ALBERT

Description: Geochemical analyses of carbonate minerals yield multiple parameters which can be used to estimate the temperature and water composition at which they formed. Analysis of fluid trapped in minerals is a potentially powerful tool to reconstruct paleotemperatures as well as diagenetic and hydrothermal processes, as these could represent the parent fluid. Internal fluids play important roles during the alteration of carbonate fossils, lowering energetic barriers associated with resetting of clumped isotopes, as well as mediating the transport of elements during diagenesis. Here, we explore the behavior of the ∆47–∆48 “dual‐clumped” isotope thermometer during fluid‐carbonate interaction and demonstrate that it is highly sensitive to the water/carbonate ratio, behaving as a linear system in “rock buffered” alteration, and as a decoupled system in water‐dominated systems due to non‐linear mixing effects in ∆48. Dry heating experiments show that the extrapolated “heated” end‐member is indistinguishable from the predicted ∆47 and ∆48 value expected for the experimental temperature. Furthermore, we evaluate two common laboratory sampling methods for their ability to thermally alter samples. We find that the temperature of the commonly used crushing cells used to vapourize water for fluid inclusion δ18O analyses is insufficient to cause fluid‐carbonate oxygen isotope exchange, demonstrating its suitability for analyses of fluid inclusions in carbonates. We also find that belemnites sampled with a hand‐drill yield significantly warmer paleotemperatures than those sampled with mortar and pestle. We conclude that thermally‐driven internal fluid‐carbonate exchange occurs indistinguishably from isotopic equilibrium, limited by the extent to which internal water and carbonate can react.

Description: Plain Language Summary: Carbonate minerals contain multiple, independent, chemical and isotopic parameters which can be used to calculate the temperature at which the mineral formed. If these proxies agree with one another, it has been confidently assumed that the temperature is indeed genuine. Here, we investigate three such parameters and show how they record kinetic processes during mineral formation, as well as thermally‐driven processes which may alter a climate record. We find that this method could potentially be used to study the kinetic factors at play during biomineralization, even if the “true” temperature is unknown. We also find that some thermal processes result in all three parameters agreeing with one another. Because thermal alteration poses a potential dilemma for climate researchers, we investigate two common laboratory preparation techniques that involve heating a sample before analysis: drilling and heating sample for fluid inclusion analysis. We find that the heat of a drill is sufficient to facilitate these reactions, and potentially imparts a warm bias onto paleotemperatures, however the apparatus used for analyzing fluid inclusions does not appear to significantly alter the material. We conclude our approach using fluid inclusion analysis and dual‐clumped isotopes has the potential to resolve many ambiguities in interpreting climate records.

Description: Key Points: We explore the behavior of dual‐clumped and fluid‐inclusion isotope paleothermometers during thermal alteration. Different conditions during diagenesis may result in discrepant paleotemperature estimates, which may be used to identify altered records. Hand‐drilling belemnites produces sufficient heat to reset paleotemperatures, but the heat during analysis of fluid inclusions does not.

Description: DFG

Description: https://doi.org/10.5281/zenodo.7565557

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Chloromethane (CH〈sub〉3〈/sub〉Cl) is the most abundant natural chlorinated organic compound in the atmosphere playing an important role in catalyzing stratospheric ozone loss. Vegetation emits the largest amounts of CH〈sub〉3〈/sub〉Cl to the atmosphere but its source strength is highly uncertain leading also to large uncertainties in the global budget of CH〈sub〉3〈/sub〉Cl. Triple‐element stable isotope analysis may help to reduce uncertainties because it provides additional process‐level information compared to conventional quantification methods. In this study we performed experiments to obtain a first triple‐elemental isotopic fingerprint (〈sup〉2〈/sup〉H, 〈sup〉13〈/sup〉C, 〈sup〉37〈/sup〉Cl) of CH〈sub〉3〈/sub〉Cl emitted by a relevant plant species (royal fern, 〈italic〉Osmunda regalis〈/italic〉). Isotopic values of all three elements showed considerable differences compared to isotopic values of industrially manufactured CH〈sub〉3〈/sub〉Cl which bodes well for future applications to distinguish individual sources. Isotopic analysis of potential precursors (rain, methoxy groups) of CH〈sub〉3〈/sub〉Cl in plants revealed no measurable change of hydrogen and chlorine isotopic ratios during formation which may provide a simpler route to estimate the isotopic composition of CH〈sub〉3〈/sub〉Cl emissions. Plant degradation experiments of CH〈sub〉3〈/sub〉Cl were carried out with club moss (〈italic〉Selaginella kraussiana〈/italic〉) revealing significant isotopic fractionation for all three elements. The fractionation pattern characterized by epsilon and lambda is inconsistent with known biotic dechlorination reactions indicating a yet unreported biotic degradation mechanism for CH〈sub〉3〈/sub〉Cl. Overall, this study provides first insights into the triple‐elemental isotopic fingerprint of plant emissions and degradation. The results may represent important input data for future isotope‐based models to improve global budget estimates of CH〈sub〉3〈/sub〉Cl and to explore the yet unknown degradation pathways.〈/p〉

Description: Plain Language Summary: Chloromethane is the most abundant chlorinated organic compound in the atmosphere. It contributes to the destruction of the ozone layer that protects us from skin cancer and genetic damage. Currently, we do not have a good understanding of the sources and removal processes of chloromethane in the atmosphere. In this paper, we use a technique that takes advantage of the different varieties of a chemical element. These so‐called isotopes behave differently during chemical reactions that lead to individual isotopic fingerprints depending on the source or removal process. We used isotopic fingerprints of all three chemical elements in chloromethane and showed that chloromethane produced by a plant (royal fern) differs substantially from chloromethane manufactured by industry. Other plant species such as club moss are able to remove chloromethane from the atmosphere but it is often not clear how this occurs. Isotopic analysis revealed that the studied club moss uses a unique, thus far unknown, way to break down chloromethane. This study demonstrates how information extracted from isotopic fingerprints will help to improve our understanding of sources and removal processes of chloromethane in the atmosphere. It can help to better predict how ozone destruction in the stratosphere affects us in the future.〈/p〉

Description: Key Points: First triple‐element isotopic characterization of plant CH〈sub〉3〈/sub〉Cl emission and degradation. Plant degradation experiments suggest another yet unknown transformation pathway. Important input data for future isotope based models to improve understanding of global CH〈sub〉3〈/sub〉Cl budget.

Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.48758/ufz.13388

Description: Large Igneous Provinces (LIPs) are unusual volcanic events in which massive amounts of melt (∼106 km3) erupt in relatively short time periods (〈106 years). Most LIP magmas have undergone extensive fractional crystallization and crustal contamination, but the crustal magmatic plumbing systems and the processes triggering eruptions are poorly understood. We present new major and trace element and radiogenic isotope data for 43 individual lava flows from a continuous 1,200 m thick stratigraphic profile through the upper, most voluminous part of the Deccan LIP (Bushe to Mahabaleshwar Formations). Eruption rates for this section are constrained by published paleomagnetic directions and absolute U‐Pb ages for zircons from weathered flow tops exposed in the profile. We find four magmatic sequences each lasting ∼104–∼105 years during which major and trace element compositions change systematically, followed by an abrupt change in geochemistry at the start of a new sequence. Within each sequence, the MgO content and proportion of crustal contamination decrease progressively, indicating a continuous replenishment of the associated magma reservoirs with less contaminated but more evolved melts. These geochemical signatures are best explained by repeated episodes of melt recharge, mixing, and eruption of variably evolved magmas originating from relatively small magma reservoir located in different crustal levels.

Description: Plain Language Summary: Volcanism occurs predominantly at plate boundaries, either at mid‐ocean ridges or subduction zones, where most mantle melts are produced. However, the Earth's history is punctuated by volcanic events which are not related to plate boundary processes and during which large amounts of melt erupt (∼106 km3) in relatively short periods of time (〈106 years). These Large Igneous Provinces (LIPs) are associated with the activity of mantle plumes and eruption rates during their main stages are significantly higher than those of today's largest magmatic systems. However, since no LIP is currently active, the architecture of the associated plumbing systems is relatively unknown. In order to understand the magmatic processes during the emplacement of a LIP, we generated geochemical data from a continuous stratigraphic profile covering the most voluminous stage of the ∼66 Ma Deccan LIP. By combining these new data with published paleomagnetic directions and absolute U‐Pb ages for zircons, we found four eruption sequences each lasting ∼104–∼105 years. During these sequences, geochemical compositions change systematically, which is best explained by repeated episodes of melt recharge, mixing, and eruption of variably evolved magmas originating from relatively small magma reservoirs located at different crustal levels.

Description: Key Points: Four recharge‐crystallization‐eruption sequences fed the most voluminous Deccan lava. Magmatic plumbing system with interconnected small‐ to medium‐sized magma reservoirs. Complex emplacement history including multiple stages of ascent, mixing, and storage.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.26022/IEDA/112672

Description: Limited constraints on the variability of the deep‐water production in the Labrador Sea complicate reconstructions of the strength of the Atlantic Meridional Overturning Circulation (AMOC) during the Late Quaternary. Large volumes of detrital carbonates were repeatedly deposited in the Labrador Sea during the last 32 kyr, potentially affecting radiogenic Nd isotope signatures. To investigate this the Nd isotope compositions of deep and intermediate waters were extracted from the authigenic Fe‐Mn oxyhydroxide fraction, foraminiferal coatings, the residual silicates and leachates of dolostone grains. We provide a first order estimation of Nd release via dissolution of detrital carbonates and its contribution to the authigenic ԑNd signatures in the Labrador Sea. During the Last Glacial Maximum the Nd isotope signatures in the Labrador Sea would allow active water mass mixing with more radiogenic ɛNd values (−12.6 and −14) prevailing in its eastern part whereas less radiogenic values (ɛNd ∼ −18.4) were found on the western Labrador slope. The deposition of detrital carbonates during Heinrich stadials (2,1) was accompanied by negative detrital and authigenic Nd isotope excursions (ɛNd ∼ −31) that were likely controlled by dissolution of dolostone or dolostone associated mineral inclusions. This highly unradiogenic signal dominated the authigenic phases and individual water masses in the Labrador Sea, serving as potential source of highly unradiogenic Nd to the North Atlantic region, while exported southward. The Holocene authigenic ɛNd signatures of the coatings and leachates significantly differed from those of the detrital silicates, approaching modern bottom water mass signatures during the Late Holocene.

Description: Plain Language Summary: The Labrador Sea is an important region for deep water formation and for the ocean circulation in the Atlantic region. Over the last 32 thousand years, numerous discharges from melting glaciers added freshwater to the Labrador Sea which could help understand the future effects of current melting glaciers. This information is necessary to better constrain climate predictions in order to gauge the effects on the Global Ocean Water Circulation. However, past deep water production in the Labrador is still poorly constrained, complicating reconstruction of the Atlantic Meridional Overturning Circulation on different timescales. In this study we investigated changes in deep and intermediate water mass circulation patterns over the last 32 kyr based on the radiogenic Nd isotope compositions that serve as a water mass circulation proxy. Analysis of four marine sediment cores show that the deposition of large volumes of detrital carbonates during studied period had a large effect on the recorded in the sediment column signals. New data suggest active water mass circulation during the maximum extent of glacial ice sheets. The modern day ocean circulation patterns have emerged during the Late Holocene (6 ka).

Description: Key Points: Estimation of Nd release via dissolution of detrital carbonates and its contribution to the authigenic ԑNd signatures in the Labrador Sea. Dissolution of detrital dolostones in the water column during Heinrich stadials at least partially controlled ɛNd signatures. During the LGM generally more radiogenic signatures possibly indicate active water mass advection and mixing in the Labrador Sea.

Description: GEOMAR Helmholtz‐Zentrum für Ozeanforschung Kiel http://dx.doi.org/10.13039/501100003153

Description: Kiel University

Description: https://doi.org/10.1594/PANGAEA.952659

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Aquatic ecosystems play an important role in global methane cycling and many field studies have reported methane supersaturation in the oxic surface mixed layer (SML) of the ocean and in the epilimnion of lakes. The origin of methane formed under oxic condition is hotly debated and several pathways have recently been offered to explain the “methane paradox.” In this context, stable isotope measurements have been applied to constrain methane sources in supersaturated oxygenated waters. Here we present stable carbon isotope signatures for six widespread marine phytoplankton species, three haptophyte algae and three cyanobacteria, incubated under laboratory conditions. The observed isotopic patterns implicate that methane formed by phytoplankton might be clearly distinguished from methane produced by methanogenic archaea. Comparing results from phytoplankton experiments with isotopic data from field measurements, suggests that algal and cyanobacterial populations may contribute substantially to methane formation observed in the SML of oceans and lakes.〈/p〉

Description: Plain Language Summary: Methane plays an important role in atmospheric chemistry and physics as it contributes to global warming and to the destruction of ozone in the stratosphere. Knowing the sources and sinks of methane in the environment is a prerequisite for understanding the global atmospheric methane cycle but also to better predict future climate change. Measurements of the stable carbon isotope composition of carbon—the ratio between the heavy and light stable isotope of carbon—help to identify methane sources in the environment and to distinguish them from other formation processes. We identified the carbon isotope fingerprint of methane released from phytoplankton including algal and cyanobacterial species. The observed isotope signature improves our understanding of methane cycling in the surface layers of aquatic environments helping us to better estimate methane emissions to the atmosphere.〈/p〉

Description: Key Points: Stable carbon isotope values of methane emitted from six phytoplankton cultures incubated in the laboratory. Isotope fractionation between methane source signature and biomass of widespread algal and cyanobacterial species. Isotopic patterns of methane released by phytoplankton may be clearly distinguished from methane formed by methanogenic archaea.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Spanish Ministry of Universities

Description: https://doi.org/10.11588/data/YYLEKU

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉

Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉

Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉

Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977

Description: Minerva PhD Fellowship Stipend

Description: Advance School for Environmental Studies

Description: https://doi.org/10.1594/PANGAEA.959629

Description: https://doi.org/10.17617/3.EXFQC2

Description: Ocean island basalts (OIB) show variable 〈sup〉182〈/sup〉W deficits that have been attributed to either early differentiation of the mantle or core‐mantle interaction. However, 〈sup〉182〈/sup〉W variations may also reflect nucleosynthetic isotope heterogeneity inherited from Earth's building material, which would be evident from correlated 〈sup〉182〈/sup〉W and 〈sup〉183〈/sup〉W anomalies. Some datasets for OIB indeed show hints for such correlated variations, meaning that a nucleosynthetic origin of W isotope anomalies in OIB cannot be excluded. We report high‐precision W isotope data for OIB from Samoa and Hawaii, which confirm previously reported 〈sup〉182〈/sup〉W deficits for these samples, but also demonstrate that none of these samples have resolvable 〈sup〉183〈/sup〉W anomalies. These data therefore rule out a nucleosynthetic origin of the 〈sup〉182〈/sup〉W deficits in OIB, which most likely reflect the entrainment of either core material or an overabundance of late‐accreted materials within OIB mantle sources. If these processes occurred over Earth's history, they may have also been responsible for shifting the 〈sup〉182〈/sup〉W composition of the bulk mantle to its modern‐day value. We also report Mo isotope data for some Hawaiian OIB, which reveal no resolved nucleosynthetic Mo isotopic anomalies. This is consistent with inheritance of 〈sup〉182〈/sup〉W deficits in OIB from the addition of either core or late‐accreted material, but only if these materials have a non‐carbonaceous (NC) meteorite‐like heritage. As such, these data rule out significant contributions of carbonaceous chondrite (CC)‐like materials to either Earth's core or late accretion.

Description: Plain Language Summary: Some ocean island basalts (OIB) may contain a record of processes and characteristics of the deepest parts of Earth's mantle, including at the boundary between the iron‐rich core and mantle. Like some prior studies, we measured tungsten isotopes within OIB from Hawaii and Samoa, and report that tungsten isotopes in these OIB differ in their characteristics compared to what is observed in modern rocks that are most representative of the upper part of Earth's mantle. One explanation for these tungsten isotope anomalies is that they are a signature of chemical interaction between the core and lower mantle, suggesting that the core 'leaks' into the lower mantle. Another possibility proposed here is that these tungsten isotope anomalies reflect ancient crust that contained dense, meteorite‐like materials, which sank to the bottom of the mantle during Earth's early history. Using isotopes of another element, molybdenum, we show that the source(s) of these tungsten isotope anomalies do not contain a significant number of materials that originated from the outer Solar System before being added to Earth during its formation.

Description: Key Points: 〈sup〉182〈/sup〉W deficits in ocean island basalts are confirmed, but correlated 〈sup〉182〈/sup〉W–〈sup〉183〈/sup〉W anomalies present in prior datasets are not confirmed. 〈sup〉182〈/sup〉W deficits may reflect core‐mantle interaction or an overabundance of late‐accreted materials, but not nucleosynthetic effects. Mo isotope data similar to BSE estimate; W‐Mo data rule out significant contribution of CC‐like material to Earth's core or late accretion.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.35003/YCUKOX

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Mass‐dependent Mo isotope variations are a promising new tracer to study magmatic processes in different geological settings. We report the first Mo isotope data for the Kamchatka arc system in the Northwest Pacific, comprising basaltic lavas of a complete Southeast‐Northwest traverse from the volcanic arc front through to the back arc region. The majority of volcanic centers investigated directly override the Hawaii‐Emperor Seamount Chain, which is currently being subducted underneath the arc system. Our Mo isotope data show systematic trends with Ce/Pb, Ce/Mo, Nb/Zr, La/Sm, and 〈sup〉143〈/sup〉Nd/〈sup〉144〈/sup〉Nd ratios from the volcanic arc front to the back arc. Arc front lavas have higher δ〈sup〉98/95〈/sup〉Mo and lower Ce/Pb, Ce/Mo, Nb/Zr, La/Sm compared to back arc lavas. Because the involvement of subducted sediments can be excluded, we attribute the observed variations to a change in the mantle source composition from the arc front to the back arc regions. The isotopic and chemical budget of arc front lavas is dominated by a slab fluid component (high δ〈sup〉98/95〈/sup〉Mo, low Ce/Pb, Ce/Mo), whereas mantle‐like Ce/Pb, Ce/Mo, elevated Nb/Zr and La/Sm in the back arc samples suggest an enriched mantle source. Combined δ〈sup〉98/95〈/sup〉Mo, Nd, and Pb isotope data in back arc lavas are very similar to those observed for modern ocean island basalts from Hawaii. We thus explore the possibility that the back arc mantle was contaminated by a Hawaii‐type, enriched asthenospheric mantle component from the subducted Hawaii‐Emperor Seamount Chain.〈/p〉

Description: Plain Language Summary: In subduction zones, tectonic plates—tens of kilometers thick and making up the outer shell of our planet—are on a collision course. Although the absolute convergence rates of these plates are minute (a few cm/year), the forces in this process are so large that one plate is pushed under the other, causing the lower plate to be recycled into the Earth's mantle over time scales of millions of years. The tangible consequences are high‐magnitude earthquakes and large‐volume volcanic eruptions along these convergent plate margins. It is thus important to better understand the geological processes that operate in subduction zones. Here, we have studied the chemical and isotopic composition of volcanic rocks from the Kamchatka subduction zone. Our results confirm that water, locked into the subducting plate while residing on the surface, is released into the hot, overlying mantle after subduction, causing the formation of large volumes of magma that eventually erupt in volcanoes on the Kamchatka Peninsula. Our data also indicate that the subducting plate, once pushed into the mantle, is being ripped apart, allowing buoyant mantle material from greater depth to rise and contribute to the large‐scale volcanism observed along this convergent plate margin.〈/p〉

Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Molybdenum isotope systematics in arc basalts from Kamchatka are consistent with presence of a slab‐derived fluid in their mantle source〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Back arc basalts also show contribution from a geochemically enriched source〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Combined Mo, Nd, and Pb isotope and trace element data for back arc basalts suggest involvement of Hawaii‐type asthenospheric mantle〈/p〉〈/list-item〉 〈/list〉 〈/p〉

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.25625/P5BBFL

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The sampling of fluvial sediment is subject to many sources of uncertainty, for example, time and location, and the number of samples collected. It is nevertheless commonly assumed that a sample taken at one time and location provides a somewhat averaged compositional signal. Any spatial or temporal variability of this signal is often neglected. This study investigates how the composition of bed load sand changes over an observation period of 1 year in four river basins with differing bedrock geology in southwestern Germany. Up to 12 bulk sediment samples were taken at the same locations using the same approach and analyzed for their granulometry and geochemistry. The results indicate that (a) different grain sizes yield different compositions due to source rock composition and hydraulic sorting effects, (b) bulk sediment composition changes temporally due to changing grain‐size distribution, and (c) compared to the bulk sample, the composition of narrow grain sizes is temporally more stable but nevertheless has an average variability of 15%. Because heavy mineral‐bound elements such as Zr have the highest variability, we relate a major component of compositional variability to temporally varying heavy mineral concentrations in response to hydrodynamic processes. Mixing modeling demonstrates that the fluvial sand faithfully reflects its catchment geology and that the sediment sources do not change substantially during the observation period, even during a flooding event. We conclude (a) that the causes for compositional variability may be disentangled using chemical and granulometric time series data and (b) that narrow grain sizes yield representative source rock contributions.〈/p〉

Description: Plain Language Summary: Sediment transported by rivers is generated by the erosion of the rocks present within the river catchment area. The composition of this sediment is controlled by various processes in the catchment, for example, climate, rock type, weathering, and flow strength. Geoscientists can use modern river sediment to understand how these processes impact sediment composition, and then apply this information to the geologic time. Sampling the river sediment is often the first step in such studies, but few studies consider the sources of uncertainty during sampling, for example, time and location of sampling, and number of collected samples. For this study, we returned to the same river location during the course of 1 year to take bulk sediment samples and analyzed how variable the size of sediment grains and the sediment chemistry are. We discovered that different grain sizes yield different chemical compositions, and this is caused by differences in rock type and hydraulic processes. Because the proportion of different grain sizes in the bulk sediment changes over the year due to water flow conditions, the chemistry of the bulk sediment sample changes over the year. We provide some quantitative estimates for this variability that should be considered in similar studies.〈/p〉

Description: Key Points: Bed load sand from 4 rivers was sampled monthly over the course of 1 year to analyze the temporal compositional variability. Composition is grain‐size‐dependent, and narrow grain‐size fractions show less variability than bulk sediment samples. Composition changes during the year, and this is related to changing grain‐size distributions rather than changing sediment sources.

