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  • Grain size  (1)
  • Methane  (1)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 267 (2008): 341-352, doi:10.1016/j.epsl.2007.11.053.
    Description: Detailed near-bottom investigation of a series of giant, kilometer scale, elongate pockmarks along the edge of the mid-Atlantic continental shelf confirms that methane is actively venting at the site. Dissolved methane concentrations, which were measured with a commercially available methane sensor (METS) designed by Franatech GmbH mounted on an autonomous underwater vehicle (AUV), are as high as 100 nM. These values are well above expected background levels (1-4 nM) for the open ocean. Sediment pore water geochemistry gives further evidence of methane advection through the seafloor. Isotopically light carbon in the dissolved methane samples indicates a primarily biogenic source. The spatial distribution of the near-bottom methane anomalies (concentrations above open ocean background), combined with water column salinity and temperature vertical profiles, indicate that methane-rich water is not present across the entire width of the pockmarks, but is laterally restricted to their edges. We suggest that venting is primarily along the top of the pockmark walls with some advection and dispersion due to local currents. The highest methane concentrations observed with the METS sensor occur at a small, circular pockmark at the southern end of the study area. This observation is compatible with a scenario where the larger, elongate pockmarks evolve through coalescing smaller pockmarks.
    Description: This work was supported by NSF grants OCE- 0242426, OCE-0242804 and OCDE-0242449 and ONR grant N00014-02-1-0691.
    Keywords: Pockmarks ; Seafloor venting ; Methane ; AUV
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 58A (2014): 99-116, doi:10.1016/j.marpetgeo.2014.04.009.
    Description: In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.
    Description: The financial support for the NGHP01, from the Oil Industry Development Board, Oil and Natural Gas Corporation Ltd., GAIL (India) Ltd. and Oil India Ltd. is gratefully acknowledged. We also acknowledge the support extended by all the participating organizations of the NGHP: MoP&NG, DGH, ONGC, GAIL, OIL, NIO, NIOT, and RIL.
    Keywords: Porosity ; Permeability ; Grain size ; Indian Ocean ; Gas hydrate ; Saturation ; Volcanic ash ; Carbonate
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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