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  • Artikel  (125)
  • Springer  (125)
  • Public Library of Science (PLoS)
  • Chemie und Pharmazie  (98)
  • Geologie und Paläontologie  (30)
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  • Artikel  (125)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of applied electrochemistry 11 (1981), S. 677-683 
    ISSN: 1572-8838
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract There are advantages if zinc can be deposited electrochemically at high current densities. In order to improve the deposit at current densities exceeding 2000 Am−2, various additions were made to the electrolyte. It was found that proteinous additives produced planar deposits with a (10.2) (10.3) orientation and a current efficiency of around 85% in a small laboratory cell.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical crystallography 13 (1983), S. 317-323 
    ISSN: 1572-8854
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract The X-ray structure determination of (η 5-C5H5)Co(HNC6H4NH) (Ib) reveals that the compound crystallizes in the monoclinic space groupP21/n witha=12.479(3),b=8.865(2),c=17.817(5) Å, {iβ}=94.70(2)°,V=1964.4(6) Å3,Z=8 (two independent molecules form the asymmetric unit). Least-squares refinement based on 1894 independent observed reflections,I≥2.5σ(I), resulted in a finalR value of 0.054. A pattern of somewhat shortened Co-N bonds (〈av〉 1.83 Å), short C-N bonds (〈av〉 1.34 Å), Co-N-C bond angles consistent with trigonally hybridized N, and a nearly planar metallocyclic ring suggest that some electron delocalization may exist in the ring. This pattern, however, may also be explicable in terms of factors other than delocalization; alternatives are discussed. The structure may best be regarded as a CoI complex containing ano-quinonediimine ligand.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of applied electrochemistry 12 (1982), S. 1-5 
    ISSN: 1572-8838
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: Abstract The conductivity of aqueous zinc chloride reaches a maximum of 10.7 Ω−1 m−1 at 3.7 M ZnCl2. Measurements on chlorinated ZnCl2 showed that at low chlorine concentrations, the conductivity increased linearly with the square root of the chlorine concentration. The increase was due to the three species: dissolved chlorine, Cl 3 − and HClO. Ammonium chloride additions increased the conductivity of aqueous zinc chloride substantially.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Monatshefte für Chemie 126 (1995), S. 839-850 
    ISSN: 1434-4475
    Schlagwort(e): Electrode glasses ; Principal Component Analysis ; Cluster analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Cluster Analysis has been shown to be partially suitable for the classification of glasses. The expansion of the clusters on theSeger's diagram allows an investigation of the influence of the different glass components. Variation of the SiO2 content results in a smaller change of properties than variation of the Na2O/RO relationship. Principal Component Analysis is convenient for showing correlations between the composition of the examined glasses, the glass structure parameters, and the different electrode properties. Properties of electrodes are mostly influenced by the content of Na2O and by the kind of the divalent cations. In contrast thereto structure parameters become basically determined by the content of SiO2 and RO. The field strength of the divalent cations plays the decisive roll again.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    ISSN: 1436-5073
    Schlagwort(e): FTIR ; rapid-scan ; thermal analysis ; nitrate salts
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A new experiment is described to advance the mechanistic description of fast thermal decomposition chemistry related to preignition and ignition. The technique is illustrated with data for ethylenediammonium dinitrate which displays separable thermochemical events in the condensed phase that correlate with the nature of the products evolved to the gas phase.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Marine geophysical researches 13 (1991), S. 287-309 
    ISSN: 1573-0581
    Schlagwort(e): SeaMARC II ; side-scan ; bathymetry ; magnetics microplates ; rift propagation ; East Pacific Rise
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract The Pito Rift area is the site of actively deforming oceanic lithosphere that has been primarily under extension for at least the past million years, based on kinematic reconstructions. The major morphologic features, Pito Deep and Pito Seamount, are aligned toward the Euler pole for relative motion between the Easter and Nazca plates. SeaMARC II side-scan and bathymetry data indicate that there are two general modes of faulting currently active in the Pito Rift area. One is associated with incipient rifting of old (∼3 Ma) Nazca lithosphere by large NW-SE normal faults, and the other is associated with a broad area of right-lateral transform shear between the Nazca and Easter plates. This transform shear is distributed over a broad region because of the northward growth of the East Rift and parallel tectonic rifting within the Pito Rift area. The majority of the Pito Rift area is composed of preexisting blocks of Nazca plate that are back-tilted away from Pito Deep and strike perpendicular to present and previous relative plate motions. This observation suggests that block-faulting and back-tilting are the primary mechanisms responsible for the distributed lithospheric extension, in agreement with gravity and magnetic analyses (Martinez et al., this issue). The only recent volcanic flows observed in side-scan data are from the Pito Seamount area and to the outside of the outer pseudofault of the East Rift. The significance of the young flows near the outer pseudofault is not understood. We interpret the flows extending northwest from the Pito Seamount as representing a newly formed seafloor spreading axis within the Pito Rift area. Gravity and magnetic analyses (Martinez et al., this issue) together with SeaMARC II bathymetry and side-scan data support this interpretation. Based on the tectonic evolution of the Easter microplate, we propose an evolutionary model for the formation of the Pito Rift area, where new ‘tectonic’ grabens form immediately west of the previous graben and with slightly more counterclockwise orientation. The duration and history of tectonic activity for each graben are not well constrained.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    ISSN: 1573-0581
