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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 15 (1981), S. 251-276 
    ISSN: 1573-4889
    Keywords: oxide dispersion strengthening ; oxidation ; hot corrosion ; powder metallurgy ; porosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Cyclic hot corrosion and oxidation testing of an experimental oxide dispersion strengthened (ODS) superalloy MA-755E were conducted in a hot gas stream at Mach 0.3. The response of the ODS alloy, bare or with protective coatings, was similar to that of a conventional cast alloy, IN-792, in hot corrosion at 900°C. However, during oxidation at 1100 and 1150°C the ODS alloy differed from the cast alloy by developing a greater amount of subsurface porosity. Compared with a diffused aluminide coating, an electron beam vapor deposited NiCrAlY coating offered superior oxidation protection and decreased porosity formation. In additional testing, the tendency to form porosity was associated with the large grains of recrystallized powder metallurgy alloys but was independent of the presence of an oxide dispersion.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2011-08-19
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: ASME, Transactions, Journal of Heat Transfer (ISSN 0022-1481); 110; 449-455
    Format: text
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  • 3
    Publication Date: 2011-08-19
    Description: With a view to developing simulation criteria for the laboratory testing of high-temperature materials for gas turbine engines, the deposition rates of sodium sulfate from sodium salt-seeded combustion gases were determined experimentally using a well instrumented high-velocity burner. In the experiments, Na2SO4, NaCl, NaNO3, and simulated sea salt solutions were injected into the combustor of the Mach 0.3 burner rig operating at constant fuel/air ratios. The deposits formed on an inert rotating collector were then weighed and analyzed. The experimental results are compared to Rosner's vapor diffusion theory. Some additional test results, including droplet size distribution of an atomized salt spray, are used in interpreting the deposition rate data.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Format: text
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  • 4
    Publication Date: 2011-08-17
    Description: Cyclic oxidation and hot corrosion tests of two cobalt-base and two nickel-base alloys are reported. The alloys were exposed to maximum temperatures of 900 and 1000 C in a Mach 0.3 burner rig whose flame was doped with various concentrations of sea salt and sodium sulfate for hot corrosion tests. The test data were subjected to a regression analysis for the development of model equations relating corrosion to temperature and for the effects of salt concentration and composition on corrosion. The corrosion resistance varied with temperature, sea salt concentration, and salt composition, concluding that the S-57 cobalt-base alloy was the most hot corrosion-resistant alloy, and the TD-NiCrAl nickel-base alloy was the least resistant. However, under straight oxidation conditions, the TD-NiCrAl was most resistant, while S-57 was the least resistant alloy.
    Keywords: METALLIC MATERIALS
    Type: Oxidation of Metals; 13; Oct. 197
    Format: text
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  • 5
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2011-08-17
    Description: A cobalt-base alloy, Co-25Cr-10Ni-5Ta-3Al-0.5Y (S-57), was subjected to hot corrosion in Mach 0.3 burner-rig combustion gases at maximum alloy temperatures of 900 and 1000 C. Various salt concentrations were injected into the burner: 0.5, 2,5, and 10 parts per million synthetic sea salt and 4 parts per million sodium sulfate (Na2SO4). The extent of corrosion was determined by measuring the maximum depth of corrosion in the alloy, and the corrosion process was studied by metallography, X-ray diffraction, scanning electron microscopy, and electron microprobe analysis. While S-57 was found to possess only moderate oxidation resistance at these temperatures, this alloy resisted significant hot corrosion attack under all but the most severe test conditions. The process of hot corrosion attack under the most severe conditions of this study was primarily sulfidation.
    Keywords: METALLIC MATERIALS
    Type: Corrosion Science; 18; 1978
    Format: text
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  • 6
    Publication Date: 2011-08-18
    Description: Cyclic hot corrosion and oxidation of an experimental oxide dispersion strengthened (ODS) superalloy MA-755E were conducted in a hot gas stream at Mach 0.3. The response of the ODS alloy, bare or with protective coatings, was similar to that of a conventional cast alloy, IN-792, in hot corrosion at 900 C. However, during oxidation at 1100 and 1150 C the ODS alloy differed from the cast alloy by developing a greater amount of subsurface porosity. Compared with a diffused aluminide coating, an electron beam vapor deposited NiCrAlY coating offered superior oxidation protection and decreased porosity formation. In additional testing, the tendency to form porosity was associated with the large grains of recrystallized powder metallurgy alloys but was independent of the presence of an oxide dispersion.
