ALBERT

Description: GOME radiance, irradiance, and ozone products were validated by NASA Goddard Space Flight Center through three tasks which included, pre-launch calibration comparisons with SBUV and TOMS radiometric standards, validation of GOME Level-1 irradiance and radiance and Level 2 total ozone data products using SBUV/2 and TOMS algorithms and data, and studies of GOME data using the Goddard radiative transfer code. The prelaunch calibration using the NASA large aperture integrating sphere was checked against that provided by TPD. Agreement in the calibration constants, derived in air, between the Goddard and TPD system were better than 3%. Validation of Level-1 irradiance data included comparison of GOME and SSBUV and the UARS solar irradiances measurements. Large wavelength dependent differences, as high as 10%, were noted between GOME and the US instruments. This discrepancy has now been attributed to radiometric sensitivity changes experienced by GOME when operating in a vacuum. GOME Earth radiance data were then compared to the NOAA-14 SBUV/2 radiances. These results show that between 340 and 400 nm the differences in GOME and SBUV/2 data are less than 5% with some wavelength dependence. At wavelengths shorter than 300 nm, differences are of the order of 10% or more where the GOME radiances are larger. To test GOME DOAS retrieved total ozone values, these values were compared with ozone amounts retrieved using GOME radiances in the TOMS version-7 algorithm. The differences showed a solar zenith angle dependence ranging from 0 to 10% where the TOMS algorithm values were higher. GOME radiances below 300 nm were further validated by selecting radiances at wavelengths normally used by SBUV and processing them through the SBUV ozone profile algorithm and then compared to climatological values. The GOME ozone profiles ranged from 10-30% lower over altitude compared to climatological values. This is consistent with the offsets detected in the SBUV/2 radiance comparisons at wavelengths shorter than 300 nm.

Description: Instruments such as the Global Ozone Monitoring Experiment (GOME, on the European Remote Sensing Satellite (ERS-2), launched 1995), the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY, on ENVISAT, to be launched July 2001) and the Ozone Monitoring Instrument (OMI on EOS Aura, to be launched 2003) make measurements of the total column of NO2. There is interest in separating the stratospheric and tropospheric contributions to the column, as the tropospheric column provides a measure of pollution. We are using a 3D chemistry and transport model driven by winds from the Goddard Space Flight Center Data Assimilation System to examine variability in the stratospheric NO2 column. Model results for NOx = NO + NO2 + 2N2O5 will be shown to compare well with sunset observations from the Halogen Occultation Experiment on the Upper Atmosphere Research Satellite, and to exhibit similar temporal and spatial dependence. Partitioning between NO, NO2, and N2O5 is also shown to compare well with observations. This good agreement supports the use of simulated fields in the stratosphere to derive the tropospheric column from the total column. Preliminary comparisons of the tropospheric column with model simulations for the troposphere will also be shown.

Description: Measuring tropospheric chemical constituents from space has been only of the "Holy Grails" of remote sensing. Tropospheric remote sensing has been done in two phases, extracting troposheric constituent information from satellite instruments designed for other purposes and constituent measurements with instruments optimized for tropospheric detection. Examples from the first phase, tropospheric ozone and aerosols from Total Ozone Mapping Spectrometer (TOMS) and Global Ozone Monitoring Experiment (GOME) will be presented. Expected results from upcoming instruments and missions, Atmospheric Ultraviolet Radiance Analyzer (AURA), Ozone Monitoring Instrument (OMI), GOME2, and Scanning Imaging Spectrometer for Atmospheric Chartography (SCIAMACHY) will be presented.

Description: Satellite instruments flown since 1970 have had great success in elucidating the processes that control stratospheric ozone. In contrast, space-based data for tropospheric constituents that affect air quality and climate have only recently become available. While these datasets highlight the rapidly advancing capabilities of spacebased tropospheric sensors, they are also pointing to the limitations of sun-synchronous, low-earth orbiting (SSO/LEO) satellite platforms for making such measurements. In our talk we will highlight the science requirements for new missions and the technological and algorithmic approaches that we are developing to meet these requirements. From these studies a clear need for advanced atmospheric composition sensors has emerged that can be put on geostationary (GEO) platforms to provide 5 km horizontal resolution with 15-60 minutes repeat cycle. Such measurements have been high priority in the recently released Decadal Survey report by the US National Research Council. The need for GEO is driven not only by the science requirements to track rapidly changing pollution events but also by the need to provide altitude-resolved information about tropospheric constituents. Currently, with the exception of aerosols, it is not possible to derive profile information about lower tropospheric constituents from satellite measurements. New algorithmic approaches are being developed to obtain this information by combining UV and IR data, by monitoring the spatial and temporal structures of the constituents, and by using low-level clouds to separate boundary layer constituents from free troposphere. All these approaches require better spatial and temporal resolution than that provided by LEO sensors.

Description: The Ozone Monitoring Instrument has gathered daily global data on NO2 and other atmospheric trace gases since its launch on the EOS Aura satellite in 2004. The large accumulated data set makes it possible to monitor changes of both meteorological and anthropogenic origin in tropospheric NOz amounts. In particular, averages on time scales on the order of a year show a distinct 'weekend effect' in NO2 variation, with smaller NO2 amounts seen on Saturday and/or Sunday than on the remaining weekdays. Using the OMI NO2 Standard Product (SP), we examine this effect in relation to geopolitical boundaries and investigate implications for identifying sources. We also use the SP data to find evidence for other short-term anthropogenic changes in NO2 emissions over heavily polluted regions including the United States, Europe and China.