ALBERT

Description: The Total Exchange Flow analysis framework computes consistent bulk values quantifying the estuarine exchange flow using salinity coordinates since salinity is the main contributor to density in estuaries and the salinity budget is entirely controlled by the exchange flow. For deeper and larger estuaries temperature may contribute equally or even more to the density. That is why we included potential temperature as a second coordinate to the Total Exchange Flow analysis framework, which allows gaining insights in the potential temperature-salinity structure of the exchange flow as well as to compute consistent bulk potential temperature and therefore heat exchange values with the ocean. We applied this theory to the exchange flow of the Persian Gulf, a shallow, semienclosed marginal sea, where dominant evaporation leads to the formation of hypersaline and dense Gulf water. This drives an inverse estuarine circulation which is analyzed with special interest on the seasonal cycle of the exchange flow. The exchange flow of the Persian Gulf is numerically simulated with the General Estuarine Transport Model from 1993 to 2016 and validated against observations. Results show that a clear seasonal cycle exists with stronger exchange flow rates in the first half of the year. Furthermore, the composition of the outflowing water is investigated using passive tracers, which mark different surface waters. The results show that in the first half of the year, most outflowing water comes from the southern coast, while in the second half most water originates from the northwestern region.

Description: We present new geochemical and isotopic data for rock samples from two island arc volcanoes, Erromango and Vulcan Seamount, and from a 500 m thick stratigraphic profile of lava flows exposed on the SW flank of Vate Trough back-arc rift of the New Hebrides Island Arc (NHIA). The basalts from the SW rift flank of Vate Trough have ages of ~0.5 Ma but are geochemically similar to those erupting along the active back-arc rift. The weak subduction component in the back-arc basalts implies formation by decompression melting during early rifting and rifting initiation by tectonic processes rather than by lithosphere weakening by arc magma. Melting beneath Vate Trough is probably caused by chemically heterogeneous and hot mantle that flows in from the North Fiji Basin in the east. The melting zone beneath Vate Trough back-arc is separate from that of the arc front, but a weak slab component suggests fluid transport from the slab. Immobile incompatible element ratios in South NHIA lavas overlap with those of the Vate Trough depleted back-arc basalts, suggesting that enriched mantle components are depleted by back-arc melting during mantle flow. The slab component varies from hydrous melts of subducted sediments in the Central NHIA to fluids from altered basalts in the South NHIA. The volcanism of Erromango shows constant compositions for 5 million years, that is, there is no sign for variable depletion of the mantle or for a change of slab components due to collision of the D'Entrecasteaux Ridge as in lava successions further north.

Description: Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.

Description: Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.

Description: Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high-purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty-four trace elements in nearly identical abundance (500, 50, 5 µg g−1) using oxide powders or element solutions, and are named ARM-1, 2 and 3, respectively. We further document that sector-field (SF) ICP-MS (Element 2 or Element XR) is capable of sweeping seventy-seven isotopes (from 7Li to 238U, a total of sixty-eight elements) in 1 s and, thus, is able to quantify up to sixty-eight elements by laser sampling. Micro- and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP-OES, ICP-MS, LA-Q-ICP-MS and LA-SF-ICP-MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty-six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.

Description: Basalts are ubiquitous in volcanic systems on several planetary bodies, including the Earth, Mars, Venus, and Jupiter's moon Io, and are commonly associated with sulfur dioxide (SO2) degassing. We present the results of an experimental study of reactions between SO2 and basaltic glasses. We examined Fe-free basalt, and Fe-bearing tholeiitic and alkali basalts with a range of Fe3+/Fetotal (0.05 to 0.79) that encompass the oxygen fugacities proposed for most terrestrial planetary bodies. Tholeiitic and alkali basalts were exposed to SO2 at 600, 700, and 800 °C for 1 hr and 24 hr. Surface coatings formed on the reacted basalts; these contain CaSO4, MgSO4, Na2SO4, Na2Ca(SO4)2, Fe2O3, Fe3O4, Fe-Ti-(Al)-oxides, and TiO2. Additionally, the SO2-basalt reaction drives nucleation of crystalline phases in the substrate to form pyroxenes and possible Fe-oxides. A silica-rich layer forms between the substrate and sulfate coatings. More oxidized basalts may readily react with SO2 to form coatings dominated by large Ca-sulfate and oxide grains. On less oxidized basalts (NNO−1.5 to NNO−5), reactions with SO2 will form thin, fine-grained aggregates of sulfates; such materials are less readily detected by spectroscopy and spectrometry techniques. In contrast, in very reduced basalts (lower than NNO−5), typical of the Moon and Mercury, SO2 is typically a negligible component in the magmatic gas, and sulfides are more likely.

Description: Substantial changes have occurred in the Arctic Ocean in the last decades. Not only sea ice has retreated significantly, but also the ocean at middepth showed a warming tendency. By using simulations we identified a mechanism that intensifies the upward trend in ocean heat supply to the Arctic Ocean through Fram Strait. The reduction in sea ice export through Fram Strait induced by Arctic sea ice decline increases the salinity in the Greenland Sea, which lowers the sea surface height and strengthens the cyclonic gyre circulation in the Nordic Seas. The Atlantic Water volume transport to the Nordic Seas and Arctic Ocean is consequently strengthened. This enhances the warming trend of the Arctic Atlantic Water layer, potentially contributing to the Arctic “Atlantification.” Our study suggests that the Nordic Seas can play the role of a switchyard to influence the heat budget of the Arctic Ocean.

Description: The hydrodynamics in estuaries is mainly governed by the competition between a horizontal density gradient, friction, and wind stress. The sensitivity of the estuarine exchange flow to the wind stress increases in the absence of tides, which is investigated here using the example of the weakly tidal Warnow river estuary in the southwestern Baltic Sea—the mouth of which is characterized by strongly varying salinities of 8 to 20 g kg−1. The interaction between a volatile salinity gradient and along-estuary wind forcing is found to cause temporary inversions of the estuarine circulation. Despite the highly dynamic conditions, the applicability of recent theories for isohaline mixing, using the framework of Total Exchange Flow, and the strength of the exchange flow, using a non-dimensional parameter space, could be confirmed. By analyzing salinity fluxes at the mouth of the estuary, a mixing completeness of 84% was calculated for the estuary. Furthermore, inversion of estuarine circulation was typically found for a local Wedderburn number (ratio of non-dimensional wind stress to non-dimensional horizontal density gradient) exceeding 0.33, indicating a high sensitivity to along-estuary wind.

Description: The in situ measurement of Sr isotopes in carbonates by MC-ICP-MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well-characterised carbonate reference materials for Sr mass fractions 〉 1000 µg g−1 are available, there is a lack of well-characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g−1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution-based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP-MS in different laboratories. The 87Sr/86Sr ratio was determined by well-established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA-MC-ICP-MS, which resulted in 87Sr/86Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low-Sr, low-REE carbonate samples. NanoSr is available from the corresponding author.

Description: The continuous improvement of analytical procedures using multi-collector technologies in ICP-mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM-AE143, ERM-AE144, ERM-AE145, IRMM-009 and NIST SRM 980 were cross-calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM-AE143 anchors all magnesium δ-scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM-AE144 and ERM-AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg).

Description: At the heart of transition research lies the question of how to "scale up" sustainable alternatives from a protected niche to the creation of mainstream practices. While upscaling processes are often seen as an essential element that contributes to societal transformation, upscaling itself remains a fuzzy concept. We argue that some fundamental dilemmas of upscaling can be identified, for example, the different understanding of the concept by researchers and practitioners. The dilemmas should be addressed in a more reflexive way by those from the worlds of science and practice who are involved in collaborative research settings.