    Keywords: METALLIC MATERIALS
    Type: Oxidation of Metals; 15; Apr. 198
    Format: text
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  • 7
    Publication Date: 2011-08-19
    Description: The application of a recently formulated vapor transport theory to predict deposition rates of corrosive salts from alkali-seeded combustion gases of a small-capacity, high-velocity, atmospheric-pressure burner rig was hampered by the relatively large dimensions of the cylindrical deposit collector compared to the diameter of the combustion gas stream. The relative dimensions lead to a highly nonadiabatic combustion gas flow around the collector and necessitate two series of experiments. In the first series, mass transfer coefficients are determined by utilizing the naphthalene sublimation technique. The second series of experiments determines the dilution effect on the sodium species concentrations due to the entrainment of ambient air. This second series involves the measurement of the temperature variation along the surface of the collector under steady state conditions. Vapor deposition rates are determined exploiting this information and the results are found to compare favorably with experimentally obtained rates.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: ASME, Transactions, Journal of Heat Transfer (ISSN 0022-1481); 110; 442-448
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  • 8
    Publication Date: 2019-06-28
    Description: Two sets of experiments have been performed to be able to predict the convective diffusion heat/mass transfer rates to a cylindrical target whose height and diameter are comparable to, but less than, the diameter of the circular cross-stream jet, thereby simulating the same geometric configuration as a typical burner rig test specimen located in the cross-stream of the combustor exit nozzlle. The first set exploits the naphthalene sublimation technique to detetermine the heat/mass transfer coefficient under isothermal conditions for various flow rates (Reynolds numbers). The second set, conducted at various combustion temperatures and Reynolds numbers, utilized the temperature variation along the surface of the above-mentioned target under steady-state conditions to estimate the effect of cooling (dilution) due to the entrainment of stagnant room temperature air. The experimental information obtained is used to predict high temperature, high velocity corrosive salt vapor deposition rates in burner rigs on collectors that are geometrically the same. The agreement with preliminary data obtained from Na2S04 vapor deposition experiments is found to be excellent.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: ASME PAPER 86-GT-68
    Format: text
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  • 9
    Publication Date: 2019-05-29
    Description: Hall coefficient of tantalum carbide as function of carbon content
    Keywords: PHYSICS, SOLID-STATE
    Type: NASA-TN-D-3135
    Format: application/pdf
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  • 10
    Publication Date: 2019-06-28
    Description: Deposition rates on platinum-rhodium cylindrical collectors rotating in the cross streams of the combustion gases of a salt-seeded Mach 0.3 burner rig were determined. The collectors were internally air cooled so that their surface temperatures could be widely varied while they were exposed to constant combustion gas temperatures. The deposition rates were compared with those predicted by the chemically frozen boundary layer (CFBL) computer program, which is based on multicomponent vapor transport through the boundary layer. Excellent agreement was obtained between theory and experiment for the NaCl-seeded case, but the agreement lessened as the seed was changed to synthetic sea salt, NaNO3, and K2SO4, respectively, and was particularly poor in the case of Na2SO4. However, when inertial impaction was assumed to be the deposition mechanism for the Na2SO4 case, the predicted rates agreed well with the experimental rates. The former were calculated from a mean particle diameter that was derived from the measured intial droplet size distribution of the solution spray. Critical experiments showed that liquid phase deposits were blown off the smooth surface of the platinum-rhodium collectors by the aerodynamic shear forces of the high-velocity combustion gases but that rough or porous surfaces retained their liquid deposits.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: NASA-TP-2225 , E-1752 , NAS 1.60:2225
    Format: application/pdf
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