ALBERT

Note: Hydrocarbon systems, by nature, are a complex interplay of elements that must be spatially and temporally aligned to result in the generation and preservation of subsurface hydrocarbon accumulations. To meet the increasing challenges of discovering hydrocarbon resources, it is essential that we advance our understanding of these systems through new geochemical approaches and analytical developments. Such development requires that academic- and industry-led research efforts converge in ways that are unique to the geosciences. The aim of this volume is to bring together a multidisciplinary geochemical community from industry and academia working in hydrocarbon systems to publish recent advances and state-of-the-art approaches to resolve the many remaining questions in hydrocarbon systems analysis. From Source to Seep presents geochemical and isotopic studies that are grouped into three themes: (1) source-rock identification and the temperature/timing of hydrocarbon generation; (2) mechanisms and time-scales associated with hydrocarbon migration, trapping, storage and alteration; and (3) the impact of fluid flow on reservoir properties. | Contents: Geochemical applications in petroleum systems analysis: new constraints and the power of integration / M. Lawson, M. J. Formolo, L. Summa and J. M. Eiler / Geological Society, London, Special Publications, 468, 1-21, 19 February 2018, https://doi.org/10.1144/SP468.6 --- Source-rock identification and the temperature/timing of hydrocarbon generation --- The utility of methane clumped isotopes to constrain the origins of methane in natural gas accumulations / Daniel A. Stolper, Michael Lawson, Michael J. Formolo, Cara L. Davis, Peter M. J. Douglas and John M. Eiler / Geological Society, London, Special Publications, 468, 23-52, 14 December 2017, https://doi.org/10.1144/SP468.3 --- The isotopic structures of geological organic compounds / John M. Eiler, Matthieu Clog, Michael Lawson, Max Lloyd, Alison Piasecki, Camilo Ponton and Hao Xie / Geological Society, London, Special Publications, 468, 53-81, 14 December 2017, https://doi.org/10.1144/SP468.4 --- Vanadium isotope composition of crude oil: effects of source, maturation and biodegradation / Yongjun Gao, John F. Casey, Luis M. Bernardo, Weihang Yang and K. K. (Adry) Bissada / Geological Society, London, Special Publications, 468, 83-103, 14 December 2017, https://doi.org/10.1144/SP468.2 --- Carbon and hydrogen isotopic compositions of n-alkanes as a tool in petroleum exploration / Nikolai Pedentchouk and Courtney Turich / Geological Society, London, Special Publications, 468, 105-125, 14 December 2017, https://doi.org/10.1144/SP468.1 --- Mechanisms and time-scales associated with hydrocarbon migration, trapping, storage and alteration --- Noble gases in conventional and unconventional petroleum systems / David J. Byrne, P. H. Barry, M. Lawson and C. J. Ballentine / Geological Society, London, Special Publications, 468, 127-149, 14 December 2017, https://doi.org/10.1144/SP468.5 --- Differentiating between biogenic and thermogenic sources of natural gas in coalbed methane reservoirs from the Illinois Basin using noble gas and hydrocarbon geochemistry / Myles T. Moore, David S. Vinson, Colin J. Whyte, William K. Eymold, Talor B. Walsh and Thomas H. Darrah / Geological Society, London, Special Publications, 468, 151-188, 18 January 2018, https://doi.org/10.1144/SP468.8 --- The impact of fluid flow on reservoir properties --- Testing clumped isotopes as a reservoir characterization tool: a comparison with fluid inclusions in a dolomitized sedimentary carbonate reservoir buried to 2–4 km / John M. MacDonald, Cédric M. John and Jean-Pierre Girard / Geological Society, London, Special Publications, 468, 189-202, 14 December 2017, https://doi.org/10.1144/SP468.7