Description: Since the middle of the 20th century, human society experiences a "Great Acceleration" manifesting in historically remarkable growth rates that create severe sustainability problems. The globally exploding potentials of information and knowledge exchange have been and are vital drivers for this acceleration. Society has now come to the point that it requires a "Great Transformation" towards sustainability to ensure the viability of the planet for a vital society. The energy transition plays a central role for this transformation. In this context, human society has developed a comparably good understanding of the necessary infrastructural changes of this transition. For transforming the patterns of energy production and use in an energy transition as part of the "Great Transformation", this process of change now needs to strengthen its focus on information, communication, and knowledge systems. Human society needs to establish a knowledge system that has the potential to create usable knowledge for sustainability solutions. This requires organizing a communication system that is sufficiently complex, interconnected, and, at the same time, efficient for integrating reflexive, open-ended, inter- and transdisciplinary learning, evaluation, and knowledge co-production processes across multiple levels. This challenge opens a wide field of research. This cumulative dissertation contributes to research in this direction by applying a systemic sustainability perspective on the content and organization of communication in the field of research on sustainable energy and the operational level of municipal climate action as part of the energy transition. Regarding sustainability, this thesis uses strong sustainability and its principles as a frame for evaluating the content of communication. Regarding the systemic perspective, the thesis particularly relies on the following theories: (i) the human-environment system model by R. Scholz as an overarching framework regarding interactions between humans and nature, (ii) social systems theory by N. Luhmann to reflect the complexity of society, (iii) knowledge management to consider the human character of knowledge and a practice-oriented perspective, and (iv) management cybernetics, in particular, the Viable System Model by S. Beer as a framework to analyze and assess organizational structures. Furthermore, the thesis leverages the potential of text mining as a method to identify and visualize patterns in texts that reflect prevalent paradigms in communication. The thesis applies the above conceptual and methodological basis in three case studies. Case Study 1 investigates the measures proposed in 16 municipal climate action plans of regional centers in Lower Saxony, Germany. It uses a text mining approach in the form of an Summary interpretation network analysis. It analyzes how different societal subsystems are connected at the semantic level and to what extent sustainability principles can be recognized. Case Study 2 analyzes and reflects paradigms and discursive network structures in international scientific publications on sustainable energy. The study investigates 26533 abstracts published from 1990 to 2016 using a text mining approach, in particular topic modeling via latent Dirichlet allocation. Case Study 3 turns again to the cases of municipal climate action in Lower Saxony examined in Case Study 1. It examines the involvement of climate action managers of these cities in multilevel knowledge processes. Using design principles for knowledge systems, it evaluates to what extent knowledge is managed in this field across levels for supporting the energy transition and to what extent local innovation potential is leveraged or supported. The three case studies show that international research on sustainable energy and municipal climate action in Germany provide promising contributions to achieve a transformation towards sustainability but do not fully reflect the complexity of society and still support a growth paradigm, in contrast to a holistic sustainability paradigm. Further, the case studies show that research and local action are actively engaging with the diversity of energy technologies but are lagging in dealing with the socio-epistemic (communication) system, especially with regard to achieving cohesion. Using the example of German municipalities, Case Studies 1 and 3 highlight the challenges of achieving coherent local action for sustainability and bottom-up organizational learning due to incomplete or uncoordinated multilevel knowledge exchange. At the same time, the studies also point out opportunities for supporting the required coherent multilevel learning processes based on local knowledge. This can be achieved, for instance, by strengthening the coordinating role of intermediary organizational units or establishing closer interactions between the local operational units and the national level. The thesis interprets and synthesizes the results of the three case studies from its systemic sustainability perspective. On this basis, it provides several generalized recommendations that should be followed for establishing viable communication systems, especially but not exclusively in policy-making: Systemic holism: Consider matter, energy, and information flows as an integrated triplet in the context of scales, structures, and time in the various subsystems. Knowledge society: Focus on the socio-epistemic (communication) system, e.g., using the perspective of knowledge systems and associated design principles considering, for instance, working environments across horizontal and vertical levels, knowledge forms and types, and knowledge processes. Sufficiency communication: Emphasize sufficiency approaches, make it attractive, and find differentiated ways for communicating them. Multilevel cohesion and innovation: Achieve cohesion between the local and higher levels and leverage local innovations while avoiding isolated local action. Organizational interface design: Define the role of organizational units by the interactions they create at the interfaces with and between societal subsystems. Local transdisciplinarity: Support local transdisciplinary approaches integrating various subsystems, especially industry, while coordinating these approaches from a higher level for leveraging local innovation. Digital public system: Exploit existing digital technologies or infrastructures in the public system and recognize the value of data in the public sphere for achieving cohesion. Beyond the above recommendations, this thesis suggests that potential for further research lies in: Advancing nature-inspired systemic frameworks. Understanding the structure and creation of human knowledge. Developing text mining methodologies towards solution-oriented approaches.

Description: The transdisciplinary research mode has gained prominence in the research on and for sustainability transformations. Yet, solution-oriented research addressing complex sustainability problems has become complex itself, with new transdisciplinary research formats being developed and tested for this purpose. Application of new formats offers learning potentials from experience. To this end, we accompanied fourteen research projects conceptualized as real-world labs (RwLs) from 2015 to 2018. RwLs were part of a funding program on "Science for Sustainability" in the German federal state of Baden-Württemberg. Here, we combine conceptual and empirical work to a structured collection of experiences and provide a comprehensive account of RwLs. First, we outline characteristics of RwLs as transformation oriented, transdisciplinary research approach, using experiments, enabling learning and having a long-term orientation. Second, we outline eleven success factors and concrete design notes we gained through a survey of the 14 RwLs: (1) find the right balance between scientific and societal aims, (2) address the practitioners needs and restrictions, (3) make use of the experimentation concept, (4) actively communicate, (5) develop a "collaboration culture", (6) be attached to concrete sites, (7) create lasting impact and transferability, (8) plan for sufficient time and financial means, (9) adaptability, (10) research-based learning, and (11) recognize dependency on external actors. Characteristics and success factors are combined to illustrate practical challenges in RwLs. Third, we show which methods could be used to cope with challenges in RwLs. We conclude discussing the state of debate on RwLs and outline future avenues of research.

Description: Practices of urban experimentation are currently seen as a promising approach to making planning processes more collaborative and adaptive. The practices develop not only in the context of ideal-type concepts of urban experiments and urban labs but also organically in specific governance contexts. We present such an organic case in the city of Wuppertal, Germany, centred around a so-called change-maker initiative, "Utopiastadt." This initiative joined forces with the city administration and collaborated with a private property owner and the local economic development agency in an unusual planning process for the development of a central brownfield site. Ultimately, the consortium jointly published a framework concept that picked up the vision of the "Utopiastadt Campus" as an open-ended catalyst area for pilot projects and experiments on sustainability and city development. The concept was adopted by the city council and Utopiastadt purchased more than 50% of the land. In order to analyse the wider governance context and power struggles, we apply the social-constructivist theory of Strategic Action Fields (SAFs). We focused on the phases of contention and settlement, the shift in interaction forms, the role of an area development board as an internal governance unit and the influences of proximate fields, strategic action, and state facilitation on the development. We aim to demonstrate the potential of the theory of SAFs to understand a long-term urban development process and how an episode of experimentation evolved within this process. We discuss the theory's shortcomings and reflect critically on whether the process contributed to strengthening collaborative and experimental approaches in the governance of city development.

Description: We conducted a random allocation experiment at fashion week in Berlin in 2017, testing how face-to-face (f2f) communication affects sales of a fashion start-up focusing on second-hand. The experiment revealed that 11% of guests of an f2f event afterwards turned paying customers with an average basket size 11.8% higher than the overall sales event average. We add insights to research on entrepreneurial practice as well as on offline operations in the context of circular consumption in fashion, exposing the leveraging effect of f2f communication for customer acquisition and revenue of start-ups in the field of sustainable fashion.

Description: Businesses like Airbnb have shown that a successful circular economy (CE) business can operate exclusively online. Although online communication and web appearance attributes have been subject to academic research given accelerated digitization, there is still a lack of knowledge about online attributes and their role in facilitating CE. We close the portrayed knowledge gap by conducting a discrete-choice experiment with best to worst scaling and focusing on the effect of CE experience on the perception of a CE website by ranking nine online attributes, grouped in three subsets. We therefore contribute by identifying online attributes that are perceived as favorable for CE businesses and detect how participation in CE activities affects the perception of these attributes. We find that third-party associated online attributes (e.g., user reviews or third-party guarantees) rank significantly higher throughout CE consumption patterns of the sample, being always amongst the top three attributes. This novel finding on online preferences opens a new direction for further research, as well as allows practitioners to optimize online operations accordingly. Furthermore, we find that users without prior touchpoints with CE have a higher need for information about the business model as compared to CE active users who are more interested in community related attributes.

Description: Citizen science is a transdisciplinary approach that responds to the current science policy agenda: in terms of supporting open science, and by using a range of science communication instruments. In particular, it opens up scientific research processes by involving citizens at different phases; this also creates a range of opportunities for science communication to happen This article explores methodological and practical characteristics of citizen science as a form of science communication by examining three case studies that took different approaches to citizens' participation in science. Through these, it becomes clear that communication in citizen science is "always" science communication and an essential part of "doing science".

Description: This research project approached the emergence of social business innovations from the periphery, working towards the core: the first article features the representation of the concept of Social Business City, which was newly implemented by Wiesbaden in 2010. Here, social businesses are to be founded with the help of a network based on both public and private institutions. At the time of conducting the research, three such Social Business Cities existed: Wiesbaden (Germany), Fukuoka (Japan) and Pistoia (Italy); in 2016 Barcelona joined the list of Social Business Cities. The second article analyses the ways in which microfinance organisations that are based on the concept of social business according to Yunus differ from one another. Included in this research was Grameen Bank in Bangladesh, Social Business Women in Germany and Grameen America in the United States. Subsequently, a third article investigates the similarities and differences to be found between social businesses and charities. The research focuses on advantages and disadvantages on both sides and aims at answering the questions: which approach is appropriate under what circumstances and which aspects could be adopted by the other? Finally, we investigated the various cooperation of the Grameen Group with global players such as Danone, Veolia and Intel in Bangladesh and the particular challenges which result therefrom.

Description: Automakers close factories, the stock exchange crashes, empty streets and cafés everywhere and suddenly working from home is recommended or even required for a large part of the working population in Germany. The Corona pandemic is defining our current everyday life and hitting Germany, Europe and the world at a time when there are a multitude of huge challenges to be solved already. Economic aid is indispensable during and in the aftermath of such a crisis, but the primary focus is to prevent the spread of the pandemic and limiting the health implications. Economic stimulus packages and structural aid are an effective means of overcoming the long-term economic consequences of such disruptive developments. However, they must not be distributed according to the "watering can principle"; financial support must be provided in a future-oriented manner for urgently needed investments. The aim must be to promote the necessary sustainable transformation processes within our economy and society, such as climate protection. According to the authors, the preparations must be made now. This discussion paper shows which criteria and measures are needed.

