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  • 1
    Publication Date: 2021-03-29
    Description: In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a 〉10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.
    Keywords: Fluid/rock interaction; Elemental transfer; Isotopic fractionation; Subduction and exhumation; Sulu ; 551 ; Earth Sciences; Mineralogy; Mineral Resources; Geology
    Language: English
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  • 2
    Publication Date: 2021-03-29
    Description: The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeirão Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeirão Neisse (arkosic sandstones and siltites), and Ribeirão do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, São Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaquã Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.
    Keywords: Dom Feliciano Belt; Ediacaran; Foreland basin; U–Pb SHRIMP ages; Provenance ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 3
    Publication Date: 2021-03-29
    Description: Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.
    Keywords: Sandstones; Pore space; Prediction; Weathering behavior; Compressive strength ; 551 ; Earth Sciences; Geology
    Language: English
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  • 4
    Publication Date: 2021-03-29
    Description: The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.
    Keywords: Neutron diffraction; Lattice-preferred orientation; Shape-preferred orientation; Magmatic flow; Podlesí granite; Meissen Massif ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 5
    Publication Date: 2021-03-29
    Description: The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580–510 Ma) Pampean, the late Cambrian–Ordovician (500–440 Ma) Famatinian and the Devonian-Carboniferous (400–350 Ma) Achalian orogenies. Geochronological and Sm–Nd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm–Nd results for the metamorphic basement suggest that the TDM age interval of 1.8–1.7 Ga, which is associated with the less radiogenic values of εNd(540) (−6 to −8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger TDM age and a more positive εNd(540) value. Pampean pre-540 Ma granitoids form two clusters, one with TDM ages between 2.0 and 1.75 Ga and another between 1.6 and 1.5 Ga. Pampean post-540 Ma granitoids exhibit more homogenous TDM ages ranging from 2.0 to 1.75 Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. TDM values for the Ordovician Famatinian granitoids define a main interval of 1.8–1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger TDM ages ranging from 1.3 to 1.0 Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic εNd(540) values that range between 0.5 and −4 and TDM ages younger than 1.3 Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.
    Keywords: Magmatism-metamorphism; Sm–Nd systematics; Tectonic evolution; Neoproterozoic-early Paleozoic orogenies; Eastern Sierras Pampeanas ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 6
    Publication Date: 2021-03-29
    Description: The expansion processes that develop in building stones upon changes of moisture content may be an important contributing factor for their deteriorations. Until recently, few data could be found in the literature concerning this parameter and weathering processes. Moreover, the processes that may be responsible for the moisture related expansion of natural building stones are not yet completely understood. To further elucidate this process, extensive mineralogical, petrophysical and fabric investigations were performed on eight German sandstones in order to obtain more information regarding the weathering process and its dependence on the rock fabric. The analysed sandstones show a wide range of pore size distributions and porosities. A positive correlation with the fabric and the pore space can be found for all studied petrophysical parameters. The intensity of the expansion and related swelling pressure cannot be attributed only to the swelling of clay minerals. The investigations suggest that the micropores and the resulting disjoining pressure during wet/dry cycles also play an important role. The results obtained suggest that the mechanism is related to the presence of liquid water within the porous material.
    Keywords: Sandstone weathering; Moisture expansion; Hygric and hydric wetting; Swelling clay minerals ; 551 ; Earth Sciences; Geology
    Language: English
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  • 7
    facet.materialart.
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    Springer-Verlag | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: The profitable production of dimension stone mainly depends on the extractable block size. The regularity and volume of the blocks are of critical importance, and are controlled by the three-dimensional pattern of the discontinuity system. Therefore, optimization of block size has to be the aim when quarrying for natural stone. This is mainly connected to the quantification of joints and fractures, i.e., their spacing and orientation. The problem of finding unfractured blocks within arbitrarily oriented and distributed planes can be solved effectively by a numerical algorithm. The main effects of joint orientations on block sizes and shapes will be presented in this article. Quantification of unfractured blocks with the aim of optimization is illustrated by detailed studies on several quarries. The algorithm used in this study can be applied as a powerful tool in the planning of a quarry and the future exploitation of dimension stone. Application of the described approach is demonstrated on practical examples of quarrying natural stones, namely, sandstone, granite, rhyolite, etc. Block quarrying can be optimized by using the new 3D-BlockExpert approach. The quantification of unfractured rock masses is also shown to contribute to a more ecological protection and the sustainable use of natural resources.
    Keywords: Production of dimension stones; Joints and fractures; Block sizes; Optimization ; 551 ; Earth Sciences; Geology
    Language: English
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  • 8
    Publication Date: 2021-03-29
    Description: Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.
    Keywords: Freeze–thaw action; Natural building stones; Microfabric; Pore space properties ; 551 ; Earth Sciences; Geology
    Language: English
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  • 9
    Publication Date: 2021-03-29
    Description: Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.
    Keywords: Stone decay; Cologne Cathedral; Compatibility of building materials; Requirements for replacement stones ; 551 ; Earth Sciences; Geology
    Language: English
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  • 10
    Publication Date: 2021-04-27
    Description: The range of substrates that the bone-eating marine worm Osedax is able to consume has important implications for its evolutionary history, especially its potential link to the rise of whales. Once considered a whale specialist, recent work indicates that Osedax consumes a wide range of vertebrate remains, including whale soft tissue and the bones of mammals, birds and fishes. Traces resembling those produced by living Osedax have now been recognized for the first time in Oligocene whale teeth and fish bones from deep-water strata of the Makah, Pysht and Lincoln Creek formations in western Washington State, USA. The specimens were acid etched from concretions, and details of the borehole morphology were investigated using micro-computed tomography. Together with previously published Osedax traces from this area, our results show that by Oligocene time Osedax was able to colonize the same range of vertebrate remains that it consumes today and had a similar diversity of root morphologies. This supports the view that a generalist ability to exploit vertebrate bones may be an ancestral trait of Osedax.
    Keywords: Deep-sea; Trace fossil; Osedax; Whale; Fish; Micro-CT; Tiefsee; Spurenfossil; Osedax; Wal; Fisch; Micro-CT ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 11
    Publication Date: 2021-03-29
    Description: Forests in lowland Bolivia suffer from severe deforestation caused by different types of agents and land use activities. We identify three major proximate causes of deforestation. The largest share of deforestation is attributable to the expansion of mechanized agriculture, followed by cattle ranching and small-scale agriculture. We utilize a spatially explicit multinomial logit model to analyze the determinants of each of these proximate causes of deforestation between 1992 and 2004. We substantiate the quantitative insights with a qualitative analysis of historical processes that have shaped land use patterns in the Bolivian lowlands to date. Our results suggest that the expansion of mechanized agriculture occurs mainly in response to good access to export markets, fertile soil, and intermediate rainfall conditions. Increases in small-scale agriculture are mainly associated with a humid climate, fertile soil, and proximity to local markets. Forest conversion into pastures for cattle ranching occurs mostly irrespective of environmental determinants and can mainly be explained by access to local markets. Land use restrictions, such as protected areas, seem to prevent the expansion of mechanized agriculture but have little impact on the expansion of small-scale agriculture and cattle ranching. The analysis of future deforestation trends reveals possible hotspots of future expansion for each proximate cause and specifically highlights the possible opening of new frontiers for deforestation due to mechanized agriculture. Whereas the quantitative analysis effectively elucidates the spatial patterns of recent agricultural expansion, the interpretation of long-term historic drivers reveals that the timing and quantity of forest conversion are often triggered by political interventions and historical legacies.
    Keywords: Bolivia; Amazon; Deforestation; Proximate causes; Spatial analysis; Multinomial logistic regression ; 551 ; Environment; Geology; Geography (general); Regional/Spatial Science; Climate Change; Nature Conservation; Oceanography
    Language: English
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  • 12
    facet.materialart.
    Unknown
    Springer Berlin Heidelberg | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: Characeae, a family of calcifying green algae, are common in carbonate-rich freshwaters. The southwestern shoreline of Lake Ganau (Kurdistan Region, northeastern Iraq) harbors dense and thick mats of these algae (genus Chara). On the lake bottom and along the shore, carbonate sands and rocks rich in the remains of stems, branches, nodes, and whorls of Chara are deposited. These deposits show all stages of growth and degradation of characean algae, including replacement and lithification into limestone. The replacement of the fragments by fine-grained calcite preserved delicate microstructures of Chara, such as cortical walls, cell shape, inner and outer layers of the stems, and reproductive organs. Based on roundness, sorting, the degree of lithification, and preserved microstructures of the grains (fragments), three facies were recognized. The first is represented by a newly formed lime sand facies showing elongated grains, poor sorting, and reduced roundness, with pristine preservation of characean surface microstructures. The second is a weathered lime sand facies, which shows better sorting and good roundness, whereas internal structures of characean fragments are still well preserved. The third is comprised of a lithified lime sand facies (grainstone), with very well sorted and rounded grains, and poorly preserved external and internal structures of the characeans. As compared to the newly formed lime sand facies, the grainstone facies shows an increase in grain size by more than 30 %, owing to precipitation of micritic lamina of possible microbial origin. Eventually, the Characeae-derived lime sands are lithified into oolitic limestones with sparry calcite cement, forming a grainstone microfacies. The present study has important implications for the interpretation of pre-Quaternary environments, as it records all stages of the fossilization process of characean green algae and highlights the role of these algae in the formation of oolitic carbonate rocks.
    Keywords: Characeae; Chara; Ooids; Green algae; Carbonate sand; Freshwater carbonates; Facies ; 551 ; Earth Sciences; Sedimentology; Biogeosciences; Geochemistry; Paleontology; Ecology
    Language: English
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  • 13
    Publication Date: 2021-03-29
    Description: The Mantiqueira Province represents a series of supracrustal segments of the South-American counterpart formed during the Gondwana Supercontinent agglutination. In this crustal domain, the process of escape tectonics played a conspicuous role, generating important NE–N–S-trending lineaments. The oblique component of the motions of the colliding tectonic blocks defined the transpressional character of the main suture zones: Lancinha-Itariri, Cubatão-Arcádia-Areal, Serrinha-Rio Palmital in the Ribeira Belt and Sierra Ballena-Major Gercino in the Dom Feliciano Belt. The process as a whole lasted for ca. 60 Ma, since the initial collision phase until the lateral escape phase predominantly marked by dextral and subordinate sinistral transpressional shear zones. In the Dom Feliciano Belt, southern Brazil and Uruguay, transpressional event at 630–600 Ma is recognized and in the Ribeira Belt, despite less coevally, the transpressional event occurred between 590 and 560 Ma in its northern-central portion and between ca. 625 and 595 Ma in its central-southern portion. The kinematics of several shear zones with simultaneous movement in opposite directions at their terminations is explained by the sinuosity of these lineaments in relation to a predominantly continuous westward compression.
    Keywords: Mantiqueira Province; Gondwana agglutination; Suture zones; Escape tectonics; Metamorphic-deformational events ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 14
    Publication Date: 2021-03-29
    Description: The Sierras Pampeanas in central and north-western Argentina constitute a distinct morphotectonic feature between 27°S and 33°S. The last stage of uplift and deformation in this area are interpreted to be closely related to the Andean flat-slab subduction of the Nazca plate beneath the South American plate. K–Ar fault gouge dating and low-temperature thermochronology along two transects within the Sierra de Comechingones reveal a minimum age for the onset of brittle deformation about 340 Ma, very low exhumation rates since Late Paleozoic time, as well as a total exhumation of about 2.3 km since the Late Cretaceous. New Ar–Ar ages (7.54–1.91 Ma) of volcanic rocks from the San Luis volcanic belt support the eastward propagation of the flat-slab magmatic front, confirming the onset of flat-slab related deformation in this region at 11.2 Ma. Although low-temperature thermochronology does not clearly constrain the signal of the Andean uplift, it is understood that the current structural relief related to the Comechingones range has been achieved after the exhumation of both fault walls (circa 80–70 Ma).
    Keywords: Sierras Pampeanas; K–Ar dating; Fault gouge dating; Low thermal geochronology; Andean uplift ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 15
    Publication Date: 2021-03-29
    Description: The Palaeogene was the most recent greenhouse period on Earth. Especially for the Late Palaeocene and Early Eocene, several superimposed short-term hyperthermal events have been described, including extremes such as the Palaeocene–Eocene Thermal Maximum. Major faunal and floral turnovers in the marine and terrestrial realms were recorded in association with these events. High-resolution palynological analysis of the early Middle Eocene maar lake sediments at Messel, near Darmstadt, Germany, provides an insight into the dynamics of a climax vegetation during the Middle Eocene greenhouse climate in a time span without significant climatic excursions. Numerical techniques like detrended correspondence analysis and wavelet analysis have been applied to recognize cyclic fluctuations and long-term trends in the vegetation through a time interval of approximately 640 kyr. Based on the numerical zoning of the pollen diagram, three phases in the development of the vegetation may be distinguished. Throughout these phases, the climax vegetation did not change substantially in qualitative composition, but a trend towards noticeably less humid conditions probably in combination with a drop of the water level in the lake may be recognized. A shift in algal population from the freshwater dinoflagellate cyst Messelodinium thielepfeifferae to a dominance of Botryococcus in the uppermost part of the core is interpreted as a response to changes in acidity and nutrient availability within the lake. Time series analyses of pollen assemblages show that variations in the Milankovitch range of eccentricity, obliquity and precession can be distinguished. In addition, fluctuations in the sub-Milankovitch range are indicated. This demonstrates that floral changes during steady depositional conditions in the Middle Eocene of Messel were controlled by orbital forcing.
    Keywords: Middle Eocene; Maar lake; Palynology; Climate variability; Milankovitch cycles; Multivariate statistics; Time series analysis ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 16
    Publication Date: 2021-03-29
    Description: In the presented case study, ascomycete fungi and green algae on a marble monument were identified by comparisons of the 18S rRNA gene sequences, which were obtained from DNA either from environmental samples or from enrichment cultures. The organisms were found to be responsible for either black or green surface coverings on different areas of the monument surface. Most fungi were related to plant-inhabiting genera, corresponding to a heavy soiling of the marble surface with honeydew. Whereas green algae of the genera Stichococcus, Chloroidium and Apatococcus were found to be dominant in all samples, isolates of two additional genera were recovered only from enrichment cultures. A reference strain of Apatococcus lobatus and an isolate of Prasiolopsis sp. were investigated with respect to putative surface adhesive structures of the cell envelope. The Prasiolopsis cell walls were covered with a thin adhesive exopolysaccharide layer involved in biofilm formation.
