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  • 1
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    PANGAEA
    In:  Supplement to: van Hulten, Marco M P; Sterl, Andreas; Middag, Rob; de Baar, Hein J W; Gehlen, Marion; Dutay, Jean-Claude; Tagliabue, Alessandro (2014): On the effects of circulation, sediment resuspension and biological incorporation by diatoms in an ocean model of aluminium. Biogeosciences, 11(14), 3757-3779, https://doi.org/10.5194/bg-11-3757-2014
    Publication Date: 2023-01-13
    Description: The distribution of dissolved aluminium in the West Atlantic Ocean shows a mirror image with that of dissolved silicic acid, hinting at intricate interactions between the ocean cycling of Al and Si. The marine biogeochemistry of Al is of interest because of its potential impact on diatom opal remineralisation, hence Si availability. Furthermore, the dissolved Al concentration at the surface ocean has been used as a tracer for dust input, dust being the most important source of the bio-essential trace element iron to the ocean. Previously, the dissolved concentration of Al was simulated reasonably well with only a dust source, and scavenging by adsorption on settling biogenic debris as the only removal process. Here we explore the impacts of (i) a sediment source of Al in the Northern Hemisphere (especially north of ~ 40° N), (ii) the imposed velocity field, and (iii) biological incorporation of Al on the modelled Al distribution in the ocean. The sediment source clearly improves the model results, and using a different velocity field shows the importance of advection on the simulated Al distribution. Biological incorporation appears to be a potentially important removal process. However, conclusive independent data to constrain the Al / Si incorporation ratio by growing diatoms are missing. Therefore, this study does not provide a definitive answer to the question of the relative importance of Al removal by incorporation compared to removal by adsorptive scavenging.
    Type: Dataset
    Format: application/zip, 2 GBytes
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  • 2
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    PANGAEA
    In:  Supplement to: van Hulten, Marco M P; Middag, Rob; Dutay, Jean-Claude; de Baar, Hein J W; Roy-Barman, Matthieu; Gehlen, Marion; Tagliabue, Alessandro; Sterl, Andreas (2017): Manganese in the west Atlantic Ocean in the context of the first global ocean circulation model of manganese. Biogeosciences, 14(5), 1123-1152, https://doi.org/10.5194/bg-14-1123-2017
    Publication Date: 2023-02-24
    Description: Dissolved manganese (Mn) is a biologically essential element. Moreover, its oxidised form is involved in removing itself and several other trace elements from ocean waters. Here we report the longest thus far (17500 km length) full-depth ocean section of dissolved Mn in the west Atlantic Ocean, comprising 1320 data values of high accuracy. This is the GA02 transect that is part of the GEOTRACES programme, which aims to understand trace element distributions. The goal of this study is to combine these new observations with new, state-of-the-art, modelling to give a first assessment of the main sources and redistribution of Mn throughout the ocean. To this end, we simulate the distribution of dissolved Mn using a global-scale circulation model. This first model includes simple parameterisations to account for the sources, processes and sinks of Mn in the ocean. Oxidation and (photo)reduction, aggregation and settling, as well as biological uptake and remineralisation by plankton are included in the model. Our model provides, together with the observations, the following insights: – The high surface concentrations of manganese are caused by the combination of photoreduction and sources contributing to the upper ocean. The most important sources are sediments, dust, and, more locally, rivers. – Observations and model simulations suggest that surface Mn in the Atlantic Ocean moves downwards into the southward-flowing North Atlantic Deep Water (NADW), but because of strong removal rates there is no elevated concentration of Mn visible any more in the NADW south of 40° N. – The model predicts lower dissolved Mn in surface waters of the Pacific Ocean than the observed concentrations. The intense oxygen minimum zone (OMZ) in subsurface waters is deemed to be a major source of dissolved Mn also mixing upwards into surface waters, but the OMZ is not well represented by the model. Improved high-resolution simulation of the OMZ may solve this problem. – There is a mainly homogeneous background concentration of dissolved Mn of about 0.10–0.15 nM throughout most of the deep ocean. The model reproduces this by means of a threshold on particulate manganese oxides of 25 pM, suggesting that a minimal concentration of particulate Mn is needed before aggregation and removal become efficient. – The observed distinct hydrothermal signals are produced by assuming both a strong source and a strong removal of Mn near hydrothermal vents.
    Keywords: GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes
    Type: Dataset
    Format: application/zip, 393.1 MBytes
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  • 3
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    PANGAEA
    In:  Supplement to: Lambert, Fabrice; Tagliabue, Alessandro; Shaffer, Gary; Lamy, Frank; Winckler, Gisela; Farías, Laura; Gallardo, Laura; De Pol-Holz, Ricardo (2015): Dust fluxes and iron fertilization in Holocene and Last Glacial Maximum climates. Geophysical Research Letters, 42(14), 6014-6023, https://doi.org/10.1002/2015GL064250
    Publication Date: 2023-10-19
    Description: Mineral dust aerosols play a major role in present and past climates. To date, we rely on climate models for estimates of dust fluxes to calculate the impact of airborne micronutrients on biogeochemical cycles. Here we provide a new global dust flux data set for Holocene and Last Glacial Maximum (LGM) conditions based on observational data. A comparison with dust flux simulations highlights regional differences between observations and models. By forcing a biogeochemical model with our new data set and using this model's results to guide a millennial-scale Earth System Model simulation, we calculate the impact of enhanced glacial oceanic iron deposition on the LGM-Holocene carbon cycle. On centennial timescales, the higher LGM dust deposition results in a weak reduction of 〈10 ppm in atmospheric CO2 due to enhanced efficiency of the biological pump. This is followed by a further ~10 ppm reduction over millennial timescales due to greater carbon burial and carbonate compensation.