Note: Table of Contents: 1 The Solid Phase of Marine Sediments / DIETER K. FÜTTERER 1.1 Introduction 1.2 Sources and Components of Marine Sediments 1.2.1 Lithogenous Sediments 1.2.2 Biogenous Sediments 1.2.3 Hydrogenous Sediments 1.3 Classification of Marine Sediments 1.3.1 Terrigenous Sediments 1.3.2 Deep-Sea Sediments 1.4 Global Patterns of Sediment Distribution 1.4.1 Distribution Patterns of Shelf Sediments 1.4.2 Distribution Patterns of Deep-Sea Sediments 1.4.3 Distribution Patterns of Glay Minerals 1.4.4 Sedimentation Rates 2 Geophysical Perspectives in Marine Sediments 2.1 Physical Properties of Marine Sediments / MONIKA BREITZKE 2.1.1 Introduction 2.1.2 Porosity and Wet Bulk Density 2.1.2.1 Analysis by Weight and Volume 2.1.2.2 Gamma Ray Attenuation 2.1.2.3 Electrical Resistivity (Galvanic Method) 2.1.2.4 Electrical Resistivity (Inductive Method) 2.1.3 Permeability 2.1.4 Acoustic and Elastic Properties 2.1.4.1 Biot-Stoll Model 2.1.4.2 Full Waveform Ultrasonic Gore Logging 2.1.5 Sediment Classification 2.1.5.1 Full Waveform Gore Logs as Acoustic Images 2.1.5.2 P-and S-Wave Velocity, Attenuation, Elastic Moduli and Permeability 2.1.6 Sediment Echosounding 2.1.6.1 Synthetic Seismograms 2.1.6.2 Narrow-Beam Parasound Echosounder Recordings 2.2 Sedimentary Magnetism / ULRICH BLEIL 2.2.1 Introduction 2.2.2 Biogenie Magnetic Minerals in Marine Sediments 2.2.3 Reduction Diagenesis of Magnetic Minerals in Marine Environments 3 Quantification of Early Diagenesis: Dissolved Constituents in Marine Pore Water / HORST D. SCHULZ 3.1 Introduction: How to Read Pore Water Concentration Profiles 3.2 Calculation of Diffusive Fluxes and Diagenetic Reaction Rates 3.2.1 Steady State and Non-Steady State Situations 3.2.2 The Steady State Situation and Fick's First Law of Diffusion 3.2.3 Quantitative Evaluation of Steady State Concentration Profiles 3.2.4 The Non-Steady State Situation and Fick's Second Law of Diffusion 3.2.5 The Primary Redox-Reactions: Degradation of Organic Matter 3.3 Sampling of Pore Water for Ex-Situ Measurements 3.3.1 Obtaining Sampies of Sediment for the Analysis of Pore Water 3.3.2 Pore Water Extraction from the Sediment 3.3.3 Storage, Transport and Preservation of Pore Water 3.4 Analyzing Constituents in Pore Water, Typical Profiles 3.5 In-Situ Measurements 3.6 Influence of Bioturbation, Bioirrigation, and Advection 4 Organic Matter: The Driving Force for Early Diagenesis / JÜRGEN RULLKÖTTER 4.1 The Organic Carbon Cycle 4.2 Organic Matter Accumulation in Sediments 4.2.1 Productivity Versus Preservation 4.2.2 Primary Production of Organic Matter and Export to the Ocean Bottom 4.2.3 Transport of Organic Matter through the Water Column 4.2.4 The Influence of Sedimentation Rate on Organic Matter Burial 4.2.5 Allochthonous Organic Matter in Marine Sediments 4.3 Early Diagenesis 4.3.1 The Organic Carbon Content of Marine Sediments 4.3.2 Chemical Composition of Biomass 4.3.3 The Principle of Selective Preservation 4.3.4 The Formation of Fossil Organic Matter and its Bulk Composition 4.3.5 Early Diagenesis at the Molecular Level 4.3.6 Biological Markers (Molecular Fossils) 4.4 Organic Geochemical Proxies 4.4.1 Total Organic Carbon and Sulfur 4.4.2 Marine Versus Terrigenous Organic Matter 4.4.3 Molecular Paleo-Seawater Temperature and Climate Indicators 4.5 Analytical Techniques 4.5.1 Sam pie Requirements 4.5.2 Elemental and Bulk Isotope Analysis 4.5.3 Rock-Eval Pyrolysis and Pyrolysis Gas Chromatography 4.5.4 Organic Petrography 4.5.5 Bitumen Analysis 4.6 The Future of Marine Geochemistry of Organic Matter 5 Bacteria and Marine Biogeochemistry / Bo BARKER JORGENSEN 5.1 Role of Microorganisms 5.1.1 From Geochemistry to Microbiology - and back 5.1.2 Approaches in Marine Biogeochemistry 5.2 Life and Environments at Small Scale 5.2.1 Hydrodynamics of Low Reynolds Numbers 5.2.2 Diffusion at Small Scale 5.2.3 Diffusive Boundary Layers 5.3 Regulation and Limits of Microbial