    Keywords: Marble monument; Biofilm; Ascomycete fungi; Green algae; Cell wall; Exopolysaccharide ; 551 ; Earth Sciences; Geology
    Language: English
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  • 17
    facet.materialart.
    Unknown
    Springer-Verlag | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: Bowing is a well-known phenomenon seen in marbles used as building veneers. This form of rock weathering occurs as a result of external factors such as temperature, humidity, the system for anchoring the marble slabs or the panel dimensions. Under the same external conditions, many factors will determine the degree of deformation including petrography, thermal properties and residual locked stresses. The usual way to solve the problem of bowed marble slabs is to replace them with other materials, such as granites, in which the deformation still exists but is less common. In this study, eight ornamental granites with different mineralogy, grain size, grain shape, porosity and fabric were tested in a laboratory to assess their susceptibility to bowing. Three slabs of granite, each cut with a different orientation, were studied under different conditions of temperature (90 and 120°C) and water saturation (dry and wet) to investigate the influence of these factors together with that of anisotropy. At 90°C, only the granite with the coarsest grain size and low porosity exhibited deformation under wet conditions. At 120°C and wet conditions, three of the granites showed evident signs of bowing. Again, the granite with the coarsest grain size was the most deformed. It was concluded that the wide grain size distribution influences microcracking more than other expected factors, such as the quartz content of the rock. Also, mineral shape-preferred orientation and porosity play an important role in the bowing of the studied granites.
    Keywords: Granitoids; Bowing; Texture; Thermal expansion ; 551 ; Earth Sciences; Geology
    Language: English
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  • 18
    Publication Date: 2021-03-29
    Description: The emplacement of the Mesoproterozoic Götemar Pluton into Paleoproterozoic granitoid host rocks of the Transscandinavian Igneous Belt is re-examined by microfabric analysis, including cathodoluminescence microscopy. Field data on the pluton-host rock system are used to strengthen the model. The Götemar Pluton, situated on the Baltic Shield of SE Sweden, is a horizontally zoned tabular structure that was constructed by the intrusion of successive pulses of magma with different crystal/melt ratios, at an estimated crustal depth of 4–8 km. Initial pluton formation involved magma ascent along a vertical dike, which was arrested at a mechanical discontinuity within the granitoid host rocks; this led to the formation of an initial sill. Subsequent sill stacking and their constant inflation resulted in deformation and reheating of existing magma bodies, which also raised the pluton roof. This multi-stage emplacement scenario is indicated by complex dike relationships and the occurrence of several generations of quartz (Si-metasomatism). The sills were charged by different domains of a heterogeneous magma chamber with varying crystal/melt ratios. Ascent or emplacement of magma with a high crystal/melt ratio is indicated by syn-magmatic deformation of phenocrysts. Complex crystallization fabrics (e.g. oscillatory growth zoning caused by high crystal defect density, overgrowth and replacement features, resorbed and corroded crystal cores, rapakivi structure) are mostly related to processes within the main chamber, that is repeated magma mixing or water influx.
    Keywords: Pluton emplacement; Microfabrics; Cathodoluminescence; Mesoproterozoic; Götemar; SE Sweden ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 19
    Publication Date: 2021-03-29
    Keywords: Provenance; Heavy minerals; Detrital zircon; U–Pb dating; Rhine River; Alps ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 20
    Publication Date: 2021-03-29
    Keywords: Landsat ETM+; Sea surface temperature; Submarine groundwater discharge; Groundwater resource ; 551 ; Earth Sciences; Geology
    Language: English
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  • 21
    Publication Date: 2021-03-29
    Description: Slates are internationally known as roof and façade-cladding material since prehistoric times. The methods required to mine and manufacture these dimensional stones are relatively simple in comparison to those utilized in granitic dimensional stones. This has led to a worldwide rentable commercialization of slate in the last centuries and also to the development of characteristic cultural landscapes. In Uruguay several slates are mined and used in architecture, especially as façade cladding and floor slabs. The most important slates regarding their production and utilization are the dolomitic slates. These dolomitic slates are associated with the Neoproterozoic thrust and fold belt of the Dom Feliciano belt. Representative samples have been geochemically and petrographically characterized, as well as petrophysically and petromechanically analyzed. The petrophysical and petromechanical properties were investigated in a very systematic way with respect to the new European standards, showing values comparable to those registered for internationally known slates. Detailed structural and deposit analysis were carried out in Uruguay in order to evaluate the dolomitic slate deposits. The slates are linked to calc-silicate strata in a greenschist facies volcano-sedimentary sequence and the deposits are located in the limb of a regional fold, where bedding and cleavage are parallel. The main lithotype is a layered and fine-grained dolomitic slate with a quite diverse palette of colors: light and dark green, gray, dark gray, reddish and black. The mined slate is split into slabs 0.5–2 cm thick. In the past, the average production in Uruguay was around 4,000 tons/year and a historical maximum of 13,000 tons was reached in 1993 (Oyhantçabal et al. in Z dt Ges Geowiss 158(3):417–428, 2007). The oscillations in the regional demand were the cause of several flourishing and decay cycles in the activity, but our investigation shows a considerable volume of indicated resources and therefore a very good potential.
    Keywords: Slates; Dimensional stones; Petrophysical properties; Petrography; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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  • 22
    Publication Date: 2021-03-29
    Description: Microstructure‐based finite-element analysis with a microcracking algorithm was used to simulate an actual degradation phenomenon of marble structures, i.e., microcracking. Both microcrack initiation and crack propagation were characterized, as were their dependence on lattice preferred orientation (LPO), grain shape preferred orientation (SPO), grain size, marble composition (calcite and dolomite) and grain‐boundary fracture toughness. Two LPOs were analyzed: a random orientation distribution function and an orientation distribution function with strong directional crystalline texture generated from a March–Dollase distribution. Three SPOs were considered: equiaxed grains; elongated grains and a mixture of equiaxed and elongated grains. Three different grain sizes were considered: fine grains of order 200 μm (only calcitic marble); medium size grains of order 1 mm (calcitic and dolomitic marbles); and large grains of order 2 mm (only dolomitic marble). The fracture surface energy for the grain boundaries, γig, was chosen to be 20 and 40 % of the fracture surface energy of a grain, γxtal, so that both intergranular and transgranular fracture were possible. Studies were performed on these idealized marble microstructures to elucidate the range of microcracking responses. Simulations were performed for both heating and cooling by 50 °C in steps of 1 °C. Microcracking results were correlated with the thermoelastic responses, which are indicators related to degradation. The results indicate that certain combinations of LPO, SPO, grain size, grain‐boundary fracture toughness and marble composition have a significant influence on the thermal-elastic response of marble. Microstructure with the smallest grain size and the highest degree of SPO and LPO had less of a tendency to microcrack. Additionally, with increasing SPO and LPO microcracking becomes more spatially anisotropic. A significant observation for all microstructures was an asymmetry in microcracking upon heating and cooling: more microcracking was observed upon cooling than upon heating. Given an identical microstructure and crystallographic texture, calcite showed larger thermal stresses than dolomite, had an earlier onset of microcracking upon heating and cooling, and a greater microcracked area at a given temperature differential. Thermal expansion coefficients with and without microcracking were also determined.
    Keywords: Marble; Microcracking; Finite-element modeling; Lattice preferred orientation; Shape preferred orientation; Strain energy density; Maximum principal stress; Thermal expansion coefficient; Thermal expansion anisotropy ; 551 ; Earth Sciences; Geology
    Language: English
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  • 23
    Publication Date: 2021-03-29
    Description: In Uruguay commercial granite varieties comprise mafic rocks, granitoids, and syenitoids. There is a long tradition in Uruguay, as well as worldwide, of using dimensional stones in architecture and art, specially granitic ones. Some of the present applications of these dimensional stones are as façade cladding, countertops, and outdoor and indoor floor slabs. The color spectrum of the Uruguayan granitic dimensional stones varies from black to light gray, covering a wide variety of red and pink and minor greenish-gray. The décor of these granitic dimensional stones is mainly determined by their fabric, fundamentally the grain size and the color distribution between the different minerals that compose the rocks. In the present research the most important commercial granites were sampled to analyze their petrography and petrophysical properties. A detailed structural analysis has been performed in several deposits, as well as the application of the software 3D Block Expert for modeling the possible raw block size distribution. Other factors controlling the mining viability of the deposits were also studied (e.g., homogeneity/heterogeneity of color and décor) and the possible reserves were calculated.
    Keywords: Granitic dimensional stones; Petrophysical properties; Petrography; Deposit characterization; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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  • 24
    Publication Date: 2021-03-29
    Description: The old mining city of Guanajuato in middle Mexico preserves one of the most important historical legacies in colonial buildings, the UNESCO declared the city World Heritage Site in 1988. Practically all the colonial constructions were built with natural stones from the neighbourhood, of which stands a greenish to reddish vulcanite, called Loseros Tuff. Although the Loseros Tuff is widely used in historical buildings in the city. It shows significant deterioration and weathering effects, principally in the parts where the tuff shows a coarse grain size. The petrographic, petrophysical, mineralogical and geochemical properties of the Loseros Tuff were analysed in order to determine the causes, effects, behaviour and response to deterioration of this volcanic rock. The results of the investigations suggest that in addition to the parameters like the grain size and the porosity properties, the pore radii distribution is decisive for the effectiveness of porosity and the water transport into the rock. It is recognized that once the liquid water invades the rock the dissolution of the matrix occurs, which is accompanied by a sudden moisture expansion favoured by the newly formed secondary porosity and the high content of expandable clay minerals.
    Keywords: Tuff; Moisture expansion; Porosity; Guanajuato ; 551 ; Earth Sciences; Geology
    Language: English
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  • 25
    Publication Date: 2021-03-29
    Description: The degree of weathering in natural stones on buildings and sculptures has been determined for many years in numerous cases by means of ultrasonic measurements. Conclusions concerning the strength of the rock and the type of weathering can thus be drawn. This relationship has not been established for all rock types. Most of the progress utilizing this method has been made in the analysis of marbles, where an increasing degree of weathering shows lower ultrasonic velocities. In the present study, four Carrara marble samples showing similar rock fabrics, but with respect to weathering exhibit considerable differences are investigated. Porosity varies between 0.2 vol. % and ca. 2.4 vol. %, whereby with increasing porosity the pore radii changes as well. Parallel to this the ultrasonic velocities change in dry samples from about 5.5 to 1.6 km/s, respectively. Model calculations reveal that the velocity reduction is caused by cracks with an extremely small aspect ratio of about 0.005 or even less. After a specific loss of strength, however, solution processes can become active, which modify the microcracks and generate an opposite trend. In the process a strong porosity increase correlates to a relatively small velocity reduction. With the presence of water the Vp porosity weathering relationship experiences a considerable modification. Parallel to the reduction of the ultrasonic velocities, it was determined that the mechanical strength (compressive strength, flexural strength, etc.) as well as the static Young’s modulus is reduced almost equally by a progressive advancement of the weathering front. In one case study dealing with tensile strengths, it was clearly documented how tensile cracks develop and propagate in dependence of the rock fabric. The rock mechanical and ultrasonic velocity data were used for stability assessments applied to the marble statuaries from the Schlossbrücke in Berlin. Stability assessments of the sculpture group 4 reveal that some critical parts must be replaced due to safety reasons.
    Keywords: Marble waethering; Mechanical properties; Ultrasonic wave velocites; Stability assessment; Cultural heritage ; 551 ; Earth Sciences; Geology
    Language: English
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  • 26
    Publication Date: 2021-03-29
    Description: Fabrics of Cambrian sedimentary dykes formed in Proterozoic granites of the Västervik area (Southeast Sweden) evidence repeated opening/filling and mineralisation/cementation events under varying conditions. Diagnostic features include (1) wall-parallel boundaries between epiclastic fillings and (2) early formed dyke sediments that appear as lithoclasts in subsequently formed sedimentary fillings. The psammitic components mostly consist of well-rounded quartz grains related to a coastal environment and fragments from the granitic host rock. Platy calcitic fragments embedded in the epiclastic matrix originally formed as microveins within already-lithified dyke sediments and the adjacent host rock. Convex downward-pointing, internal sagging structures, together with the preferred orientation of compositional boundaries and long axes of grains/rock fragments parallel to the dyke walls, are interpreted as the result of suction-controlled flow of unconsolidated fillings during episodes of downward dyke growth. Pressure solution of quartz grains are evidence of extensional phases with dyke propagation that were interrupted by phases of horizontal compression normal to the dyke walls. The N–S and NE–SW striking sedimentary dykes formed by opening of a pre-existing joint set during NW–SE oriented rifting during the Cambrian.
    Keywords: Sedimentary dykes; Proterozoic; Southeast Sweden; Microfabrics; Passive infill; Cambrian geodynamics ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
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  • 27
    Publication Date: 2021-03-29
    Description: Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.
    Keywords: Weathering of tuffs; Hygric expansion; Hydric expansion; Clay mineralogy; Microporosity; Disjoining pressure ; 551 ; Earth Sciences; Geology
    Language: English
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  • 28
    Publication Date: 2021-03-29
    Description: Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO2 polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase, whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO2 phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand. For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO2 analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace elements proves to be a valuable tool besides Raman spectroscopy.
    Keywords: TiO2 polymorph discrimination; Phase classification; Anatase; Brookite; Rutile; Erzgebirge; Zr-in-rutile thermometry ; 551 ; Earth Sciences; Mineral Resources; Mineralogy; Geology
    Language: English
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  • 29
    Publication Date: 2021-03-29
    Description: A new U–Pb SHRIMP age of 551 ± 4 Ma on a mylonitic porphyry that intruded into the Sierra Ballena Shear Zone (Southernmost Dom Feliciano Belt, Uruguay) and a review of relevant published data make possible a more refined correlation and reconstruction of Brasiliano/Pan-African transpressional events. Paleogeographic reconstruction, kinematics and timing of events indicate a connection between the shear systems of the Dom Feliciano and Kaoko Belts at 580–550 Ma. Sinistral transpression recorded in shear zones accommodates deformation subsequent to collision between the Congo and Río de la Plata Cratons. The correlation is strengthened by the similarity of magmatic and metamorphic ages in the Coastal Terrane of the Kaoko Belt and the Punta del Este Terrane of the Dom Feliciano Belt. This post-collisional sinistral transpression brought these units near to their final position in Gondwana and explains the different evolution at 550–530 Ma. While in the Kaoko Belt, an extensional episode resulted in exhumation as a consequence of collision in the Damara Belt, in the Dom Feliciano Belt, sinistral transpression occurred associated with the closure of the southern Adamastor Ocean due to Kalahari-Río de la Plata collision.
