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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 760-765 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of carbon dioxide absorption by 0.01, 0.05, and 0.1 molar sodium hydroxide solutions were measured at 25°C. for exposure times from 1.4 to 21.6 milliseconds with a laminar-jet technique. Absorption rates were calculated with a model based on one-dimensional diffusion occurring simultaneously with two consecutive irreversible chemical reactions. The resulting partial differential equations were solved with an IBM-709 computer. The calculated absorption rates agreed within 5% of the experimental values.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 211-221 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion and cracking-corrosion of prestressing steelsSummarizing report about extent and causes of damages of prestressing steels caused by hydrogen cracking-corrosion. Fundamental research of cracking-corrosion of prestressing steel. Results of cracking-corrosion tests with stressed materials in not pure water, in such moistened sand and of water condensating tests. Hereby consideration of contents of chlorides and sulfates as existing in unfilled tubes; partly little addition of the hydrogen-promotor rhodanide.Result that under practical conditions prestressing steels prefer hydrogen induced cracking-corrosion while hereby especially oxygen-poor electrolytes and local corrosion attacks (pitting scars) tend to this hydrogen reception and therefore to failure. These effects are for example often caused by the conditions of crevice-corrosion and by contact with moistened mineral phases (sands). Such is resulting that sensitive prestressing steels are exposed to the danger of failure already before being embedded with mortar.
    Notes: Zusammenfassende Darstellung über Umfang und Ursache von Schadensfällen infolge Wasserstoffrißkorrosion bei Spannstählen. Grundlagen der Rißkorrosion bei Spannstählen. Ergebnisse von Spannungsrißkorrosionsversuchen in verdünnten, wäßrigen Lösungen, in mit verdünnten Lösungen getränktem Sand und unter Schwitzwasserbeanspruchung. Dabei Berücksichtigung praxisnaher Chlorid- und Sulfatgehalte entsprechend dem Hüllrohrwasser; zum Teil Zugabe des Wasserstoffpromotors Rhodanid in geringen Konzentrationen.Feststellung, daß unter praxiskonformen Bedingungen Spannstähle am ehesten einer Wasserstoffrißkorrosion unterliegen, wobei insbesondere sauerstoffverarmte Elektrolyte und örtliche Korrosionsangriffe (Lochfraßnarben) eine Wasserstoffaufnahme und Bruchbildung fördern. Diesbezüglich wirken z. B. Spaltkorrosionseffekte, wie auch Kontakte mit lösungsgetränkten mineralischen Bestandteilen (Sand). Aufgrund der Ergebnisse muß davon ausgegangen werden, daß empfindliche Spannstähle bereits im Zeitraum der Verarbeitung hinsichtlich Wasserstoffrißkorrosion gefährdet sind.
    Additional Material: 17 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 672-674 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 46 (1995), S. 579-587 
    ISSN: 0006-3592
    Keywords: hybridoma cells ; process control ; energy metabolism ; on-line nutrient feeding ; fed-batch culture ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A hybridoma cell line was cultivated in fed-batch cultures using a low-protein, serum-free medium. On-line oxygen uptake rate (OUR) measurement was used to adjust the nutrient feeding rate based on glucose consumption, which was estimated on-line using the stoichiometric relations between glucose and oxygen consumption. Through on-line control of the nutrient feeding rate, not only sufficients were supplied for cell growth and antibody production, but also the concentrations of glucose and other important nutrients such as amino acids were maintained at low levels during the cell growth phase. During the cultivation, cell metabolism changed from high lactate production and low oxygen consumption to low lactate production and high oxygen consumption. As a result the accumulation of lactate was reduced and the growth phase was extended. In comparison with the batch cultures, in which cells reached a concentration of approximately 2 × 106 cells/mL, a very high concentration of 1.36 × 107 cells/mL with a high cell viability (〉90%) was achieved in the fed-batch culture. By considering the consumption of glucose and amino acids, as well as the production of cell mass, metabolites, and antibodies, a well-closed material balance was established. Our results demonstrate the value of coupling on-line OUR measurement and the stoichiometric realations for dynamic nutrient feeding in high cell concentration fed batch cultures. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 237 (1938), S. 79-88 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 237 (1938), S. 89-100 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 227 (1936), S. 237-248 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das dreiwertige Ruthenium bildet stark komplexe Ammine mit der Koordinationszahl 6.
    Additional Material: 5 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 235 (1938), S. 352-362 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Aus dem Verhältnis Ru(NH3)5CI3 : Ru ergibt sich als Mittel von 11 Einzelbestimmungen für das Atomgewicht des Rutheniums der Wert: Ru = 101,08 ± 0,05. Als Tabellenwert für die praktische Verwendung wird vorgeschlagen: Ru = 101,1 statt bisher Ru = 101,7.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 235 (1938), S. 201-210 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Durch Einwirkung von Natrium-bisulfit auf Salze der Pentammino-Reihe des dreiwertigen Rutheniums entstehen die Verbindungen: [RuII(NH3)4(SO3H)2] farblose derbe Kristalle, fast unlöslich, und Na4[RuII(NH3)4(SO3)2(SO3H)2] · 6H2O kleine weiße schwer lösliche Kristalle. 4 Mol. Kristall-H2O sind sehr locker gebunden, die beiden restlichen H2O entweichen bei 110°.
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