Description: https://doi.pangaea.de/10.1594/PANGAEA.959006

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Due to the inherently fluid‐mobile nature of W, the 〈sup〉182〈/sup〉W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 〈sup〉182〈/sup〉W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th 〈 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 〈sup〉182〈/sup〉W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ〈sup〉182〈/sup〉W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 〈sup〉182〈/sup〉W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton.〈/p〉

Description: Plain Language Summary: The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities.〈/p〉

Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomalies〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Negative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoids〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Felsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone units〈/p〉〈/list-item〉 〈/list〉 〈/p〉

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.5880/digis.2023.005

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Hydrochemical data of karst springs provide valuable insights into the internal hydrodynamical functioning of karst systems and support model structure identification. However, the collection of high‐frequency time series of major solute species is limited by analysis costs. In this study, we develop a method to retrieve the individual solute concentration time series and their uncertainty at high temporal resolution for karst springs by using continuous observations of electrical conductivity (EC) and low‐frequency ionic measurements. Due to the large ion content and non‐negligible concentrations of aqueous complexes in karst systems, the concentration of each solute species occurring as free ion and as part of aqueous complexes are computed separately. The concentration of species occurring as free ions are computed considering their contributions to the total EC, whereas the concentration of the species as part of complexes are obtained from speciation calculations. The pivotal role of the complexation processes for the reconstruction of solute concentration time series starting from the EC signal is investigated in two karstic catchments with different geologies and temporal resolution of the available hydrochemical datasets, that is the Kerschbaum dolostone system in Austria and the Baget limestone system in France. The results show that complexation processes are significant and should be considered for the estimation of the total solute concentration in case of SO〈sub〉4〈/sub〉, Ca, Mg and HCO〈sub〉3〈/sub〉. The EC signal of a karst spring can be used to interpolate and quantify the dynamics of those solutes characterized by large contribution (approximately >6%) to the total EC and low relative variability, that is HCO〈sub〉3〈/sub〉, Ca and Mg. Moreover, the presented method can be used to estimate concentrations of solutes when applied to karst systems with stationary and hydrogeochemical homogeneous contributing area. On the contrary, the method is affected by large uncertainty in case of dynamic systems characterized by varying contributions of water from different geological areas. This study aims to contribute to the problem of hydrogeochemical data availability and to support future works on karst systems conceptualization.〈/p〉

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: École Polytechnique Fédérale de Lausanne http://dx.doi.org/10.13039/501100001703

Description: European Regional Development Fund http://dx.doi.org/10.13039/501100008530

Description: http://www.hydroshare.org/resource/fb92daaffced415fb7a991747e73adfa

Description: Fe(III) hydroxides stabilize organic carbon (OC) and P in soils. Observations of rising stream Fe concentrations are controversially posited to result from a flushing of iron‐rich deeper soil layers or a decrease of competing electron acceptors inhibiting Fe reduction (NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and SO42− $\mathrm{S}{{\mathrm{O}}_{4}}^{2-}$). Here, we argue that catchment topography constrains the release of Fe, OC, and P to streams. We therefore incubated organic topsoil and mineral subsoil and modified the availability of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$. We found that Fe leaching was highest in topsoil. Fe, OC, and P released at quantities proportional to their ratios in the source soil. Supply of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ reduced Fe leaching to 18% and increased pore water OC:Fe and P:Fe ratios. Subsoil, however, was an insignificant Fe source (〈0.5%). Here, the leached quantities of Fe, OC and P were highly disproportionate to the soil source with an excess of released OC and P. We tested if experimental findings scale up using data from 88 German catchments representing gradients in NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ concentration and topography. Average stream Fe concentrations increased with decreasing NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and were high in catchments with shallow topography where high groundwater levels support reductive processes and topsoils are hydrologically connected to streams; but Fe concentrations were low in catchments with steep topography where flow occurs primarily through subsoils. OC:Fe and P:Fe ratios in the streams similarly varied by NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and topography. This corroborates the findings from the laboratory experiment and suggests that catchment topography and competing electron acceptors constrain the formation of Fe‐reducing conditions and control the release of Fe, OC, and P to streams.

Description: Plain Language Summary: Iron is the second most abundant metal in the crust; its cycle is tightly connected to those of carbon, oxygen, and sulfur. The oxidized form (FeIII) is almost insoluble, but Fe can be mobilized by complexation or microbial Fe reduction. Both processes depend on availability of organic C. We found that Fe concentrations in streams were constrained by the topography of catchments and NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ abundance. Shallower catchments are characterized by higher groundwater tables connecting the organic topsoils efficiently to streams. NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ suppresses Fe reduction as a competing electron acceptor to Fe. We conclude that trends in soil wetness or atmospheric N deposition can change the stability of Fe and thus the release of PO43− $\mathrm{P}{{\mathrm{O}}_{4}}^{3-}$ and harmful metals to surface waters.

Description: Key Points: Organic topsoils leach substantial amounts of Fe when incubated in the absence of NO3, a competing electron acceptor that inhibits Fe reduction. Shallow catchments with fluvially coupled topsoils and low NO3 availability release 200 fold more Fe than steep ones with high NO3 abundance. Catchment topography and NO3 availability explain 62%–64% of the variability of Fe concentration and OC:Fe and P:Fe ratios across 88 streams.

Description: EFRE‐Europe

Description: https://doi.org/10.4211/hs.43601618877945c5a46b715aa98db729

Description: Radiocarbon (14C) is commonly used as a tracer of the carbon cycle to determine how fast carbon moves between different reservoirs such as plants, soils, rivers, or oceans. However such studies mostly emphasize the mean value (as Δ14C) of an unknown probability distribution. We introduce a novel algorithm to compute Δ14C distributions from knowledge of the age distribution of carbon in linear compartmental systems at steady‐state. Our results demonstrate that the shape of the distributions might differ according to the speed of cycling of ecosystem compartments and their connectivity within the system, and might contain multiple peaks and long tails. The distributions are also sensitive to the variations of Δ14C in the atmosphere over time, as influenced by the counteracting anthropogenic effects of fossil‐fuel emissions (14C‐free) and nuclear weapons testing (excess 14C). Lastly, we discuss insights that such distributions can offer for sampling and design of experiments aiming to capture the precise variance of Δ14C values present in the multi‐compartmental ecosystems.

Description: Plain Language Summary: Radiocarbon (14C) is a radioactive isotope of carbon prominent in environmental sciences for tracing the dynamics of ecosystems, especially as recent changes in atmospheric radiocarbon allow tracking excess 14C created by nuclear weapons testing in the atmosphere on timescales shorter than what can be determined using radioactive decay. For climate change mitigation, a crucial uncertainty is the time carbon captured through photosynthesis spends in ecosystems before being released. For this purpose, radiocarbon can be valuable as a biological tracer; however, it is necessary to accurately link the real age of carbon and its radiocarbon age, as they usually differ. Forests and soils are open systems, connecting components with intrinsically different cycling timescales, so that the mean age comes from an age distribution that is usually unknown. Here, we developed an algorithm to compute the 14C contents for models consisting of multiple interconnected carbon pools. Our approach offers more accurate estimations of the mean 14C content of the system and computations of the distribution of 14C within the system at different points in time. Results obtained from this method can provide additional insights on the dynamics of the carbon cycle in multiple compartments, and can help to better interpret observations.

Description: Key Points: Probability distributions of radiocarbon in ecosystem compartments can be derived from carbon age distributions. The shape of these distributions vary according to the speed of carbon cycling and the year of observation. Probability distributions of radiocarbon provide insights to study carbon dynamics and to interpret radiocarbon data.

Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347

Description: Max‐Planck‐Gesellschaft (MPG) http://dx.doi.org/10.13039/501100004189

Description: https://doi.org/10.5281/zenodo.6373329

Description: Four zircon Raman bands were previously calibrated to give consistent estimates of the accumulated self‐irradiation α‐dose in unannealed volcanic samples. Partial annealing of radiation damage produces inconsistent values because of differences in the relative annealing sensitivities. The damage estimates based on the external rotation band (DER) at ∼356 cm−1 and that based on the ν2(SiO4) band (D2) at ∼438 cm−1 are the most and least sensitive to damage annealing. The D2/DER‐ratio thus provides a numerical estimate of the extent of geologic annealing that a zircon sample has experienced. This ratio characterizes the thermal history of a zircon sample but also its state of radiation damage during the course of its geologic history, and thus the manner in which this state influences other thermochronologic methods. Meaningful interpretation of the zircon Raman age requires that the spectra are free of measurement artifacts. The major artifacts result from micrometer‐scale gradients of the damage densities within a zircon grain due to uranium and thorium zoning. The micrometer‐sized sampled volume may span different densities, producing overlapping spectra, causing apparent peak broadening, overestimated damage densities, and zircon Raman ages. The D3/D2‐ratio of the damage densities calculated from the ν3(SiO4) and ν2(SiO4) bands, most and least affected by overlap, is an efficient indicator of a meaningless signal. It reveals overlap in annealed and unannealed samples, because the used bands have similar responses to annealing. Multi‐band Raman maps can be converted to damage‐ratio maps for screening zircon mounts, and selecting spots for thermochronologic investigations.

Description: Plain Language Summary: Radioactive processes cause damage to the lattice of zircon crystals. This damage can be measured with a Raman instrument. Such measurements are important for methods determining the ages and thermal histories of zircon grains in rocks. Thus, the Raman measurements must be reliable and meaningful. This work proposes tools for detecting effects that hinder the interpretation of zircon Raman data. These effects are mixed signals and loss of damage due to exposure to elevated temperatures in the geologic environment. Zircon Raman spectra have different bands that respond differently to mixed signals and temperature. The ratio of the damage estimates from the least and most temperature‐sensitive bands thus indicates partial annealing. Raman spectra of zoned zircons often straddle areas with different lattice damage. Their overlapping signals cause artificial band broadening, and a damage overestimation. The ratio of the damage estimated from the least and the most affected bands identifies mixed signals and allows to reject unsuitable samples. The damage ratios can also be plotted in maps for damage screening and for selecting optimal spots for measurements.

Description: Key Points: Annealing and inhomogeneous damage are two main factors hindering radiation‐damage estimation for zircon Raman dating. Comparison of internal and external Raman bandwidths allows to detect partial annealing of radiation damage in zircon. Comparison of internal Raman bandwidths allows to detect artifactual broadening in zoned zircon.

Description: Studienstiftung des Deutschen Volkes (Studienstiftung) http://dx.doi.org/10.13039/501100004350

Description: http://dx.doi.org/10.25532/OPARA-155

Description: Methane production in peatlands is controlled by the availability of electron acceptors for microbial respiration, including peat dissolved organic matter (DOM) and particulate organic matter (POM). Despite the much larger mass of POM in peat, knowledge on the ranges of its electron transfer capacities—electron accepting capacity (EAC), and electron donating capacity (EDC)—is scarce in comparison to DOM and humic and fulvic acids. Moreover, it is unclear how peat POM chemistry and decomposition relate to its EAC and EDC. To address these knowledge gaps, we compiled peat samples with varying carbon contents from mid to high latitude peatlands and analyzed their EACPOM and EDCPOM, element ratios, decomposition indicators, and relative amounts of molecular structures as derived from mid infrared spectra. Peat EACPOM and EDCPOM are smaller (per gram carbon) than EAC and EDC of DOM and terrestrial and aquatic humic and fulvic acids and are highly variable within and between sites. Both are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. Element ratio‐based models failed to predict EACPOM and EDCPOM, while mid infrared spectra‐based models can predict peat EACPOM to a large extent, but not EDCPOM. We suggest a conceptual model that describes how vegetation chemistry and decomposition control polymeric phenol and quinone contents as drivers of peat EDCPOM and EACPOM. The conceptual model implies that we need mechanistic models or spatially resolved measurements to understand the variability in peat EDCPOM and EACPOM and thus its role in controlling methane formation.

Description: Plain Language Summary: Peatlands accumulated large amounts of carbon via photosynthesis and slow decomposition of senesced plant material. Microorganisms within the peat form methane. For this reason, peatlands are important global sources of the greenhouse gas methane and therefore can contribute to climate change. In order to produce methane, the microorganisms have to transfer electrons between compounds in respiration processes. Only recently, it has been found that the peat itself can reversibly transfer electrons and that its capacities to reversibly accept electron accepting capacity (EAC) and reversibly donate electron donating capacity (EDC) electrons are large. We investigated which conditions favor large or small EAC and EDC of peat so that we can better explain methane formation. We argue that vegetation and decomposition control the amount of phenols and quinones—molecules in the peat that presumably are responsible for most of the peat's EAC and EDC. The EAC and EDC probably are largest for peat formed from vegetation rich in quinones and phenols, such as shrubs, and smaller for other vegetation types, for example, certain mosses. Intense decomposition may reduce both the EAC and EDC.

Description: Key Points: Peat particulate organic matter electron accepting and donating capacities per grams of carbon are smaller than for humic and fulvic acids. Both capacities are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. We explain these patterns with parent vegetation chemistry and conditions during decomposition.

Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659

Description: CAS | Youth Innovation Promotion Association (YIPA) http://dx.doi.org/10.13039/501100012492

Description: https://github.com/henningte/redoxpeat

Description: We developed a numerical thermodynamics laboratory called “Thermolab” to study the effects of the thermodynamic behavior of nonideal solution models on reactive transport processes in open systems. The equations of the state of internally consistent thermodynamic data sets are implemented in MATLAB functions and form the basis for calculating Gibbs energy. A linear algebraic approach is used in Thermolab to compute Gibbs energy of mixing for multicomponent phases to study the impact of the nonideality of solution models on transport processes. The Gibbs energies are benchmarked with experimental data, phase diagrams, and other thermodynamic software. Constrained Gibbs minimization is exemplified with MATLAB codes and iterative refinement of composition of mixtures may be used to increase precision and accuracy. All needed transport variables such as densities, phase compositions, and chemical potentials are obtained from Gibbs energy of the stable phases after the minimization in Thermolab. We demonstrate the use of precomputed local equilibrium data obtained with Thermolab in reactive transport models. In reactive fluid flow the shape and the velocity of the reaction front vary depending on the nonlinearity of the partitioning of a component in fluid and solid. We argue that nonideality of solution models has to be taken into account and further explored in reactive transport models. Thermolab Gibbs energies can be used in Cahn‐Hilliard models for nonlinear diffusion and phase growth. This presents a transient process toward equilibrium and avoids computational problems arising during precomputing of equilibrium data.

Description: Plain Language Summary: The behavior of Earth materials, rocks, minerals, melts, fluids, and gases is important to predict physical processes in the Earth with computer models. The purpose of this is to study how the changes of variables such as fluid and solid composition influence the diffusion, fluid flow, and reaction in rocks. Here, we present a set of computer codes, called Thermolab, to calculate important physical properties such as density and chemical composition of solids, fluids, and melts in chemical equilibrium. The calculations are based on the Gibbs energy that exists for every material. We use computer codes, written in MATLAB/OCTAVE language, to show how this Gibbs energy is calculated and used to compute chemical equilibrium and find the physical properties such as density and chemical composition. We discuss techniques for accurate calculation of chemical equilibrium and physical properties in real rocks. Finally, we use Thermolab to formulate a computer model of fluids reacting with rocks. We find that chemical composition of the fluid and rock strongly affects the speed and shape of the boundary between reacted and unreacted rock. Thermolab can be used in phase growth models to investigate the way in which rocks develop toward equilibrium.

Description: Key Points: Thermolab: a set of MATLAB codes is presented to perform equilibrium and nonequilibrium thermodynamic calculations. Local thermodynamic equilibrium is used to study effects of nonideality of solution models on nonlinear transport processes. Nonlinear diffusion processes are investigated with Thermolab providing a transient natural physical process toward equilibrium.

Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659

Description: Russian Ministry of Science and Higher Education

Description: https://hansjcv.github.io/Thermolab/

Description: https://doi.org/10.5281/zenodo.6383253

Description: Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches.

Description: Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes.

Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347

Description: Swedish Research Concil

Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318

Description: https://doi.org/10.1594/PANGAEA.871273

Description: https://www.ncdc.noaa.gov/paleo-search/study/31772

Description: https://doi.org/10.1594/PANGAEA.914500

Description: https://www.iceandclimate.nbi.ku.dk/data/

Description: https://doi.org/10.1594/PANGAEA.932965

Description: The compound‐specific hydrogen isotopic composition (δ2H) of n‐alkanes is a valuable proxy to investigate hydrological conditions in lake sediments. While terrestrial n‐alkanes reflect the isotopic signal of the local precipitation, aquatic n‐alkanes incorporate the isotopic signal of the lake's water, which can be strongly modulated by evaporative enrichment. So far, the spatial distribution of the terrestrial and aquatic δ2H signal within lakes have not systematically been investigated. Here, we present compound‐specific δ2H results of terrestrial (δ2HC31) and aquatic (δ2HC23) n‐alkanes of surface sediment samples from Lake Khar Nuur, a semi‐arid and high‐altitude lake in the Mongolian Altai, and additionally investigate the δ2H signal of topsoils from the catchment. Our results show that the majority of the n‐alkane δ2H values from the catchment topsoils correspond well with modeled local growing season precipitation (JJAS). However, few samples in the northern catchment show more positive δ2H values possibly due to increased evapo(transpi)ration by southward exposition and shallower soils there. The only small variability of δ2HC31 in the surface sediments is in the range of most topsoils δ2H from the catchment, and thus, well reflects local growing season precipitation. δ2HC23 in surface sediment samples from the central and deepest parts of the lake, that is, the lake's sediment accumulation zones, shows distinctly more positive δ2HC23 values due to evaporative lake water enrichment. Consequently, Δaq‐terr, which is the isotopic offset between δ2HC23 and δ2HC31, indicates distinct lake water enrichment in the lake's accumulation zones and is a valuable proxy to investigate past hydrological changes.

Description: Key Points: The hydrogen isotopic composition of terrestrial C31 n‐alkanes reflects the local growing season precipitation at Lake Khar Nuur. Aquatic C23 n‐alkanes incorporate the isotopic signal of the lake's water, which is strongly modulated by evaporative enrichment. The isotopic offset between C23 and C31 is a valuable proxy for evaporation in the lake and past hydrological changes in the catchment.