    Keywords: Dom Feliciano Belt; Kaoko Belt; Brasiliano; Pan-African; Transpressional deformation; Shear Zones ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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  • 30
    Publication Date: 2021-03-29
    Keywords: Eastern Sierras Pampeanas; Provenance; Tectonic setting; Gondwana margin; Geodynamic evolution ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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  • 31
    Publication Date: 2021-03-29
    Description: This study documents the chemical and textural responses of zircon in the Elba igneous complex, with particular reference to the 7- to 7.8-Ma-old Monte Capanne pluton in relation to its coeval volcanic counterpart (Capraia), using BSE imaging and quantitative electron microprobe analyses. The Monte Capanne pluton displays multiple field and geochemical evidence for magma mixing. The samples we have investigated (including monzogranitic, mafic enclave and dyke samples) display similar zircon textures and are associated with an extremely large range of trace and minor element (Hf, Y, HREE, Th, U) compositions, which contrast with relatively simple textures and zoning patterns in zircons from a Capraia dacite. We have used a relatively simple textural classification (patchy zoning, homogenous cores, oscillatory zoning and unzoned zircon) as the basis for discussing the chemical composition and chemical variation within zircons from the Monte Capanne pluton. Based on these data and other works (Dini et al. 2004 in Lithos 78:101–118, 2004) , it is inferred that mixing between metaluminous and peraluminous melts occurred early in the evolution of the Monte Capanne magma chamber. In particular, mixing was responsible for the development of the patchy-zoning texture in the zircon cores, which was associated with reactions between other accessory phases (including monazite, apatite, allanite), which we infer to have significantly affected the Th distribution in zircon. Zircons from the MC pluton displaying “homogeneous cores” have chemical affinities with zircons in the coeval Capraia volcanic system, consistent with the participation of a Capraia-like mantle end-member during mixing. Further zircon growth in the MC pluton produced the oscillatory zoning texture, which records both long-term (crystal fractionation) and transient (recharge with both silicic and mafic magmas) events in a hybrid magma chamber. It is inferred that Hf and the Th/U ratio cannot be used alone to infer magmatic processes due to their dependency on temperature, nor are they a diagnostic feature of xenocrystic grains. This study shows that zircon chemistry coupled with detailed textural analysis can provide a powerful tool to elucidate the complex evolution of a magma system.
    Keywords: Granite petrology; Zircon; Elba; Capraia; Electron microprobe; Magma mixing ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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  • 32
    Publication Date: 2021-03-29
    Description: The bowing of natural stone panels is especially known for marble slabs. The bowing of granite is mainly known from tombstones in subtropical humid climate. Field inspections in combination with laboratory investigations with respect to the thermal expansion and the bowing potential was performed on two different granitoids (Cezlak granodiorite and Flossenbürg granite) which differ in the composition and rock fabrics. In addition, to describe and explain the effect of bowing of granitoid facade panels, neutron time-of-flight diffraction was applied to determine residual macro- and microstrain. The measurements were combined with investigations of the crystallographic preferred orientation of quartz and biotite. Both samples show a significant bowing as a function of panel thickness and destination temperature. In comparison to marbles the effect of bowing is more pronounced in granitoids at temperatures of 120°C. The bowing as well as the thermal expansion of the Cezlak sample is also anisotropic with respect to the rock fabrics. A quantitative estimate was performed based on the observed textures. The effect of the locked-in stresses may also have a control on the bowing together with the thermal stresses related to the different volume expansion of the rock-forming minerals.
    Keywords: Granitoids; Bowing; Residual strain; Texture; Thermal expansion ; 551 ; Geosciences; Geology
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  • 33
    Publication Date: 2021-03-29
    Description: Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ18O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher Sri and δ18O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ18O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins (NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed by crustal differentiation starting at ~0.9 Ga.
    Keywords: Nd–Sr–Hf–O; Arabian–Nubian Shield; Magma-sources; Zircon ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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  • 34
    Publication Date: 2021-03-29
    Description: Oligoclase and labradorite crystals have been experimentally replaced by albite in an aqueous sodium silicate solution at 600°C and 2 kbars. The replacement is pseudomorphic and is characterised by a sharp chemical interface which progresses through the feldspar while preserving the crystallographic orientation. Reaction rims of albite, up to 50 μm thick, can be readily achieved within 14 days. Re-equilibration of plagioclase in an 18O-enriched sodium- and silica-bearing solution results in oxygen isotope redistribution within the feldspar framework structure. The observed characteristics of the reaction products are similar to naturally albitised plagioclase and are indicative of an interface-coupled dissolution–reprecipitation mechanism. Chemical analyses demonstrate that the albitisation is accompanied by the mobilisation of major, minor and trace elements also including elements such as Al and Ti which are commonly regarded as immobile during hydrothermal alteration. The results contribute to developing our understanding of the close association between large-scale albitisation and secondary ore mineralisation which is common in nature.
    Keywords: Plagioclase albitisation; Fluid–mineral interaction; Interface-coupled dissolution–reprecipitation; Hydrothermal experiments; Element mobility ; 551 ; Earth Sciences; Mineralogy ; Mineral Resources ; Geology
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  • 35
    Publication Date: 2021-03-29
    Description: The Sierra de San Luis forms the southern tip of the Eastern Sierras Pampeanas in central Argentina. Two narrow belts of low-grade phyllites and quartz arenites, i.e. the San Luis Formation, have accommodated part of the strain-related differential exhumation of the medium- to high-grade metamorphic domains that constitute to the basement complex of the sierra. Eleven phyllite samples were subjected to the K/Ar fine-fraction dating technique. Results are interpreted in relation to the Kübler index of the illites, which indicate epimetamorphic conditions for the majority of the samples. Obtained ages between 330 and 290 Ma cover a period of compressional tectonics in the late Mississippian (Visean/Serpukhovian boundary) followed by the subsidence during the formation of the Paganzo Basin in the provinces of La Rioja and San Luis. These tectonic movements are coincident with the Toco orogeny in northern Chile and southern Bolivia. This suggests that the older K/Ar ages document the compressional stage and that younger ages record the cooling of the basement during the subsequent extensional uplift of the basement.
    Keywords: Eastern Sierras Pampeanas; San Luis Formation; Paganzo Basin; K/Ar; Illite fine fractions ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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  • 36
    Publication Date: 2021-03-29
    Description: A review of the lithostratigraphic units in the Río de la Plata Craton and of new and previously published geochronological, isotopic and geophysical data is presented. Sm–Nd TDM model ages between 2.6 and 2.2 Ga characterize the Piedra Alta Terrane of this craton. Crystallization ages between 2.2 and 2.1 Ga for the metamorphic protoliths and 2.1–2.0 Ga for the post-orogenic granitoids indicate juvenile crust, followed by a short period of crustal recycling. Cratonization of this terrane occurred during the late Paleoproterozoic. Younger overprinting is not observed, suggesting it had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina. Sm–Nd TDM model ages for the Nico Pérez Terrane show two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga). The crystallization ages on zircon ranges between 3.1 and 0.57 Ga, which is evidence for long-lived crustal reworking. The age for cratonization is still uncertain. In the Taquarembó Block, which is considered the prolongation of the Nico Pérez Terrane in southern Brazil, a similar scenario can be observed. These differences together with contrasting geophysical signatures support the redefinition of the Río de la Plata Craton comprising only the Piedra Alta Terrane and the Tandilia Belt. The Sarandí del Yí Shear Zone is regarded as the eastern margin of this Craton.
    Keywords: Precambrian; Transamazonian cycle; South American platform; Río de la Plata Craton ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
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  • 37
    Publication Date: 2021-03-29
    Keywords: Mud mound; Peloids; Automicrites; Micro-framework; Carboniferous; Spain ; 551 ; Earth Sciences; Ecology; Paleontology; Geochemistry ; Biogeosciences; Sedimentology
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  • 38
    Publication Date: 2021-03-29
    Keywords: Campi Flegrei; Phlegraean fields; Campanian Ignimbrite; Neapolitan Yellow Tuff; Geochemistry; Sr and Nd isotopes; Magma batches; Precursor activity ; 551 ; Geosciences; Sedimentology ; Mineralogy ; Geophysics/Geodesy ; Geology
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  • 39
    Publication Date: 2021-03-29
    Description: The volcaniclastic Tepoztlán Formation (TF) represents an important rock record to unravel the early evolution of the Transmexican Volcanic Belt (TMVB). Here, a depositional model together with a chronostratigraphy of this Formation is presented, based on detailed field observations together with new geochronological, paleomagnetic, and petrological data. The TF consists predominantly of deposits from pyroclastic density currents and extensive epiclastic products such as tuffaceous sandstones, conglomerates and breccias, originating from fluvial and mass flow processes, respectively. Within these sediments fall deposits and lavas are sparsely intercalated. The clastic material is almost exclusively of volcanic origin, ranging in composition from andesite to rhyolite. Thick gravity-driven deposits and large-scale alluvial fan environments document the buildup of steep volcanic edifices. K-Ar and Ar-Ar dates, in addition to eight magnetostratigraphic sections and lithological correlations served to construct a chronostratigraphy for the entire Tepoztlán Formation. Correlation of the 577 m composite magnetostratigraphic section with the Cande and Kent (1995) Geomagnetic Polarity Time Scale (GPTS) suggests that this section represents the time intervall 22.8–18.8 Ma (6Bn.1n-5Er; Aquitanian-Burdigalian, Lower Miocene). This correlation implies a deposition of the TF predating the extensive effusive activity in the TMVB at 12 Ma and is therefore interpreted to represent its initial phase with predominantly explosive activity. Additionally, three subdivisions of the TF were established, according to the dominant mode of deposition: (1) the fluvial dominated Malinalco Member (22.8–22.2 Ma), (2) the volcanic dominated San Andrés Member (22.2–21.3 Ma) and (3) the mass flow dominated Tepozteco Member (21.3–18.8 Ma).
    Keywords: Magnetostratigraphy; K-Ar Geochronology; Volcaniclastics; Miocene; Tepoztlán Formation; Transmexican Volcanic Belt; Central Mexico ; 551 ; Earth Sciences; Sedimentology; Mineralogy; Geophysics/Geodesy; Geology
    Language: English
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  • 40
    Publication Date: 2021-03-29
    Description: The Sierra Ballena Shear Zone (SBSZ) is part of a high-strain transcurrent system that divides the Neoproterozoic Dom Feliciano Belt of South America into two different domains. The basement on both sides of the SBSZ shows a deformation stage preceding that of the transcurrent deformation recognized as a high temperature mylonitic foliation associated with migmatization. Grain boundary migration and fluid-assisted grain boundary diffusion enhanced by partial melting were the main deformation mechanisms associated with this foliation. Age estimate of this episode is 〉658 Ma. The second stage corresponds to the start of transpressional deformation and the nucleation and development of the SBSZ. During this stage, pure shear dominates the deformation, and is characterized by the development of conjugate dextral and sinistral shear zones and the emplacement of syntectonic granites. This event dates to 658–600 Ma based on the age of these intrusions. The third stage was a second transpressional event at about 586 to 〈560 Ma that was associated with the emplacement of porphyry dikes and granites that show evidence of flattening. Deformation in the SBSZ took place, during the late stages, under regional low-grade conditions, as indicated by the metamorphic paragenesis in the supracrustals of the country rocks. Granitic mylonites show plastic deformation of quartz and brittle behavior of feldspar. A transition from magmatic to solid-state microstructures is also frequently observed in syntectonic granites. Mylonitic porphyries and quartz mylonites resulted from the deformation of alkaline porphyries and quartz veins emplaced in the shear zone. Quartz veins reflect the release of silica associated with the breakdown of feldspar to white mica during the evolution of the granitic mylonites to phyllonites, which resulted in shear zone weakening. Quartz microstructures characteristic of the transition between regime 2 and regime 3, grain boundary migration and incipient recrystallization in feldspar indicate deformation under lower amphibolite to upper greenschist conditions (550–400°C). On the other hand, the mylonitic porphyries display evidence of feldspar recrystallization suggesting magmatic or high-T solid-state deformation during cooling of the dikes.
    Keywords: Brasiliano; Pan-African; Shear zone; Dom Feliciano Belt; Uruguay; Kinematic analysis ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
    Language: English
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  • 41
    Publication Date: 2021-03-29
    Description: Movement within the Earth’s upper crust is commonly accommodated by faults or shear zones, ranging in scale from micro-displacements to regional tectonic lineaments. Since faults are active on different time scales and can be repeatedly reactivated, their displacement chronology is difficult to reconstruct. This study represents a multi-geochronological approach to unravel the evolution of an intracontinental fault zone locality along the Danube Fault, central Europe. At the investigated fault locality, ancient motion has produced a cataclastic deformation zone in which the cataclastic material was subjected to hydrothermal alteration and K-feldspar was almost completely replaced by illite and other phyllosilicates. Five different geochronological techniques (zircon Pb-evaporation, K–Ar and Rb–Sr illite, apatite fission track and fluorite (U-Th)/He) have been applied to explore the temporal fault activity. The upper time limit for initiation of faulting is constrained by the crystallization age of the primary rock type (known as “Kristallgranit”) at 325 ± 7 Ma, whereas the K–Ar and Rb–Sr ages of two illite fractions 〈2 μm (266–255 Ma) are interpreted to date fluid infiltration events during the final stage of the cataclastic deformation period. During this time, the “Kristallgranit” was already at or near the Earth’s surface as indicated by the sedimentary record and thermal modelling results of apatite fission track data. (U–Th)/He thermochronology of two single fluorite grains from a fluorite–quartz vein within the fault zone yield Cretaceous ages that clearly postdate their Late-Variscan mineralization age. We propose that later reactivation of the fault caused loss of helium in the fluorites. This assertion is supported by geological evidence, i.e. offsets of Jurassic and Cretaceous sediments along the fault and apatite fission track thermal modelling results are consistent with the prevalence of elevated temperatures (50–80°C) in the fault zone during the Cretaceous.
