multi‐model mean (MMM). Moreover, the halocline is too fresh in the MMM. Overall our findings indicate that there is no obvious improvement in the representation of the Arctic hydrography in CMIP6 compared to CMIP5. The climate change projections reveal that the sub‐Arctic seas are outstanding warming hotspots, causing a strong warming trend in the Arctic AW layer. The MMM temperature increase averaged over the upper 700 m at the end of the 21st century is about 40% and 60% higher in the Arctic Ocean than the global mean in the SSP245 and SSP585 scenarios, respectively. Salinity in the upper few hundred meters is projected to decrease in the Arctic deep basin in the MMM. However, the spread in projected salinity changes is large and the tendency toward stronger halocline in the MMM is not simulated by all the models. The identified biases and projection uncertainties call for a concerted effort for major improvements of coupled climate models.
    Description: Plain Language Summary: Coupled climate models are crucial tools for understanding and projecting climate change, especially for the Arctic where the climate is changing at unprecedented rates. A cold fresh layer of water (aka halocline) has been protecting sea‐ice at the surface from the warm layer of water (aka Atlantic Water layer) which flows underneath and could potentially accelerate sea ice melting from below. Climate change disturbs this vertical structure by changing the temperature and salinity of the Arctic Ocean (in a process known as Atlantification and Pacification) which may lead to additional sea ice basal melting and accelerate sea ice decline. We examined the simulated temperature and salinity in the Arctic Ocean deep basin in state‐of‐the‐art climate model simulations which provided the basis for the IPCC Assessment Report. We found that although there are persistent inaccuracies in the representation of Arctic temperature and salinity, the Arctic Ocean below 100 m is subject to much stronger warming than the average global ocean. On the other hand, the upper Arctic Ocean salinity is projected to decrease, which on average may strengthen the isolation of sea ice from Atlantic Water heat in the Arctic deep basin area.
    Description: Key Points: A too deep and thick Arctic Atlantic Water layer continues to be a major issue in contemporary climate models contributing to the CMIP6. The Arctic Ocean below the halocline is subject to much stronger warming than the global mean during the 21st century. The multi‐model mean upper ocean salinity is projected to decrease in the future but with high uncertainty.
    Description: European union's Horizon 2020 research and innovation programme
    Description: German Helmholtz climate initiative REKLIM
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://esgf-data.dkrz.de/projects/esgf-dkrz/
    Description: http://psc.apl.washington.edu/nonwp_projects/PHC/Data3.html
    Keywords: ddc:551
    Language: English
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    The Effect of Land Use Classification on the Gas‐Phase and Particle Composition of the Troposphere: Tree Species Versus Forest Type Information (2022)
    Details
    Publication Date: 2022-06-17
    Description: Relationships between vegetation and air quality are intricate and still not fully understood. For regional air quality assessments, a better understanding of the diverse feedback mechanisms is crucial. The present article investigates the impact of land use data set detailedness on air quality predictions. Therefore, two different land use data sets were applied for simulations with COSMO‐MUSCAT for Germany in May 2014. One data set includes detailed information about tree species while the second one obtains generalized widely applied land use classes including mixed and coniferous forests. Moreover, we examined the role of agricultural NO soil emissions, agricultural biomass density enhancements, and model resolution. For a more comprehensive implementation of the secondary organic aerosol (SOA) formation, the SOA module was extended considering additional biogenic volatile organic compound (BVOC) precursor groups from isoprene, α‐pinene, limonene, and sesquiterpene oxidations. The model studies showed substantial differences in BVOC emission patterns between the two land use data sets. The application of detailed tree species information leads to complex BVOC emission patterns with high emission spots. In contrast, coarser forest information lead to standardized comprehensive emissions which result in 50% higher BVOC emissions. These differences affect both the atmospheric oxidizing potential and the production rates of SOA precursors. Land use induced regional differences (tree species minus forest information) in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%) concentrations, and SOA (−60%) mass are modeled. Overall, the simulations demonstrate that detailed land use information, extended organic chemistry treatment, and high spatial resolution are mandatory for air quality assessments.