Description: Addressing the prevailing mode of high-carbon lifestyles is crucial for the transition towards a net-zero carbon society. Existing studies fail to fully investigate the underlining factors of unsustainable lifestyles beyond individual determinants nor consider the gaps between current footprints and reduction targets. This study examines latent lifestyle factors related to carbon footprints and analyzes gaps between decarbonization targets and current lifestyles of major consumer segments through exploratory factor analysis and cluster analysis. As a case study on Japanese households, it estimates carbon footprints of over 47,000 households using expenditure survey microdata, and identifies high-carbon lifestyle factors and consumer segments by multivariate regression analysis, factor analysis, and cluster analysis. Income, savings, family composition, house size and type, ownership of durables and automobiles, and work style were confirmed as determinants of high-footprint Japanese households, with eight lifestyles factors, including long-distance leisure, materialistic consumption, and meat-rich diets, identified as the main contributory factors. The study revealed a five-fold difference between lowest and highest footprint segments, with all segments overshooting the 2030 and 2050 decarbonization targets. The findings imply the urgent need for policies tailored to diverse consumer segments and to address the underlying causes of high-carbon lifestyles especially of high-carbon segments.

Description: This doctoral research is located in the branch of sustainability sciences that has the realisation of sustainable development as its core subject of research. The most broadly accepted notion of sustainable development is that which evolves along the resolutions, declarations, and reports from international processes in the framework of the United Nations (UN). The consensual outputs from such processes feature global-generalised and context-free perspectives. However, implementation requires action at diverse and context-rich local levels as well. Moreover, while in such UN processes national states are the only contractual parties, it is increasingly recognised that other ("nonstate") actors are crucial to sustainability. The research presented here places the attention on bottom-up initiatives that are advancing innovative ways to tackle universal access to clean energy and to strengthen small-scale family farmers. This means, the focus is on bottom-up initiatives advancing local implementation of global sustainability targets, more precisely, targets that make part of the Sustainable Development Goals two and seven (SDG 2 and SDG7). The research asks how such bottom-up initiatives can contribute to the diffusion of sustainability innovations, thereby also contributing to social change.

Description: Background: Facing planetary boundaries, we need a sustainable energy system providing its life support function for society in the long-term within environmental limits. Since science plays an important role in decision-making, this study examines the thematic landscape of research on sustainable energy, which may contribute to a sustainability transformation. Understanding the structure of the research field allows for critical reflections and the identification of blind spots for advancing this field. Methods: The study applies a text mining approach on 26533 Scopus-indexed abstracts published from 1990 to 2016 based on a latent Dirichlet allocation topic model. Models with up 1100 topics were created. Based on coherence scores and manual inspection, the model with 300 topics was selected. These statistical methods served for highlighting timely topic trends, differing thematic fields, and emerging communities in the topic network. The study critically reflects the quantitative results from a sustainability perspective. Results: The study identifies a focus on establishing and optimizing the energy infrastructure towards 100% renewable energies through key modern technology areas: materials science, (biological) process engineering, and (digital) monitoring and control systems. Energy storage, photonic materials, nanomaterials, or biofuels belong to the topics with the strongest trends. The study identifies decreasing trends for general aspects regarding sustainable development and related economic, environmental, and political issues. Conclusions: The discourse is latently adopting a technology-oriented paradigm focusing on renewable energy generation and is moving away from the multi-faceted concept of sustainability. The field has the potential to contribute to climate change mitigation by optimizing renewable energy systems. However, given the complexity of these systems, horizontal integration of the various valuable vertical research strands is required. Furthermore, the holistic ecological perspective considering the global scale that has originally motivated research on sustainable energy might be re-strengthened, e.g., by an integrated energy and materials perspective. Beyond considering the physical dimensions of energy systems, existing links from the currently technology-oriented discourse to the social sciences might be strengthened. For establishing sustainable energy systems, future research will not only have to target the technical energy infrastructure but put a stronger focus on issues perceivable from a holistic second-order perspective.

Description: Climate researchers agree that anthropogenic greenhouse gas emissions significantly contribute to climate change, and that radical measures to reduce greenhouse gas emissions and to adapt to the impacts of no longer avoidable climate change are needed. The German Federal Government with its Climate Protection Plan 2050 reinforced its target to reduce Germany's greenhouse gas emissions by 80 to 95 percent compared with 1990. The achievement of these targets requires nothing less than a fundamental transformation of spatial planning. In the paper a methodology to scientifically assess the likely impacts of possible combinations of policies or strategies to achieve the energy transition, i.e. to reduce the greenhouse gas emissions of urban mobility and transport is proposed and demonstrated, using the Ruhr Area, the largest conurbation in Germany, as an example. The results of the policies examined so far can be summarised as follows: Push measures as high energy prices, speed limits or reduction of the number of lanes of main roads are more effective in reducing greenhouse gas emissions than pull measures as the promotion of cycling, walking, electric cars or public transport. Between policies or policy packages there can be positive or negative synergies, i.e. the impacts of measures can reinforce or weaken each other. The results show that even with ambitious policies the greenhouse gas emission targets of the national and state governments will not be achieved and that more radical policies are needed.

Description: The decarbonisation of the building stock is an important element for the success of the German Energiewende (energy transition). Despite some progress having been made, the rate of energy renovation falls below the level required to meet political commitments. This gives rise to the question: what deters property owners from making energy efficiency investments and how can the policy framework foster such investments? To answer this question, the paper focuses on a widely neglected property owner group: small private landlords (SPL). Although they manage 37% of all residential rental properties in Germany, very little is known about their decision-making processes for energy efficiency investments. We applied a mixed-method design to identify factors that hindered and supported their investments. In an explorative study, we initially conducted 18 problem-centred interviews. Subsequently, we carried out a postal survey and analysed the questionnaires using a hierarchical linear regression model. The results show that energy renovation is a multi-dimensional decision-making process, which can only be adequately addressed by a comprehensive policy package. To develop such a package, the author recommends that the specific investment behaviour of SPL must be better targeted, their knowledge about energy efficiency investments must be improved through exchange and networking, a sense of responsibility for the neighbourhood must be fostered, and greater focus must be placed on improving local framework conditions

Description: Science and education are central fields and a lever for sustainable development. With the newly developed student teaching and learning format "Transformative Innovation Lab" - TIL for short - students are to be enabled to conduct independent transformative research. To this end, the researchers, under the direction of the Wuppertal Institute, developed and tested the new learning concept in the project "Development, testing and dissemination of new qualification offers for 'change agents' for transformative learning using the real-world laboratory approach" (EEVA). The detailed results and numerous implementation tips have been published in a practical handbook aimed at academic teaching staff and other multipliers.

Description: Semi-enclosed marginal seas like the Baltic Sea are often characterized by permanently anoxic deep layers, and may therefore serve as important model systems to study the causes and consequences of the predicted global expansion of oxygen minimum zones. Here, we focus on the role of lateral intrusions in maintaining the “hypoxic transition zone” (HTZ) of the Baltic Sea, which characterizes the quasi-permanent hypoxic region located between the oxygenized surface layer and the sulfidic deep-water region. Based on long-term deployments of an autonomous profiling system in the central Baltic Sea, we show that oxic mid-water intrusions are ubiquitous features, providing the most important oxygen source for the HTZ, and largely control the vertical and lateral extent of the hypoxic areas. An oxygen budget for the HTZ suggests that oxygen turnover in the HTZ is, to first order, determined by a long-term balance between sedimentary oxygen demand and oxygen import by intrusions. The downward mixing of oxygen into the HTZ is generally non-negligible but unlikely to provide a first-order contribution to the HTZ oxygen budget. On the long-term average, mid-water intrusions were shown to inject 30–60 Gmol of oxygen per year into the deep-water region below the permanent halocline. This is approximately one order of magnitude larger than the average amount of oxygen imported during the massive deep-water inflow events (Major Baltic Inflows) that occur on an approximately decadal time scale, highlighting the HTZ as a hotspot for biogeochemical turnover.

Description: In the Antarctic ozone hole, ozone mixing ratios have been decreasing to extremely low values of 0.01–0.1 ppm in nearly all spring seasons since the late 1980s, corresponding to 95–99% local chemical loss. In contrast, Arctic ozone loss has been much more limited and mixing ratios have never before fallen below 0.5 ppm. In Arctic spring 2020, however, ozonesonde measurements in the most depleted parts of the polar vortex show a highly depleted layer, with ozone loss averaged over sondes peaking at 93% at 18 km. Typical minimum mixing ratios of 0.2 ppm were observed, with individual profiles showing values as low as 0.13 ppm (96% loss). The reason for the unprecedented chemical loss was an unusually strong, long-lasting, and cold polar vortex, showing that for individual winters the effect of the slow decline of ozone-depleting substances on ozone depletion may be counteracted by low temperatures.