    Keywords: Argillic alteration; Fault zone; K–Ar illite; Apatite fission track; (U–Th)/He thermochronology ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
    Language: English
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  • 42
    Publication Date: 2021-03-29
    Keywords: Community-based co-management; Community forestry; Livelihood; Governance; Policy; Mechanism; Participation ; 551 ; Environment; Climate Change; Geology; Oceanography; Geography (general); Regional/Spatial Science; Nature Conservation
    Language: English
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  • 43
    Publication Date: 2021-03-29
    Description: The application of the SHRIMP U/Pb dating technique to zircon and monazite of different rock types of the Sierras de Córdoba provides an important insight into the metamorphic history of the basement domains. Additional constraints on the Pampean metamorphic episode were gained by Pb/Pb stepwise leaching (PbSL) experiments on two titanite and garnet separates. Results indicate that the metamorphic history recorded by Crd-free gneisses (M2) started in the latest Neoproterozoic/earliest Cambrian (553 and 543 Ma) followed by the M4 metamorphism at ~530 Ma that is documented in the diatexites. Zircon ages of 492 Ma in the San Carlos Massif correlate partly with rather low Th/U ratios (〈0.1) suggesting their growth by metamorphic fluids. This age is even younger than the PbSL titanite ages of 506 Ma. It is suggested that the fluid alteration relates to the beginning of the Famatinien metamorphic cycle in the neighbouring Sierra de San Luis and has not affected the titanite ages. The PTt evolution can be correlated with the plate tectonic processes responsible for the formation of the Pampean orogene, i.e., the accretion of the Pampean basement to the Río de La Plata craton (M2) and the later collision of the Western Pampean basement with the Pampean basement.
    Keywords: Eastern Sierras Pampeanas; Sierras de Córdoba; Pampean and Famatinian cycles; Geodynamic evolution; SHRIMP dating; Titanite and Garnet Pb–Pb step-wise leaching ; 551 ; Earth Sciences; Geology ; Geophysics/Geodesy
    Language: English
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  • 44
    facet.materialart.
    Unknown
    Springer-Verlag | Berlin/Heidelberg
    Publication Date: 2021-04-25
    Description: Aspidochirote holothurian ossicles were discovered in Upper Ordovician-aged Öjlemyr cherts from Gotland, Sweden. The well-preserved material allows definitive assignment to the family Synallactidae, a deep-sea sea cucumber group that is distributed worldwide today. The new taxon Tribrachiodemas ordovicicus gen. et sp. nov. is described, representing the oldest member of the Aspidochirotida. The further fossil record of Synallactidae and evolutionary implications are also discussed.
    Keywords: Echinodermata; Holothuroidea; Ordovician; Sweden; Baltic Sea; Echinodermata; Holothuroidea; Ordovizium; Schweden; Ostsee ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 45
    Publication Date: 2021-03-29
    Description: The configurational heat capacity, shear modulus and shear viscosity of a series of Na2O–Fe2O3–Al2O3–SiO2 melts have been determined as a function of composition. A change in composition dependence of each of the physical properties is observed as Na2O/(Na2O + Al2O3) is decreased, and the peralkaline melts become peraluminous and a new charge-balanced Al-structure appears in the melts. Of special interest are the frequency dependent (1 mHz–1 Hz) measurements of the shear modulus. These forced oscillation measurements determine the lifetimes of Si–O bonds and Na–O bonds in the melt. The lifetime of the Al–O bonds could not, however, be resolved from the mechanical spectrum. Therefore, it appears that the lifetime of Al–O bonds in these melts is similar to that of Si–O bonds with the Al–O relaxation peak being subsumed by the Si–O relaxation peak. The appearance of a new Al-structure in the peraluminous melts also cannot be resolved from the mechanical spectra, although a change in elastic shear modulus is determined as a function of composition. The structural shear-relaxation time of some of these melts is not that which is predicted by the Maxwell equation, but up to 1.5 orders of magnitude faster. Although the configurational heat capacity, density and shear modulus of the melts show a change in trend as a function of composition at the boundary between peralkaline and peraluminous, the deviation in relaxation time from the Maxwell equation occurs in the peralkaline regime. The measured relaxation times for both the very peralkaline melts and the peraluminous melts are identical with the calculated Maxwell relaxation time. As the Maxwell equation was created to describe the timescale of flow of a mono-structure material, a deviation from the prediction would indicate that the structure of the melt is too complex to be described by this simple flow equation. One possibility is that Al-rich channels form and then disappear with decreasing Si/Al, and that the flow is dominated by the lifetime of Si–O bonds in the Al-poor peralkaline melts, and by the lifetime of Al–O bonds in the relatively Si-poor peralkaline and peraluminous melts with a complex flow mechanism occurring in the mid-compositions. This anomalous deviation from the calculated relaxation time appears to be independent of the change in structure expected to occur at the peralkaline/peraluminous boundary due to the lack of charge-balancing cations for the Al-tetrahedra.
    Keywords: Frequency dependent; Shear modulus; Heat capacity; Silicate melts; Relaxation time ; 551 ; Earth Sciences; Mineral Resources ; Geochemistry ; Mineralogy ; Crystallography
    Language: English
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  • 46
    Publication Date: 2021-03-29
    Description: The giant ignimbrites that erupted from the Cerro Galán caldera complex in the southern Puna of the high Andean plateau are considered to be linked to crustal and mantle melting as a consequence of delamination of gravitationally unstable thickened crust and mantle lithosphere over a steepening subduction zone. Major and trace element analyses of Cerro Galán ignimbrites (68–71% SiO2) that include 75 new analyses can be interpreted as reflecting evolution at three crustal levels. AFC modeling and new fractionation corrected δ18O values from quartz (+7.63–8.85‰) are consistent with the ignimbrite magmas being near 50:50 mixtures of enriched mantle (87Sr/86Sr ~ 0.7055) and crustal melts (87Sr/86Sr near 0.715–0.735). Processes at lower crustal levels are predicated on steep heavy REE patterns (Sm/Yb = 4–7), high Sr contents (〉250 ppm) and very low Nb/Ta (9-5) ratios, which are attributed to amphibolite partial melts mixing with fractionating mantle basalts to produce hybrid melts that rise leaving a gravitationally unstable garnet-bearing residue. Processes at mid crustal levels create large negative Eu anomalies (Eu/Eu* = 0.45–0.70) and variable trace element enrichment in a crystallizing mush zone with a temperature near 800–850°C. The mush zone is repeatedly recharged from depth and partially evacuated into upper crustal magma chambers at times of regional contraction. Crystallinity differences in the ignimbrites are attributed to biotite, zoned plagioclase and other antecrysts entering higher level chambers where variable amounts of near-eutectic crystallization occurs at temperatures as low as 680°C just preceding eruption. 40Ar/39Ar single crystal sanidine weighted mean plateau and isochron ages combined with trace element patterns show that the Galán ignimbrite erupted in more than one batch including a ~ 2.13 Ma intracaldera flow and outflows to the west and north at near 2.09 and 2.06 Ma. Episodic delamination of gravitationally unstable lower crust and mantle lithosphere and injection of basaltic magmas, whose changing chemistry reflects their evolution over a steepening subduction zone, could trigger the eruptions of the Cerro Galán ignimbrites.
    Keywords: Cerro Galán; Puna ignimbrite chemistry; 40Ar/39Ar ages; Delamination; Plateau evolution ; 551 ; Earth Sciences; Sedimentology; Geophysics/Geodesy; Mineralogy; Geology
    Language: English
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  • 47
    Publication Date: 2021-03-29
    Description: The construction suitability of a dimension stone depends on its weathering properties along with the petrology and the petrophysical properties. The aim of this study was to evaluate the suitability of the dimension stones from the “Drei Gleichen” area for construction and replacement purposes. In total, six sandstones (Ingersleben, Wachsenburg, Hindfelden, Seeberg, Röhnberg, Gleichenberg; Upper Triassic) as well as two carbonates (Wachsenburg sinter; Quaternary, Wandersleben dolomite; Middle Triassic) were analysed. The results from our laboratory and on-site studies of the dimension stones show that rocks from the same stratigraphic layer, like the sandstones from the upper Triassic, can show major differences in their petrophysical and weathering properties. These differences are attributed to their different diagenesis, resulting, e.g. in varying pore space, water balance and strength properties. The pore size distribution can be divided into four different groups based on their occurring maxima and micropore content. The determined water balance properties as well as moisture expansion and salt attack depend on these groups. Next to this, the mineralogical composition significantly influences the weathering resistance. Sandstones with a high content of altered lithoclasts show a high amount of moisture expansion, low strength and, in consequence, a low weathering resistance against salt attack. Based on the results of the present study, an evaluation of construction suitability could be accomplished. From the analysed sandstones, only the Seebergen sandstone is suitable for construction purposes due to its good availability, good strength properties (high compressive and tensile strength, low softening degree) as well as a low porosity. Furthermore, the Wachsenburg sandstone also shows good petrophysical and petrological properties, but exploitable deposits are too sparse to be of commercial interest. From the carbonates, the Wachsenburg sinter shows very suitable rock parameters, but only sparse outcrops occur, which are not appropriate for mining.
    Keywords: Dimension stones; Sandstones; Carbonates; Weathering ; 551 ; Earth Sciences; Geology
    Language: English
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  • 48
    Publication Date: 2021-03-29
    Keywords: 551 ; Earth Sciences; Geology
    Language: English
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  • 49
    Publication Date: 2021-03-29
    Description: In the Aztec period and in colonial times different natural stones originating in the Valley of Mexico were used for building construction. Stone weathering was investigated onsite at various historical buildings within the old quarter of Mexico City. In this study, different aspects of weathering and deterioration at three significant historical buildings will be presented, the Aztec excavation site Templo Mayor, the Metropolitan Cathedral, and the colonial palace of the dukes of Heras Soto. Petrophysical properties of the main building stones of these structures were investigated like density, porosity, pore radii distribution, water uptake rate and coefficient, thermal and hygric expansion, and the mechanical properties of uniaxial compressive strength. A relationship between single critical property values, according to anisotropy fabric characteristics, and specific weathering forms could be deduced.
    Keywords: Stone weathering; Mexico-DF; Petrophysical properties; Isotropy–anisotropy; Critical values ; 551 ; Earth Sciences; Geology
    Language: English
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  • 50
    Publication Date: 2021-03-29
    Description: A 782 d solubilization study using not shaken batch experiments and involving one uranium-bearing rock and three natural carbonate minerals was conducted to characterize uranium (U) leaching under oxic conditions. Results showed that aqueous U concentration increased continuously with a solubilization rate of 0.16 mgm-2h-1 for the first 564 d (1.5 y). After 1.5 y, U concentration reached a maximum value (saturation) and decreased afterwards. The saturation concentration of 54 mgL-1 (mean value) was influenced to various extent by the presence of carbonate minerals. Dissolution/precipitation, adsorption or ion exchange processes appear to control U solubilization.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 425-435
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  • 51
    Publication Date: 2021-03-29
    Keywords: Wadi Kafrein; Groundwater modelling; Model calibration; Arid and semiarid areas ; 551 ; Earth Sciences; Geology
    Language: English
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  • 52
    Publication Date: 2021-04-24
    Description: The northern German Lower Cretaceous Bückeberg Formation yields numerous dinosaur tracksites, some of which have produced material of impressive quality. Stratigraphically, the localities are concentrated in the Obernkirchen Sandstone, a thin subunit within this formation. The Obernkirchen Sandstone represents mainly a sandy barrier to back-barrier and lagoonal setting within a limnic deltaic facies complex, which was deposited during the late Berriasian (Cypridea alta formosa ostracod subzone) in the southeast of the Lower Saxony Basin, northwest Germany. A few tracksites occur more proximally in coeval fluvial deposits. Dinosaur footprint assemblages were left by ornithopods, theropods, sauropods, ankylosaurs, and small, bipedal ornithischians. Other vertebrate tracks are those of turtles and, possibly, crocodilians. Due to the decrease in sandstone quarrying in recent decades, many old tracksites are inaccessible today. Additionally, historical descriptions of the tracks were of highly variable quality and often published in remote and today nearly unobtainable sources. Here we provide a catalogue of 13 tracksites compiled from the literature and some new observations. Of these 13 tracksites, only five are still accessible and currently under study. Descriptions of each locality are provided, with a comprehensive compilation of existing data on lithofacies, stratigraphy, palaeogeography and palaeoecology of the Obernkirchen Sandstone and equivalent strata. A short review of the track-bearing lithofacies assemblage indicates that the outcrop areas have distinctly different facies and environments, and, therefore, track-bearing horizons can only be correlated stratigraphically between adjacent outcrops. For this reason, the identification of a megatracksite in the Obernkirchen Sandstone is currently regarded as premature and uncertain.
    Keywords: Vertebrate tracks; Dinosauria; Cretaceous; Berriasian; Obernkirchen; Münchehagen; Germany; Wirbeltier-Fährten; Dinosauria; Kreide; Berriasium; Obernkirchen; Münchehagen; Deutschland ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 53
    facet.materialart.
    Unknown
    Springer-Verlag Berlin Heidelberg | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: Many of the reasons behind the anthropogenic contamination problems in rural environments of developing countries lie in changes in the traditional way of life and the ignorance on the toxic potential of introduced manufactured products. A generalization trend exists within the international community suggesting that water in developing countries is of poor quality. However, the water quality is rarely analytically determined. Existing potabilization solutions may be prohibitively expensive for the rural populations. Therefore, efficient and affordable technologies are still needed to ameliorate the water quality. In the recent two decades,elemental iron has shown the capacity to remove all possible contaminants (including viruses) from the groundwater. This paper presents a concept to scale down the conventional iron barrier technology to meet the requirements of small communities and households in rural environments worldwide.
    Keywords: 551 ; VJF 000 ; 38.32
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 121-130
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  • 54
    Publication Date: 2021-04-25
    Description: The morphologically conspicuous bivalve Oxytoma (Palmoxytoma) cygnipes (Young & Bird, 1822), known for its palaeogeographically bipolar distribution, from a limestone bed in the boundary “Belemniten–Schichten”/Amaltheenton formation, Lower Jurassic, in N Germany is described. The occurrence of this palaeoceanographically significant bivalve points to an influx of cool seawater from the Arctic to the North-German Basin at the base of the Upper Pliensbachian, just before the deposition of the Amaltheenton formation. A review of previously reported occurrences on the NW European Shelf indicates two distinct stratigraphic intervals of occurrence of this taxon: the Rhaetian–Hettangian boundary and the Upper Pliensbachian. Whereas the former interval of occurrence may be related to short-term cooling in the course of the end-Triassic extinction event, the latter is interpreted as reflecting the influx of a cool water current to the eastern part of the NW European Shelf, which continued southwards parallel to the coast of the Bohemian–Vindelician High.
    Keywords: Bivalvia; Germany; Triassic–Jurassic boundary; Pliensbachian; Boreal; Bivalvia; Deutschland; Trias–Jura-Grenze; Pliensbachium; Boreal ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 55
    Publication Date: 2021-03-29
    Description: In the present study, the diversity of ascomycete fungi was investigated on two wall areas of the “Burg Gleichen”, Thuringia (Germany), made of various types of sandstones, travertine and Grenzdolomit. From a W-exposed, shaded wall area, free-living ascomycetes (mainly “black fungi”) and green algae could be retrieved from sandstone lithologies. Sandstone from an ESE-exposed area was mainly colonized by lichen ascomycetes and the lichen alga Trebouxia. Both areas share a small number of generalist species, related to the ascomycete black fungi Sarcinomyces petricola, Phaeococcomyces chersonesos and Stichococcus mirabilis. Free-living black fungi were isolated and characterized with respect to cell wall morphology and melanin content. A remarkably rigid melanin layer, incorporated in the cell wall of a Cladosporium isolate is presented in detail.
