ALBERT

Description / Table of Contents: Contents: Foreword. - Seasonal variations of the atmospheric electric field potential gradient and their relationships to the atmospheric circulation forms / V. A. Kamyshanova. - Measurements of electric field over the Atlantic and Indian Oceans / V. P. Kolokov, V. A. Kurilov, Yu. V. Shamansky. - The electrical conductivity air over the Indian Ocean / V. P. Kolokov, V. A. Kurilov, Yu. V. Shamansky. - The upper atmosphere potential / A. V. Latyshev, E. V. Chubarina. - On the methods high-altitude atmospheric electricity measurements / A. V. Latyshev, E. V. Chubarina. - Some results of regular measurements of electrical conductivity of air / L. V. Oguryaeva, Ya. M. Shwarts. - On the analysis of the observation data concerning many-year behaviour of the atmospheric electricity parameters near the earth's surface / L. V. Oguryaeva, Ya. M. Shwarts. - On the recurrent processes in the atmospheric electric field / A. V. Tsvetkov. - The results of regular observations of electrical conductivity of air over Verkhnee Dubrovo / L. K. Cheremiskin. - On the variability of the atmospheric electricity parameters / Ya. M. Swartz, L. V. Oguraeva, A. H. Filippov. - The development of the methods for measuring the atmospheric electricity parameters / V. P. Gordyuk, L. G. Sokolenko

Description / Table of Contents: The Holocene stratigraphy in Scoresby Sund is based on climatic change as reflected by fluctuations in fjord and valley glaciers, immigration and extinction of marine molluscs, and the vegetation history recorded in pollen diagrams from five lakes. The histories are dated by C-14, and indirectly by emergence curves showing the patterns of isostatic uplift. From c. 10100-10400 to 9400 yr BP the major fjord glaciers showed oscillatory retreat with abundant moraine formation, the period of the Milne Land Moraines. The vegetation in the ice free areas was a sparse type of fell field vegetation but with thermophilous elements indicating temperatures similar to the present. From 9400 yr BP the fjord glaciers retreated rapidly in the narrow fjords, the few moraines formed are referred to the R0defjord stages and indicate topographically conditioned stillstands. At 8000 yr BP the low arctic Betula nana imigrated into the area, and in the period until 5000 yr BP dense dwarf shrub heath grew in areas where it is now absent. In the fjords the subarctic Mytilus edulis and Pecten islandica lived, suggesting a climate warmer than the present. From c. 5000 yr BP the dense dwarf shrub heath began to disappear in the coastal areas, and a 'poor' heath dominated by the high arctic Salix Arctica and Cassiope tetragona expanded. These two species, which are now extremely common, apparently did not grow in the area until c. 6000 yr BP. In lakes in the coastal area minerogenic sedimentation at c. 2800 yr BP, reflecting the general climatic deterioration.

Description / Table of Contents: Contents: 1. Climatology as a science ; 2. Climate-forming factors ; 3. Geographical distribution and variation of major meteorological elements ; 4. A brief survey of major types of climate ; 5. Changes and fluctuations of climates

Description / Table of Contents: The history of climate by A. S. Monin, Yu. A. Shishkov presents the history of the earth's climate from the contemporary positions of the general history of our planet based on the latest achievements in the field of planetology, geology, geophysics, oceanology, meteorology and climatology. The book deals with the factors responsible for climate formation on the earth, presents the major stages of the earth's history, the results of the most recent paleogeographic reconstructions. Further the book presents the history of climate proper from Pre-Cambrian to the recent time in increasing detail. The methods used for paleoclimatic reconstructions are described. Data on Pre-Cambrian glaciations and the major Fanerozoic climatological events are discussed. The book is meant, first of all, for the inquisitive reader, however, it will undoubtedly be of interest for the specialists climatologists, meteorologists, oceanographers and geophysicists.

Description / Table of Contents: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Description / Table of Contents: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Description / Table of Contents: Subsurface aspects of the ore-forming process can be described in terms of standard chemical transport parameters such as T-P gradients, mineral solubilities, solvent chemistry and volume, diffusion parameters and energy flow. These necessary factors are rather easily assessed by geochemical, isotopic and structural studies. If deposition is in the surface environment, a complex array of factors will determine the success of the natural concentration process and the chances of preservation of a deposit. Basically, most large-scale ore-forming processes involve large fluid volumes and energy sources. Many environments where these requirements are met, the modern ocean ridge and the subduction environment, are still not well understood. The need for remote-sensing techniques in the submarine environment is stressed.

Description / Table of Contents: This report first discusses the general approach for calculating the horizontal forces an ice cover exerts on a structure. Ice force determination consists of two parts: (1) the analysis of the in-plane forces assuming that the ice cover remains intact and (2) the use of a failure criterion, since an ice force cannot be larger than the force capable of breaking up the ice cover. For an estimate of the largest ice force, an elastic plate analysis and a failure criterion are often sufficient. A review of the literature revealed that, in the majority of the analyses, it is assumed that the failure load is directly related to a 'crushing strength' of the ice cover. However, observations in the field and tests in the laboratory show that in some instances the ice cover fails by buckling. This report reviews the ice force analyses based on the buckling failure mechanism and points out their shortcomings. The report then presents a new method of analysis which is based on the buckling mechanism