Description: Micron-sized HNO3-containing particles in polar stratospheric clouds are known to denitrify the polar winter stratosphere and support chemical ozone loss. We show that populations of nitric acid trihydrate (NAT) particles with volume-equivalent median radii of 3–7 μm can be detected vortex-wide by means of infrared limb sounding. Key for detection are the applied optical characteristics of highly aspherical particles consisting of the β-NAT phase. Spectroscopic signatures and ambient conditions of detected populations show that these particles play a key role in denitrification of the Arctic winter stratosphere. Complementary gas-phase HNO3 observations indicate collocated highly efficient HNO3 sequestration within days and are consistent with measured spectral signals of populations of large NAT particles. High amounts of condensed gas-phase equivalent HNO3 exceeding 10 ppbv and long persistence of detected populations, despite expected gravitational settling, imply that our understanding of the particles is incomplete.

Description: The Global Carbon Budget 2018 (GCB2018) estimated by the atmospheric CO 2 growth rate, fossil fuel emissions, and modeled (bottom-up) land and ocean fluxes cannot be fully closed, leading to a “budget imbalance,” highlighting uncertainties in GCB components. However, no systematic analysis has been performed on which regions or processes contribute to this term. To obtain deeper insight on the sources of uncertainty in global and regional carbon budgets, we analyzed differences in Net Biome Productivity (NBP) for all possible combinations of bottom-up and top-down data sets in GCB2018: (i) 16 dynamic global vegetation models (DGVMs), and (ii) 5 atmospheric inversions that match the atmospheric CO 2 growth rate. We find that the global mismatch between the two ensembles matches well the GCB2018 budget imbalance, with Brazil, Southeast Asia, and Oceania as the largest contributors. Differences between DGVMs dominate global mismatches, while at regional scale differences between inversions contribute the most to uncertainty. At both global and regional scales, disagreement on NBP interannual variability between the two approaches explains a large fraction of differences. We attribute this mismatch to distinct responses to El Niño–Southern Oscillation variability between DGVMs and inversions and to uncertainties in land use change emissions, especially in South America and Southeast Asia. We identify key needs to reduce uncertainty in carbon budgets: reducing uncertainty in atmospheric inversions (e.g., through more observations in the tropics) and in land use change fluxes, including more land use processes and evaluating land use transitions (e.g., using high-resolution remote-sensing), and, finally, improving tropical hydroecological processes and fire representation within DGVMs.

Description: Abstract Although the core velocity of the Atlantic North Equatorial Undercurrent (NEUC) is low (0.1−0.3 m s−1), it has been suggested to act as an important oxygen supply route towards the oxygen minimum zone in the eastern tropical North Atlantic. For the first time, the intraseasonal to interannual NEUC variability and its impact on oxygen are investigated based on shipboard and moored velocity observations around 5°N, 23°W. In contrast to previous studies that were mainly based on models or hydrographic data, we find hardly any seasonal cycle of NEUC transports in the central Atlantic. The NEUC transport variability is instead dominated by sporadic intraseasonal events. Only some of these events are associated with high oxygen levels suggesting an occasional eastward oxygen supply by NEUC transport events. Nevertheless, they likely contribute to the local oxygen maximum in the mean shipboard section along 23°W at the NEUC core position.

Description: In this study we demonstrate the potential of a kinetic energy backscatter scheme for use in global ocean simulations. Ocean models commonly employ (bi)harmonic eddy viscosities causing excessive dissipation of kinetic energy in eddy-permitting simulations. Overdissipation not only affects the smallest resolved scales but also the generation of eddies through baroclinic instabilities, impacting the entire wave number spectrum. The backscatter scheme returns part of this overdissipated energy back into the resolved flow. We employ backscatter in the FESOM2 multiresolution ocean model with a quasi-uniform 1/4° mesh. In multidecadal ocean simulations, backscatter increases eddy activity by a factor 2 or more, moving the simulation closer to observational estimates of sea surface height variability. Moreover, mean sea surface height, temperature, and salinity biases are reduced. This amounts to a globally averaged bias reduction of around 10% for each field, which is even larger in the Antarctic Circumpolar Current. However, in some regions such as the coastal Kuroshio, backscatter leads to a slight overenergizing of the flow and, in the Antarctic, to an unrealistic reduction of sea ice. Some of the bias increases can be reduced by a retuning of the model, and we suggest related adjustments to the backscatter scheme. The backscatter simulation is about 2.5 times as expensive as a simulation without backscatter. Most of the increased cost is due to a halving of the time step to accommodate higher simulated velocities.

Description: Recent evidence shows that wind-driven ocean currents, like the western boundary currents, are strongly affected by global warming. However, due to insufficient observations both on temporal and spatial scales, the impact of climate change on large-scale ocean gyres is still not clear. Here, based on satellite observations of sea surface height and sea surface temperature, we find a consistent poleward shift of the major ocean gyres. Due to strong natural variability, most of the observed ocean gyre shifts are not statistically significant, implying that natural variations may contribute to the observed trends. However, climate model simulations forced with increasing greenhouse gases suggest that the observed shift is most likely to be a response of global warming. The displacement of ocean gyres, which is coupled with the poleward shift of extratropical atmospheric circulation, has broad impacts on ocean heat transport, regional sea level rise, and coastal ocean circulation.

Description: Simulating Arctic Ocean mesoscale eddies in ocean circulation models presents a great challenge because of their small size. This study employs an unstructured-mesh ocean-sea ice model to conduct a decadal-scale global simulation with a 1-km Arctic. It provides a basinwide overview of Arctic eddy energetics. Increasing model resolution from 4 to 1 km increases Arctic eddy kinetic energy (EKE) and total kinetic energy (TKE) by about 40% and 15%, respectively. EKE is the highest along main currents over topography slopes, where strong conversion from available potential energy to EKE takes place. It is high in halocline with a maximum typically centered in the depth range of 70–110 m, and in the Atlantic Water layer of the Eurasian Basin as well. The seasonal variability of EKE along the continental slopes of southern Canada and eastern Eurasian basins is similar, stronger in fall and weaker in spring.

Description: A method using a linear shallow water model is presented for decomposing the temporal variability of the barotropic stream function in a high-resolution ocean model. The method is based on the vertically averaged momentum equations and is applied to the time series of annual mean stream function from the model configuration VIKING20 for the northern North Atlantic. An important result is the role played by the nonlinear advection terms in VIKING20 for driving transport. The method is illustrated by examining how the Gulf Stream transport in the recirculation region responds to the winter North Atlantic Oscillation (NAO). While no statistically significant response is found in the year overlapping with the winter NAO index, there is a tendency for the Gulf Stream transport to increase as the NAO becomes more positive. This becomes significant in lead years 1 and 2 when the mean flow advection and eddy momentum flux contributions, associated with nonlinear momentum advection, dominate. Only after 2 years, does the potential energy term, associated with the density field, start to play a role and it is only after 5 years that the transport dependence on the NAO ceases to be significant. It is also shown that the potential energy contribution to the transport stream function has significant memory of up to 5 years in the Labrador and Irminger Seas. However, it is only around the northern rim of these seas that VIKING20 and the transport reconstruction exhibit similar memory. This is due to masking by the mean flow advection and eddy momentum flux contributions.

Description: Phytoplankton functional-type (PFT) data are assimilated into the global coupled ocean-ecosystem model MITgcm-REcoM2 for two years using a local ensemble Kalman filter. The ecosystem model has two PFTs: small phytoplankton (SP) and diatoms. Three different sets of satellite PFT data are assimilated: Ocean-Color-Phytoplankton Functional Type (OC-PFT), Phytoplankton Differential Optical Absorption Spectroscopy (PhytoDOAS), and SYNergistic exploitation of hyper- and multi-spectral precursor SENtinel measurements to determine Phytoplankton Functional Types (SynSenPFT), which is a synergistic product combining the independent PFT products OC-PFT and PhytoDOAS. The effect of assimilating PFT data is compared with the assimilation of total chlorophyll data (TChla), which constrains both PFTs through multivariate assimilation. While the assimilation of TChla already improves both PFTs, the assimilation of PFT data further improves the representation of the phytoplankton community. The effect is particularly large for diatoms where, compared to the assimilation of TChla, the SynSenPFT assimilation results in 57% and 67% reduction of root-mean-square error and bias, respectively, while the correlation is increased from 0.45 to 0.54. For SP the assimilation of SynSenPFT data reduces the root-mean-square error and bias by 14% each and increases the correlation by 30%. The separate assimilation of the PFT data products OC-PFT, SynSenPFT, and joint assimilation of OC-PFT and PhytoDOAS data leads to similar results while the assimilation of PhytoDOAS data alone leads to deteriorated SP but improved diatoms. When both OC-PFT and PhytoDOAS data are jointly assimilated, the representation of diatoms is improved compared to the assimilation of only OC-PFT. The results show slightly lower errors than when the synergistic SynSenPFT data are assimilated, which shows that the assimilation successfully combines the separate data sources.

Description: During seawater circulation in permeable intertidal sands, organic matter degradation alters the composition of percolating fluids and remineralization products discharge into surficial waters. Concurrently, coastal seawater nutrient and organic matter composition change seasonally due to variations in pelagic productivity. To assess seasonal changes in organic matter degradation in the intertidal zone of a high energy beach (Spiekeroog Island, southern North Sea, Germany), we analyzed shallow pore waters for major redox constituents (oxygen [O2], manganese [Mn], and iron [Fe]) and inorganic nitrogen species (nitrite [NO2−], nitrate [NO3−], and ammonium [NH4+]) in March, August, and October. Surface water samples from a local time series station were used to monitor seasonal changes in pelagic productivity. O2 and NO3− were the dominating pore water constituents in March and October. Dissolved Mn, Fe, and NH4+ were more widely distributed in August. Seasonal changes in seawater temperature as well as organic matter and nitrate supply by seawater were assumed to affect microbial rates and degradation pathways. Pore water and seawater variability led to seasonally changing constituent effluxes to surface waters. Mn, Fe, and NH4+ effluxes are minimal in March and reached their maximum in August. Furthermore, the intertidal sands switched from a net dissolved inorganic nitrogen sink in March to a net source in August. In conclusion, seasonal effects on intertidal pore water biogeochemistry affect constituent fluxes across the sediment-water interface. The seasonality of the beach bioreactor must be considered when fluxes are extrapolated to annual timescales.