    Keywords: Dimension stone; Biofilm; Ascomycete fungi; Green algae; Cell wall; Melanin ; 551 ; Earth Sciences; Geology
    Language: English
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  • 56
    Publication Date: 2021-03-29
    Description: Microstructure-based finite element simulations were used to study the influence of grain shape fabric and crystal texture on thermoelastic responses related to marble degradation phenomena. Calcite was used as an illustrative example for studying extremes of shape preferred orientation (SPO) in shape fabric and lattice preferred orientation (LPO) in crystal texture. Three SPOs were analyzed: equiaxed grains, elongated grains, and a mixture of equiaxed and elongated grains. Three LPOs were considered: a random orientation distribution function and two degrees of strong directional crystal texture. Finally, the correlation between the direction of the LPO with respect to that of the SPO was examined. Results show that certain combinations of SPO, LPO, and their directional relationship have significant influence on the thermomechanical behavior of marble. For instance, while there is no major dependence of the elastic strain energy density and the maximum principal stress on SPO for randomly textured microstructures, there is a strong synergy between LPO and its directional relationship with respect to the SPO direction. Microcracking precursors, elastic strain energy density, and maximum principal stress, decrease when the crystalline c-axes have fiber texture perpendicular to the SPO direction, but increase significantly when the c-axes have fiber texture parallel to the SPO direction. Moreover, the microstructural variability increases dramatically for these latter configurations. In general, the influence of LPO was as expected, namely, the strain energy density and the maximum principal stress decreased with more crystal texture, apart from for the exception noted above. Spatial variations of these precursors indicated regions in the microstructure with a propensity for microcracking. Unexpectedly, important variables were the microstructural standard deviations of the spatial distributions of the microcracking indicators. These microstructural standard deviations were as large as or larger than the variables themselves. The elastic misfit-strain contributions to the coefficients of thermal expansion were also calculated, but their dependence was as expected.
    Keywords: Shape fabric; Shape preferred orientation; Crystal texture; Lattice preferred orientation; Marble; Calcite; Finite element simulations; Thermal expansion anisotropy; Elastic strain energy density; Maximum principal stress; Orientation distribution function; Coefficient of thermal expansion ; 551 ; Earth Sciences; Geology
    Language: English
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  • 57
    Publication Date: 2021-03-29
    Description: The present study documents the results of an inter-disciplinary model project that was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbrücke (Berlin). Such a system would need to fulfil the various requirements for structural stability, aesthetics, climate and practical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. The study is characterised by the use of complex scientific instruments such as special laboratory analysis and numerical simulation tools. The interaction between the environment and the artefacts in connection with the innovative winter covering structures were studied by extensive climatic monitoring.
    Keywords: Marble sculptures; Marble weathering; Winter cover; Climate data; Numerical simulations ; 551 ; Earth Sciences; Geology
    Language: English
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  • 58
    facet.materialart.
    Unknown
    Springer Berlin Heidelberg | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: This study evaluates and compares the trends in CO2 emissions for the manufacturing industries of three countries: two developed countries (Germany and Sweden) that have applied several measures to promote a shift towards a low-carbon economy and one developing country (Colombia) that has shown substantial improvements in the reduction of CO2 emissions. This analysis is conducted using panel data cointegration techniques to infer causality between CO2 emissions, production factors and energy sources. The results indicate a trend of producing more output with less pollution. The trends for these countries’ CO2 emissions depend on investment levels, energy sources and economic factors. Furthermore, the trends in CO2 emissions indicate that there are emission level differences between the two developed countries and the developing country. Moreover, the study confirms that it is possible to achieve economic growth and sustainable development while reducing greenhouse gas emissions, as Germany and Sweden demonstrate. In the case of Colombia, it is important to encourage a reduction in CO2 emissions through policies that combine technical and economic instruments and incentivise the application of new technologies that promote clean and environmentally friendly processes.
    Keywords: CO2 emissions; Manufacturing industries; Panel data model ; 551 ; Environment; Climate Change; Climate Change Impacts; Oceanography; Geography (general); Regional/Spatial Science; Nature Conservation
    Language: English
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  • 59
    Publication Date: 2021-03-29
    Description: Severe stone deterioration is evident at the Cologne cathedral. In particular, the “Drachenfels” trachyte, which was the building material of the medieval construction period, shows significant structural deterioration as well as massive formation of gypsum crusts. The present article investigates crust formation on limestone, sandstone, and volcanic rock from the Cologne cathedral as well as from the Xanten and Altenberg cathedrals. These three buildings, showing varying degrees of deterioration, are located in different areas and exposed to varying industrial, urban, and rural pollution. Thin laminar and black framboidal crusts form on calcareous as well as silicate stone. The lack of a significant intrinsic calcium and sulfur source for the formation of the gypsum crusts on the Drachenfels trachyte indicates major extrinsic environmental impact: a sufficient offer of SOx from pollutant fluxes as well as external calcium sources (e.g., pollution, mortars, neighboring calcite stones). Chemical analyses reveal strong gypsum enrichment within the crusts as well as higher concentrations of lead and other pollutants (arsenic, antimony, bismuth, tin, etc.), which generally can be linked to traffic and industry. The formation of weathering crusts in an industrial environment is clearly distinguishable from that in rural areas. Scanning electron microscopy observations confirm that the total amount of pollution is less at the Altenberg cathedral than at the Cologne and Xanten cathedrals. XRF analyses show that the formation of gypsum occurs in lower amounts at Altenberg. This correlates well with the measured SO2 content and the intensity of the decay at the different locations. Furthermore, the different types of crusts, e.g., framboidal and laminar, can be differentiated and assigned to the different locations. The black weathering crusts on the silicate Drachenfels trachyte contribute to the degradation of the historic building material. They enhance mechanical moisture-related deterioration processes and the decay by chemical corrosion of rock-forming minerals. Although SO2 concentrations in air have shown a strong decrease over the past 30 years, degradation in connection with weathering crusts is still observed. This indicates that not only contemporary or recent emissions, but also past pollutant concentrations have to be considered.
    Keywords: Cologne cathedral; Xanten cathedral; Altenberg cathedral; Weathering crusts; Pollution impact; Stone decay processes; Drachenfels trachyte ; 551 ; Earth Sciences; Geology
    Language: English
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  • 60
    Publication Date: 2021-03-29
    Description: The St. Servatius Church in Quedlinburg (UNESCO’s World Heritage Site, Germany) is characterised by long-standing stability problems and structural damages, which have been known over the last several centuries. The monotonous Cretaceous sandstone with its poor lithification is considered to be the main factor. The sandstone is characterised by a high porosity of around 30 Vol.% (max. ca. 35 Vol.%) and a corresponding high w-value. The porosity and the degree of cementation are responsible for the very low compressive strength of around 8 MPa at maximum, whereas under moisture these values are significantly reduced up to 40%. The freeze–thaw tests indicate a very poor resistance to frost weathering, which may explain the near-surface softening of the sandstone. Direct shear experiments with an approximate 60° angle of friction on the sandstone clearly demonstrate the safety margins. Initial geotechnical modelling does not favour the hypothesis that a landslide of the hill parallel to the southward dipping bedding planes (i.e. shear failure along weak zones) can occur. A prominent clay layer (also with a southward dip) below the entire castle hill is monitored to determine the possible amount of movement with respect to the geological discontinuities (e.g. joints, fractures). At present, a combination of foundation problems are being considered for the stability situation at the church. These include construction deficiencies due to deformation or softening of the foundation of the forerunner churches and missing or faulty connections from building additions. Geological factors responsible for the stability problems include the softening of the sandstone by the influence of weathering and penetrating water as well as the presence of possible shear planes and joints.
    Keywords: Cretaceous sandstone; Lithology; Diagenetic processes; Weathering; Petrophysical properties; Stability assessment ; 551 ; Earth Sciences; Geology
    Language: English
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  • 61
    Publication Date: 2021-03-29
    Description: Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic–basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. The Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed in this study. The petrophysical properties of Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.
    Keywords: Dolerites; Black dimensional stones; Petrophysical properties; Structural analysis; Block size distribution; Uruguay ; 551 ; Earth Sciences; Geology
    Language: English
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  • 62
    Publication Date: 2021-03-29
    Description: One of the properties that makes marble such an excellent construction and ornamental material is its low porosity. It is very difficult for water or decay agents to penetrate the internal structure of materials with no or few pores, so enhancing the durability of these materials. However, environmental temperature fluctuations bring about significant physical changes in marbles that result in an increase in porosity, due to the appearance of new microcracks and the expansion of existing ones. These cracks offer new paths into the marble which make it easier for solutions containing pollutants to penetrate the material. Thermal expansion tests were performed on three different types of marble known as White, Tranco, and Yellow Macael (Almeria, Spain), after which an increase in porosity (from 17 to 73% depending on marble type) was observed, mainly due to crack formation. The structural changes occurring during thermal expansion tests were more significant in the case of White Macael samples, a fact that is not only related to its mineralogical composition but also to the morphology of the grains, grain boundaries and crystal size. Our research suggests that thermally weathered White Macael marble could be more susceptible to decay by other contaminant agents than Tranco or Yellow Macael. The use of hot-stage environmental scanning electron microscopy is proposed as a valid tool for observing, both in situ and at high magnification, changes in the fracture system of building stones induced by thermal stress.
    Keywords: Marble; Microcracks; Thermal expansion anisotropy; Grain boundaries ; 551 ; Earth Sciences; Geology
    Language: English
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  • 63
    Publication Date: 2021-03-29
    Keywords: 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 64
    facet.materialart.
    Unknown
    Univ. Bremen
    Publication Date: 2017-06-09
    Description: The different benthic foraminiferal species (epibenthic as well as endobenthic) colonize wide areas of the ocean floor and are widely used for paleoceanographic reconstructions. To improve these reconstructions, it is an important part in research to continuously develop and refine proxies by e.g. improving measuring techniques as well as introducing other species in paleoceanograhpy. The main focus of the presented thesis is a regional examination of the trace element ratios of the rarely used benthic foraminifer Oridorsalis umbonatus and the investigation of their suitability for paleoceanographic applications. Since O. umbonatus is not very abundant in the sediments, it was necessary . as a prerequisite for such studies . to investigate, whether laser ablation ICP-MS can be used for trace element measurements on benthic foraminifera. Therefore, as a first step, trace elements were measured using laser ablation ICP-MS on a set of modern core top samples collected along a depth transect on the continental slope off Namibia at 25.5.S (320 . 2300m water depth; 2.9. to 10.4.C). The Mg/Ca ratios where than calibrated against bottom water temperatures (BWT). The study demonstrates clearly that benthic foraminiferal trace elements can be reliably measured with the laser ablation technique and that the Mg/Ca ratio of O. umbonatus has the potential to be used as a proxy for BWTs...
    Description: thesis
    Keywords: 579.44 ; 579.44 ; UHG 000 ; VXE 000 ; UHG 000 ; VXE 000 ; Paläoozeanologie ; Protozoa {Paläozoologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 81 S.
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  • 65
    Publication Date: 2017-06-09
    Description: In the early 1990`s the first IPCC report stated the effect of anthropogenic CO2 emissions on global warming and John Martin`s Iron Hypothesis (Martin and J.H 1990), relating atmospheric dust deposition, a major source of iron to the surface ocean, to the CO2 concentration in the atmosphere and the last ice age, culminating in the well known sentence Give me (half) a tanker of iron and I’ll give you a new ice age!. Since then, several large-scale in situ Fe fertilisation experiments revealed that in large areas of the ocean, the so called high nutrient low chlorophyll (HNLC) areas, phytoplankton growth is partly limited by depleted Fe conditions (Geider et al. 1994; De Baar and Boyed 2000; Boyd et al. 2007). The ocean receives Fe from upwelling, riverine input, melting icebergs, atmospheric dust input, input from anoxic sediments, hydrothermal vents and direct recycling by organisms(Tovar-Sanchez et al. 2007). However, in HNLC regions the Fe input to surface waters is very low resulting in Fe limitation of phytoplankton growth. Fe is an important nutrient for marine phytoplankton (Geider et al. 1994; Falkowski et al. 1998; Morel and Price 2003), being essential in metabolic reactions like the photosynthetic electron transport and the assimilation of nitrogen. It is also required for the synthesis of chlorophyll (Martin et al. 1988; Maldonado et al. 1999) as well as for the functioning of the enzyme superoxide dismutase which inhibits the breakdown of chlorophyll by superoxide radicals (Coale 1991)...
    Description: thesis
    Keywords: 577.14 ; VJE 000 ; VJC 210 ; VJE 000 ; VJC 210 ; Organische Geochemie ; Geochemie des Meerwassers
    Language: English
    Type: monograph , publishedVersion
    Format: 106 S.
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  • 66
    Publication Date: 2021-03-29
    Description: Mg/Ca ratios in benthic foraminiferal shells are frequently used in paleoceanographic studies to estimate past bottom water temperatures. Apart from temperature, other factors may exert additional influences on foraminiferal Mg/Ca. These include the Mg/Ca ratio of seawater, partial dissolution of shell calcite, salinity, physiological effects, and, probably of capital importance, the carbonate chemistry of seawater. In this context, the seperate effects of temperature and seawater carbonate chemistry on the magnesium incorporation into benthic foraminideral calcite are unraveled and quantified in this thesis...
    Description: thesis
    Keywords: 579.44 ; 579.44 ; 560 ; VXE 000 ; VJE 220 ; VXE 000 ; VJE 220 ; Protozoa {Paläozoologie} ; Geochemie der Fauna
    Language: English
    Type: monograph , publishedVersion
    Format: 88 S.
