ALBERT

Description: Marine organic-carbon-rich deposits occur where there is an ample rain of organic particulate material to the sea floor and conditions favorable to its preservation. It was originally thought that the accumulation of organic carbon (Corg) was dependent mostly on anoxic conditions at the site of deposition; two such environments, the stagnant basin and the O2 minimum, were often cited as models. High productivity in the overlying waters has become recognized to be of greater importance. In an overall evaluation of burial of Corg in marine sediments, it is apparent that terrigenous input of organic matter is the largest source, followed by marine organic matter fixed in highly productive coastal areas receiving nutrients from land. In terms of rich accumulations of marine organic matter most likely to generate petroleum, areas of ocean upwelling along continental margins are most significant.

Description: It is well documented that animals take risk of predation into account when making decisions about how to behave in particular situations, often trading-off risk against opportunities for mating or acquiring energy. Such an ability implies that animals have reliable information about the risk of predation at a given place and time. Chemosensory cues are an important source of such information. They reliably reveal the presence of predators (or their presence in the immediate past) and may also provide information on predator activity level and diet. In certain circumstances (e.g., in the dark, for animals in hiding) they may be the only cues available. Although a vast literature exists on the responses of prey to predator chemosensory cues (or odours), these studies are widely scattered, from marine biology to biological control, and not well known or appreciated by behavioural ecologists. In this paper, we provide an exhaustive review of this literature, primarily in tabular form. We highlight some of the more representative examples in the text, and discuss some ecological and evolutionary aspects of the use of chemosensory information for prey decision making. Curiously, only one example illustrates the ability of birds to detect predator odours and we have found no examples for terrestrial insects, suggesting a fruitful area for future study.

Description: The role of cephalopod haemocyanins in oxygen transport is analysed in the light of the coordination of metabolism, acid‐base regulation and gas exchange processes. Results obtained in squid, the most active among cephalopod species, indicate that the pH dependence of their haemocyanin supports a Po2‐buffer function for the pigment. The release of base equivalents from the tissue during aerobic exercise and the minimal release of protons during anaerobic octopine formation protect arterial pH and, thus, oxygen binding. The extent of respiratory acidification and haemocyanin deoxygenation on the venous side is higher in blood returning from the mantle than from the head. In vivo blood gas measurements reported for squid and for other cephalopod species support the conclusion that CO2 accumulation and respiratory acidification of the blood occur in excess of the effect expected from the consumption of haemocyanin bound O2 and RQ values derived from protein catabolism. This suggests that a considerable fraction of the oxygen consumed by the animal enters via the skin, especially in the mantle. Model calculations demonstrate that skin O2 uptake in the mantle increases during activity in squid. In other cephalopod species like cuttlefish, the special process of arterial CO2 binding to oxygenated haemocyanin and its release during venous deoxygenation may provide the excess CO2 required for venous acidification. All of these processes allow the classical Bohr effect to function supporting oxygen loading at the gills and oxygen unloading in the tissues. The large pH‐dependent cooperativity and the Bohr effect combine to maximize the Po2‐buffer function of the respiratory pigment. These adaptations probably evolved after the ancestors of modern cephalopods lost their shells and locomotor activity assumed a greater role in their lifestyle.

Description: A number of reproductive indices were compared with a subjective maturity scale for assessment of Loligo forbesi maturity. The ratio between nidamental gland length and mantle length corresponded well with female maturation, as did the ovary mass-soma mass and nidamental gland mass-soma mass ratios. For males, the ratio between spermatophoric complex mass and somatic mass was found to be the most suitable for maturity assessment. The timing of recruitment and maturation of L. forbesi in Irish waters was described from the size and maturity of squid in commercial landings in the south of Ireland during the years 1991–1993. Immature squid first appeared in commercial catches in July and August, and this represented the main period of recruitment. A second period of recruitment was apparent in December 1991, but was not identified in the 1992–1993 season. Mature females were present in the commercially exploited population between November and April, with a small number also found in the summer. The abundance of egg masses was used to indicate timing of spawning. Egg masses recovered from the Cork coast indicated that peak spawning occurred during the winter months, but continued on a small scale for much of the year.

Description: Some deep water squids are known to achieve neutral buoyancy by storing ammonium in their body tissues. The Cranchiidae use a unique coelomic cavity to store ammoniacal fluid; in 15 other families, ammonium appears to be sequestered in either vacuoles in the active body tissues or in a gelatinous outer layer. The hypothesis that these squids form a single lineage is here reconsidered through reviews of morphological characters that could support this hypothesis and physiological mechanisms that could contribute to the repeated evolution of ammonium storage. No readily apparent character identifies all ammoniacal squids as belonging to a single lineage, although 5 families of tissue ammoniacal squids appear to be monophyletic. If the elaborate funnel locking apparatus of this group arose within the clade, it is not homologous with that in other taxa, refuting a basis on which close relationships were suggested for ammoniacal squids. Given the limited data available, we question whether some squids considered to be ammoniacal may develop these characters as a result of senescence. Squids are all thought to derive energy from amino acid catabolism, produce large quantities of ammonia and have very low blood pH's which effectively remove ammonia from cells that produce it. They also minimize H+ ion transfer between muscle cells and blood. These features may be important preadaptations for ammonium storage. Given the physiological data, and the absence of morphological evidence supporting monophyly, we argue that ammoniacal squids be best considered to be a polyphyletic group, evolved in parallel.

Description: Horizontal starch gel electrophoresis was employed to investigate levels of genetic differentiation between 13 samples of the neritic squid species Loligo forbesi Steenstrup obtained from throughout the majority of its known geographical range. Six enzyme loci identified in a preliminary study as being polymorphic were screened for variation between samples. No significant differences in allele distribution were detected between any of the samples obtained from the Faroe Bank in the north to Lisbon in the south, suggesting that squid throughout this range in the vicinity of the continental shelf are able to maintain panmixia, and effectively belong to a single population sharing a common gene pool. No clinal variation in allele distribution was detected throughout this range, a result which complements the findings of a detailed morphological companion study of the same individuals. Comparison of this homogenous European continental shelf population with squid from the Azores revealed highly significant (P〈0.01) differences in allele distribution at five of the six polymorphic enzyme loci studied. A genetic identity value (I) equivalent to 0.93 over 33 loci was obtained. Analysis of F-statistics suggested migration rates between sites to be as low as one individual per five generations, a rate deemed insufficient under most models to prevent divergence by random genetic drift. The large distance and oceanic depths separating the Azores from continental Europe seem to present an effective barrier to gene flow to L. forbesi, a squid belonging to a family considered to be confined in distribution to relatively shallow, near coastal waters. The two populations of squid in the Azores and along the European continental shelf currently both ascribed to L. forbesi should therefore probably best be regarded as relative subspecies.

Description: Beak lengths (lower rostral length and upper rostral length) were taken for a sample of Moroteuthis ingens which were captured on the Chatham Rise, New Zealand. Beak lengths were plotted against both mantle length and wet weight to determine the relationship between these parameters for future use in biomass estimates in predator analysis. Although M. ingens is markedly sexually dimorphic, with females reaching 5 times the weight of males, there was no obvious sexual dimorphism in either lower or upper rostral length. This resulted in sex-specific relationships between both LRL and mantle length, LRL and weight; and URL and mantle length, and URL and weight. Males appeared to have a curvilinear relationship between beak length and mantle length and beak length and weight (even for log-transformed data). There was also considerable spread in the data in the plot between beak length and weight for females of similar weight. These characteristics of the data makes biomass estimates based on rostral length measurements for this species difficult. Other beak parameters may prove more useful for estimating biomass of M. ingens.

