ALBERT

Notes: Using the static form of a system of equations for seismic waves (de la Cruz & Spanos 1989), we show how various compressibilities can be calculated in a straightforward manner. The results obtained have many points of contact with those found in the literature. In particular, we verify all identities among drained compressibilities given in, e.g., Zimmerman (1991), thus providing an alternative route towards them. The undrained compressibility is described within the context of this work and its relation to the various drained compressibilities (Gassmann 1951) is verified. For greater experimental flexibility, we introduce a one-parameter family of compressibilities which includes the drained and the undrained compressibilities as members. The family of compressibilities is also used to obtain an expression for the pore-pressure build-up coefficient. In this work we also address the problem of macroscopic shearing. Experiments are proposed for the determination of the macroscopic shear modulus, leading to natural expressions for ‘Young's modulus’ and ‘Poisson's ratio’ for the porous medium under drained conditions. We also establish connections with Biot's (1956a) parameters.

Notes: The 7E gene is expressed late in normal development of Dictyostelium discoideum after pseudoplasmodium formation. After disaggregation of the developing cells, transcription of this gene depends entirely on exogenous 3′5′ cyclic AMP (cAMP). The 5′ flanking region of the 7E gene contains two TATA box-oligo (dT) promoter motifs but analysis of 7E gene expression by primer extension shows only a single primary transcript with transcription initiating immediately after the most proximal promoter motif during development or in disaggregated cells in the presence of exogenous cAMP. Four C-rich sequence lie within 350 bp upstream of the cap site, analogus to the upstream elements implicated in the cAMP regulation of several other Dictyostelium genes expressed in development.

Notes: Residues of fluazifop-butyl were determined in strawberries from New Brunswick and Nova Scotia, Canada and North Carolina, U.S.A. using a High Performance Liquid Chromatography (HPLC) system. Strawberries harvested within 28 days of treatment (pre-harvest interval= PHI) had detectable residues of fluazifop, ranging from 0.05 ppmw with a split application of 0.25 kg ha-1 and a 18-day PHI to 3.24 ppmw with a split application of 0.5 kg ha−1 and a 12-day PHI. Fluazifop was not detected in samples treated 287 days or more before harvest (prior growing season) at 0.25–1.65 kg ha−1 (three applications of 0.55 kg ha−1). Fluazifop-butyl did not provide acceptable control (50% with two applications of 0.25 kg ha−1) of Elymus repens (L.) Gould in a commercial planting in New Brunswick. Control of Digitaria sanguinalis (L.) Scop. was better than 90% with two applications of 0.30 kg ha−1 in North Carolina. Fluazifop-butyl did not injure strawberries at any of the rates or sites tested. Résidus et efficacité du fluazifop-butyle en culture de fraises Les résidus du fluazifop-butyle dans des fraises provenant de New Brunswick et Nova Scotia au Canada et de North Carolina aux Etats-Unis ont été déterminés en utilisant un système de chromatographie liquide à haute performance (HPLC). Des fraises récoltées avant 28 jours après le traitement (PHI 28) contenaient des résidus de fluazifop décelables, allant de 0.05 ppmw après un apport fractionné de 0,25 kg ha−1 et PHI 18 à 3,24 ppmw après un apport fractionné de 0,5 kg ha−1 et PHI 12. Nulle trace de fluazifop n'a été décelée dans des échantillons traités au moins 287 jours avant la récolte, c'est-à-dire pendant la saison précédente, aux doses de 0,25 à 1,65 kg ha−1 (trois pulvérisations à 0,55 kg ha−1). Le fluazifop-butyle n'a pas permis une destruction convenable d'Elymus repens (L.) Gould dans une exploitation commerciale au New Brunswick (50% suivant deux pulvérisations à 0,25 kg ha−1). La destruction de Digitaria sanguinalis (L.) Scop. avec deux pulvérisations à 0,30 kg ha−1 en North Carolina dépassait 90%. Le fluazifop-butyle n'a provoqué de dégâts dans les fraises à aucune des doses testées ni à aucune localité. Rückstände und Wirkung von Fluazifop-Butyl in Erdbeeren Erdbeeren von Neu-Braunschweig, Neu-Schott-land (Kanada) und Nord-Karolina (U.S.A.) wurden mittels Hochleistungs-Flüssigkeits-Chromatographie (HPLC) auf Rückstande von Fluazifop-Butyl untersucht. Innert 28 Tagen nach der Behandlung (Intervall vor der Ernte = PHI) geerntete Erdbeeren enthielten messbare Rückstande von Fluazifop; sie betrugen zwischen 0,05 ppmw nach einer Split-Applikation von 0,25 kg ha−1 und einem PHI von 18 Tagen und 3,24 ppmw nach Split-Applikation von 0,5 kg ha−1 und 12 Tagen PHI. Es wurden keine Rückstände in Proben gefunden, die 287 oder mehr Tage vor der Ernte mit 0,5–1,65 kg ha−1 (drei Applikationen von je 0,55 kg ha−1) behandelt worden waren (vor der Wachstumsperiode). Fluazifop-Butyl erzielte keine genügende Kontrolle von Elymus repens (L.) Gould (50% Erfolg nach zwei Behandlungen mit 0,25 kg ha−1) in einer Produktionspflanzung in Neu-Braunschweig. Der Erfolg gegen Digitaria sanguinalis (L.) Scop. war in Nord-Karolina nach zwei Applikationen von 0,30 kg ha−1 höher als 98%. Fluazifop-Butyl schädigte die Erdbeeren an keinem der Standorte und mit keiner Dosierung.