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  • 67
    Publication Date: 2021-03-29
    Description: Organic-walled dinoflagellate cysts, oxidation, degradation, organic matter. - Species-selective aerobic decomposition affects fossil organic-walled dinoflagellate cyst (dinocyst) records and hence dinocyst-based interpretations of primary productivity and oceanographic conditions. However, since the recognition of dinocyst species sensitive and resistant to oxic degradation (S- and R-cysts, respectively) it has become apparent that R-cysts may still serve as reliable productivity and oceanographic conditions proxies. On the other hand S-cysts provide a way to quantify aerobic degradation of organic matter (OM) and past bottom-water O2 concentrations. OM degradation plays a key role in global carbon cycling and is important for global climate change. Therefore dinocysts are a valuable tool for estimating the rate of diagenetic process. Questions concerning species-selective aerobic degradation still remain and will be adressed here. To obtain information on the rate of S-cyst decomposition, the relationship between S-cyst degradation and O2 concentrations, and the aerobic degradation of extinct dinocyst species, a natural exposure experiment has been conducted and studies of both Quaternary and pre-Quaternary material from sediment cores were executed. The exposure experiment was conducted in the natural setting of the Eastern Mediterranean. During a 15 month exposure period to oxic water masses, concentrations of S-cysts (Brigantedinium spp. and Echinidinium granulatum) decreased by 24 to 57%. However, taxa such as Nematosphaeropsis labyrinthus, Echinidinium aculeatum, Operculodinium israelianum and Impagidinium aculeatum demonstrated a slight increase in concentration, indicating resistance to aerobic degradation. These results show that even short-term exposure to oxygen may cause considerable changes in the dinocyst assemblage ...
    Description: thesis
    Keywords: 560 ; VVA 560 ; VXE 000 ; VVA 560 ; VXE 000 ; Aktuopaläontologie ; Protozoa {Paläozoologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 159 S.
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  • 68
    Publication Date: 2021-03-29
    Description: Marine snow, underwater cameras, particle flux, aggregation, suspended particulate matter, particle transport. - This study focusses on the vertical distribution and transportation pathways of marine particles off NW-Africa with aid of optical methodologies. A profiling camera system and a remotely operated vehicle (ROV) was used for in-situ observations on the distribution, transport processes and sinking behaviour of marine particulate matter. Between the regional areas of investigation Cape Blanc, Dakhla and Cape Bojador significant differences could be observed with respect to distribution and transportation patterns. These differences are primarily related to the different primary production conditions between the investigation areas. Primary production is the most important factor for the abundance of particulate matter, where highest particle concentrations in the entire water column were seen off Cape Blanc. Next to primary production, water depth, currents and density gradients are factors influencing the particle distribution patterns. With respect to the prevailing transport processes, the Cape Blanc region is characterised by vertically orientated transport patterns. In addition to the continuous supply of large, relatively fast sinking particle aggregates a sinking event could be documented for the first time in-situ in the water column. These events deliver huge amounts of particulate matter from the ocean surface ...
    Description: thesis
    Keywords: 551
    Language: English
    Type: monograph , publishedVersion
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  • 69
    Publication Date: 2021-03-29
    Description: Madagascar; Jurassic; Karoo; Gondwana; Breakup; Rift; Microfauna; Macrofauna; Ammonites; Indian Ocean. - The breakup of Gondwana along the former East African Orogen is widely interpreted to have lasted from the Late Palaeozoic to the Callovian. The present study indicates that the Permian-Triassic or Karoo phase of rifting was not responsible for the separation of East- and West-Gondwana, since that rift system failed in the Late Triassic. Instead the breakup of Gondwana occurred in the Late Liassic. The pre-rift phase in the Morondava Basin is represented by the Karoo deposits, and the syn-rift phase is recorded by Toarcian marine shales, locally overlain by Aalenian sandstones. A major Early Bajocian unconformity is interpreted as the breakup unconformity. The initial post-rift or drift phase is represented by the Bajocian-Bathonian carbonates, marls and sandstones of coastal plain environment and a coastal barrier/lagoon complex. During the Bathonian the siliciclastic shoreface system moved basinward. Callovian-Early Kimmeridgian shales with interbedded iron-oolites represent ...
    Description: thesis
    Keywords: 551 ; VAE 500 ; VDB 100 ; VEQ 300 ; Geotektonische Entwicklung der Erdkruste {Geologie} ; Gondwana ; Madagaskar {Geologie}
    Language: English
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  • 70
    facet.materialart.
    Unknown
    Univ. Bremen
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551.9 ; VJE 200 ; VJC 210 ; Geochemie Lebender Materie ; Geochemie des Meerwassers
    Language: English
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  • 71
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 560 ; VYF 200 ; Pyrrophyceae {Paläobotanik}
    Language: English
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  • 72
    facet.materialart.
    Unknown
    Univ. Bremen
    Publication Date: 2021-03-29
    Description: This thesis describes the adaptive shallow water model PLASMA-FEMmE. It solves on the sphere the shallow water equations, the prototype for partial differential equations in atmospheric modeling, using a semi-implicit semi-Lagrangian time step and linear finite elements. Both statically and dynamically adapted grids created by the grid generator amatos are investigated. The results are compared with those of the predecessor model FEMmE that uses a static uniform grid. The outcome demonstrates the capability of the chosen approach as well as its limits. Grid adaptation can easily be achieved with amatos. No reflexions at the grid interfaces are observed. Though in one test case instabilities are released at the grid interfaces. The numerical errors are reduced without a considerable enhancement of the computational effort in another test case with a well-known analytical solution. In respect to the conservation properties the results are more complicated. Mass conservation can be achieved in one test case with an appropriate static grid. In case of complex flow regimes all conservation properties are weakened during the simulation using dynamic grid adaptation...
    Description: thesis
    Keywords: 532.5 ; 551.46 ; 550 ; Meteorologische Modelle ; Fluiddynamik {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 135 S.
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  • 73
    Publication Date: 2021-03-29
    Description: The polar ice sheets are unique paleoclimatic archives and play an important role in recent and future climate. The melting of the big freshwater reservoirs will not only increase the global sea level, but will also influence the ocean currents. Therefore, it will be of particular interest to improve the currently available numeric climate models to achieve more accurate statements about climatic change and its consequences. In this work, the evaluation and the different applications of GPS and altimetry data will be described in respect to enhance models. The antarctic area of investigation, Dronning Maud Land (DML), is of particular interest for German polar research, because both the overwintering station Neumayer and the summer station Kohnen are located within it. In the surroundings of these two stations, highly accurate kinematic GPS measurement were made, which will be the basis for the digital elevation model presented here. Because these data are spatially limited, they are supplemened with remotely sensed data. For this purpose, two airborne altimetry data sets and spaceborne laser altimetry data of the Ice, Cloud, and land Elevation Satellite (ICESat) are used...
    Description: thesis
    Keywords: 551.312 ; 551 ; 550 ; TWC 600 ; VAR 980 ; TQI 000 ; TSY 200 ; Geophysikalische Satellitenfernerkundung ; Antarktis {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 140 S.
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  • 74
    Publication Date: 2021-03-29
    Description: Marine sediments, diagenesis, anoxic environments, paleomagnetism, low-temperature magnetism, magnetic Fe-Ti-Oxides. - Magnetic particles usually occur in very minor concentrations in igneous and sedimentary rocks, soils, volcanic ashes, dusts and even in living organisms. Many of these magnetic grains are capable of carrying a stable permanent magnetization and therefore act as recorders of the recent and ancient Earth's magnetic field. Thus paleomagnetism refers to the study of this remanent magnetization in sedimentary and volcanic rocks through time. From this magnetization, directional intensity information can be recovered concerning the geomagnetic field that prevailed at the sample location at the time of the rock formation. The magnetic parameter on which such paleomagnetic studies are based is the natural remanent magnetization (NRM). In continental margin regions the remanence acquisition process is often complicated by post-depositional modifications of the original magnetic material. After deposition magnetic minerals can be altered or new magnetic phases can be formed. Consequently the original NRM might be obscured or even fully erased. The process of diagenesis and authigenesis may thus seriously compromise paleomagnetic interpretation. Therefore our knowledge of the geomagnetic field behavior based on sediment records from continental margin regions remains limited. To obtain fully reliable information about the geomagnetic field or paleoenvironmental conditions from continental margin regions, the effect of early diagenetic processes occurring after deposition of the sediment must be understood in detail.
    Description: thesis
    Keywords: 551.4686 ; 538.727 ; 550 ; TOT 320 ; VKB 380 ; TSZ 100 ; Paläomagnetismus {Geophysik} ; Sedimente bestimmter Regionen ; Atlantischer Ozean {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 113 S.
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  • 75
    Publication Date: 2021-03-29
    Description: Anaerobe Oxidation of Methane, AOM, methanotrophy, stable isotope labeling, stable isotope probing, carbon assimilation, flow-through columns, ANME, Seep-SRB, Gullfaks, Tommeliten. - Anaerobic oxidation of methane (AOM) performed by consortia of methanotrophic archaea (ANME) and sulfate reducing bacteria (SRB) is the major sink of methane in marine sediments. This thesis describes methane consumption at two of the most active North Sea cold seeps (Gullfaks, Tommeliten), their microbial community and the resulting lipid biomarker patterns. Experiments in flow-through setups are presented, focusing on physiological parameters of AOM activity such as different methane and sulfate concentrations and on the tolerance of AOM to starvation periods. The roles of inorganic carbon (DIC) and methane as carbon sources for the microbial community performing AOM were examined combining stable isotope probing and lipid biomarker analyses. For archaea substantial uptake of carbon from DIC and methane was found, indicting a novel carbon assimilation pathway. Biomass from SRB was exclusively labeled by DIC indicating a methane dependent, but autotrophic growth consortial SRB.
    Description: thesis
    Keywords: 551.9
    Language: English
    Type: monograph , publishedVersion
    Format: 153 S.
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  • 76
    facet.materialart.
    Unknown
    Univ. Bremen
    Publication Date: 2021-03-29
    Description: Black Sea, seafloor seepage, mud volcanoes, seeps, fluid migration, gas hydrates, diapirs. - The Black Sea is the worldwide largest anoxic basin with thick gas rich sediments facilitating seafloor seepage, which is widely distributed along the continental slopes of the Black Sea. In two areas, the Sorokin Trough off Crimea and at the continental slope off Batumi (Georgia), the distribution, structure and evolution of two different vent systems and their relation to fluid migration pathways and gas/gas hydrate occurrences have been investigated by means of high resolution multichannel seismic data. In both regions, the distribution of seafloor seepage is controlled by fluid migration along permeable pathways associated with diapiric uplift in the subsurface. In the Sorokin Trough, seepage is expressed by intensive material upflow and the formation of mud volcanoes; offshore Batumi, gas seeps with low material flux dominate. In the Sorokin Trough, most mud volcanoes are associated with near-subsurface mud diapirs. The great morphological variability of the mud volcanoes reflects different driving mechanisms, which depend on the availability of permeable fluid migration pathways and the depositional environment. A 3D seismic dataset images the detailed three-dimensional ...
    Description: thesis
    Keywords: 551.466 ; 550 ; TSZ 100 ; VAT 300 ; VEZ 120 ; TQC 600 ; Atlantischer Ozean {Geophysik} ; Geologie des Meeresboden ; Randmeere {Geologie} ; Tiefseeseismik {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 154 S.
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  • 77
    Publication Date: 2021-03-29
    Description: Ozone, balloon-borne measurements, atmospheric trace gases, concentration profiles, climate change. - In the frame of this work, a new small-size balloon-borne sonde was developed. A miniature grating spectrometer in the sonde measures simultaneously the solar spectral irradiance at a wide wavelength range from 200 to 850. As a first application, ozone profiles have been determined by measuring the changes in the spectral irradiance, caused by ozone absorption in the Huggins band. The wide spectral coverage of the spectrometer offers the possibility for measurements of other trace gases which absorb within the wavelength range, e.g. NO2 and BrO. The low weight of the new sonde (1.7 kg), the moderate price, and the autonomous portable telemetry system makes it a very versatile tool for satellite validation and for case studies, which requires a high number of launches. The newly developed sonde works well without temperature stabilisation, even so the spectrometer experiences rather large temperature changes (15 - 20 K) during the ascent through the atmosphere. Laboratory measurements were performed in ...
    Description: thesis
    Keywords: 551.5 ; 551.8 ; 550
    Language: English
    Type: monograph , publishedVersion
    Format: 148 S.
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  • 78
    Publication Date: 2021-03-29
    Description: Sea ice is a very important component of the climate system. While the Arctic sea ice extent has retreated during the past 20 years, it has remained constant in the Antarctic. In order to better understand the role of sea ice in the climate system in the context of global warming currently used coupled Atmosphere-Ocean Global Circulation Models have to be improved. This requires to know the sea ice concentration C for a long period for both hemispheres and at the best possible spatial resolution. Currently used methods to obtain C like the NASA Team (NT) algorithm are based on data acquired by the Special Sensor Microwave/Imager (SSM/I) at 19 and 37GHz. The SEA LION (SL) algorithm presented here allows to infer C from the polarization P at 85GHz taking advantage of the higher spatial resolution at this frequency. However, the decrease of P caused by the weather influence leads to an overestimation of C. Therefore, P is corrected using a radiative transfer model and atmospheric data taken from Numerical Weather Prediction models and/or derived from SSM/I measurements. The various sea ice and snow properties are considered calculating monthly sea ice tie points. The average standard deviation of C derived with the SL algorithm is 12% for C 〈 50% and below 5% for C 〉 90%. The SL ice edge agrees within 10km with the one evident in VIS/IR images. The SL ice concentration gradient across the marginal ice zone (MIZ) agrees much better with the one evident in SAR images compared to results of the NT algorithm. Using the higher spatial resolution at 85GHz the SL algorithm allows to detect smaller open water areas than known algorithms. A major limitation of the SL algorithm arises from the quality of atmospheric data needed for the weather correction. A spatial resolution of these data lower than the 85GHz SSM/I channels and/or a time lag larger than half an hour between both data sets can cause relative errors above 100%, particulary in the cloud-covered parts of the MIZ.
    Description: thesis
    Keywords: 550.28 ; 551.31 ; 550 ; TWH 500 ; TWC 100 ; Einfluss von Eis {Klimatologie} ; Instr. Ergebn. zu Klimaänderungen und Klimaschwankungen
    Language: English
    Type: monograph , publishedVersion
    Format: 186 S.
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  • 79
    Publication Date: 2021-03-29
    Description: Carbon export; SeaWiFS; variability; upwelling; Atlantic Ocean; chlorophyll filament; SeaWiFS; SST. - The North Atlantic off NW Africa is characterized by the trade wind induced upwelling of cold and nutrient rich waters. As one of most strongest eastern boundary upwelling areas it is marked by low sea surface temperature and high bio-production, both subject to strong seasonal and interannual variations.Satellite measurements of sea surface temperature (SST) and chlorophyll-a (Chl-a) in the upper water-column were used to (a) recognize the upwelling of deep water and its distribution and mixing in the surface, (b) identify the development of phytoplankton blooms and (c) provide further insights in the characteristics of its variations.Measurements of surface Chl-a were compared to deep-sea fluxes of organic carbon in order to determine the relationship between both parameters and to further calculate the export of Corg and the export variation strength.The off-shore extension of SST-defined upwelling from 1988 through 1999 between 18ʿ and 25ʿN shows maxima in January and May/June with an average area of 140,000 km2 (standard deviation of 20,000 km2). Minima in August exhibit an extension of 43,000 km2 (15,000 km2 standard deviation). A correlation between ...