Description: Body size at sexual maturity, egg-size distributions, and potential reproductive output have been estimated for female and male squid, Loligo forbesi Steenstrup, off the west coast of Scotland. Two size modes at maturity were found in both sexes, but separation into size cohorts was more pronounced in males (180 and 350 mm mantle length, ML). Preliminary ageing studies based on statolith ring-counts suggest that these size modes are not due to different age groups at breeding. Females have a single size mode of mature eggs in the proximal oviduct, but may have at least two size modes of eggs within the ovary. This finding is interpreted as evidence of batch-spawning in this squid. There was a weak relationship between total egg numbers (range 1000 to 16000) and body size (range 196 to 318 mm ML) and between mature egg size and body size. Males showed a strong positive relationship between spermatophore length and body length but a weak relationship between total number of spermatophores and body size. The results are discussed in the context of flexibility of breeding strategies in the loliginids and variety of life-cycle patterns.

Description: This study assesses the potential of the tropical loliginid squid Photololigo sp. to lay multiple batches of eggs and examines changes in somatic growth during reproduction. Histological analysis of the ovary and the relative size of the oviduct to mantle weight and ovary weight were used to determine the potential for multiple spawning. Ovaries of mature females always had immature and mature oocytes present, suggesting that not all the oocytes were maturing simultaneously and that multiple batches of eggs were being produced. Furthermore, poor correlations of oviduct weight with body size and ovary weight indicated that mature oocytes were not accumulating in the oviduct for a single spawning event. Both these observations supported the hypothesis that Photololigo sp. has the potential to lay multiple batches of eggs throughout its life. Specific growth rates, length-weight relationships, relative growth of somatic and reproductive tissue and microscopic assessment of muscle tissue were compared between immature and mature females. Growth rates of immature females were almost twice as fast as those of mature females. Mature females also had no large muscle fibres present, suggesting that energy for reproduction was mobilised from the muscle tissue.

Description: The quick development of the skull structure is of vital importance to animals during the early stages of life given that here in are located the governing center and the mechanisms which make feeding possible. However, the rhythm of growth changes thoughout the life cycle, a process which is particularly manifest in the proportionate head/body growth. The mouth structures grow proportionately to head growth. These accentuated changes in the anatomy of the animal could be reflected in its behavioural pattern (migrations between two areas in the case of some species and significant changes in diet connecting to these migrations). Scomber japonicus (Pisces. Scombridae) and Illex coindetii(Cephalopoda, Ommastrephidae) both undergo significant changes in the rhythm of growth of their respective mouth structures when they reach around 13-15 and 14-20 cm of total body length (mantle length in cephalopods) respectively. In Illex coindetii there are also differences by sex, being the changes of growth at 15 cm in males and around 20 cm in females. In both of these species, this change in the rhythm of growth implies a significant variation in dietas the consequence of a shift of habitat.

Description: Two species of third-stage larvae of the family Anisakidae are described from the Japanese common squid (Todarodes pacificus Steenstrup) from the Sea of Japan. The larvae of 1 of them, Anisakis simplex (Rudolphi, 1809), commonly occur encapsulated in the viscera of squid, whereas those of another 1, identified as Lappetascaris sp., are found free in the mantle musculature. The latter, characterized by the presence of a very long ventricular appendix, a conspicuous esophageal gland, and the structure of the cephalic end (presence of sclerotized supports of lip anlagen), previously were reported by various authors as members of the genera Contracaecum, Thynnascaris, or Hysterothylacium. It appears that the larvae form the mantle of squid belong to a hitherto undescribed Lappetascaris species whose adults parasitize an, as yet unknown, predatory marine fish.

Description: Cephalopod research in Thailand has been underway since 1978 with the goal of developing successful mass-culture techniques. Results of mass cultivation have demonstrated several favorable aquaculture characteristics of cephalopods, i.e., high growth rates, short life cycle, high fecundity, high hatching rate, and absence of true larval stages. Three species are being cultured: bigfin squid, Sepioteuthis lessoniana; spineless cuttlefish, Sepiella inermis; and pharaoh cuttlefish, Sepia pharaonis. They were listed in declining order of production and suitability for aquaculture. About 2 million cephalopod seed have been produced and released annually since 1990 to enhance natural stock. Biohistory, behavior and water quality requirements are also being studied in order to supply basic information for aquaculture. However, there are also several obstacles, particularly development of cost-effective feeds.

Description: The rigid, polycrystalline otolith of teleosts is a side-branch of the general evolution of endolymphatic otoconia that extends from the sharks and rays to the higher vertebrates including man. The transition from the otoconial mass found in the endolymphatic sac of sharks and rays to the rigid polycrystalline otolith of teleosts probably occurred by progressive fusion of otoconia from a loose aggregate to a semi-rigid mass. Traces of the primitive fused otoconia type of otolith still occur in the otherwise polycrystalline otoliths of some teleosts, and a few species of fish retain otoliths that are probably similar to the primitive fused otoconia type of otolith. The morphology of the fusion of otoconia varies according to the polymorph of calcium carbonate that is involved, as well as the particular crystal habit of the polymorph. Analyses of the size distributions of the polymorph-specific morphologies and crystal structure of otoconia suggest that three physical chemical processes, Ostwald ripening, Keith-Padden spherulitic growth and carbonate cementation are significant in the chemistry of fusion of otoconia in the evolution of the aragonite teleost otolith. Predictions of otoconia growth rate from the theory of Ostwald ripening can be compared with predictions from the Keith-Padden theory of spherulitic growth.

Description: One of the most puzzling characteristics of sea-floor morphology is the occurrence of anomalously shallow, fracture-zone–parallel, oceanic transverse ridges. A model is proposed for the formation of transverse ridges near lat 21° and 24°N on the Mid-Atlantic Ridge in which the differential responses of large-offset and small-offset fracture zones to recent changes in spreading direction result in the generation of normal faults that coincide with the off-axis traces of fracture zones. Numerical models of the flexural response of the lithosphere to normal faulting suggest that modest amounts of extension (〈5 km) along low-angle faults (〈45°) are responsible for the transverse ridges.

Description: This study experimentally examines potential shifts in epilithic bacterial biomass and productivity in response to variations in epilithic algal biomass and labile dissolved organic carbon (DOC) during stream biofilm colonization. I predicted that epilithic bacteria would respond positively to allochthonous DOC early in biofilm colonization and respond positively to increased algal biomass late in biofilm colonization. Using once-through, experimental-stream channels, a 2 × 2 factorial design was employed in which light (shaded vs. non-shaded) and labile DOC (glucose-amended vs. ambient) were manipulated. Ceramic tiles were used as substrates for biofilm colonization and were sampled at different colonization stages. Shading significantly reduced chlorophyll a, live-algal bio-volume, and ash-free dry mass throughout colonization. Bacterial biomass increased significantly during biofilm colonization, but was not significantly different among treatments. Incorporation of [〈sup〉3〈/sup〉H]thymidine into bacterial DNA, which was measured as a surrogate for bacterial productivity, was significantly greater in the glucose-amended channels throughout colonization, but it increased in the unshaded, ambient treatment in late colonization as well. These results suggest that labile DOC in the water column can potentially function as a control for epilithic bacteria throughout biofilm colonization, whereas epilithic algae can stimulate bacteria late in biofilm colonization in productive stream ecosystems.

