ISSN:
1572-8854
Schlagwort(e):
X-ray diffraction
;
xanthenedione
;
heterocyclic fused rings
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Geologie und Paläontologie
,
Physik
Notizen:
Abstract Several 9-(2-R phenyl)xanthenediones have been synthesized and the x-ray diffraction structure for the 2-methylphenyl derivative (4b) has been determined. This compound crystallizes in the monoclinic system, space group P21/n, with a = 11.729 (3), b = 9.674 (3), c = 14.628 (4) Å, and β = 106.30°. It presents a partially hydrogenated xanthene system in distorted boat conformation for the heterocyclic central ring, and an almost ideal envelope conformation for the outer rings. The aromatic substituent at the ninth position is at 84° in angle with the xanthene system.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1009583417391
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