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  • Chemical Engineering  (363)
  • 1965-1969  (200)
  • 1960-1964  (163)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 663-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In predicting interfacial area in liquid-liquid systems there are several published reports which give different results. Differences in methods of measurement of interfacial area and impeller design and location account for some of these discrepancies.For one pair of liquids, 40 parts by volume of ethylhexanol and 60 parts water, it was found that over wide ranges of impeller size to tank size ratio (0.27 to 0.67) that equal power per unit volume gave equal interfacial area per unit volume.
    Additional Material: 5 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 708-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 681-688 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 606-608 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 797-800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The captured vortex system produced by the flow of a fluid along a plate containing a transverse rectangular cavity was investigated by measuring the local mass transfer coefficient kg on the cavity walls. Both transverse and peripheral kg profiles are presented for cavity depth-to-length ratios of 0.5, 1.0, and 2.0 at free-stream velocities of 6.8, 13.5, and 27 ft./sec. for water evaporating into air. These profiles reflect the three-dimensional nature of the flow in the cavity.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 100-105 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A region into which particles arrive in a random manner, remain a random amount of time, and then leave is considered. This model is used in penetration theories of heat and mass transfer. From observations of the number of particles present at any time, it is desired to estimate arrival and exit statistics, residence time statistics, and average rates of transfer across the region. Assuming arrival is a Poisson process, equations governing the above statistics are derived. Some problems in spectral analysis arising from the use of nondifferentiable stochastic processes are solved. Estimators for important parameters are discussed, and it is shown that generally they are biased. A derivation linking the rate of transfer across the region with the rates of transfer of particles is obtained and compared with other such results.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 551-558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of design and operational variables on the performance of one type of hydrogen-oxygen ion exchange membrane fuel cell has been studied. Only the results of cells based on a phenolsulfonic acid formaldehyde type of ion exchange membrane containing one type of reinforcement are described. Platinum, palladium, iridium, and rhodium are adequate electrode materials for room-temperature operation. Performance of cells with platinum gauze current collectors bonded to the cell surfaces was only slightly better than that with external contacts about 1 cm. apart.Open circuit voltages range from 0.9 to 1.1 v. (theoretical 1.23) depending on the catalyst. The typical current at 0.5 v. is 30 ma./sq. cm. Better cells have delivered 80 ma./sq. cm. at 0.5 v. Life tests indicate that these cells can be expected to deliver a minimum of about 40 amp.-hr./sq. cm., when operated in the load range 8.5 to 230 ohm sq. cm., before failure of the electrolyte owing to pinhole formation. Current efficiency is very nearly 100%. Cell performance vs. temperature in the range 0° to 85°C. shows a maximum at about 55°C.
    Additional Material: 24 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 418-420 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 659-662 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer rates and flooding limits are basic to the use of packed columns for liquid-liquid extraction. The input of pulsing energy increases transfer rates and promotes counterflow of the two phases. The wetting characteristics of the packing influence performance.The toluene-benzoic acid-water system was used to observe the performance of a 2-in. diam. column containing ceramic (hydrophilic) rings, polyethylene (hydrophobic) rings, or a sieve-plate cartridge. The packed columns showed lower flooding limits than the plate column, but polyethylene packing gave highest transfer rates and capacities. The pulsing energy input was much lower for the plastic packing to effect a higher transfer rate.Flooding limits for the pulsed, packed columns were lower than for packed columns which were not pulsed. Columns packed with rings so that the ratio of diameter to packing size was 4:1 gave higher flooding limits and better performance than a ratio of 8:1. The use of the two types of packing in alternating bands resulted in a performance intermediate between that of each packing employed separately, and no advantage was indicated in reference to flooding limits or transfer rates.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 268-273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The motion of individual air bubbles in a water stream flowing turbulently in a 4 in. × 4 in. vertical conduit is investigated by photographic means. The bulk water velocity ranges from 40.8 to 267 cm./sec., corresponding to a system Reynolds number range of 48,600 to 386,000. Both tap and demineralized water were used at or near room temperatures. Air bubbles range from 0.038 to 0.70 cm. in equivalent radius and the corresponding bubble Reynolds number based on relative velocity ranges from 58 to 4,500.The results indicated that the bubble relative velocity in a turbulent water stream is similar to the rise velocity of single bubbles through a quiescent liquid. It was found to be practically independent of the system Reynolds number for bubbles having an equivalent radius above 0.3 cm. Large fluctuations in the bubble velocities were noted in all cases. The drag coefficient is, in general, lower for the demineralized water tests than for tap water when the bubble Reynolds number is below 2,000. Above this value, a mergence of the drag coefficients for all tests occur with a peak of approximately 2.0 at a bubble Reynolds number of 3,000, which is lower than the nonflow value of 2.6.
    Additional Material: 9 Ill.
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