Description: Internal-tide generation has been quantified using both pressure work and energy conversion. When calculating the pressure work from simulated or observed data, the internal-tide pressure has to be decomposed from the full pressure, for which various options exist. We show that the conversion, that has to be derived from the depth-integrated energy equations, contains the work done by both the form drag at the bottom and that at the surface, with the latter being about 1% of the former. For calculating the pressure work, the internal-tide pressure identified as the deviation from the depth-averaged pressure perturbation has to be used. We analyzed the work done by the bottom form drag in STORMTIDE2, a concurrent simulation of circulations and tides. As expected, the identified internal-tide pressure reveals the characteristic pressure drop from the windward to the leeward side of an obstacle. The M2 internal-tide generation in STORMTIDE2 is more strongly controlled by the barotropic tide than by the topographic slope, partly because the tidal velocity can change up to one order of magnitude from the top to the foot of a high ridge within a short distance, a feature only produced by a high-resolution model. Consequently, the intense generation maps the immediate proximities of the summits of high ridges, making the global generation to be strongest near 1,200 m and decreasing drastically below 3,000 m. The depth structure of the generation differs in different basins, which could impact differently on circulations in different basins.

Description: The space-borne geodetic temporal mean dynamic topography (MDT) is obtained from the difference of altimetric mean sea surface (MSS) h and the geoid height N. With the geostrophic surface currents obtained from its gradient, the MDT is an essential parameter when describing the ocean dynamics. Spectral consistency of h and N is crucial to minimize MDT errors. Frequently, h is globalized to allow for a spherical harmonic analysis, and small scales beyond maximum degree and order (d/o) resolved in the geoid are cut off. However, common globalization causes ocean-land steps in h−N and spectral inconsistencies of N and h over land. To overcome both issues, a methodology is proposed based on globalization of the MDT. A Laplacian smoother with the coastal MDT values as boundary condition is applied, resulting in a smooth surface over land and a continuous ocean-land transition. The new methodology strongly reduces Gibbs effects and the need to work with high-resolution MDTs to minimize them. Reduction of resolution is tested to reduce MDT uncertainties caused by the commission error expected to increase with decreasing scale. Applying drifter data and a high-resolution hydrodynamic ocean model, it is shown that for the Gulf Stream and the Kuroshio, geodetic MDTs applying recent combined geoid models contain physical information up to at least d/o 420 (48-km spatial scale). For oceanic regions with strong geoid gradients, a higher-resolution MDT might be needed to prevent Gibbs effects caused by remaining inconsistencies between the geoid and the MSS.

Description: The Atlantic Subtropical Cells (STCs) are shallow wind-driven overturning circulations connecting the tropical upwelling areas to the subtropical subduction regions. In both hemispheres, they are characterized by equatorward transport at thermocline level, upwelling at the equator, and poleward Ekman transport in the surface layer. This study uses recent data from Argo floats complemented by ship sections at the western boundary as well as reanalysis products to estimate the meridional water mass transports and to investigate the vertical and horizontal structure of the STCs from an observational perspective. The seasonally varying depth of meridional velocity reversal is used as the interface between the surface poleward flow and the thermocline equatorward flow. The latter is bounded by the 26.0 kg m−3 isopycnal at depth. We find that the thermocline layer convergence is dominated by the southern hemisphere water mass transport (9.0 ± 1.1 Sv from the southern hemisphere compared to 2.9 ± 1.3 Sv from the northern hemisphere) and that this transport is mostly confined to the western boundary. Compared to the asymmetric convergence at thermocline level, the wind-driven Ekman divergence in the surface layer is more symmetric, being 20.4 ± 3.1 Sv between 10°N and 10°S. The net poleward transports (Ekman minus geostrophy) in the surface layer concur with values derived from reanalysis data (5.5 ± 0.8 Sv at 10°S and 6.4 ± 1.4 Sv at 10°N). A diapycnal transport of about 3 Sv across the 26.0 kg m−3 isopycnal is required in order to maintain the mass balance of the STC circulation.

Description: The TICON (TIdal CONstants) dataset contains harmonic constants of 40 tidal constituents computed for 1,145 tide gauges distributed globally. The tidal estimations are based on publicly available sea level records of the second version of the Global Extreme Sea Level Analysis (GESLA) project and were derived through a least squares-based harmonic analysis on the single time series. A preliminary screening was performed on all records to exclude doubtful observations. Only the records containing more than 70% of valid measurements were processed, that correspond to 89.7% of the total 1,276 original public GESLA records. The results are stored in a text file, and include additional information on the position of the stations, the starting and ending years of the analysed record, the estimated error of the fit, a code that corresponds to the source of the record and additional information on the single time series. In ocean tide models, data from in situ stations are used for validation purposes, and TICON is a useful and easy-to-handle data set that allows the users to select the records according to different criteria most suitable for their purposes. The data are provided with DOI identification in the PANGAEA repository.

Description: The Denmark Strait overflow is the major export route of dense water from the Arctic Mediterranean into the North Atlantic. At the Strait's shallow sill, the overflow is a bottom-intensified cold and dense plume, bound to the east by a thermal front formed with the warmer, northward flowing North Icelandic Irminger Current. More than two decades of observations at the sill show strong fluctuations of volume flux on daily time scales. To better understand the source of this variability, a five-mooring array was installed at the sill, capturing nearly 1 year of velocity and bottom temperature measurements at a high temporal and spatial resolution. Bottom temperature fluctuations that exceed 4 °C indicate a meandering of the front between the plume and the North Icelandic Irminger Current. Current vector rotation shows trains of alternating cyclones and anticyclones at the sill. An eddy crosses the sill every 3 to 6 days with a mean velocity of 0.4 m/s and a typical diameter of 30 to 40 km. The results suggest that anticyclones, with centers passing through the deepest part of the sill, may be responsible for periods of increased volume flux—also referred to as boluses and pulses in previous studies. Although the relationship between eddies, pulses, and boluses is still unclear, the results show that eddies are directly linked to fluctuations in the strength, thickness, and position of the overflow plume.

Description: The Filchner-Ronne Ice Shelf, fringing the southern Weddell Sea, is Antarctica's second largest ice shelf. At present, basal melt rates are low due to active dense water formation; however, model projections suggest a drastic increase in the future due to enhanced inflow of open-ocean warm water. Mooring observations from 2014 to 2016 along the eastern flank of the Filchner Trough (76°S) revealed a distinct seasonal cycle with inflow if Warm Deep Water during summer and autumn. Here we present extended time series showing an exceptionally warm and long inflow in 2017, with maximum temperatures exceeding 0.5°C. Warm temperatures persisted throughout winter, associated with a fresh anomaly, which lead to a change in stratification over the shelf, favoring an earlier inflow in the following summer. We suggest that the fresh anomaly developed upstream after anomalous summer sea ice melting and contributed to a shoaling of the shelf break thermocline.

Description: The Weddell Sea is of global importance in the formation of dense bottom waters associated with sea ice formation and ocean-ice sheet interaction occurring on the shelf areas. In this context, the Weddell Sea boundary current system (BCS) presents a major conduit for transporting relatively warm water to the Weddell Sea ice shelves and for exporting some modified form of Wedell Sea deep and bottom waters into the open ocean. This study investigates the downstream evolution of the structure and the seasonality of the BCS along the Weddell Sea continental slope, combining ocean data collected for the past two decades at three study locations. The interannual-mean geostrophic flow, which follows planetary potential vorticity contours, shifts from being surface intensified to bottom intensified along stream. The shift occurs due to the densification of water masses and the decreasing surface stress that occurs westward, toward the Antarctic Peninsula. A coherent along-slope seasonal acceleration of the barotropic flow exists, with maximum speed in austral autumn and minimum speed in austral summer. The barotropic flow significantly contributes to the seasonal variability in bottom velocity along the tip of the Antarctic Peninsula. Our analysis suggests that the winds on the eastern/northeastern side of the gyre determines the seasonal acceleration of the barotropic flow. In turn, they might control the export of Weddell Sea Bottom Water on seasonal time scales. The processes controlling the baroclinic seasonality of the flow need further investigation.

Description: A geoarchaeological soil phosphorus (P) prospection is used to identify a gate within the prehistoric rampart of the Milseburg hillfort (Hesse, Germany). This study compares the application of a P fractionation scheme and P extraction with ammonium-oxalate. We hypothesized that oxalate-extractable P (P-ox) and the related degree of P saturation (DPS) could replace the more expensive and time-consuming fractionation schemes for geoarchaeological investigations. Comparing the results, the P fractionation helped to verify the existence of another section of the prehistoric ramparts and to identify the location of a gate within it. It also helped to discover the archaeologically relevant soil depths in the investigated area. This information could not be retrieved from the P-ox data alone. Soil P-ox contents and DPS values are relatively unspecific with regard to prehistoric land use. However, DPS at least indicates settled versus unsettled areas. Still, the results of the P fractionation more clearly delineate Iron Age land use areas including settlement, non-settlement, rampart, and rampart gap (probable gate). Thus, in geoarchaeological contexts, this method seems to be preferable to a singular P-ox extraction. However, for better results, P-ox determination could be integrated into a P fractionation scheme.