Description: https://doi.pangaea.de/10.1594/PANGAEA.940115

Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: CONACYT‐FONCICYT‐DADC

Description: https://doi.org/10.11588/data/TMYLWS

Description: https://doi.org/10.11588/data/GYLDH5

Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image

Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).

Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.

Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912

Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.

Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.

Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347

Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.

Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.

Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246

Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106

Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.

Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.

Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.

Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207

Description: https://doi.org/10.1594/PANGAEA.942455

Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.

Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.

Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.

Description: German Research Foundation

Description: Netherlands Organization for Scientific Research

Description: https://doi.pangaea.de/10.1594/PANGAEA.859558

Description: https://doi.pangaea.de/10.1594/PANGAEA.871030

Description: https://doi.pangaea.de/10.1594/PANGAEA.868396

Description: https://doi.pangaea.de/10.1594/PANGAEA.905347

Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc

Description: https://doi.pangaea.de/10.1594/PANGAEA.933431

Description: https://www.bco-dmo.org/dataset/718440

Description: https://doi.org/10.1594/PANGAEA.936029

Description: https://doi.org/10.1594/PANGAEA.936027

Description: https://doi.pangaea.de/10.1594/PANGAEA.927429

Description: Iron(II) (Fe(II)) can be formed by abiotic Fe(III) photoreduction, particularly when Fe(III) is organically complexed. Light‐influenced environments often overlap or even coincide with oxic or microoxic geochemical conditions, for example, in sediments. So far, it is unknown whether microaerophilic Fe(II)‐oxidizing bacteria are able to use the Fe(II) produced by Fe(III) photoreduction as electron donor. Here, we present an adaption of the established agar‐stabilized gradient tube approach in comparison with liquid cultures for the cultivation of microaerophilic Fe(II)‐oxidizing microorganisms by using a ferrihydrite‐citrate mixture undergoing Fe(III) photoreduction as Fe(II) source. We quantified oxygen and Fe(II) gradients with amperometric and voltammetric microelectrodes and evaluated microbial growth by qPCR of 16S rRNA genes. We showed that gradients of dissolved Fe(II) (maximum Fe(II) concentration of 1.25 mM) formed in the gradient tubes when incubated in blue or UV light (400–530 nm or 350–400 nm). Various microaerophilic Fe(II)‐oxidizing bacteria (Curvibacter sp. and Gallionella sp.) grew by oxidizing Fe(II) that was produced in situ by Fe(III) photoreduction. Best growth for these species, based on highest gene copy numbers, was observed in incubations using UV light in both liquid culture and gradient tubes containing 8 mM ferrihydrite‐citrate mixtures (1:1), due to continuous light‐induced Fe(II) formation. Microaerophilic Fe(II)‐oxidizing bacteria contributed up to 40% to the overall Fe(II) oxidation within 24 h of incubation in UV light. Our results highlight the potential importance of Fe(III) photoreduction as a source of Fe(II) for Fe(II)‐oxidizing bacteria by providing Fe(II) in illuminated environments, even under microoxic conditions.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Ministerium für Wissenschaft, Forschung und Kunst Baden‐Württemberg http://dx.doi.org/10.13039/501100003542

Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347

Description: Biological nitrogen fixation is an important oceanic nitrogen source, potentially stabilizing marine fertility in an increasingly stratified and nutrient‐depleted ocean. Iron limitation of low latitude primary producers has been previously demonstrated to affect simulated regional ecosystem responses to climate warming or nitrogen cycle perturbation. Here we use three biogeochemical models that vary in their representation of the iron cycle to estimate change in the marine nitrogen cycle under a high CO2 emissions future scenario (RCP8.5). The first model neglects explicit iron effects on biology (NoFe), the second utilizes prescribed, seasonally cyclic iron concentrations and associated limitation factors (FeMask), and the third contains a fully dynamic iron cycle (FeDyn). Models were calibrated using observed fields to produce near‐equivalent nutrient and oxygen fits, with productivity ranging from 49 to 75 Pg C yr−1. Global marine nitrogen fixation increases by 71.1% with respect to the preindustrial value by the year 2100 in NoFe, while it remains stable (0.7% decrease in FeMask and 0.3% increase in FeDyn) in explicit iron models. The mitigation of global nitrogen fixation trend in the models that include a representation of iron originates in the Eastern boundary upwelling zones, where the bottom‐up control of iron limitation reduces export production with warming, which shrinks the oxygen deficient volume, and reduces denitrification. Warming‐induced trends in the oxygen deficient volume in the upwelling zones have a cascading effect on the global nitrogen cycle, just as they have previously been shown to affect tropical net primary production.

Description: Plain Language Summary: Phytoplankton need nutrients to grow. Two of those nutrients are nitrogen and iron. Climate change projections suggest that in the future there could be less nitrogen supplied to the surface ocean, which might reduce phytoplankton growth. Less phytoplankton growth could impact a wide range of ocean services, like fishing and fossil carbon draw‐down. However, some phytoplankton have the ability to add “new” nitrogen to the surface ocean directly from the atmosphere. In this study, we explore how this biological fixation of new nitrogen might change into the future using three models. These models differ in how iron is represented, but all do equally well in representing the observed nutrient and oxygen distribution. Biological nitrogen fixation slightly decreases with climate change in the very complex iron model and the moderately complex iron model, but it increases strongly (by more than 70% by the year 2100) in the model that does not include iron effects on biology. Our study addresses the importance of iron models and how they can change our view of how the ocean responds to climate change.

Description: Key Points: Models performing similarly with respect to global NO3, PO4, and O2 distributions yield diverse responses in marine N2 fixation to warming. Marine N2 fixation trends are sensitive to whether iron limits primary production in upwelling regions, for example, the Eastern Tropical Pacific.

Description: Helmholtz Research School for Ocean System Science and Technology

Description: New Zealand Ministry of Business, Innovation and Employment

Description: https://data.geomar.de/downloads/20.500.12085/673e7de0-20ab-4dd3-afe9-c4bfb00b1faf/

Description: Relationships between vegetation and air quality are intricate and still not fully understood. For regional air quality assessments, a better understanding of the diverse feedback mechanisms is crucial. The present article investigates the impact of land use data set detailedness on air quality predictions. Therefore, two different land use data sets were applied for simulations with COSMO‐MUSCAT for Germany in May 2014. One data set includes detailed information about tree species while the second one obtains generalized widely applied land use classes including mixed and coniferous forests. Moreover, we examined the role of agricultural NO soil emissions, agricultural biomass density enhancements, and model resolution. For a more comprehensive implementation of the secondary organic aerosol (SOA) formation, the SOA module was extended considering additional biogenic volatile organic compound (BVOC) precursor groups from isoprene, α‐pinene, limonene, and sesquiterpene oxidations. The model studies showed substantial differences in BVOC emission patterns between the two land use data sets. The application of detailed tree species information leads to complex BVOC emission patterns with high emission spots. In contrast, coarser forest information lead to standardized comprehensive emissions which result in 50% higher BVOC emissions. These differences affect both the atmospheric oxidizing potential and the production rates of SOA precursors. Land use induced regional differences (tree species minus forest information) in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%) concentrations, and SOA (−60%) mass are modeled. Overall, the simulations demonstrate that detailed land use information, extended organic chemistry treatment, and high spatial resolution are mandatory for air quality assessments.

Description: Plain Language Summary: Trees are associated with being the lungs of the atmosphere as they filter out harmful substances from the air, they store CO2, and produce oxygen via photosynthesis. Other by‐products of photosynthesis are biogenic volatile organic compounds (BVOCs). BVOCs are chemical substances with a high vapor pressure already at room temperatures, so they quickly evaporate from the leaves into the surrounding air and are responsible for the characteristic forest smell. The amount and composition of BVOC emissions strongly depend on the tree species. Every plant has its own distinct emission properties. The chemical degradation of BVOCs impacts the chemical composition of the troposphere and is connected to ground level ozone production and the formation of secondary organic aerosols (SOA), contributing substantially to particulate matter (PM). On a global scale, standardized BVOC emission information on forest levels are often used, but for regional air quality assessments detailed plant specific information is crucial, but still often lacking. Therefore, two different land use data sets were applied in the present study to investigate the impact of standardized forest versus detailed tree‐species information for Germany in May 2014. The study reveals changes in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%), and SOA (−60%) concentrations.

Description: Key Points: Detail of land use data sets crucial for biogenic volatile organic compound emission strength and composition. Composition and concentration variation of these organic compounds induce changes in regional air quality predictions. Detailed land use information, extended organic matter treatment, and high‐resolution simulations are mandatory for air quality assessments.

Description: Deutsche Bundesstiftung Umwelt (DBU) http://dx.doi.org/10.13039/100007636

Description: https://doi.org/10.5281/zenodo.4783106

Description: http://ebas.nilu.no/

Description: Abundant volcanic activity occurs in the back‐arc region of the northern Tofua island arc where the Northeast Lau Spreading Center (NELSC) propagates southwards into older crust causing the formation of numerous seamounts at the propagating rift tip. An off‐axis volcanic diagonal ridge (DR) occurs at the eastern flank of the NELSC, linking the large rear‐arc volcano Niuatahi with the NELSC. New geochemical data from the NELSC, the southern propagator seamounts, and DR reveal that the NELSC lavas are tholeiitic basalts whereas the rear‐arc volcanoes typically erupt lavas with boninitic composition. The sharp geochemical boundary probably reflects the viscosity contrast between off‐axis hydrous harzburgitic mantle and dry fertile mantle beneath the NELSC. The new data do not indicate an inflow of Samoa plume mantle into the NELSC, confirming previously published He isotope data. The NELSC magmas form by mixing of an enriched and a depleted Indian Ocean‐type upper mantle end‐member implying a highly heterogeneous upper mantle composition in this area. Most NELSC lavas are little affected by a slab component implying that melting is adiabatic beneath the spreading center. The DR lavas show the influence of a component from the subducted Louisville Seamount Chain, which was previously thought to be restricted to the nearby arc volcanoes Niuatoputapu and Tafahi. This signature is rarely detected along the NELSC implying little mixing of melts from the low‐viscosity hydrous portion of the mantle wedge beneath the rear‐arc volcanoes into the melting region of the dry mantle beneath the NELSC.

Description: Plain Language Summary: Volcanic activity is abundant at subduction zones and the chemical analysis of the erupted rocks allows to determine the material transport in the Earth's mantle. The Northeast Lau Spreading Center (NELSC) forms by extension and volcanism behind the northern Tofua island arc. Several large volcanic structures occur east of the NELSC and the lavas of these off‐axis volcanoes are chemically and isotopically distinct implying little mixing with the magmas of the NELSC. The differences suggest decompression melting of relatively dry mantle beneath the NELSC whereas the off‐axis volcanoes reflect melting of water‐rich mantle affected by fluids from the subducting Pacific Plate. The sharp geochemical boundary between the NELSC and off‐axis volcanoes is probably due to a large viscosity contrast between hydrous harzburgitic mantle and dry fertile mantle. Element and isotope ratios indicate that the NELSC magmas form by mixing of enriched and depleted portions of the upper mantle, and we do not find evidence for inflow of the Samoa deep mantle plume from the north. Some of the off‐axis lavas contain a component from a volcanic chain that was subducted some 4 million years ago and that was previously only known in two volcanoes of the Tofua island arc.

Description: Key Points: Variably enriched mantle sources melt beneath the Northeast Lau Spreading Center (NELSC) but there is no evidence for Samoa mantle plume inflow. Relatively dry fertile mantle beneath NELSC causes sharp geochemical boundary with hydrous harzburgitic North Tonga mantle wedge. Subducted Louisville Seamount Chain material affects rear‐arc volcanism.

Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347

Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659

Description: The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional (87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 208,207,206Pb/204Pb), it is important to examine isotopic affinities in multi‐dimensional data space. Here, we apply t‐distributed stochastic neighbor embedding (t‐SNE), a multi‐variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t‐SNE results show that the apparent overlap of MORB‐OIB data trends in 2‐3D isotope ratios diagrams does not exist in multi‐dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB‐OIB mantle sources on a global scale. Rather, MORB‐OIB sample stochastically distributed small‐scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t‐SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off‐ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t‐SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”

Description: Plain Language Summary: The isotopic heterogeneity of basalts erupted at mid ocean ridges (MORB) and ocean islands (OIB) reflects the chemical evolution of Earth's mantle. The visual inspection of various 2D isotope ratio diagrams has fueled a four decade‐long discussion whether basalt heterogeneity reflects melting of only a small number of mantle components, and in particular, whether the apparent overlap of local data trends in global 2D isotope ratio diagrams indicates that melting of a common mantle component contributes to most MORB‐OIB. Here, we use multi‐variate statistical data analysis to show that the apparent overlap of MORB‐OIB data trends in 2D isotope ratio diagrams does not exist in multi‐dimensional isotope data space. Our finding invalidates any inference made for mantle compositional evolution based on the previously proposed existence of a common mantle component, its potential nature or distribution within the mantle. Rather, global MORB‐OIB sample small‐scale isotopic heterogeneities that are distributed stochastically in the Earth's mantle. Yet, MORB‐OIB with the same isotopic affinity, as identified by our multi‐variate data analysis, delineate several globally distributed regional domains. Within the regional geodynamic context, this discovery forms a fundamentally new basis for relating isotopic variations in MORB‐OIB to mantle geodynamics.

Description: Key Points: Multi‐variate statistical data analysis (t‐distributed stochastic neighbor embedding) identifies global Sr‐Nd‐Hf‐Pb isotopic affinities of oceanic basalts. There is no “common mantle component;” rather, global mid ocean ridge‐ocean island basalts sample stochastically distributed small‐scale isotopic heterogeneities. Globally distributed regional domains of isotopically alike oceanic lavas define a new basis for relating isotopic variations to geodynamics.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711

Description: DAAD, German Academic Exchange Service

Description: https://doi.org/10.25625/0SVW6S

Description: https://doi.org/10.25625/BQENGN

Description: Volatiles released from magma can form bubbles and leave the magma body to eventually mix with atmospheric air. The composition of those volatiles, as derived from measurements made after their emission, is used to draw conclusions on processes in the Earth's interior or their influences on Earth's atmosphere. So far, the discussion of the influence of high‐temperature mixing with atmospheric air (in particular oxygen) on the measured volcanic gas composition is almost exclusively based on thermodynamic equilibrium (TE) considerations. By modeling the combined effects of C‐H‐O‐S reaction kinetics, turbulent mixing, and associated cooling during the first seconds after magmatic gas release into the atmosphere we show that the resulting gas compositions generally do not represent TE states, with individual species (e.g., CO, H2, H2S, OCS, SO3, HO2, H2O2) deviating by orders of magnitude from equilibrium levels. Besides revealing the chemical details of high‐temperature emission processes, our results question common interpretations of volcanic gas studies, particularly affecting the present understanding of auto‐catalytic conversion of volcanic halogen species in the atmosphere and redox state determination from volcanic plume gas measurements.

Description: Plain Language Summary: A major fraction of magmatic gas emissions are released into the atmosphere from open vents. The emission processes are characterized by fast turbulent mixing with atmospheric air (within seconds) and associated rapid cooling. Hardly anything is known about the chemical kinetics within this brief mixing and cooling period. We simulate the chemical kinetics during the first seconds of hot magmatic gases in the atmosphere and find severe deviation to common interpretations and central thermodynamic equilibrium assumptions prevailing in volcanic gas geochemistry.

Description: Key Points: We model the chemical kinetics of high‐temperature volcanic gas emissions within the first seconds of mixing with atmospheric air. We identify key chemical processes within the magma‐atmosphere interface and quantify influences on the volcanic plume composition. Our results question common assumptions prevailing in volcanic gas geochemistry and refine interpretations of gas emissions from open vents.

Description: German Research Foundation

Description: Fossil‐bound organic material holds great potential for the reconstruction of past changes in nitrogen (N) cycling. Here, with a series of laboratory experiments, we assess the potential effect of oxidative degradation, fossil dissolution, and thermal alteration on the fossil‐bound N isotopic composition of different fossil types, including deep and shallow water scleractinian corals, foraminifera, diatoms and tooth enamel. Our experiments show that exposure to different oxidizing reagents does not significantly affect the N isotopic composition or N content of any of the fossil types analyzed, demonstrating that organic matter is well protected from changes in the surrounding environment by the mineral matrix. In addition, we show that partial dissolution (of up to 70%–90%) of fossil aragonite, calcite, opal, or enamel matrixes has a negligible effect on the N isotopic composition and N content of the fossils. These results suggest that the isotopic composition of fossil‐bound organic material is relatively uniform, and also that N exposed during dissolution is lost without significant isotopic discrimination. Finally, our heating experiments show negligible changes in the N isotopic composition and N content of all fossil types at 100°C. At 200°C and hotter, any N loss and associated nitrogen isotope changes appear to be directly linked to the sensitivity of the mineral matrix to thermal stress, which depends on the biomineral type. These results suggest that, so long as high temperature does not compromise the mineral structure, the biomineral matrix acts as a closed system with respect to N, and the N isotopic composition of the fossil remains unchanged.

Description: Plain Language Summary: The ratio of the heavy and light isotopes of nitrogen (15N and 14N) in the organic material contained within the mineral structure of fossils can be used to reconstruct past changes in biological and chemical processes. With a series of laboratory experiments, we evaluate the potential effects of chemical conditions, fossil dissolution, and heating on the nitrogen isotopic composition (15N/14N ratio) of corals, foraminifera, diatoms and tooth enamel. Our results indicate that these processes do not have a significant effect on the 15N/14N of fossils, suggesting that the mineral matrix provides a barrier that isolates a fossil's organic nitrogen from the surrounding environment, preventing alteration of its 15N/14N. In addition, we show that if part of the fossil‐bound organic nitrogen is exposed by dissolution or heating, it is lost without affecting the 15N/14N of the organic material that remains in the mineral. These findings imply that the original 15N/14N ratio incorporated by the organism is preserved in the geologic record. Therefore, measurements of the nitrogen isotopes on fossils can provide faithful biological, ecological, and environmental information about the past.

Description: Key Points: Fossil‐bound organic matter is well protected by the mineral matrix from chemical changes in the surrounding environment. Partial dissolution of fossil calcite, aragonite, opal, and enamel has a negligible effect on their N isotopic composition and N content. During heating, fossil N content and isotopic composition remains unchanged if the structure of the inorganic matrix is not compromised.