    Type: Dataset
    Format: application/x-netcdf, 769.4 kBytes
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  • 4
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    PANGAEA
    In:  Supplement to: Browning, Thomas J; Achterberg, Eric Pieter; Rapp, Insa; Engel, Anja; Bertrand, E M; Tagliabue, Alessandro; Moore, C Mark (2017): Nutrient co-limitation at the boundary of an oceanic gyre. Nature, 551(7679), 242-246, https://doi.org/10.1038/nature24063
    Publication Date: 2023-09-27
    Description: Nutrient limitation of oceanic primary production exerts a fundamental control on marine food webs and the flux of carbon into the deep ocean1. The extensive boundaries of the oligotrophic sub-tropical gyres collectively define the most extreme transition in ocean productivity, but little is known about nutrient limitation in these zones1,2,3,4. Here we present the results of full-factorial nutrient amendment experiments conducted at the eastern boundary of the South Atlantic gyre. We find extensive regions in which the addition of nitrogen or iron individually resulted in no significant phytoplankton growth over 48 hours. However, the addition of both nitrogen and iron increased concentrations of chlorophyll a by up to approximately 40-fold, led to diatom proliferation, and reduced community diversity. Once nitrogen–iron co-limitation had been alleviated, the addition of cobalt or cobalt-containing vitamin B12 could further enhance chlorophyll a yields by up to threefold. Our results suggest that nitrogen–iron co-limitation is pervasive in the ocean, with other micronutrients also approaching co-deficiency. Such multi-nutrient limitations potentially increase phytoplankton community diversity.
    Keywords: GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 5
    Publication Date: 2024-03-02
    Description: In this dataset we present a global compilation of over 1000 sedimentary records of 230Th from across the global ocean at two time slices, the Late Holocene (0-5000 years ago, or 0-5 ka) and the Last Glacial Maximum (18.5-23.5 ka). Data have been screened for age control, errors, and lithogenic corrections. Overall quality levels were computed by summing each record's scores on the individual criteria. A record is optimal if it is based on a chronology that is constrained by δ18O or 14C and it provides both the raw nuclide concentrations and the associated errors. About one quarter of the records in the database achieved this highest quality level. The large majority of the records in the database are good, passing two of the three criteria, while the remaining quarter are of fair or poor quality.
    Keywords: Comment; DEPTH, water; Distance; Flag; Focusing factor; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; Identification; LATITUDE; LONGITUDE; Ocean; ORDINAL NUMBER; Quality level; Ratio; Reference/source; Thorium-230 excess, decay-corrected; Total sediment, flux; Uranium/Thorium ratio
    Type: Dataset
    Format: text/tab-separated-values, 15667 data points
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  • 6
    Publication Date: 2024-03-15
    Description: Surface ocean pH is declining due to anthropogenic atmospheric CO2 uptake with a global decline of ~0.3 possible by 2100. Extracellular pH influences a range of biological processes, including nutrient uptake, calcification and silicification. However, there are poor constraints on how pH levels in the extracellular microenvironment surrounding phytoplankton cells (the phycosphere) differ from bulk seawater. This adds uncertainty to biological impacts of environmental change. Furthermore, previous modelling work suggests that phycosphere pH of small cells is close to bulk seawater, and this has not been experimentally verified. Here we observe under 140 μmol photons/m**2/s the phycosphere pH of Chlamydomonas concordia (5 µm diameter), Emiliania huxleyi (5 µm), Coscinodiscus radiatus (50 µm) and C. wailesii (100 µm) are 0.11 ± 0.07, 0.20 ± 0.09, 0.41 ± 0.04 and 0.15 ± 0.20 (mean ± SD) higher than bulk seawater (pH 8.00), respectively. Thickness of the pH boundary layer of C. wailesii increases from 18 ± 4 to 122 ± 17 µm when bulk seawater pH decreases from 8.00 to 7.78. Phycosphere pH is regulated by photosynthesis and extracellular enzymatic transformation of bicarbonate, as well as being influenced by light intensity and seawater pH and buffering capacity. The pH change alters Fe speciation in the phycosphere, and hence Fe availability to phytoplankton is likely better predicted by the phycosphere, rather than bulk seawater. Overall, the precise quantification of chemical conditions in the phycosphere is crucial for assessing the sensitivity of marine phytoplankton to ongoing ocean acidification and Fe limitation in surface oceans.
    Keywords: Acid-base regulation; Alkalinity, total; Aragonite saturation state; Bicarbonate ion; Bottles or small containers/Aquaria (〈20 L); Calcite saturation state; Calculated using seacarb after Nisumaa et al. (2010); Carbon, inorganic, dissolved; Carbonate ion; Carbonate system computation flag; Carbon dioxide; Chromista; Coscinodiscus wailesii; Figure; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Hydrogen ion concentration; Laboratory experiment; Laboratory strains; Not applicable; OA-ICC; Ocean Acidification International Coordination Centre; Ochrophyta; Partial pressure of carbon dioxide (water) at sea surface temperature (wet air); Pelagos; pH; Phytoplankton; Proton gradients; Salinity; Single species; Species, unique identification; Temperature, water; Thickness; Treatment; Type
    Type: Dataset
    Format: text/tab-separated-values, 3286 data points
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  • 7
    ISSN: 0022-328X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    FEBS Letters 243 (1989), S. 394-398 
    ISSN: 0014-5793
    Keywords: (RAJI B lymphoma, EL4-6.1 thymoma) ; Interleukin 1 receptor ; Interleukin 1α ; Interleukin 1β
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Nuclear Physics 23 (1961), S. 144-152 
    ISSN: 0029-5582
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 409 (1983), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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