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  • Growth from solid phases  (1)
  • Optoelectronic devices  (1)
  • Solid phase epitaxy  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 11 (1989), S. 1805-1818 
    ISSN: 0392-6737
    Keywords: Methods of crystal growth and purification ; Growth from solid phases ; Radiation damage and other irradiation effects, ions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Nel presente lavoro è stata analizzata la ricrescita epitassiale indotta da fasci ionici di strati di Si amorfo depositati da fase di vapore su substrati di Si monocristallino di orientazione (100). La ricrescita è stata indotta da un fascio di ioni Kr++ da 600 keV e con dosi variabili tra 2·1015 e 6·1015 ioni/cm2, mantenendo costante e pari a 1·1012 ioni/cm2s il flusso, di ioni incidenti. La temperatura del campione è stata posta a 450°C. Durante gli irraggiamenti la velocità dell'interfaccia cristallo-amorfo è stata misuratain situ seguendo il segnale di riflettività della luce di un laser He-Ne incidente sulla superficie del campione. Dopo l'irraggiamento alcuni campioni sono stati anche analizzati tramite retrodiffusione alla Rutherford di4He+ da 2 MeV in combinazione con l'effetto di incanalamento e mediante microscopia elettronica in trasmissione. La velocità di crescita degli strati depositati dipende dalla procedura di pulizia eseguita sui campioni prima della deposizione, vale a dire dalla quantità totale di ossigeno presente all'interfaccia tra strato depositato e substrato. È stato anche osservato che gli strati ricristallizzati contengono del materiale geminato la cui concentrazione è fortemente dipendente dalla pulizia del substrato. Questi fenomeni sono spiegati in termini di una diminuzione della velocità di crescita assistita da fasci ionici in presenza di alte concentrazioni di ossigeno. I dati sono discussi e confrontati con quelli ottenuti con trattamenti termici convenzionali.
    Abstract: Резюме Наблюается ионно-стимулированный рост пленок Si, осажденных из химического пара на подложках (100)Si. Рост был индуцирован пучком ионов Kr++ с энергией 600 кэВ при дозах в области (2·1015÷6·1015) см−2 и при интенсивности изменения дозы 1·1012 см−2с−1. Температура мишени составляяла 450°C. Во время облучения скорость границы раздела «кристалл-аморфное тело» измерялось посредством мониторирования коэффициента отражения пучка He-Ne лазера, сфокусированного на поверхности образца. После облучения также проводился анализ некоторых образцов с помощью обратного Резерфордовского рассеяния в сочетании с эффектом каналирования и трансмиссионной электронной спектроскопией. Скорость роста осажденных слоев зависит от процедуры очистки перед непылением, т.е. от результирующего количества кислорода, имеющегося на границе раздела между осажденным слоем и подложкой. В рекристаллизованных слоях наблюдается двойниковый материал и его концентрация сильно зависит от частоты подложки. Эти явления объясняются терминах уменьшения скорости роста при высоких концентрациях кислорода. Полученные данные обсуждаются и сравниваются с данными, полученными при чистом температурном отжиге.
    Notes: Summary The ion-assisted regrowth of chemical-vapour deposited Si films onto (100) Si substrates is reported. The regrowth was induced by a 600 keV Kr++ beam at doses in the range (2·1015÷6·1015)/cm2 and at a dose rate of 1·1012/cm2s. The target temperature was set at 450°C. During irradiations the crystal-amorphous interface velocity was measuredin situ by monitoring the reflectivity of a He-Ne laser light focused onto the sample surface. After irradiation some samples were also analysed by Rutherford backscattering in combination with the channelling effect and by transmission electron microscopy. The growth rate of deposited layers depends on the cleaning procedure performed prior to deposition,i.e on the total amount of oxygen present at the deposited layer/substrate interface. Moreover, twinned material is observed in the recrystallized layers and its concentration is strongly dependent on substrate cleaning. These phenomena are explained in terms of a decrease in the ion-assisted growth rate in the presence of high oxygen concentrations. The data are discussed and compared with those obtained during pure thermal annealing.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 1131-1148 
    ISSN: 0392-6737
    Keywords: Optoelectronic devices ; Conference proceedings
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary In this work we demonstrate that efficient light emission at 1.54 μm can be achieved when Er ions are incorporated into crystalline Si or in heavily oxygen-doped amorphous and polycrystalline Si films (SIPOS). We have found that temperature quenching of photo- and electroluminescence, which is the major limitation towards the achievement of room temperature luminescence, can be strongly reduced by codoping these films with oxygen. This impurity is already present in as-prepared SIPOS and it is introduced by ion-implantation in crystalline Si. Er luminescence is obtained under both optical and electrical excitation and we demonstrate that excitation occurs through a carrier-mediated process. Electrical excitation is obtained by incorporating Er in properly designed device structures. It is found that this excitation can occur both through the recombination of hole-electron pairs and through impact excitation of the Er ions by hot electrons. These two mechanisms have different efficiencies and impact excitation is shown to prevail at room temperature. These data are presented and possible future developments are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 15 (1993), S. 399-414 
    ISSN: 0392-6737
    Keywords: Ions ; Ultraviolet and visible radiation (including laser beams) ; Solid phase epitaxy ; Liquid phase epitaxy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary The phase transition of amorphous to single-crystal silicon has been investigated not only by conventional heating in a furnace but under direct-energy processes like pulsed-laser and ion beam irradiation. The first method allows the experimental determination of the free-energy-temperature diagram for amorphous, liquid and crystalline silicon. Due to the very fast heating and cooling the amorphous-to-liquid transition can be investigated in both directions. Ion beam irradiation induces either a layer-by-layer amorphization or crystallization by the movement of the initial α-Si/c-Si interface according to the substrate temperature. The two processes are governed by different types of defects created by the beam in the amorphous and in the crystalline side of the interface. The existence of a native-oxide layer at the interface between single crystal and deposited layer retards the ion beam crystallization until oxygen atoms are dispersed by beam mixing in the matrix. A recent alternative way of crystallizing deposited layers is by short high-temperature anneals obtained by incoherent-light irradiations. In this case the rupture of the native-oxide layer is achieved by the agglomeration of oxide into beads, thus allowing the realignment. This technique appears to be particularly promising for several technological applications.
    Type of Medium: Electronic Resource
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