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  • 1
    Publication Date: 2019-07-20
    Description: Exploration of our Solar System has revealed a number of locations that are now habitable or could have supported life in the past. One approach to finding life involves detection of informational polymers like deoxyribonucleic acid (DNA) and ribonucleic acid (RNA) that are definitive biosignatures for life as we know it. Alternatively, structural variants of DNA and RNA, collectively termed xenonucleic acids (XNAs) have been shown in the laboratory to behave similarly. Nanopore-based sequencers differ from traditional sequencing technologies in that they do not explicitly require synthesis of DNA before or during analysis. Because of this, nanopore sequencers have been used for the direct sequencing of RNA, and could be used for the detection and analysis of other charged polymers. Here we describe results of exposing the MinION hardware, flow cells, and key reagents to ionizing radiation at doses relevant to Mars and Europa missions (10 to 3000 silicon-equivalent gray).
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-E-DAA-TN66686
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  • 2
    Publication Date: 2017-10-02
    Description: Using in-situ x-ray fluorescence, we determined the Cr/Fe, Mn/Fe and Ni/Fe of a particle captured in aerogel on MIR are approximately chondritic, indicating an extraterrestrial origin. Impurity of the aerogel precluded determining the Cu and Zn.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Lunar and Planetary Science XXXI; LPI-Contrib-1000
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  • 3
    Publication Date: 2018-06-11
    Description: The determination of oxidation conditions for basaltic magmas derived by the melting of planetary mantles is critical to our understanding of the nature and evolution of planetary interiors. Yet, these determinations are compromised in terrestrial and especially extraterrestrial basalts by our analytical and computational methods for estimating oxygen fugacity (fO2). For example, mineralogical barometers (1, 2) can be reduced in effectiveness by subsolidus re-equilibration of mineral assemblages, inversion of mineralogical data to melt characteristics, and deviations of the natural mineral compositions from ideal thermodynamic parameters.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Lunar and Planetary Science XXXV: Special Session: Oxygen in the Solar System, II; LPI-Contrib-1197
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  • 4
    Publication Date: 2018-06-12
    Description: This paper investigates the non-Boltzmann modeling of the radiating atomic and molecular electronic states present in lunar-return shock-layers. The Master Equation is derived for a general atom or molecule while accounting for a variety of excitation and de-excitation mechanisms. A new set of electronic-impact excitation rates is compiled for N, O, and N2+, which are the main radiating species for most lunar-return shock-layers. Based on these new rates, a novel approach of curve-fitting the non-Boltzmann populations of the radiating atomic and molecular states is developed. This new approach provides a simple and accurate method for calculating the atomic and molecular non-Boltzmann populations while avoiding the matrix inversion procedure required for the detailed solution of the Master Equation. The radiative flux values predicted by the present detailed non-Boltzmann model and the approximate curve-fitting approach are shown to agree within 5% for the Fire 1634 s case.
    Keywords: Lunar and Planetary Science and Exploration
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  • 5
    Publication Date: 2018-06-11
    Description: We have been developing an oxygen barometer based on the valence state of V (V(2+), V(3+), V(4+), and V(5+)) in solar system basaltic glasses. The V valence is determined by synchrotron micro x-ray absorption near edge structure (XANES), which uses x-ray absorption associated with core-electronic transitions (absorption edges) to reveal a pre-edge peak whose intensity is directly proportional to the valence state of an element. XANES has advantages over other techniques that determine elemental valence because measurements can be made non-destructively in air and in situ on conventional thin sections at a micrometer spatial resolution with elemental sensitivities of approx. 100 ppm. Recent results show that fO2 values derived from the V valence technique are consistent with fO2 estimates determined by other techniques for materials that crystallized above the IW buffer. The fO2's determined by V valence (IW-3.8 to IW-2) for the lunar pyroclastic glasses, however, are on the order of 1 to 2.8 log units below previous estimates. Furthermore, the calculated fO2's decrease with increasing TiO2 contents from the A17 VLT to the A17 Orange glasses. In order to investigate these results further, we have synthesized lunar green and orange glasses and examined them by XANES.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Workshop on Oxygen in the Terrestrial Planets; 35; LPI-Contrib-1203
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  • 6
    Publication Date: 2019-07-27
    Description: Iron redox systematics of the high FeO shergottitic liquids are poorly known, yet have a fundamental control on stability of phases such as magnetite, ilmenite, and pyroxenes.
