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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 31 (1992), S. 641-643 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 4 (1975), S. 33-64 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This review briefly illustrates the state of the art in the recognition of the various sources and natural sinks of gaseous pollutants. The removal mechanisms include absorption by vegetation, soil, stone, and water bodies, precipitation scavenging, and chemical reactions within the atmosphere. The nature and magnitude of anthropogenic and natural emissions of the gases (H2S, SO2, N2O, NO, NO2, NH3, CO, O3, and hydrocarbons), along with their ambient background concentrations and information on their major sinks identified to date, are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 6 (1976), S. 71-95 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Although considerable effort has been devoted to the development of air pollution models, little has been done to incorporate natural mechanisms capable of removing pollutants from the atmosphere. One important process is the uptake of atmospheric pollutants by water bodies. In this paper, a calculational scheme to quantify this transport process is presented. In particular, two models characterizing wind induced turbulence in a water body are invoked to estimate the liquid phase mass transfer coefficient. A priori specification of parameters yielded predictions well within an order of magnitude of experimental evidence in both the laboratory and the field.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 606-608 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 606-611 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of vapor-phase equilibrium in the reaction system acetic acid-ethanol-ethyl acetate-water has been made including an evaluation of past investigations, a calculation of equilibrium constants from thermal data, and new experimental determinations utilizing gas chromatography in a novel method. It was found that the magnitude of the thermodynamic equilibrium constant and its true variation with temperature are appreciably different than previously indicated. This is due to the failure of earlier workers to adequately account for competing reactions, primarily the dehydration of ethanol to ethyl ether. Equilibrium constants were obtained at 100, 120.8, and 170°C. for the ethanol dehydration reaction. Equilibrium positions of the esterification reaction have been determined accurately at the same three temperatures, however the corresponding values of the thermodynamic equilibrium constant remain imperfectly specified because of uncertainty concerning the acetic acid association equilibrium.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 412-412 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 621-628 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work is an experimental assessment of the Langmuir-Hinshelwood model of heterogeneous catalysis. The vapor-phase dehydration of ethanol to diethyl ether, as catalyzed by cation exchange resin in the acid form, was the reaction chosen for study.Initial reaction rate data, determined from the integral kinetic data obtained experimentally, allowed selection of the most suitable rate equation from among several plausible equations derived in accordance with the above model. The Langmuir equilibrium adsorption constants in the rate equation were compared with the corresponding constants determined directly from pure component studies in a static adsorption system. The adsorption constants determined for the three reacting components by these independent methods showed definite order-of-magnitude agreement. The adsorption studies also provided significant information about the nature of the catalytic site.The extent of agreement in the constants determined by these two independent approaches is considered to be evidence of the theoretical validity of this model. Additional interpretation of the adsorption and kinetic data via this model suggests that the ethanol dehydration reaction proceeds through the reaction of adjacently adsorbed ethanol molecules.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 358-359 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 627-636 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The vapor phase dehydration of ethanol to diethyl ether, as catalyzed by ion exchange resin, has been studied experimentally and theoretically for the transient state period following a step increase in flow rate. A mathematical model is developed to account quantitatively for the effects of adsorption and surface reaction on the product distribution in the effluent of a tubular reactor. The solution of the model is in good agreement with the experimentally observed behavior.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 1081-1082 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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