Description: Riparian zones are important buffer zones for streams as they are hotspots of nitrate transformation and removal in agricultural catchments. However, mixing of water from different sources and various transformation processes can complicate the quantification of nitrate turnover in riparian zones. In this study, we analyzed nitrate concentration and isotope data in riparian groundwater along a 2-km stream section in central Germany. We developed a mathematical model combining end-member mixing and isotope modeling to account for mixing of river water and groundwater and quantify nitrate transformation in riparian groundwater. This enabled us to explicitly determine the extent of denitrification (as process leading to permanent nitrate removal from riparian groundwater) and transient nitrate removal by additional processes associated with negligible isotope fractionation (e.g., plant uptake and microbial assimilation) and to perform an extensive uncertainty analysis. Based on the nitrogen isotope data of nitrate, the simulations suggest a mean removal of up to 27% by additional processes and only about 12% by denitrification. Nitrate removal from riparian groundwater by additional processes exceeded denitrification particularly in winter and at larger distance from the river, underlining the role of the river as organic carbon source. This highlights that nitrate consumption by additional processes predominates at the field site, implying that a substantial fraction of agricultural nitrogen input is not permanently removed but rather retained in the riparian zone. Overall, our model represents a useful tool to better compare nitrogen retention to permanent nitrogen removal in riparian zones at various temporal and spatial scales.

Description: Emissions of the potent greenhouse gas methane (CH4) from streams and rivers are a significant component of global freshwater methane emissions. The distribution of CH4 production and oxidation within stream sections and in vertical sediment profiles is not well understood, and the environmental controls on CH4 production and emission in such systems create a significant challenge for assessing larger-scale dynamics. Here we investigate factors driving the spatial variability of sediment potential methane production (PMP) and potential methane oxidation (PMO) in a temperate stream network in Germany. PMP was highly variable, ranging from 5 × 10−4 to 28.58 μg CH4 gDW−1 d−1 and PMO ranged from 0.43 μg CH4 gDW−1 d−1 to 14.41 μg CH4 gDW−1 d−1. Important drivers of spatial variability of PMP and PMO in the sediments of the stream main-stem were related to fine sediment fraction and organic carbon content. At smaller spatial scale, that is, in a sub-catchment stream section, the drivers were more complex and included sediment nitrogen and organic carbon content, as well as porewater dissolved organic carbon, dissolved organic matter quality, and metal concentrations. As with reservoirs and impounded rivers, fine sediment deposition and organic carbon content were found to be key controls on the spatial variability of CH4 production and oxidation. These findings enhance our understanding of CH4 dynamics, improve the potential for identifying CH4 production hotspots in small streams, and provide a potential means for upscaling emission rates in larger-scale assessments.

Description: Separate evaluation of methane (CH4) emission dynamics (e.g., oxidation, production, and transportation) at the soil-plant-atmosphere and soil-water-atmosphere interfaces has been limited in tropical rice paddies, but it is crucial for comprehending the entire CH4 cycles. We investigated CH4 oxidation, production, and transportation through plant and water pathways during the reproductive stage in a tropical Thailand rice paddy field using natural abundance carbon stable isotope ratios (δ13CH4 and δ13CO2). Mass balance equations using δ13CH4 and δ13CO2 in soil gases indicated that CH4 oxidation in the planted soil exceeded those in the interrow soil due to oxygen supply through rice roots. In addition, at 1–11 cm depth acetate fermentation was the dominant process in the planted soil, whereas in the interrow soil the dominant process was H2/CO2 reduction. The water pathway showed a significant negative correlation between CH4 flux and released δ13CH4 over 24 hr, driven by a diel change in episodic ebullition, steady ebullition, and diffusion, all due to diel changes in soil temperature and atmospheric pressure. In contrast, the plant pathway showed a significant positive relationship between CH4 flux and emitted δ13CH4 throughout one day. A comparison of the diel change in emitted δ13CH4 between the water and plant pathways showed that the rice plants transported CH4 in soil bubbles without any large isotopic fractionation. The diel change in the plant-mediated CH4 transportation was mainly controlled by diel changes in soil bubble expansion and CH4 diffusion through plants, which were probably regulated by diel changes in soil temperature and atmospheric pressure.

Description: We analyzed velocity and hydrographic data from 23 moorings in the northeast Chukchi Sea from 2011 to 2014. In most years the eastern side of Hanna Shoal was strongly stratified year-round, while weakly stratified regions prevailed on the shelf south and west of the Shoal. Stratification differences cause differential vertical mixing rates, which in conjunction with advection of different bottom water properties resulted in seasonally varying along-isobath density gradients. In agreement with numerical models, we find that bottom waters flow anticyclonically around the Shoal. Whereas most of the shelf responded barotropically to wind-forcing, there was a strong baroclinic component to the flow field northeast of Hanna Shoal, resulting in no net vertically integrated transport on average. In contrast there is a net eastward transport from west of the Shoal, which implies convergence north of the Shoal. Convergence and along-isobath density gradients may foster cross-shelf exchange north of Hanna Shoal. Modal analyses indicate that the shelf south of the Shoal and Barrow Canyon responded coherently to local and remote winds, whereas the wind-current response around Hanna Shoal was less coherent. Barotropic topographic waves, of ~3-day period, were generated episodically northeast of the Shoal and propagate clockwise around Hanna Shoal, but are blocked from entering Barrow Canyon and are possibly scattered by the horizontally sheared flow and converging isobaths on the western side of the Shoal. Analysis of water properties on the western side of Hanna Shoal suggests that these include contributions from the western and southern portions of the Chukchi Sea.

Description: Ocean bottom pressure (OBP) variability serves as a proxy of ocean mass variability, the knowledge of which is needed in geophysical applications. The question of how well it can be modeled by the present general ocean circulation models on time scales in excess of 1 day is addressed here by comparing the simulated OBP variability with the observed one. To this end, a new multiyear data set is used, obtained with an array of bottom pressure gauges deployed deeply along a transect across the Southern Ocean. We present a brief description of OBP data and show large-scale correlations over several thousand kilometers at all time scales using daily and monthly averaged data. Annual and semiannual cycles are weak. Close to the Agulhas Retroflection, signals of up to 30 cm equivalent water height are detected. Further south, signals are mostly intermittent and noisy. It is shown that the models simulate consistent patterns of bottom pressure variability on monthly and longer scales except for areas with high mesoscale eddy activity, where high resolution is needed to capture the variability due to eddies. Furthermore, despite good agreement in the amplitude of variability, the in situ and simulated OBP show only modest correlation.

Description: The influence of large-scale oceanic circulation on salinity in the northern North Sea has lead to the hypothesis that nutrient concentrations in this region are also driven by remote oceanic anomalies. Here, using a newly established biogeochemical data set of the North Sea, we show that interannual to decadal variability in winter nutrient concentrations exhibits distinct phase deviations from salinity. The variability in salinity is explained by zonal shifts in the position of the subpolar front (SPF) in the eastern North Atlantic and the associated advective delay. However, the high correlation and absence of advective delay between the position of the SPF and winter nutrient concentrations in the Shetland region (59–61°N, 1°W to 3°E) point to the role of atmospheric variability in driving concurrent changes in winter nutrient concentrations and the SPF position. Our analysis suggests that the prevailing wind direction and local distribution of winter nutrient concentrations together determine the interannual to decadal variability in winter nutrient concentrations in this region. In the analyzed observations, we find a strong spatial gradient in mean winter nutrient concentrations northwest of the Shetland region, which is absent in salinity. The horizontal shift of this spatial gradient, forced by changes in wind direction, has a larger influence on winter nutrient concentration in the Shetland region than the nutrient signal in oceanic anomalies originating from the eastern subpolar North Atlantic. Overall, we conclude that interannual to decadal variability in the observed nutrient concentrations is mainly driven by atmospheric variability here expressed as wind direction.

Description: Deep convection over tropical oceans often appears intensified at the edge of convectively active regions, both in idealized studies and in observations. This edge intensification of convection is studied in detail here, using the steady state of a radiative-convective equilibrium study, marked by a single convective cluster with deep convection intensified at the edge of this cluster. The cause for edge intensification and its dependence on the cluster area is investigated by comparing the spatial distribution of deep convection to different variables known to be important for convection. Analysis of the simulation suggests that the edge is marked by an increased probability for the triggering of convection rather than by stronger updrafts. In particular, while the edge of the moist region is not thermodynamically more favorable, we find strong surface convergence and therefore dynamical lifting at this edge. The surface convergence is shown to result from two opposing flows. On the one hand, there is, as expected from previous radiative-convective equilibrium simulations, a low-level inflow directed toward the moist region. On the other hand, there is a positive density anomaly at the surface which is the result of continuously forming cold pools within the convectively active region, creating a super-cold-pool. As the velocity of the low-level inflow approximately matches the potential propagation speed of the super-cold-pool boundary, these opposing flows explain the presence of strong convergence at the edge of this region. Whether the resulting lifting induces the formation of deep convection is shown to depend on the large-scale instability.

