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  • Inorganic Chemistry  (7)
  • Lunar and Planetary Science and Exploration  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 399 (1973), S. 225-230 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A New Contribution to the Phosphazo ReactionThe reaction of acrylonitrile with phosphorus pentachloride gives ClCH2CCl2CCl2NPCl3 (I) and a hexachlorophosphate with the composition C3H2Cl14NP3 (II). For the first time the structure of (II) has been exactly determined by using 1H- and 31P-NMR-spectra. The course of reaction was studied in detail. 3-chloropropionitrile has been found as the product of a secondary reaction. The reaction of butyramide with PCl5 has also been investigated, and was found to be analogous.
    Notes: Bei der Umsetzung von Acrylnitril mit PCl5 entsteht neben ClCH2CCl2CCl2NPCl3 (I) auch das Hexachlorophosphat mit der Zusammensetzung C3H2Cl14NP3 (II). Die Struktur von (II) konnte durch 1H- und 31P-NMR-Untersuchungen erstmals eindeutig bestimmt werden. Der gesamte Reaktionsablauf wurde untersucht. Infolge einer Sekundärreaktion entsteht u. a. 3-Chlorpropionitril. Die Umsetzung von Butyramid mit PCl5 wird ebenfalls beschrieben. Sie zeigt einen analogen Verlauf.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 406 (1974), S. 214-220 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Investigations on Phosphazo Compounds from Anilines with Phosphorus PentachlorideThe reaction of anilines with PCl5 gives the monomer compound ArNPCl3. This will dimerize in many cases to (ArNPCl3)2. There are no indications for the former postulated intermediate product ArNHPCl4. We can correlate the tendency to dimerize with the basicity of the anilines. This is confirmed by the measurements of the constants of basicity in acetonitrile.
    Notes: Bei der Reaktion von Anilinen mit PCl5 entsteht die monomere Verbindung ArNPCl3. Diese dimerisiert in vielen Fällen zu (ArNPCl3)2. Für die früher postulierte Zwischenstufe ArNHPCl4 gibt es keine Hinweise. Die Neigung zur Dimerisation ist mit der Basizität der Aniline korrelierbar. Dies wird durch die Messung der Basenkonstanten in Acetonitril bestätigt.
    Additional Material: 2 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 479 (1981), S. 113-118 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structural Chemistry of Organotitanium Compounds: Structure of [(π-C5H5)2Ti(NO3)]2OCareful hydrolysis of (π-C5H5)2Ti(NO3)2 in tetrahydrofuran yields crystals of [(π-C5H5)2Ti(NO3)]2O (A). Crystal data of A: monoclinic, space group P21/c; lattice constants: a = 12.656(4), b = 10.181(5), c = 16.197(3) Å, ß = 93.57(3)º, Z = 4. As an X-ray analysis shows, the NO3 groups act as monodentate ligands with Ti—O distances of 2.085 and 2.059 Å. The ligands are arranged in a nearly tetrahedral way around the Ti atoms. The bond angle at the bridging O atom is 171.8º.
    Notes: Bei der vorsichtigen Hydrolyse von (π-C5H5)2Ti(NO3)2 in Tetrahydrofuran entsteht der Zweikernkomplex [(π-C5H5)2Ti(NO3)]2O (A) Kristalldaten von A: monoklin, Raumgruppe P21/c; Gitterkonstanten: a = 12,656(4), b = 10,181(5), c = 16,197(3) Å, ß = 93,57(3)º und Z = 4. Eine Röntgenstrukturanalyse ergibt, daß die Nitratgruppen als einzähnige Liganden mit Ti—O-Abständen von 2,085 und 2,059 Å fungieren. Die Ti-Atome weisen eine annähernd tetraedrische Koordination auf. Der Winkel am Brücken-O-Atom beträgt 171,8º.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 396 (1973), S. 261-266 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of Adipic Acid Diamide with Phosphorus PentachlorideThe reaction of adipamide (I) with phosphorus pentachloride in a solvent leads to (Cl3P=NCCl2CCl2CH2)2 (II). The stages of the reaction are: 1. chlorination of the keto and methylen groups 2. formation of the —N=PCl3 group.This result is a supplement of the existing conception about the course of the reaction of carboxylic acid amides with phosphorus pentachloride.The reaction of (I) with PCl5 without any solvent has been reproduced and the course of reaction has also been investigated. This reaction gives mainly NC(CH2)4CN.The resulting product of a careful hydrolysis of (II) is (Cl2OPN=CClCl2CH2)2. A total hydrolysis gives back (I).
    Notes: Bei der Umsetzung von Adipinsäurediamid (I) mit Phosphorpentachlorid in einem Verdünnungsmittel bildet sich (Cl3P=NCCl2CCl2CH2)2 (II). Der Reaktionsablauf ist: 1. Chlorierung der Keto- und Methylengruppen und 2. Bildung der —N=PCl3-Gruppierung. Dieses Ergebnis ist eine Ergänzung der bisherigen Vorstellungen über den Reaktionsablauf bei der Umsetzung von Säureamiden mit Phosphorpentachlorid.Die Reaktion von (I) mit PCl5 ohne Lösungsmittel wurde nachgearbeitet und ebenfalls in ihrem Ablauf untersucht. Hierbei entsteht vornehmlich NC(CH2)4CN.Bei vorsichtiger Hydrolyse von (II) erhält man (Cl2OPN=CClCCl2CH2)2. Totalhydrolyse führt zur Rückbildung von (I).
