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  • Artikel  (36)
  • Polymer and Materials Science  (30)
  • Amino Acid Sequence  (6)
  • Theorie
  • Physik  (36)
  • 1
    Digitale Medien
    Digitale Medien
    Hydroxyl-modified epoxy resins: Some technical and analytical aspectsDedicated to Professor Dr. H. Batzer in honour of his 60th birthday (1980)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 181 (1980), S. 1-17 
    Details
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The modification of epoxy resins by reactions involving their hydroxyl groups is described. For example, reactions with enol ethers, acrylonitrile, ethyl acetoacetate and certain other carboxylic esters, or triethyl orthoformate, gave products which had reduced reactivities towards various hardeners, and which therefore gave lower peak temperatures on cure and/or longer usable lives. Suitable modification of epoxy resins with various other reagents(certain acid anhydrides, epichlorohydrin, or N-hydroxymethylacrylamide) introduces additional useful functional groups. The uses of a diisocyanate and of α-naphthyl isocyanate to modify epoxy resins or their mixtures prior to GPC analysis are also mentioned.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/macp.1980.021810101
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  • 2
    Digitale Medien
    Digitale Medien
    Factors influencing izod impact properties of thermoplastics measured with the autographic impact test (1964)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 119-140 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The standardization of notched Izod impact test data to normalized values of foot pounds per inch of notch is based on the assumption of a 1:1 increase in breaking strength with increasing notch width. This assumed relation is not supported by experimental tests on commercial thermoplastics. As notch width was increased from 1/8 to 1/4 to 3/8 to 1/2 in., nine of ten thermoplastics tested showed a decrease in normalized impact strength. Each material appears to show a characteristic loss in breaking strengths as the notch width increases. A technique developed for calibration of pendulum impact testers has been used to examine the variation of impact breaking strength in relation to the total kinetic energy of the hammer. Experimental tests show practically no change in impact strengths up to values that take 2/3 of the available hammer energy. Experimental work on the comparison of the impulse transferred by the hammer during breaking with impulse curves photographed by the Autographic Impact test show very good agreement for catastrophic breaks and fair agreement for plastic type breaks. The reduction in recorded impulse is attributed to the degrading of the sample during the plastic portion of the breaking cycle. The peak force of thermoplastics as measured by the Autographic Impact test increases as the temperature decreases from 100°C. or above to 0°C. Over the same temperature range flexural tests on small cantilever samples of these thermoplastics show the same thermal dependence for the flexural yield or permanent distortion stress. Plots of the impact peak forces and flexural yield stress at corresponding temperatures give a linear correlation. Each thermoplastic material exhibits a unique relation for this correlation between impact yielding and flexural yielding. This correlation between the impact and flexural tests over the range of temperatures is the first known experimental indication of a direct relation between impact properties and standard physical tests.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1964.070080109
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  • 3
    Digitale Medien
    Digitale Medien
    Swelling characteristics of gel fractions of formaldehyde-modified cotton cellulosesPresented in part at the Spring Meeting of The Fiber Society at Williamsburg, Va., May 1966. (1966)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1777-1786 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A method for assessing extent of swelling of the gel fraction of formaldehyde-modified cottons, employing cupriethylenediamine hydroxide as the swelling agent, is described. Substantial differences in apparent specific volumes of swollen gel fractions are observed for cottons crosslinked by different processes to the same level of agent. The apparent crosslink density measured by the swelling of gel fraction increases with formaldehyde content of the cotton; at 0.20% formaldehyde the order of increasing crosslink density in the various processes of reaction is as follows: nonaqueous system (forms D and D′) 〈 aqueous system (forms W and W′) 〈swelling system (form F) 〈 vapor system (form V) 〈 bake-cure system (form C).
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1966.070101115
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  • 4
    Digitale Medien
    Digitale Medien
    Analysis of resorcinol-phenol-formaldehyde resins by NMR spectroscopy (1972)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 26 (1972), S. 171-176 
    Details
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Es wird eine NMR-Methode zur Bestimmung der ungefähren Verhältnisse zwischen aus Phenolkernen, Resorcinkernen und Formaldehyd gebildeten Gruppenin Kondensationsprodukten aus Phenol, Resorcin und Formaldehyd beschrieben.
    Notizen: A method is reported, based on NMR spectroscopy, for approximate determination of the component ratios of resins formed by condensation of resorcinol, phenol and formaldehyde.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/apmc.1972.050260113
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  • 5
    Digitale Medien
    Digitale Medien
    Organo-metal carbonyl compounds of iron, molybdenum, and manganese as photosensitisers of the anhydride cure of epoxy resins (1976)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 50 (1976), S. 9-14 
    Details
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Verbindungen der Strukturformeln [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], und [(π-CH3C5H4)Mn(CO)3] wurden als Katalysatoren für die Härtung von Epoxidharzen unter verschiedenen Bedingungen geprüft. Es wurde gefunden, daß die Verbindungen [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) und [π-C5H5Mo(CO)3CH3] wirksame lichtempfindliche Beschleuniger für die Anhydridhärtung von Expoxidharzen sind. Der Aktivierungsmechanismus wird diskutiert.