    Description: thesis
    Keywords: 910 ; UKB 100 ; Nordatlantik {Regionale Ozeanologie}
    Language: English
    Type: monograph , publishedVersion
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  • 80
    Publication Date: 2021-03-29
    Description: This study focuses on the interactions between climate and ice sheets in order to obtain a better understanding of the processes involved. Two periods in the geological past are explored; the Middle Miocene and the mid-Pliocene. For both periods, foraminiferal oxygen-isotope records from deep-sea sediment cores as well as stratigraphical data, suggest a global sea-level lowering. The magnitude of these reductions in sea level indicate large-scale ice-sheet build-up. However, the origin of these events and even the geographic locations of the ice sheets, are still under discussion. The ice sheet-climate model developed in this study provides a tool to test some of the hypotheses brought forward to explain the ice-sheet expansion events. It describes the Antarctic ice sheet and is forced by a climate component based on energy and mass balances. Further more, the model computes the oxygen-isotopic composition of the ice-sheet, thereby providing the possibility to compare numerical results directly to deep-sea sediment records. Numerical experiments focus on the interactions between atmospheric CO2, temperature, ice volume (sea-level equivalent) and the isotopic composition of sea water...
    Description: thesis
    Keywords: 551.69 ; 551 ; 550 ; TWC 600 ; VAR 980 ; Paläoklimatologie ; Antarktis {Glazialgeologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 137 S.
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  • 81
    Publication Date: 2021-03-29
    Description: The Late BarremianLate Aptian interval was characterised by several major changes in the ocean/climate system related to the onset of the Mid-Cretaceous greenhouse world. North Africansedimentary deposits offer excellent archives of the ecological changes on the southern Tethyscontinental margin during this time interval. In the present phD thesis sedimentology, palaeontology,biostratigraphy, chemostratigraphy, and geochemistry are combined to reconstruct the palaeoenvironmental evolution and sea-level changes of the Tunisian carbonate platform margin.Respect is paid to major palaeoceanographic and palaeoclimatic events including the late Early Aptian Oceanic Anoxic Event 1a (OAE 1a) and two time intervals associated with widespread carbonate platform drowning in the early- and mid-Late Aptian. The last chapter deals with the cephalopod fauna of the platform margin. Results of the detailed regional investigations are compared to global marine palaeoenvironments and discussed in a broad geological context...
    Description: thesis
    Keywords: 551.77 ; 551 ; 550 ; TWC 600 ; VKB 372 ; VEN 130 ; VDH 300 ; Paläoklimatologie ; Karbonatische Sedimentgesteine ; Tunesien {Geologie} ; Kreide
    Language: English
    Type: monograph , publishedVersion
    Format: 160 S.
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  • 82
    Publication Date: 2021-03-29
    Description: ICP-MS, Time of Flight, laser ablation, solid and liquid samples, ice cores, Antarctica, mineral dust, trace element analysis. - The analysis of the inorganic composition of climatic archives provides proxies for climate reconstruction. For many applications commercially available inductively coupled plasma quadrupole mass spectrometry (ICP-Q-MS) systems are used for investigations. One aim of this thesis was to test the laser ablation (LA)-ICP-Q-MS method for the analysis of different sample matrices (polar ice cores, bivalves, frozen lake sediment cores). The main limitation of LA-ICP-Q-MS measurements is the number of analysed isotopes, especially for point scan analysis of embedded particles in the ice matrix and the analysis of growth bands of bivalve shells. Analysing as many isotopes as possible is of interest to deduce e.g. the corresponding source region of embedded particles in the ice matrix. The quasi-simultaneous detection of several isotopes of transient signals is realised in ICP-Time of Flight-MS (ICP-TOF-MS) systems. The applicability of the newly developed ICP-TOF-MS system for ice core analysis in climatic research was explored in this thesis. With the present experimental setup the analysis of trace elements in ice core samples is only possible for liquid samples. The accuracy and precision compares to well established ICP-Q-MS systems. Using the Aridus II as sample introduction system the signal sensitivity was 2-10 times lower for the ICP-TOF-MS compared to ICP-Q-MS systems. Calibration studies and investigation of reference materials showed that the calibration range is limited to an order of magnitude of about 10exp4 to 10exp5 except for m/z ratios between 23 amu and 72 amu where it is even lower. The observed ...
    Description: thesis
    Keywords: 551.6 ; VJA 240 ; TWC 100 ; TWC 500 ; VAR 980 ; Spektroskopische Verfahren {Geochemie} ; Instr. Ergebn. zu Klimaänderungen und Klimaschwankungen ; Klimaschwankungen und Klimaänderungen im Quartär ; Antarktis {Glazialgeologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 185 S.
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  • 83
    Publication Date: 2021-03-29
    Description: Slope stability, submarine slides, Svalbard, Arctic Ocean, Sophia Basin. - With increasing interest in slope stability issues on continental shelves the causes and trigger mechanism of submarine slides get more and more into the scientific focus. Within the ESF EUROMARGINS project 'Slope Stabilities on Europe's passive continental Margin' (SPACOMA) sediment dynamics of megaslides along the passive continental margin north of Svalbard have been investigated. The study concentrated on identification and sedimentological characterisation of megafailure events, their dating and interpretation in relation to paleoceanography and climate history of the Svalbard archipelago. Integrated interpretation of multibeam bathymetric, sediment-penetrating acoustic (PARASOUND) and seismic data shows a multiple slope failure on the northern European continental margin, north of Spitsbergen. One huge submarine slide has been identified which was first described by Cherkis et al. (1999) - the Yermak Slide (later named Hinlopen/Yermak Megaslide). The extent of the Hinlopen/Yermak Megaslide has been revised based on new acoustic and detailed bathymetric data. Details from the side's internal structure give evidence for one main slide event followed by repeated minor events. The first slide event occurred during MIS 3 around 30 cal. kyr. BP and was characterised by highly dynamic and rapid evacuation of ca. 1.250 kmÃÂđ of sediment from the lower to the upper part of the shelf slope. During this megaslide event, headwalls up to 1600 m have been created and ca. 1150 kmÃÂđ material from hemipelagic sediments and from the lower preexisting trough mouth fan has been entrained and transported into the semi-enclosed Sophia Basin. This megaslide was followed by a secondary evacuation of debris material to the Nansen Basin accomplished by funnelling of the debris through the Littke Channel between Polarstern Seamount and the adjacent continental slope. The main slide debris is overlain by a set of fining-upwards sequences as evidence for the associated suspension cloud and ...
    Description: thesis
    Keywords: 551.307 ; 551.69 ; 551 ; Nordatlantische Polarinseln {Geologie} ; Sedimente bestimmter Regionen ; Sonstige Sedimentationsprozesse ; Paläoklimatologie
    Language: English
    Type: monograph , publishedVersion
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  • 84
    Publication Date: 2021-03-29
    Description: Sea ice, surface emissivity, emitting layer temperature, temperature profile, microwave radiometry. - Polar regions play a key role in the global climate. The information on atmospheric parameters in these regions is sparse. Among the polar surfaces, sea ice varies in extent and physical properties with region and season and so does the surface emissivity. In the present study a method to retrieve the emissivity is applied over two selected regions in the Arctic, one covered by first-year ice and the other by multiyear ice and it investigates the application of them in the improvement of temperature profile retrieval ver sea ice. The retrieval of surface emissivity is done by combining simulated brightness temperatures with the satellite measured brightness temperature. In order to determine the surface emissivity of sea ice, the observations of the microwave instruments amsu (Advanced Microwave Sounding Unit) and amsr-e (Advanced Microwave Scanning Radiometer- Earth Observing System) are used. Determination of emissivity requires the knowledge of the temperature of the emitting layer. The penetration depth of microwaves in sea ice varies between millimeters and decimeters depending on the frequency and micro-physical structure. A year-round observation of temperature profiles of sea ice from the Surface Heat Budget of the Arctic Ocean (sheba) campaign at a first-year and a multiyear ice site is used to derive a set of coefficients a and b to linearly relate ...
    Description: thesis
    Keywords: 551.343 ; VAQ 990 ; VAQ 100 ; Meereis {Glaziologie} ; Gletscheruntersuchungen im Allgemeinen
    Language: English
    Type: monograph , publishedVersion
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  • 85
    Publication Date: 2021-03-29
    Description: The hyperspectral UV-vis-NIR spectrometer SCIAMACHY will be launched aboard the European satellite Envisat. Its limb measurements will provide vertically resolved profiles of trace gases and other atmospheric parameters. No retrieval algorithms and radiative transfer models have been established for these measurements yet.In this thesis, a unique, fast radiative transfer model for UV-vis-NIR limb radiances has been developed, implemented, and validated. It takes into account the sphericity of the atmosphere and up to two orders of scattering and surface reflection. The weighting functions for all parameters are calculated from analytical formulae. A realistic instrument model with field-of-view integration and signal-to-noise computation and retrieval algorithms have also been implemented. All have been combined in the new program package SCIARAYS. The package has been applied for the characterisation of the limb measurements in several ways:The simulated weighting functions agree well with those due to full multiple scattering. Thus they may be used to calculate theoretical precision estimates and averaging kernels. In conformance with this, test retrievals with approximate weighting functions converge correctly. Therefore, the approximate weighting functions of SCIARAYS are well suited for retrievals from SCIAMACHYś limb measurements.Detailed theoretical retrieval precisions have been calculated for SCIAMACHYś trace gas targets. The conclusion is that a UV-vis-NIR limb sensor like SCIAMACHY is well suited for studying the vertical structure of the stratosphere and also of the upper troposphere above cloud top.Further investigations show that the vertical resolution of retrievals from SCIAMACHYś limb measurements can be improved beyond its geometrical limits. As a trade-off for better vertical resolution, the retrieval precision gets worse. Thus O3 profile features with 1km vertical extent will be detectable with a precision of 20-30%.
    Description: thesis
    Keywords: 551.5 ; 550.28 ; 550 ; TUA 850 ; TQI 000 ; TVA 210 ; Satellitenmeteorologie ; Geophysikalische Satellitenfernerkundung ; Chemische Zusammensetzung der Atmosphäre {Meteorologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 247 S.
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  • 86
    Publication Date: 2021-03-29
    Description: Carbon, Upwelling, Namibia, shelf, sediments. - This PhD thesis is an essential component of the 'Namibia Gas' (NAMIBGAS) project, which aims to improve the understanding of the rate and fluxes of hydrogen sulfide and methane to the sediment surface and into the water column on the Namibian shelf, which is one of the most productive upwelling systems on Earth. Organic matter degradation in the sediment drives hydrogen sulfide production, the maintenance of anoxia, and methane formation. Therefore, the primary aims of the thesis are to study carbon transformation processes within the sediment, determine the reactivity of organic carbon in the sediment and, investigate the control of microbial community structure and activity by the amount and accessibility of carbon sources. The emphasis is on linking microbial community structure (identity) to their function (activity) to provide new insights into the microbial ecology that controls carbon turnover in these upwelling sediments. By studying the stepwise degradation of organic carbon a complete process overview of organic carbon mineralization could be obtained. Firstly, the diagenetic transformation of dissolved organic carbon (DOC), in particular dissolved carbohydrates, was studied by using both biogeochemical methods and molecular techniques. The bulk sediment composition, pore water chemistry, polysaccharide hydrolysis rates, 35S-sulfate reduction rates, and the abundance of active bacteria involved in the initial and terminal processes of organic carbon degradation within the top 15 cm of the sediment from two sampling stations were determined (Chapter 2). Secondly, the diversity of bacteria from the same ...
    Description: thesis
    Keywords: 551 ; VAT 270 ; VGE 500 ; Flachsee-Sedimente {Geologie} ; Biomineralisation
    Language: English
    Type: monograph , publishedVersion
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  • 87
    Publication Date: 2021-03-29
    Description: High-resolution climate reconstruction, North Sea, annual banded proxy, Arctica islandica. - Until now, there has been no published documentation of North Sea year-to-year climate variability during the last 8000 to 10000 years. High-resolution instrumental time series of climatic and environmental data for the North Sea and the adjacent North Atlantic are only available for the last decades or a century at best. Long term paleoclimatic reconstructions in higher latitudes have been predominantly undertaken using land-based annually banded archives, such as trees, varves, glaciers, and speleothems. A suitable long-term environmental archive with annual may be provided by CaCO3-skeletons of long-lived marine invertebrates. This study evaluates whether recent and subfossil shells of the long-lived bivalve Arctica islandica from the North Sea carry feasible information on Holocene climatic and oceanographic conditions. I compared modern shells of Arctica islandica from two very different habitats, a near-coastal shallow site (German Bight) and a northerly, more central, deep site (Fladen Ground). From the latter, subfossil shells were analysed, also. This study demonstrates that Arctica from both sites provides suitable archives of marine environmental conditions in the form of (i) variations in annual shell ...
    Description: thesis
    Keywords: 560 ; TWC 500 ; VAR 990 ; VXM 200 ; VZZ 120 ; Klimaschwankungen und Klimaänderungen im Quartär ; Meeresräume {Glazialgeologie} ; Lamellibranchiata {Paläozoologie} ; Randmeere {Paläontologie}
    Language: English
    Type: monograph , publishedVersion
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  • 88
    Publication Date: 2021-03-29
    Description: Calanus simillimus, Rhincalanus gigas, grazing, biogeochemistry, biogenic silica. - The role of copepod grazing, particularly of Calanus simillimus and Rhincalanus gigas, in the biogeochemical cycles of silicon (Si) and carbon (C) in the Antarctic Circumpolar Current (ACC) of the Southern Ocean is investigated. The two grazers show differences in feeding behavior before and in response to a diatom bloom stimulated by in situ iron fertilization. The continuously high feeding activity of C. simillimus on diatoms is conducive to enhance the export of primary produced C and Si. The grazing impact of this key species is high enough to influence population dynamics in the microplankton communities of the ACC. In the pre-bloom situation, R. gigas fulfils most of its carbon requirement through grazing on detritus and thereby effectively reduces the vertical fecal flux produced by C. simillimus. It is proposed that a Copepod-Retention-System for organic material is put in place by the copepod community under High Nutrient Low Chlorophyll (HNLC) conditions. Prey switching by R. gigas from detritus to diatoms in the bloom situation lifts the grazing check on the detritus flux and enables loss of particulate C and Si from the surface layer with fast sinking fecal pellets. Results from dissolution experiments indicate that the enclosure of biogenic silica (BSi) in copepod fecal pellets prevents the dissolution of diatom frustules. Diatoms submitted to grazing of copepods and krill (Euphausia superba) dissolved 4 to 26 times slower than un-grazed controls.