Processes 5.3.1 Substrate Uptake by Microorganisms 5.3.2 Temperature as a Regulating Factor 5.3.3 Other Regulating Factors 5.4 Energy Metabolism of Prokaryotes 5.4.1 Free Energy 5.4.2 Reduction-Oxidation Processes 5.4.3 Relations to Oxygen 5.4.4 Definitions of Energy Metabolism 5.4.5 Energy Metabolism of Microorganisms 5.4.6 Chemolithotrophs 5.4.7 Respiration and Fermentation 5.5 Pathways of Organic Matter Degradation 5.5.1 Depolymerization of Macromolecules 5.5.2 Aerobic and Anaerobic Mineralization 5.5.3 Depth Zonation of Oxidants 5.6 Methods in Biogeochemistry 5.6.1 Incubation Experiments 5.6.2 Radioactive Tracers 5.6.3 Example: Sulfate Reduction 5.6.4 Specific Inhibitors 5.6.5 Other Methods 6 Early Diagenesis at the Benthic Boundary Layer: Oxygen and Nitrate in Marine Sediments / CHRISTIAN HENSEN AND MATTHIAS ZABEL 6.1 Introduction 6.2 Oxygen and Nitrate Distribution in Seawater 6.3 The Role of Oxygen and Nitrate in Marine Sediments 6.3.1 Respiration and Redox Processes 6.3.1.1 Nitrification and Denitrification 6.3.1.2 Coupling of Oxygen and Nitrate to other Redox Pathways 6.3.2 Determination of Consumption Rates and Senthic Fluxes 6.3.2.1 Fluxes and Concentration Profiles Determined by In-Situ Devices 6.3.2.2 Ex-Situ Pore Water Data from Deep-Sea Sediments 6.3.2.3 Determination of Denitrification Rates 6.3.3 Oxic Respiration, Nitrification and Denitrification in Different Marine Environments 6.3.3.1 Quantification of Rates and Fluxes 6.3.3.2 Variation in Different Marine Environments: Case Studies 6.4 Summary 7 The Reactivity of Iron / RALF R. HAESE 7.1 Introduction 7.2 Pathways of Iron Input to Marine Sediments 7.2.1 Fluvial Input 7.2.2 Aeolian Input 7.3 Iron as a Limiting Nutrient for Primary Productivity 7.4 The Early Diagenesis of Iron in Sediments 7.4.1 Dissimilatary Iran Reductian 7.4.2 Solid Phase Ferric Iron and its Bioavailability 7.4.2.1 Properties of Iron Oxides 7.4.2.2 Bioavailability of Iron Oxides 7.4.2.3 Bioavailability of Sheet Silicate Sound Ferric lron 7.4.3 Iron and Manganese Redax Cycles 7.4.4 Iron Reactivity towards S, O2, Mn, NO3, P, HCO3, and Si-AI 7.4.4.1 lron Reduction by HS and Ligands 7.4.4.2 Iron Oxidation by O2, NO3, and Mn4+ 7.4.4.3 Iron-Sound Phosphorus 7.4.4.4 The Formation of Siderite 7.4.4.5 The Formation of lron Searing Aluminosilicates 7.4.5 Discussion: The Importance of Fe-and Mn-Reactivity in Various Enyironments 7.5 The Assay for Ferric and Ferrous Iron 8 Sulfate Reduction in Marine Sediments / SABINE KASTEN AND BO BARKER JØRGENSEN 8.1 Introduction 8.2 Sulfate Reduction and the Degradation of Organic Matter 8.3 Biotic and Abiotic Processes Coupled to Sulfate Reduction 8.3.1 Pyrite Formation 8.3.2 Effects of Sulfate Reduction on Sedimentary Solid Phases 8.4 Determination of Sulfate Reduction Rates 9 Marine Carbonates: Their Formation and Destruction / RALPH R. SCHNEIDER, HORST D. SCHULZ AND CHRISTIAN HENSEN 9.1 Introduction 9.2 Marine Environments of Carbonate Production and Accumulation 9.2.1 Shallow-Water Carbonates 9.2.2 Pelagic Calcareous Sediments 9.3 The Calcite-Carbonate-Equilibrium in Marine Aquatic Systems 9.3.1 Primary Reactions of the Calcite-Carbonate-Equilibrium with Atmospheric Contact in Infinitely Diluted Solutions 9.3.2 Primary Reactions of the Calcite-Carbonate-Equilibrium without Atmospheric Contact 9.3.3 Secondary Reactions of the Calcite-Carbonate-Equilibrium in Seawater 9.3.4 Examples for Calculation of the Calcite-Carbonate-Equilibrium in Ocean Waters 9.4 Carbonate Reservoir Sizes and Fluxes between Particulate and Dissolved Reservoirs 9.4.1 Production Versus Dissolution of Pelagic Carbonates 9.4.2 Inorganic and Organic Carbon Release trom Deep-Sea Sediments 10 Influences of Geochemical Processes on Stable Isotope Distribution in Marine Sediments / TORSTEN SICKERT 10.1 Introduction 10.2 Fundamentals 10.2.1 Principles of Isotopic Fractionation 10.2.2 Analytical Procedures 10.3 Geochemicallnfluences on 18O/16O Ratios 10.3.1 δ18O of Seawater 10.3.2 δ18O in Marine Carbonates 10.4 Geochemical Influences on 13C/12C Ratios 10.4.1