Description: We establish the relationship between shell oxygen(6le0) and carbon (S13C) isotopic composition and size and thickness for the planktonic foraminifers Orbulina universa and Neogloboquadrina dutertrei (size only). The degree to which the stable isotopic composition of individual shells correlates with shell size limits their applicability to paleoenvironmental reconstructions and must therefore be examined carefully. We selected shelis from four intervals from a western and an eastern equatorial Atlantic core corresponding to the glacialhnterglacial extremes of the last 150,000 years (isotope stages 1, 2, 5e, and 6). We estimate the shell thickness of 0, universa using a mathematical relationship between the geometry and physical properties of a calcite sphere. Thickness measurements on selected shells of this species confirm that the calculated thickness, once it has been corrected for shell porosity, is equivalent to the measured thickness. There are no consistent trends between 0. universa 6l80 or 613C values and shell size or thickness for the size range 450-900 pm. For N. dutertrei, there are no systematic fluctuations between shell 6l80 and size between 450-700 pm. N. dutertrei shells larger than 500 pm show no 613C : size relationship. We are confident that the stable isotopic variability contained in 0. universa (450-900 pm) and N. dutertrei (〉500 pm) assemblages analyzed does not fluctuate with differences in shell morphology. The stable isotope data from these size ranges can thus be confidently used for paleoenvironmental reconstructions.

Description: The only known population of coelacanths, in the Comores, western Indian Ocean, is endangered by human predation. Historical catch data from Grande Comore reveal that annual catch rates increased steadily from 1954 until the 1970s. This trend was temporarily interrupted due to an international policy introducing motorized boats and promoting offshore fishing techniques. Coelacanths are only caught from traditional unmotorized outrigger canoes as an incidental by-catch of deep water line fishing. A complete survey of all motorized and unmotorized vessels in 1995 at Grande Comore in comparison to earlier years indicated that a recent decreased use of motors and increase of unmotorized canoe fishing has led to an increase in coelacanth catches. Conservation measures and strategies for reducing the fishing pressure exerted on coelacanths are discussed. The southwest coast of Grande Comore should be designated as a nature reserve and protected area where immediate protection measures should be taken, an opinion which is supported by Comorian authorities.

Description: The Sula Ridge Reef complex, a large cold-water coral reef structure on the mid-Norwegian shelf built mainly by Lophelia pertusa, was mapped entirely using a high-resolution sidescan sonar. In addition, a dense echosounding grid, underwater vide observations and dives using the manned research submersible Jago, provided precise high-quality ground-truthing, and allowed a detailed interpretation of the reef structure and its surrounding geological features. The result of this visual sidescan sonar interpretation is a facies map that delineates different potential habitats within the coral reef environment, e.g. live coral reef, dead coral structure and sediment-covered coral/rubble, etc. In an attempt to improve this interpretation, computer-assisted image analysis was applied to a representative section of the sonar data to try to reveal patterns 'invisible' to the human eye (using the TexAn software). Texture analysis uses Grey-Level Cooccurrence Matrices (GLCMs) to calculate statistical indices quantifying the distribution of grey levels and their spatial relationship within the image. For example, regions of rough textures (coral mounds) can be distinguished from areas of smooth background sediment or zones of heterogeneous texture resulting from sediment-covered coral debris and dropstones colonized by sponges. The results of the computer-assisted approach were carefully compared with the earlier visual interpretation ro identify the differences and to see where the interpretation could be improved. Overall, it shows that texture analysis is a useful tool to make facies/habitat mapping from sidescan sonar easier and faster, revealing details overlooked during visual interpretation. However, validation of certain details by an experienced interpreter is still necessary, and therefore visual and computer-assisted interpretation should be used as complementary tools.

Description: Verklebte Fischerei-Netze, gestörte Organismen, schwere gesundheitliche Schäden, eingehandelt im "ach so sauberen Seewasser", sind die Folgen einer unsichtbaren Invasion. In den letzten 150 Jahren haben sich alleine in Nord- und Ostsee mehr als 100 neue Arten angesiedelt, die aus fernen Regionen stammen. Nichtheimische Arten neigen zur Massenvermehrung und richten millionenschweren Schaden an. Aus dem Chinesischen Meer stammende Algen bevölkern inzwischen unsere Randmeere, die Sandklaffmuschel - ursprünglich an der nordamerikanischen Ostküste beheimatet - tummelt sich im Wattenmeer, der Schiffsbohrwurm wurde im Ballastwasser herangefahren. Mangels Masse begnügt er sich mit dem Verzehr hölzerner Hafenanlagen. Aus China stammt die schädliche Wollhandkrabbe. Eingeschleppt wurde auch die Pantoffelschnecke.

Description: Both enantiomers or trichodenones A, and B and C, the cytotoxic metabolites from a strain of Trichoderma harzianum from the sponge Halichondria okadai, have been synthesized from (R)- and (S)-4-hydroxy-2-cyclopentenones as chiral building blocks, respectively. These syntheses allowed assignment of absolute stereostructures for these natural products.

Description: Pliensbachian and Toarcian Ostracoda first described by Exton (Geological Paper, Carleton University, Ottawa, 79: 1–104 1979) from the Lusitanian Basin, west-central Portugal have been re-examined. As a result, a greater diversity in the Ostracoda (80 species) is now recognized. Two species are newly described (Eucytherura zambujalensis sp. nov., Ektyphocythere mediodepressa sp. nov.) from the marls and calcareous shales of the Maria Pares Hill section near the village of Zambujal. Poor preservation precludes a complete taxonomic review of the present material. Five ostracod zones are proposed; Gammacythere ubiquita–Ogmoconchella gruendeli Zone, Poly cope cerasia–Polycope cincinnata Zone, Liasina lanceolata–Ogmoconcha convexa Zone, Bairdiacypris rectangularis–Kinkelinella sermoisensis Zone, and Cytherella toarcensis-Kinkelinella costata Zone. Although the ostracod assemblages possess strong similarities to those described from Northwest Europe, some of the Zambujal assemblages are dominated by the genus Polycope. A marked faunal turnover, in association with the extinction of the Metacopina occurs in the lower Subzone of the tenuicostatum Zone of Lower Toarcian age. These faunal events are discussed in relation to changing environmental conditions.

Description: In a recent paper I stated that the hypothesis of a continuously cooling earth had “consistently failed to lead to any adequate explanations of fissure eruptions and other volcanic and tension phenomena, mountain-building processes and their distribution in time and space, and the alternation of marine transgressions and recessions”. It seems to be desirable that I should further justify this sweeping integration of objections, for Dr. Harold Jeffreys, who has actively explored the consequences of this theory during recent years, takes exception to my discouraging view of the position, and claims that the alleged failures include the principal successes of the theory. The evidence on which my summary indictment was based will be reviewed in this paper; and attention will be directed to certain other phenomena—such as the growth of geosynclines—of which the significance has not yet been generally realized. As a preliminary it will be convenient to discuss the gradually converging evidence bearing on the thickness and substructure of the continents.

Description: A new image of the French continental crust between Brabant (Belgium) and the Basque province of Spain is presented on the basis of considerable recent geological and geophysical information as well as the compilation and reInterprétation of previously available data. The resulting section, which shows the main basement structures to a depth of 45 km, also is the first nonspeculative image of the westernmost part of the Variscan orogen. The French Global Geoscience Transect reveals a complete picture of this orogen between its remnant root and the surface. The divergent thrusts are bounded on the north and in the south by the old Brabant and Ebro-Aquitaine cratons, respectively; these thrusts also involve two previous plate boundaries. The lower part of the orogen is limited by a layered lower crust, probably of Permian age. Near the surface the Hercynian orogen is buried—near the northern end of the transect by the Paris Basin, which can be considered an eastward extension of the English Channel, and in the south by the South Armorican continental margin, which makes a transition between the oceanic crust of the Bay of Biscay and the axis of the Variscan orogen. In this area, the deep Parentis graben is located at the site of pronounced crustal thinning, since only 7 km of Hercynian crust are now preserved.

