ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • INORGANIC AND PHYSICAL CHEMISTRY  (23)
  • FLUID MECHANICS AND HEAT TRANSFER  (3)
  • 1
    facet.materialart.
    Unknown
    Deposition of Na2SO4 from salt-seeded combustion gases of a high velocity burner rig (1985)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: With a view to developing simulation criteria for the laboratory testing of high-temperature materials for gas turbine engines, the deposition rates of sodium sulfate from sodium salt-seeded combustion gases were determined experimentally using a well instrumented high-velocity burner. In the experiments, Na2SO4, NaCl, NaNO3, and simulated sea salt solutions were injected into the combustor of the Mach 0.3 burner rig operating at constant fuel/air ratios. The deposits formed on an inert rotating collector were then weighed and analyzed. The experimental results are compared to Rosner's vapor diffusion theory. Some additional test results, including droplet size distribution of an atomized salt spray, are used in interpreting the deposition rate data.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 2
    facet.materialart.
    Unknown
    Reactions of NaCl with gaseous SO3, SO2, and O2 (1984)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Hot corrosion of gas turbine engine components involves deposits of Na2SO4 which are produced by reactions between NaCl and oxides of sulfur. For the present investigation, NaCl single crystals were exposed at 100 to 850 C to gaseous mixtures of SO3, SO2, and O2. The products formed during this exposure depend, primarily, on the temperatures. The four product films were: NaCl-SO3; Na2S2O7; Na2SO4; and NaCl-Na2SO4. The kinetics of the reactions were measured.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Electrochemical Society, Journal (ISSN 0013-4651); 131; 2414-241
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 3
    facet.materialart.
    Unknown
    Investigation of the formation of gaseous sodium sulfate in a doped methane-oxygen flame (1977)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: Na2SO4(g) formation was measured at atmospheric pressure in CH4-O2 flames, with high pressure, free-jet expansion, mass spectrometric sampling used to identify and measure reaction products. Measured composition profiles of reaction products for a doped 9.5 mole ratio O2/CH4 flame are presented. Weight percentages of reactants were 4.7 CH4, 89.0 O2, 3.5 H2O, 2.0 SO2 and 0.35 NaCl.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Electrochemical Society; vol. 124
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 4
    facet.materialart.
    Unknown
    Experimental and theoretical deposition rates from salt-seeded combustion gases of a Mach 0.3 burner rig (1984)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Deposition rates on platinum-rhodium cylindrical collectors rotating in the cross streams of the combustion gases of a salt-seeded Mach 0.3 burner rig were determined. The collectors were internally air cooled so that their surface temperatures could be widely varied while they were exposed to constant combustion gas temperatures. The deposition rates were compared with those predicted by the chemically frozen boundary layer (CFBL) computer program, which is based on multicomponent vapor transport through the boundary layer. Excellent agreement was obtained between theory and experiment for the NaCl-seeded case, but the agreement lessened as the seed was changed to synthetic sea salt, NaNO3, and K2SO4, respectively, and was particularly poor in the case of Na2SO4. However, when inertial impaction was assumed to be the deposition mechanism for the Na2SO4 case, the predicted rates agreed well with the experimental rates. The former were calculated from a mean particle diameter that was derived from the measured intial droplet size distribution of the solution spray. Critical experiments showed that liquid phase deposits were blown off the smooth surface of the platinum-rhodium collectors by the aerodynamic shear forces of the high-velocity combustion gases but that rough or porous surfaces retained their liquid deposits.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: NASA-TP-2225 , E-1752 , NAS 1.60:2225
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 5
    facet.materialart.
    Unknown
    Combustion of solid carbon rods in zero and normal gravity (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: In order to investigate the mechanism of carbon combustion, normal and zero gravity experiments were conducted in which spectroscopic carbon rods were resistance ignited and burned in an oxygen environment. Direct mass spectrometric sampling was used in the normal gravity tests to measure gas phase concentrations. The gas sampling probe was positioned near the circumference of the horizontally mounted carbon rods, either at the top or at angles of 45 or 90 deg from the top, and yielded concentration profiles of CO2, CO, and O2 as a function of distance from the carbon surface. The experimental concentrations were compared to those predicted by a stagnant film model. Zero gravity droptower tests were conducted in order to assess the effect of convection on the normal gravity combustion process. The ratio of flame diameter to rod diameter as a function of time for oxygen pressures of 5, 10, 15, and 20 psia was obtained for three different diameter rods. It was found that this ratio was inversely proportional to both the oxygen pressure and the rod diameter.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Annual Meeting; Nov 25, 1979 - Nov 29, 1979; San Francisco, CA
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 6
    facet.materialart.