Note: L. M. Parson, C. L. Walker, and D. R. Dixon: Hydrothermal vents and processes / Geological Society, London, Special Publications, 87:1-2, doi:10.1144/GSL.SP.1995.087.01.01 --- C. R. German, E. T. Baker, and G. Klinkhammer: Regional setting of hydrothermal activity / Geological Society, London, Special Publications, 87:3-15, doi:10.1144/GSL.SP.1995.087.01.02 --- Sergey G. Krasnov, Irina M. Poroshina, and Georgiy A. Cherkashev: Geological setting of high-temperature hydrothermal activity and massive sulphide formation on fast- and slow-spreading ridges / Geological Society, London, Special Publications, 87:17-32, doi:10.1144/GSL.SP.1995.087.01.03 --- Bramley J. Murton, Cindy Van Dover, and Eve Southward: Geological setting and ecology of the Broken Spur hydrothermal vent field: 29°10′N on the Mid-Atlantic Ridge / Geological Society, London, Special Publications, 87:33-41, doi:10.1144/GSL.SP.1995.087.01.04 --- S. G. Krasnov, G. A. Cherkashev, T. V. Stepanova, B. N. Batuyev, A. G. Krotov, B. V. Malin, M. N. Maslov, V. F. Markov, I. M. Poroshina, M. S. Samovarov, A. M. Ashadze, L. I. Lazareva, and I. K. Ermolayev: Detailed geological studies of hydrothermal fields in the North Atlantic / Geological Society, London, Special Publications, 87:43-64, doi:10.1144/GSL.SP.1995.087.01.05 --- Edward T. Baker: Characteristics of hydrothermal discharge following a magmatic intrusion / Geological Society, London, Special Publications, 87:65-76, doi:10.1144/GSL.SP.1995.087.01.06 --- J. M. Edmond, A. C. Campbell, M. R. Palmer, G. P. Klinkhammer, C. R. German, H. N. Edmonds, H. Elderfield, G. Thompson, and P. Rona: Time series studies of vent fluids from the TAG and MARK sites (1986, 1990) Mid-Atlantic Ridge: a new solution chemistry model and a mechanism for Cu/Zn zonation in massive sulphide orebodies / Geological Society, London, Special Publications, 87:77-86, doi:10.1144/GSL.SP.1995.087.01.07 --- G. P. Klinkhammer, C. S. Chin, C. Wilson, and C. R. German: Venting from the Mid-Atlantic Ridge at 37°17′N: the Lucky Strike hydrothermal site / Geological Society, London, Special Publications, 87:87-96, doi:10.1144/GSL.SP.1995.087.01.08 --- R. H. James, H. Elderfield, M. D. Rudnicki, C. R. German, M. R. Palmer, C. Chin, M. J. Greaves, E. Gurvich, G. P. Klinkhammer, E. Ludford, R. A. Mills, J. Thomson, and A. C. Williams: Hydrothermal plumes at Broken Spur, 29°N Mid-Atlantic Ridge: chemical and physical characteristics / Geological Society, London, Special Publications, 87:97-110, doi:10.1144/GSL.SP.1995.087.01.09 --- M. R. Palmer, E. M. Ludford, C. R. German, and M. D. Lilley: Dissolved methane and hydrogen in the Steinahóll hydrothermal plume, 63°N, Reykjanes Ridge / Geological Society, London, Special Publications, 87:111-120, doi:10.1144/GSL.SP.1995.087.01.10 --- Rachel A. Mills: Hydrothermal deposits and metalliferous sediments from TAG, 26°N Mid-Atlantic Ridge / Geological Society, London, Special Publications, 87:121-132, doi:10.1144/GSL.SP.1995.087.01.11 --- F. M. Stuart, P. J. Harrop, R. Knott, A. E. Fallick, G. Turner, Y. Fouquet, and D. Rickard: Noble gas isotopes in 25 000 years of hydrothermal fluids from 13°N on the East Pacific Rise / Geological Society, London, Special Publications, 87:133-143, doi:10.1144/GSL.SP.1995.087.01.12 --- Penny Dickson, Adam Schultz, and Andrew Woods: Preliminary modelling of hydrothermal circulation within mid-ocean ridge sulphide structures / Geological Society, London, Special Publications, 87:145-157, doi:10.1144/GSL.SP.1995.087.01.13 --- A. Rachel Pascoe and Johnson R. Cann: Modelling diffuse hydrothermal flow in black smoker vent fields / Geological Society, London, Special Publications, 