Description: A non-Fickian physico-chemical model for electrolyte transport in high-ionic strength systems is developed and tested with laboratory experiments with copper sulfate as an example electrolyte. The new model is based on irreversible thermodynamics and uses measured mutual diffusion coefficients, varying with concentration. Compared to a traditional Fickian model, the new model predicts less diffusion and asymmetric diffusion profiles. Laboratory experiments show diffusion rates even smaller than those predicted by our non-Fickian model, suggesting that there are additional, unaccounted for processes retarding diffusion. Ionic diffusion rates may be a limiting factor in transporting salts whose effect on fluid density will in turn significantly affect the flow regime. These findings have important implications for understanding and predicting solute transport in geologic settings where dense, saline solutions occur.

Description: Mayotte fore-slopes exhibit a distinct pattern in overall morphology, starting in the deep with an unlithified sedimentary wedge and slope, followed upwards by a cemented slope, and finally by a steep, almost vertical wall. On top of the wall, drowned reefs occur. Dated corals may reveal the history of sea-level changes indicating pristine reef growth during late isotope stage 3 (at 55–24 ka) at a present-day water depth greater than 80 m. A maximum sea-level drop of 150 m occurred during the last glacial maximum, around 20 ka. This lowering of sea-level is documented by karst features such as small caves and corroded and jagged surfaces. The phase of deglaciation is recorded by two give-up reef levels at 100–90-m water depth and 65–55-m water depth which we may relate to the Bølling (14 ka) and post Younger Dryas (11.5 ka) meltwater pulses, known from the deep-sea record.

Description: Knowledge of ambient optical noise is essential for designers of free space optical links, for designing resilient circuits. An experimental characterisation of the most commonly encountered ambient optical radiation is presented. The study includes tungsten filament sources, low and high frequency fluorescent lights, IR headphones, TV remote controls and daylight. Practical means to reduce their influence on the performance of the links are also given. The results are also valuable for setting a standard way of comparing wireless IR links, based on testing their performance under such ambient noise.

Description: The structure and location of the seminal receptacles of 14 species of Abralia, eight species of Abraliopsis, three species of Enoploteuthis, and Watasenia scintillans (Berry), of the family Enoploteuthidae, are described. Although the receptacles in Abralia, Abraliopsis, and Watasenia are situated on the dorsal side of females in the proximity of the collar, they exhibit variability in specialization and position. The receptacles of Enoploteuthis are less specialized and are situated elsewhere within the mantle cavity.

Description: Rates of petroleum seepage must ultimately be related to the rate of supply from below. This could be either from a leaking accumulation or directly from the source rock itself. However, many things can happen during migration to the surface, such that the relationship between trap leakage rates and surface seep rates remains obscure. We calculate the potential flux rates of gas leakage across seals and compare these with measurements of fluxes for three seepage sites on the European continental shelf. We conclude that seepage flow rates can be modeled effectively by assuming Poiseuille flow through the matrix of mudstone seals. Flow rates calculated in this way are about 0.4-1.0 m3 gas/m2/year, consistent with field observations.

Description: In the present work ion chromatography (IC), differential pulse anodic (DPASV) or cathodic stripping voltammetry (DPCSV), and Zeeman graphite furnace atomic absorption spectroscopy (ZGFAAS) were applied to the determination of heavy and transition metals in wine. The matrix is degraded by oxidative UV photolysis in a digester equipped with a high-pressure mercury lamp. The temperature of the sample is maintained at 85 ( 5 °C by a combined air/water cooling system. This procedure has decisive advantages if compared with other sample pretreatment techniques. Most organic wine constituents degrade in 〈1 h, whereas metals quantitation remains unaffected by UV radiation, with the exception of manganese. The clear solution is directly analyzed for most common heavy and transition metals such as cadmium, cobalt, copper, iron, lead, nickel, and zinc. In the absence of standards, the results obtained by different techniques are compared and are found in good agreement. All of the considered techniques appear to be equivalent, but ZGFAAS is more time-consuming because it does not permit multielement analyses.

Description: VHF telemetry was used in November and December 1995 on 8 Humboldt penguins Spheniscus humboldti breeding at Pan de Azúcar Island (26°S, 70°W), Northern Chile, to determine at-sea behaviour of the birds. We obtained 2710 locations, 90% of which were within a radius of 20 km around the island. Mean travelling speed of the birds was 0.92 m s-1 and speed distribution showed peaks at 1.6 and 3 m s-1. Penguins travelling between foraging areas remained submerged for an average of 8.4 s between surfacings, whereas foraging dives lasted on average 61 s. The analysis of 79 complete foraging trips showed that tracks deviated from a straight course, and range (maximum distance from island) was only 0.37 times total horizontal distance swum. Birds did not forage synchronously or in the same foraging areas. However, foraging ranges were correlated between birds, indicating similar search strategies during periods of low food availability. The results obtained here via VHF telemetry agreed well with those of previous studies employing satellite transmitters and data loggers.

Description: It is shown that where μ̅s is the average cosine of scattering, then for any set of photons that undergoes exactly n scatterings per photon, the average cosine after scattering is μ̅0μ̅s n, where μ̅0 is the average cosine of the photon flux before scattering. For a set of photons that has traversed distance d through a medium with scattering coefficient b, the average cosine is μ̅0 exp[-bd(1 - μ̅s)]. For water bodies in which loss of upward-scattered photons through the surface is small enough to be disregarded, the value of μ̅c (the average cosine of all the photons instantaneously present in the water column) for any given incoming flux of photons with average cosine μ̅0 is determined entirely by the inherent optical properties of the water in accordance with μ̅c= μ̅0/[1 + (b/a)(1 - μ̅s)], where a and b are the absorption and scattering coefficients.

Description: Calcareous algae are generally considered as good palaeoenvironmental indicators, but devoid of importance for bio- or chronostratigraphy. During the last two decades, authors have reconsidered this view, and certain groups of algae, especially dasyclads, are considered valuable for biostratigraphy. This paper presents the stratigraphical range of two groups of green algae, dasycladales and caulerpales. The genera and species with potential as index taxa are indicated, together with the characteristic assemblages for different time intervals, and the most important events in the evolution of the two algal groups during the Phanerozoic.

Description: Alkaline volcanic rocks including nephelinites, basanites and trachybasalts dredged from the volcanic pedestal of Rakahanga Atoll and from a volcanic edifice with 100 satellite volcanoes at the eastern edge of the Manihiki Plateau, ca. 40 km southwest of the atoll, fall well within the category of EM-type ocean island basalts. They indicate a hotspot involvement during the formation of the plateau basement. The rocks are thought to be products of explosive eruptions which took place subaerially or in shallow water in the Aptian. The volcanoes, together with other volcanic eruption centers, most likely were responsible for the formation of the 230 m thick volcaniclastite layer which rests on the basement for at least 5000 km2 of the eastern part of the Manihiki Plateau. Erosion has prevented any substantial sediment cover on the volcanic cone field and most of the slope of Rakahanga and thin pelagic limestones were deposited instead at least since the Maastrichtian.