Description: Max Planck Society

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: US National Science Foundation

Description: Paul Crutzen Nobel Prize Fellowship

Description: https://doi.org/10.5281/zenodo.6884681

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In this contribution we report the first systematic study of zircon U‐Pb geochronology and δ〈sup〉18〈/sup〉O‐〈italic〉ε〈/italic〉Hf〈sub〉(〈italic〉t〈/italic〉)〈/sub〉 isotope geochemistry from 10 islands of the hot‐spot related Galapagos Archipelago. The data extracted from the zircons allow them to be grouped into three types: (a) young zircons (0–∼4 Ma) with 〈italic〉ε〈/italic〉Hf〈sub〉(〈italic〉t〈/italic〉)〈/sub〉 (∼5–13) and δ〈sup〉18〈/sup〉O (∼4–7) isotopic mantle signature with crystallization ages dating the islands, (b) zircons with 〈italic〉ε〈/italic〉Hf〈sub〉(〈italic〉t〈/italic〉)〈/sub〉 (∼5–13) and δ〈sup〉18〈/sup〉O (∼5–7) isotopic mantle signature (∼4–164 Ma) which are interpreted to date the time of plume activity below the islands (∼164 Ma is the minimum time of impingement of the plume below the lithosphere), and (c) very old zircons (∼213–3,000 Ma) with mostly continental (but also juvenile) 〈italic〉ε〈/italic〉Hf〈sub〉(〈italic〉t〈/italic〉)〈/sub〉 (∼−28–8) and δ〈sup〉18〈/sup〉O (∼5–11) isotopic values documenting potential contamination from a number of sources. The first two types with similar isotopic mantle signature define what we call the Galápagos Plume Array (GPA). Given lithospheric plate motion, this result implies that GPA zircon predating the Galápagos lithosphere (i.e., >14–164 Ma) formed and were stored at sublithospheric depths for extended periods of time. In order to explain these observations, we performed 2D and 3D thermo‐mechanical numerical experiments of plume‐lithosphere interaction which show that dynamic plume activity gives rise to complex asthenospheric flow patterns and results in distinct long‐lasting mantle domains beneath a moving lithosphere. This demonstrates that it is physically plausible that old plume‐derived zircons survive at asthenospheric depths below ocean islands.〈/p〉

Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Our data define the Galápagos Plume Array defined by mantle 〈italic〉ε〈/italic〉Hf〈sub〉(〈italic〉t〈/italic〉)〈/sub〉 and δ18O values in the range ∼0–164 Ma〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉This finding allows dating back plume activity to, at least, early Middle Jurassic (∼164 Ma)〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Numerical experiments confirm it is plausible that old Plume‐derived zircons survive in the asthenosphere for extended periods of time〈/p〉〈/list-item〉 〈/list〉 〈/p〉

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España http://dx.doi.org/10.13039/501100010198

Description: Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837

Description: European Research Council http://dx.doi.org/10.13039/501100000781

Description: https://doi.org/10.5281/zenodo.7047729

Description: https://doi.org/10.5281/zenodo.6967187

Description: We present high‐resolution profiles of dissolved, labile, and total particulate trace metals (TMs) on the Northeast Greenland shelf from GEOTRACES cruise GN05 in August 2016. Combined with radium isotopes, stable oxygen isotopes, and noble gas measurements, elemental distributions suggest that TM dynamics were mainly regulated by the mixing between North Atlantic‐derived Intermediate Water, enriched in labile particulate TMs (LpTMs), and Arctic surface waters, enriched in Siberian shelf‐derived dissolved TMs (dTMs; Co, Cu, Fe, Mn, and Ni) carried by the Transpolar Drift. These two distinct sources were delineated by salinity‐dependent variations of dTM and LpTM concentrations and the proportion of dTMs relative to the total dissolved and labile particulate ratios. Locally produced meltwater from the Nioghalvfjerdsbræ (79NG) glacier cavity, distinguished from other freshwater sources using helium excess, contributed a large pool of dTMs to the shelf inventory. Localized peaks in labile and total particulate Cd, Co, Fe, Mn, Ni, Cu, Al, V, and Ti in the cavity outflow, however, were not directly contributed by submarine melting. Instead, these particulate TMs were mainly supplied by the re‐suspension of cavity sediment particles. Currently, Arctic Ocean outflows are the most important source of dFe, dCu, and dNi on the shelf, while LpTMs and up to 60% of dMn and dCo are mainly supplied by subglacial discharge from the 79NG cavity. Therefore, changes in the cavity‐overturning dynamics of 79NG induced by glacial retreat, and alterations in the transport of Siberian shelf‐derived materials with the Transport Drift may shift the shelf dTM‐LpTM stoichiometry in the future.

Description: Plain Language Summary: Trace metals (TMs) including cobalt (Co), iron (Fe), manganese (Mn), copper (Cu), and nickel (Ni) are essential micronutrients for marine productivity. The Northeast Greenland shelf is a climatically sensitive region, influenced by both outflowing Arctic waters and local glacier melting. We lack knowledge on how these Arctic surface waters affect TM dynamics on the Greenland shelf and how climatic shifts may influence TM dynamics. Here, we distinguish local submarine meltwater from Arctic surface waters using distinct tracers; noble gases and radium isotopes. We show that the TM dynamics on the shelf are largely controlled by the intrusion of Arctic surface waters which creates a near‐surface plume of dissolved and labile particulate TMs. Conversely, submarine meltwater creates a subsurface plume enriched in dissolved TMs but depleted in particulate TMs, which is exported from underneath a floating ice tongue. In the future, increasing Arctic river discharge and local glacial melting may both significantly change shelf micronutrient ratios demonstrating downstream impacts of a changing cryosphere on marine biogeochemical cycles.

Description: Key Points: The overall dissolved and particulate trace metal (TM) dynamics were mainly regulated by the mixing with Arctic surface waters. Resuspension of cavity sediments is a major localized source of labile and total particulate Cd, Co, Fe, Mn, Ni, Cu, Al, V, and Ti. Whilst dissolved and particulate TMs are mostly coupled on the Greenland shelf, cavity outflow decouples both phases.

Description: Kuwait Institute for Scientific Research

Description: Deutsche Forschungsgemeinschaft

Description: https://doi.pangaea.de/10.1594/PANGAEA.871030

Description: https://doi.pangaea.de/10.1594/PANGAEA.871030

Description: https://doi.pangaea.de/10.1594/PANGAEA.871028

Description: https://doi.pangaea.de/10.1594/PANGAEA.905347

Description: https://doi.pangaea.de/10.1594/PANGAEA.933431

Description: https://doi.pangaea.de/10.1594/PANGAEA.948466

Description: https://doi.pangaea.de/10.1594/PANGAEA.936029

Description: https://doi.pangaea.de/10.1594/PANGAEA.936027

Description: https://doi.org/10.1594/PANGAEA.931336

Description: Geometric 3D models are a very efficient tool to visualize geological units and structural features that have been presented before just in two dimensions on maps or cross-sections. Most of the information of 3D models is presented as 3D views, virtual wells or horizontal or vertical cross-sections. However, are there further options to transfer as much as possible of the complex information of a 3D model in an adequate way to the user? Is it useful and promising to analyse 3D objects like surfaces or volumes in GIS software? In our investigation we performed a GIS based analysis of an existing geotechnical-geological 3D model of periglacial sediments. The two steps were multiple raster calculations to create geotechnical maps and a digital analysis of surface parameters based on geomorphological techniques and statistics. The investigation area is located in southern Lower Saxony and covers the city of Goettingen and surrounding regions within the valley of the river Leine. The valley is filled by unconsolidated, periglacial sediments of Quaternary age with a variable thickness ranging from 1 to 70 m. The analysed 3D model was constructed with GoCAD in a former project (Nix et al. 2009). The model is based on a heterogenous dataset comprising well data, thematic maps, and outcrop descriptions. Finally, the surfaces and volumes of the following units were modelled, with a special focus on their different geotechnical properties: (1) anthropogenic material, (2) floodplain and slope deposits, (3) freshwater limestone, peat and organic clay, (4) loess, displaced loess, and loess loam, (5) fluvial gravel, (6) outwash fan material, (7) solifluction material, (8) mixed, hetereougenous fillings of subrosion sinks and (9) the surface of the underlying hardrocks. Each top and bottom surface of the Gocad volumes was exported as raster file with additional information stored in an associated attribute table. In ArcGIS various geoprocessing tools were used to calculate and analyse these rasters and to develope thematic geotechnical and geological maps. The geomorphological analysis was subdivided in several steps. Firstly, the surfaces were described visually, concerning their outline, shape and distribution, as well as superficial structures like distinct edges, holes, channels. Secondarily, descriptive statistic parameters of thickness, area and elevation of each surface were calculated. Thirdly, geoprocessing tools of the Spatial Analyst were performed on each surface. Finally, several surfaces were combined to analyse them together, calculating ratios and overlay combinations. Seven thematical geoengineering and geological maps were created, each of them presenting one portion of the three-dimensional dataset: Map of the stratigraphy and depth of the Quaternary base, Map of the thickness of the Quaternary sediments, Distribution map of model units 1 m below ground level, Distribution map of model units 2 m below ground level, Maps of types of different foundation soils, Distribution map of sediments with low loading capacity and Map of distribution and quality of the wells. While the map creation focused on the geotechnical aspects of the model, the applied geomorphological analysis revealed various parameters and values that are related to the geological formation of the model units. Despite the complex dataset represented by the analysed 3D model, thematical information could be transfered into 2D as thematic maps. Some geological characteristics and parameters of the model units were extracted by the descriptive and GIS-based analysis. References Nix, T., Wagner, B., Lange, T. , Fritz, J., Sauter, M. (2009): 3D-Baugrundmodell der quartären Sedimente des Leinetals bei Göttingen. – 17. Tagung für Ingenieurgeologie, S. 223-227, Zittau

Description: poster

Description: The mineralogy, chemical composition, and physical properties of cratonic mantle eclogites with oceanic crustal protoliths can be modified by secondary processes involving interaction with fluids and melts, generated in various slab lithologies upon subduction (auto‐metasomatism) or mantle metasomatism after emplacement into the cratonic lithosphere. Here we combine new and published data to isolate these signatures and evaluate their effects on the chemical and physical properties of eclogite. Mantle metasomatism involving kimberlite‐like, ultramafic carbonated melts (UM carbonated melts) is ubiquitous though not pervasive, and affected between ~20% and 40% of the eclogite population at the various localities investigated here, predominantly at ~60–150 km depth, overlapping cratonic midlithospheric seismic discontinuities. Its hallmarks include lower jadeite component in clinopyroxene and grossular component in garnet, an increase in bulk‐rock MgO ± SiO2, and decrease in FeO and Al2O3 contents, and LREE‐enrichment accompanied by higher Sr, Pb, Th, U, and in part Zr and Nb, as well as lower Li, Cu ± Zn. This is mediated by addition of a high‐temperature pyroxene from a UM carbonated melt, followed by redistribution of this component into garnet and clinopyroxene. As clinopyroxene‐garnet trace‐element distribution coefficients increase with decreasing garnet grossular component, clinopyroxene is the main carrier of the metasomatic signatures. UM carbonated melt‐metasomatism at 〉130–150 km has destroyed the diamond inventory at some localities. These mineralogical and chemical changes contribute to low densities, with implications for eclogite gravitational stability, but negligible changes in shear‐wave velocities, and, if accompanied by H2O‐enrichment, will enhance electrical conductivities compared to unenriched eclogites.

Description: Plain Language Summary: Oceanic crust formed at spreading ridges is recycled in subduction zones and undergoes metamorphism to eclogite. Some of this material is captured in the overlying lithospheric mantle, where it is exhumed by passing magmas. Having formed in spreading ridges, these eclogites have proven invaluable archives for the onset of plate tectonics, for the construction of cratons during subduction/collision, as probes of the convecting mantle from which their precursors formed, and as generators of heterogeneity upon recycling into Earth's convecting mantle. During subduction and until exhumation, interaction with fluids and melts (called metasomatism) can change the mineralogy, chemical composition, and physical properties of mantle eclogites, complicating their interpretation, but a comprehensive study of these effects is lacking so far. We investigated mantle eclogites from ancient continents (cratons) around the globe in order to define hallmarks of metasomatism by subduction‐related fluids and small‐volume ultramafic carbonated mantle melts. We find that the latter is pervasive and occurs predominantly at midlithospheric depths where seismic discontinuities are detected, typically causing diamond destruction and a reduction in density. This has consequences for their gravitational stability and for the interpretation of shearwave velocities in cratons.

Description: Key Points: Exploration of metasomatic effects during subduction of ancient oceanic crust and after its emplacement into cratonic lithospheric mantle. Metasomatism by kimberlite‐like ultramafic melt affected between 20% and 40% of mantle eclogite suites worldwide, mostly at 2–5 GPa. Metasomatism lowers FeO, hence density in eclogite; no significant effect on shearwave velocities.

Description: German Research Foundation http://dx.doi.org/10.13039/501100001659

Description: National Research Foundation (NRF) http://dx.doi.org/10.13039/501100001321

Description: Wilhelm and Else Heraeus Foundation http://dx.doi.org/10.13039/501100011618

Description: Deutsche Forschungsgemeinschaft (DFG, INST

Description: research

Description: Pyrroloquinoline quinone (PQQ) is an important cofactor of calcium‐ and lanthanide‐dependent alcohol dehydrogenases, and has been known for over 30 years. Crystal structures of Ca–MDH enzymes (MDH is methanol dehydrogenase) have been known for some time; however, crystal structures of PQQ with biorelevant metal ions have been lacking in the literature for decades. We report here the first crystal structure analysis of a Ca–PQQ complex outside the protein environment, namely, poly[[undecaaquabis(μ‐4,5‐dioxo‐4,5‐dihydro‐1H‐pyrrolo[2,3‐f]quinoline‐2,7,9‐tricarboxylato)tricalcium(II)] dihydrate], {[Ca3(C14H3N2O8)2(H2O)11]·2H2O}n. The complex crystallized as Ca3PQQ2·13H2O with Ca2+ in three different positions and PQQ3−, including an extensive hydrogen‐bond network. Similarities and differences to the recently reported structure with biorelevant europium (Eu2PQQ2) are discussed.

Description: Pyrroloquinoline quinone (PQQ) is an important cofactor of calcium‐ and lanthanide‐dependent alcohol dehydrogenases. The crystal structure of a Ca–PQQ complex (Ca3PQQ2·13H2O) is reported for the first time outside a protein environment. image

Description: research

Description: In Structural Geology, many projects start with intensive field-based data acquisition campaigns, which might be performed in quite different types of natural or artificial outcrops. For some years, this field work has been substantially influenced and transformed by various close-range sensing techniques that allow the field geologist to create a digital outcrop model (DOM) and to take along plenty of geometrical and spectral information about the outcropping rocks. In general, DOMs can be utilized for outcrop visualization, documentation, manual outcrop analysis (“point-picking”), extraction of spectral data and/or semi-automatic extraction of geometric data. Within a structural investigation DOMs might be deployed for fold analysis, fault analysis, extraction of fracture networks, fracture roughness estimation, detection of neotectonic activities or digitization of geological features for 3D-models of various scales resulting in a large number of analyzing techniques. Latter might be carried out on point clouds or meshes (with or without spectral information) and may differ in pre-processing and processing steps as well as in software solution. Therefore, the analyzing structural geologist faces various tools, data formats, file types, operations and outcomes. Our investigation focus on the compilation of useful, transparent, sustainable and comparable workflows or “pipelines”, which can be executed by open-source/open-access solutions.

Description: poster

Description: Quantitative fold structure analyses at different scales are essential for deducing deformation mechanisms and the reconstruction of the deformation history of orogens. However, not only the field surveying of fold structures, especially in view of their quantification in three dimensions with the classical tools as measuring tape, grid mapping with measuring tapes, geological compass, field book and camera is a time consuming and laborious job, but also the construction of a georeferenced 3D-model of fold structures based on classical data. Another crucial aspect of the classical field surveying of folds is the limitation by poor outcrop conditions. Reasons might be restricted or no accessibility due to high outcrop walls, water or fences, limited visibility because of vegetation, difficult measurability due to very smooth walls or complexity as a result of irregular outcrop walls or distant outcrops. Furthermore, inappropriate oriented outcrop surfaces in respect to the fold geometry can make a survey even worse. Over the past years modern 3D surveying techniques like terrestrial Lidar and digital photogrammetry became progressively affordable for geological field work and now start to complement or replace traditional methods. We started to utilize these techniques on fold structure surveying and to apply quantitative fold structure analysis on different outcrop settings in Central Germany. Different workflows were developed and tested to optimize data conversion, handling and representation. We applied a laser scanner and a single lens reflex camera, complemented by a differential GPS device and laser tachymeter. Data conversion, correction and analysis were done by means of different free as well as commercial software packages. To test different outcrop situations, different quarries, salt mines and steep cliffs, exposing from single fold to complex folds in limestone, greywacke, cherts, rock salt or potassium salt, were selected. As a result, exact 3D point clouds of all exposed folds could be generated by the use of both techniques. The resultant point clouds are suited as excellent visualisation objects as well as base for accurate geometrical measurements in the range of mm or cm of single and complex folds. In addition, the point clouds serve as input dataset for the construction of detailed geological 3D models comprising punctual, linear and plane fold elements. In summary, terrestrial Lidar and digital photogrammetry are excellent field techniques to survey and document exposed folds in the range of few meters to tens of meters, especially under poor outcrop conditions. Different fold sections can now easily be correlated in 3D space to construct complete fold structures with their 3D-fold geometry. Certain fold elements, e.g. axial planes, can be reconstructed much faster and much more accurate compared to the classical approach. The only limiting factor are the very large datasets and the processing power. As next steps, we seek (1) to involve drones for completing data sets from inaccessible areas and perspectives and (2) to incorporate 3D-microfabric analysis data in the fold models as e.g. grain shape an crystallographic preferred orientations to better understand stain paths and deformation mechanisms.

Description: poster

Description: Under certain conditions, ocean surface gravity waves (SGW) interact with the seafloor underneath to trigger relatively faint but measurable seismic waves known as ocean microseisms. Cyclonic storms (e.g. hurricanes, typhoons) wandering over the ocean are major (non-stationary) sources of the former, thus opening the possibility of tracking and studying cyclones by means of their corresponding microseims. For this purpose, we identified storm-related microseisms hidden in the ambient seismic wavefield via array processing. Polarization beamforming, a robust and well-known technique is implemented. The analyses hinge on surface waves (Love and Rayleigh) which, in contrast to P-waves, are stronger but only constrain direction of arrival (without source remoteness). We use a few land-based virtual seismic arrays surrounding the North Atlantic to investigate the signatures of major hurricanes in the microseismic band (0.05-0.16 Hz), in a joint attempt to continuously triangulate their tracks. Our findings show that storm microseisms are intermittently excited with modulated amplitude at localized oceanic regions, particularly over the shallow continental shelves and slopes, having maximum amplitudes virtually independent of storm category. In most cases no detection was possible over deep oceanic regions, nor at distant arrays. Additionally, the rear quadrants and trailing swells of the cyclone provide the optimum SGW spectrum for the generation of microseisms, often shifted more than 500 km off the "eye". As a result of the aforementioned and added to the strong attenuation of storm microseisms, the inversion of tracks or physical properties of storms using a few far-field arrays is discontinuous in most cases, being reliable only if benchmark atmospheric and/or oceanic data is available for comparison. Even if challenging due to the complexity of the coupled phenomena responsible for microseisms, the inversion of site properties, such as bathymetric parameters (e.g. depth, seabed geomorphology), near- bottom geology or SGW spectrum might be possible if storms are treated as natural sources in time-lapse ambient noise investigations. This will likely require near-field (land and underwater) observations using optimal arrays or dense, widespread sensor networks. Improved detection and understanding of ocean microseisms carries a great potential to contribute to mechanically coupled atmosphere-ocean-earth models.

Description: Universität Hamburg

Description: poster

Description: Tropical forests contribute about one third to global annual CH4 uptake by soils. Understanding the factors that control the soil‐atmosphere exchange of CH4 at a large scale is a critical step to improve the CH4 flux estimate for tropical soils, which is presently poorly constrained. Since tropical forest degradation often involves shifts in nutrient availabilities, it is critical to evaluate how this will affect soil CH4 flux. Here, we report how nitrogen (N; 50 kg N ha−1 yr−1), phosphorus (P; 10 kg P ha−1 yr−1), and combined N + P additions affect soil CH4 fluxes across an elevation gradient of tropical montane forests. We measured soil CH4 fluxes in a nutrient application experiment at different elevations over a period of 5 years. Nutrient additions increased soil CH4 uptake after 4–5 years of treatment but effects were not uniform across elevations. At 1,000 m, where total soil P was high, we detected mainly N limitation of soil CH4 uptake. At 2,000 m, where total soil P was low, a strong P limitation of soil CH4 uptake was observed. At 3,000 m, where total P was low in the organic layer but high in mineral soil, we found N limitation of soil CH4 uptake. Our results show that projected increases of N and P depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrient status and plant‐microbial competition for N and P.

Description: Plain Language Summary: CH4 is a potent greenhouse gas that contributes to global warming. Tropical forests are a natural sink of CH4 but increasing nutrient depositions due to industrialization may alter the sink strength of tropical forests. Our results show that projected increases of nitrogen and phosphorus depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrients and plant‐microbial competition.

Description: Key Points: Projected increases in nitrogen and phosphorus depositions in the tropics will stimulate soil methane uptake in tropical montane forests. The direction, magnitude, and timing of nutrient deposition effects on soil methane uptake will depend on forests' nutrient status. Nutrient limitations on ecosystem processes have to be investigated in actual field conditions.

Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659

Description: https://doi.org/10.25625/XLNKNK

Description: Water isotope ratios of ice cores are a key source of information on past temperatures. Through fractionation within the hydrological cycle, temperature is imprinted in the water isotopic composition of snowfalls. However, this signal of climatic interest is modified after deposition when snow remains at the surface exposed to the atmosphere. Comparing time series of surface snow isotopic composition at Dome C with satellite observations of surface snow metamorphism, we found that long summer periods without precipitation favor surface snow metamorphism altering the surface snow isotopic composition. Using excess parameters (combining D,17O, and 18O fractions) allow the identification of this alteration caused by sublimation and condensation of surface hoar. The combined measurement of all three isotopic compositions could help identifying ice core sections influenced by snow metamorphism in sites with very low snow accumulation.