    Unknown
    Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous Na2SO4 or K2SO4 molecules were formed in residence times on the order of 1 msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Symposium on High Temperature Metal Halide Chemistry; Oct 09, 1977 - Oct 14, 1977; Atlanta, GA
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 7
    facet.materialart.
    Unknown
    Interaction of NaCl/g/ and HCl/g/ with condensed Na2SO4 (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: Na2SO4(l)-NaCl(g) interactions were studied at a total pressure of one atmosphere of air or oxygen for various temperatures of Na2SO4(l) and for various partial pressures of NaCl(g) and H2O(g). Mass spectrometric sampling techniques were used to identify and monitor gas phase species. Continuous recording thermomicrogravimetric measurements were conducted to determine condensed phase weight change rates. Experimental measurements were supplemented with thermodynamic calculations. Numerous experiments were performed at sample temperatures of 900 and 1000 C with 300 ppm NaCl(g). In these experiments, the reproducibility of the Na2SO4 vaporization weight loss rate and initial weight gain upon addition of NaCl(g) were found to be satisfactory. It was found that the addition of NaCl(g) to air flowing over Na2SO4(l) at 900 and 1000 C enhances the rate of weight loss of the Na2SO4(l). This enhancement increases when H2O(g) is also added to the air flow.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Symposium on High Temperature Metal Halide Chemistry; Oct 09, 1977 - Oct 14, 1977; Atlanta, GA
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 8
    facet.materialart.
    Unknown
    Volatile products from the interaction of KCl/g/ with Cr2O3 and LaCrO3 in oxidizing environments (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: Based on cooled target collection methods and high pressure mass spectrometer sampling, oxidative vaporization rates and emanating volatile products were evaluated for interactions of KCl(g) with Cr2O3 and LaCrO3 in oxidizing environments. It was found that: (1) increased rates of oxidative vaporization upon exposure to the reactants are exhibited by chromia and fresh lanthanum chromite samples, and (2) these increased rates result from the heterogeneous formation of complex molecules such as KCl sub 1,2,3CrO3 and KOH sub 1,2CrO3. No increased rates were observed for lanthanum chromite subjected to prolonged oxidative vaporization.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Symposium on High Temperature Metal Halide Chemistry; Oct 09, 1977 - Oct 14, 1977; Atlanta, GA
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 9
    facet.materialart.
    Unknown
    Volatile products from the interaction of KCl(g) with Cr2O3 and LaCrO3 in oxidizing environments (1977)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: Cooled target collection techniques and high pressure mass spectrometric sampling were used to measure the relative rates of oxidative vaporization and to identify the volatile products emanating from samples of chromia and Mg-doped lanthanum chromite. The materials were exposed to partial pressures of KCl with and without H2O in one atmosphere of slowly flowing oxygen at elevated temperatures. Chromia and fresh samples of lanthanum chromite exhibited enhanced rates of oxidative vaporization upon exposure to these reactants. Mass spectrometric identification showed that the enhancements resulted from the heterogeneous formation of complex molecules of the type KCl sub 1,2,3 CrO3 and KOH sub l,2 CrO3. Lanthanum chromite that had undergone prolonged oxidative vaporization exhibited no enhanced oxidation upon exposure to the reactants.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: NASA-TM-73795 , Symp. on High Temp. Metal Halide Chem.; Oct 09, 1977 - Oct 14, 1977; Atlanta
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 10
    facet.materialart.
    Unknown
    Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates (1977)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous NA2SO4 or K2S04 molecules were formed in residence times on the order of msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: NASA-TM-73794 , Symp. on High Temp. Metal Halide Chem.; Oct 09, 1977 - Oct 14, 1977; Atlanta
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...