Description: Climate change is expected to enhance the hydrological cycle in northern latitudes reducing the salinity in the Baltic Sea, a land-locked marginal sea with a large catchment area located in northern Europe. With the help of ocean simulations forced by historical atmospheric and hydrological reconstructions and local observations, we analyzed long-term changes in the sea surface salinity of the Baltic Sea as well as its latitudinal gradient. The variability of both is dominated by multidecadal oscillations with a period of about 30 years, while both atmospheric variables, wind and river runoff, contribute to this variability. Centennial changes show a statistically significant positive trend in the North-South gradient of sea surface salinity for 1900–2008. This change is mainly attributed to increased river runoff from the northernmost catchment indicating a footprint of the anthropogenic impact on salinity with consequences for the marine ecosystem and species distributions.

Description: An approach to analyze high-end sea level rise is presented to provide a conceptual framework for high-end estimates as a function of time scale, thereby linking robust sea level science with stakeholder needs. Instead of developing and agreeing on a set of high-end sea level rise numbers or using an expert consultation, our effort is focused on the essential task of providing a generic conceptual framework for such discussions and demonstrating its feasibility to address this problem. In contrast, information about high-end sea level rise projections was derived previously either from a likely range emerging from the highest view of emissions in the Intergovernmental Panel on Climate Change assessment (currently the Representative Concentration Pathway 8.5 scenario) or from independent ad hoc studies and expert solicitations. Ideally, users need high-end sea level information representing the upper tail of a single joint sea level frequency distribution, which considers all plausible yet unknown emission scenarios as well as involved physical mechanisms and natural variability of sea level, but this is not possible. In the absence of such information we propose a framework that would infer the required information from explicit conditional statements (lines of evidence) in combination with upper (plausible) physical bounds. This approach acknowledges the growing uncertainty in respective estimates with increasing time scale. It also allows consideration of the various levels of risk aversion of the diverse stakeholders who make coastal policy and adaptation decisions, while maintaining scientific rigor.

Description: C-band microwave sea surface radar backscatter observations from the FINO-2 tower in the western Baltic are analyzed with respect to their relevance for air-sea CO2 transfer velocity parameterizations. The scatterometer measurements observed from a height of 25 m above the sea surface using a multifrequency scatterometer instrument of the University of Hamburg were obtained quasi-simultaneously with eddy covariance CO2 flux measurements. Both data sets are merged here to derive a gas transfer velocity parameterization based on radar backscatter measurements. At the location of the FINO-2 tower, the resulting time-averaged gas transfer velocity amounts to 26.95 cm/hr. In combination with ΔPCO2 measurements available from the vicinity of the FINO-2 platform, a time-mean CO2 flux of 0.23 μmol·m−2·s−1 into the Baltic was estimated. Applied to monthly mean satellite-based C-band ASCAT scatterometer data, the newly derived gas transfer velocity parameterization provides estimates of seasonal and annual mean global maps of air-sea transfer velocities. The new results agree in their general pattern with previous estimates using wind speed parameterization. However, the backscatter-based transfer velocities appear smaller at higher latitudes. Globally averaged air-sea CO2 fluxes would thereby be reduced by 20%. To what extent this is a robust result, or if it depends on the fact that the training data set did not represent conditions, has to be investigated in the future.

Description: Neodymium (Nd) isotopes extracted from authigenic sediment phases are increasingly used as a proxy for past variations in water mass provenance. To better constrain the controls of water mass provenance and nonconservative effects on the archived Nd isotope signal, we present a new depth transect of Nd isotope reconstructions from the Blake Bahama Outer Ridge along the North American continental margin covering the past 30 ka. We investigated five sediment cores that lie directly within the main flow path of the Deep Western Boundary Current, a major advection route of North Atlantic Deep Water. We found offsets between core tops and seawater Nd isotopic compositions that are observed elsewhere in the Northwest Atlantic. A possible explanation for this is the earlier suggested redistribution of sediment by nepheloid layers at intermediate as well as abyssal depths, transporting material downslope and along the continental margin. These processes potentially contributed to Nd isotope excursions recorded in Northwest Atlantic sediment cores during the Bølling-Allerød and early Holocene. An Atlantic-wide comparison of Nd isotope records shows that the early Holocene excursions had an additional contribution from conservative advection of unradiogenic dissolved Nd. Nevertheless, the trends of the Nd isotope records are in general agreement with previous reconstructions of water mass provenance from the entire Atlantic and also reveal millennial-scale changes during the last deglaciation in temporal high resolution, which have rarely been reported before. Further, the new records confirm that during cold periods the Northwest Atlantic was bathed by an increased contribution of southern sourced water.

Description: A regional seismic survey on the southeastern Lomonosov Ridge (LR) and adjacent basins provides constraints on the coupled evolution of ocean circulations, depositional regime, and tectonic processes. First, Mesozoic strata on the LR, its faulted flanks and the initial Amundsen Basin were covered with syn-rift sediments of Paleocene to early Eocene age. Numerous vertical faults indicate differential compaction of possibly anoxic sediments deposited in the young, still isolated Eurasian Basin. The second stage, as indicated by a prominent high-amplitude-reflector sequence covering the ridge, was a time of widespread changes in deposition conditions, likely controlled by the ongoing subsidence of the LR and gradual opening of the Fram Strait. Episodic incursions of water masses from the North Atlantic probably were the consequences and led to the deposition of thin sedimentary layers of different lithology. The third stage is marked by continuous deposition since the early Miocene (20 Ma). At that time, the ridge no longer posed an obstacle between the Amerasia and Eurasia Basins and pelagic sedimentation was established. Drift bodies, sediment waves, and erosional structures indicate the onset of circulation. Faulting on the ridge slope has led to a series of terraces where sediment drifts have accumulated since the early Miocene. It is suggested that ongoing sagging of the ridge and currents may have shaped the steep sediment free flanks of the terraces. Lastly, a sequence of high-amplitude reflectors marks the transition to the early Pliocene large-scale Northern Hemisphere glaciations.

Description: The paper describes an update of the GECCO (German contribution to the Estimating the Circulation and Climate of the Ocean project) ocean synthesis, now in its version 3, and provides an evaluation of the results with assimilated and independent data. GECCO3 covers the 71-year period 1948–2018 and differs from its predecessor by returning to a single assimilation window instead of partitioning the period in 5-year-long overlapping windows which was previously necessary to yield convergence. A solution to the convergence problem is presented. GECCO3 is intended to be used for the initialization of coupled climate models and is configured for the higher-resolution version of the earth system model (MPI-ESM) developed at the Max Planck Institute for Meteorology. It uses the bathymetry and grid of the MPI-ESM with quasi-uniform resolution of 0.4°, thereby providing the first global eddy-permitting synthesis based on the adjoint method. The synthesis additionally features the estimation of various mixing parameters and can regionally choose between explicit or parametrized eddy fluxes. Except for the altimeter data in tropical regions, GECCO3 is in better agreement with the assimilated data than GECCO2. The improvements relative to the in situ data partly result from the much larger amount of Argo data, which show lower model–data differences. Global heat content changes are in good agreement with recent estimates, but show uptake almost exclusively in the top 700 m. An alternative version of GECCO3, created by starting from different first-guess control parameters, was used to evaluate the uncertainty of the estimated parameters and state due to lack of convergence. This estimate suggests a large uncertainty related to the uptake of heat into the lower layers, while estimates of mean meridional transport of heat and freshwater are not affected.

Description: Low-mode internal waves propagate over large distances and provide energy for turbulent mixing when they break far from their generation sites. A realistic representation of the oceanic energy cycle in ocean and climate models requires a consistent implementation of their generation, propagation, and dissipation. Here we combine the long-term mean energy flux from satellite altimetry with results from a 1/10° global ocean general circulation model that resolves the low modes of internal waves and in situ observations of stratification and horizontal currents to study energy flux and dissipation along a 1000 km internal tide beam in the eastern North Atlantic. Internal wave fluxes were estimated from twelve 36- to 48-hr stations in along- and across-beam direction to resolve both the inertial period and tidal cycle. The observed internal tide energy fluxes range from 5.9 kW m−1 near the generation sites to 0.5 kW m−1 at distant stations. Estimates of energy dissipation come from both finestructure and upper ocean microstructure profiles and range, vertically integrated, from 0.5 to 3.3 mW m−2 along the beam. Overall, the in situ observations confirm the internal tide pattern derived from satellite altimetry, but the in situ energy fluxes are more variable and decrease less monotonically along the beam. Internal tides in the model propagate over shorter distances compared to results from altimetry and in situ measurements, but more spatial details close the main generation sites are resolved.

Description: To which extent do happiness correlates contribute to the stability of life satisfaction? Which method is appropriate to provide a conclusive answer to this question? Based on life satisfaction data of the German SOEP, we show that by Negative Binomial quasi-maximum likelihood estimation statements can be made as to how far correlates of happiness contribute to the stabilisation of life satisfaction. The results show that happiness correlates which are generally associated with a positive change in life satisfaction, also stabilise life satisfaction and destabilise dissatisfaction with life. In such as they lower the probability of leaving positive states of life satisfaction and increase the probability of leaving dissatisfied states. This in particular applies to regular exercise, volunteering and living in a marriage. We further conclude that both patterns in response behaviour and the quality of the measurement instrument, the life satisfaction scale, have a significant effect on the variation and stability of reported life satisfaction.