Notes: We present, as a progress report, a revised and much enlarged version of the thermodynamic dataset given earlier (Holland & Powell, 1985). This new set includes data for 123 mineral and fluid end-members made consistent with over 200 P–T–XCO2–fO2 phase equilibrium experiments. Several improvements and advances have been made, in addition to the increased coverage of mineral phases: the data are now presented in three groups ranked according to reliability; a large number of iron-bearing phases has been included through experimental and, in some cases, natural Fe:Mg partitioning data; H2O and CO2 contents of cordierites are accounted for with the solution model of Kurepin (1985); simple Landau theory is used to model lambda anomalies in heat capacity and the Al/Si order–disorder behaviour in some silicates, and Tschermak-substituted end-members have been derived for iron and magnesium end-members of chlorite, talc, muscovite, biotite, pyroxene and amphibole.For the subset of data which overlap those of Berman (1988), it is encouraging to find both (1) very substantial agreement between the two sets of thermodynamic data and (2) that the two sets reproduce the phase equilibrium experimental brackets to a very similar degree of accuracy. The main differences in the two datasets involve size (123 as compared to 67 end-members), the methods used in data reduction (least squares as compared to linear programming), and the provision for estimation of uncertainties with this dataset. For calculations on mineral assemblages in rocks, we aim to maximize the information available from the dataset, by combining the equilibria from all the reactions which can be written between the end-members in the minerals. For phase diagram calculations, we calculate the compositions of complex solid solutions (together with P and T) involved in invariant, univariant and divariant assemblages. Moreover we strongly believe in attempting to assess the probable uncertainties in calculated equilibria and hence provide a framework for performing simple error propagation in all calculations in thermocalc, the computer program we offer for an effective use of the dataset and the calculation methods we advocate.

Notes: On the basis of fluid inclusion evidence, pervasive influx of deep-seated CO2-rich fluids has been invoked to account for mid- to upper amphibolite facies (M2B) metamorphism on the island of Naxos (Cyclades, Greece). In this paper, mineral devolatilization and melt equilibria are used to constrain the composition of both syn- and post-peak-M2B fluids in the deepest exposed levels of the metamorphic complex. The results indicate that peak-M2B fluids were spatially and compositionally heterogeneous throughout the high-grade core of the complex, whereas post-peak-M2B fluids were generally water-rich. The observed heterogeneities in syn-M2B fluid composition are inconsistent with pervasive CO2-flushing models invoked by previous workers on the basis of fluid inclusion evidence. It is likely that few CO2-rich fluid inclusions on Naxos preserve fluids trapped under peak metamorphic conditions. It is suggested that many of these inclusions have behaved as chemically open systems during the intense deformation that accompanied the uplift of the metamorphic complex. A similar process may explain the occurrence of some CO2-rich fluid inclusions in granulite facies rocks.