Description: Most highly fecund marine fish show a steep decline in natural death rate from egg to first maturity, after which the natural mortality rate remains constant, or may even increase with age for old animals. Relatively few investigations have quantified early life-history mortality vectors for short-lived invertebrate stocks, but this overall picture is also true here for species with planktonic life stages such as penaeid shrimps, and for squids. If M decreases rapidly with age, one logical approach to demographic analysis is by subdividing the lifespan into intervals which increase in duration in proportion to the age up to the start of each interval. This time subdivision strategy is referred to as `gnomonic’. Earlier work (Caddy, 1990) showed that if a reciprocal mortality function applies with age, the product of the instantaneous annual rate of natural mortality and interval duration should be roughly constant for gnomonic intervals. This working hypothesis is shown to produce similar results to the reciprocal function for Mt, but allows a simpler approach to generating realistic life history Mt vectors in the absence of direct estimates of M for stock assessment. Values of a constant probability of death, G = Mt Δt, were used to generate vectors of M-at-age for a gnomonic series of intervals from hatching up to the mean parental age. The value of G is found by iteration that results in 2 survivors from the mean population fecundity by 1 year of age, under the assumption of steady-state population replacement for an unexploited stock. The natural mortality rate in the final, longest interval was assumed to correspond to the ‘constant adult M’ value used in stock assessment. Two extremes of reproductive strategy were chosen by comparison with data from for annual species of cephalopods or penaeid shrimps: cephalopods such as Sepia sp. and Rossia sp., with few, large yolky eggs (and/or parental care), occupy one extreme, and are contrasted with high fecundity penaeid shrimps and at least some Illex squids. The first category has a low fecundity (130–150 eggs, and a K-selected reproductive strategy). Values of ‘adult M’ of the order of 1.0–1.3 are predicted for the last 60–80% of the annual life span. The high fecundity category (200 000 eggs or more) are opportunistic spawners such as many penaeids and some oceanic squids, and follow an r-selected reproductive strategy. An instantaneous value for pre-spawning M of the order of 2.8–3.4 is predicted for the same period mentioned above. Neither range of values falls outside those in the literature, for which a brief summary is presented. An important research question relates to the order of magnitude of post-hatching mortality under population stability: it is suggested that irrespective of the specific model used for changes in M with age, this falls rapidly from an initial rate of some 50–75% per day for short-lived, high fecundity species in the 2 days following hatching, unless adult M values are much higher than above, and of the order of 25–40% for the low fecundity organisms over the same initial interval.

Description: The acoustic response from areas of varying nodule abundance and number densities in the Central Indian Ocean has been studied by using the echo peak amplitudes of the normal incidence beam in the Multibeam Hydrosweep system. It is observed that in areas of higher nodule abundance, the acoustic response is more deterministic. The coefficient of variation of the echopeak amplitude is observed to be the highest for areas with medium nodule abundance and number densities.

Description: Some aspects of the atmospheric chemistry of methyl thiolformate (CH3SCHO), a recently detected intermediate in the oxidation of dimethyl sulfide, have been investigated at 298 K and 1000 mbar total pressure in large reaction chambers using long path in situ FTIR absorption spectroscopy for the analysis. Rate coefficients of (1.11 ± 0.22) × 10-11 and (5.80 ± 0.80) × 10-11 cm3 molecule-1 s-1 have been determined for its reaction with OH radicals and Cl atoms, respectively. The UV spectrum of CH3SCHO has been measured in the range 220−355 nm and a lower limit of 5.4 days determined for its atmospheric photolytic lifetime. Detailed product analyses have made for the OH and Cl initiated photooxidation of CH3SCHO. Strong SO absorption bands observed in both systems are tentatively assigned to CH3SOCHO in the OH system and to CH3SOCl in the Cl system. The first gas-phase spectra of CH3SCl and CH3SOCl are also presented. The results are discussed with respect to the atmospheric chemistry of CH3SCHO and possible consequences for the photooxidation mechanism of dimethyl sulfide.

Description: oder: wir schreiben das Buch "Antarktisreisen leicht gemacht"

Description: Abstract The famous association of metagabbros, eclogites, glaucophanites, jadeite rocks and ultramafics from the island of Syros forms a distinct lithostratigraphic or tectonic unit. It is interpreted as a high-pressure metamorphic ophiolite suite. This paper provides geochemical and Sr-isotope constraints on the geotectonic setting in which the magmatic protoliths of the Syros metabasites were formed. A compositional gap exists between the metagabbros with Mg-numbers [Mg# = Mg/(0.85Fetot + Mg) atomic ratio] of 0.75-0.88 on the one hand and eclogites and garnet-glaucophanites on the other hand with Mg# of 0.35-0.62, and maximum total iron contents of up to 18 wt.% FeOtot. Metagabbros from various localities and glaucophanites collected around Manna form geochemically coherent groups with smooth correlations between compatible as well as immobile incompatible elements and Mg#. By contrast, the behaviour of immobile incompatible elements, and to some extent also of compatible elements, is highly unsystematic in the eclogites and garnet-glaucophanites. Also, the more mobile elements display a wide scatter in all rocks. This, in conjunction with the unsystematic variation of Sr-isotopes, is thought to be due to secondary alteration. From the strong correlation of Ni and Cr with Mg# and the flat REE patterns lacking Eu-anomalies, a cumulus nature is inferred for olivine, clinopyroxene, and spinel, associated with intercumulus formation of plagioclase in the magmatic protoliths of the metagabbros. There is no direct genetic link between these rocks and the precursors of the Manna-type glaucophanites with REE characteristics typical of N- to T-type MORB. The extremely high geochemical diversity of the eclogites and garnet-glaucophanites from Syros favours individual evolution of their protoliths in small magma bodies as suggested for superferric eclogites from the Western and Ligurian Alps, as well as the ferrogabbros from the ophiolites of the Northern Apennines. From the geochemistry of the Syros metabasites along with the initial 87Sr/86Sr ratios of the metagabbros between 0.7031 and 0.7033, as well as an eNd value of 7.7 from a garnet glaucophanite, the magmatic protoliths are inferred to have formed in a back-arc setting. By analogy to the association of gabbros and ferrogabbros adjacent to the Atlantis II fracture zone of the SW Indian Ridge, we further suggest an origin at a spreading ridge in proximity to a transform fault.

Description: A model is presented which tests the representation of the maturity process in terms of gonadosomatic indices (GSI) in chokka squid Loligo vulgaris reynaudii. It assumes that the true maturation process is reflected by the results of histological investigation, which cannot be used in large-scale ecological work in the field. However, the maturity scales used in ecological studies define some morphological categories which can be linked directly to microscopic development. Therefore, the overlap of GSI ranges for each morphological maturity category may be used to judge how well the GSIs represent the histological stages. Results have shown that the overlap is large and that GSI cannot be recommended as adequately reflecting the maturation process in squid. A morphological scale of maturity with possible broad applications in exploited families of squid is proposed as a better representation of the maturation process than GSI.

Description: Morphological differences between paralarvae of two loliginid squid species common in southern African waters (Loligo vulgaris reynaudii and Lolliguncula mercatoris) are described. The differences are: Loligo — "cheek patches" consisting of four dark chromatophores, nine large dark dorsal chromatophores on the mantle, tentacular clubs broad and much wider than tentacle stalks, proximal row of three club suckers with others tetraserial, suckers large enough to appear crowded on the club surface; Lolliguncula — "cheek patches" with three dark chromatophores, two pairs of" large, dark dorsal chromatophores on the mantle, tentacular clubs narrow, proximal club suckers arranged in three pairs, suckers small, not particularly crowded. Relationships with other myopsids are briefly discussed.