Description: We examine the relative dispersion and the contribution of tides on the relative diffusivities of surface drifters in the North Sea. The drifters are released in two clusters, yielding 43 pairs, in the vicinity of a tidal mixing front in the German Bight, which is located in the southeastern area of the North Sea. Both clusters indicate decreasing dispersion when crossing the tidal mixing front, followed by exponentially increasing dispersion with e-folding times of 0.5 days for Cluster 1 and 0.3 days for Cluster 2. A transition of the dispersion regimes is observed at scales of the order of the Rossby radius of deformation (10 km). After that, the relative dispersion grows with a power-law dependency with a short period of ballistic dispersion (quadratic growth), followed by a Richardson regime (cubic growth) in the final phase. Scale-dependent metrics such as the relative diffusivities are consistent with these findings, while the analysis of the finite-scale Lyapunov exponents (FSLEs) shows contradictory results for the submesoscales. In summary, the analysis of various statistical Lagrangian metrics suggests that tracer stirring at the submesoscales is nonlocal and becomes local at separation scales larger than 10 km. The analysis of meridional and zonal dispersion components indicates anisotropic dispersion at the submesoscales, which changes into isotropic dispersion on the mesoscales. Spectral analysis of the relative diffusivity gives evidence that semidiurnal and shallow-water tides influence relative diffusivity at the mesoscales, especially for drifter separations above 50 km.

Description: Storms are infrequent, intense, physical forcing events that represent a potentially significant driver of ocean ecosystems. The objective of this study was to assess changes in water column structure and turbulent fluxes caused by storms using an autonomous underwater glider, as well as the chlorophyll a (Chl a) response to the altered physical environment. The glider was able to measure throughout the complete life cycle of Storm Bertha as it passed over the North Sea in August 2014, from its arrival to dissipation. Storm Bertha triggered rapid mixing of the thermocline through shear instability, increasing vertical fluxes by nearly an order of magnitude, and promoting increases in surface layer Chl a. The results demonstrate that storms represent a significant fraction of seasonal vertical turbulent fluxes, with potentially important consequences for biological production in shelf seas.

Description: Methane (CH4) production in the ocean surface mixed layer is a widespread but still largely unexplained phenomenon. In this context marine algae have recently been described as a possible source of CH4 in surface waters. In the present study we investigated the effects of temperature and light intensity (including daylength) on CH4 formation from three widespread marine algal species Emiliania huxleyi, Phaeocystis globosa, and Chrysochromulina sp. Rates of E. huxleyi increased by 210% when temperature increased in a range from 10°C to 21.5°C, while a further increase in temperature (up to 23.8°C) showed reduction of CH4 production rates. Our results clearly showed that CH4 formation of E. huxleyi is controlled by light: When light intensity increased from 30 to 2,670 μmol m−2 s−1, CH4 emission rates increased continuously by almost 1 order of magnitude and was more than 1 order of magnitude higher when the daylength (light period) was extended from 6/18 hr light-dark cycle to continuous light. Furthermore, light intensity is also an important factor controlling CH4 emissions of Chrysochromulina sp. and P. globosa and could therefore be a species-independent regulator of phytoplankton CH4 production. Based on our results, we might conclude that extensive blooms of E. huxleyi could act as a main regional source of CH4 in surface water, since blooming of E. huxleyi is related to the seasonal increase in both light and temperature, which also stimulate CH4 production. Under typical global change scenarios, E. huxleyi will increase its CH4 production in the future.

Description: The target of zero emissions sets a new standard for industry and industrial policy. Industrial policy in the twenty-first century must aim to achieve zero emissions in the energy and emissions intensive industries. Sectors such as steel, cement, and chemicals have so far largely been sheltered from the effects of climate policy. A major shift is needed, from contemporary industrial policy that mainly protects industry to policy strategies that transform the industry. For this purpose, we draw on a wide range of literatures including engineering, economics, policy, governance, and innovation studies to propose a comprehensive industrial policy framework. The policy framework relies on six pillars: directionality, knowledge creation and innovation, creating and reshaping markets, building capacity for governance and change, international coherence, and sensitivity to socio-economic implications of phase-outs. Complementary solutions relying on technological, organizational, and behavioural change must be pursued in parallel and throughout whole value chains. Current policy is limited to supporting mainly some options, e.g. energy efficiency and recycling, with some regions also adopting carbon pricing, although most often exempting the energy and emissions intensive industries. An extended range of options, such as demand management, materials efficiency, and electrification, must also be pursued to reach zero emissions. New policy research and evaluation approaches are needed to support and assess progress as these industries have hitherto largely been overlooked in domestic climate policy as well as international negotiations.

Description: Cities and municipalities have had to endure a great deal in recent years, including a global coronavirus pandemic, fire disasters in the US and devastating floods like those in Germany. These are also consequences of anthropogenic climate change, and cities have to be better prepared for such events in future. In particular, the cata-strophic flooding Germany experienced in July 2021 demonstrated how ill-equipped municipalities are for this type of incident. In this paper, we look at how cities can become more resilient, sustainable and ready for the future.

Description: Nutrition is one of the most important areas for the great transformation. So how can a shift towards a sustainable food system be achieved? This paper addresses this question - based on more than ten years of research on sustainable nutrition at the Wuppertal Institute. It focuses on public catering, because even small changes - for example in the choice of ingredients - have a huge impact here. With appropriate policy frameworks, public catering can serve as an easily accessible place for consumers to experience sustainable food and at the same time be a reliable buyer of biodiversity and climate-friendly food from farmers. However, other actors are also needed for a transformation of the food system: The "Zukunftsimpuls" addresses politics, (agricultural) industry, science and every individual - because the transformation of the food system is a task for the entire society.

Description: Ocean heat transport is often thought to play a secondary role for Arctic surface warming in part because warm water which flows northward is prevented from reaching the surface by a cold and stable halocline layer. However, recent observations in various regions indicate that occasionally, warm water is found directly below the surface mixed layer. Here we investigate Arctic Ocean surface energy fluxes and the cold halocline layer in climate model simulations from the Coupled Model Intercomparison Project Phase 5. An ensemble of 15 models shows decreased sea ice formation and increased ocean energy release during fall, winter, and spring for a high-emission future scenario. Along the main pathways for warm water advection, this increased energy release is not locally balanced by increased Arctic Ocean energy uptake in summer. Because during Arctic winter, the ocean mixed layer is mainly heated from below, we analyze changes of the cold halocline layer in the monthly mean Coupled Model Intercomparison Project Phase 5 data. Fresh water acts to stabilize the upper ocean as expected based on previous studies. We find that in spite of this stabilizing effect, periods in which warm water is found directly or almost directly below the mixed layer and which occur mainly in winter and spring become more frequent in high-emission future scenario simulations, especially along the main pathways for warm water advection. This could reduce sea ice formation and surface albedo.

Description: Changes in ocean gateway configuration can induce basin-scale rearrangements in ocean current characteristics. However, there is large uncertainty in the relative timing of the Oligocene/Miocene subsidence histories of the Greenland-Scotland Ridge (GSR) and the Fram Strait (FS). By using a climate model, we investigate the temperature and salinity changes in response to the subsidence of these two key ocean gateways during early to middle Miocene. For a singular subsidence of the GSR, we detect warming and a salinity increase in the Nordic Seas and the Arctic Ocean. As convection sites shift to the north of Iceland, North Atlantic Deep Water (NADW) is formed at cooler temperatures. The associated deep ocean cooling and upwelling of deep waters to the Southern Ocean surface can cause a cooling in the southern high latitudes. These characteristic responses to the GSR deepening are independent of the FS being shallow or deep. An isolated subsidence of the FS gateway for a deep GSR shows less pronounced warming and salinity increase in the Nordic Seas. Arctic temperatures remain unaltered, but a stronger salinity increase is detected, which further increases the density of NADW. The increase in salinity enhances the contribution of NADW to the abyssal ocean at the expense of the colder southern source water component. These relative changes largely counteract each other and cause a negligible warming in the upwelling regions of the Southern Ocean.

Description: The isotopic composition of Si in biogenic silica (BSi), such as opal buried in the oceans' sediments, has changed over time. Paleorecords suggest that the isotopic composition, described in terms of δ30Si, was generally much lower during glacial times than today. There is consensus that this variability is attributable to differing environmental conditions at the respective time of BSi production and sedimentation. The detailed links between environmental conditions and the isotopic composition of BSi in the sediments remain, however, poorly constrained. In this study, we explore the effects of a suite of offset boundary conditions during the Last Glacial Maximum (LGM) on the isotopic composition of BSi archived in sediments in an Earth System Model of intermediate complexity (EMIC). Our model results suggest that a change in the isotopic composition of Si supply to the glacial ocean is sufficient to explain the observed overall low(er) glacial δ30Si in BSi. All other processes explored trigger model responses of either wrong sign or magnitude or are inconsistent with a recent estimate of bottom water oxygenation in the Atlantic Sector of the Southern Ocean. Caveats, mainly associated with generic uncertainties in today's pelagic biogeochemical modules, remain.