Description: Plain Language Summary: Water isotopes in ice core records are often used to reconstruct past climate temperature variations. Classically, the temperature signal is thought to be imprinted in water isotopes of precipitation, and then archived in the ice core as it falls, and in cold areas of Antarctica, piles up for very long period. Here, we show that the surface snow isotopic composition varies in between precipitation events, suggesting that there might be more than one contribution to the isotopic signal in ice core records. This is particularly important for low accumulation sites, where the snow at the surface remains exposed for very long time periods. The combined use of several isotopic ratios in surface snow helps us disentangle the processes that create this signal.

Description: Key Points: During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. The d‐excess and 17O‐excess of the snow is a proxy of snow metamorphism for low accumulation regions.

Description: FP7 Ideas: European Research Council (FP7 Ideas) http://dx.doi.org/10.13039/100011199

Description: Foundation Prince Albert of Monaco

Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156

Description: DFG project CLIMAIC

Description: https://doi.pangaea.de/10.1594/PANGAEA.934273

Description: The radiocarbon signature of respired CO2 (∆14C‐CO2) measured in laboratory soil incubations integrates contributions from soil carbon pools with a wide range of ages, making it a powerful model constraint. Incubating archived soils enriched by “bomb‐C” from mid‐20th century nuclear weapons testing would be even more powerful as it would enable us to trace this pulse over time. However, air‐drying and subsequent rewetting of archived soils, as well as storage duration, may alter the relative contribution to respiration from soil carbon pools with different cycling rates. We designed three experiments to assess air‐drying and rewetting effects on ∆14C‐CO2 with constant storage duration (Experiment 1), without storage (Experiment 2), and with variable storage duration (Experiment 3). We found that air‐drying and rewetting led to small but significant (α 〈 0.05) shifts in ∆14C‐CO2 relative to undried controls in all experiments, with grassland soils responding more strongly than forest soils. Storage duration (4–14 y) did not have a substantial effect. Mean differences (95% CIs) for experiments 1, 2, and 3 were: 23.3‰ (±6.6), 19.6‰ (±10.3), and 29.3‰ (±29.1) for grassland soils, versus −11.6‰ (±4.1), 12.7‰ (±8.5), and −24.2‰ (±13.2) for forest soils. Our results indicate that air‐drying and rewetting soils mobilizes a slightly older pool of carbon that would otherwise be inaccessible to microbes, an effect that persists throughout the incubation. However, as the bias in ∆14C‐CO2 from air‐drying and rewetting is small, measuring ∆14C‐CO2 in incubations of archived soils appears to be a promising technique for constraining soil carbon models.

Description: Plain Language Summary: Soils play a key role in the global carbon cycle by sequestering carbon from the atmosphere for decades to millennia. However, it is unclear if they will continue to do so as the climate changes. Microbial decomposition of soil organic matter returns carbon back to the atmosphere, and radiocarbon dating of this returning CO2 (∆14C‐CO2) can be used to quantify how long carbon is stored in ecosystems. Incubating archived soils could provide unique insight into soil carbon sequestration potential by quantifying the change in ∆14C‐CO2 over time. However, air‐drying, duration of archiving, and subsequent rewetting of soils may bias estimates of sequestration potential by altering the balance of younger versus older carbon leaving the soil. We compared ∆14C‐CO2 from soils incubated with and without air‐drying and archiving, and found that the air‐dried soils appeared to release slightly older carbon than soils that had never been air‐dried. The amount of time the soils were archived did not have an effect. Since the bias from air‐drying and rewetting was small, incubating archived soils appears to be a promising technique for improving our ability to model soil carbon cycling under global climate change.

Description: Key Points: ∆14C of CO2 measured in incubations of archived soils provides additional constraints for soil carbon models. Air‐drying and rewetting soils shifted the ∆14C of respired CO2 by 10‰–20‰ independent of the duration of storage. Differences in direction and magnitude of ∆14C‐CO2 shifts between forests and grasslands depended on sampling year and system C dynamics.

Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663

Description: https://doi.org/10.5281/zenodo.4959705

Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.

Description: Deutsche Forschungsgemeinschaff (DFG)

Description: Carbonate‐associated sulfate (CAS) is an important proxy for reconstructing marine sulfur cycling throughout Earth's history. In order to assess the impact of carbonate neomorphism on δ34SCAS data, a mineralogical‐spatial transect from early diagenetic limestone into low‐temperature hydrothermal dolostone was analyzed in the middle Triassic Latemar platform interior, northern Italy. This study addresses the yet unconstrained question whether hydrothermal dolostone preserves a marine δ34SCAS signature and, hence, might represent an archive for past seawater sulfate. In this study, δ34SCAS values were measured in low‐temperature hydrothermal dolostone and compared with data from their corresponding precursor limestone. Results shown here reveal that δ34SCAS values for dolostone and precursor limestone are indistinguishable. This points to a rock‐buffered middle Triassic marine δ34S signature not affected by hydrothermal alteration. Hence, hydrothermal dolostone represents, under favorable conditions, an archive for unraveling past marine sulfur cycling.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Fjords are recognized as hotspots of organic carbon (OC) burial in the coastal ocean. In fjords with glaciated catchments, glacier discharge carries large amounts of suspended matter. This sedimentary load includes OC from bedrock and terrigenous sources (modern vegetation, peat, soil deposits), which is either buried in the fjord or remineralized during export, acting as a potential source of CO2 to the atmosphere. In sub‐Antarctic South Georgia, fjord‐terminating glaciers have been retreating during the past decades, likely as a response to changing climate conditions. We determine sources of OC in surface sediments of Cumberland Bay, South Georgia, using lipid biomarkers and the bulk 14C isotopic composition, and quantify OC burial at present and for the time period of documented glacier retreat (between 1958 and 2017). Petrogenic OC is the dominant type of OC in proximity to the present‐day calving fronts (60.4 ± 1.4% to 73.8 ± 2.6%) and decreases to 14.0 ± 2.7% outside the fjord, indicating that petrogenic OC is effectively buried in the fjord. Beside of marine OC, terrigenous OC comprises 2.7 ± 0.5% to 7.9 ± 5.9% and is mostly derived from modern plants and Holocene peat and soil deposits that are eroded along the flanks of the fjord, rather than released by the retreating fjord glaciers. We estimate that the retreat of tidewater glaciers between 1958 and 2017 led to an increase in petrogenic carbon accumulation of 22% in Cumberland West Bay and 6.5% in Cumberland East Bay, suggesting that successive glacier retreat does not only release petrogenic OC into the fjord, but also increases the capacity of OC burial.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Quantifying the anthropogenic fluxes of CO2 is important to understand the evolution of carbon sink capacities, on which the required strength of our mitigation efforts directly depends. For the historical period, the global carbon budget (GCB) can be compiled from observations and model simulations as is done annually in the Global Carbon Project's (GCP) carbon budgets. However, the historical budget only considers a single realization of the Earth system and cannot account for internal climate variability. Understanding the distribution of internal climate variability is critical for predicting the future carbon budget terms and uncertainties. We present here a decomposition of the GCB for the historical period and the RCP4.5 scenario using single‐model large ensemble simulations from the Max Planck Institute Grand Ensemble (MPI‐GE) to capture internal variability. We calculate uncertainty ranges for the natural sinks and anthropogenic emissions that arise from internal climate variability, and by using this distribution, we investigate the likelihood of historical fluxes with respect to plausible climate states. Our results show these likelihoods have substantial fluctuations due to internal variability, which are partially related to El Niño‐Southern Oscillation (ENSO). We find that the largest internal variability in the MPI‐GE stems from the natural land sink and its increasing carbon stocks over time. The allowable fossil fuel emissions consistent with 3 C warming may be between 9 and 18 Pg C yr−1. The MPI‐GE is generally consistent with GCP's global budgets with the notable exception of land‐use change emissions in recent decades, highlighting that human action is inconsistent with climate mitigation goals.

Description: Key Points: We use a single‐model large ensemble to estimate uncertainties from internal climate variability in the global carbon budget. The land sink accounts for most internal climate uncertainty which may permit 9–18 Pg C yr−1 in allowable emissions by 2050 (for 3°C warming).

Description: European Union's Horizon 2020

Description: There is still a paucity of hydrological data explaining the relationship between (rapid, millennial‐scale) climate forcing and Mediterranean rainfall since the Last Glacial. We show that distinct lake‐level fluctuations at Lake Trasimeno (Italy) are associated with changing aridity in the central Mediterranean during the last ~47 800 years. The lake‐level fluctuations are reconstructed based on carbonate mineral content and carbonate mineral species, as well as the stable oxygen and carbon isotope (δ18O and δ13C) geochemistry of endogenic carbonates. Low lake levels are linked to high carbonate, Mg‐calcite and aragonite contents, and high δ18O and δ13C values. Inferred hydrological changes are linked to glacial–interglacial and, tentatively within the limitations of our chronology, to millennial‐scale climate variability as well as the intensity of the Atlantic Meridional Overturning Circulation (AMOC). Prior to the Last Glacial Maximum (LGM), during intervals equivalent to Marine Isotope Stage 3 (MIS 3), a stronger AMOC associated with Greenland interstadial periods (Dansgaard/Oeschger (D/O) warm periods) and stronger Asian monsoon probably coincide with increased precipitation in central Italy as inferred from high lake levels at Lake Trasimeno. Periods of weak AMOC intensity such as during Greenland stadials (D/O cold periods), during Heinrich events, and weak Asian monsoons are correlated with lake level lowstands, which imply relatively dry conditions in central Italy. Lake Trasimeno’s water level during the LGM and the Lateglacial (MIS 2) is relatively stable, with recorded changes showing distinct similarities to orbital configurations. Although muted, high latitude climate forcing is still evident in the data during peak glacial conditions. The transition from D/O‐like hydrological variability at Lake Trasimeno during MIS 3 to orbitally controlled fluctuations during the Lateglacial to Holocene transition coincides with an increasing amplitude in local winter and summer insolation, probably indicating increasing seasonality and a larger temperature gradient between low‐ and high‐latitude settings.

Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655

Description: The early exhumation history of the Tauern Window in the European Eastern Alps and its surface expression is poorly dated and quantified, partly because thermochronological and provenance information are sparse from the Upper Austrian Northern Alpine Foreland Basin. For the first time, we combine a single‐grain double‐dating approach (Apatite Fission Track and U‐Pb dating) with trace‐element geochemistry analysis on the same apatites to reconstruct the provenance and exhumation history of the late Oligocene/early Miocene Eastern Alps. The results from 22 samples from the Chattian to Burdigalian sedimentary infill of the Upper Austrian Northern Alpine Foreland Basin were integrated with a 3D seismic‐reflection data set and published stratigraphic reports. Our highly discriminative data set indicates an increasing proportion of apatites (from 6% to 23%) with Sr/Y values 〈0.1 up‐section and an increasing amount of apatites (from 24% to 38%) containing 〉1,000 ppm light rare‐earth elements from Chattian to Burdigalian time. The number of U‐Pb ages with acceptable uncertainties increases from 40% to 59% up‐section, with mostly late Variscan/Permian ages, while an increasing number of grains (10%–27%) have Eocene or younger apatite fission track cooling ages. The changes in the apatite trace‐element geochemistry and U‐Pb data mirror increased sediment input from an ≥upper amphibolite‐facies metamorphic source of late Variscan/Permian age – probably the Ötztal‐Bundschuh nappe system – accompanied by increasing exhumation rates indicated by decreasing apatite fission track lag times. We attribute these changes to the surface response to upright folding and doming in the Penninic units of the future Tauern Window starting at 29–27 Ma. This early period of exhumation (0.3–0.6 mm/a) is triggered by early Adriatic indentation along the Giudicarie Fault System.

Description: Science Foundation Ireland http://dx.doi.org/10.13039/501100001602

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Preservation of organic carbon (OC) in marine sediments exerts a major control on the cycling of carbon in the Earth system. In these marine environments, OC preservation may be enhanced by diagenetic reactions in locations where deposition of fragmental volcanic material called tephra occurs. While the mechanisms by which this process occurs are well understood, site‐specific studies of this process are limited. Here, we report a study of sediments from the Bering Sea (IODP Site U1339D) to investigate the effects of marine tephra deposition on carbon cycling during the Pleistocene and Holocene. Our results suggest that tephra layers are loci of OC burial with distinct δ13C values, and that this process is primarily linked to bonding of OC with reactive metals, accounting for ∼80% of all OC within tephra layers. In addition, distribution of reactive metals from the tephra into non‐volcanic sediments above and below the tephra layers enhances OC preservation in these sediments, with ∼33% of OC bound to reactive phases. Importantly, OC‐Fe coupling is evident in sediments 〉700,000 years old. Thus, these interactions may help explain the observed preservation of OC in ancient marine sediments.

Description: Plain Language Summary: The burial of organic carbon (OC) in marine sediments is one of the major carbon sinks on Earth, meaning that it removes carbon dioxide from the ocean‐atmosphere system. However, the speed at which burial occurs varies across the globe, and is dependent on a range of factors, from the amount of nutrients in the water column, to the type of sediment. Despite evidence suggesting that when tephra is deposited to the seafloor carbon burial is enhanced, very little work has been done to investigate this process. We have therefore analyzed sediments from the Bering Sea, where volcanoes from the Aleutian Islands and Kamchatka regularly deposit tephra in the ocean. We found that OC burial is indeed associated with ash deposition, and importantly, that OC is preserved in the ash layers themselves. We show here that this carbon is preserved effectively because of chemical reactions between the OC and reactive iron, which is released by the ash, creating conditions which preserve carbon for hundreds of thousands of years.

Description: Key Points: Tephra layers are loci of marine organic carbon (OC) burial with distinct carbon isotopic compositions. Preservation primarily linked to association of OC with reactive iron phases, accounting for ∼80% of all OC in tephra layers. OC‐reactive Fe coupling is observed in sediments 〉700,000 years old, indicating long‐term persistence of these complexes.

Description: NERC

Description: The winter 2019/2020 showed the lowest ozone mixing ratios ever observed in the Arctic winter stratosphere. It was the coldest Arctic stratospheric winter on record and was characterized by an unusually strong and long‐lasting polar vortex. We study the chemical evolution and ozone depletion in the winter 2019/2020 using the global Chemistry and Transport Model ATLAS. We examine whether the chemical processes in 2019/2020 are more characteristic of typical conditions in Antarctic winters or in average Arctic winters. Model runs for the winter 2019/2020 are compared to simulations of the Arctic winters 2004/2005, 2009/2010, and 2010/2011 and of the Antarctic winters 2006 and 2011, to assess differences in chemical evolution in winters with different meteorological conditions. In some respects, the winter 2019/2020 (and also the winter 2010/2011) was a hybrid between Arctic and Antarctic conditions, for example, with respect to the fraction of chlorine deactivation into HCl versus ClONO2, the amount of denitrification, and the importance of the heterogeneous HOCl + HCl reaction for chlorine activation. The pronounced ozone minimum of less than 0.2 ppm at about 450 K potential temperature that was observed in about 20% of the polar vortex area in 2019/2020 was caused by exceptionally long periods in the history of these air masses with low temperatures in sunlight. Based on a simple extrapolation of observed loss rates, only an additional 21–46 h spent below the upper temperature limit for polar stratospheric cloud formation and in sunlight would have been necessary to reduce ozone to near zero values (0.05 ppm) in these parts of the vortex.

Description: Key Points: The Arctic stratospheric winter 2019/2020 showed the lowest ozone mixing ratios ever observed and was one of the coldest on record. Chemical evolution of the Arctic winter 2019/2020 was a hybrid between typical Arctic and typical Antarctic conditions. Only an additional 21–46 h below PSC temperatures and in sunlight would have been necessary to reduce ozone to near zero locally.

Description: International Multidisciplinary Drifting Observatory for the Study of the Arctic Climate (MOSAiC)

Description: research

Description: Molecular hydrogen (H2) released during serpentinization of mantle rocks is one of the main fuels for chemosynthetic life. Processes of H2 production at slow-spreading mid-ocean ridges (MORs) have received much attention in the past. Less well understood is serpentinization at passive continental margins where different rock types are involved (lherzolite instead of harzburgite/dunite at MORs) and the alteration temperatures tend to be lower (〈200°C vs. 〉200°C). To help closing this knowledge gap we investigated drill core samples from the West Iberia margin. Lherzolitic compositions and spinel geochemistry indicate that the exhumed peridotites resemble sub-continental lithospheric mantle. The rocks are strongly serpentinized, mainly consist of serpentine with little magnetite, and are generally brucite-free. Serpentine can be uncommonly Fe- rich, with XMg Mg/(Mg + Fe) 〈 0.8, and shows distinct compositional trends toward a cronstedtite endmember. Bulk rock and silicate fraction Fe(III)/ Fe ratios are 0.6–0.92 and 0.58–0.8, respectively; our data show that 2/3 of the ferric Fe is accounted for by Fe(III)- serpentine. Mass balance and thermodynamic calculations suggest that the sample’s initial serpentinization produced ∼120 to 〉300 mmol H2 per kg rock. The cold, late-stage weathering of the serpentinites at the seafloor caused additional H2 formation. These results suggest that the H2 generation potential evolves during the transition from continental break-up to ultraslow and, eventually, slow MOR spreading. Metamorphic phase assemblages systematically vary between these settings, which has consequences for H2 yields during serpentinization. At magma-poor rifted margins and ultraslow- spreading MORs, serpentine hosts most Fe(III). Hydrogen yields of 120 to 〉300 mmol and 50–150 mmol H2 per kg rock, respectively, may be expected at temperatures of 〈200°C. At slow-spreading MORs, in contrast, serpentinization may produce 200–350 mmol H2, most of which is related to magnetite formation at 〉200°C. Since, in comparison to slow-spreading MORs, geothermal gradients at magma-poor margins and ultraslow-spreading MORs are lower, larger volumes of low-temperature serpentinite should form in these settings. Serpentinization of lherzolitic rocks at magma-poor margins should produce particularly high amounts of H2 under conditions within the habitable zone. Magma-poor margins may hence be more relevant environments for hydrogenotrophic microbial life than previously thought.

Description: research

Description: https://doi.org/10 .1594/PANGAEA.920208

Description: research

Description: Few data exist that provide insight into pro- cesses affecting the long-term carbon cycle at shallow fore- arc depths. To better understand the mobilization of C in sediments and crust of the subducting slab, we investigated carbonate materials that originate from the subduction chan- nel at the Mariana forearc (〈 20 km) and were recovered during International Ocean Discovery Program Expedition 366. Calcium carbonates occur as vein precipitates within metavolcanic and metasedimentary clasts. The clasts repre- sent portions of the subducting lithosphere, including ocean island basalt, that were altered at lower blueschist facies conditions and were subsequently transported to the fore- arc seafloor by serpentinite mud volcanism. Euhedral arag- onite and calcite and the lack of deformation within the veins suggest carbonate formation in a stress-free environ- ment after peak metamorphism affected their hosts. Inter- growth with barite and marked negative Ce anomalies in car- bonate attest the precipitation within a generally oxic envi- ronment, that is an environment not controlled by serpen- tinization. Strontium and O isotopic compositions in car- bonate (87Sr/86Sr = 0.7052 to 0.7054, δ18OVSMOW = 20 to 24 ‰) imply precipitation from slab-derived fluids at tem- peratures between ∼ 130 and 300 ◦C. These temperature es- timates are consistent with the presence of blueschist facies phases such as lawsonite coexisting with the carbonates in some veins. Incorporated C is inorganic (δ13CVPDB = −1 ‰ to +4 ‰) and likely derived from the decarbonation of cal- careous sediment and/or oceanic crust. These findings pro- vide evidence for the mobilization of C in the downgoing slab at depths of 〈 20 km. Our study shows for the first time in detail that a portion of this C forms carbonate precipitates in the subduction channel of an active convergent margin. This process may be an important asset in understanding the deep carbon cycle since it highlights that some C is lost from the subducting lithosphere before reaching greater depths.