    Notizen: Compounds of the types [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], and [(π-CH3C5H4)Mn(CO)3] have been examined as catalysts for the cure of epoxy resins under various conditions. It was found that the compounds [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) and [π-C5H5Mo(CO)3CH3] are active photosensitizing agents for the anhydride cure of certain epoxy resins. The mechanism of the process is discussed.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/apmc.1976.050500102
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  • 6
    Digitale Medien
    Digitale Medien
    Paramagnetic shifts induced by europium and praseodymium chelates in the NMR spectrum of bisphenol a diglycidyl ether (1972)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 27 (1972), S. 159-164 
    Details
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Es wurde eine Voruntersuchung des Einflusses unternommen, den die Verschiebereagenzien Tris-(dipivaloylmethano)-europium uncl Tris-(dipivaloylmethano)-pra-seodym auf das NMR-Spektrum des Diglyzidyläthers des Bisphenol A ausüben. Es ergab sich, daß die Signale der am Epoxidring anliegenden Protonen durch den Zusatz dieser Chelate weit mehr als die Signale der exozyklischen -OCH2-Gruppen verschoben werden. Die Verschiebung kann man durch den Zusatz eines Alkohols rückgängig machen, der vorzugsweise mit dem Verschiebemittel reagiert.
    Notizen: A preliminary study has been made of the effects of the shift reagents Eu (DPM)3 and Pr(DPM)3 on the NMR spectrum of Bisphenol A diglycidyl ether (I). Protons attached to the epoxy ring were observed to shift appreciably more than protons of the exocyclic —OCH2— group, on addition of these chelates. The shifts could be reversed by addition of an alcohol, which interacted preferentially with the shift reagent.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/apmc.1972.050270111
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  • 7
    Digitale Medien
    Digitale Medien
    Paramagnetic shifts induced by europium and praseodymium complexes in the NMR spectra of some substituted phenols (1972)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 27 (1972), S. 151-157 
    Details
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Es wurden die Verschiebungen untersucht, die durch Tris-(dipivaloylmethano)-europium und Tris-(dipivaloylmethano)-praseodym im NMR- Spektrum versehiedener Derivate substituierter Phenole hervorgerufen werden. Der Zweck dieser Arbeiten war, die Möglichkeiten zu erfassen, die diese Verschiebereagenzien als Hilfsmittel in der NMR-Analyse von Phenolharzen bieten, und Information über Verschiebungen bei Molekülen zu gewinnen, die mehr als eine Koordinationsposition besitzen.
    Notizen: An investigation into the shifts induced in the NMR spectra of some derivatives of substituted phenols by tris(dipivalomethanato)europium and tris(dipivalomethanato)praseodymium is reported. The phenol derivatives were studied to ascertain the possible utility of the shift reagents as an aid in the analysis of phenolformaldehyde resins by NMR spectroscopy, and to gain information on induced shifts with molecules having more than one possible co-ordination site.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/apmc.1972.050270110
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  • 8
    Digitale Medien
    Digitale Medien
    Investigation by carbon-13 and proton NMR spectroscopy of the diglycidyl derivative of phenolphthalein (1976)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 56 (1976), S. 157-162 
    Details
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: 13C-und 1H-NMR-Untersuchungen haben überzeugend gezeigt, daß die Hauptkomponente des Epoxidharzes aus Phenolphthalein und Epichlorhydrin ein aromatischer Diglycidyläther mit einem Lactonring ist und nicht eine chinoide Verbindung mit Glycidylätherund Glycidylesterstruktur.
    Notizen: 13C- and 1H-NMR studies have shown conclusively that the main component of the epoxy resin derived from phenolphthalein and epichlorohydrin is an aromatic diglycidyl ether containing a lactone ring, rather than a glycidyl ether-glycidyl ester compound containing a quinoid ring.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/apmc.1976.050560112
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  • 9
    Digitale Medien
    Digitale Medien
    Ionene elastomers from polytetramethylene oxide diamines and reactive dihalides. I. Effect of dihalide structure on polymerization and thermal reversibility (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 1535-1547 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The reaction of α,ω-bis(dimethylamino) polytetramethylene oxide with various dihalides provided a series of elastomeric ionenes. The influence of dihalide structure on the reaction was studied and a number of substituents were found which dramatically increased the rate of polymerization and ultimate molecular weights achieved. These ionene elastomers were thermoplastic and it was shown that in some cases this result was due at least in part to a depolymerization reaction via a dequaternization of the ammonium links. Again, structural features in the dihalide were important not only for the reverse reaction, but for the repolymerization to high molecular weight elastomer as well. An uncharged “analogue” was also prepared to address the feature of microphase separation and compared with the above ionene materials.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1989.070380810
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  • 10
    Digitale Medien
    Digitale Medien
    Structure-property behavior of elastomeric segmented PTMO-ionene polymers. II (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 1549-1565 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A series of segmented ionene polymers based on the reaction of α,ω-bis(dimethyl amino)polytetramethylene oxide with various dihalide compounds were investigated with respect to their structure-property behavior. The placement of quaternary ammonium ions and halide counterions along the polymer chains was varied by changing the molecular weight of the PTMO soft segment and the structure of the dihalide linking agent. The techniques of dynamic mechanical spectroscopy, thermal analysis, small angle X-ray scattering, and stress-strain behavior analysis were applied. For the case when the PTMO soft segment was amorphous, the ambient temperature properties of these materials displayed low modulus, high strength, and high elongation elastomeric behavior with tensile strength enhanced by the strain-induced crystallization of the PTMO. A high level of phase separation existed between the dihalide component relative to the PTMO soft segment. Due to the Coulombic association of the ionene species, these materials displayed many similarities to the segmented urethane ionomers. In particular, distinct domain structure was noted by SAXS, whose dimensional scale was similar to the segmented urethanes. It was also shown, however, that the driving forces for the microphase separation was caused by favorable electrostatic or Coulombic interactions in contrast to segment-segment incompatibility features as in the segmented urethanes.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1989.070380811
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