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  • Articles  (871)
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  • 1
    Publication Date: 2021-02-17
    Description: Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH4 continue to increase, making CH4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO2). The relative importance of CH4 compared to CO2 depends on its shorter atmospheric lifetime, stronger warming potential, and variations in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in reducing uncertainties in the atmospheric growth rate arise from the variety of geographically overlapping CH4 sources and from the destruction of CH4 by short-lived hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottomup estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). For the 2008–2017 decade, global methane emissions are estimated by atmospheric inversions (a top-down approach) to be 576 TgCH4 yr􀀀1 (range 550–594, corresponding to the minimum and maximum estimates of the model ensemble). Of this total, 359 TgCH4 yr􀀀1 or 60% is attributed to anthropogenic sources, that is emissions caused by direct human activity (i.e. anthropogenic emissions; range 336–376 TgCH4 yr􀀀1 or 50 %–65 %). The mean annual total emission for the new decade (2008–2017) is 29 TgCH4 yr􀀀1 larger than our estimate for the previous decade (2000–2009), and 24 TgCH4 yr􀀀1 larger than the one reported in the previous budget for 2003–2012 (Saunois et al., 2016). Since 2012, global CH4 emissions have been tracking the warmest scenarios assessed by the Intergovernmental Panel on Climate Change. Bottom-up methods suggest almost 30% larger global emissions (737 TgCH4 yr􀀀1, range 594–881) than top-down inversion methods. Indeed, bottom-up estimates for natural sources such as natural wetlands, other inland water systems, and geological sources are higher than top-down estimates. The atmospheric constraints on the top-down budget suggest that at least some of these bottom-up emissions are overestimated. The latitudinal distribution of atmospheric observation-based emissions indicates a predominance of tropical emissions ( 65% of the global budget, 〈30 N) compared to mid-latitudes ( 30 %, 30–60 N) and high northern latitudes ( 4 %, 60–90 N). The most important source of uncertainty in the methane budget is attributable to natural emissions, especially those from wetlands and other inland waters. Some of our global source estimates are smaller than those in previously published budgets (Saunois et al., 2016; Kirschke et al., 2013). In particular wetland emissions are about 35 TgCH4 yr􀀀1 lower due to improved partition wetlands and other inland waters. Emissions from geological sources and wild animals are also found to be smaller by 7 TgCH4 yr􀀀1 by 8 TgCH4 yr􀀀1, respectively. However, the overall discrepancy between bottom-up and top-down estimates has been reduced by only 5% compared to Saunois et al. (2016), due to a higher estimate of emissions from inland waters, highlighting the need for more detailed research on emissions factors. Priorities for improving the methane budget include (i) a global, high-resolution map of water-saturated soils and inundated areas emitting methane based on a robust classification of different types of emitting habitats; (ii) further development of process-based models for inland-water emissions; (iii) intensification of methane observations at local scales (e.g., FLUXNET-CH4 measurements) and urban-scale monitoring to constrain bottom-up land surface models, and at regional scales (surface networks and satellites) to constrain atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) development of a 3D variational inversion system using isotopic and/or co-emitted species such as ethane to improve source partitioning.
    Description: Published
    Description: 1561–1623
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Atmospheres 120 (2015): 2647–2660, doi:10.1002/2014JD022531.
    Description: The ecosystems in Northern Eurasia (NE) play an important role in the global water cycle and the climate system. While evapotranspiration (ET) is a critical variable to understand this role, ET over this region remains largely unstudied. Using an improved version of the Terrestrial Ecosystem Model with five widely used forcing data sets, we examine the impact that uncertainties in climate forcing data have on the magnitude, variability, and dominant climatic drivers of ET for the period 1979–2008. Estimates of regional average ET vary in the range of 241.4–335.7 mm yr−1 depending on the choice of forcing data. This range corresponds to as much as 32% of the mean ET. Meanwhile, the spatial patterns of long-term average ET across NE are generally consistent for all forcing data sets. Our ET estimates in NE are largely affected by uncertainties in precipitation (P), air temperature (T), incoming shortwave radiation (R), and vapor pressure deficit (VPD). During the growing season, the correlations between ET and each forcing variable indicate that T is the dominant factor in the north and P in the south. Unsurprisingly, the uncertainties in climate forcing data propagate as well to estimates of the volume of water available for runoff (here defined as P-ET). While the Climate Research Unit data set is overall the best choice of forcing data in NE according to our assessment, the quality of these forcing data sets remains a major challenge to accurately quantify the regional water balance in NE.