Description / Table of Contents: Abstract: Measurements of the concentrations of Aitken nuclei in maritime air were made near Barrow, Alaska, in June 1975 with a modified Nolan-Pollack small-particle detector. The concentrations varied from 50 to 300 particles cm^-3 depending upon meteorological conditions. The mean Aitken nuclei count was 100 particles cm^-3 for diameters greater than 2 x 10^-3 μm. Transmission electron micrographs of aerosols in maritime air near Barrow were taken. The size range was measured to be 0.01 to 2.5 μm in diameter with the most frequently observed diameter being 0.04 μm. The volume of the maritime air and the collection efficiency of aerosol particles on filmed grids for electron microscopy were measured. The aerosol concentrations were found to be 76 to 101 particles cm^-3 ; the mean concentration was calculated to be 87 particles cm^-3. The aerosol particles in the maritime air were identified by electron microscopy and selected area electron diffraction analysis. About 20% of the aerosol particles were identified, and 80% of the particles were too small for electron diffraction analysis. Sea salt particles constituted 2% of the total, and clay minerals 3%; these particles were considered to be of natural origin. Solid combustion by-products such as coagulated carbon particles and fly ash particles constituted 16%. Despite the comparative remoteness of the sampling site, the measurements indicate that many anthropogenic aerosols were found using an electron microscope.

Description / Table of Contents: A model investigation of drifting snow conditions was conducted in a hydraulic flume using a sand-water analog. Model results were evaluated to define modeling parameters that would allow quantitative correlation between measured prototype drift conditions and the model. The modeled structure was the standard plan snow fence designed by the Wyoming Highway Department and installed along Interstate Highway 80 in 1971. The performance of this system was documented by the Rocky Mountain Forest and Range Experiment Station of the U.S. Forest Service. Models of the fence were constructed for three heights and two geometric scales. Geometric scaling was based on terrain roughness and boundary layer thickness considerations, while velocity scaling was based on particle fall velocity and threshold of motion characteristics. Simulation of the atmospheric boundary layer was found to be of primary importance. Velocity scaling analysis suggested the use of a 'significant wind' concept based on a combination of velocity magnitude and frequency. Similarity of precipitation rate was not essential, and could be altered within limits to adjust the time scale. The response of the model to the shape of model elements was significant. Although the model is distorted and inexact similarity is achieved, it appears useful on a practical basis.

Description / Table of Contents: Road test sections of membrane-enveloped silt and clay soils overlain with asphalt cement concrete were subjected to repetitive dynamic plate-bearing loadings to determine their strength variations during freeze-thaw cycles. The recoverable surface deformations in the load deflection bowl were continuously measured during the loading cycles and analyzed using the Chevron layered elastic computer program to obtain the in situ resilient deformation modulus of the various section layers at different stages of the freeze-thaw cycles. The resilient stiffness of the pavement system (the total load per unit of resilient load plate deflection) was also calculated for the various freeze-thaw conditions. The modulus values of the asphalt cement concrete varied inversely with its temperature by an order of magnetide (90,000 psi to 1,300,000 psi). The resilient stiffness of the pavement system varied in the same manner by nearly a factor of eight (228.4 kips/in. to 1740.2 kips/in.). Despite the wide strength variations of the sections during freeze-thaw cycles, membrane-enveloped fine-grained soils can be utilized instead of granular materials as base and subbase layers in flexible pavements in cold regions where moisture migration is a major concern. Moisture migration did not occur at saturation levels up to 75%, thus there was no strength loss during thawing.

Description / Table of Contents: Results of measurements of salinity, grain size, substructure dimensions and crystal fabrics of the undeformed 2.15-m-thick annual sea ice sheet near Narwhal Island, Alaska, are presented. A notable observation was the formation of a dominant c-axis horizontal structure in all ice below 14 cm, including transformation to a pronounced east-west alignment of the c-axes by a depth of 66 cm. This study confirms earlier reports of the occurrence of very strong horizontal c-axis alignments in arctic fast ice.

Description / Table of Contents: The mathematical theory for the bearing capacity of river ice for vehicles is presented. The floating ice sheet is assumed to have simple supports at the shore line. Solutions are presented for loads uniformly distributed over circular and rectangular areas. Numerical evaluations are made for a number of vehicles and the results presented in graphical form

Description / Table of Contents: The results of axial double point-load tests on disk samples of snow and ice obtained from the area of McMurdo Sound, Antarctica, are presented. They show the effects of temperature, sample length, load point diameter and specific gravity on failure load. It was determined that 13 samples should be tested to obtain a representative mean strength index. The results show that the axial double point-load test has good possibilities as a rapid field test for determining the unconfined comrpessive strength of snow and ice but that further evaluation of the variables affecting test results must be made.

Description / Table of Contents: Abstract: Ageneral computer model to simulate municipal snow removal has been developed. Programs which aid in the routing of snowplows are a part of this package. Once vehicle routes are created, the simulation program can be used to assess situations varying both equipment and meteorological parameters. Time for each plow to complete its route is calculated. Considerations are made for the above variable parameters plus plowing windrow, route starting depth, overlapping truck routes and intersection delay time. The effects of storm length, snowfall rate and starting depth on total plowing time are examined in a test case.

Description / Table of Contents: Ten roofs in Concord, New Hampshire, were surveyed for wet insulation using a hand-held infrared camera. Suspected wet areas were marked on the roof with spray paint and roof samples were obtained to verify wet and dry conditions. Recommendations for maintenance and repair were made based on infrared findings, water contents, and visual examinations. An incremental economic study is presented to serve as a guide in determining the most cost-effective approach.