Description: research

Description: Changes in penguin populations on the Antarctic Peninsula have been linked to several environmental factors, but the potentially devastating impact of volcanic activity has not been considered. Here we use detailed biogeochemical analyses to track past penguin colony change over the last 8,500 years on Ardley Island, home to one of the Antarctic Peninsula’s largest breeding populations of gentoo penguins. The first sustained penguin colony was established on Ardley Island c. 6,700 years ago, pre-dating sub-fossil evidence of Peninsula- wide occupation by c. 1,000 years. The colony experienced five population maxima during the Holocene. Overall, we find no consistent relationships with local-regional atmospheric and ocean temperatures or sea-ice conditions, although the colony population maximum, c. 4,000–3,000 years ago, corresponds with regionally elevated temperatures. Instead, at least three of the five phases of penguin colony expansion were abruptly ended by large eruptions from the Deception Island volcano, resulting in near-complete local extinction of the colony, with, on average, 400–800 years required for sustainable recovery.

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3080_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3081_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3082_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3083_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3084_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3085_ESM.xlsx

Description: https://static-content.springer.com/esm/art%3A10.1038%2Fncomms14914/MediaObjects/41467_2017_BFncomms14914_MOESM3086_ESM.xlsx

Description: research

Description: The ungrouped iron meteorite Nedagolla is the first meteorite with bulk Mo, Ru, and Ni isotopic compositions that are intermediate between those of the noncarbonaceous (NC) and carbonaceous (CC) meteorite reservoirs. The Hf‐W chronology of Nedagolla indicates that this mixed NC–CC isotopic composition was established relatively late, more than 7 Myr after solar system formation. The mixed NC–CC isotopic composition is consistent with the chemical composition of Nedagolla, which combines signatures of metal segregation under more oxidizing conditions (relative depletions in Mo and W), characteristic for CC bodies, and more reducing conditions (high Si and Cr contents), characteristic for some NC bodies, in a single sample. These data combined suggest that Nedagolla formed as the result of collisional mixing of NC and CC core material, which partially re‐equilibrated with silicate mantle material that predominantly derives from the NC body. These mixing processes might have occurred during a hit‐and‐run collision between two differentiated bodies, which also provides a possible pathway for Nedagolla's extreme volatile element depletion. As such, Nedagolla provides the first isotopic evidence for early collisional mixing of NC and CC bodies that is expected as a result of Jupiter's growth.

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: The accessories perovskite, pyrochlore, zirconolite, calzirtite and melanite from carbonatites and carbonate-rich foidites from the Kaiserstuhl are variously suited for the in situ determination of their U–Pb ages and Sr, Nd- and Hf-isotope ratios by LA-ICP-MS. The 143Nd/144Nd ratios may be determined precisely in all five phases, the 176Hf/177Hf ratios only in calzirtite and the 87Sr/86Sr ratios in perovskites and pyrochlores. The carbonatites and carbonate-rich foidites belong to one of the three magmatic groups that Schleicher et al. (1990) distinguished in the Kaiserstuhl on the basis of their Sr, Nd and Pb isotope ratios. Tephrites, phonolites and essexites (nepheline monzogabbros) form the second and limburgites (nepheline basanites) and olivine nephelinites the third. Our 87Sr/86Sr isotope data from the accessories overlap with the carbonatite and olivine nephelinite fields defined by Schleicher et al. (1990) but exhibit a much narrower range. These and the εNd and εHf values plot along the mantle array in the field of oceanic island basalts relatively close to mid-ocean ridge basalts. Previously reported K–Ar, Ar–Ar and fission track ages for the Kaiserstuhl lie between 16.2 and 17.8 Ma. They stem entirely from the geologically older tephrites, phonolites and essexites. No ages existed so far for the geologically younger carbonatites and carbonate-rich foidites except for one apatite fission track age (15.8 Ma). We obtained precise U–Pb ages for zirconolites and calzirtites of 15.66, respectively 15.5 Ma (± 0.1 2σ) and for pyrochlores of 15.35 ± 0.24 Ma. Only the perovskites from the Badberg soevite yielded a U–P concordia age of 14.56 ± 0.86 Ma while the perovskites from bergalites (haüyne melilitites) only gave 206Pb/238U and 208Pb/232Th ages of 15.26 ± 0.21, respectively, 15.28 ± 0.48 Ma. The main Kaiserstuhl rock types were emplaced over a time span of 1.6 Ma almost 1 million years before the carbonatites and carbonate-rich foidites. These were emplaced within only 0.32 Ma.

Description: Frankfurt Institute for Advanced Studies (FIAS) (4401)

Description: The resuspension of sediment leads to an increased release of nutrients and organic substances into the overlying water column, which can have a negative effect on the oxygen budget. Especially in the warmer months with a lower oxygen saturation and higher biological activity, the oxygen content can reach critical thresholds in estuaries like the upper Elbe estuary. Many studies have dealt with the nutrient fluxes that occur during a resuspension event. However, the sediment properties that influence the oxygen consumption potential (OCP) and the different biochemical processes have not been examined in detail. To fill this gap, we investigated the biogeochemical composition, texture, and OCP of sediments at 21 locations as well as the temporal variability within one location for a period of 2 years (monthly sampling) in the upper Elbe estuary. The OCP of sediments during a seven-day resuspension event can be described by the processes of sulphate formation, nitrification, and mineralisation. Chlorophyll, total nitrogen (Ntotal), and total organic carbon showed the highest correlations with the OCP. Based on these correlations, we developed a prognosis model to calculate the OCP for the upper Elbe estuary with a single sediment parameter (Ntotal). The model is well suited to calculate the oxygen consumption of resuspended sediments in the Hamburg port area during the relevant warmer months and shows a normalised root mean squared error of 〈 0.11 ± 0.13. Thus, the effect of maintenance measures such as water injection dredging and ship-induced wave on the oxygen budget of the water can be calculated.

Description: Hamburg Port Authority

Description: Universität Hamburg (1037)

Description: Many terrestrial silicate reservoirs display a characteristic depletion in Nb, which has been explained in some studies by the presence of reservoirs on Earth with superchondritic Nb/Ta. As one classical example, K-rich lavas from the Sunda rear-arc, Indonesia, have been invoked to tap such a high-Nb/Ta reservoir. To elucidate the petrogenetic processes active beneath the Java rear-arc and the causes for the superchondritic Nb/Ta in some of these lavas, we studied samples from the somewhat enigmatic Javanese rear-arc volcano Muria, which allow conclusions regarding the across-arc variations in volcanic output, source mineralogy and subduction components. We additionally report some data for an along-arc sequence of lavas from the Indonesian part of the Sunda arc, extending from Krakatoa in the west to the islands of Bali and Lombok in the east. We present major and trace element concentrations, Sr–Nd–Hf–Pb isotope compositions, and high-field-strength element (HFSE: Nb, Ta, Zr, Hf, W) concentrations obtained via isotope dilution and MC-ICP-MS analyses. The geochemical data are complemented by melting models covering different source compositions with slab melts formed at variable P–T conditions. The radiogenic isotope compositions of the frontal arc lavas in combination with their trace element systematics confirm previously established regional variations of subduction components along the arc. Melting models show a clear contribution of a sediment-derived component to the HFSE budget of the frontal arc lavas, particularly affecting Zr–Hf and W. In contrast, the K-rich rear-arc lavas tap more hybrid and enriched mantle sources. The HFSE budget of the rear-arc lavas is in particular characterized by superchondritic Nb/Ta (up to 25) that are attributed to deep melting involving overprint by slab melts formed from an enriched garnet–rutile-bearing eclogitic residue. Sub-arc slab melting was potentially triggered along a slab tear beneath the Sunda arc, which is the result of the forced subduction of an oceanic basement relief ~ 8 Myr ago as confirmed by geophysical studies. The purported age of the slab tear coincides with a paucity in arc volcanism, widespread thrusting of the Javanese basement crust as well as the short-lived nature of the K-rich rear-arc volcanism at that time.

Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655

Description: Gottfried Wilhelm Leibniz Universität Hannover (1038)

Description: The partitioning of major and trace elements between eclogite and aqueous fluids with variable salinity was studied at 700–800 °C and 4–6 GPa in piston cylinder and multi anvil experiments. Fluid compositions were determined using the diamond trap technique combined with laser ablation ICP-MS measurements in the frozen state. In addition to NaCl, SiO2 is the main solute in the fluids. The fluid/eclogite partition coefficients of the large ion lithophile elements (LILE), such as Rb, Cs, Sr, and Ba as well as those of the light rare earths (LREE), of Pb, and of U increase by up to three orders of magnitude with salinity. These elements will therefore be efficiently transported by saline fluids. On the other hand, typical high field strength elements, such as Ti, Nb, and Ta, are not mobilized even at high salinities. Increasing temperature and pressure gradually increases the partitioning into the fluid. In particular, Th is mobilized by silica-rich fluids at 6 GPa already at low salinities. We show that we can fully reproduce the trace element enrichment pattern of primitive arc basalts by adding a few percent of saline fluid (with 5–10 wt% Cl) released from the basaltic slab to the zone of melting in the mantle wedge. Assuming 2 wt% of rutile in the eclogite equilibrated with the saline fluid produces a negative Nb Ta anomaly that is larger than in most primitive arc basalts. Therefore, we conclude that the rutile fraction in the subducted eclogite below most arcs is likely 〈 1 wt%. In fact, saline fluids would even produce a noticeable negative Nb Ta anomaly without any rutile in the eclogite residue. Metasomatism by sediment melts alone, on the other hand, is unable to produce the enrichment pattern seen in arc basalts. We, therefore, conclude that at least for primitive arc basalts, the release of hydrous fluids from the basaltic part of the subducted slab is the trigger for melting and the main agent of trace element enrichment. The contribution of sediment melts to the petrogenesis of these magmas is likely negligible. In the supplementary material, we provide a “Subduction Calculator” in Excel format, which allows the calculation of the trace element abundance pattern in primitive arc basalts as function of fluid salinity, the amount of fluid released from the basaltic part of the subducted slab, the fluid fraction added to the source, and the degree of melting.

Description: DFG

Description: Universität Bayreuth (3145)

Description: Noble gases are important tracers of planetary accretion and acquisition of volatiles to planetary atmospheres and interiors. Earth’s mantle hosts solar-type helium and neon for which 〈sup〉20〈/sup〉Ne/〈sup〉22〈/sup〉Ne ratios advocate either incorporation of solar wind irradiated solids or solar nebula gas dissolution into an early magma ocean. However, the exact source location of primordial signatures remains unclear. Here we use high-resolution stepwise heating gas extraction experiments to analyse interior samples of the iron meteorite Washington County and find that they contain striking excesses of solar helium and neon. We infer that the Washington County protolith was irradiated by solar wind and that implanted noble gases were partitioned into segregating metal melts. The corollary that solar signatures are able to enter the cores of differentiated planetesimals and protoplanets validates hypotheses that Earth’s core may have incorporated solar noble gases and may be contributing to the solar signatures observed in Earth’s mantle.

Description: Incorporation of iron meteorites in the core could explain variable noble gas signatures in different mantle reservoirs, according to stepwise heating experiments which show that the Washington County meteorite carries solar wind-derived He and Ne.

Description: Klaus Tschira Stiftung (Klaus Tschira Foundation) https://doi.org/10.13039/501100007316

Description: https://doi.org/10.26022/IEDA/111938

Description: Lake Victoria is the second largest freshwater lake and the largest tropical lake in the world. The transboundary lake has the fastest growing population in its catchment, which can impact the water and sediment quality. To determine the extent of anthropogenic effects on sediment quality in the Ugandan part of Lake Victoria, the contents and binding behaviour of trace elements were analysed, as well as organic matter and phosphorus in different sediment layers of both deep and coastal sediments near the coastal cities of Entebbe, Kampala and Jinja. The data were assessed using the German LAWA criteria for trace-element pollution, the Geo-Index, Cluster- and Factor analyses. Mostly, no critical trace-element contamination in the sediments of the investigated area was observed. However, changes in element distributions caused by anthropogenic influences from around the lake were detected, like higher contents of Cu, Ti and V in near shore sediments with urban surrounding. Near Jinja, industrial wastewaters caused particularly elevated contents of Cu in the sediments (70–121 mg/kg, 3.5–6 times the geogenic background), exceeding the LAWA criteria and potentially harming the aquatic habitat. In addition, temporally growing organic matter contents in the lake sediments near the estuary of River Nzoia (from 4.2 to 17.6% in around 60 years) due to increased soil erosion in the river’s catchment area and blooms of the water hyacinth became visible. This study demonstrates that the whole catchment area is responsible to ensure a healthy aquatic ecosystem in Lake Victoria.

Description: International Foundation for Science (IFS)

Description: Organisation for the Prohibition of Chemical Weapons http://dx.doi.org/10.13039/501100004766

Description: Helmholtz-Zentrum für Umweltforschung GmbH - UFZ (4215)

Description: We investigate the "macronutrient-access hypothesis", which states that the balance between stoichiometric macronutrient demand and accessible macronutrients controls nutrient assimilation by aquatic heterotrophs. Within this hypothesis, we consider bioavailable dissolved organic carbon (bDOC), reactive nitrogen (N) and reactive phosphorus (P) to be the macronutrients accessible to heterotrophic assimilation. Here, reactive N and P are the sums of dissolved inorganic N (nitrate-N, nitrite-N, ammonium-N), soluble-reactive P (SRP), and bioavailable dissolved organic N (bDON) and P (bDOP). Previous data from various freshwaters suggests this hypothesis, yet clear experimental support is missing. We assessed this hypothesis in a proof-of-concept experiment for waters from four small agricultural streams. We used seven different bDOC:reactive N and bDOC:reactive P ratios, induced by seven levels of alder leaf leachate addition. With these treatments and a stream-water specific bacterial inoculum, we conducted a 3-day experiment with three independent replicates per combination of stream water, treatment, and sampling occasion. Here, we extracted dissolved organic matter (DOM) fluorophores by measuring excitation-emission matrices with subsequent parallel factor decomposition (EEM-PARAFAC). We assessed the true bioavailability of DOC, DON, and the DOM fluorophores as the concentration difference between the beginning and end of each experiment. Subsequently, we calculated the bDOC and bDON concentrations based on the bioavailable EEM-PARAFAC fluorophores, and compared the calculated bDOC and bDON concentrations to their true bioavailability. Due to very low DOP concentrations, the DOP determination uncertainty was high, and we assumed DOP to be a negligible part of the reactive P. For bDOC and bDON, the true bioavailability measurements agreed with the same fractions calculated indirectly from bioavailable EEM-PARAFAC fluorophores (bDOC r〈sup〉2〈/sup〉 = 0.96, p 〈 0.001; bDON r〈sup〉2〈/sup〉 = 0.77, p 〈 0.001). Hence we could predict bDOC and bDON concentrations based on the EEM-PARAFAC fluorophores. The ratios of bDOC:reactive N (sum of bDON and DIN) and bDOC:reactive P (equal to SRP) exerted a strong, predictable stoichiometric control on reactive N and P uptake (R〈sup〉2〈/sup〉 = 0.80 and 0.83). To define zones of C:N:P (co-)limitation of heterotrophic assimilation, we used a novel ternary-plot approach combining our data with literature data on C:N:P ranges of bacterial biomass. Here, we found a zone of maximum reactive N uptake (C:N:P approx. 〉 114: 〈 9:1), reactive P uptake (C:N:P approx. 〉 170:21: 〈 1) and reactive N and P co-limitation of nutrient uptake (C:N:P approx. 〉 204:14:1). The “macronutrient-access hypothesis” links ecological stoichiometry and biogeochemistry, and may be of importance for nutrient uptake in many freshwater ecosystems. However, this experiment is only a starting point and this hypothesis needs to be corroborated by further experiments for more sites, by in-situ studies, and with different DOC sources.

Description: Rural and Environment Science and Analytical Services Division http://dx.doi.org/10.13039/100011310

Description: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656

Description: Helmholtz-Zentrum für Umweltforschung GmbH - UFZ (4215)

Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Between 1973 and 1994, 15 samples of CI chondrites were analyzed by neutron activation analysis at the Max‐Planck‐Institute for Chemistry, Department of Cosmochemistry in Mainz, Germany. The analyses comprise nine Orgueil samples and three samples of Ivuna, two of Alais and one of Tonk. Samples came from various sources and had masses between 5 and 600 mg. Most data are published here for the first time. The results for the nine Orgueil samples demonstrate the essentially homogeneous chemical composition of Orgueil at a level of a few milligrams. The analytical results of Ivuna, Alais, and Tonk agree, with only few exceptions, with the results of Orgueil analyses. All samples agree within ±3% in their contents of Sc, Ir, Cr, Fe, Co, Zn, and Se. The elements Sc and Ir represent the refractory component; Cr, Fe, and Co the main component; and Zn and Se the volatile component. Thus, in all CI chondrites there are essentially the same fractions of the fundamental cosmochemical components. The essentially identical chemical composition of all samples shows that their water contents are constant at about 20 ± 5 wt%. There is excellent agreement between the data listed here with data reported in the relevant literature. There is no doubt that the CI composition is a well‐defined entity, which is thought to represent the non‐gaseous compositions of the solar nebula and the photosphere of the Sun. In addition, we conclude that the recently proposed new CI chondritic chlorine and Br values are too low, when compared to earlier measurements.〈/p〉

Description: Porous and fractured aquifers exist in the area of Hurghada, Eastern Desert of Egypt, whose recharge processes through the common flash floods are not identified. Hydrochemical parameters, stable isotopes 〈sup〉18〈/sup〉O, 〈sup〉2〈/sup〉H and tritium in floodwater and groundwater were applied in the area subject to study. Additionally, He isotopes were investigated in the deep wells in the faulted zone at the Abu Shaar Plateau. 〈sup〉3〈/sup〉H activity in all sampled points lies below the detection limit excluding a recent recharge component in groundwater. However, the hydrochemical ratios and the stable isotope signature confirm that the shallow wells and springs (Red Sea Hills group) are being recharged from modern precipitation. The hydrochemical parameters of the deep wells at the Abu Shaar Plateau (coastal plain group) confirm another origin for the ions rather than the modern precipitation. Together with the 〈sup〉18〈/sup〉O and 〈sup〉2〈/sup〉H values, the Br/Cl ratio of this group confirms the absence of seawater intrusion component and the role of the fault as a hydraulic barrier. These 〈sup〉18〈/sup〉O and 〈sup〉2〈/sup〉H values deviate from the GMWL confirming an evaporation effect and colder infiltration conditions and reveal strongly a possible mixing with the Nubian Sandstone in the region. The 〈sup〉3〈/sup〉He/〈sup〉4〈/sup〉He ratio confirms a mantle contribution of 2% from the total He components.

Description: Open Access funding enabled and organized by Projekt DEAL

Description: Purpose: This field study aimed to guide the planning of iron amendments for phosphorus retention by investigating the long-term fate of iron added to two urban lakes (Plötzensee and Groß Glienicker See) in Berlin, Germany. The contributions of iron dosing to improve lake status as well as the relevance of competing processes for management success were evaluated. Methods: Sediment stratigraphy, as well as occurrence of iron minerals, and fluxes between water and sediment were examined using geochemical analyses (i.e. element composition, sequential extraction, X-ray diffraction, and pore water analyses). A one-box lake model was used to relate these fluxes to monitoring data from the water column and to sediment inventories. Results: In both lakes, the added iron was preserved in the sediment. Whereas phosphorus retention increased following the addition of iron to Groß Glienicker See, sulphur was retained by the excess iron in Plötzensee. This contrasting effect is attributed to significantly different sulphate reduction rates in two lakes (Wilcoxon rank sum test: W = 25, p = 0.008). According to the one-box model, sulphate reduction explained both the decrease in measured sulphate concentrations after iron application as well as the observed increase in sulphur deposition in the sediments. Conclusion: Management interventions involving iron amendments to enhance phosphorus retention must consider the competing process of iron sulphide formation during the entire management plan period, and additional iron may need to be applied to account for this effect.