87:159-173, doi:10.1144/GSL.SP.1995.087.01.14 --- Rowena C. Duckworth, Richard Knott, Anthony E. Fallick, David Rickard, Bramley J. Murton, and Cindy Van Dover: Mineralogy and sulphur isotope geochemistry of the Broken Spur sulphides, 29°N, Mid-Atlantic Ridge / Geological Society, London, Special Publications, 87:175-189, doi:10.1144/GSL.SP.1995.087.01.15 --- Steven D. Scott and Raymond A. Binns: Hydrothermal processes and contrasting styles of mineralization in the western Woodlark and eastern Manus basins of the western Pacific / Geological Society, London, Special Publications, 87:191-205, doi:10.1144/GSL.SP.1995.087.01.16 --- Richard Knott, Anthony E. Fallick, David Rickard, and Harald Bäcker: Mineralogy and sulphur isotope characteristics of a massive sulphide boulder, Galapagos Rift, 85°55′W / Geological Society, London, Special Publications, 87:207-222, doi:10.1144/GSL.SP.1995.087.01.17 --- G. A. Cherkashev: Hydrothermal input into sediments of the Mid-Atlantic Ridge / Geological Society, London, Special Publications, 87:223-229, doi:10.1144/GSL.SP.1995.087.01.18 --- R. A. Hodkinson and D. S. Cronan: Hydrothermal sedimentation at ODP Sites 834 and 835 in relation to crustal evolution of the Lau Backarc Basin / Geological Society, London, Special Publications, 87:231-248, doi:10.1144/GSL.SP.1995.087.01.19 --- S. M. Sudarikov, M. P. Davydov, V. L. Bazelyan, and V. G. Tarasov: Distribution and transformation of Fe and Mn in hydrothermal plumes and sediments and the potential function of microbiocoenoses / Geological Society, London, Special Publications, 87:249-255, doi:10.1144/GSL.SP.1995.087.01.20 --- Cindy Lee van Dover: Ecology of Mid-Atlantic Ridge hydrothermal vents / Geological Society, London, Special Publications, 87:257-294, doi:10.1144/GSL.SP.1995.087.01.21 --- Bruce Shillito, Jean-Pierre Lechaire, Gérard Goffinet, and Francoise Gaill: Composition and morphogenesis of the tubes of vestimentiferan worms / Geological Society, London, Special Publications, 87:295-302, doi:10.1144/GSL.SP.1995.087.01.22 --- P. R. Dando, J. A. Hughes, and F. Thiermann: Preliminary observations on biological communities at shallow hydrothermal vents in the Aegean Sea / Geological Society, London, Special Publications, 87:303-317, doi:10.1144/GSL.SP.1995.087.01.23 --- S. M. Sudarikov and S. V. Galkin: Geochemistry of the Snake Pit vent field and its implications for vent and non-vent fauna / Geological Society, London, Special Publications, 87:319-327, doi:10.1144/GSL.SP.1995.087.01.24 --- Gareth Rieley, Cindy L. van Dover, David B. Hedrick, David C. White, and Geoffrey Eglinton: Lipid characteristics of hydrothermal vent organisms from 9°N, East Pacific Rise / Geological Society, London, Special Publications, 87:329-342, doi:10.1144/GSL.SP.1995.087.01.25 --- D. R. Dixon, D. A. S. B. Jollivet, L. R. J. Dixon, J. A. Nott, and P. W. H. Holland: The molecular identification of early life-history stages of hydrothermal vent organisms / Geological Society, London, Special Publications, 87:343-350, doi:10.1144/GSL.SP.1995.087.01.26 --- Don A. Cowan: Hyperthermophilic enzymes: biochemistry and biotechnology / Geological Society, London, Special Publications, 87:351-363, doi:10.1144/GSL.SP.1995.087.01.27 --- Christopher R. German and Martin V. Angel: Hydrothermal fluxes of metals to the oceans: a comparison with anthropogenic discharge / Geological Society, London, Special Publications, 87:365-372, doi:10.1144/GSL.SP.1995.087.01.28 --- Kevin G. Speer and Karl R. Helfrich: Hydrothermal plumes: a review of flow and fluxes / Geological Society, London, Special Publications, 87:373-385, doi:10.1144/GSL.SP.1995.087.01.29 --- Mark D. Rudnicki: Particle formation, fallout and cycling within the buoyant and non-buoyant plume above the TAG vent field / Geological Society, London, Special Publications, 87:387-396, doi:10.1144/GSL.SP.1995.087.01.30