    Description: Plain Language Summary: Trees are associated with being the lungs of the atmosphere as they filter out harmful substances from the air, they store CO2, and produce oxygen via photosynthesis. Other by‐products of photosynthesis are biogenic volatile organic compounds (BVOCs). BVOCs are chemical substances with a high vapor pressure already at room temperatures, so they quickly evaporate from the leaves into the surrounding air and are responsible for the characteristic forest smell. The amount and composition of BVOC emissions strongly depend on the tree species. Every plant has its own distinct emission properties. The chemical degradation of BVOCs impacts the chemical composition of the troposphere and is connected to ground level ozone production and the formation of secondary organic aerosols (SOA), contributing substantially to particulate matter (PM). On a global scale, standardized BVOC emission information on forest levels are often used, but for regional air quality assessments detailed plant specific information is crucial, but still often lacking. Therefore, two different land use data sets were applied in the present study to investigate the impact of standardized forest versus detailed tree‐species information for Germany in May 2014. The study reveals changes in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%), and SOA (−60%) concentrations.
    Description: Key Points: Detail of land use data sets crucial for biogenic volatile organic compound emission strength and composition. Composition and concentration variation of these organic compounds induce changes in regional air quality predictions. Detailed land use information, extended organic matter treatment, and high‐resolution simulations are mandatory for air quality assessments.
    Description: Deutsche Bundesstiftung Umwelt (DBU) http://dx.doi.org/10.13039/100007636
    Description: https://doi.org/10.5281/zenodo.4783106
    Description: http://ebas.nilu.no/
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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    Effects of the Hydrous Domain in the Mantle Wedge on Magma Formation and Mixing at the Northeast Lau Spreading Center, SW Pacific (2022)
    Details
    Publication Date: 2022-08-09
    Description: Abundant volcanic activity occurs in the back‐arc region of the northern Tofua island arc where the Northeast Lau Spreading Center (NELSC) propagates southwards into older crust causing the formation of numerous seamounts at the propagating rift tip. An off‐axis volcanic diagonal ridge (DR) occurs at the eastern flank of the NELSC, linking the large rear‐arc volcano Niuatahi with the NELSC. New geochemical data from the NELSC, the southern propagator seamounts, and DR reveal that the NELSC lavas are tholeiitic basalts whereas the rear‐arc volcanoes typically erupt lavas with boninitic composition. The sharp geochemical boundary probably reflects the viscosity contrast between off‐axis hydrous harzburgitic mantle and dry fertile mantle beneath the NELSC. The new data do not indicate an inflow of Samoa plume mantle into the NELSC, confirming previously published He isotope data. The NELSC magmas form by mixing of an enriched and a depleted Indian Ocean‐type upper mantle end‐member implying a highly heterogeneous upper mantle composition in this area. Most NELSC lavas are little affected by a slab component implying that melting is adiabatic beneath the spreading center. The DR lavas show the influence of a component from the subducted Louisville Seamount Chain, which was previously thought to be restricted to the nearby arc volcanoes Niuatoputapu and Tafahi. This signature is rarely detected along the NELSC implying little mixing of melts from the low‐viscosity hydrous portion of the mantle wedge beneath the rear‐arc volcanoes into the melting region of the dry mantle beneath the NELSC.