Description: The natural feeding of 485 Octopus mimus (164 to 3088 g) was studied in relation to the species' life cycle and environmental seasonal variations off the north of Chile from autumn 1991 to summer 1992. Analysis of digestive-tract contents revealed that O. mimus preyed upon 25 different prey items belonging to five zoological groups (Teleostei, Mollusca, Crustacea, Echinodermata and Polychaeta). Cannibalism was only occasional. The results indicate that the diet and food intake of this species are significantly affected by sex and maturation. Senescent individuals ingest a small amount of food, and their diet is mainly based on small, not very motile prey. The food intake, expressed as body weight, of non-senescent individuals is higher in females than in males. Seasonal changes in sea-water temperature seem to be followed by adjustments in food intake. Like other Octopus species, O. mimus appears to be an opportunistic predator.

Description: The relationship between reproduction and condition was studied in a 15 mo sample of 919 maturing, mature and post-spawning female Octopus mimus (388 to 3714 g) caught in Iquique (North Chile). O. mimus is a semelparous species, with reproduction taking place all year round. Investment in reproductive tissues was, on average, 9.9% of mature female body weight, independent of season. However, somatic growth during maturation was dependent on season and varied between 26 and 63% of the whole-body growth in weight. The condition of females did not vary markedly until spawning, although seasonal variations were apparent, winter being the most unfavourable. Condition deteriorated dramatically after spawning, during parental care of the eggs. During this period, somatic-tissue depletion, mainly from the muscles, was 〉25% of the total body weight of mature females. The fecundity of O. mimus was probably limited by the costs associated with parental care of the eggs.

Description: Logs collected while drilling measured density in situ, through the accretionary prism and decollement zone of the northern Barbados Ridge. Consolidation tests relate void ratio (derived from density) to effective stress and predict a fluid pressure profile, assuming that the upper 100 m of the prism is at a hydrostatic pressure gradient. The calculated fluid pressure curve rises to 〉90% of lithostatic below thrusts in the prism, presumably due to the increase in overburden and lateral tectonic loading. Thin (0.5–2.0 m) intervals of anomalously low density and resistivity in the logs through the basal decollement zone suggest dilation and perhaps hydrofracturing. A peak in hydraulic head in the upper half of the decollement zone requires lateral influx of fluid, a conclusion consistent with previous geochemical studies. Although the calculated fluid-pressure profile is model dependent, its inherent character ties to major structural features.

Description: Recent data from research cruises and explorator fishing in the Antarctic Polar Frontal Zone (APFZ) of the Scotia Sea, together with data from dietary studies of Antarctic vertebrate predators, have revealed a large, previously overlooked trophic system in the Southern Ocean (Fig. 1). The upper trophic levels of this open-ocean epipelagic community are exceptional in that they contain no fish species. Fishes are replaced by cephalopods, including the ommastrephid squid, Martialia hyadesi. This squid preys on mesopelagic m.yctophids (lanternfish), which feed largely on copepods. We identify here a geographically distinct, Antarctic, open-ocean food chain which is of importance to air breathing predator species but where Antarctic krill, Euphausia superba, is absent. This system is probably prevalent in areas of higher primary productivity, especially the Scotia Sea and near the peri-Antarctic islands. Squid stocks in the APFZ may have potential for commercial exploitation, but they, and the predators they support, are likely to be sensitive to overfishing. Squid have a short, semelparous lifecycle, so overfishing in a single year can cause a stock to collapse.

Description: Statolith morphology and microstructure were studied in two common species of panktonic cranchiid squids, Belonella borealis [four juveniles with mantle length (ML) 375–450 mm] and Galiteuthis phyllura (13 paralarvae and juveniles, ML 9–235mm), caught near the bottom and in pelagic layers over the continental slope of Siberia in the northwest Bering Sea. The total number of growth increments within the statoliths ranged from 277 to 294 in B.borealis and from 10 to 209 in G.phyllura. Assuming that these increments were produced daily, both species grow rapidly in length (daily growth rate = 1.13mm day−1 during the first 8–10 months of their juvenile phase in the mesopelagic layers, prior to migration into deeper waters for maturation.

Description: The first record of Potamothrix bedoti (Piguet, 1913) in Norway is from the eutrophic lake Ärungen 34 m a.s.1. (59°45’N, 10°41’E) in the county of Akershus, where 31 mature specimens were collected in the littoral zone from 1.0 to 3.0 m depth in silt and clay Sediments. In Scandinavia, the species is also known from Sweden. Six mature specimens of Haber speciosus (Hrabe, 1931) were found in the northem part of the oligotrophic lake Maridalsvannet 149 m a.s.L (59°59’N, 10°47’E) in the county of Oslo. The worms were found in the littoral zone on sandy bottom with scattered Isoetes sp. Vegetation at approximately 1.5 m depth. The species has earlier not been recorded from Scandinavia.

Description: More than 15 sedimentary cycles dated to the last glacial period (53-10 ka BP) have been recognized in a contourite deposit on the Faeroe Drift in the southern part of the Norwegian Sea. Each cycle consists of a silty, basaltic lower part and a clayey, acidic (siliceous) upper part. The sedimentary cycles can be accurately correlated with the Dansgaard-Oeschger temperature cycles in the Greenland ice cores, and it appears that the cyclic sedimentation was controlled by climatic and palaeoceanographic changes. The basaltic layers were deposited during warm interstadial periods in a current regime that resembles the modern circulation system in the North Atlantic region. Deep bottom-water created by thermohaline convection in the Norwegian-Greenland Seas flowed along the Iceland-Faeroe Ridge into the Atlantic Ocean, with the Faeroe-Shetland Channel as the main gateway. The source of the basaltic sediments was the volcanic rocks and detritus on the Iceland-Faeroe Ridge and on the shelf of eastern Iceland. The fine-grained acidic (siliceous) layers were deposited during intervening cold periods, in which convection took place in the subpolar North Atlantic Ocean and the circulation was reversed in the Faeroe-Shetland Channel. The acidic deposits were carried into the Norwegian Sea from the Hebrides and West Shetland shelves and the northeastern Atlantic Ocean.

Description: A 900-m-thick section of tuffaceous sedimentary rock, vitric fallout tuff, and ash-flow tuff is well exposed along Trapper Creek in south-central Idaho. This section provides nearly continuous exposure through the fill of the Goose Creek basin, a major north-trending Miocene extensional basin located along the southern margin of the Snake River Plain volcanic province (SRPVP). Some 51 separate units of vitric fallout tuff are recognized in the Trapper Creek section. Petrographic and chemical characteristics of these vitric tuffs indicate that most are from SRPVP sources. New 40Ar/39Ar laser-fusion dating, along with prior isotopic age determinations, show that the Trapper Creek tuffs span the period ca. 13.9 – 8.6 Ma. Chemical correlation indicates that fallout tuffs in the central part of the Trapper Creek section (12.5 – 10.0 Ma) are from sources in the Bruneau-Jarbidge volcanic field of the SRPVP centered ≈100 km west of Trapper Creek. Underlying fallout tuffs may have had sources in the Owyhee-Humboldt field of the SRPVP centered ≈200 km west of Trapper Creek, while overlying fallout tuffs, interlayered with several ash-flow tuffs, had a relatively proximal source, possibly in the proposed Twin Falls volcanic field centered ≈60 km north of Trapper Creek. The Trapper Creek tuffs provide insight into the characteristics of explosive silicic volcanism within the SRPVP during middle – late Miocene time. From ca. 13.9 to ca. 9.5 Ma, major eruptions (those depositing ≥1.5 m of fallout tuff) were frequent (about one event per 200 k.y.); their products display a trend toward the eruption of progressively less evolved, higher temperature silicic magma after 12.5 Ma. This trend to higher temperature eruptions, termed the Cougar Point “flare-up,” culminated in the eruption of high-temperature (≈1000°C), plagioclase-rich magma during the period 10.5 – 9.5 Ma. In contrast to these eruptions, later (〈7.0 Ma) major silicic eruptions within the SRPVP were characterized by the lower temperature (≈850°C) of the erupted magma and by the longer intervals (about one event per ≈500 – 600 k.y.) between eruptions. Variations in the character of SRPVP explosive silicic eruptions may reflect changes in the structure, composition, or state of stress in the crust beneath the eastward propagating SRPVP, or, perhaps, changes in the Yellowstone hot-spot plume that may drive the SRPVP volcanism.