    Description: thesis
    Keywords: 560 ; VJE 220 ; Geochemie der Fauna
    Language: English
    Type: monograph , publishedVersion
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  • 89
    Publication Date: 2021-03-29
    Description: Volcanology, volcanic rift zones, Madeira, fluid inclusions, thermobarometry, geochemistry, geochronology. - Madeira and the Desertas Islands show two well-developed volcanic rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). To examine a possible genetic link, volcanic structures, rock ages and rock compositions were investigated at the Desertas and São Lourenço. Barometric data derived from fluid inclusions and clinopyroxene-melt compositions indicate fractionation at multiple levels within the mantle beneath the rift zones, followed by temporary magma stagnation within the crust. Depths of crustal stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a shallow magma reservoir feeding both rifts. This suggests that Madeira and the Desertas have separated magma supply systems. 40Ar/39Ar age determinations revealed that Desertas volcanism lasted from 〉5.1 to 1.9 Ma overlapping in age with the shield phase of Madeira. Eruptive quiescence between 4 and 2.5 Ma at São Lourenço coincides with the main period of volcanism on the Desertas. Major and trace elements and ...
    Description: thesis
    Keywords: 551 ; VAD 600 ; VAD 700 ; VAE 840 ; VEF 139 ; Paläovulkanismus {Geologie} ; Regionaler Vulkanismus {Geologie} ; Rifts {Geologie} ; Balearen un Pityusen {Geologie}
    Language: English
    Type: monograph , publishedVersion
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  • 90
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VAQ 990 ; Meereis {Glaziologie}
    Language: English
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  • 91
    Publication Date: 2020-10-05
    Description: Coccolithophores, a major group of the nanophytoplankton, belong to the class Prymnesiophyceae.The cells of coccolithophores are typically surrounded by layer(s) of calcium carbonate plates, the coccoliths. Certain coccolithophores can be assigned to particular water masses or to photic zone characteristics and, therefore, single species as well as whole assemblages can be used as oceanographical indicators for the present and the past. Due to their ocean wide distribution, their large contribution to the fine grained carbonate ooze of the deep sea, their ability to photosynthesize and to calcificate they play an important role in the global carbon cycle...
    Description: thesis
    Keywords: 579.17 ; 577.7 ; 577.15 ; 579.82 ; 560 ; VJI 000 ; VU 000 ; VU 000 ; VJI 000 ; Geobiologie ; Geochemische Kreislaufmodelle
    Language: English
    Type: monograph , publishedVersion
    Format: 151 S.
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  • 92
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 560 ; TWC 600 ; VYF 200 ; VYA 500 ; VWH 300 ; VDH 320 ; Paläoklimatologie ; Pyrrophyceae {Paläobotanik} ; Paläökologie {Paläobotanik} ; Kreide {Stratigraphische Paläontologie} ; Oberkreide
    Language: English
    Type: monograph , publishedVersion
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  • 93
    Publication Date: 2021-03-29
    Description: The marine carbonate pump includes the production of calcium carbonate, CaCO3 by marine organisms and its subsequent transport to depth. The balance between carbonate production in surface waters and dissolution and accumulation in sediments influences the surface water CO2 concentration and thus the oceanś capacity to take up atmospheric CO2.Models are developed to investigate on calcium carbonate dissolution in the oceanic water column. Model results yield that dissolution in zooplankton guts contributes a significant portion of the proposed carbonate loss. Dissolution fueled by the respiration of organic matter in marine snow aggregates is very sensitive to the size and settling velocity of the aggregate, which determines the boundary layer thickness and the stability of an undersaturated microenvironment. The constraints set by field data yield that the chemical gradients between the aggregate and the bulk seawater are too small to enable significant carbonate dissolution. Furthermore, the role of the carbonate pump in regulating atmospheric pCO2 on glacial to interglacial timescales is investigated ...
    Description: thesis
    Keywords: 551.9 ; VJI 000 ; Geochemische Kreislaufmodelle
    Language: English
    Type: monograph , publishedVersion
    Format: 132 S.
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  • 94
    Publication Date: 2021-03-29
    Description: The major objective of the study is to investigate how near-surface sediment structures and other geological aspects control the nature and occurrence of cold fluid seepage. Mainly high resolution multichannel seismic data and swatch bathymetry data were used to study nearsurface seismostratigraphy, structure and seismic fluid-indicating features in two different fluid seepage provinces: Campeche Knolls, southern Gulf of Mexico and the frontal Makran, offshore Pakistan. The two areas have fundamentally different tectonic settings: The Campeche Knolls, southern Gulf of Mexico represents a passive margin influenced by salt tectonism, while the frontal Makran is the most basinward part of the Makran accretionary prism, characterized by plate subduction, sediment accretion, thrust faulting and development of sediment imbricate slices. However, they share quite a few similarities in shallow sediment structures and fluid seepage patterns...
    Description: thesis
    Keywords: 551.23 ; 553.28 ; 550 ; TSZ 100 ; VAE 880 ; TSZ 200 ; Atlantischer Ozean {Geophysik} ; Passive und aktive Kontinentalränder {Geologie} ; Indischer Ozean {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 125 S.
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  • 95
    Publication Date: 2021-03-29
    Description: Deformation, shear zone, granular, micromechanic, numerical model, discrete element method, distinct element method. - This thesis was inspired by the lack of detailed (i.e. particle scale) knowledge concerning deformation processes of mechanically weak sediments, especially intrinsically weak layers on the basal shear plane of submarine landslides. It has been known for some time that many different parameters influence shear strength and localization features. This is true not only for sediments, but also for other kinds of weak layers, such as fault gouge. These parameters include for example mineralogy (e.g. smectite, illite, quartz), sediment composition (clay, silt), sediment structure and texture (microfabric), grain size distribution, excess pore pressure, magnitude of effective stress, and deformation history. However, to date it has not been possible to rank or to quantify the influence of each of these parameters. The main goal of this study is to analyze the influence of some of these parameters and, if possible, rank and quantify them. Standard methods to examine shear strength of sediments and fault gouge are various geotechnical shear experiments. In these, a sample is sheared under defined conditions and resulting coefficient of friction, void ratio change, and other meaningful parameters are analyzed. Unfortunately, it is not possible to 'look' inside a shear box during a test and to analyze grain deformation behaviour on a microscopic scale. Therefore, this study employs a different approach to specifically address the problem of microscopic deformation processes. Here, a numerical modelling technique, the Discrete Element Method (DEM), is used. The DEM is a numerical tool based on the ...
    Description: thesis
    Keywords: 551.8 ; VAE 130 ; VAE 130 ; Geomechanik
    Language: English
    Type: monograph , publishedVersion
    Format: 138 S.
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  • 96
    Publication Date: 2021-03-29
    Description: During the last years and decades issues related to the physics and chemistry of the Earthś atmosphere have attracted much scientific and public interest. The most important problems are stratospheric ozone loss and the ò̀zone hole ́́above Antarctica, global warming and climate change, and tropospheric air pollution. The understanding of the impact of human activities on the Earthś atmosphere requires measurements on a global scale. These enable the spatial and temporal variability of the atmospheric constituents to be investigated. Recently efforts have been made to establish a global observation system comprising satellite instruments and ground-based networks. To process data supplied by the instruments which belong to the global observation system, the development of radiative transfer models and retrieval algorithms is essential. This thesis contributes to the development of the radiative transfer models and retrieval algorithms intended to interprete measurements of the spectral radiance scattered in the atmosphere or transmitted through the atmosphere in UV-Vis-NIR spectral region performed by a new-generation remote sensing satellite spectrometer SCIAMACHY. In this study, main problems of radiative transfer through a spherical planetary atmosphere compared to a plane-parallel atmosphere are investigated. An efficient spherical radiative transfer model intended to simulate SCIAMACHY limb measurements was developed and validated. The model can also be used for the interpretation of measurements performed by other space-borne instruments as well as to compute air mass factors for ground-based measurements. An approximate approach allowing the simulation of limb measurements to be substantially accelerated was developed and its accuracy was investigated. Furthermore, a numerical radiative transfer model intended to simulate SCIAMACHY occultation measurements was developed and then coupled with an appropriate selected inverse technique.
    Description: thesis
    Keywords: 551.5 ; 550.28 ; 550 ; TQI 000 ; Geophysikalische Satellitenfernerkundung
    Language: English
    Type: monograph , publishedVersion
    Format: 150 S.
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  • 97
    Publication Date: 2021-03-29
    Description: Giant shear processes shaped Africa's southern margin during the breakup of the supercontinent Gondwana. They acted along a more than 1000 km long transform fault, whose remnant structure the Agulhas-Falkland Fracture Zone stretches today from the Falkland Plateau to the southeastern margin of Africa. A study of the processes which initiated such a long-offset transform fault and acted during their active phase is essential to understand how this sheared margin developed. Africa’s southern margin is not only one of the best examples to study the sharp continent-ocean-transition zones, the marginal ridge, fracture zone, and basin structures usually associated with transform margins, but it provides the unique opportunity to study how excessive magmatic processes acted which formed a Large Igneous Province at a sheared margin. In this thesis, I use seismic refraction, seismic reflection data and plate-tectonic reconstructions to investigate the structure and dynamics of this margin. These are ideal methods as they lead to high-quality velocity-depth models showing the present-day structure across the margin and provide timing and geometries by means of plate kinematics...
    Description: thesis
    Keywords: 550 ; TSR 000 ; TSZ 200 ; VAE 880 ; VAE 890 ; VER 100 ; VEZ 200 ; Südafrika {Geophysik} ; Indischer Ozean {Geophysik} ; Passive und aktive Kontinentalränder {Geologie} ; Ozeanische Kruste {Tektonik} ; Republik Südafrika {Geologie} ; Indischer Ozean {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 157 S.
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  • 98
    Publication Date: 2021-03-29
    Description: Antarctica represents a key component in the investigation of the geological history and reconstruction of the supercontinents Rodinia and Gondwana. Remnants of the formation and disintegration of these former land masses can be found, although great uncertainties remain in the location of tectonic boundaries beneath the ice sheet of Antarctica due to general lack of outcrops and the limited amount of geological data. Space and airborne measurements are the only possibility to obtain comprehensive spatial data coverage of geophysical data over the extensive large polar areas. Common knowledge of the geological framework displays three major tectonic events which formed Dronning Maud Land (DML): the Grenvillian Orogen (1.1 Ga) build up Rodinia, the Pan-African-Antarctic Orogen (EAAO, 500 Ma) rose in the supercontinent Gondwana and finally the breakup of Gondwanaland, at around 180 Ma...
    Description: thesis
    Keywords: 526.7 ; 559 ; 538.87 ; 550 ; TSY 200 ; Antarktis {Geophysik} ; Aerogeophysik
    Language: English
    Type: monograph , publishedVersion
    Format: 174 S.
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  • 99
    Publication Date: 2021-03-29
    Description: Integrated studies of conjugate margins provide important constraints for the sequence of events of synrift tectonic and magmatic processes. The northeast Greenland margin is investigated based on seismic refraction data acquired across the continent ocean transition zone between the Jan Mayen and Greenland fracture zones. Transects of seismic velocity models reveal a clear segmentation of the margin, which is compatible with the potential field data. A crucially important observation is a thick high velocity lower crustal body which clearly decreases northwards. Excessive magmatism is inferred to have occurred during long-term rifting in the south, while reduced syn-rift intrusions account for the norhtern magma-starved margin. Asymmetries and variations across the adjacent and conjugate East Greenland and Norwegian margins, are controversially discussed in terms of the origin of the lower crustal body and magnetic spreading anomalies. Three hypothetical scenarios for the timing and formation of the high velocity lower crustal body are presented. A comprehensive subsidence analysis is established which quantifies the amount of magmatic underplating.
    Description: thesis
    Keywords: 551.136 ; VAE 880 ; TSY 100 ; VBM 000 ; VAE 880 ; TSY 100 ; VBM 000 ; Passive und aktive Kontinentalränder {Geologie} ; Arktis {Geophysik} ; Geologische Interpretation geophysikalischer Beobachtungen
    Language: English
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  • 100
    Publication Date: 2021-03-29
    Description: Seismic, marine, walvis ridge, bottom currents, climatic events. - The history of sedimentation and current activities at the northeastern flank of Walvis Ridge is investigated by a correlation of multichannel seismic data collected during R/V Meteor Cruise M49/1 in early 2001 with borehole measurements of Ocean Drilling Project (ODP) Leg 208. During Meteor Cruise M 49/1 multi-frequency seismic data were collected using two different seismic sources, in a quasi simultaneous mode in order to get best possible penetration and resolution of the sub-surface structures. Walvis Ridge divides the southeastern Atlantic Ocean into two basins, the Angola Basin to the north and the Cape Basin to the south. It is well known as an impassable barrier for bottom waters which separates Antarctic Bottom Waters (AABW) widely distributed in the Cape Basin from North Atlantic Depth Waters (NADW) in the Angola Basin. The sediments of the northeastern flank of Walvis Ridge are characterized by mostly undisturbed sequences of Cenozoic sediments, with varying thickness of ~150 m at the edge of the Angola Basin and ~450 m at the axis of the ridge. A correlation of seismic data with borehole data was accomplished by calculating synthetic seismograms using GRA density measurements of the cores and an averaged velocity model. This 'simple' event modeling allows to assign ages to the seismic reflectors and to identify key horizons/boundaries like the E/O and the K/T boundaries as well as the ELMO event and deposits of the PETM, representing Cenozoic climatic events. The seismic pattern of these target horizons shows similar properties at the different sites indicating their regional distribution. A special static correction in addition to standard seismic processing steps resulted in high quality high resolution deep sea Watergun images. A comparison between the seismic images and the magnetic core ...
    Description: thesis
    Keywords: 551.69 ; 551.462 ; 551 ; 550 ; Tiefseeseismik {Geophysik} ; Atlantischer Ozean {Geophysik} ; Geologische Bohrungen in einzelnen Regionen ; Teilgebiete {Atlantischer Ozean: Geologie} ; Marine Sedimente einzelner Meere und Ozeane {Geologie} ; Paläoklimatologie
    Language: English
    Type: monograph , publishedVersion
    Format: 133 S.
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