    Schlagwort(e): Magnetic inversion ; Bouguer anomalies ; block faulting ; modelling ; microplate ; rift propagation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract We present results from a SeaMARC II bathymetry, gravity, and magnetics survey of the northern end of the large-offset propagating East Rift of the Easter microplate. The East Rift is offset by more than 300 km from the East Pacific Rise and its northern end has rifted into approximately 3 Ma lithosphere of the Nazca Plate forming a broad (70–100 km) zone of high (up to 4 km) relief referred to as the Pito Rift. This region appears to have undergone distributed and asymmetric extension that has been primarily accommodated tectonically, by block faulting and tilting, and to a lesser degree by seafloor spreading on a more recently developed magmatic accretionary axis. The larger fault blocks have dimensions of 10–15 km and have up to several km of throw between adjacent blocks suggesting that isostatic adjustments occur on the scale of the individual blocks. Three-dimensional terrain corrected Bouguer anomalies, a three-dimensional magnetic inversion, and SeaMARC II backscatter data locate the recently developed magmatic axis in an asymmetric position in the western part of the rift. The zone of magmatic accretion is characterized by an axis of negative Bouguer gravity anomalies, a band of positive magnetizations, and a high amplitude magnetization zone locating its tip approximately 10 km south of the Pito Deep, the deepest point in the rift area. Positive Bouguer gravity anomalies and negative magnetizations characterize the faulted area to the east of the spreading axis supporting the interpretation that this area consists primarily of pre-existing Nazca plate that has been block faulted and stretched, and that no substantial new accretion has occurred there. The wide zone of deformation in the Pito Rift area and the changing trend of the fault blocks from nearly N-S in the east to NW-SE in the west may be a result of the rapidly changing kinematics of the Easter microplate and/or may result from ridge-transform like shear stresses developed at the termination of the East Rift against the Nazca plate. The broad zone of deformation developed at the Pito Rift and its apparent continuation some distance south along the East Rift has important implications for microplate mechanics and kinematic reconstructions since it suggests that initial microplate boundaries may consist in part of broad zones of deformation characterized by the formation of lithospheric scale fault blocks, and that what appear to be pseudofaults may actually be the outer boundaries of tectonized zones enclosing significant amounts of stretched pre-existing lithosphere.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Earth, moon and planets 7 (1973), S. 453-474 
    ISSN: 1573-0794
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    ISSN: 1432-1157
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie
    Notizen: Abstract The hypothesis that variations of the Amazon plume are forced primarily by wind is further explored through a series of simplified numerical model simulations. The wind's role in the change in plume structure and the nature of this change are investigated for two events: a shift in wind direction from westward to southeastward and a reduction in magnitude of the westward wind speed. Under winds with a southeastward component, the plume is confined to below 5°N; this simulation represents a rare but illustrative event showing how the balance of forces is quickly adjusted under changing winds. The freshest portions of the plume expand eastward, but are confined near the river mouth, as observed. The cross-shelf and alongshelf dynamic balances are similar in magnitude to those with westward wind stress, but the balance between the equatorial jet and buoyancy-driven cross-shelf flow is altered, controlling a new along-shelf position of the front. During wind-relaxation events, the plume widens near the mouth as a result of strong, eastward cross-shelf velocities associated with an equatorial Kelvin wave.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Fresenius' journal of analytical chemistry 363 (1999), S. 185-188 
    ISSN: 1432-1130
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract 15N solid state NMR without enrichment is rarely used because of the low sensitivity and low natural abundance of this nucleus. As demonstrated on different nitrogen-containing polysilanes and polysilazanes, it can be shown that with the CP/MAS technique spectra can be obtained in good quality and within acceptable measuring time. Three main different nitrogen sites – NSi3, NSi2H and NSiH2– can be observed as well as changes in the intensities of these sites with reaction and tempering conditions. Thus the spectra give valuable additional information for a better understanding of the structures and their changes within the investigated systems.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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