    Description: This research is supported by the NASA Land Use and Land Cover Change program (NASA- NNX09AI26G, NN-H-04-Z-YS-005-N, and NNX09AM55G); the Department of Energy (DE-FG02-08ER64599); the National Science Foundation (NSF-1028291, NSF-0919331, and AGS 0847472); and the NSF Carbon and Water in the Earth Program (NSF-0630319). D.G.M. acknowledges financial support from The Netherlands Organisation for Scientific Research (NWO) Veni grant 863.14.004
    Description: 2015-10-03
    Keywords: Evapotranspiration ; Northern Eurasia ; Terrestrial ecosystem model ; Climate reanalysis ; Forcing uncertainty
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 3
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    Frontiers Media SA
    In:  EPIC3Frontiers in microbiology, Frontiers Media SA, 13
    Publication Date: 2022-08-11
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
    Format: application/pdf
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  • 4
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 330-332 (Feb. 2007), p. 107-110 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Stability of hydroxyapatite(HA) structure is influenced by preparation conditions andafterwards heat treatment. In this paper, the powders with different Ca/P molar ratio were calcinedto investigate the influence of Ca/P and heat treatment on thermal decomposition and reconstitutionof HA. The results show that the Ca/P has little change even calcined at a high temperature of1500℃. The Ca/P molar ratio close to 1.67 is beneficial to form high purity HA. HA graduallyreleases its OH- ions in the temperature range of 800-1200℃. The decomposition takes place atabout 1200℃ and will become more and more severe with the increase of temperature. Coolingwith slow rate and post-heat treatment in wet atmosphere are beneficial to both the rehydration andthe recovery of HA from the decomposition products (TTCP and α-TCP)
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 546-549 (May 2007), p. 691-696 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The horizontal direct chill (HDC) casting process is a well-established production route foran aluminum alloy ingot; however, the ingot may suffer from inhomogeneous microstructures andserious macrosegregation due to the unbalanced cooling condition and gravitational effect. In order tocontrol the defect, a low frequency electromagnetic field has been applied in the HDC casting processand its influences on microstructures and macrosegregation have been studied. The results show thatthe low frequency electromagnetic field can improve macrostructures, reduce inhomogeneousmicrostructures and macrosegregation in HDC product; and two main parameters of theelectromagnetic field—density and frequency influence the microstructures and solution distributionalong the diameter of the ingot significantly. In the range of ampere-turns and frequency employed inthe experiments, the optimum ampere-turns and frequency have been found to be 10000At, 30Hz
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 575-578 (Apr. 2008), p. 869-874 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Bonding degradation at interface is one of main damage forms of composites, especiallyunder fatigue loading. Interfacial bonding degradation of FRC under two-stage tension loading isstudied, which is base for variable-amplitude cyclic loading existing widely in actual engineering.Based on the shear-lag model and considered the asymmetry of interfacial damage, the mechanicalgoverning equations of fiber and matrix are established and related solutions are obtained firstly.Two kinds of loading models are chosen, one is low-high alternate loading, and the other is lowearly and high late loading. By the aid of the Paris law and the energy release theory, a relationshipbetween debond rate and cycle number is established. Then the interfacial debonding is simulatedunder the two-stage tension loading. The rules of the crack growth are analyzed for low-hightwo-stage loadings. It is found that stress amplitude has great influence on interfacial debondingunder two-stage loading. Low stress amplitude in a certain range can postpone interfacial bondingdegradation. And interfacial damage extent is greater than that under constant-amplitude fatigueloading. Present study is helpful for analyzing the fatigue damage of engineering materials andstructures
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 3104-3108 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Acetylene and its evolution products (CCH, C2, and CCH2) on the Cu (001) surface are studied using the density functional method with cluster models. The binding energies, geometries, STM images, and vibrational frequencies for the adsorbates are obtained. The results agree well with the available experimental results. By comparing the calculated frequencies with the experimental ones, we identify the thermal evolution product of acetylene on Cu(001) in the HREELS experiment as CCH2, and establish its orientation relative to the surface. CCH2 is found to be more stable than C2H2 on Cu(001). © 2002 American Institute of Physics.
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  • 9
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The infrared spectra of PH3 molecule were recorded on a Bruker IFS 120HR Fourier transform spectrometer from 4000 to 9500 cm−1. The P–H stretching vibrational frequencies and intensities were derived from the experimental data. The Morse oscillator parameters De and α in the anharmonically coupled anharmonic oscillator local mode model were determined by the least-squares fitting with the observed vibrational band centers. The ab initio three-dimensional P–H stretching dipole moment surfaces were calculated by the density functional theory method. The dipole moment vectors were projected to three kinds of molecule-fixed reference systems. The corresponding dipole moment components were fitted to polynomial functions in terms of the P–H bond length displacements with the molecular symmetry taken into account. The absolute band intensities were obtained and then compared with the experimental data. The results showed that a proposed improved bond dipole model can predict the absolute band intensities within a factor of 2 for most of the observed transitions, indicating a reasonably good agreement. © 2001 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 9624-9631 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An ab initio quartic force field of PH3 is derived using the coupled-cluster theory with all singles and doubles supplemented with quasiperturbative treatment of the connected triple excitations [CCSD(T)], and Dunning's correlation consistent polarized valence triple zeta cc-pVTZ basis set. Improved geometry and quadratic force constants are evaluated, respectively, with the correlation consistent polarized valence quadruple zeta cc-pVQZ, core–valence quadruple zeta cc-pCVQZ, and weighted core–valence quadruple zeta cc-pwCVQZ basis sets. In the latter two cases, all electrons are correlated to account for the core correlation effects. Core–valence correlation effect on geometry is found to be significant. By comparing the cc-pCVQZ and cc-pwCVQZ results with the cc-pVQZ ones, the bond length re is reduced by 0.0045 or 0.0049 Å and the bond angle θe by 0.07° or 0.06°, respectively. Cubic and quartic force fields are further determined with the correlation consistent polarized weighted core–valence triple zeta cc-pwCVTZ basis set. Vibrational analysis based on second-order perturbation theory is carried out with the calculated force constants. Computed fundamentals of PH3 agree to better than 4 cm−1 on average with the experimental data. Spectroscopic constants are also predicted for a number of symmetric and asymmetric top isotopomers of PH3. With a minor empirical adjustment of our best force field, agreement of 1 cm−1 between the computed and experimental fundamentals is found for all isotopomers. © 2000 American Institute of Physics.
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