Notes: A combination of fluid inclusion, stable isotope and geochemical techniques has been used to study the nature of fluids present and their behaviour during Caledonian low-grade metamorphism of the Harlech Dome, north Wales. Fluid inclusion studies show that in most of the metasedimentary sequence the peak metamorphic fluid was an aqueous Na–K–Cl brine but in the graphitic Clogau Formation and in parts of the overlying Maentwrog Formation immiscible H2O-rich and CH4-rich fluids coexisted.Late-stage inclusions are of calcium-rich brine and a dilute aqueous fluid. The chemical composition of chlorite in metamorphic veins and rocks varies between different formations and quartz-oxygen isotopic compositions show considerable variation between different units. Both of these features are taken to indicate that there was little or no pervasive movement of fluid between different units at the peak of metamorphism. After the metamorphic peak there was focused flow of fluid upward through the sequence along fractures, in response to end-Caledonian uplift and unloading. Where the migrating fluid crossed the graphitic shales, interaction between the fluid and the shales gave rise to the formation of the auriferous veins of the Dolgellau Gold Belt. Subsequent to this mineralizing event there was widespread development of 18O-enriched calcites and micas.In the case of vein minerals it is possible that these crystallized directly from late-stage fluids at lower temperature than the quartz in the same veins. Alternatively, the original vein minerals may have re-equilibrated with later 18O-enriched or cooler fluid. In the case of muscovites in the rock matrix it is proposed that the isotopically heavy compositions are the result of re-equilibration of initially light grains with an introduced fluid, requiring considerable influx of fluid. This event may relate to either of two late-stage fluids observed as inclusions.

Notes: Abstract This, the second of two papers, represents the application of a least squares approach, discussed in the previous paper, to the generation of an internally consistent thermodynamic dataset involving 60 reactions among 43 phases, in the system K2O–Na2O–CaO–MgO–Al2O3–SiO2–H2O–CO2. We make the assumption that all the thermodynamic data, with the exception of enthalpies of formation of the phases, are well known, and solve for an internally consistent set of enthalpies which reproduces the 60, experimentally determined, phase equilibrium reactions. An important difference between our dataset and that of previous alternatives in the literature is that we are able to determine the uncertainties on, and correlations between, the enthalpies of formation for all phases in the set, and hence are able to apply simple error propagation techniques to determine the uncertainties in any phase equilibrium calculations performed using this dataset. Selection of reactions, for geothermometry and geobarometry, may be more readily made by choosing equilibria with small uncertainties in their thermodynamics. Our data are in reasonably close agreement with the high temperature molten oxide calorimetry results on silicate minerals where available, a fact which lends a degree of confidence to the results.

Notes: Sapphirine, coexisting with quartz, is an indicator mineral for ultrahigh-temperature metamorphism in aluminous rock compositions. Here a new activity-composition model for sapphirine is combined with the internally consistent thermodynamic dataset used by THERMOCALC, for calculations primarily in K2O-FeO-MgO-Al2O3-SiO2-H2O (KFMASH). A discrepancy between published experimentally derived FMAS grids and our calculations is understood with reference to H2O. Published FMAS grids effectively represent constant aH2O sections, thereby limiting their detailed use for the interpretation of mineral reaction textures in compositions with differing H2O.For the calculated KFMASH univariant reaction grid, sapphirine + quartz assemblages occur at P–T in excess of 6–7 kbar and 1005 °C. Sapphirine compositions and composition ranges are consistent with natural examples. However, as many univariant equilibria are typically not ‘seen’ by a specific bulk composition, the univariant reaction grid may reveal little about the detailed topology of multi-variant equilibria, and therefore is of limited use for interpreting the P–T evolution of mineral assemblages and reaction sequences. Calculated pseudosections, which quantify bulk composition and multi-variant equilibria, predict experimentally determined KFMASH mineral assemblages with consistent topology, and also indicate that sapphirine stabilizes at increasingly higher pressure and temperature as XMg increases. Although coexisting sapphirine and quartz can occur in relatively iron-rich rocks if the bulk chemistry is sufficiently aluminous, the P–T window of stability shrinks with decreasing XMg. An array of mineral assemblages and mineral reaction sequences from natural sapphirine + quartz and other rocks from Enderby Land, Antarctica, are reproducible with calculated pseudosections. That consistent phase diagram calculations involving sapphirine can be performed allows for a more thorough assessment of the metamorphic evolution of high-temperature granulite facies terranes than was previously possible. The establishment of a a-x model for sapphirine provides the basis for expansion to larger, more geologically realistic chemical systems (e.g. involving Fe3+).