Description: Leibniz-Institut für Gewässerökologie und Binnenfischerei (IGB) im Forschungsverbund Berlin e.V. (3473)

Description: In this paper, fluoride geochemistry and health risk of groundwater in Coimbatore district is studied. The order of dominance of ions were HCO〈sub〉3〈/sub〉 〉 Cl 〉 SO〈sub〉4〈/sub〉 〉 CO〈sub〉3〈/sub〉 and Na 〉 Ca 〉 Mg 〉 K. Alkaline groundwater and the dominance of HCO〈sub〉3〈/sub〉 and Na is favourable for the fluoride enrichment. Around 46% of the samples, N–NE regions, have F〈sup〉−〈/sup〉 higher than permissible limit of 1.5 mg/L. Pink granites, charnockite and gneisses in lithology is the possible origin of F〈sup〉−〈/sup〉. However, NO〈sub〉3〈/sub〉 vs F plot shows positive trend in some samples, indicating anthropogenic inputs of F〈sup〉−〈/sup〉. Correlation plots of F〈sup〉−〈/sup〉 was trending positive with pH, HCO〈sub〉3〈/sub〉 and Na and but negative for Ca, indicating the control of these ions in F〈sup〉−〈/sup〉 mobility. This result is supported by undersaturation of fluorite and supersaturation of carbonates. Four significant principal components were derived, which have explained 87% of the total variation. PC1 has high factor loadings for EC, Ca, Mg Na, Cl, SO〈sub〉4〈/sub〉, NO〈sub〉3〈/sub〉 indicating both natural and anthropogenic influences. PC2, PC3 and PC4 have higher loading for pH and HCO〈sub〉3〈/sub〉, K and HCO〈sub〉3〈/sub〉 and F〈sup〉−〈/sup〉, respectively, indicating geogenic factors in the F〈sup〉−〈/sup〉 enrichment. Human health risk assessment (HHRA) by ingestion and dermal pathways were calculated using Hazard Quotient HQ and Hazard Index (HI). 27% of males, 36% of females and 39% of the children have HI 〉 1, posing noncarcinogenic risks.

Description: Freie Universität Berlin (1008)

Description: On the Qinghai-Tibetan Plateau, the ecological crisis appears in every physical and social aspect, and typically affects the rangelands on which most local people depend for their livelihood. Until today, however, changes in land use and vegetation cover on this Plateau have not yet been adequately and practically treated in studying the framework of sustainability. This thesis deals first with the basic ecological influences and interactions before reviewing their implications for development. The limitations of an ecological perspective is recognized, but this stems mainly from the misapplication of perspective and should not detract from its value. Ecology is undoubtedly the most basic and pervasive of the many determinants of the pastoral production systems of the high-frigid land. To ignore ecology or to fail to take it into account is to court disaster. The amount of literature reflects the importance of the subject but is not reviewed here in any detail; rather the aim is simply to set the scene for later discussions.

Description: thesis

Description: DFG, SUB Göttingen

Description: Unter Berücksichtigung der Forschungssituation und der Resultate der wissenschaftstheoretischen Vororientierung stellt sich diese Arbeit zum einen die Aufgabe, die bei SOULAVIE mit den Bezeichnungen "géographie physique des plantes“, "géographie physique des animaux" und "geographie physique de l'homme et de la femme" verbundenen Grundannahmen, Fragestellungen, Verfahrensweisen und Ergebnisse aus seinen naturhistorischen Schriften zu erschließen, sie zu systematisieren und als Gedankensystem zu rekonstruieren. Zum anderen fragt sie nach dem Spannungsverhältnis von Konventionalität und Neuartigkeit, in dem diese Forschungsansätze SOULAVIES zu den naturwissenschaftlichen Bemühungen seiner Epoche stehen. Da die wesentlichen Aussagen eines einzelnen Forschers nur aus ihrer Einbettung in die Wissenschaft ihrer Zeit verständlich werden, erfordert auch die Bearbeitung der erstgenannten Problemstellung einen Rekurs auf den zeitgenössischen wissenschaftlichen Hintergrund. Es versteht sich von selbst, dass angesichts dieses doppelten Rückbezuges auch Licht auf die ideengeschichtlichen Wurzeln der geographischen Konzeptionen SOULAVIES fällt.

Description: thesis

Description: DFG, SUB Göttingen

Description: Der vorliegende Band 52 der Abhandlungen „Anthropogeographie“ des Instituts für Geographische Wissenschaften der Freien Universität Berlin erfasst mit 54 Beiträgen den wissenschaftlichen Forschungsstand der IGU-Kommission “Urban Development and Urban Life”. Die vorgelegten Fassungen stellen die diskutierte und revidierte Form der Beiträge dar, die während der Jahrestagung der Kommission vom 15. bis 20. August 1994 in Berlin gehalten wurden. Die Tagung selbst stand unter dem Thema “Urban Transition and Quality of Life” und forderte damit in den jeweils zwei Einführungs- und zahlreichen weiterführenden Referaten der drei Arbeitsthemen 1) “Restructuring Urban Systems in Central and Eastern Europe“, 2) “Unemployment and Informal Economy in Cities” und 3) “Urban Identity, City Image and Urban Marketing” zu Bewertungen des Forschungsstandes bzw. kritischen Stellungnahmen durch aktuelle Forschungen heraus.

Description: 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0004.pdf"〉Titelseite〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0005.pdf"〉Titelseite〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0006.pdf"〉Vorwort〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0007.pdf"〉Foreword〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0008.pdf"〉Inhaltsverzeichnis〈/a〉〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0009.pdf"〉I. Introduction〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0010.pdf"〉Reflections Between Urban and University Structures and Planning〈/a〉〈br〉(Dietz, K., Braun, G. O.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0011.pdf"〉Berlin - Metropolis in Transition: The State of Urban Development in 1994〈/a〉〈br〉(Ellger, C.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0014.pdf"〉Planning for the Future of Berlin〈/a〉〈br〉(Branoner, W.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0016.pdf"〉Strategic Planning in Berlin〈/a〉〈br〉(Braun, G. O.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0019.pdf"〉Change in the Urban Structure in the Five New Länder: The Example of Eisenach〈/a〉〈br〉(Cassel, M., Schwaderer, G.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0021.pdf"〉II. Restructuring of Inter- and Intra-Urban Systems〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0022.pdf"〉Questions on Hierarchical Change in Urban Systems in Eastern and Central Europe〈/a〉〈br〉(Rey, V.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0026.pdf"〉Urban and Urban System Development in Central and Eastern Europe〈/a〉〈br〉(Grimm, F.-D., Taege, G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0030.pdf"〉The Impact of Recent Socio-Political and Economic Changes on the Development of Slovenian Towns〈/a〉〈br〉(Pak, M.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0033.pdf"〉An Urban Evolution Model Applied to Romania's Towns〈/a〉〈br〉(Ianos, I.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0038.pdf"〉Warsaw: Development Problems and Strategies〈/a〉〈br〉(Korcelli, P., Potrykowska, A., Weclawowicz, G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0039.pdf"〉The Urban System and Emerging Structure: An Application of Gibb's Measure to the Case of India〈/a〉〈br〉(Mookherjee, D.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0041.pdf"〉Reorganisation of the Urban System in Sri Lanka〈/a〉〈br〉(Wanasinghe, D. S.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0046.pdf"〉The Formation of an European Urban System〈/a〉〈br〉(Rozenblat, C., Pumain, D.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0051.pdf"〉On the Impact of Internationalization Process on the Finnish Settlement System〈/a〉〈br〉(Palomäki, M.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0055.pdf"〉Global Perspective of Seoul as a World City in the Region of Pacific Rims〈/a〉〈br〉(Kim, I.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0057.pdf"〉Urban Systems Dynamics: Evidence for the Toronto Urban System: 1930-1991〈/a〉〈br〉(Preston, R. E.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0060.pdf"〉The Growth of Toronto: A Market-Share Approach〈/a〉〈br〉(Simmons, J.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0064.pdf"〉Industrial Restructuring and Urban Development: An Examination in Metropolitan Detroit〈/a〉〈br〉(Sinclair, R.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0067.pdf"〉Counter-Urbanization in Perspective: Images and Reality in Settlement System Change〈/a〉〈br〉(Davies, W.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0069.pdf"〉Urban Region as a Geoeconomic and Geopolitical Unit in "A Europe of Regions"〈/a〉〈br〉(Vartiainen, P.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0070.pdf"〉The Ethnic and Social Division of a World City: The Case of London〈/a〉〈br〉(Petsimeris, P.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0075.pdf"〉Transformation in the South African Apartheid City – Residential Desegregation in Pietersburg: A Case Study〈/a〉〈br〉(Donaldson, S. E., Kotze, N. J.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0078.pdf"〉Intra-Urban Distribution of Ethnic Minorities in Munich and Duisburg〈/a〉〈br〉(Yamamoto, K.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0083.pdf"〉New Urban Poverty in the Basque Country and Navarra〈/a〉〈br〉(Ferrer, M., d’Entremont, A., Ciscar, I., Saracibar, M. A.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0085.pdf"〉Polarization and the Dutch Welfare State. The Case of Amsterdam〈/a〉〈br〉(Ostendorf, W., Musterd, S.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0088.pdf"〉III. Informal Economy〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0089.pdf"〉The Labour Market and the Role of Informality in Urban Mexico〈/a〉〈br〉(Aguilar, A. G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0092.pdf"〉The Informal Economy in Chinese Cities〈/a〉〈br〉(Qi, S. D.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0093.pdf"〉The Urban Informal Sector: A Third World Experience〈/a〉〈br〉(Geeta Reddy, A., Rajkumar, G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0094.pdf"〉Informal Urban Economy in the Lake Chad Basin〈/a〉〈br〉(Simeu-Kamdem, M.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0095.pdf"〉IV. Recent Urban Processes〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0096.pdf"〉City Challenge: Involving the Community in UK Urban Policy? 〈/a〉〈br〉(Lewis, J. R.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0098.pdf"〉Intra-Metropolitan Relocation of Work Places: The Case of Stockholm〈/a〉〈br〉(Mahieu, R.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0102.pdf"〉Problems of Mobility and Traffic in the Ruhr〈/a〉〈br〉(Lötscher, L., Fleisgarten, S.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0103.pdf"〉Moscow 1993: The Emergence of Housing Market and the Problems of Intra-Urban Segregation〈/a〉〈br〉(Vendina, O. I.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0107.pdf"〉V. Urban Marketing, City Management, Urban Identity〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0108.pdf"〉Urban Marketing: A Review〈/a〉〈br〉(Borchert, J. G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0109.pdf"〉Urban Identity, City Image and Urban Marketing〈/a〉〈br〉(Dematteis, G.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0110.pdf"〉The Hidden Faces of the City〈/a〉〈br〉(Racine, J.-B.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0111.pdf"〉The City of Bergen. Image and Marketing〈/a〉〈br〉(Sjøholt, P.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0113.pdf"〉Structural Underpinnings of an Olympic City Bid〈/a〉〈br〉(Davies, R. J.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0116.pdf"〉Double Cities: Identity and Marketing of a New Urban Product〈/a〉〈br〉(Buursink, J.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0118.pdf"〉Corporate Space and Emerging Spatial Order in Japan〈/a〉〈br〉(Fujita, N.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0125.pdf"〉The Development of International Tourism in Tallinn, Estonia〈/a〉〈br〉(Kuus, M.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0126.pdf"〉Conflict, Consent, Cooperation: Comprehensive Planning in Germany Beyond Market and State〈/a〉〈br〉(Helbrecht, I.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0127.pdf"〉Urban Strategies: Mega Events. A Copenhagen Perspective〈/a〉〈br〉(Thor Andersen, H., Wichmann Matthiessen, C.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0129.pdf"〉From Spaces of Planning to Places of Resistance〈/a〉〈br〉(Haarni, T.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0132.pdf"〉VI. Re-Cycling Urban Landscape〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0133.pdf"〉The Role of Gentrification in the Changing Ecology of Income: Evidence From Canadian Cities and Implications for Further Research〈/a〉〈br〉(Bourne, L. S.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0134.pdf"〉Gentrification and the Youth Movements of the 1960s〈/a〉〈br〉(Ley, D.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0135.pdf"〉Recycling Urban Landscapes - Beyond the Power〈/a〉〈br〉(Andersson, H.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0136.pdf"〉Why was the Central City Population Stabilized? The Case of Copenhagen〈/a〉〈br〉(Illeris, S.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0138.pdf"〉Toronto's Underground City: Excavating the Terms of Access〈/a〉〈br〉(Hopkins, J.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0140.pdf"〉The Interpretation of Sea in Urban Planning and Everyday Life: The Case of Helsinki〈/a〉〈br〉(Karvinen, M.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0141.pdf"〉Urban Destinies - What are the Trends?〈/a〉〈br〉(Wärneryd, O.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0142.pdf"〉VII. Urban Modelling〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0143.pdf"〉DUVA – A Concept for a Metadata Driven Statistical Production and Information System〈/a〉〈br〉(Kopp, N.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0145.pdf"〉A New Era for Urban Modelling?〈/a〉〈br〉(Pumain, D.)〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0146.pdf"〉Competing Order Parameters in a Self-Organizing City〈/a〉〈br〉(Portugali, J., Benenson, I.)〈/li〉 〈/body〉 〈/html〉 〈br〉 〈html〉 〈body〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0150.pdf"〉Authors and Addresses〈/a〉〈/li〉 〈li〉〈a href="https://gdz.sub.uni-goettingen.de/download/pdf/PPN1030505985/LOG_0151.pdf"〉[Werbung]〈/a〉〈/li〉 〈/body〉 〈/html〉

Description: conference

Description: DFG, SUB Göttingen

Description: Since the 14th century, moderate seismic activity with 14 earthquakes of magnitude MW≥5.0 occurred in Western Europe in a region extending from the Lower Rhine Graben (LRG) to the southern North Sea. In this paper, we investigate how well this seismic activity could reflect that of the future. The observed earthquake activity in the LRG is continuous and concentrates on the Quaternary normal faults delimiting the LRG, which are also the source of large surface rupturing Holocene and Late Pleistocene earthquakes. The estimated magnitudes of these past earthquakes range from 6.3±0.3 to 7.0±0.3 while their average recurrence on individual faults varies from ten thousand to a few ten thousand years, which makes foreseeing future activity over the long-term possible. Three of the largest historical earthquakes with MW≥5.5 occurred outside the LRG. Late Quaternary activity along the fault zones suspected to be the source of two of these earthquakes, i.e. the 1580 Strait of Dover and 1692 northern Belgian Ardennes earthquakes, is very elusive if it exists. Hence, similar earthquakes would be very infrequent at these locations suggesting that the seismicity outside of the LRG would be episodic and clustered on some faults during periods of a few hundreds of years interrupted by long periods of inactivity typically lasting for some tens to hundreds of thousand years. Seismic moment release estimation and its comparison between recent geological and historical seismicity periods lead us to suggest that the high seismicity level observed between AD 1350 and AD 1700 west of the LRG would be uncommon.

Description: research

Description: In the weekly newspaper of Osnabrück (Germany) of November 3, 1770, a report about a local earthquake was published. Pastor Buck described ground motion effects in the manor ‘Haus Horst’, 1.5 km away from the village of Alfhausen: ‘roof tiles rattled, a chimney fell down, inside the house the top of a stove was overturned, abraded chalk trickled down in all rooms; in the nearby villages, people felt the shaking, and especially the churches suffered noticeably’. The epicentral intensity was estimated to VII (MSK) by Ahorner et al. (1970), but later modified to VI (EMS) by Meier & Grünthal (1992) considering Buck’s report in detail. Since this event is the only documented earthquake in this region, a reliable characterization of its parameters is important. Our re-examination reveals that some reported effects are quite contradictory. Contrary to Buck’s statement, no documents of damages on churches or costs of repairs could be found in the parish registers. As a result, the event appears to be a tectonic earthquake with an epicenter at Alfhausen / Haus Horst. Applying intensity-attenuation relationships, a revised value of the epicentral intensity of I_0≤V (EMS-98) with a focal depth of z≥2 km was derived. A cavity collapse due to leaching processes as a cause of the effects can be ruled out here. However, several details given in the primary source turned out to be unrealistic or at least exaggerated. The tectonic earthquake on September 3, 1770 near Alfhausen should be classified therefore as uncertain or even doubtful.

Description: research

Description: Central Europe is an intraplate domain which is characterized by low to moderate seismicity with records of larger seismic events occurring in historical and recent times. These records of seismicity are restricted to just over one thousand years. This does not reflect the long seismic cycles in Central Europe which are expected to be in the order of tens of thousands of years. Therefore, we have developed a paleoseismic database (PalSeisDB) that documents the records of paleoseismic evidence (trenches, soft-sediment deformation, mass movements, etc.) and extends the earthquake record to at least one seismic cycle. It is intended to serve as one important basis for future seismic hazard assessments. In the compilation of PalSeisDB, paleoseismic evidence features are documented at 129 different locations in the area of Germany and adjacent regions.

Description: research

Description: Current procedures to collect macroseismic data in Germany are diverse and scattered. At least 10 institutions collect macroseismic data by internet. Several institutes have a long tradition in seismology and have collected macroseismic data using paper forms for many decades. In addition, the responsibilities for geoscientific issues in Germany are a matter of the federal states and several of them have a state earthquake service. The only institution that automatically calculates and maps intensities online in near real time is Erdbebenstation Bensberg in cooperation with the Royal Observatory of Belgium. Baden-Württemberg uses a short form internet questionnaire at the moment. 5 state earthquake services (Bayern, Hessen, Niedersachsen, Rheinland-Pfalz, Sachsen) have implemented the standard German earthquake questionnaire (Kaiser 2014) which is adapted from the standard questionnaire developed by the ESC Working Group on Internet Macroseismology published by Musson & Cecić (2012). Most institutions express their strong need to implement standard procedures for automatic intensity assignment and a standard format for the exchange of questionnaire responses. References Kaiser, D. (2014): Der neue einheitliche Erdbeben-Fragebogen. Mitteilungen / Deutsche Geophysikalische Gesellschaft, 2/2014, 29-33. Musson, R. M. W. & Cecić, I. (2012): Intensity and Intensity Scales. In: New Manual of Seismological Observatory Practice 2 (NMSOP-2).- Deutsches GeoForschungsZentrum GFZ, 1-41; Potsdam. doi:10.2312/GFZ.NMSOP-2_ch12

Description: lecture

Description: We develop empirical relationships between the surface wave magnitude MS and macroseismic data, i.e. the epicentral intensity I0, isoseismal radii R(I) of different intensities I and the focal depth h. The basis of this study is formed by carefully selected instrumental parts (since 1900) of 2 earthquake catalogues: Kárník 1996 (Europe and the Mediterranean), and Shebalin et al. 1998 (Central and Eastern Europe). We use the orthogonal regression because we presume that all parameters are in error and because it has the advantage to provide a reversible regression equation. From Shebalin et al.1998 catalogue we obtain MS = 0.65 I0 + 1.90 log(h) – 1.62 with equivalent error δMS = ±0.21. In order to establish a relationship between MS and isoseismal radii we apply a theoretically based model which takes into account both exponential decay and geometrical spreading. From Shebalin et al. 1998catalogue we find MS = 0.673 I + 2.44 log (S(I)) + 0.00163 S(I) – 2.48 with δMS = ±0.28. Here I is the macroseismic intensity (I = 3…9) of the isoseismal in the focal distance S(I) [km]. Kárník 1996 gives isoseismal radii for I = 3 and 5. We obtain: MS = 0.808 I + 2.84 log (S(I)) + 0.00190 S(I) – 3.71 with δMS = ±0.65. These equations make possible reliably estimates of MS . We recommend them for application. The use of high quality data only as input in the regression analysis provides reliable relationships to estimate magnitudes. The magnitude estimation of a historical earthquake from the epicentral intensity gives reliable results only if the focal depth is known well enough. The relationship using isoseismal radii is of greater practical importance as it allows more reliable magnitude estimations of historical earthquakes. We observe regional variations in the relationships which need further investigation.

Description: poster

Description: The earthquake catalogue of southwestern Germany for the last millennium now contains about 30,000 digital macroseismic intensity data points (IDPs). Intensity assessments are based mainly on primary sources using the European Macroseismic Scale 1998 (EMS). The article describes a guideline for best practice of conventional macroseismic evaluation in application to historical and modern-time earthquakes in SW-Germany. Suitability of various diagnostics for intensity assessment is discussed. Assumptions to estimate damage grades and vulnerability classes of buildings are presented. Data restrictions and treatment of special cases are outlined. Further topics are quantification of uncertainties and IDP quality as well as substitutes for intensity. An essential task is to bridge the gap between information from historical sources and seismological needs for use in the earthquake catalogue, thus all issues have a focus on historical earthquakes. Questions of completeness, subjectivity, transparency, and interdisciplinary work are addressed also. Special emphasis is given to a well balanced use of the EMS scale throughout all time periods leading to consistent assessments in the catalogue.