    Description: Plain Language Summary: Volcanic activity is abundant at subduction zones and the chemical analysis of the erupted rocks allows to determine the material transport in the Earth's mantle. The Northeast Lau Spreading Center (NELSC) forms by extension and volcanism behind the northern Tofua island arc. Several large volcanic structures occur east of the NELSC and the lavas of these off‐axis volcanoes are chemically and isotopically distinct implying little mixing with the magmas of the NELSC. The differences suggest decompression melting of relatively dry mantle beneath the NELSC whereas the off‐axis volcanoes reflect melting of water‐rich mantle affected by fluids from the subducting Pacific Plate. The sharp geochemical boundary between the NELSC and off‐axis volcanoes is probably due to a large viscosity contrast between hydrous harzburgitic mantle and dry fertile mantle. Element and isotope ratios indicate that the NELSC magmas form by mixing of enriched and depleted portions of the upper mantle, and we do not find evidence for inflow of the Samoa deep mantle plume from the north. Some of the off‐axis lavas contain a component from a volcanic chain that was subducted some 4 million years ago and that was previously only known in two volcanoes of the Tofua island arc.
    Description: Key Points: Variably enriched mantle sources melt beneath the Northeast Lau Spreading Center (NELSC) but there is no evidence for Samoa mantle plume inflow. Relatively dry fertile mantle beneath NELSC causes sharp geochemical boundary with hydrous harzburgitic North Tonga mantle wedge. Subducted Louisville Seamount Chain material affects rear‐arc volcanism.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.21 ; ddc:551.116 ; ddc:551.9
    Language: English
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    Collisional mixing between inner and outer solar system planetesimals inferred from the Nedagolla iron meteorite (2021)
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    Publication Date: 2022-07-28
    Description: The ungrouped iron meteorite Nedagolla is the first meteorite with bulk Mo, Ru, and Ni isotopic compositions that are intermediate between those of the noncarbonaceous (NC) and carbonaceous (CC) meteorite reservoirs. The Hf‐W chronology of Nedagolla indicates that this mixed NC–CC isotopic composition was established relatively late, more than 7 Myr after solar system formation. The mixed NC–CC isotopic composition is consistent with the chemical composition of Nedagolla, which combines signatures of metal segregation under more oxidizing conditions (relative depletions in Mo and W), characteristic for CC bodies, and more reducing conditions (high Si and Cr contents), characteristic for some NC bodies, in a single sample. These data combined suggest that Nedagolla formed as the result of collisional mixing of NC and CC core material, which partially re‐equilibrated with silicate mantle material that predominantly derives from the NC body. These mixing processes might have occurred during a hit‐and‐run collision between two differentiated bodies, which also provides a possible pathway for Nedagolla's extreme volatile element depletion. As such, Nedagolla provides the first isotopic evidence for early collisional mixing of NC and CC bodies that is expected as a result of Jupiter's growth.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:549.112
    Language: English
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    Scaling Laws in Aeolian Sand Transport Under Low Sand Availability (2022)
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    Publication Date: 2022-11-01
    Description: The transport of sand by wind shapes the Earth's surface and constitutes one major factor for the emission of dust aerosols. The accurate modeling of wind‐blown sand transport is thus important to achieve reliable climate simulations and to make predictions about the propagation of desertification. Previous models of wind‐blown sand were designed to compute sand transport rates over a thick sand layer, such as the surface of large, active sand dunes. However, natural soils encompass a broad range of low sand availability conditions, such as crusted or bare soils. It has been a long‐standing open question how wind‐blown sand transport rates respond to wind velocity when the bare ground is covered by a thin layer of sand. Here we calculate the trajectories of wind‐blown sand grains and find that sand transport rates increase faster with wind speed under low sand availability conditions than over sand dunes. The reason for this behavior is elucidated in our simulations: The hopping sand grains fly higher the less sand is covering the hard surface. We obtain mathematical expressions for the sand transport rates as a function of the thickness of sand covering the bare soil, which will be important to improve climate models.
    Description: Key Points: We introduce a particle‐based model in investigating Aeolian (wind‐blown) sand transport when the sand cover on the soil is sparse. The scaling of the Aeolian transport rate with the wind shear velocity has a dependency on the sand cover thickness. There is an anomaly in the functional dependence of the transport rate on the sand cover thickness, depending on the rigid ground roughness.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.6084/m9.figshare.19469501
    Keywords: ddc:550.78
    Language: English
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