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 476 (1981), S. 62-68 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A Titanium (IV) Complex with Two Coordinatively Bonded Water Molecules: [(π-C5H5)2Ti(H2O)2](NO3)2(π-C5H5)2Ti(NO3)2 and H2O react in acetone to form the diaquo complex [(π-C5H5)2-Ti(H2O)2](NO3)2 (A). An X-ray analysis shows the titanium atom to be nearly tetrahedrally coordinated. Mean values of distances: Ti—O 2.01 Å, Ti—Z 2.03 Å (Z = center of ring); angles: O—Ti—O 92.7°, Z—Ti—Z 133.6°. Anions and cations are joined by hydrogen bonds to form strands that run in the direction of the crystallographic a axis. A crystallizes in the orthorhombic space group Pnma with Z = 4 and lattice parameters at - 100°C a = 7.601(2), b = 13.458(4) and c = 13.139(4) Å.
    Notes: (π-C5H5)2Ti(NO3)2 reagiert mit Wasser in Aceton unter Bildung des Diaquokomplexes [(π-C5H5)2Ti(H2O)2](NO3)2 (A). Eine Röntgenstrukturanalyse ergibt, daß das Ti-Atom eine annähernd tetraedrische Koordination besitzt. Mittelwerte der Abstände: Ti—O 2,01 Å, Ti—Z 2,03 Å (Z = Ringzentrum); Winkel: O—Ti—O 92, 7°, Z—Ti—Z 133,6°. Die Anionen und Kationen sind entlang der kristallographischen a-Achse durch Wasserstoffbrücken zu Strängen verknüpft. A kristallisiert in der orthorhombischen Raumgruppe Pnma mit Z = 4 und den Gitterkonstanten bei — 100°C a = 7,601(2), b = 13,458(4) und c = 13,139(4) Å.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 256 (1948), S. 239-252 
    ISSN: 0372-7874
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1Es werden die Zustandsdiagramme von: Aluminium/Indium, Gallium-Thallium, Gallium/Silicium, Gallium/Germanium, Indium/Silicium, Indium/Germanium, Thallium/Germanium bestimmt.2Die von Valentiner und Mitarbeitern bearbeiteten Zustandsdiagramme des Indiums mit Thallium, Zinn und Blei werden, zum Teil auf Grund neuer Versuche, erörtert.3Es wird das Verhalten der Elemente der III. Gruppe zueinander wie zu den Elementen der IV. Gruppe besprochen. Es ergibt sich, daß die Elemente der III. Gruppe sowohl in der Tendenz zur Verbindungsbildung als auch in der Neigung zur Mischbarkeit ein Minimum aller Gruppen darstellen.4Es wird eine einfache Heizkamera beschrieben.
    Additional Material: 11 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 58 (1925), S. 2740-2747 
    ISSN: 0365-9631
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 8
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    In:  Other Sources
    Publication Date: 2011-08-24
    Description: A major argument in the claim that life had been discovered during the Viking mission to Mars is that the results obtained in the Labeled Release (LR) experiment are analogous to those observed with terrestrial microorganisms. This assertion is critically examined and found to be implausible.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life (ISSN 0169-6149); Volume 29; 6; 625-31
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  • 9
    Publication Date: 2019-07-13
    Description: The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Planetary and space science (ISSN 0032-0633); 46; 7-Jun; 769-77
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  • 10
    Publication Date: 2019-08-14
    Description: The search for evidence of life on Mars is a highly interdisciplinary enterprise which extends beyond the traditional life sciences. Mars conceivably had a pervasive ancient biosphere which may have persisted even to the present, but only in subsurface environments. Understanding the history of Mars' global environment, including its inventory of volatile elements, is a crucial part of the search strategy. Those deposits (minerals, sediments, etc.) which could have and retained a record of earlier biological activity must be identified and examined. While the importance of. seeking another biosphere has not diminished during the years since the Viking mission, the strategy for Mars exploration certainly has been modified by later discoveries. The Viking mission itself demonstrated that the present day surface environment of Mars is hostile to life as we know it. Thus, to search effectively for life on Mars, be it extant or extinct, we now must greatly improve our understanding of Mars the planet. Such an understanding will help us broaden our search beyond the Viking lander sites, both back in time to earlier epochs and elsewhere to other sites and beneath the surface. Exobiology involves much more than simply a search for extant life beyond Earth. It addresses the prospect of long-extinct biospheres and also the chemistry, organic and otherwise, which either led to life or which occurred on rocky planets that remained lifeless. Even a Mars without a biosphere would reveal much about life. How better to understand the origin and impact of a biosphere than to compare Earth with another similar but lifeless planet? Still, several relatively recent discoveries offer encouragement that a Martian biosphere indeed might have existed. The ancient Martian surface was extensively sculptured by volcanism and the activity of liquid water. Such observations invoke impressions of an ancient martian atmosphere and environment that resembled ancient Earth more than present-day Mars. Since Viking, we have learned that our own biosphere began prior to 3.5 billion years ago, during an early period when our solar system apparently was sustaining clement conditions on at least two of its planets. Also, we have found that microorganisms can survive, even flourish, in environments more extreme in temperature and water availability than had been previously recognized. The common ancestor of life on Earth probably was adapted to elevated temperatures, raising the possibility that hydrothermal systems played a central role in sustaining our early biosphere. If a biosphere ever arose on Mars, at least some of its constituents probably dwelled in the subsurface. Even today, conditions on Mars and Earth become more similar with increasing depth beneath their surfaces. For example, under the martian permafrost, the geothermal gradient very likely maintains liquid water in environments which resemble aquifers on Earth. Indigenous bacteria have recently been recovered from deep aquifers on Earth. Liquid groundwater very likely persisted throughout Mars' history. Thus, martian biota, if they ever existed, indeed might have survived in subsurface environments.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Lunar and Planetary Science Conference; Mar 13, 1995 - Mar 17, 1995; Houston, TX; United States
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