Description: research

Description: Considering the importance of migration research and the dearth in literature on migration, the following study has been done, with the intention of examining the complex interrelation between internal migration and the development process in Bangladesh. Thereby, emphasis has been given to the investigation and analysis of the causes of rural-urban migration and its spatial as well as socioeconomic consequences, with examples from Dhaka. To construct a framework for the present study, some consideration has been given to both theoretical as well as empirical studies on internal migration. The discussion of general theories which follows in the next section, has mainly been done to assess the validity of these in the analysis of internal migration in the Third World countries.

Description: research

Description: DFG, SUB Göttingen

Description: Induced earthquakes are of public concern and of legal significance if they are felt or if they cause damage. Models to describe the relation between macroseismic intensities, magnitude, and distance from the epicenter or hypocenter are therefore of fundamental importance. With the aim of developing such models for induced earthquakes in Germany, the following data were analyzed: The earthquake database for Germany GERSEIS contains parameters for ~180 induced seismic events with information on magnitude M and intensity I, of which 47 include information on mean isoseismal radii. In addition, the published macroseismic maps of seismic events in mining areas in Germany were evaluated. In Germany, earthquakes caused by mining with moderate to severe building damage (intensity 7 and 8) have so far only occurred in potash and salt mining. Slight building damage (intensity 6) has also been caused by seismic events in coal mining. Over the past 20 years, the frequency of felt earthquakes has increased in regions with natural gas production and in recent years also in regions of deep geothermal energy production. Focal depths show a large influence on the relationship between M and I. Intensity 5 has been observed for shallow (~1 km depth) events with magnitudes as small as ML=1.8. Simple models of the form I = a + b M + c log R, with R = hypocentral distance, can be fitted to the observations. Models for tectonic earthquakes do not fit for induced earthquakes; for induced earthquakes I is smaller for a given M and R. Major differences were found between different mining areas: In natural gas production areas intensity 5 effects were observed at greater hypocentral distances for a given magnitude, compared to coal and potash mining areas. Since macroseismic data (especially intensity data points) in Germany are available almost exclusively in analog form and are often difficult to access, it is necessary to establish a database for induced earthquakes with macroseismic data.

Description: research

Description: Apart from the traditional contribution of geographers to the study of population, this particular thesis attempts to divert the emphasis of geographical enquiry towards the examination of how particular innovations affect the population distribution and the organization of human society. It deals specifically with questions concerning the demographic, social and economic impact of population mobility on both sending in receiving areas. It attempts to shed light on the different variables that work to produce a selective type of population mobility within a particular socio—economic set-up. Although various aspects of population mobility have been studied in some detail during the present decade, no attempt has been made, however, towards a concrete presentation of its multiple causes and its socio-economic impact on the areas and people that are left behind. Far from assuming complete coverage of all interrelated fields of study we attempt here to draw attention t0 the expected socio-economic repercussions of population mobility as induced by a particular factor, namely agricultural mechanization. Certain limitations‚ however, have made it difficult to deal with every aspect of population mobility in the Sudan.

Description: thesis

Description: DFG, SUB Göttingen

Description: Jede Gesellschaft (und jede Stadtregion) muss auf die Auswirkungen dieser Transformation (erhöhte Wohnraumnachfrage, schnelles Wirtschaftswachstum, starkes Dezentralisierungspotential neuer Technologien, drohender Bedeutungsverlust der Kernstadt) reagieren. Wir betrachten im Rahmen dieser Arbeit räumliche Entwicklungen als "kulturelle“ Antwort auf solche Veränderungen. Denn während der ökonomische und technologische Wandel ein eher universelles Phänomen darstellt, unterscheiden sich doch die Strategien zur räumlichen Handhabung und Gestaltung von Wachstum von Land zu Land enorm. So gesehen ist die uns umgebende Realität von Suburbanisierung und Dezentralisierung eben auch das Resultat von Entscheidungen, die unter spezifischen politischen und ideologischen Bedingungen getroffen worden sind. Für die Analyse der Wachstumsideologien haben wir drei westliche Industriestaaten ausgewählt: Kanada, die USA und die Bundesrepublik Deutschland. Dabei wurden sowohl die lokale bzw. regionale als auch die Ländern Provinz- bzw. Bundesebene untersucht. Für die lokale Ebene wurden Flächennutzungsmaßnahmen und statistische Wachstumsindikatoren von sechs "Fallbeispielen" analysiert und verglichen: Frankfurt/M.‚ München, Toronto, Vancouver, San Francisco und Los Angeles/San Diego. Für die überregionale Ebene ergänzt ein Vergleich staatlicher Steuerungsmaßnahmen die Analyse und Interpretation lokaler Trends.

Description: thesis

Description: DFG, SUB Göttingen

Description: This publication developed from the 5th International Colloquium on “Historical Earthquakes, Paleoseismology, Neotectonics and Seismic Hazard” which was held from 11 to 13 October 2017 at the Federal Institute for Geosciences and Natural Resources (BGR) in Hannover, Germany. It comprises four contributions: Brüstle, W., Braumann, U., Hock, S. & Rodler, F.-A. (2020). Best practice of macroseismic intensity assessment applied to the earthquake catalogue of southwestern Germany. In: Kaiser, D. (Ed.). Historical Earthquakes, Paleoseismology, Neotectonics, and Seismic Hazard: New Insights and Suggested Procedures, DGEB-Publikation 18, Deutsche Gesellschaft für Erdbebeningenieurwesen und Baudynamik. doi: 10.23689/fidgeo-3864 Camelbeeck, T., Vanneste, K., Verbeeck, K., Garcia-Moreno, D., Van Noten, K. & Lecocq, T. (2020). How well does known seismicity between the Lower Rhine Graben and southern North Sea reflect future earthquake activity? In: Kaiser, D. (Ed.). Historical Earthquakes, Paleoseismology, Neotectonics, and Seismic Hazard: New Insights and Suggested Procedures, DGEB-Publikation 18, Deutsche Gesellschaft für Erdbebeningenieurwesen und Baudynamik. doi: 10.23689/fidgeo-3866 Hürtgen, J., Reicherter, K., Spies, T., Geisler, C. & Schlittenhardt, J. (2020). The Paleoseismic Database of Germany and Adjacent Regions PalSeisDB v1.0. In: Kaiser, D. (Ed.). Historical Earthquakes, Paleoseismology, Neotectonics, and Seismic Hazard: New Insights and Suggested Procedures, DGEB-Publikation 18, Deutsche Gesellschaft für Erdbebeningenieurwesen und Baudynamik. doi: 10.23689/fidgeo-3867 Leydecker, G. & Lehmann, K. (2020). The earthquake of September 3, 1770 near Alfhausen (Lower Saxony, Germany): a real, doubtful, or a fake event? In: Kaiser, D. (Ed.). Historical Earthquakes, Paleoseismology, Neotectonics, and Seismic Hazard: New Insights and Suggested Procedures, DGEB-Publikation 18, Deutsche Gesellschaft für Erdbebeningenieurwesen und Baudynamik. doi: 10.23689/fidgeo-3865

Description: Introduction to DGEB-Publikation Nr. 18 Deutsche Gesellschaft für Erdbebeningenieurwesen und Baudynamik (DGEB)

Description: editorial

Description: Ba zonation patterns in sanidine phenocrysts from mafic and intermediate phonolite and crystal-rich cumulates from the Laacher See volcano (12.9 ka) in western Germany document diffusion times suggestive of periodic recharge events throughout the magma reservoir’s entire lifespan of ~ 24 ky. Phenocrysts analysed from samples that formed late at the base of the compositionally zoned magma reservoir by mixing and mingling between a resident phonolite magma and recharging basanite show resorption and thin (2–10 μm) late-stage Ba-rich overgrowth. Short diffusion profiles across these boundaries give diffusion times of ~ 1.5–3 years at most, which are interpreted to be the maximum duration between the most recent recharge by the basanite and eruption. The lack of such late overgrowth in samples from other parts of the phonolite reservoir suggests that effect of this mixing and mingling was limited to the crystal-rich base. Sanidines in the cumulates, by contrast, are generally devoid of zoned crystals. Only rare cumulate crystals with resorbed outer boundaries and very thin overgrowths (a few microns) with very sharp compositional changes imply the remobilization of cumulates only months before eruption. Based on the diffusion timescales and storage temperatures obtained in a previous study, we present a genetic model for the conditions and timing of storage and (re-)activation of the magma system prior to the eruption of Laacher See, which is the largest volcanic event in Central Europe since the last glaciation.

Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655

Description: Tree roots penetrate the soil to several meters depth, but the role of subsoils for the supply of nutrient elements such as phosphorus (P) to the trees is poorly understood. Here, we tested the hypothesis that increased P deficiency in the topsoil results in an increased microbial recycling of P from the forest subsoil. We sampled soils from four German temperate forest sites representing a gradient in total P stocks. We analyzed the oxygen isotopic composition of HCl-extractable phosphate (δ18OP) and identified differences in P speciation with increasing soil depth using X-ray absorption near-edge structure (XANES) spectroscopy. We further determined microbial oxygen demand with and without nutrient supply at different soil depths to analyse nutrient limitation of microbial growth and used nanoscale secondary ion mass spectrometry (NanoSIMS) to visualize spatial P gradients in the rhizosphere. We found that δ18OP values in the topsoil of all sites were close to the isotopic signal imparted by biological cycling when oxygen isotopes in phosphate are exchanged by enzymatic activity. However, with increasing soil depth and increasing HCl-P concentrations, δ18Ο values continuously decreased towards values expected for primary minerals in parent material at depths below 60 cm at sites with high subsoil P stocks and below more than 2 m at sites with low subsoil P stocks, respectively. For these depths, XANES spectra also indicated the presence of apatite. NanoSIMS images showed an enrichment of P in the rhizosphere in the topsoil of a site with high P stocks, while this P enrichment was absent at a site with low P stocks and in both subsoils. Addition of C, N and P alone or in combination revealed that microbial activity in subsoils of sites with low P stocks was mostly P limited, whereas sites with high P stocks indicated N limitation or N and P co-limitation. We conclude that subsoil P resources are recycled by trees and soil microorganisms. With continued weathering of the bedrock and mobilisation of P from the weathered rocks, P cycling will proceed to greater depths, especially at sites characterised by P limitation.

Description: Rheinische Friedrich-Wilhelms-Universität Bonn (1040)

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: Rheinische Friedrich-Wilhelms-Universität Bonn (1040)

Description: The reported partition coefficients of REE with calcite are reviewed and critically discussed. In some of the reported experimental sets, REE concentrations are found to be supersaturated with respect to individual REE2(CO3)3 but never to REE(OH)3. Although the solutions are unsaturated with respect to individual REY carbonates, REY including Y are incorporated in calcite surfaces, where they are overgrown by calcite. Charge balances may be obtained by building {REY–Na-(CO3)2}n or by exchange of 2Ca2+ against REY3+ + blank space calcite lattice. These surface compounds may either be homogeneously distributed or clustered. Both the size and frequency of clusters increase with [REY]/[Ca] or [ΣREY3+]/[Ca2+] in solution. If these surface precipitates are removed into solutions saturated with respect to ΣREE2(CO3)3, they start growing in the aqueous phase. In this case, the apparent DREY and kREY values decrease with increasing REY concentrations in solution. In previous studies, only the individual distribution coefficients are reported not considering that the entirety of REY determines their behavior in partitioning. Given enough time, these surface clusters equilibrate with the aqueous phase before being overgrown by calcite. In the double logarithmic plots of {REY}/{Ca} versus [REY]/[Ca] or [REY3+]/[Ca2+], two relationships evolve characterizing the REY distribution in marine calcite and experimental calcites grown in Mg2+-free solutions. The double logarithmic plots of partition coefficients of REYi3+ in calcite grown from seawater show a slope exceeding unity, whereas those from fluids without Mg2+ depict slopes less than unity being both in contrast to the Henderson–Kracek rule.

Description: Coastal waters have strong gradients in dissolved organic matter (DOM) quantity and characteristics, originating from terrestrial inputs and autochthonous production. Enclosed seas with high freshwater input therefore experience high DOM concentrations and gradients from freshwater sources to more saline waters. The brackish Baltic Sea experiences such salinity gradients from east to west and from river mouths to the open sea. Furthermore, the catchment areas of the Baltic Sea are very diverse and vary from sparsely populated northern areas to densely populated southern zones. Coastal systems vary from enclosed or open bays, estuaries, fjords, archipelagos and lagoons where the residence time of DOM at these sites varies and may control the extent to which organic matter is biologically, chemically or physically modified or simply diluted with transport off-shore. Data of DOM with simultaneous measurements of dissolved organic (DO) nitrogen (N), carbon (C) and phosphorus (P) across a range of contrasting coastal systems are scarce. Here we present data from the Roskilde Fjord, Vistula and Öre estuaries and Curonian Lagoon; four coastal systems with large differences in salinity, nutrient concentrations, freshwater inflow and catchment characteristics. The C:N:P ratios of DOM of our data, despite high variability, show site specific significant differences resulting largely from differences residence time. Microbial processes seemed to have minor effects, and only in spring did uptake of DON in the Vistula and Öre estuaries take place and not at the other sites or seasons. Resuspension from sediments impacts bottom waters and the entire shallow water column in the Curonian Lagoon. Finally, our data combined with published data show that land use in the catchments seems to impact the DOC:DON and DOC:DOP ratios of the tributaries most.

Description: Academy of Sciences of Finland

Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659

Description: BONUS COCOA and Bundesministerium für Bildung und Forschung

Description: Academy of Finland

Description: Danish Research Council for Independent Research

Description: BONUS COCOA Project

Description: Leibniz-Institut für Ostseeforschung Warnemünde (IOW) (3484)

Description: Significant sedimentation of manganese (Mn) in form of manganese oxides (MnOx) and the subsequent formation of authigenic calcium-rich rhodochrosite (Mn(Ca)CO3) were observed in the seasonally stratified hard water Lake Stechlin in north-eastern Germany. This manganese enrichment was assumed to be associated with recent eutrophication of the formerly oligotrophic lake. The mechanisms and processes involved were examined by analysing: (i) short sediment cores obtained from seven locations along a depth transect ranging from 69.5 m (the deepest point) to 38 m; (ii) sediment traps located at 20 m and 60 m water depths; (iii) water column profiles; and (iv) porewater profiles at 69.5 m and 58 m depths. Sedimentary Mn enrichment was observed at water depths below 56 m and increased to more than 25 wt% at the deepest site. Between 2010 and 2017, Mn accumulation at the deepest site was 815 g Mn m−2. Transfer of Mn from the shallower towards the deepest parts of the lake was initiated by reductive dissolution of MnOx and diffusion of dissolved Mn from the sediment to the overlying water column. Manganese was then dissipated via turbulent mixing and subsequently oxidised to MnOx before being transported towards the deepest zone. Transformation of the redeposited MnOx to Mn(Ca)CO3 favoured the final burial of Mn. We show that eutrophication and the areal spreading of anoxic conditions may intensify diagenetic processes and cause the spatial redistribution of Mn as well as its effective burial. Contrary to many previous findings, we show that increases of Mn and Mn/Fe can also be used as indicators for increasing anoxic conditions in previously oligotrophic lakes.

Description: Leibniz-Gemeinschaft http://dx.doi.org/10.13039/501100001664

Description: Leibniz-Institut für Gewässerökologie und Binnenfischerei (IGB) im Forschungsverbund Berlin e.V. (3473)

Description: Purpose: Sb is a metalloid that naturally occurs in traces in the Northern German Lowland Area, only. Its frequent and still growing demand for industrial purposes and its release during coal combustion and by vehicular emissions lead to an enrichment of Sb in topsoils. Numerous analyses on heavy metals have been conducted in the urban environment so far, but although Sb can be ecologically harmful and potentially carcinogenic, only few studies on Sb in soils were carried out.

Description: Materials and methods: Due to the formation of anthropogenic soils by men, especially in the course of industrialization and after World War II, more than 50% of the Berlin soils consist of anthropogenic material like redeposited natural material, debris, waste, or ashes. This composition of soils of the Berlin Metropolitan Area can function as a model for other metropolitan regions of Central Europe. In the urban and peri-urban area of Berlin, analysis of more than 900 topsoil samples has been performed measuring the content of 12 heavy metals and metalloids (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sb, and Zn). As a reference for the natural environment, soil profiles of typical parent rock material have been investigated taking also the regional (0.3 mg/kg), the local background value (0.61 mg/kg), and the baseline value (0.07 mg/kg) for Sb into account.

Description: Results: By doing so, we could show the spatial distributional pattern of Sb in the Berlin Metropolitan Area and statistically evaluate our results in dependency of land-use, parent material, and soil parameters such as organic carbon content and pH. Thereby, we could prove an average enrichment two to six times over the regional background value. Median Sb content is very low in forest topsoils (0.54 mg/kg) and reaches its maximum in roadside soils (1.75 mg/kg). Technogenic materials, vehicular emissions, industrial processes, and (former) land-use are the predominant factors for Sb enrichment and distribution in the study area. Some single samples show an enrichment of up to 600% of the regional background value for topsoils.

Description: Conclusion: Our study revealed that the Sb content in the Berlin Metropolitan Area is elevated compared to natural environments. Furthermore, we could demonstrate that Sb is a previously neglected key pollutant, specific to metropolitan areas. Due to the high environmental relevance, further Sb data from selected investigated spaces in other metropolises and specific land-use types are needed to assess the potential environmental risk of Sb in metropolitan areas.

Description: Humboldt-Universität zu Berlin (1034)

Description: Purpose: To understand the impact of geochemical sedimentation history for arsenic (As) distribution in the sediment profiles of the Hetao Basin, we (1) evaluated sediments provenance and variations of weathering intensities, (2) attempted to reconstruct the depositional environments, and (3) explored the As and Fe speciation in the sediments. Combining the information above, different sedimentation facies were distinguished in the vertical profiles.

Description: Methods: Two sediments cores were drilled up to 80 m depth. Major and trace element compositions, including rare earth elements (REE), were analyzed. Carbon isotope ratios (δ13Corg) of embedded organic matter in the sediments were analyzed by isotope ratio mass spectrometry (IR-MS). Arsenic and Fe speciation of the sediments were determined by sequential extractions.

Description: Results and discussion: The similar REE geochemistry of rocks from the Lang Mountains and sediments in the Hetao Basin indicated that the sediments originated from the Lang Mountains. The C/N ratio (~ 4 to ~ 10) in combination with δ13Corg (− 27‰ to −2 4‰) suggested that sediments were mainly deposited in aquatic environments. The unconfined aquifer equaled the lacustrine deposit with less intensive weathering during last glacial maximum (LGM). Here, the As content (average, 5.4 mg kg−1) was higher than in the aquifer sediments below (average, 3.6 mg kg−1).

Description: Conclusion: Higher content of releasable As in combination with paleolake-derived organic matter aquifer sediments probably contributes to higher groundwater As concentration in the unconfined aquifer. This study provides the first insight into the impact of sedimentation history on As distributions in sediment profiles in the Hetao Basin.

Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543

Description: Mass fractions of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl were determined via isotope dilution quadrupole ICP-MS in twenty-one geological reference materials (RMs) and the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3). The RMs comprise basaltic/mafic (BCR-2, BE-N, BHVO-1, BHVO-2, BIR-1, BRP-1, JB-2, OKUM, W-2, WS-E), intermediate/felsic (AGV-2, G-2, JA-2, RGM-1), ultramafic (DTS-2b, MUH-1, PCC-1, UB-N) and sedimentary (MAG-1, OU-6) rocks. Pressure digestion was applied for nonbasaltic samples to ensure effective sample digestion. For basaltic RMs, hot plate digestion was found to be sufficient for a quantitative recovery of the target elements. To minimise interferences and increase ion beam intensities during isotope ratio analyses by ICP-MS, separation of the target elements was carried out from single sample aliquots using a novel anion exchange procedure. The intermediate precision (2s) estimated from two to four replicate analyses was usually 〈 4% and results are in agreement with literature data, where available. Especially for Ag and Tl, the intermediate precision was compromised, likely due to low ion beam intensities and, hence, higher background and blank contributions. For ultramafic RMs, nugget effects and incomplete digestion might compromise the intermediate precision. Results for the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3) agree well with previously reported data.

Description: Dieser Band enthält 42 Beiträge zu Themengebieten der Physik der festen Erde, des magnetischen und elektrischen Felds der Erde, der Physik der Atmophäre und der angewandten Geophysik, veröffentlicht durch die Deutsche Geophysikalische Gesellschaft in dem Jahr 1937.