Description: Knowledge of the solubility of ore minerals and the speciation of ore metals in hydrothermal solutions is required for a complete understanding of the genesis of hydrothermal ores. In this chapter, we explore the factors that control solubility and speciation, demonstrate how to carry out quantitative calculations, and review the current state of knowledge for a number of economically important metals. The term solubility refers to the sum of the concentrations of all dissolved forms of a given metal in a hydrothermal solution in equilibrium with a mineral (or minerals) containing that metal. We use the term speciation to denote the relative concentrations of the various forms of a metal in solution.

Description: Detrital sediment is carried from land to the sea by three agents, rivers, glaciers, and winds. The shoreline is an arbitrary boundary within the detrital sediment transport system, which extends from a site of origin across areas of temporary storage to a site of long-term deposition. The most important of the agents moving sediment across the land is river transport, estimated to be in the order of 20×1012 kg of sediment annually at present. Analysis of drainage basins indicates that relief and runoff are the most important factors in determining the sediment load of rivers. The competence of rivers to transport sediment is governed by the volume flow, gradient, and the sediment load itself. Today, most large rivers are fed by snowmelt in highland areas, runoff from rainfall in the drainage basin, and groundwater inflow. Along the river course, water is lost to evaporation and groundwater infiltration. River courses can often be divided into two segments, a degradational section in which the gradient is relatively steep and little temporary storage of sediment takes place, and an aggradational section where the gradient is sharply reduced through meandering, and where large-scale temporary sediment storage forms a flood plain. Lakes trap sediment inland and prevent its transport to the sea. Today, many high and mid-latitude rivers are interrupted by lakes of glacial origin. There are also some large areas of internal drainage that deliver no sediment to the sea. The load carried by rivers has been markedly altered by human activity, and may have doubled over the past few thousand years, only to be reduced in the past century by the widespread construction of dams. The ancient use of fire in hunting and its subsequent use in clearing land has increased erosion. Extensive deforestation and cultivation processes have also increased the sediment supply. Dam construction is a relatively new factor and affects the sediment transport system by trapping sediment before it can reach the sea. The resulting lower sediment supply from rivers is, at least in part, compensated by increased coastal erosion. Glacial erosion is difficult to estimate. There is an ongoing controversy whether ice sheets are effective erosive agents or not. Estimates of the present global flux of glacial detritus range from 0.8–50×1012 kg annually, with the lower value most probable. The dust flux is in the order of 0.5 to 0.9×1012 kg annually, but may vary greatly with time.

Description: Bottom shots have been used for a number of years in seismic studies on the ocean floor. Most experiments utilized explosives as the energy source, though researchers have recognized the usefulness of collapsing water voids to produce seismoacoustic signals. Implosive sources, however, suffered generally from a lack of control of source depth. We present a new experimental tool, called SEEBOSEIS, to carry out seismic experiments on the seafloor utilizing hollow glass spheres as controlled implosive sources. The source is a 10-inch BENTHOS float with penetrator. Inside the sphere we place a small explosive charge (two detonators) to destabilize the glass wall. The time of detonation is controlled by an external shooting device. Test measurements on the Ninetyeast Ridge, Indian Ocean, show that the implosive sources can be used in seismic refraction experiments to image the subbottom P- wave velocity structure in detail beyond that possible with traditional marine seismic techniques. Additionally, the implosions permit the efficient generation of dispersed Scholte waves, revealing upper crustal S-wave velocities. The frequency band of seismic energy ranges from less than 1 Hz for Scholte modes up to 1000 Hz for diving P-waves. Therefore, broadband recording units with sampling rates 〉2000 Hz are recommended to sample the entire wave field radiated by implosive sources.

Description: This chapter discusses the rates of protein synthesis in fish. Protein synthesis can be viewed at a number of levels. Whole-animal values can be integrated into the descriptions of assimilation/growth or assimilation/metabolism patterns in different fish species and is the focus of the chapter. The measurement of protein synthesis rates in body organs and tissues can provide information on the extent to which differences exist among various tissues and offer a challenge in understanding the integration of organ metabolism into whole animal physiology. The majority of methods for estimating protein synthesis measure the flux of an amino acid or nitrogen. This involves the use of tracer substances—that is, amino acids labeled with an isotope, which are given in a single dose or by continuous infusion. The measurements, parameters, and formulae that are commonly employed in the studies of protein growth, synthesis, and degradation are described in the chapter. It discusses the mechanism of nutrition and protein synthesis in the fish and explains the impact that protein synthesis has upon the rates of oxygen consumption.

Description: General Subject of research: Detailed study of the shallow water hydrothermal system around Kolbeinsey and Grimsey islands

Description: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.

Description: Grain‐size‐dependent flow mechanisms tend to be favored over dislocation creep at low differential stresses and can potentially influence the rheology of low‐stress, low‐strain rate environments such as those of planetary interiors. We experimentally investigated the effect of reduced grain size on the solid‐state flow of water ice I, a principal component of the asthenospheres of many icy moons of the outer solar system, using techniques new to studies of this deformation regime. We fabricated fully dense ice samples of approximate grain size 2±1 μm by transforming “standard” ice I samples of 250±50 μm grain size to the higher‐pressure phase ice II, deforming them in the ice II field, and then rapidly releasing the pressure deep into the ice I stability field. At T≤200 K, slow growth and rapid nucleation of ice I combine to produce a fine grain size. Constant‐strain rate deformation tests conducted on these samples show that deformation rates are less stress sensitive than for standard ice and that the fine‐grained material is markedly weaker than standard ice, particularly during the transient approach to steady state deformation. Scanning electron microscope examination of the deformed fine‐grained ice samples revealed an unusual microstructure dominated by platelike grains that grew normal to the compression direction, with c axes preferentially oriented parallel to compression. In samples tested at T≥220 K the elongation of the grains is so pronounced that the samples appear finely banded, with aspect ratios of grains approaching 50:1. The anisotropic growth of these crystallographically oriented neoblasts likely contributes to progressive work hardening observed during the transient stage of deformation. We have also documented remarkably similar microstructural development and weak mechanical behavior in fine‐grained ice samples partially transformed and deformed in the ice II field.