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-CN-26749 , The Mantle of Mars Workshop; 10-12 Sept. 2012; Houston, TX; United States
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  • 7
    Publication Date: 2019-07-18
    Description: We measured minor element contents of carbonate from ALH84001 and report trends in the Ca, V, Mn and Sr in carbonate and the associated magnetite bands. Additional information is contained in the original extended abstract.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Lunar and Planetary Science XXXIII; LPI-Contrib-1109
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  • 8
    Publication Date: 2019-07-18
    Description: The Cl/Br ratios in fracture-filling materials in veins in Nakhla olivine was determined using x-ray microprobe (Br) and EDX (Cl) techniques. The Cl/Br ratio of 55 (standard deviation: 13) shows that the secondary altered material is pristine, extraterrestrial and akin to the Martian soil. Additional information is contained in the original extended abstract.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Lunar and Planetary Science XXXIII; LPI-Contrib-1109
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  • 9
    Publication Date: 2019-07-13
    Description: Large abundance of Martian atmospheric gases and neutron-induced isotopic excesses as well as Rb-Sr isotopic variations determined in some impact glasses in basaltic shergottites (e.g., Shergotty #DBS, Zagami #H1 and EET79001 #27, #8 and #104) provide definitive evidence for the occurrence of a Martian regolith component in their constituent mineral assemblages. Some of these glass-es, known as gas-rich impact-melts (GRIM), contain numerous micron-sized iron sulfide blebs along with minor amounts of iron sulfate particulates. As these GRIM glasses contain a Martian regolith component and as iron sulfates (but not sulfides) are found to occur abundantly on the Mars surface, we suggested that the sulfide blebs in GRIMs were likely generated by shock-reduction of the parental iron sulfate bearing regolith material that had been incorporated into the cavities/crevices of basaltic host rock prior to the impact event on Mars. To test whether the sulfates could be reduced to sulfides by impact shock, we carried out laboratory shock experiments on a basalt plus ferric sulfate mixture at 49 GPa at the Caltech Shock Wave Laboratory and at 21 GPa at Johnson Space Center (JSC) Experimental Impact Laboratory. The experimental details and the preliminary results for the Caltech 49 GPa experiment were presented at LPSC last year. Here, we report the results for the 21 GPa experiment at JSC and compare these results to obtain further insight into the mechanism of the bleb formation in the GRIM glasses.
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-CN-27859 , JSC-CN-27988 , Lunar and Planetary Science Conference; Mar 18, 2013 - Mar 22, 2013; The Woodlands, TX; United States
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  • 10
    Publication Date: 2019-07-13
    Description: Martian magmas are known to be FeO-rich and the dominant FeO-bearing mineral at many sites visited by the Mars Exploration rovers (MER) is magnetite [1]. Morris et al. [1] propose that the magnetite appears to be igneous in origin, rather than of secondary origin. However, magnetite is not typically found in experimental studies of martian magmatic rocks [2,3]. Magnetite stability in terrestrial magmas is well understood, as are the stability of FeO and Fe2O3 in terrestrial magmas [4,5]. In order to better understand the variation of FeO and Fe2O3, and the stability of magnetite (and other FeO-bearing phases) in martian magmas we have undertaken an experimental study with two emphases. First we document the stability of magnetite with temperature and fO2 in a shergottite bulk composition. Second, we determine the FeO and Fe2O3 contents of the same shergottite bulk composition at 1 bar and variable fO2 at 1250 C, and at variable pressure. These two goals will help define not only magnetite stability, but pyroxene-melt equilibria that are also dependent upon fO2.
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-CN-24912 , 34th Symposium on Antarctic Meteorites; Nov 17, 2011 - Nov 18, 2011; Tokyo; Japan
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