Description: Microstructural changes taking place in two shear bands of Toyoura and Ticino sands were examined by means of an X-ray method and optical measurements using a microscope and thin sections. The following must be taken into account in order to produce a realistic micro-structural deformation model for granular soils: (1) shear band boundaries are not straight, but are gently curved with different inclination angles to the major principal stress from section to section; (2) extremely large voids are produced in shear bands, and the resulting local void ratio can be larger than the maximum void ratio determined by standard methods; (3) the particle orientation changes sharply at shear band boundaries, so that a high gradient of particle rotation can be developed within a relatively narrow zone during the shear banding process; (4) particle rotation, on average, takes place in parallel with the corresponding geotoscopic rotation in the continuum sense; (5) the thickness of shear bands is about 7 to 8 times the mean particle size. In addition to these observations, photoelastic pictures taken from a biaxial test on a two-dimensional assembly of oval rods were analysed and used in proposing a microstructural deformation mode. In the model, the main microstructural change during the strain hardening process is the setting up of columns extending parallel to the major principal stress direction. The columns start buckling at the peak stress, and the buckling columns tend to concentrate in shear bands during the strain softening process, which causes not only the growth of the extremely large voids but also the particle rotation in shear bands. On the basis of this model, the following two points are emphasized: (1) rotation stiffness at contacts must be one of the important components controlling the strength of granular soils, and (2) the presence of rotational restraint at contacts must be taken into account in the formulation of static equilibrium conditions in a shear band and in the interpretation of residual strength of granular soils.

Description: The tissue of 31 demosponge and 7 hexachnelhd species was analyzed for its composition of organic and lnorganic matter With one excephon (Hahclona cf gausaana) inorganic matter i e n~ostly the siliceous skeleton, accounted for most of the dry weight, varying between about 60 and 95%dry wt There were no general trends in the ratio of organic to inorganic matter within sponge orders or genera, and within one species, the ratio could vary between stations For one of the hexactinellids Bathydorus spmosus, several size classes were analyzed and there was no systematic change in the organic inorganic matter ratio w t h specimen size For some species the results from the Weddell Sea sponges are in good agreement with earlier data from McMurdo Sound The low organic matter content in Weddell Sea sponges mphes that sponge biomasses are much lower than hitherto assumed on the basis of then high abundances and large sizes In consequence Antarctic sponges despite their ubiquitousness, may only channel a m n o r fractlon of the general bentho-pelagic flow of matter and energy and their maln role in the ecosystem is likely structural rather than dynamic

Description: Auf- und Abbauprozesse und Bedeutung deponierter Skelettelemente für die Struktur der Lebensräume

Description: Climate changes since AD 1200 have been of high magnitude. Significant lowering of temperatures occurred during the neoglacial (‘Little Ice Age’), between AD 1200–1400 and AD 1600–1800 with maximum cooling in the mid-late eighteenth century. At this time many European valley/cirque glaciers reached their maximum extent since the late Pleistocene. Neoglaciation was followed by an overall warming trend, although with significant reversals superimposed. Alongside these temperature changes were variations in the nature and amount of precipitation, and in consequence, river basins in north, west and central Europe experienced enhanced fluvial activity between 1250 and 1550 and particularly between 1750 and 1900. These phases coincide with periods of climatic transition; cooling after the Medieval optimum and warming during the latter stages of the Little Ice Age respectively. In contrast, the intervening period (1550–1750), which corresponds with the most severe phases of the last neoglacial, was associated with lower rates of fluvial activity.

Description: During 5 consecutive summer seasons (1990 to 1994) both Aureliaaurita medusa and mesozooplankton abundances were investigated at 2 stations in the Kiel Bight (western Baltic Sea). Stocks of medusae varied considerably between the years, with median abundance of 1 and 0.3 ind. 100 m-3 in 1990 and 1991, 3 and 4 ind. 100 m-3 in 1992 and 1994, but 9 ind. 100 m-3 in 1993. Significant differences in the mesozooplankton stock and community composition were observed in 1993 when compared with the year of rather low Aurelia abundance (1991). Total zooplankton and copepod numbers both exhibited an inverse relationship with the abundance of medusae and were thus considerably lower in 1993 than in 1991. However, not all copepod species were affected by A. aurita. Pseudo- and Paracalanus spp. and Oithonasimilis showed dramatically reduced stocks in the bloom year when compared with the medusa-poor situation, but no significant changes were found for Centropageshamatus and Acartia spp. Also other zooplankton groups with the exception of bivalve larvae were reduced by the medusae. The differential response of zooplankton to varying abundance of medusae led to a shift in the trophic structure of the zooplankton community. Fine-filter feeders and raptorial feeders were much more important in years when medusae occurred in low densities, whereas coarse-filter feeders dominated in the opposite situation.

Description: The modern ocean is comprised of four units: an equatorial belt shared by the two hemispheres, tropical subtropical anticyclonic gyres, mid-latitude belts of water with steep meridional temperature gradients, and polar oceans characterized by cyclonic gyres. These units are separated by lines of convergence, or fronts: The Early Cretaceous ocean closely resembled the modern ocean. The developing Atlantic was analogous to the modern Mediterranean and served as an Intermediate Water source for the Pacific. Because sea-ice formed seasonally in the Early Cretaceous polar seas, deep water formation probably took place largely in the polar region. In the Late Cretaceous, the high latitudes were warm and deep water moved from the equatorial region toward the poles, enhancing the ocean's capacity to transport heat poleward. The contrast between surface gyre waters and intermediate waters was less. -from Author

Description: Age and growth of the large oceanic squid Thysanoteuthis rhombus were estimated by statolith increment analysis of 72 specimens [mantle length (ML) ranging from 25 to 805 mm] and reproductive biology was studied on 162 T. rhombus (ML 150 to 850 mm) captured in the eastern tropical Atlantic and southwestern Pacific between 1976 and 1990. The maximum ages found in our samples were observed in a mature female of 750 mm ML (305 d) and in a mature male of 770 mm ML (309 d). The life span of T. rhombus was estimated to be about 1 yr; males and females matured at age 6 to 8 mo. T. rhombus is one of the fastest-growing squids: by age 300 d, they reached 750 to 800 mm ML and 17 to 17.5 kg body weight (BW). The increase in both ML and BW during ontogenesis was best fitted by a logistic growth curve. T. rhombus has high potential fecundity (up to 4.8 million oocytes), but a rather small maximum volume of oviducts (up to 140000 eggs) and egg masses (35000 to 75000 eggs). It is suggested that T. rhombus is an intermittent spawner with multiple filling and evacuation of oviducts. The main function of the (for squid) unusual behaviour of T. rhombus, i.e. living in pairs consisting of a male and female, is reproduction and is optimal given the low density of T. rhombus populations and low active movement of squids.

Description: In the nodule field of the Peru Basin, situated south of the zone of high bioproductivity, a relatively high flux of biogenic matter explains a distinct redox boundary at about 10 cm depth separating very soft oxic surface sediments from stiffer suboxic sediments. Maximum abundance (50 kg m−2) of diagenetic nodules is found near the calcite compensation depth (CCD), currently at 4250 m. There, the accretion rate of nodules is much higher (100 mm Ma−1) than on ridges (5 mm Ma−1). Highest accretion rates are found at the bottom of large nodules that repeatedly sink to a level immediately above the redox boundary. There, distinct diagenetic growth conditions prevail and layers of dense laminated Mn oxide of very pure todorokite are formed. The layering of nodules is mainly the result of organisms moving nodules within the oxic surface sediment from diagenetic to hydrogenetic environments. The frequency of such movements is much higher than that of climatic changes. Two types of nodule burial occur in the Peru Basin. Large nodules are less easily moved by organisms and become buried. Consequently, buried nodules generally are larger than surface nodules. This type of burial predominates in basins. At ridges where smaller nodules prevail, burial is mainly controlled by statistical selection where some nodules are not moved up by organisms.